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Title: Chapter 21(1)
Started: November 29, 2009 5:11 PM
Submitted: November 29, 2009 5:35 PM
Time spent: 00:23:53
Total score: 11/12 = 91.67% Total score adjusted by 0.0 Maximum possible score: 12

1. Balance Redox Acid 36


Balance the following equation in acidic solution using the lowest possible integers and give
the coefficient of water.
Zn(s) + NO3-(aq) ® Zn2+(aq) + N2(g)

Student Correct
Value Feedback
Response Answer
1. 5 0%
2. 6 100%
3. 2 0%
4. 3 0%
5. 4 0%

Score: 1/1

2. Balance Redox Base 15


Balance the following equation in basic solution using the lowest possible integers and give
the coefficient of water.

I-(aq) + O2(g)® I2(s) + OH–(aq)

Student Correct
Value Feedback
Response Answer
1. 1 0%
2. 3 0%
3. 4 0%
4. 2 100%

Score: 1/1

3. Balance Redox Acid 31


Balance the following equation in acidic solution using the lowest possible integers and give
the coefficient of H+.
Cr2O72- + Fe2+(aq) ® Cr3+(aq) + Fe3+(aq)

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Student Correct
Value Feedback
Response Answer
1. 14 100%
2. 6 0%
3. 10 0%
4. 7 0%
5. 8 0%

Score: 1/1

4. Balance Redox Base 25


Balance the following equation in basic solution using the lowest possible integers and give
the coefficient of hydroxide ion.

MnO4-(aq) + C2O42- ® MnO2(s) + CO32- (aq)

Student Correct
Value Feedback
Response Answer
1. 1 0%
2. 3 0%
3. 4 100%
4. 2 0%
5. 0 0%

Score: 1/1

5. Voltaic Cells Picture 2


Which letter represents the cathode in the figure shown

Student Correct
Value Feedback
Response Answer
1. S 0%
2. T 100%
3. X 0%
4. Y 0%

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5. Z 0%

Score: 1/1

6. Voltaic Cells Picture 10


Consider the Figure shown in which X represent Zn(s), T represents Co(s), and S is a
solution that is 1.0 M in Co2+.

At which electrode does oxidation occur? The reduction potentials of Co2+ and Zn2+ are
-0.27 V and -0.76 V, respectively.

Student Correct
Value Feedback
Response Answer
a. S 0%
b. T 0%
c. X 100%
d. Y 0%
e. Z 0%

Score: 1/1

7. Chapter 12 Eo values 14

Determine Eo for the following reaction, using the given standard reduction potentials:
Co3+(aq) + Zn(s) ® Co2+(aq) + Zn2+(aq)
Eo for Zn2+(aq) = -0.76 V;
Eo for Co3+(aq) = 1.81 V
Do not put in units.

Student Response Value Correct Answer


Equals 2.57 (100%)
1. 2.57 100%
Equals 2.57 (0%)

Score: 1/1

8. Ecell Calc 4

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Calculate Eo cell for the reaction:

Mn2+(aq) + Co3+(aq) => MnO2(s) + Co2+(aq) (in acidic solution)

Use the fact that the reduction potential for MnO2(s) is +1.23 V and for Co3+(aq) it is +1.82
V.
You should give your answer with 1 digit before the decimal point and to 2 decimal places.
Do NOT include units..... Also - do not use scientific notation!

Student Response Value Correct Answer


Equals 0.59 (100%)
1. -3.05 0% Equals .59 (100%)
Equals 5.90E-1 (100%)

Score: 0/1

9. Chapter 12 Eo values 55

Determine Eo for the following reaction, using the given standard reduction potentials:
Ag+(aq) + Mn(s) ® Ag(s) + Mn2+(aq)
Eo for Mn2+(aq) = -1.18 V
Eo for Ag+(aq) = 0.80 V
Do not put in units.

Student Response Value Correct Answer


Equals 1.98 (100%)
1. 1.98 100%
Equals 1.98 (0%)

Score: 1/1

10. Best Agent from List 3


Consider the following half-reactions. Which of these is the strongest reducing agent listed
here?
I2(s) + 2 e- => 2 I-(aq) Eo = 0.53 V
S2O82-(aq) + 2 e- => 2 SO42-(aq) Eo = 2.01 V
Cr2O72-(aq) + 14 H+ + 6 e-=> Cr3+(aq) + 7 H2O(l) Eo = 1.33 V

Student Correct
Value Feedback
Response Answer
1. I2(s) 0%
2. I-(aq) 100%
3. S2O82-(aq) 0%
4. SO42- 0%
5. Cr2O72- 0%

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6. Cr3+(aq) 0%

Score: 1/1

11. Redox Agents 5


Identify the oxidizing agent and the reducing agent in the reaction.

8H+(aq) + 6Cl–(aq) + Sn(s) + 4NO3–(aq) ® SnCl62–(aq) + 4NO2(g) + 4H2O(l)

Student Correct
Value Feedback
Response Answer
1. oxidizing 100%
agent:
NO3– ;
reducing
agent:
Sn
2. oxidizing 0%
agent:
Cl– ;
reducing
agent:
H+
3. oxidizing 0%
agent:
NO3–;
reducing
agent:
H+
4. oxidizing 0%
agent:
Sn ;
reducing
agent:
Cl–

Score: 1/1

12. Ered from Ecel and another E 1

Consider the reaction between sulfite and a metal anion, X2-, to form the metal, X, and
thiosulfate:
2 X2-(aq) + 2 SO32- + 3 H2O(l) => 2 X(s) + S2O32- (aq) + 6 OH-
for which Eo cell = 0.28.
Given that the Eo red for sulfite is -0.57 V, calculate Eo red for X. Even though it is incorrect to
do so, as usual, use THREE significant figures for your answer.

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Student Response Value Correct Answer


Answer -.850 100% -0.850

Score: 1/1

Done

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