Advanced Materials and Structures and their Fabrication Processes

Book manuscript, Narvik University College, HiN

Dag Lukkassen and Annette Meidell August 23, 2007 Contents I Materials and Structures 8
11 11 12 13 14 14 15 18 19 19 20 20 23 23 25 26 28 28 30

1 Ceramics and glasses . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.1 Ceramics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.2 Glasses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3 Industrial Importance of Ceramics and Glasses . . . . . . . . . . . 1.4 Industrially Important Glasses . . . . . . . . . . . . . . . . . . . . 1.5 Technical Ceramics . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5.1 High-performance ceramics . . . . . . . . . . . . . . . . . . 2 Metals and metal alloys . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1 High-peformance Metals . . . . . . . . . . . . . . . . . . . . . . . 2.1.1 High-Performance Aluminum . . . . . . . . . . . . . . . . 2.1.2 High-Performance Steel . . . . . . . . . . . . . . . . . . . . 2.1.3 Space-age metals . . . . . . . . . . . . . . . . . . . . . . . 3 Polymers and Plastics . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1 The structure of polymers . . . . . . . . . . . . . . . . . . . . . . 3.2 Crystallinity in polymers . . . . . . . . . . . . . . . . . . . . . . . 3.2.1 The glass transition temperature and melting temperature 3.3 Plastics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.4 Properties of plastics . . . . . . . . . . . . . . . . . . . . . . . . . 3.4.1 Thermosettings . . . . . . . . . . . . . . . . . . . . . . . .

3.4.2 Types of Thermosettings . . . . . . . . . . 3.4.3 Thermoplastics . . . . . . . . . . . . . . . 3.4.4 Types of Thermoplastics . . . . . . . . . . 3.5 Classification . . . . . . . . . . . . . . . . . . . . 3.6 Additives in Plastics . . . . . . . . . . . . . . . . 3.6.1 Oriented Plastics . . . . . . . . . . . . . . 3.7 Elastomers & Rubbers . . . . . . . . . . . . . . . 3.7.1 Rubber and Artificial Elastomers . . . . . 3.8 Biopolymers . . . . . . . . . . . . . . . . . . . . . 3.8.1 What makes a polymer a biopolymer? . . 3.8.2 Applications of biopolymers . . . . . . . . 3.8.3 Properties of biopolymers . . . . . . . . . 3.8.4 Additional information on raw materials in 3.8.5 Plastic taste better with sugar . . . . . . . 4 Composites . . . . . . . . . . . . . . . . . . . . . . . . 4.1 The history of composites . . . . . . . . . . . . . 4.2 Natural composites . . . . . . . . . . . . . . . . . 4.3 Man-made Composites . . . . . . . . . . . . . . . 4.3.1 Fiber-Reinforced Composites . . . . . . . . 4.3.2 Classification of composites . . . . . . . . 4.4 Ceramic matrix composites CMC . . . . . . . . . 4.5 Metal Matrix Composites MMC . . . . . . . . . . 4.6 Polymer Matrix Composites PMC . . . . . . . . . 4.7 Fiber reinforcement . . . . . . . . . . . . . . . . . 4.7.1 Choosing fibers . . . . . . . . . . . . . . . 4.7.2 Glass fibers . . . . . . . . . . . . . . . . . 4.7.3 Carbon fibers . . . . . . . . . . . . . . . . 4.7.4 Boron fiber . . . . . . . . . . . . . . . . . 4.7.5 Ceramic fibers . . . . . . . . . . . . . . . . 4.7.6 Polymer Fibers . . . . . . . . . . . . . . . 4.7.7 Carbon nanotube (CNT) fibers . . . . . . 4.7.8 Fiber hybrids . . . . . . . . . . . . . . . . 4.7.9 Spider silk . . . . . . . . . . . . . . . . . . 4.8 Aerogel composites . . . . . . . . . . . . . . . . . 4.9 Textile composites . . . . . . . . . . . . . . . . . 4.10 Bio-inspired materials . . . . . . . . . . . . . . . 4.11 Self-healing composites . . . . . . . . . . . . . . . 2

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . biopolymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

30 32 34 39 39 41 41 43 47 47 48 48 50 51 55 56 56 58 60 60 61 64 65 66 67 69 70 71 71 72 74 75 75 76 78 78 79

5

6 7

8

9

4.12 Left-handed metamaterials . . . . . . . . . . . . . Smart (intelligent) Materials and Structures . . . . . . 5.1 Color Changing Materials . . . . . . . . . . . . . 5.1.1 Photochromic materials . . . . . . . . . . 5.1.2 Thermochromic materials . . . . . . . . . 5.2 Light Emitting Materials . . . . . . . . . . . . . . 5.2.1 Electroluminescent materials . . . . . . . . 5.2.2 Fluorescent materials . . . . . . . . . . . . 5.2.3 Phosphorescent materials . . . . . . . . . . 5.3 Moving Materials . . . . . . . . . . . . . . . . . . 5.3.1 Conducting polymers . . . . . . . . . . . . 5.3.2 Dielectric elastomers . . . . . . . . . . . . 5.3.3 Piezoelectric materials . . . . . . . . . . . 5.3.4 Polymer gels . . . . . . . . . . . . . . . . . 5.3.5 Shape memory materials (SMM) . . . . . 5.3.6 Nanostructured Shape Memory Materials . 5.3.7 Magnetic Shape Memory (MSM) Materials 5.4 Temperature Changing Materials . . . . . . . . . 5.4.1 Thermoelectric materials . . . . . . . . . . Functional Gradient Materials . . . . . . . . . . . . . . Solar Cell Materials . . . . . . . . . . . . . . . . . . . . 7.1 Light-absorbing materials . . . . . . . . . . . . . 7.2 Silicon . . . . . . . . . . . . . . . . . . . . . . . . 7.3 Thin films . . . . . . . . . . . . . . . . . . . . . . 7.4 Silicon solar cell device manufacture . . . . . . . . Nano - materials - and technology . . . . . . . . . . . . 8.1 Carbon Nanotubes (CNT) . . . . . . . . . . . . . 8.1.1 Strength . . . . . . . . . . . . . . . . . . . 8.2 Nanocomposites . . . . . . . . . . . . . . . . . . . 8.3 Flexible ceramics . . . . . . . . . . . . . . . . . . 8.4 New type of High-performance Ceramic . . . . . . 8.5 Back to square one? . . . . . . . . . . . . . . . . Cellular Solids, Structures & Foams . . . . . . . . . . . 9.1 Metal Foams . . . . . . . . . . . . . . . . . . . . . 9.1.1 Aluminium foam: . . . . . . . . . . . . . . 9.2 Polymeric foam . . . . . . . . . . . . . . . . . . . 9.3 Refractory foams / Ceramic foam . . . . . . . . . 3

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

81 87 88 88 88 88 89 89 90 91 91 92 92 93 94 95 96 97 97 98 101 101 102 103 104 106 107 108 109 110 111 112 116 117 118 119 122

9.3.1 Carbon foam . . . . . . . . . . . . . . . . . . . . . . . . . 123 9.4 Hierarchical structures (multiscale structures) . . . . . . . . . . . 123 9.5 Biomaterials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124

II

Sandwich Constructions

127

10 Why use sandwich constructions? . . . . . . . . . . . . . . . . . . . . . 128 10.1 Face materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 10.2 Core materials and structures . . . . . . . . . . . . . . . . . . . . 131 10.2.1 Foam Cores . . . . . . . . . . . . . . . . . . . . . . . . . . 132 10.2.2 Honeycomb Cores . . . . . . . . . . . . . . . . . . . . . . . 132 10.2.3 Corrugated Cores . . . . . . . . . . . . . . . . . . . . . . . 135 10.2.4 Wood Cores . . . . . . . . . . . . . . . . . . . . . . . . . . 136 10.3 Adhesives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 11 Design of sandwich constructions . . . . . . . . . . . . . . . . . . . . . 140 11.1 Design of sandwich beams . . . . . . . . . . . . . . . . . . . . . . 140 11.2 Preliminaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 11.3 The Flexural Rigidity and Shear Rigidity . . . . . . . . . . . . . . 143 11.4 Tensile and Compressive Stresses . . . . . . . . . . . . . . . . . . 144 11.4.1 Due to bending (transversal loading) . . . . . . . . . . . . 144 11.4.2 Due to in-plane loading (axial) . . . . . . . . . . . . . . . 147 11.5 Shear stresses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 11.5.1 Summary of approximations . . . . . . . . . . . . . . . . . 153 11.6 Sandwich design: stiffness, strength and weight . . . . . . . . . . 155 11.7 Example of beam calculations . . . . . . . . . . . . . . . . . . . . 157 11.8 Strength and stiffness design example . . . . . . . . . . . . . . . . 160 12 Failure modes of sandwich panel . . . . . . . . . . . . . . . . . . . . . . 163 12.1 Failure loads and stresses . . . . . . . . . . . . . . . . . . . . . . . 164 12.2 Failure-mode maps . . . . . . . . . . . . . . . . . . . . . . . . . . 167 12.2.1 Transition equation between face yielding and face wrinkling 167 12.2.2 Transition equation between face yield and core shear . . . 169 12.2.3 Transition equation between face wrinkling and core shear 169 13 Design Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 13.1 The stiffness of sandwich structures and its optimization . . . . . 174 13.1.1 Example of minimum weight design for given stiffness . . . 177

4

III

Cellular Solids

180
180 183 183 184 187 188

14 Some definitions of cellular solids . . . . . . . . . . . . . . . . . . . . . 14.1 Mechanics of honeycombs . . . . . . . . . . . . . . . . . . . . . . 14.2 In-plane deformation properties, uniaxial loading of hexagonal honeycombs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14.2.1 Linear-elastic deformation . . . . . . . . . . . . . . . . . . 14.3 Out-of-plane deformation properties . . . . . . . . . . . . . . . . . 14.3.1 Linear-elastic deformation . . . . . . . . . . . . . . . . . .

IV Mechanics and Effective Properties of Composite Structures and Honeycombs 191
15 16 17 18 19 On effective Properties of Composite Structures . . . The thermal problem . . . . . . . . . . . . . . . . . . Isotropic elastic materials . . . . . . . . . . . . . . . . Orthotropic composites . . . . . . . . . . . . . . . . . Square symmetric unidirectional two-phase structure 19.1 Calculation of stiffness and compliance matrix . 20 Numerical methods for periodic structures . . . . . . 20.1 Coordinate transformation . . . . . . . . . . . . 21 A computational example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 191 193 194 196 198 200 202 206

V

Fabrication processes
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

210
210 218 221 221 223 224 229 229 233 235 235 236 236

22 Fabrication of plastics . . . . . . . . . . . . . . . . 22.1 Processing of Rubber and elastomers . . . . . 23 Fabrication of Fiber-Reinforced Composites (FRC) 23.1 Manufacturing processes of Reinforcements . 23.2 Prepregs, Preforms and Compounds . . . . . . 23.3 Fabrication processes of FRC . . . . . . . . . 23.4 Fabrication of Functionally Gradient Materials 23.5 Fabrication of sandwich constructions . . . . . 24 Layer Manufacturing Technology (LMT) . . . . . . 24.1 Ballistic particle manufacturing (inkjet) BMP 24.2 Fused deposition modelling - FDM . . . . . . 24.3 LOM - Laminated object manufacturing . . . 24.4 Selective laser sintering - SLS . . . . . . . . .

5

24.5 Laser Engineered Net Shaping (LENS) . . . 24.6 Stereo lithography - SLA . . . . . . . . . . . 24.7 Solid ground curing - SGC . . . . . . . . . . 24.8 Three dimensional printing (3DP) . . . . . . 24.9 PowderProcessing/PowderMetallurgy . . . . 24.10Vapor Deposition CVD/PVD . . . . . . . . 24.11Selection of a layered manufacturing process 25 Design Considerations . . . . . . . . . . . . . . . 25.1 Designing for Manufacturability (DFM) ) . . 25.2 Product design guidelines . . . . . . . . . . 25.3 Evaluation of design alternatives . . . . . . . 25.4 The meaning of colors . . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

. . . . . . . . . . . .

237 238 239 240 241 243 243 247 247 248 249 250

6

Preface
This manuscript is written in order to use it as lecture notes in the course ”Advanced materials” given at Narvik University College for master students in the field of Engineering Design. In the course the students will be familiar with different kind of advanced materials and structures such as for instance smart materials, functional gradient materials, polymers and plastics, nano-materials, elastomers and rubbers, biopolymers, cellular solids and structures, and different types of composite materials, which can be found in Part 1 of this report. In Part 2, the fabrication-processes of different advanced materials, structures and forms is described. The different types of sandwich constructions included the design of such structures are subjects that are discussed in Part 3, while in Part 4 we will have a closer look at mechanics and effective properties of composite structures and honeycombs. This report may also be used as literature for students studying mechanical engineering, material science, production engineering. We assume that the reader has a bachelor degree in Engineering.

7

Figure 0.1: Classes of materials.

Part I

Materials and Structures
In this part we will mainly consider the concepts of materials and structures. The difference between a material and a structure is not clearly defined. Many draw the lines between what you understand as a homogeneous material when you see it with your bare eyes, and the inhomogeneous material structure that you clearly see is made up of a fixed geometry or mixing of materials. For instance an alloy is by this definition a material even though it consists of two or more components, but a honeycomb core built up of two different components is a structure. Materials are often classified into the six broad classes that are shown in figure 0.1; metals, ceramics, glasses, elastomers, polymers and composites. But, when we also include material structures, the number is bigger, and the classification of the term ”materials and structures”, even though it is not a conventional way of making a classification, may look like the one purposed in figure 0.2. We will in this book briefly mention main properties of each group in figure 0.2, but the advanced term in the title of the book refers to a thoroughly study of composites, polymers, smart materials, sandwich constructions, nano-technology, functional materials, cellular structures.

8

Figure 0.2: Classes of materials and structures.

High Performance Materials (HPM)
High-performance materials (or Advanced Engineering Materials) are materials that provide specific performance advantages in comparison with the counterpart conventional materials. Often it is difficult to place materials strictly into the group of high-performance group or other groups, but we often divide materials into the following main groups: • Standard materials, which are used in products that is exposed to noncritical environments and low-stress applications • Standard Engineering Materials, which are used in products that must have general bearing and wear properties • High-performance materials or advanced engineering materials, which are used in products that must have superior properties (extreme service environments, superior chemical resistance, wear resistance, and loading properties) There are several types of materials currently called high-performance materials, for instance high-performance concrete, high-performance composites, highperformance plastics, high-performance aluminum, high-performance ceramics, and high-performance steel. What they all have in common is that they have outstanding properties compared to the materials we used earlier. In short time 9

maybe the materials we know as HPM today may not be so high-performance tomorrow, since the materials-science is rapidly changing and growing. While research laboratories are still exploring ways to exploit these materials, some of them are ready for use. Because there is little data available on the long-term results of many high-performance materials and because there is frequently a relatively high initial cost, states are reluctant to take on such a venture independently. Questions: What is the conventional way of making a classification of materials? What is the new way of making a classification of materials? What is so special about high performance materials? References: High-performance materials: http://www.hiper-group.com/hcproducts.htm http://www.greatachievements.org/?id=3809 free internet books: http://books.nap.edu/

10

1. Ceramics and glasses
A ceramic is often broadly defined as any inorganic nonmetallic material. By this definition, ceramic materials would also include glasses; however, many materials scientists add the stipulation that ”ceramics” must also be crystalline. Recall that crystalline materials have their molecules arranged in repeating patterns, see Figure 1.1. Therefore we often divide the ceramics and glasses into two separate

Figure 1.1: Crystalline structure. subgroups of materials. 1.1. Ceramics Examples of ceramic materials can be anything from NaCl (table salt) to clay (a complex silicate).The term ceramic comes from the Greek word keramikos, which means burnt stuff, indicating that desirable properties of these materials are normally achieved through a high-temperature heat treatment process called firing. Ceramics are refractory (fireproof) materials, and has therefore a melting ◦ temperature > 1580 C. Due to the covalent character of the chemical bond refractory ceramics exhibit very high (about 3000◦ C) melting point, low mobility of atoms, low plasticity and high hardness at temperatures up to 2000◦ C. Therefore, refractory materials can substitute metals, alloys and intermetallics in a lot of high temperature engineering, chemical and electronic applications. Ceramics are in general hard, brittle, high-melting-point materials with low electrical and thermal conductivity, low thermal expansion, good chemical and thermal stability, good creep resistance, high elastic modulus, high compressive strength, low density, high stiffness, high hardness, high wear resistance, and high 11

corrosion resistance. Many ceramics are good electrical and thermal insulators. Some ceramics have special properties: some ceramics are magnetic materials; some are piezoelectric materials; and a few special ceramics are superconductors at very low temperatures. Ceramics are widely used in the electrical industry mostly due to their high electrical resistance. Ceramics and glasses have one major drawback: they are brittle. Their extremely low fracture toughness is the drawback of ceramics in comparison with metals. It means that ceramics have a very low tolerance of crack-like flaws. Ceramic fibers such as graphite and aluminum oxide with their extremely high stiffness have led to the production of fiber-reinforced composites. These materials are only a few of an ever-growing list of industrially important ceramics. Recently, new groups of ceramics have emerged with the possibility to use them as loadbearing materials. 1.2. Glasses Glass is an inorganic nonmetallic material that does not have a crystalline structure. Such materials are said to be amorphous. Recall that amorphous materials have their molecules arranged randomly and in long chains which twist and curve

