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• Reaksi makin
sempurna
kekanan
• reaksi dpt
dipergunakan
utk titrasi
asam basa
2. ∆ pH hrs besar pd TE
Harus ada
loncatan pH
3. Salah titrasi ≤ 2%
{ [ ][ ]}
Fabsolut = ∑[asam]+ ∑[basa ]+ H 3O + + OH − grek / l
Fabsolut
Frelatif = × 100%
∑T
∑T: jml grek/l zat pentiter yg
ditambahkan
SALAH TITRASI KEBETULAN
Tahapan kerja:
{ [ ][ ]}
Aabsolut = ∑[asam ]− ∑[basa ]+ H 3O + − OH − grek / l
Aabsolut
Arelatif = × 100%
∑C
pH = - Log H+
Absis ordinat
Y = mx m=1
Grafik: grs melalui ttk (0,0) mempunyai
arah 45o kekanan
DIAGRAM LOGARITMIK OH
-
as + H2O ⇄ bs + H3O+
[bs]× [ H 3 O + ] as + bs = Cawal
Ka =
[as] bs = C - as
[C − as][ H 3O + ] C × [ H 3O + ]
Ka = [as ] =
[as] K a + [ H 3O + ]
Diagram logaritmik asam lemah
Absis: pH Ordinat: - log(asam)
Pendekatan
1. pH = pKa C × [ H 3O + ]
[as ] =
K a + [ H 3O + ]
[as] = C/2
C × [ H 3O + ] C × [ H 3O + ]
[as ] = [as ] =
K a + [ H 3O + ] Ka
diabaikan
-log[as] = pH + [-pKa – log C]
y mx n
diabaikan
− log (as ) = − log C
y n
contoh
Buatlah diagram logaritmik CH3COOH 10-4M
Ka = 2 x 10-5
1 [pKa,(-logC+log2)]
as + H2O ⇄ bs + H3O+
as + bs = C awal
+
[bs ]× [ H 3 O ] as = Cawal - bs
Ka =
[as ]
[bs ]× [ H 3O + ] Ka × C
Ka = (bs ) =
K a + ( H 3O + )
[C − bs ]
Diagram logaritmik basa lemah
Pendekatan:
1. pH = pKa (H3O+)= Ka
Ka × C
(bs ) = (bs ) = C
K a + ( H 3O + ) 2
− log(bs ) = − log C + log 2
Ka × C
(bs ) = (bs ) = C
K a + ( H 3O + )
diabaikan
− log(bs ) = − log C
y n
Ka × C Ka × C
(bs ) = (bs ) =
K a + ( H 3O + ) ( H 3O + )
diabaikan
− log(bs ) = − pH + ( pK a − log C )
1 [pKa,(-logC+log2)]
2
3
1
3 2
Dptkah indikator fenolftalein ( pH 8 – 9,6)
dipergunakan pada titrasi HAc dengan NaOH
0,1M?
Tahapan kerja
1. Buat diagram logaritmik HAc
2. Tarik grs // ordinat pada pH 8 ( sesuai
dengan range pH indicator)
3. Hitung salah titrasi sistimatik
4. Indikator dapat dipergunakan bila
perhitungan salah titrasi relatif ≤ 2 %
pH
-log C
{ [ ][
Aabsolut = ∑[asam]− ∑[basa ]+ H 3 O + − OH − grek / l ]}
= - [ 10-4,3 - 0 + 10-8 - 10-6
= - 2,4 x 10-5 grek/lt
pH ekivalent
Rx Protolisa H2PO4-
H2PO4- + H2PO4- ⇄ HPO4= + H3PO4
1.Hitung nilai K
2. Hitung salah titrasi kebetulan
10 ml
z = 0,1 M
Y = 0,05 M
NaOH Na2HPO4
(VxN)awal = (VxN)stlh +H2O (VxN)awal = (VxN)stlh +H2O
10 x NNaOH = 100 x 0,1 10 x NNa2HPO4 = 100 x 0,05
NNaOH = 1M NNa2HPO4 = 0,5M
Soal 3
Tuliskan tahapan kerja yang sdr lakukan
jika sdr ingin menentukan kadar
NaHCO3 dalam 10 ml larutan yang
mengandung Na2CO3 dan NaHCO3
Soal 4.