Figure 1.2: Amorph structure. around one-another, making large regions of highly structured morphology unlikely, see Figure 1.2. Examples of glasses range from the soda-lime silicate glass in soda bottles to the extremely high purity silica glass in optical fibers. The major raw material of glass is sand (or "quartz sand") that contains almost 100 % crystalline silica in the form of quartz. Most glass formulations contain about 70—72 % by weight of silicon dioxide (SiO2). Soda-lime glass which is the most common form of glass contains nearly 30 % sodium and calcium oxides 12

Figure 1.3: A transmission cable containing hundreds of glass optical fibers. or carbonates. Pyrex is borosilicate glass containing about 10 % boric oxide. Lead crystal is a form of lead glass that contains a minimum of 24 % lead oxide. Large natural single crystals of quartz are pure silicon dioxide, and upon crushing are used for high quality specialty glasses. Synthetic amorphous silica, an almost 100 % pure form of quartz, is the raw material for the most expensive specialty glasses. 1.3. Industrial Importance of Ceramics and Glasses Silicon [Si] (do not confuse it with Silicone which are mixed inorganic-organic polymers) has many industrial uses, for instance is it the principal component of most semiconductor devices (whose electrical conductivity is in between that of a conductor and that of an insulator), most importantly integrated circuits or microchips. Silicon has been THE material which has made computers possible. In the form of silica and silicates, silicon forms useful glasses, cements, and ceramics. It is also a component of silicones, a class-name for various synthetic plastic substances made of silicon, oxygen, carbon and hydrogen, often confused with silicon itself. Glasses have historically been used for low technology applications such as soda bottles and window panes. However, glasses, like ceramics, have recently found new application in high technology fields (particularly the semiconductor microelectronics industry where silica is widely used as an insulator in transistors and the fiber optic cable industry where high purity silica glass has made advanced telecommunications possible, see Figure 1.3). As with ceramics, the list of industrially important glasses also continues to grow. As a result of their unique properties, ceramics and glasses are materials which will be used extensively in areas such as aerospace, automobiles, microelectronics, and telecommunications. 13

1.4. Industrially Important Glasses Silicon [Si] (do not confuse with Silicone which are mixed inorganic-organic polymers) has many industrial uses, for instance is it the principal component of most semiconductor devices (whose electrical conductivity is in between that of a conductor and that of an insulator), most importantly integrated circuits or microchips. In the form of silica and silicates, silicon forms useful glasses, cements, and ceramics. It is also a component of silicones, a class-name for various synthetic plastic substances made of silicon, oxygen, carbon and hydrogen, often confused with silicon itself. • Silica glass (SiO2 ) is used for optical fibers when it is very pure. • Soda-lime glass (SiO2 -Na2 O-CaO) is the standard glass used for bottles and windows due to its low cost and easy manufacturing. • Borosilicate glass (SiO2 -B2 O3 ) is good in applications where thermal shock resistance is necessary (e.g. laboratory glassware) because of its low coefficient of thermal expansion • Lead glass (SiO2 -PbO) commonly known as ”crystal”, this glass has a high index of refraction causing it to sparkle (much like a diamond) 1.5. Technical Ceramics Technical Ceramics covers ceramic materials and products for technical application. Terms such as: · functional ceramics (Components which fulfill an electrical, magnetic, dielectrical, optical etc. function) · structural ceramics, engineering ceramics, or industrial ceramics (Components which are subjected mainly to mechanical loads.) · electro-ceramics · cutting ceramics · bio-ceramics · high-performance ceramics (see below) describe the products groups of Technical Ceramics, but due to overlapping there is not a clear classification.

14

Figure 1.4: Products made of ceramic material. 1.5.1. High-performance ceramics High-performance ceramics are ceramics with incredibly light weight, high hardness, non-corrodable, high melting points, high price and advanced applications, see Figure 1.4. Components made from high-performance ceramics are often determining the functionality of machinery by possessing excellent corrosion resistance, very high thermal stability and wear resistance, as well as high biocompatibility. Density, porosity, electrical and optical characteristics can be varied within a wide range. Highly specialized and flexible production techniques enable us to match our products to the specific customer demands. In ENV 12212 (classification system for European comity for standardization, CEN) high-performance ceramics are defined as ”highly developed, highperformance applicable ceramic material, which is mainly non-metallic and inorganic, and has certain functional properties.” The term is seen as a differentiation to traditional clay based ceramic that includes china-ware, sanitary ceramic tiles and bricks and covers all technical ceramics. The materials for electrical engineering are standardized according to the international standard IEC 627 (International Electrotechnical Commission, IEC). The terms used above are often still used in classify technical ceramics. However a precise classification is only possible if the materials are listed under their following chemical composition: • silicate ceramics — technical porcelain (quartz, feldspar and kaolin. ) 15

— steatite (major component: soapstone, additives: clay and flux) — cordierite (these magnesium silicates occur during the sintering of soapstone with added clay, kaolin, corundium and mullite.) — mullite-ceramic (Al2 O3 and SiO2 ,where mullite: (3 Al2 O3 2 SiO2 ) and corundium (Al2 O3 ) ) • oxide ceramics — aluminium oxide (AL2 O3 ) — magnesium oxide (MgO) — zirconium oxide (ZrO2 ) — aluminium titanate (AT) — piezo ceramic (PZT), (the most important piezoelectrical ceramic materials are based on the oxide mixed crystals system lead zirconate and lead titanate) • nonoxide ceramics: — carbide: Silicon carbide (SIC), Sintered silicon carbide (SSIC), Reaction bonded silicom infiltrated silicon carbide (SSIC), Recrystallized silicon carbide (RSIC), and Nitride bonded silicom carbide (NSIC) — nitride: Silicon nitride (Si3 N4 ), Silicon aluminium oxynitride (SIALON), and Aluminium nitride (ALN). Questions: • What is the special properties of ceramics and glasses? • What are they used for? • What are the industrally important glasses? • What kind of different ceramics are there? • What is a high-performance ceramic? • What is the drawback of ceramics compared to metals? References: http://www.keramverband.de/keramik/englisch/fachinfo/ werkstoffe/definitionen.htm 16

http://www.globaltechnoscan.com/ 31stOct-6thNov02/high_performance_ceramics.htm http://www.globaltechnoscan.com/ http://www.sciam.com/explore_directory.cfm http://www.mse.cornell.edu/courses/engri111/ceramic.htm http://www.mse.cornell.edu/courses/engri111/impglass.htm http://biotsavart.tripod.com/327.htm http://www.engr.sjsu.edu/WofMatE/

17

Figure 2.1: A suspension bridge.

2. Metals and metal alloys
Metals are elements that generally have good electrical and thermal conductivity. Many metals have high strength, high stiffness, and have good ductility. Some metals, such as iron, cobalt and nickel are magnetic. Many metals and alloys have high densities and are used in applications which require a high mass-to-volume ratio. At extremely low temperatures, some metals and intermetallic compounds become superconductors (a superconductor can conduct electricity without electrical resistance at temperatures above absolute zero. The change from normal electrical conductivity to superconductivity occurs suddenly at a critical temperature Tc ). Pure metals are elements which comes from a particular area of the periodic table. Examples of pure metals include copper in electrical wires and aluminum in cooking foil and beverage cans. Metal Alloys contain more than one metallic element. Their properties can be changed by changing the elements present in the alloy. Examples of metal alloys include stainless steel which is an alloy of iron, nickel, and chromium; and gold jewelry which usually contains an alloy of gold and nickel. Some metal alloys, such as those based on aluminum, have low densities and are used in aerospace applications for fuel economy. Other examples: Many metal alloys also have high fracture toughness, which means they can withstand impact and are durable. Many beverage cans are made of aluminum metal. Many structures, such as this suspension bridge, are made of steel alloys, see Figure 2.1. Aircraft skins are made of lightweight aluminum alloys with high fracture toughness. 18

2.1. High-peformance Metals When metal components must perform under critical conditions, manufacturers need high-performance metals. Titanium-base alloys, and specialty steels for the aerospace industry are metals of exceptional wear resistance, corrosion resistance, heat resistance, toughness, and strength. Nickel- and cobalt-based materials are known as superalloys. Turbine blades are for instance made of superalloys in ◦ order to withstand the temperatures well above 2,000◦ F (1093.3 C). The most advanced of these turbine blades are grown from molten metal as single crystals in ceramic molds, in order to obtain maximum possible resistance to hightemperature deformation. 2.1.1. High-Performance Aluminum Aluminum bridge decks have a number of advantages over concrete and steel decks. Aluminum is about 80 percent lighter than concrete. This substantial weight savings allows many bridges to be strengthened without extensive reengineering of substructures. Aluminum requires fewer welds than steel, eliminating many potential failure points. Compared to steel, aluminum is less expensive, both in the short term and the long term. An aluminum deck is also more resistant to corrosion and other environmental degradation. Aluminium alloys are often used in Defense and Aerospace, which is one of the most demanding industries, see Figure 2.2. These industries use high strength 5xxx series (Al-Mg) which are non-heat treatable base alloys for some applications, but also make use of some of the more specialized heat treatable aluminum alloys with superior mechanical properties. Aluminum armor plating is used for its impact strength and strength-to-weight ratio, and here alloy 5083, 7039 (Al-Zn) and and 2519 (AL-Cu ) are used as base materials. Missiles are constructed of alloys 2019 and 2219. Perhaps the most exotic aluminum alloys, with exceptional strength over a wide range of operating temperatures, are used in the aerospace industry. Some of these alloys are 2219, 2014, 2090, 2024, and 7075. These base materials are typically used in specialized high performance applications and have their own welding characteristics and associated problems that require special considerations when joining.

19

Figure 2.2: Aerospace industry. 2.1.2. High-Performance Steel A new grade of high performance steel, HPS-485W or HPS-70W, uses a new chemical composition that provides improved welding and toughness properties. The increase in strength and performance will allow targeted use of HPS that will extend the useful life of steel bridge structures; and even greater savings with the reduction of the total steel weight. Structural components in new cars are for example made from high-performance steel that is 3 times stronger than ordinary steel (900 MPa instead of 300 which is ususal). This makes the new cars very crash resistant such that the passengers are much more protected if there should be a collision. 2.1.3. Space-age metals In jet aircrafts, rockets, missiles and nuclear reactors, the metals columbium (Nb, 41), titanium (Ti, 22), hafnium (Hf, 72), zirconium (Zr, 40) and tantalum (Ta, 73) are used. Columbium (niobium) can withstand high temperatures and can be used for the skin and structural members of aerospace equipment and missiles. It is a lightweight metal and a superconductor of electricity (which means that it could be possible to use it in storing and transferring large amounts of energy in the future). Titanium is as strong as steel and 45% lighter, and is often used for jet engine components (rotors, fins, and compressor parts) and other aerospace 20

parts. Hafnium and zirconium are always found together are they make it possible to control nuclear reactors in a precise way. The superior corrosion resistance of zirconium makes it (and its alloys) very useful in the chemical industry and for surgical implants. Pure zirconium has for a long time been used as the light source in photo flash tubes, since it is a reactive metal that burns in air with a brilliant white light. Tantalum (often occurs as the mineral columbitetantalite) is ◦ very malleable and ductile. Its melting point is at 2996 C, and is often used as a replacement for platinium in chemical, and dental equipment and instruments. It is also used to make electrolytic capacitors and are used in vacuum furnaces. A superconducting material transmits electricity with virtually no energy loss. Superconductivity, which occurs in many metals and alloys, is very new and is therefore not yet in widespread use. Superconductivity is a phenomenon occurring in certain materials at extremely low temperatures, characterized by exactly zero electrical resistance and the exclusion of the interior magnetic field (the Meissner effect). Superconductivity occurs in a wide variety of materials, including simple elements like tin and aluminium, various metallic alloys and some heavilydoped semiconductors. Superconductivity does not occur in noble metals (metals that are resistant to corrosion or oxidation, for instance gold, silver, tantalum, platinum, palladium and rhodium; unlike most base metals), nor in most ferromagnetic metals. Questions: •Why are metals and metal alloys used? •What is so special about high performance metals? • In the space-age, what features in a material or material structure would be important in the future? •What kind of metals are used in space equipment, and why are they used? References: http://www.mse.cornell.edu/courses/engri111/metal.htm http://www.allvac.com/ http://www.greatachievements.org/ http://www.hiper-group.com/hcproducts.htm http://www.spacedaily.com/news/materials-02zh.html http://www.alcotec.com/ataafi.htm http://www.weldreality.com/aluminumalloys.htm High Performance Steel Designers’ Guide: http://www.fhwa.dot.gov/bridge/guidetoc.htm 21

http://www.mmc.co.jp/alloy/english/products/taisyoku/gijyutsu3.html R. Gregg Bruce, Mileta M. Tomovic, John E. Neely and Richard R. Kibble, Modern materials and manufacturing processes, ISBN: 0-13-186859-4, Second edition, Prentice Hall, 1998.

22

Figure 3.1: Polymerization by addition of equal monomers.

3. Polymers and Plastics
Polymer etymology: The word polymer comes from Greek: poly means ‘many’ and mer comes from merous which roughly means ‘parts’. Polymers are organic materials characterized by long chain-like molecules built up from many units (monomers), see Figure 3.1, generally repeated hundreds or thousands of times. All atoms in a chain are bonded by covalent bond to each other, while Van der Waals bonding keeps the chains together. Starch, cellulose, and proteins are natural polymers. Nylon and polyethylene are synthetic polymers. From organic chemistry, polymer is defined as: ”a large molecule formed by the union of at least five identical monomers; it may be natural, such as cellulose or DNA, or synthetic, such as nylon or polyethylene; polymers usually contain many more than five monomers, and some may contain hundreds or thousands of monomers in each chain.” 3.1. The structure of polymers Polymerization is the word for the process of forming large molecules from small molecules. When there are no possibility to add any more atoms, the molecules are said to be saturated. When molecules do not have the maximum number of atoms, because atoms in the molecule are held together with double or triple covalent (shared) bonds, they are called unsaturated. The unsaturated molecules are important in the polymerization process, which means that small molecules are linked together to form large molecules, as you can see in Figure 3.1, where the process has taken place through addition mechanism. Here, a large molecule 23

Figure 3.2: Methane and ethane. (polymer) is formed by a repeated unit (mer). Activators or catalysts (benzoyl peroxide) are often required to drive the reaction. A polymer can also be made from a condensation process which means that reactive molecules combine with one another to produce a polymer plus small, by-product molecules, such as water. Often, heat, pressure or a catalyst are required to drive the reaction. In most commercial available plastics the number of mers in the polymer (which is known as the degree of polymerization) range from 75 to 750. When two different types of mers are combined into the same addition chain, we call them copolymers. And, in terpolymers three different monomers are included. The molecular structure of polymers are often based on paraffin-type hydrocarbons where carbon and hydrogen are linked in the relationship Cn H2n+2 , as we see in Figure 3.2. Hydrogen can be replaced by chlorine, flouring and also benzene. Carbon can be replaced by oxygen, silicon, sulfur or nitrogen. These possibilities are the reason why a wide range of organic compounds can be created. By the description of polymers we see that wood (cellulose-type materials, see Figure 3.3) are included in the group of polymer. It has been accepted for many years that cellulose is a long chain polymer, made up of repeating units of glucose, a simple sugar. As a carbohydrate, the chemistry of cellulose is primarily the chemistry of alcohols; and it forms many of the common derivatives of alcohols, such as esters, ethers, etc. These derivatives form the basis for much of the industrial technology of cellulose in use today. Cellulose derivatives are used commercially in two ways, as transient intermediates or as permanent products.

24

Figure 3.3: The structure of cellulose. 3.2. Crystallinity in polymers We need to distinguish between crystalline (see Figure 1.1) and amorphous materials (see Figure 1.2) and then show how these forms coexist in polymers. The reasons for the differing behaviors lie mainly in the structure of the solids. The morphology of most polymers is semi-crystalline. That is, they form mixtures of small crystals and amorphous material, see Figure 3.4 and melt over a range of temperature instead of at a single melting point. The crystalline material shows a high degree of order formed by folding and stacking of the polymer chains. The amorphous or glass-like structure shows no long range order, and the

Figure 3.4: A polymer with the combination of amorphous and crystalline areas, from: http://plc.cwru.edu/tutorial/enhanced/files/polymers/orient/orient.htm 25

chains are tangled. There are some polymers that are completely amorphous, but most are a combination with the tangled and disordered regions surrounding the crystalline areas. Most thermoplastics have crystalline regions alternating with amorphous regions, while 3.2.1. The glass transition temperature and melting temperature The glass transition temperature Tg (also called the glass temperature), describes the temperature at which amorphous polymers undergo a second order phase transition from a rubbery, viscous amorphous solid to a brittle, glassy amorphous solid. Tg is a property of amorphous polymers which do not have a sharp melting point, and is defined as the temperature at which the specific volume vs temperature plot has a change in slope, see Figure 3.5. When we cool an amorphous material from the liquid state, there is no abrupt change in volume such as occurs in the case of cooling of a crystalline material through its freezing point, Tf (=Tm ). Instead, at the glass transition temperature, Tg , there is a change in slope of the curve of specific volume vs. temperature, moving from a low value in the glassy state to a higher value in the rubbery state over a range of temperatures. This comparison between a crystalline material (1) and an amorphous material (2) is illustrated in Figure 3.5. Note that the intersections of the two straight line segments of curve (2) defines the quantity Tg . When a polymer is cooled below Tg , the molecules have little relative mobility, and the material becomes hard and brittle, like glass. Some polymers are used above their glass transition temperatures, and some are used below. Tg is usually referred to wholly or partially amorphous phases in glasses and polymers. As the temperature of a polymer drops below Tg , it behaves in an increasingly brittle manner. As the temperature rises above the Tg , the polymer becomes more rubber-like. In general, values of Tg well below room temperature define the domain of elastomers and values above room temperature define rigid, structural polymers. The glass transition is not the same thing as melting. Among synthetic polymers, (crystalline) melting temperature Tm crystalline melting is only discussed with regards to thermoplastics, as thermosetting polymers will decompose at high temperatures rather than melt. Tm (also called flow temperature for amorphous materials) happens when the polymer chains fall out of their crystal structures, and become a disordered liquid. Even crystalline polymers will have a some amorphous portion. This portion usually makes up 40-70% of the polymer sample. This is why the same sample of a 26

Figure 3.5: Comparison between a crystalline material (1) and an amorphous material
(2). From: http://plc.cwru.edu/tutorial/enhanced/files/polymers/therm/therm.htm

polymer can have both a glass transition temperature and a melting temperature. But you should know that the amorphous portion undergoes the glass transition only, and the crystalline portion undergoes melting only. According to Wikipedia, the disaster of the space Shuttle Challenger was caused by rubber O-rings that were below their Tg , on an unusually cold Florida morning, and thus could not flex enough to form proper seals between sections of the two solid-fuel rocket boosters (SRB), see Wikipedia. SRB’s are used to provide the main thrust (reaction force) in spacecrafts launches from the earthe up to about 45 kilometres. Polymer science is a broad field that includes many types of materials which incorporate long chain structure of many repeat units as discussed above. The two major polymer classes are: • Elastomers • Plastics Another important property of polymers, also strongly dependent on their temperatures, is their response to the application of a force, as indicated by two 27

Figure 3.6: Plastics. main types of behavior: elastic and plastic. Elastic materials will return to their original shape once the force is removed. Plastic materials will not regain their shape. In plastic materials, flow is occurring, much like a highly viscous liquid. Most materials demonstrate a combination of elastic and plastic behavior, showing plastic behavior after the elastic limit has been exceeded. 3.3. Plastics Plastics, see Figure 3.6, are a large group of polymers that has properties between elastomers and fibers, and has plastic behavior. As such, plastics have a wide range of properties such as flexibility and hardness and can be synthesized to have almost any combination of desired properties. Plastics are polymers which, under appropriate conditions of temperature and pressure, can be molded or shaped (such as blowing to form a film). In contrast to elastomers, plastics have a greater stiffness and lack reversible elasticity. All plastics are polymers but not all polymers are plastics. Cellulose is an example of a polymeric material which must be substantially modified before processing with the usual methods used for plastics. Every day plastics such as polyethylene and poly(vinyl chloride) have replaced traditional materials like paper and copper for a wide variety of applications. 3.4. Properties of plastics New types of plastics are developed all the time, and therefore it is helpful to have a brief knowledge of the following general basic properties of plastics. 28

• Light weight: Most plastics have a specific gravity (SG) between 1.1 and 1.6. Magnesium has a SG about 1.75. Specific gravity is the heaviness of a substance compared to that of water, and it is expressed without units. In the metric system specific gravity is the same as in the English system. If something is 7.85 times as heavy as an equal volume of water (such as iron is) its specific gravity is 7.85. Its density is 7.85 grams per cubic centimeter, or 7.85 kilograms per liter, or 7.85 metric tons per cubic meter. • Corrosion resistance: Many plastics perform well in hostile, corrosive environments. • Electrical resistance: Plastics are often used as insulating materials. • Low thermal conductivity: Plastics are relatively good thermal insulators. • Variety of optical properties: You can get a plastic in almost any color you would like, and the color can go throughout (not only at the surface). You can also get transparent or opaque plastics. • Formability: Plastics are easy to form (often in only one single operation). Extrusion, casting and molding are widely used. • Surface finish: You can get the surface you want, from rough to excellent surface finish. • Comparatively low cost: Both material and processing/manufacturing processes are cheap. Tool costs are also low. • Low energy content: Plastics melt at low temperature compared with metals, and are therefore produced with little energy. The mechanical strength of plastics are not especially high, compared to metals, but the low density makes them comparable to metals due to their strengthto-weight ratio (or specific strength). A material has high specific strength if the ratio of its strength to its weight is high. Plastics are usually divided into two main groups: thermosettings or thermoplastics. The terms refer to the materials response to elevated temperature. It is important to know whether the plastic is a thermosetting or a thermoplastic since it determines how the plastic will perform in service. 29

3.4.1. Thermosettings In some plastics, polymerization produces cross linkage between long molecular weight chain molecules. These plastics are known as thermosetting plastics because they are permanently hardened by heat. The setting process is irreversible, so that these materials do not become soft under high temperatures. Additional heating do not lead to softening, but the material maintain their mechanical properties up to the temperature at which they char, or burn. Thermosetting plastics usually have a highly cross-linked or three dimensional framework structure in which all atoms are connected by strong, covalent bonds. They are generally produced by the process of condensation polymerization where elevated temperature promotes the irreversible reaction, hence the term thermosetting. The thermosettings are stronger and more rigid than the thermoplastics, but have a lower ductility and poorer impact properties. These plastics also resist wear and attack by chemicals and they are very durable, even when exposed to extreme environments. Typical thermosetting-type plastics are the aminos, most polyesters, alkyds, epoxies, phenolics and urethanes. 3.4.2. Types of Thermosettings PUR - Polyurethane/polyurethene (or PU) PUR is found in a variety of forms ranging from stiff to soft types. Stiff PUR is used for casings and modelling material (artificial wood). Softer rubber-like PUR is used for handtools. Expanded PUR is used for mattresses and car inner panels where it both forms the foam and the leather-like skin. Expandable insulation foam and moisture hardening glue are also made from PUR. Large parts are often made from PUR due to low tooling cost. In general it has excellent outdoor performance and resistance to most acids and solvents. Genoa stacking chair. PUR can be made from a wide variety of raw materials to give hard, clear resins for surface coating: soft flexible resins for oil resistant and abrasion resistant rubbers; rigid or flexible foams for thermal insulation, cushion and fabric stiffeners. In building surface coating and thermal insulation are their main applications. Products: Mil-Tek high pressure cleaner, Panton chair, Shoe soles, and it is used as modelling material (produced by Westnofa) in the Product Design course at HiN . 30

EP - Epoxy Epoxy is a strong and very resistant thermoset plastic. It is used as an adhesive agent, as filling material, for moulding dies, and as a protective coating on steel and concrete. Many composite materials are reinforced epoxy. Epoxy is resistant to almost all acids and solvents, but not to strong bases or solvents with chlorine content. By adding a hardening agent curing takes place. The type of hardener has a major influence on properties and applications of epoxies. Products: Surfing board, Composite bicycle, Badminton racket, Wheel chair, Knee support, Soda stream pressure, container, Skull, model, Car space frame, Wheel chair ramp, Swing wheel. UP - Unsaturated Polyester UP is widely used as filler material with glass fibre in sailing boats, hard tops for cars, furniture, etc. In general UP is not resistant to solvents and bases. Apart from sulphuric acid it resists acids. To improve appearance and resistance a surface layer (gel coat or paint) is often added. UP does not require expensive equipment or tooling to work with UP, and it is therefore often used for prototypes and low-volume production. Products: Sailing boat, Chair, Hard top for car, Printed circuit board, Pedestrian bridge. UF - Urea formaldehyde Urea thermoset molding compounds offer a wide range of applications for every-day living and industry. Urea formaldehyde (UF) thermosets are economically priced, they are strong, glossy, and durable. They are not affected by fats, oils esters, ether, petrol, alcohol or acetone, nor by detergents or weak acids, and they exhibit good resistance to weak alkalis. Their high mechanical strength, heat and fire resistance, and good electrical arc and tracking resistance make them an ideal plastic for numerous industrial and household applications, from doorknobs and toilet seats to electrical components and cosmetics enclosures. You name it — if it can be plastic, it can be stronger and brighter as a (Perstorp) urea thermoset. MF - Melamine formaldehyde Melamine thermoset plastics are similar to urea molding compounds, but melamine has even better resistance to heat, chemicals, moisture, electricity and scratching.

31

Melamine formaldehyde (MF) thermosets are ideal for dinnerware, kitchen utensils, bathroom accessories, and electrical components. The molded compounds are bright, inviting, and highly resistant to scratches and staining. (Perstorp’s) melamine thermosets are approved for contact with foodstuffs, and they do not affect the food’s flavor - even at high temperatures. They are very, very durable. Like urea molding compounds, melamine thermosets consist of plastic that has high surface hardness and gloss, brilliant and precise colors, and light fastness. UF or MF thermosets can be manufactured in a precise and vibrant array of colors. Two-tone compression molding using doublepunch tools will enable you to express your creative designs. For example, your cups or sinks can have white inside and tasteful color outside. The choice of color and shape is limited only by your imagination. Alkyd resins This group of polyesters are usually compression moulded from powders. Originally produced for inclusions in paints, they are resistant to heat and electricity and will withstand attack by acids and solvents. Alkyd plastics find applications in enamels for cars, refrigerators and washing machines and are also used for electric motor insulation and some television parts. Silicones Silicon is an element whose atoms have similar linking properties to those of carbon, but it is stable at much higher temperatures. To utilize the properties of silicon, certain plastics, called silicones have been developed based on the element. Although they are much more expensive, they contain excellent properties. These super materials are available as oil, plastics and rubbers. To quote an example illustrating their value: silicone rubber will retain its elasticity over a temperature range of -80◦ C to 250◦ C. The stability of silicones under widely varying service conditions make them valuable materials for applications such as laminates in the aerospace industry, gaskets and seals for engineering purposes and cable insulation for aircraft electrical systems. 3.4.3. Thermoplastics Thermoplastics, alternatively thermosoftenings, as the name implies, are hard at low temperatures but soften when they are heated. The softening and hardening can be repeated without any change in the chemical structure. Although they are 32

Figure 3.7: The easiest way to identify the type of thermoplastic you’re working with
is to look for the Plastic ID symbol the backside of the part.

less commonly used than thermosetting plastics they do have some advantages, such as greater fracture toughness, long shelf life of the raw material, capacity for recycling and a cleaner, safer workplace because organic solvents are not needed for the hardening process. Thermoplastics have weak bonds between the neighboring molecules and they are weakened by elevated temperature which means they soften at high temperature and are stronger and harder when cooled. They do not have any definite melting temperature, they have a range of temperatures where they soften. When cooled below the glass transition temperature, Tg , the linear polymer retains its amorphous structure, but becomes hard, brittle, and glasslike. Thermoplastics are not cross-linked and can be softened and hardened over and over again. The majority of polymers are thermoplastic. Today there are primarily six commodity polymers in use, namely polyethylene terephthalate (PETE), polyethylene (PE), polyvinyl chloride (PVC), polypropylene (PP), polystyrene (PS) and polycarbonate (PC). These make up nearly 98% of all polymers and plastics encountered in daily life, see ref.[33]. The Society of the Plastics Industry, Inc. (SPI) introduced its resin identification coding system in 1988 at the urging of recyclers around the country. The SPI code was developed to meet recyclers needs while providing manufacturers a consistent, uniform system that could apply nationwide, see figure 3.7. Look at the bottom of a recyclable plastic bottle - chances are you will see a PE or PS which means polyethylene or polystyrene. These materials are examples of what happens 33

to polymers when they solidify: the chains are entangled and packed together to make light, tough, flexible materials. If you heat up PE or PS to moderate temperatures, if the chains have not been chemically stuck together (‘cross-linked’) they will melt, and turn into goopy liquids, which are called polymer melts. Some polymers melts even at room temperature, like polydimethylsiloxane (PDMS), or poly(ethylene-propylene) (PEP). 3.4.4. Types of Thermoplastics PET - Polyethylene terephthalate (or PETE) PET has good barrier properties against oxygen and carbon dioxide. Therefore, it is utilized in bottles for mineral water. Other applications include food trays for oven use, roasting bags, audio/video tapes as well as mechanical components. PET exists both as an amorphous (transparent) and as a semi-crystalline (opaque and white) thermoplastic material. Generally, it has good resistance to mineral oils, solvents and acids but not to bases. The semi-crystalline PET has good strength, ductility, stiffness and hardness. The amorphous PET has better ductility but less stiffness and hardness. Danish Name PET - thermoplastic polyester Products: Bottle for mineral water, Trays for oven use, Oven foils, Audio and video tapes, Thermo scarf (fleece) PE - Polyethylene PE is a semi-crystalline thermoplastic material and one of the most commonly used plastics. It is generally ductile, flexible and has low strength. PE is one of the most commonly used thermoplastic material due to the good properties combined with a low price. There are two basic families: LDPE (low density), and HDPE (high density): • LDPE - low density polyethylene: LDPE is the low density version of PE. This has less hardness, stiffness and strength compared to HDPE, but better ductility. It is opaque and only thin foils can be transparent. LDPE is used for packaging like foils, trays and plastic bags both for food and non-food purposes. Used as protective coating on paper, textiles and other plastics, for instance in milk cartons. Products: Wrapping foil for packaging, Plastic bag (soft type that does not crackle), Garbage bag, Tubes, Ice cube plastic bag. 34

• HDPE - high density polyethylene: HDPE is the high density version of PE plastic. It is harder, stronger and a little heavier than LDPE, but less ductile. Dishwasher safe. HDPE is lighter than water, and can be moulded, machined, and joined together using welding (difficult to glue). The appearance is wax-like, lusterless and opaque. The use of UV-stabilizators (carbon black) improves its weather resistance but turns it black. Some types can be used in contact with food. Products: Milestone, Bottle for motor oil, Bottle for organic solvents, Street bollard, Hedge cutter, Gasoline tank, Milk bottles, Plastic bag (stiff type that crackles), Children’s toys, Lid for honey pot, Beer crate, Dolphin bicycle trailer. PVC - Polyvinyl chloride (vinyl) PVC is one of the oldest and most commonly used thermoplastic material, it is a heavy, stiff, ductile and medium strong amorphous (transparent) material. By adding softeners, a range of softer materials can be achieved, ranging from a flexible to an almost rubber-like elastic soft material. Softeners also help to increase the manufacturability. PVC has brilliant resistance to acids and bases, but is affected by some solvents. Soft PVC is exceptionally resistant to most chemicals. The poor weather resistance can be improved using additives. PVC has good barrier properties to atmospheric gasses. PVC has a Tg of 83◦ C, making it good, for example, for cold water pipes, but unsuitable for hot water. PVC will also always be a brittle solid at room temperature. Products: Boat fender, garden hose, electrical wire insulation, vinyl flooring, roof gutter, vinyl record, children’s doll, wrapping film, medical transparent tube, Pneumatic chair. PP - Polypropylene PP is an inexpensive, ductile, low strength material with reasonable outdoor performance. The material surface is soft wax-like and scratches easily. It has a high stiffness, good strength even in relatively high temperatures, abrasion resistant, good elastic properties and a hard glossy surface. In low temperatures PP gets brittle (< 0◦ C). Stiffness and strength are often improved using reinforcement of glass, chalk or talc. The color is opaque and white, but it can be dyed in many colors. In many ways, PP is similar to HDPE, but it is stiffer and melts at 165170◦ C. PP can be manufactured by all the methods used for thermoplastics. PP has high crystallinity (70-80 %), and is one of the lightest thermoplastics on the marked. The chemical properties are good. PP is resistant to inorganic chemicals

35

and water. It is resistant to most strong mineral acids and basics. PP is not resistant to nitrous gasses, halogens and strong oxidizing acids. Products: Childrens toy bin, transport box, fuel tank, suitcase, garbage bin, rope, shaver (rechargeable), air intake, tubes, packing material, auto parts etc. The material is often used for hinges as it can be flexed millions of times before breaking. PS - Polystyrene Polystyrene is an inexpensive amorphous thermoplastics that has good mechanical proprieties. It is vitreous, brittle and has low strength. However it is also hard and stiff. Foamed PS is used for packaging and insulation purposes. PS is not weather resistant, and therefore not suitable for outdoor uses. PS is transparent (it transmits about 90% of the sunlight) and has unlimited dyeing possibilities. Assembly can be done with gluing. Products: CD and MC covers, disposable drinking glass, glass for bicycle lamp, salad bowl, razor (ordinary), razor (biodegradable), disposable articles, signs, machine parts and picture frames etc. PC - Polycarbonate Polycarbonate is an amorphous plastic with very high impact strength, good ductility and high stiffness. It is very difficult to break and the material is therefore considered fracture-proof (e.g. bullet-proof glass). Light transmission is 85-90% but depends on the thickness. It has good outdoors resistance in the UV-stabilized form, but it tends to turn yellow by long exposition to sunlight. PC is transparent and can be dyed in many colors. PC has a relatively good chemical resistance. Products: PC is commonly used for shielding of work places and machines, sight glass, tubes etc. due to its transparency and high impact resistance, CD compact disc, bullet-proof glass, water container. ABS -Acrylonitrile-butadiene- styrene Acrylnitrile contributes with thermal and chemical resistance, and the rubberlike butadiene gives ductility and impact strength. Styrene gives the glossy surface and makes the material easily machinable and less expensive. Generally, ABS has good impact strength also at low temperatures. It has satisfactory stiffness and dimensional stability, glossy surface and is easy to machine. If UV-stabilizators are added, ABS is suitable for outdoor applications. Products: LEGO building bricks, Computer mouse, Vacuum jug, KimBox suitcase, Ceramic advanced wet shave razor, Hedge cutter handle, Handle for 36

high pressure cleaner, Shaver, rechargeable, Ensemble chair (ABS blended with PA), auto body parts, suitcases, toys etc. Extruded profiles, tubes and bolts can be made from ABS when the requirements are high impact resistance and a nice surface. PA - Polyamide (nylon) PA is a group of amorphous (transparent) and semi-crystalline (opal-white) plastics. Arguments for using PA include strength (fishing line, axe handle), wear resistance (bearings), barrier properties (food packaging) and machinability. Polamide is recognised for good abrasion resistance, low friction coefficient, good resistance to heat and good impact resistance. PA absorbs water which makes it softer. UV-stabilizators are required for outdoor applications. Products: Nylons (stockings), fishing line, bicycle trailer (rainproof cover), bearing, axe, hedge cutter, handle for, high pressure cleaner, bottle for tomato ketchup (barrier layer), ensemble chair (PA blended with ABS), bottle-opener. Kevlar (aramid fibre) is a family of nylons. Acrylic - PMMA (plexiglas) PMMA (polymethyl-methacrylate) is an amorphous thermoplastic material with very good optical properties (as transparent as glass and it allows 92% of the sunlight to pass!). PMMA is hard, stiff and medium strong, easy to scratch, notch sensitive, but easy to polish and has a very good weather resistance. Exceptional outdoor performance, such as weather and sunlight resistance, without reduction neither of optical nor mechanical properties. PMMA is resistant to water, basics, inorganic salts diluted in water, most diluted acids. It is not resistant to strong acids, basics and polar solvents. Products: Tail light glass, exhibition case, folding chair, kitchen scale, decoration articles, transparent tubes, signs, windows, level glass etc.. POM - (polyoxymethylene) Acetal Acetal is a crystalline plastic often used for technical applications due to its strength, ductility and good machinability. It has good creep properties which makes it suitable for click connections (e.g. bicycle lamp holder). It exhibits good stiffness, strength and hardness up to 120◦ C, and the elasticity is comparable with that of many metals. Acetal is wear resistant and has a very low friction coefficient. The color is opaque white. To protect it from UV-light carbon black can be added, changing its color into black.

37

Products: Vacuum jug (top), Holder for bicycle lamp, Fitting for Vico Duo chair, Gearwheel. PTFE - Fluoropolymer (Teflon) Fluoropolymers can be used to make a variety of articles having a combination of mechanical, electrical, chemical, temperature and friction-resisting properties unmatched by articles made of any other material. Commercial use of these and R other valuable properties combined in one material has established TEFLON° resins as outstanding engineering materials for use in many industrial and milR itary applications. TEFLON° resins may also be compounded with fillers or reinforcing agents to modify their performance in use. R TEFLON° PTFE resins have a continuous service temperature of 260◦ C ◦ (500 F). Much higher temperatures can be satisfactorily sustained for shorter exposures. Teflon is used in: Food processing, Electrical parts, Coaxial cable connectors, Terminal insulators, Transformers, Relays, Medical industry, Washers, Gaskets, Flanges, Valve components, Pump Components, Baffles, Seals, Bearings, Rings, Bushings , High heat applications. Teflon is available as: Sheets, Rods, Tubes, Heavy wall tubing, Film, Rectangular bar, Pressure sensitive, tape. TPUR - Thermoplastic urethane (or TPU) TPU is a urethane based TPE (thermoplastic elastomer). It is made of long chained molecules of diols and diisocyanates. Urethane is the unit which is repeated in polyurethane. TPU has a very good abrasion resistance. It is a tough material with a good elasticity over a wide temperature range. TPU is filling the gap between rubber material and the more traditional thermoplastics. The electrical conductance is very low. TPU is a hygroscopic material, and the conductance is dependent on the content of moisture. TPU is resistant to oil, fat, gasoline, and ozone. It is not resistant to hot water, steam, strong acids and basics. Polyether based TPU is resistant to microbes. TPU is available in a variety of qualities. Products: Bumpers, hoses, tubes, sleeves, cushions, coating, insulators, apron rollers etc. PEEK - Polyetheretherketone PEEK is a high temperature resistant engineered thermoplastic with excellent chemical and fatigue resistance plus thermal stability. They exhibit superior mechanical and electrical properties. With a maximum continuous working temperature of 249◦ C (480◦ F), they have excellent retention of mechanical properties 38

up to 299◦ C (570◦ F) in a steam or high-pressure water environment. Superior chemical resistance has allowed them to work effectively as a metal replacement in harsh environments. They are inert to all common solvents and resist a wide range of organic and inorganic liquids. When ∆extensive machining is required, a secondary annealing process should be considered. PEEK is an excellent material for a wide spectrum of applications where thermal,chemical, and combustion properties are critical to performance. The addition of glass fiber and carbon fiber reinforcements enhances the mechanical and thermal properties of the basic PEEK material. Products: automobile engine parts, medical equipment, aerospace products. Today there are primarily six commodity polymers in use, namely polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, polystyrene and polycarbonate. These make up nearly 98% of all polymers and plastics encountered in daily life. 3.5. Classification • Standard plastics used in non-critical and low-stress applications are materials like PS, ABS, PVC, PP, HDPE, and LDPE. • Engineering plastics that are used in general structural, bearing and wear purpose are plastics like PPO (Polyphenylene oxide, modified), Acrylic, PC (Polycarbonate), PET-P (Polyethylene Terephtalate), POM (Poly-oxymethylene =Acetal), PA (Polyamide = Nylon), and UHMW-PE (Ultra high mole wt. Polyethylene). • Advanced engineering plastics that have superior properties and can be used in extreme environments are plastics like PSU (Polysulfone), PPSU (Polyphenylsulfone), PEI (Polyetherimide), PTFE (Polytetraflouroethylene = Teflon), PPS (Polyphenylene sulfide), PEEK (Polyetheretherketone), PI (Polyimid), PAI (Polyamide-imide), and PBI (Polybenzimidazole). 3.6. Additives in Plastics Very often, some additional materials are mixed into plastics, to obtain: • improved properties 39

• reduced cost • improved moldability • wanted color These additional materials are classified as fillers, plasticizers, lubricants, coloring agents, stabilizers, antioxidants, flame retardants, foaming or blowing agents, antifogging agents, antistatic agents, clarifying agents and optical brighteners. New ones are added to the list continuously, so we briefly mention a few of them. Fillers Improve mechanical properties, reduce shrinkage, reduce weight or provide bulk. Fillers comprise a large percentage of the total volume of the plastic. Example of fillers can be: wood flour, cloth fibers, glass fibers, clay. Plasticizers Increase flexibility, improve flow during molding, reduce shrinkage, reduce weight. Lubricants Comparison of both internal lubricants and external lubricants which can be blended with various materials to reduce friction, and wear, improve mar resistance, and extend the useful life of products which are subject to friction. They also improve moldability and extraction from molds. Coloring Agents Coloring Agents are put in the plastic to Impart color. Stabilizers Stabilizers retard degradation due to heat or light. Antioxidants Antioxidants retard degradation due to oxidation. Flame retardants Flame retardants reduce flammability. Foaming Agents Foaming Agents, also known as Blowing or Nucleating Agents, can eliminate sink marks, reduce density, shorten cycle time and reduce total production costs. In extrusion and injection molding, foaming agents can save material weight and lower total cost. They also improve extrusion rates by increasing the volume that 40

can be processed per extruder in a given period of time, and endothermic foaming agents absorb heat and improve injection molding cycle time. Antifogging agents Antifogging agents reduce the formation of condensed droplets on the surface of polyolefin films, such as for food-packaging or agricultural films, resulting in better film transparency and consequently providing better food preservation. Antistatic agents These new permanent antistatic agents, form a conductive network throughout the polymer matrix which dissipates the electrical charge as it builds up. They are already effective for processing and even work at low environmental humidity. Clarifying agents/Optical brighteners Clarifying agents/optical brighteners are designed to give brilliance and whitening to a variety of applications. Synthetic fibers for example, have an inherent yellowish tint. Add optical brighteners and the fibers appear cleaner and whiter. R IRGACLEAR° is a range of products that not only improves the clarity and transparency of polypropylene, but also enhances the mechanical properties. 3.6.1. Oriented Plastics The strength of the intermolecular bond increases with reduced separation distance, and that is why a processing that makes the molecules align parallel make the long-chain thermoplastic higher strength in a given direction. This is called an orientation process, and can be obtained by stretching, rolling, or extrusion, as shown in the Figure 3.8. When a polymer (amorphous or crystalline) is subjected to stress (tensile), the molecular chains become aligned or oriented parallel to the direction of applied stress. The polymer is then in an oriented state. Orienting may increase the tensile strength by more than 200%, but 25% is more typical. 3.7. Elastomers & Rubbers Elastomers, or rubbery materials, have a loose cross-linked structure. Natural and synthetic rubbers are both common examples of elastomers. Elastomers possess memory, that is, they return to their original shape after a stress is applied. Elastomers are amorphous polymers and consist of long polymer chains above their glass transition temperature. The structure of elastomers is tightly twisted or curled. 41

Figure 3.8: Presentation of the alignment of the plastic molecules in the orienting process.

Figure 3.9: Elastomers. Elastomers are reversibly stretchable for small deformations. When stretched, the polymer chains become elongated and ordered along the deformation direction. When no longer stretched, the chains randomize again. The cross-links guide the elastomer back to its original shape. They are very flexible and elastic, which means that they can undergo large elastic deformations without ruptures and recover substantially in shape and size after the load has been removed. Many elastomers can be stretched to several times their original length. Also, the cycle can be repeated numerous times with identical results, as with the stretching of a rubber band. Elastomers are generally resistant to oil and fuel, impermeable to liquids and gases, but tend to deteriorate by oxidation. 42

Like plastics, elastomers are either thermoplastic material (they can be remelted) or thermoset material (that cannot be remelted). Rubber is an older name for elastomers. Elastomeric polymers do not follow Hooks’s law (as most engineering material do). The behavior of the elastomers is a bit more complex due to the molecular shape and the fact that small degree of viscous deformation in produced when load is applied. 3.7.1. Rubber and Artificial Elastomers The oldest commercial elastomer is natural rubber, which is made from a processes sap of a tropical tree. Natural rubber (NR) is a biopolymer which is known as polyisoprene. The rubber tree (Hevea brasiliensis) is the most common source of natural rubber used today. Polyisoprene can also be synthesized by polymerization from its monomer isoprene (CH2=C(CH3)CH=CH2), (IR). This is a rare example of a natural polymer that we can make almost as well as nature does. Rubber has been used for centuries by the South American Indians. They most probably were the people who discovered that if latex (a milky fluid that circulates in the inner portions of the bark of many tropical and subtropical trees and shrubs) is dried, it can be pressed into useful objects such as bottles, shoes and balls. Figure 3.10 shows the common use of rubber. However, it was not until the 1830s (when John Haskins and Edward Chaffee organized the first rubber-goods factory in the United States) that the commercial rubber industry really began to flourish. But rubber had many weaknesses; it softened with heat and hardened with cold; it was tacky, odorous, and perishable. In 1834 the German chemist Friedrich Ludersdorf and the American chemist Nathaniel Hayward discovered that if they added sulfur to gum, then rubber lessened or eliminated the stickiness of finished rubber goods. Charles Goodyear discovered in 1839, that cooking natural rubber with sulfur removed the gum’s unfavorable properties and could be strengthened by cross-linking it with approximately 30% sulfer and heating it to a suitable temperature. This process is called vulcanization, and led to many and varied applications of natural rubber, since the rubber then has got increased strength and elasticity and greater resistance to changes in temperature. It is also impermeable to gases, and resistant to abrasion, chemical action, heat, and electricity, in addition to have high frictional resistance on dry surfaces and low frictional resistance on water-wet surfaces. The vulcanization process remains fundamentally the same as it was in

43

Figure 3.10: Common use of rubber. 1839. Vulcanized rubber has numerous practical applications, such as • excellent abrasion resistance which makes it valuable for the treads of vehicle tires, conveyor belts (soft rubber), pump housings and piping used in the handling of abrasive sludges (hard rubber). • flexibility characteristics which makes it suitable for use in hoses, tires, and rollers for a wide variety of devices ranging from domestic clothes wringers to printing presses. • its elasticity makes it suitable for various kinds of shock absorbers and for specialized machinery mountings designed to reduce vibration. Since it its relatively impermeable to gases its used as air hoses, balloons, balls, and cushions. • resistance to water and to the action of most fluid chemicals has led to its use in rainwear, diving gear, and chemical and medicinal tubing, and as a lining for storage tanks, processing equipment, and railroad tank cars.

44

• high electrical resistance, soft rubber goods are used as insulation and for protective gloves, shoes, and blankets. Hence, hard rubber is used for articles such as telephone housings, parts for radio sets, meters, and other electrical instruments. • coefficient of friction (resistance to movement) of vulcanized rubber, which is high on dry surfaces and low on wet surfaces, leads to the use of rubber both for power-transmission belting and for water-lubricated bearings in deep-well pumps. • uncertainty of price and supply of natural rubber led to the development of artificial elastomers. Some artificial elastomers are inferior to natural rubber, others have superior characteristics. Rubber that has not undergone the vulcanization process has few practical uses because of its poor heat resistance and high plasticity. It is used for cements, adhesive, insulating, friction tapes and for crepe rubber used in insulating blankets and footwear. Some other elastomers include: Polybutadiene (BR): Polybutadiene was one of the first types of synthetic elastomer, or rubber, to be invented. It is very similar to natural rubber, polyisoprene, and is good for uses which require exposure to low temperatures. Tires treads are often made of polybutadiene copolymers. Belts, shoe soles, hoses, gaskets and other automobile parts are made from polyubutadiene, because it stands up to cold temperatures better than other elastomers. Polyisobutylene (PIB): Polyisobutylene is a synthetic rubber, or elastomer. It is the only rubber that is gas impermeable, (can hold air for long periods of time). For instance, balloons will go flat after a few days because they are made of polyisoprene, which is not gas impermeable. Since polyisobutylene will hold air, it is used to make things like the inner liner of tires, and the inner liners of basketballs. Polyisobutylene, sometimes called butyl rubber, is a vinyl polymer, and is very similar to polyethylene and polypropylene in structure, except that every other carbon is substituted with two methyl groups. Poly(styrene-butadiene-styrene) (SBS) : Poly(styrene-butadiene-styrene), is a hard rubber, and is therefore used in soles of shoes, tire treads, and other places 45

Figure 3.11: Poly(styrene-butadiene-styrene), or SBS. where durability is important. It is a type of copolymer called a block copolymer. Its backbone chain is made up of three segments, where the first is a long chain of polystyrene, the middle a long chain of polybutadiene, and the last segment is another long section of polystyrene, see Figure 3.11. Polystyrene is a tough hard plastic, which gives SBS its durability, while polybutadiene is a rubbery material, and gives SBS its rubber-like properties. The material the ability to retain its shape after being stretched; SBS is a type of unusual material called a thermoplastic elastomer. Polyurethanes (AU or EU): (See also 3.4.2) Polyurethanes are the most well known polymers that are used to make foams. But, polyurethanes are more than foam. Polyurethanes are the single most versatile family of polymers there is. Polyurethanes can be elastomers, and they can be paints. They can be fibers, and they can be adhesives. You can find them everywhere. A well-known polyurethane is spandex (DuPont sells it under the trade name Lycra). Lycra is a fiber that acts like an elastomer, and allows us to make fabric that stretches for exercise clothing and the like. Polychloroprene (CR) : Polychloroprene is usually sold under the trade name Neoprene, and it is especially resistant to oil, and was the first synthetic elastomer that became a hit commercially. It was Arnold Collins, while working under the same fellow who invented nylon, Wallace Carothers that invented polychloroprene. Silicones (Q): (See also 3.4.2) Silicones can be used for a lot of things. Silicones are inorganic polymers, that is, there are no carbon atoms in the backbone chain. The backbone is a chain of alternating silicon and oxygen atoms. Each silicone has two groups attached to it, and these can be any organic groups. Sili46

Figure 3.12: Biopolymers. cones can stand high temperatures without decomposing, but they have very low glass transition temperatures. 3.8. Biopolymers Biopolymers are an alternative to petroleum-based polymers (traditional plastics) produced by living organisms. The field of biopolymers, is still in its early stage, but is growing in popularity every day. The term biopolymers is often used for all polymers that are made from natural renewable resources and/or are completely biodegradable. Biopolymers can be produced by biological systems like microorganisms, plants and animals, or chemically synthesized from biological starting materials (e.g. sugars, starch, natural fats or oils, etc.). Most of the biopolymers are biodegradable, some of them are even water soluble, most of the biopolymers are compostable or will biodegrade in landfill, time can vary from a couple of days to even years, but they will eventually degrade. Biopolymers can be used in all kinds of applications, and with all kinds of production techniques, like injection moulding, thermoforming and blow moulding! Some biopolymers can directly replace synthetic plastics in traditional applications, while others possess unique properties that may open new applications. 3.8.1. What makes a polymer a biopolymer? Biopolymers are defined as biologically degradable polymers. Biopolymers are polymers that are generated from renewable natural sources, are often biodegrad47

able, and not toxic to produce. According to the American Society for Testing and Materials (ASTM), biopolymers are degradable polymers in which degradation results from the action of naturally occurring micro-organisms such as bacteria, fungi and algae. 3.8.2. Applications of biopolymers Biopolymers can be used for a lot of applications, from packaging to disposables, from diapers to cottonsticks, from carparts to bottles, etc. In theory conventional plastics may be substituted by biopolymers in many applications. In practice substitution is not always feasible, wanted or the most lucrative way to use biopolymers. Besides technical development which is needed for some applications, the applications have to be economically feasible within a reasonable term. The economic feasibility depends on the investments needed for material and product development and the added value of the biopolymer in the application. 3.8.3. Properties of biopolymers Properties of biopolymers depend on the raw material they are based on, on additives used and on the (chemical) modifications during production. Different types of biopolymers Starch, proteins and peptides, and DNA and RNA are all examples of biopolymers, in which the monomer units, respectively, are sugars, amino acids, and nucleic acids. Biopolymers found in and used by living cells can be divided into the following four classes: • Lipids (fats, oils, phospholipids waxes, and steroids) • Carbohydrates (Starch, Cellulose, and Sugars as polysaccharides) • Proteins (Protein is a polymer with the monomer made up of amino-acid residues, and is contained in skin, bones, muscles, blood and hair ) • Nucleic acids (complex polymeric molecules which store and translate genetic information ) The most common way to divide biopolymers in different types is on the basis of the raw material used for production. However, some biopolymers can 48

be produced from different raw materials. Some examples of different types of biopolymers are: Starch-based polymers (SBP) are often a blend of starch and other plastics (e.g PE), which allows for enhanced environmental properties. Starch is a polymeric carbohydrate (a polysaccharide), in which the monomers are glucose units joined to one another Starch is abundantly present in many crops. The starch is stored in granules within the plant. This facilitates the isolation from the plant. Starch may be modified in order to become a thermoplastic. This makes the starch polymer suitable for current processes in the plastics industry like: injection moulding and extrusion. Thermoplastic starch has an affinity with moisture. The material therefore is not suitable for wet food packaging applications. Direct contact with water only is possible for a short time. By acetylation a certain resistance to water may be achieved. By adding PCL the flexibility of the bioplastic increases. Starch polymer has good oxygen barrier properties. Starch polymers are the most produced and used biopolymers at the moment. Starch (in particular cornstarch) is used in cooking for thickening foods such as sauce. In industry, it is used in the manufacturing of adhesives, paper, textiles and as a mold in the manufacture of sweets such as wine gums and jelly beans. It is a white powder, and depending on the source, may be tasteless and odourless. Cellulose polymers (cellulose esters, cellulose ethers, cellophane) Cellophane is one of the oldest packaging materials. Cellulose pulp from trees or cotton may be used to produce cellophane. It is a relatively expensive packaging material which can be used for a wide range of products such as cd’s, candy and cigarettes. The higher price is a reason why a large market share was lost to polypropylene. At the moment new applications in which the specific properties may be used, are sought for. The material is transparent and has good folding properties. The foil has a high gas barrier and if a coating is applied may resist water vapor as well. Protein polymers There is no information about protein polymers available yet, but see for instance http://www.ppti.com/Technology/technology.htm.

49

3.8.4. Additional information on raw materials in biopolymers Lactic acid is produced by the microbial fermentation of sugars such as glucose or hexose. Feedstocks can include potato skins and corn. The lactic acid monomers can be used to create low or high molecular weight polylactide polymers (PLA). PLA commodity polymers are being developed for use as pulping additives in paper manufacturing and as biodegradable packing materials, clothes, cups, packaging and many other everyday products. Polylactic acid (PLA) is derived from lactic acid for which carbohydrates in sugar beets, potatoes, wheat, maize and milk are the source. Polylactic acid is a substance familiar to the human body, as we ourselves produce it by every muscle contraction. It can be broken down by the body. PLA can be processed through for example injection moulding, foil blowing and deep drawing. PLA may be applied as a coating. PLA is water resistant but cannot withstand high temperatures (>55◦ C). In comparison to starch biopolymer the degradation process is very slow. However, within a composting facility it can be broken down in 3 to 4 weeks. Polyhydroxyalkanoates (PHAs) (polyhydroxybutyrate (PHB), polyhydroxybutyrate/valerate (PHB/HV)) PHA’s are generally derived through fermentation of glucose, sucrose of fatty acids by micro-organisms. PHB can be processed through for example injection moulding and deep drawing. It is an excellent material for the coating of paper coffee cups. The most important features of PHB are the resistance to high temperatures up to 120◦ C and the resistance to water. Chitin, a polysaccharide found in the exoskeletons of insects and shellfish, possesses many desirable characteristics. Chitin’s most important derivative, chitosan, is nearly a ”model” biopolymer with it’s useful physical and chemical properties, high strength, biodegradability, and nontoxicity. In fact, chitosan brings new meaning to the word ”biodegradable” as the human body easily breaks it down into simple carbohydrates, carbon dioxide, and water. This accounts for the research that is trying to use chitosan in drug delivery systems. Other natural Biopolymers: Protein Proteins are biopolymers consisting of one or more strings of amino acid residues joined head-to-tail via peptide bonds. Protein also makes up much of 50

the structure of animals: collagen and keratin are components of skin, hair, and cartilage; and muscles are composed largely of proteins. Peptides Peptides are the family of molecules formed from the linking, in a defined order, of various amino acids. Peptides differ from proteins, which are also long chains of amino acids, by virtue of their size. Traditionally, those peptide chains that are short enough to make synthetically from the constituent amino acids are called peptides rather than proteins. The dividing line is at approximately 50 amino acids in length, since naturally-occurring proteins tend, at their smallest, to be hundreds of residues long. DNA Deoxyribonucleic acid (DNA) is the molecule in living things that contains the coding information for creating proteins. It is also the molecule of heredity— whenever an organism reproduces, each offspring gets a copy of its parents’ DNA. RNA Ribonucleic acid, a nucleic acid structurally distinguished from DNA by the presence of an additional hydroxyl group attached to each pentose ring, and functionally distinguished by its multiple roles in the intracellular transmission of genetic information from the site of transcription (from DNA) to the site of translation (into protein). 3.8.5. Plastic taste better with sugar Chemists in India are lacing plastics with sugar to make them palatable to soil bacteria. The plastics, which normally survive for decades in landfills, start to biodegrade within days. The tweaked plastics are polythene, polystyrene and polypropylene. These make up around a fifth of urban waste by volume. Bottles, bags and sacks are made of polyethylene, food packaging is made of polypropylene, and drinking cups, fast-food cartons and the hard casing of electronic equipment are fashioned from polystyrene. Digambar Gokhale and colleagues at the National Chemical Laboratory in Pune mix the styrene subunits of polystyrene with small amounts of another substance that provides a chemical hook for sucrose or glucose pieces. They then add sugars to the styrene chains like pendants on a necklace. 51

c Figure 3.13: One fifth of urban rubbish is plastics like polystyrene. ° GettyImages

By weight, less than 3% of the final polymer is sugar, so the material is more or less the same. But bacteria such as Pseudomonas and Bacillus break open the chains when they chomp on these sugary snacks, kicking off decay. It remains to be seen whether the polymer biodegrades into entirely non-toxic substances. Fully broken down, the end products are carbon dioxide and water. But along the way, all sorts of other compounds are produced, such as organic acids and aldehydes. Indeed, it is not yet clear how far, or how quickly, the plastic will break down in the real world. And adding the sugar would require significant manufacturing changes, which could be costly. Other additives that make polythene, polystyrene and polypropylene biodegradable have been toxic and can leach out of garbage. Another approach is to initiate the breakdown process using heat, ultraviolet light or exposure to oxygen, but this is cumbersome and expensive. Published in: Nature News Service, 2.december 2002; see also http://www.nature.com/nsu/021125/021125-12.html. References:
Polymers: http://www-materials.eng.cam.ac.uk/mpsite/ http://www.plasticsusa.com/ http://www.polymer-age.co.uk/directry/plastic.htm http://www.mse.cornell.edu/courses/engri111/ http://www.amco.ws/home.asp

52

http://naturalrubber.cjb.net/ http://www3.jaring.my/inro/ http://www.phy.uni-bayreuth.de/theo/tp3/members/elast.htm http://www.psrc.usm.edu/macrog/crystal.htm http://www.uvi.edu/Physics/SCI3xxWeb/Structure/Polymerization.html http://www.zeusinc.com/ http://islnotes.cps.msu.edu/trp/toc.html http://abalone.cwru.edu/tutorial/enhanced/files/textbook.htm http://www.thermosets.com/thermosets.html http://www.aipma.org/t&ti/thermos.htm http://www.polymer-age.co.uk/techlink.htm http://en.wikipedia.org/wiki/Glass_transition_temperature http://en.wikipedia.org/wiki/Polymer#Polymer_science Elastomers: http://www.psrc.usm.edu/macrog/elas.htm Biopolymers: http://www.biopolymer.net/ http://www.biopolymer.com/ http://www.biotec.de http://www-classes.usc.edu/engr/ms/125/MDA125/biopolymers/ http://online.itp.ucsb.edu/online/infobio01/lancet2/ http://www.cheresources.com/biopoly2zz.shtml http://www.proterra.nl/norms.html http://www.dblab.helsinki.fi/~rtuma/biopolymers.htm http://www.wikipedia.org/wiki/Biopolymer http://www.brooklyn.cuny.edu/bc/ahp/SDPS/PSLectNotes/SD.PS.LectP2.html http://www.bipp.nl/about_3.html http://www.forskning.no/Artikler/2002/desember/1038997297.18 http://www.nature.com/nsu/021125/021125-12.html http://www.ppti.com/Technology/technology.htm Galgali, P., Varma, A. J., Puntambekar, U. S. & Gokhale, D. V. Towards biodegradable

polyolefins: strategy of anchoring minute quantities of monosaccharides and disaccharides onto functionalized polystyrene, and their effect on facilitating polymer biodegradation. Chemical Communications, 2002, 2884 - 2885, (2002). Questions • Explain the expression thermosetting and thermoplastic. 53

• What is the glass transition temperature? • What is the difference between an amorphous and crystalline plastic? • What happens to a thermoplastic when it is cooled down below melting temperature? • How do thermosetting polymers respond to subsequent heating? • What is the difference between a saturated and an unsaturated molecule? • Describe the two different processes of forming polymers: addition and condensation. • What are some attractive engineering properties of plastics, and in what area do they fall? • What are some reasons that additive agents are incorporated into plastics? • What kind of additive agents are there, and what are their objective? • What is the primary engineering benefit of an oriented plastic? • What is the unique mechanical property of elastomeric materials? • What is vulcanization? • What is rubber? • What is a SPI code, and what is it good for? • What groups of SPI codes are there? • What is a biopolymer? • What kind of different biopolymers exist? • What products can be made from biopolymers? Polymers can be described as being thermosetting or thermoplastic a. Why are the thermosetting polymers so different from thermoplastic polymers? b. What decides if a polymer will be thermosetting or thermoplastic? c. What are three important, common thermosetting polymers? d. What are three important, common thermoplastic polymers? Polymers can be described as being amorphous or crystalline polymers a. Compare the physical and chemical properties of amorphous and crystalline polymers. b. What are three important amorphous polymers? c. What are three important crystalline polymers? d. How does light penetration qualities depend on the degree of crystallization?

54

4. Composites
Composite materials are materials that combine two or more materials (a selected filler or reinforcing elements and compatible matrix binder) that have quite different properties that when combined offer properties which are more desirable than the properties of the individual materials . The different materials work together to give the composite unique properties, but within the composite you can easily see the different materials, they do not dissolve or blend into each other. The key characteristic of composites is the • Specific strength (the strength to weight ratio σ/ρ) • Specific stiffness or specific modulus (the stiffness-to-weight ratio E/ρ) • Tailored material ( since composites are composed of 2 or more ”phases”, they can be formulated to meet the needs of a specific application with considerable ease) Composites are not a single material but a family of materials whose stiffness, strength, density, and thermal and electrical properties can be tailored. The matrix, the reinforcement material, the volume and shape of the reinforcement, the location of the reinforcement, and the fabrication method etc. can all be varied to achieve required properties. Composite applications Specific composite applications are detailed in each market category: • Transportation • Electrical/Electronics • Building Construction • Infrastructure • Aerospace/Defense • Consumer/Recreation • Medical Products • Sport equipment

55

4.1. The history of composites The theory behind the construction of composite materials comes from the need to create a strong stiff and light material. Materials such as glass, carbon and Kevlar have extremely high tensile and compressive strength, but in solid form, many random surface flaws present in such materials, cause them to crack and fail at a much lower stress that it theoretically should. To overcome this problem, the material is produced in a fibre form, although the flaws will occur at the same frequency, the flaws will be reduced to a small number of fibres at any one point, and the remaining ones will carry the load with the materials theoretical strength. To prevent flaws occurring from abrasion on the surface of the material, or from existing flaws transferring to other fibres, it is necessary to isolate the fibres. This is why a resin matrix system is used. Another well-known composite is concrete. Here, aggregate (small stones or gravel) is bound together by cement. Concrete has good strength under compression, and it can be made stronger under tension by adding metal rods, wires, mesh or cables to the composite (so creating reinforced concrete). Most composites are made up of just two materials. One material (the matrix or binder) surrounds and binds together a cluster of fibres or fragments of a much stronger material (the reinforcement). There are both natural and man-made composites. 4.2. Natural composites Composites exist in nature. A piece of wood is a composite, see Figure 4.1, with long fibres of cellulose (a very complex form of starch) held together by a much weaker substance called lignin. Cellulose is also found in cotton and linen, but it is the binding power of the lignin that makes a piece of timber much stronger than a bundle of cotton fibres. Other examples of natural composites are: Spider silk Spider silk is a biopolymer fibre and a natural composite material, see Figure 4.2. Its composition is a mix of an amorphous polymer (which makes the fibre elastic), and the two simplest proteins (which give it toughness), in other words, it is simply a protein. The result is a good combination of strength and toughness. 56

Figure 4.1: The cell-structure of a natural composite, a tree. It is five times as strong as steel, twice as strong as Kevlar at same weight, twice as elastic as polyamide fibres (it can be stretched by 31% without breaking), more elastic than aramid fibre, finer than a human hair, and lighter than cotton. Promises are: bulletproof vests, parachute cords, bridge suspension cables, wear-resistant shoes and clothing, seat belts, rustfree bumpers for automobiles, artificial tendons and ligaments, etc. Spider silk is produced either by spider or (in the future) by bacteria or plants, therefore in an environment-friendly way. It is an environment-friendly biopolymer and is easy to recycle. Spider silk does not decompose like other proteins by fungi, or bacteria because they contain substances that makes it durable. The thread of the garden spider (Araneus) would have to be 80 km long before it would snap under its own weight. When synthesis of spider silk in bacteria or plants becomes efficient, spider silk will have a commercial relevance. Human hair, bone and muscles are also natural composites. These kind of structures are also called hierarchical structures since they have structures in many levels, see also chapter 9.4.

57

Figure 4.2: Spidersilk. 4.3. Man-made Composites Humans have been using composite materials for thousands of years. Take mud bricks for example. A cake of dried mud is easy to break by bending, which puts a tension force on one edge, but makes a good strong wall, where all the forces are compressive. A piece of straw, on the other hand, has a lot of strength when you try to stretch it but almost none when you crumple it up. But if you embed pieces of straw in a block of mud and let it dry hard, the resulting mud brick resists both squeezing and tearing and makes an excellent building material. Put more technically, it has both good compressive strength and good tensile strength. In the case of mud bricks, the two roles are taken by the mud and the straw; in concrete, by the cement and the aggregate; in a piece of wood, by the cellulose and the lignin. In fiberglass, the reinforcement is provided by fine threads or fibres of glass, often woven into a sort of cloth, and the matrix is a plastic. Composite materials are composed of a matrix material reinforced with any of a variety of fibers made from ceramics, metals, or polymers. The reinforcing fibers are the primary load carriers of the material, with the matrix component transferring the load from fiber to fiber. Reinforcement of the matrix material may be achieved in a variety of ways. Fibers may be either continuous or discontinuous, see Figure 4.3. Reinforcement may also be in the form of particles. The matrix material is usually one of the many available engineering plastics/polymers. Selection of the optimal reinforcement form and material is dependent on the property requirements of the finished part. 58

Figure 4.3: Composite materials with different types of reinforcements. The threads of glass in fiberglass are very strong under tension but they are also brittle and will snap if bent sharply. The matrix not only holds the fibres together, it also protects them from damage by sharing any stress among them. The matrix is soft enough to be shaped with tools, and can be softened by suitable solvents to allow repairs to be made. Any deformation of a sheet of fiberglass necessarily stretches some of the glass fibres, and they are able to resist this, so even a thin sheet is very strong. It is also quite light, which is an advantage in many applications. Over recent decades many new composites have been developed, some with very valuable properties. By carefully choosing the reinforcement, the matrix, and the manufacturing process that brings them together, engineers can tailor the properties to meet specific requirements. They can, for example, make the composite sheet very strong in one direction by aligning the fibres that way, but weaker in another direction where strength is not so important. They can also select properties such as resistance to heat, chemicals, and weathering by choosing an appropriate matrix material.

59

4.3.1. Fiber-Reinforced Composites Fiber Reinforced Plastics (FRP) is a general term for composite materials or parts that consist of a resin matrix that contains reinforcing fibers such as glass or fiber and have greater strength or stiffness than the resin. FRP is most often used to denote glass fiber-reinforced plastics. Reinforcing fibers can be made of metals, ceramics, glasses, or polymers that have been turned into graphite and known as carbon fibers. Fibers increase the modulus of the matrix material. The strong covalent bonds along the fiber’s length gives them a very high modulus in this direction because to break or extend the fiber the bonds must also be broken or moved. Fibers are difficult to process into composites, making fiber-reinforced composites relatively expensive. Fiber-reinforced composites are used in some of the most advanced, and therefore most expensive, sports equipment, such as a time-trial racing bicycle frame which consists of carbon fibers in a thermoset polymer matrix. Body parts of race cars and some automobiles are composites made of glass fibers (fiberglass) or carbon fibers in a thermoset matrix. On the basis of stiffness and strength alone, fibre reinforced composite materials do not have a clear advantage particularly when it is noted that their elongation to fracture is much more lower than metals with comparable strength. The advantage of composite materials appear when the modulus per unit weight (specific modulus) and strength per unit weight (specific strength) are considered. The higher specific weight and high specific strength of the composite materials means that the components weight can be reduced. Although glass fibres are by far the most common reinforcement, many advanced composites now use fine fibres of pure carbon. Carbon fibres are much stronger than glass fibres, but are also more expensive to produce. Carbon fibre composites are light as well as strong. They are used in aircraft structures and in sporting goods (such as golf clubs), and increasingly are used instead of metals to repair or replace damaged bones. Even stronger (and more costly) than carbon fibres are threads of boron. 4.3.2. Classification of composites Many terms have been used to define FRP composites. Modifiers have been used to identify a specific fiber such as Glass Fiber Reinforced Polymer (GFRP), Carbon Fiber Reinforced Polymer (CFRP), and Aramid Fiber Reinforced Polymer 60

(AFRP). Another familiar term used is Fiber Reinforced Plastics. In addition, other acronyms were developed over the years and its use depended on geographical location or market use. For example, Fiber Reinforced Composites (FRC), Glass Reinforced Plastics (GRP), and Polymer Matrix Composites (PMC) can be found in many references. Although different, each of before mentioned terms mean the same thing; FRP composites. There are many ways of classifying composite materials. For instance, we can classify the microcomposite materials based on the size, shape and distribution of the different phases in the composite for instance like this: • Continuous fibres in matrix: aligned, random • Short fibres in matrix: aligned, random • Particulates (spheres, plates, ellipsoids, irregular, hollow or solid) in matrix • Dispersion strengthened, as for the point above, but the particle size < 10−8 m • Lamellar structures (used in laminates) • Skeletal or interpenetrating networks • Multicomponent, fibres, particles etc. Clearly, the distinction between the different groups is not always a sharp one. Nanocomposites are composites on nanoscale (10−9 meter). They have constituents that are mixed on a nanometer-length scale. Mostly, we classify composites according to their matrix phase. The role of the matrix is to act as a medium to keep the fibers properly oriented and to protect them from the environment. There are ceramic matrix composites (CMC’s), metal matrix composites (MMC’s), and polymer matrix composites (PMC’s). Materials within these categories are often called ”advanced” if they combine the properties of high strength and high stiffness, low weight, corrosion resistance, and in some cases special electrical properties. This combination of properties makes advanced composites very attractive for aircraft and aerospace structural parts. 4.4. Ceramic matrix composites CMC Monolithic ceramics have the disadvantage of being brittle, see Figure 4.4 from: www.ms.ornl.gov/programs/ energyeff/cfcc/iof/chap24-6.pdf. A reinforcing phase can improve the toughness of these materials, while still taking advantage of the matrix’s other properties such as wear resistance, hardness, corrosion resistance, and temperature resistance. A wide range of ceramic 61

Figure 4.4: Failure modes for monolithic ceramic and CFCCs. matrix composites (CMCs) have thus been developed that combine a matrix material with a reinforcing phase of different composition (such as alumina and silicon carbide) or the same composition (alumina/alumina or silicon carbide/silicon carbide). Figure 4.5 compares the approximate service temperature ranges of some important polymers, metals and ceramics. The CMC market is divided into two classes; the oxide and non-oxide materials. Some of the more common oxide matrices include alumina, silica, mullite, barium aluminosilicate, lithium aluninosilicate and calcium aluminosilicate. Oxide matrices are often more mature and environmentally stable, but non-oxide ceramics have more superior structural properties and hardness are rapidly entering the marketplace. Examples of non-oxide ceramics are silicone carbide (SiC), silicone nitride (Si3 N4 ), boron carbide (B4 C) and aluminium nitride (AlN). The oxide CMCs often consist of oxide fibers (for instance alumina Al2 O3 ), while the non-oxide CMCs consist of non-oxide fibers (for instance SiC) (see also Chapter 4.7 for more information concerning fibers). Non-oxide CMCs are more advanced than oxide CMCs since they have higher thermal conductivity, lower 62

Figure 4.5: Service temperature ranges of some important polymers, metals and ceramics.

thermal expansion and are more stable at high temperatures than oxide CMCs. The non-oxide CMCs are used in thermally loaded components (combustor liners, vanes, blades and heat exchangers). The oxide CMCs have good oxidation resistance, alkali corrosion resistance, low dielectric constants and potentially low cost, and are therefore used for hot gas filters, exhaust components of aircraft engines, and in long-life, lower temperature components. The reinforcements of CMCs can include carbides, borides and oxides. Specific examples of reinforcements include carbon, silicon carbide, titanium diboride, silicon nitride and alumina. Some of the more common ceramic discontinuous reinforcement include whiskers, platelets, and particulates having compositions of Si3 N4 , SiC, AlN, titanium dibori, boron carbide, and boron nitride. Ceramics and CMCs can also result in fuel efficiency in heat engines because of higher operating temperatures, and reduction or elimination of cooling systems. The temperature requirement in such applications is not as high as in aerospace materials applications. Other applications of CMCs include wear parts, such as seals, nozzles, pads, liners, grinding wheels, brakes, etc. For instance, carbon fiber reinforced carbon composites are being used in aircraft brakes. 63

4.5. Metal Matrix Composites MMC Metal Matrix Composites (MMC’s) are increasingly found in the automotive industry. They consist of a metal such as aluminium as the matrix, and a reinforcement that could be continuos fibres such as silicon carbide, graphite or alumina, wires such as tungsten, beryllium, titanium and molybdenium, and discontinuous materials. Metals containing ceramic particles, whiskers or (short or long) fibers are also gaining importance. MMC are said to be materials for the demands of the future. When the demands for high thermal conductivity, reduced weight, heat dissipation, and high strength are factors for design, MMCs represent the Next Generation of solutions for today’s electronic requirements. Metal-matrix composites are either in use or prototyping for the Space Shuttle, commercial airliners, electronic substrates, bicycles, automobiles, golf clubs, and a variety of other applications. While the vast majority are aluminum matrix composites, a growing number of applications require the matrix properties of superalloys, titanium, copper, magnesium, or iron. Regardless of the variations, however, aluminum composites offer the advantage of low cost over most other MMCs. In addition, they offer excellent thermal conductivity, high shear strength, excellent abrasion resistance, high-temperature operation, nonflammability, minimal attack by fuels and solvents, and the ability to be formed and treated on conventional equipment. Aluminum MMCs are applied in brake rotors, pistons, and other automotive components, as well as golf clubs, bicycles, machinery components, electronic substrates, extruded angles and channels, and a wide variety of other structural and electronic applications. Compared to monolithic metals, MMCs have: • Higher strength-to-density ratios • Higher stiffness-to-density ratios • Better fatigue resistance • Better elevated temperature properties: -Higher strength -Lower creep rate • Lower coefficients of thermal expansion • Better wear resistance The advantages of MMCs over polymer matrix composites (PMCs) are:

64

• Higher temperature capability • Fire resistance • Higher transverse stiffness and strength • No moisture absorption • Higher electrical and thermal conductivities • Better radiation resistance • No outgassing • Fabricability of whisker and particulatereinforced MMCs with conventional metalworking equipment Some of the disadvantages of MMCs compared to monolithic metals and polymer matrix composites are: • Higher cost of some material systems • Relatively immature technology • Complex fabrication methods for fiber-reinforced systems (except for casting) • Limited service experience 4.6. Polymer Matrix Composites PMC Polymer Matrix Composites (PMC’s) are the most common composites, and are also known as FRP - Fibre Reinforced Polymers (or Plastics). These materials use a polymer-based resin as the matrix, and a variety of fibres such as glass, carbon and aramid as the reinforcement. Matrix materials are either thermosetting or thermoplastic polymers. Reinforcing fibers are either continuous or chopped. In general, polymer composites processing includes contracting of polymer and fibers, shaping, controlled heating and/or reactions, and cooling. The technology of polymer composites has been driven to a large extent by aerospace and military applications. Advantages of Polymer Composites Polymer composites make the largest and most diverse use of composites due to ease of fabrication, low cost and good properties. Also, they have: • High specific strength properties (20-40% weight savings) • Ability to fabricate directional mechanical properties • Outstanding corrosion resistance • Excellent Fatigue and fracture resistance • Lower tooling cost alternatives • Lower thermal expansion properties 65

Figure 4.6: • Simplification of manufacturing by parts integration • Potential for rapid process cycles • Ability to meet stringent dimensional stability requirements Glass-fiber reinforced composites (GFRC) are strong, corrosion resistant and lightweight, but not very stiff and cannot be used at high temperatures. Applications include auto and boat bodies, aircraft components. Carbon-fiber reinforced composites (CFRC) use carbon fibers, which have the highest specific module (module divided by weight). CFRC are strong, inert, allow high temperature use. Applications include fishing rods, golf clubs, aircraft components. 4.7. Fiber reinforcement Fibers (see [14]) are pliable hair-like substances, built up by long chains of basic molecules. Fibres are very small in diameter in relation to their length. Long continuous strands of fibers are called filaments. The only natural filament fibre is silk from butterflies or spiders. Fibre’s properties depend strongly on both the external and internal fibre structure as well as the chemical composition. Properties therefore vary significantly. Crystalline areas give tensile strength, stiffness and stability, while amorphous areas are weaker but more movable. The fibers can be individual strands as thin as a human hair or they can be multiple fibers braided in the form of a yarn (or tow).

66

4.7.1. Choosing fibers The fibers in advanced composites are usually non-metallic in nature, consisting of such materials as glass, carbon, silicon carbide, alumina, boron or Kevlar. Other fibers such as spectra and quartz are also available, but these are usually reserved for specialized application. The table below shows some advantages and disadvantages of some fibertypes, while Figure 4.7 shows some properties of some fibers. Fiber E-, S-Glass Advantages - High strength - Low cost Disadvantages - Low stiffness - Short fatigue life - High temp sensitivity High tensile strength - Low comp. strength Low density - High moisture absorp. High stiffness - High cost High comp. strength High strength - Moderate cost High stiffness Very high stiffness - Low strength - High cost High stiffness - Low strength High use temp - High cost

Boron Carbon (AS4, T300) Graphite (pitch) Aramid (Kevlar) Ceramic (silicon carbide, alumina) -

Figure 4.8 shows a plot of specific strength vs. specific stiffness of some fibers. High-strength fibers utilized in high-performance composites include carbon, glass, aramid, ultrahigh molecular-weight polyethylene (PE), boron, quartz, ceramic and hybrid combinations. Continuous bundles (tow or roving) are the basic fiber forms for high-performance composite applications. These forms may be used directly in processes such as filament winding or pultrusion or may be converted into tape, fabric and other forms. In high-performance composites, the structural properties of the finished part are derived primarily from the fiber. A fiber-to-matrix ratio of 60:40 or higher is common for both thermoset- and thermoplastic-matrix composites. Desirable properties are not achieved, however, without effective adhesion between fiber and matrix, which requires sufficient saturation with resin (wetout) at the fiber-matrix 67

Figure 4.7: Properties of some fibers.

Figure 4.8: Specific strength vs. specific stiffness of some fibers. 68

interface. Attention to fiber surface preparation, such as use of a surface finish or coupling agent and selection of a compatible fiber and matrix combination, ensures good adhesion. We will have a closer look at some types of fibers.

4.7.2. Glass fibers Glass fibers (GF) are the most widely used reinforcement for plastic and rubber products, and are also the finest (smallest diameter) of all fibers, typically 1 to 4 microns in diameter. Glass fibers, see Figure 4.9, are made of silicon oxide with addition of small amounts of other oxides. Glass fibers are characteristic for their high strength, good temperature and corrosion resistance, and low price. Over 90% in the composite industry is glass fibers. Properties of glass fibers are bound

Figure 4.9: Glass fiber. to the chemical composition of the mixture, but they are also influenced by the spinning way. Usually, they are divided into: Use Multipurpose fibers Acid resistant fibers Alkali resistant fibers High strength fibers Fibers with good dielectric properties Type of glass glass E glass A, C, CR glass R, S glass R, S glass D

69

The two types of glass fibers that are most common are the E-glass and Sglass. The first type is the most used, and takes its name from its good electrical properties (no electrical interference in thunderstorms, and no sparks). The second type is very strong (S-glass), stiff, and temperature resistant. They are used as reinforcing materials in many sectors, e.g. automotive and naval industries, sport equipment. S-glass are used for instance in aircraft flooring, helicopter blades etc. Some properties for E- and S- glass are listed in the following table: E-glass S-glass ◦ ◦ - softens at ≈850 C - softens at ≈1000 C - most inexpensive fiber ≈ 30% stronger than E-glass - most commonly used fiber today ≈ 15% stiffer than E-glass - insulators and capacitors ≈ 3 times as expensive as E-glass - high quality glass fiber - high technical purposes The most widely used composite material is fiberglass in polyester resin, which is commonly referred to as just fiberglass. Fiberglass is light weight, corrosion resistant, economical, easily processed, has good mechanical properties, and has over 50 years of history. It is the dominant material in industries such as boat building and corrosion equipment, and it plays a major role in industries such as automotive, medical, recreational, and industrial equipment.

Quartz fibers Quartz fibers (SiO2 ) are very high silica version of glass with much higher mechanical properties and excellent resistance to high temperatures ◦ and can be used continuously to 1048.9 C and for short-temperature applications, ◦ even to 1248,9 C. They are more expensive than E-glass and S-glass, provide significantly better electromagnetic properties than glass, making them a good choice for parts such as aircraft radomes.

4.7.3. Carbon fibers Carbon fibers (CF) appeared on the market in 1960 and are produced of organic fibers (rayon, acrylics etc.) or from remaining of petroleum or tar distillation. 70

Figure 4.10: Carbon fibre. Carbon fibers, see Figure 4.10, are the stiffest and strongest reinforcing fibres for polymer composites, the most used after glass fibres. Made of pure carbon in form of graphite, they have low density and a negative coefficient of longitudinal thermal expansion. Carbon fibres are very expensive and can give galvanic corrosion in contact with metals. They are generally used together with epoxy, where high strength and stiffness are required, i.e. race cars, automotive and space applications, sport equipment.

4.7.4. Boron fiber Boron (BF) is a metal known for its exceptional resistance and form. BF is five times as strong and twice as stiff as steel. Boron provides strength, stiffness, light weight and excellent compressive properties, as well as buckling resistance. Use of boron composites ranges from sporting goods, such as fishing rods, golf club shafts, skis and bicycle frames, to aerospace applications such as aircraft empennage skins, space shuttle truss members and prefabricated aircraft repair ◦ patches. It has a melting point at 2180 C.

4.7.5. Ceramic fibers Ceramic fibers (CEF) are mostly used as refractory fibers in uses over 1000◦ C and are characterized by a polycrystalline structure rather than amorphous. Some of the more common ceramic continuous reinforcements include silica, mullite, 71

alumina, carbon, zirconia, and silicon carbide in addition. The more sophisticated kinds of fibers, have a basis of borate, carbide, silicon nitrure and borate nitrure. They are very expensive fibers because only a small quantity is produced, and they are used in particular fields such as aerospace. Ceramic fibers offer high to very high temperature resistance but poor impact resistance and relatively poor room-temperature properties. They are often divided into the following two groups: * Non-oxide fibers can be such as Siliconcarbide (SiC), boron nitride (BN), silicon nitride (SiN), aluminium nitride (AlN) and multiphase fibers consisting of silicon, carbon, boron, nitride, titanium, (Si-C-B-N-Ti). * Oxide fibers can be such as aluminium oxide (Al2 O3 ), alumina zirconia mixtures (Al2 O3 +Zr2 O2 ), yttria-alumina-garnet (YAG), and mullite (3Al2 O3 -2SiO2 ). Ceramic fibers of pure Al2 O3 in a single crystalline microstructure are called sapphire fibers.

4.7.6. Polymer Fibers Aramid fiber (Kevlar) R R Aramids are a family of nylons, including Nomex° and Kevlar° ( Polyamide -PA). Aramid fibers, see Figure 4.11 are known for their large hardness and resistance to penetration. Thanks to their toughness aramid fibres are used where high

Figure 4.11: Aramid fibre. impenetrability is required, e.g. bulletproof vests, bike tires, airplanes wings, and sport equipment. These fibres are not as spread as glass or carbon fibres, mostly because of their cost, high water absorption, and their difficult post-processing. 72

R R (References: DuPont (Kevlar° ) Fibers of KEVLAR° consist of long molecular chains produced from poly-paraphenylene terephthalamide). PPTA is the acronym for para-phenylen-terephthalamid. Polymers are not only used for the matrix, they also make a good reinforcement material in composites. For example, Kevlar is a polymer fibre that is immensely strong and adds toughness to a composite. It is used as the reinforcement in composite products that require lightweight and reliable construction (e.g., structural body parts of an aircraft). Composite materials were not the original use for Kevlar; it was developed to replace steel in radial tires and is now used in bulletproof vests and helmets. Kevlar, and aramid-fiber composite can be used as textile fibers. Applications include bullet-proof vests, tires, brake and clutch ◦ linings. Servicetemperature of Aramid fibre is up to 250 C, and its melting tem◦ perature is 426.7 C.

UHMW-PE - Ultra-high molecular weight polyethylene UHMW, see Figure 4.12, is a polymer material composed of long chains with

Figure 4.12: UHMW.
R a very high molecular weight. It even replaced Kevlar° for making bullet-proof vests! UHMW-PE combines the traditional abrasion and cut resistance of metal alloys with the impact and corrosion resistance of synthetic materials. Tough as a metal, self-lubricating and slippery. UHMW-PE fibres have the tendency to elongate under load (creep). They are extremely low density, and they can float. ◦ ◦ Melting-point between 120 and 150 C. Applications are being developed particularly in the areas of ballistic protection and ropes. The material is inflammable. These fibres have a tensile strength 20 times greater than that of steel, and 40% stronger than aramid. Their free breaking length is around 330 km (steel breaks at 25, glass at 135, carbon at 195 and aramid at 235).

73

Figure 4.13: Liquid crystal polymer. Products: Bullet-proof vest, Cut-resistant gloves, Psychiatric clothing. LCP - Liquid crystal polymer LCP, see Figure 4.13 is a thermoplastic fibre with exceptional strength and rigidity (five times that of steel), and about 15 times the fatigue resistance of aramid. Very good impact resistance. It doesn’t absorb moisture, has very low stretch, it doesn’t creep like UHMW-PE fibre, and has excellent abrasion, wear, ◦ and chemical resistance. Its high melting-point (320 C) allows the retention of these properties over broad ranges of temperatures. It is suitable for industrial, electronic, and aerospace applications, as well as for ropes, and sport equipment. Products: Fishing line, High performance rope, Tennis racket.

4.7.7. Carbon nanotube (CNT) fibers Strong and versatile carbon nanotubes are finding new applications in improving conventional polymer-based fibers and films. For example, composite fibers made from single-walled carbon nanotubes (SWNTs) and polyacrylonitrile, a carbon fiber precursor, are stronger, stiffer and shrink less than standard fibers. Nanotube-reinforced composites could ultimately provide the foundation for a new class of strong and lightweight fibers with properties such as electrical and thermal conductivity unavailable in current textile fibers

74

Figure 4.14: Spidersilk. 4.7.8. Fiber hybrids Fiber hybrids capitalize on the best properties of various fiber types, while reducing raw material costs. Hybrid composites combining carbon/aramid and carbon/glass fibers have been used successfully in ribbed aircraft engine thrust reversers, telescope mirrors, drive shafts for ground transportation and infrastructure column-wrapping systems. For example, in hybrid-fiber flywheels for electric vehicles, the composite components withstand energy forces as high as 2.5 million ft-lb. 4.7.9. Spider silk Spider silk is a biopolymer fiber and a natural composite, see Figure 4.14 and chapter 4.2. It is 5 times as strong as steel and 2 times as strong as Kevlar. Man-made spider silk has now become a reality. "Spider-goats," ( goats that are created having one spider gene added to the 70,000 genes that make a goat a goat) for example, produce an extra protein in their milk that can be spun into man-made spider silk. Spider silk is stronger, by weight, than anything else on earth. The hope was to spin silk from milk - and use the ultra-light material for things like bulletproof vests. It turns out that it takes a lot of goat milk to make just a small bit of silk, so for now the idea of making bulletproof vests out of spider silk has been put aside. Other uses of the material, medical sutures, for example are in progress instead.

75

Figure 4.15: Crayons on Aerogel over a flame. 4.8. Aerogel composites Aerogel is 99.8% air, and provides 39 times more insulating than the best fiberglass insulation, and is 1,000 times less dense than glass, see Figure 4.15 http://stardust.jpl.nasa.gov/ tech/aerogel.html where the picturecan be found. A cube of 1x1x1 meter of aerogel will only weight three kg. It can also be exposed to temperatures up to 1400◦ C before it will soften. Aerogel is not like conventional foams, but is a special porous material with extreme microporosity on a micron scale. It is composed of individual features only a few nanometers in size. These are linked in a highly porous dendritic-like structure. This exotic substance has many unusual properties, such as low thermal conductivity, refractive index and sound speed - in addition to its exceptional ability to capture fast moving dust. Aerogel is made by high temperature and pressurecritical-point drying of a gel composed of colloidal silica structural units filled with solvents. Silica aerogel is just another form of glass. If aerogel is handled roughly, it will break just like glass. However, if care is taken, the material can be handled and shaped effectively. Silica aerogels are inorganic solids, very brittle and usually very low density materials. A collapse of the solid network in the material occurs gradually, spreading the force of impact out over a longer time, and is why they can be very useful as energy absorbing materials. Aerogels can be added different materials/particles in order to obtain special 76

effect of the materials. For instance can we add metal salts, or other compounds to a sol before gelation. Then we may obtain a deep blue aerogel by adding nickel; while a pale green color appears by adding copper; a black gel contains carbon and iron; and orange aerogel is added iron oxide. It is also possible to obtain a magnetic aerogel by using chemical vapor infiltration to get iron oxide introduced in the material. The aerogel can also be made photoluminescent, which means that it glows-in-the-dark by using a pigment that absorbs light and emits that energy over a period of time -even after the light source has been removed. The pigment is rechargeable. Flexible aerogels In the mid to late 1990’s, Aspen Systems perfected proprietary changes in the formulation, processing and drying of aerogels, reducing drying time to a few hours. Besides a cost effective drying time, the aerogels were also isolated in the form of thin, flexible blankets. The blankets were much more robust than the monoliths and beads, and could also be easily installed like any other flexible batting. These breakthroughs led to the formation of Aspen Aerogels, Inc. in 2001, and the commercialization of aerogel technology for broad use, see for instance the Figure 4.16 Aspen Aerogels has created a variety of organic and inorganic/organic hybrid aerogel formulations including those made from polydimethylsiloxane/silica, cellulose polyurethane, polyimide, polymethylmethacrylate/silica, and polybutadiene rubber. These materials show enhanced physical and mechanical properties relative to pure silica aerogel. As shown in the table below, aerogels offer significantly more insulating value per unit of material than other insulations: Material Aerogel Polyurethane foam Polystyrene foam Microporous silica fiberglass Mineral wool Perlite Calcium Silicate
W Thermal Conductivity (k) [ mK ] 0.012 0.021 0.038 0.019-0.038 0.040 0.038 0.040-0.060 0.047

77

Figure 4.16: Areas that Aspens flexible aerogels can be used in. The picture is from:
http://www.aerogel.com/markets.htm

4.9. Textile composites There is a new ”class” of composites, called textile composites. The material comes from a new technique which instead of the reinforcing fibres being put in place individually, which is slow and costly, they can be knitted or woven together to make a sort of cloth. This can even be three-dimensional rather than flat, see Figure 4.17. The spaces between and around the textile fibers may be filled with the matrix material (such as a resin) to make the final product. This process can quite easily be done by machines rather than by hand, making it faster and cheaper. Connecting all the fibres together also means that the composite is less likely to be damaged when struck. 4.10. Bio-inspired materials Researchers are making rapid progress in the design and synthesis of non-natural oligomers and polymers that emulate the properties of natural proteins (also called bio-inspired materials). For instance is NASA trying to tailor new materials that can mimic the extraordinary structural and self-repairing properties of biological 78

Figure 4.17: Three dimensional braiding of composite structures. substances such as bone or sea shells, also called bio-inspired materials. Such biologically inspired materials can adapt to changing conditions and therefore they can help to make airplanes and spacecraft lighter, stronger and more reliable. New advanced materials can also be able to change their shapes (i.e. airplane wings which today is done with hydraulics). The hope is to find materials that change shape on command because then we could improve for instance airplanes tremendously. Also the so-called ’self-healing’ materials could be very important to space exploration, thus even small sand grain particle of a meteor could puncture the hull of existing space vehicles. 4.11. Self-healing composites Inspired by biological systems in which damage triggers an autonomic healing response, researchers at the University of Illinois have developed a synthetic material that can heal itself when cracked or broken. The material — consisting of a microencapsulated healing agent and a special catalyst embedded in a structural composite matrix — could increase the reliability and service life of thermosetting polymers used in a wide variety of applications ranging from microelectronics to aerospace. ”Once cracks have formed within typical polymeric materials, the integrity of the structure is significantly compromised,” said Scott White, a UI professor of aeronautical and astronautical engineering and lead author of a paper published in the Feb. 15 (2001) issue of the journal Nature that described the new self-healing material. 79

Figure 4.18: Self healing composite from http://www.cerncourier.com. ”Often these cracks occur deep within the structure where detection is difficult and repair is virtually impossible.” In the new material, however, the repair process begins as soon as a crack forms. ”When the material cracks, the microcapsules rupture and release the healing agent into the damaged region through capillary action,” White said. ”As the healing agent contacts the embedded catalyst, polymerization is initiated which then bonds the crack face closed.” In recent fracture tests, the self-healed composites recovered as much as 75 percent of their original strength. And because microcracks are the precursors to structural failure, the ability to heal them will enable structures that last longer and require less maintenance. The concept of the autonomic healing system. ”Filling the microcracks will also mitigate the harmful effects of environmentally assisted degradation such as moisture swelling and corrosion cracking,” White said. ”This technology could increase the lifetime of structural components, perhaps by as much as two or three times.” The ability to self-repair and restore structural integrity also could extend the lifetimes of polymer composite circuit boards, where microcracks can lead to both mechanical and electrical failure.

80

Figure 4.19: (a) In a right-handed material, where both permittivity and permeability are positive, the index of refraction is positive and the law of optics follow our intuition. (b) This is not the case in a left-handed material with negative permittivity and permeability. In that case the index of refraction is negative and a convergent lens becomes divergent. Figure from: http://www.ifh.ee.ethz.ch/~martin/res10.en.html 4.12. Left-handed metamaterials Metamaterials are engineered composites exhibiting properties that are not observed in the constituent materials and not observed in nature. The response of a material to electromagnetic fields is entirely characterized by its permittivity and its permeability. The former gives the response to an applied electric field, while the latter describes the response to a magnetic field. They determine how electromagnetic waves (including microwaves and visible light) interact with the material. These two parameters are not constant, but depend on the illumination frequency (for example a semiconductor can be opaque in the visible range, but transparent in the infrared). Quite surprising effects can also arise for specific values of these two parameters. For example, when the permittivity takes particular negative values plasmon resonances can be excited in the material, see Figure 4.19.

Composite Material with ”reversed” physical properties
Minneapolis, MN-Physicists at the University of California, San Diego (UCSD) have produced a new class of composite materials with unusual physical properties that scientists theorized might be possible, but have never before been able to produce in nature. ”Composite materials like this are built on a totally new concept,” said the two co-leaders of the UCSD team, Sheldon Schultz and David R. Smith, who 81

announced their discovery at a news conference. ”While they obey the laws of physics, they are predicted to behave totally different from normal materials and should find interesting applications.” The unusual property of this new class of materials is essentially its ability to reverse many of the physical properties that govern the behavior of ordinary materials. One such property is the Doppler effect, which makes a train whistle sound higher in pitch as it approaches and lower in pitch as it recedes. According to Maxwell’s equations, which describe the relationship between magnetic and electric fields, microwave radiation or light would show the opposite effect in this new class of materials, shifting to lower frequencies as a source approaches and to higher frequencies as it recedes. Similarly, Maxwell’s equations further suggest that lenses that would normally disperse electromagnetic radiation would instead focus it within this composite material. This is because Snell’s law, which describes the angle of refraction caused by the change in velocity of light and other waves through lenses, water and other types of ordinary material, is expected to be exactly opposite within this composite. ”If these effects turn out to be possible at optical frequencies, this material would have the crazy property that a flashlight shining on a slab can focus the light at a point on the other side,” said Schultz. ”There’s no way you can do that with just a sheet of ordinary material.” Underlying the reversal of the Doppler effect, Snell’s law, and Cerenkov radiation (radiation by charged particles moving through a medium) is that this new material exhibits a reversal of one of the ”right-hand rules” of physics which describe a relationship between the electric and magnetic fields and the direction of their wave velocity. The new materials are known by the UCSD team colloquially as ”left-handed materials,” after a term coined by Veselago, because they reverse this relationship. What that means is physically counterintuitive-pulses of electromagnetic radiation moving through the material in one direction are composed of constituent waves moving in the opposite direction. The UCSD physicists emphasized that while they believe their new class of composites will be shown to reverse Snell’s law, the specific composite they produced will not do so at visible-light frequencies. Instead, it is now limited to transmitting microwave radiation at frequencies of 4 to 7 Gigahertz-a range somewhere between the operation of household microwave ovens (3.3 Gigahertz) and military radars (10 Gigahertz). 82

The composite constructed by the UCSD team-which also consisted of Willie J. Padilla, David C. Vier, and Syrus C. Nemat-Nasser-was produced from a series of thin copper rings and ordinary copper wire strung parallel to the rings. It is an example of a new class of materials scientists call ”metamaterials.” ”Even though it is composed of only copper wires and copper rings, the arrangement has an effective magnetic response to microwaves that has never been demonstrated before,” said Schultz. What’s unusual about the new class of materials produced by the UCSD team is that it simultaneously has a negative electric permittivity and a negative magnetic permeability, a combination of properties never before seen in a natural or man-made material. ”And the interesting thing is that it’s produced with no magnetic material,” said Schultz. ”It’s all done with copper.” ”The bottom line,” said Smith, ”is that this material- this metamaterial, at frequencies where both the permittivity and permeability are negative, behaves according to a left-handed rule, rather than a right-handed rule.” Questions • What is the theory behind composite materials? • What is a composite material? • How do we classify composite materials according to their matrix phase? • What is the greatest advantage of composite materials? • What is the greatest disadvantage of composite materials? • Why is specific modulus and specific strength important? • What does Fiber Reinforced Plastics (FRP) mean? • What kind of reinforcement can composites have? Illustrated them. • What kind of fibers are there, and what are their advantages/disadvantages? • What is so special about spider silk, can you find out the prospect for commercialisation of spider silk? • What is the primary function of the reinforcement and the matrix in the composite material? • How do we find the modulus of the entire composite? • How do we classify composites? •What is so special about high performance materials? • What is the strength of the composite primarily depending on? • What is CMC, MMC, and PMC? What are the differences? Where are the applications? 83

• What is the advantages of MMCs compared to monolithic metals? • What is the advantages of MMCs compared to PMC’s? • What is the disadvantages of MMCs compared to PMC’s and monolithic metals? • How does a self-healing composite work? • What is a left-handed material? • What is a metamaterial? References: Natural composites: http://www.imb-jena.de/~sponner/Current.html Fibers http://www.azonano.com/news.asp?newsID=82 MMC: http://www.tms.org/pubs/journals/JOM/0104/Rawal-0104.html http://www.electrovac.com/metall/indexe.htm http://www.machinedesign.com/bde/materials/compsites/rvmat2d.html http://www.pcc-aft.com/tech/mmc/mmc.html Ceramics: http://www-materials.eng.cam.ac.uk/mpsite/properties/non-IE/max_service_temp.html http://www.albint.com/web/techweav/techw.nsf/ http://www.engr.utk.edu/~cmc/ http://www.onera.fr/dmsc-en/matcer/ http://www.mmat.ubc.ca/other/courses/mmat382/cnc63.htm http://books.nap.edu/books/0309059968/html/7.html#pagetop http://www.ms.ornl.gov/programs/energyeff/cfcc/iof/chap24-6.pdf PMC http://www.npl.co.uk/npl/cmmt/cog/cmmthm098.html http://www.egr.msu.edu/cmsc/nsf/polymeric.html http://www.raypubs.com http://www.raypubs.com/hpcsb/sbover2.html#partdesign High-performance composites: http://www.etcusa.com/hpc/ Material database on internet: http://www.matweb.com/index.asp?ckck=1

84

Composites: http://composite.about.com/mbody.htm http://composite.about.com/cs/aboutcomposites/ http://www.mil17.org/ http://www.netcomposites.com/ http://www.science.org.au/nova/059/059key.htm http://www.efunda.com/materials/polymers/properties/ polymer_cat.cfm?MajorID=PA http://www.sdplastics.com/ http://www.howstuffworks.com/ question87.htm http://www.users.globalnet.co.uk/~weeks/Composite%20Materials.htm http://callisto.my.mtu.edu/my472/ http://home.earthlink.net/~ttc/about.html http://www.mech.utah.edu/~rusmeeha/labNotes/composites.html http://ice.chem.wisc.edu/materials/composite.html http://www.psrc.usm.edu/macrog/index.htm http://callisto.my.mtu.edu/MY472/ http://www.matweb.com/searchcompenglish.htm http://plastics.about.com/library/weekly/aa980323.htm http://www.advancedcomposites.com/technology.htm http://www.nap.edu/books/0309059968/html/index.html http://www.technica.net/NF/NF2/efibreinorganiche.htm http://www.fibreglast.com/ Aerogel materials: http://www.ntnu.no/gemini/2002-05/16-19.htm http://www.tu.no/snadder/article.jhtml?articleID=14148 http://stardust.jpl.nasa.gov/tech/aerogel.html http://www.taasi.com/what.htm http://www.aspensystems.com/ http://www.aerogel.com/technology.htm Textile composites: http://www.mtm.kuleuven.ac.be/Research/C2/poly/Modelling.htm http://www.muratec.net/braider/ http://www.engr.ukans.edu/~rhale/textiles/index.htm http://www.ntcresearch.org/pdf-rpts/AnRp00/I00-A06.pdf http://www.innovationave.com/storage/PDF/advmaterials/ghosh.pdf 85

http://fiberarchitects.com/ http://www.mtm.kuleuven.ac.be/Research/C2/poly/wisetex.html http://www.stru.polimi.it/Compositi/Compositi_dx.htm John Summerscales, Microstructural characterisation of fibre-reinforced composites, ISBN 1 85573 240 8, 320 pages, 1998. General: http://claymore.engineer.gvsu.edu/~jackh/eod/ Race-car: http://www.mse.cornell.edu/courses/engri111/racecar.htm FRP manufact: http://www.owenscorning.com/owens/composites/about/introduction.asp Sspace-age materials: http://www.spacedaily.com/news/materials-02zh.html High-performance composites: http://www.etcusa.com/hpc/ http://www.raypubs.com/hpcsb/sboverview.html http://www.atlcomposites.com/products_composite_duflex_intro.htm http://www.quadrantepp-europe.com/idqua001.asp http://www.bayplastics.co.uk/ http://www.tstar.com/pdf/quadrant-DF.pdf High-performance materials: http://www.hiper-group.com/hcproducts.htm Self-healing material: http://www.news.uiuc.edu/scitips/01/0214selfheal.html http://www.globaltechnoscan.com/21stFeb-27thFeb01/biological.htm Left-handed composite materials/metamaterials: http://ucsdnews.ucsd.edu/newsrel/science/mccomposite.htm http://www-physics.ucsd.edu/lhmedia/ http://www.ing.dk/konf/root/redproduktion/sub/graenseland/html/0106.html http://physics.ucsd.edu/~drs/left_home.htm http://www.ifh.ee.ethz.ch/~martin/res10.en.html http://physics.ucsd.edu/lhmedia/

86

5. Smart (intelligent) Materials and Structures
Smart materials are not smarter than you. Smart materials respond to environmental stimuli with particular changes in some variables. For that reason they are often also called responsive materials or functional materials. Depending on changes in some external conditions, ”smart” materials change either their properties (mechanical, electrical, appearance), their structure or composition, or their functions. They are materials able to transform other forms of energy to mechanical energy and, sometimes, vice versa. These are unique type of materials and have similarities in microstructures and deformation mechanisms. Fundamental understanding on the behavior of these materials is still on the way, meanwhile, various novel applications of these materials are found of successful. The technological field of smart materials (see [16]) has evolved over the past decades with increasing pace during the 1990s. At a more sophisticated level, such smart materials become intelligent when they have the ability to respond intelligently and autonomously to dynamicallychanging environmental conditions. Potential applications are widespread and have excited interest in industrial, military, commercial, medical, automotive and aerospace fields. Embedded fibreoptic sensing systems are employed in many engineering disciplines to monitor critical characteristics. Several smart skins programmes have been initiated for both civil and military aircraft. Large space structures are also candidates for the incorporation of smart structural systems because of the variable service conditions in which they operate. Typical applications include, sensors and actuators, vibration suppression and damping device, micro-electro-mechanical-system, biomedical engineering, space, robot, etc., to name a few. These materials will greatly help us to further improve the way of living of our human being (see i.e.[19]). Furthermore, one should note that the terms Smart materials, Intelligent Materials, Active Materials, Adaptive Materials, (and to some extent) actuators and sensors, are almost always, used interchangeably. We will consider the following 4 main groups of smart materials in more detail • — — — — Color Changing Materials Light Emitting Materials Moving Materials Temperature Changing Materials

87

5.1. Color Changing Materials Color changing materials are materials that change color due to different external stimuli. 5.1.1. Photochromic materials Photochromic materials change reversibly color with changes in light intensity, see Figure 5.1. Usually, they are colorless in a dark place, and when sunlight or ultraviolet radiation is applied molecular structure of the material changes and it exhibits color. When the relevant light source is removed the color disappears. Changes from one color to another color are possible mixing photochromic colors with base colors. They are used in paints, inks, and mixed to mould or

Figure 5.1: Photochromic material. casting materials for different applications. 5.1.2. Thermochromic materials Thermochromic materials change reversibly color with changes in temperature, see Figure 5.2. They usually are semi-conductor compounds. The change in color happens at a determined temperature, which can be varied doping the material. They are used to make paints, inks or are mixed to moulding or casting materials for different applications. 5.2. Light Emitting Materials Light emitting materials are materials that change the light in some sense, due to some external stimuli. 88

Figure 5.2: Thermochromic material. 5.2.1. Electroluminescent materials Electroluminescent materials produce a brilliant light of different colors when stimulated electronically, see Figure 5.3.

Figure 5.3: Electroluminescent material. Electroluminescent materials are a combination of phosphorous and fluorocarbons that produce a brilliant light of different colors when stimulated electronically (e.g. by AC current). While emitting light no heat is produced. They can be used for making lightstripes for decorating buildings, or for industrial and public vehicles safety precautions. 5.2.2. Fluorescent materials Fluorescent materials produce visible or invisible light as a result of incident light of a shorter wavelength (i.e. X-rays, UV-rays, etc.). The effect ceases as soon as 89

the source of excitement is removed, see Figure 5.4.

Figure 5.4: Fluorescent material. Fluorescent pigments in daylight have a white or light color, whereas under excitation by UV radiation they irradiate an intensive fluorescent color. They can be used for paints, inks or mixed to moulding or casting materials for different applications. 5.2.3. Phosphorescent materials Phosphorescent materials (or afterglow materials) produce visible or invisible light as a result of incident light of a shorter wavelength (i.e. X-rays, UV-rays, etc.), detectable only after the source of the excitement has been removed, see Figure 5.5.

Figure 5.5: Phosphorescent material.

90

Afterglow effect pigments are polycrystalline inorganic zinc sulphide (green afterglow) or alkaline earth sulphides (red or blue afterglow), and can be used in paints, inks or mixed to moulding or casting materials for different applications. 5.3. Moving Materials Moving materials are materials that in some sense move when exposed to some special external source. 5.3.1. Conducting polymers Conducting polymers are conjugated polymers, through which electrons can move from one end of the polymer to the other. The most common are polyaniline

Figure 5.6: Conducting polymer. (PAni) and polypyrrole (PPY). Polipyrrole has been used for the development of micro muscles. Polyaniline films sandwiched around a ion-conducting film are considered as material for artificial muscles for robots. A current flow reduces one side and oxidizes the other. Ions are transferred. One side expands and the other contracts, resulting in a bending of the sandwich, see Figure 5.6. Electrical and chemical energies are in this way transformed into mechanical energy. Conducting polymers are still at a research level. Presently, the expected lifetime of the muscle is of 100.000 actuations. In the Year 2000 Alan Heeger got the Nobel Price in chemistry for the invention of a conducting polymer.

91

5.3.2. Dielectric elastomers Dielectric elastomers (also called electrostrictive polymers) exhibit a mechanical strain when subjected to an electric field as shown in Figure 5.7. The most com-

Figure 5.7: Dielectric elastomers. mon are PMMA-based electrostrictive polymers. Thanks to their electrostrictive strain, they can be sandwiched between two electrodes to emulate the operation of muscles. In an electric field, the elastomer expands in the plane of the electrodes, amplifying the normal compression due to the electrostatic charges on the electrodes. The result is a muscle with large strain capability, and a large actuation pressure. 5.3.3. Piezoelectric materials Piezoelectric materials produce an electric field when exposed to a change in dimension caused by an imposed mechanical force (piezoelectric or generator effect), see Figure 5.8. Conversely, an applied electric field will produce a mechanical stress (electrostrictive or motor effect). They transform energy from mechanical to electrical and vice-versa and are used for sensing purposes (e.g. microphone, transducer), and for actuating applications. Similar to piezoelectric materials are electrostrictive and magnetostrictive materials used in high precision actuation. They are ferromagnetic materials which experience an elastic strain when subjected to an electric or magnetic field respectively. Products: Smart skis, Mothra plain, Acoustic transducer, Multilayer cofired actuator, Magnetostrictive linear motor, Smart skin.

92

Figure 5.8: Piezoelectric material. 5.3.4. Polymer gels Polymer gels consist of a cross-linked polymer network inflated with a solvent such as water, see Figure 5.9. They have the ability to reversibly swell or shrink

Figure 5.9: Polymer gels. (up to 1000 times in volume) due to small changes in their environment (pH, temperature, electric field). Micro sized gel fibres contract in milliseconds, while thick polymers layers require minutes to react (up to 2 hours or even days). They have high strength and can deliver sizeable stress (approximately equal to that of human muscles). The most common are polyvinylalcohol (PVA), polyacrylicacid (PAA) and 93

polyacrylonitrile (PAN). There are many potential applications for these materials (e.g. artificial muscles, robot actuators, adsorbers of toxic chemicals), but presently, few of them have a commercial diffusion. Response time is still not fast enough for artificial muscles. Lifetime of a gel actuator is very short. Their structure gradually degrades and they become unusable. Commercial reality is still far away. 5.3.5. Shape memory materials (SMM) Shape memory alloys (SMA) are metals that, after being strained, at a certain temperature revert back to their original shape, see Figure 5.10. A change in their crystal structure above their transformation temperature causes them to return to their original shape. SMAs enable large forces (generated when encountering any resistance during their transformation) and large movements actuation, as they can recover large strains.

Figure 5.10: Shape memory alloys (SMA). Shape-memory materials are also superelastic, namely they are able to sustain a large deformation at a constant temperature, and when the deforming force is released they return to their original undeformed shape. Typically, they can undergoe elastic strain up to 10%. The shape memory effect is a unique property of certain alloys. Even though the alloy is deformed in the low temperature phase, it recovers its original shape on being heated to a critical higher temperature. The material is one that undergoes a change of crystal structure at a certain temperature called the transformation temperature. Above this temperature the material has one crystal structure (cubic 94

in the case of Cu-Al-Ni) and below this temperature it has another (orthorhombic for Cu-Al-Ni). The low temperature structure of these types of materials allows the material to be easily and apparently permanently deformed. However on heating the material returns to its high temperature structure which has only one possible shape. Thus the material has ”remembered” its shape (see also [20]). Generally, these materials can be plastically deformed at some relatively low temperature, and upon exposure to some higher temperature will return to their shape prior to the deformation. Materials that exhibit shape memory only upon heating are referred to as having a one-way shape memory. Some materials also undergo a change in shape upon recooling. These materials have a two-way shape memory. Products: SMA stent for veins, Superelastic glasses, Coffeepot thermostat, Electrical connector. Also shape-memory ceramics and polymers (SMP) exist. Shape-memory polymer for instance, converts from a temporary shape (top) to its parent shape (bottom) in 45 seconds at 65o C. Commercial SME Alloys The only two alloy systems that have achieved any level of commercial exploitation are the NiTi alloys and the copper-base alloys. Properties of the two systems are quite different. The NiTi alloys have greater shape memory strain (up to 8% versus 4 to 5% for the copper-base alloys), tend to be much more thermally stable, have excellent corrosion resistance compared to the copper-base alloys’ medium corrosion resistance and susceptibility to stress-corrosion cracking, and have much higher ductility. On the other hand, the copper-base alloys are much less expensive, can be melted and extruded in air with ease, and have a wider range of potential transformation temperatures. The two alloy systems thus have advantages and disadvantages that must be considered in a particular application. 5.3.6. Nanostructured Shape Memory Materials Nanoscale materials have enjoyed recent interest because of the changes that occur in material behavior as surface effects and grain boundary behavior play a larger role in the overall mechanical behavior of the material. Shape memory alloys continue to be explored for more dramatic superelastic behavior and several of these alloys have already proven to have wide ranging applications in the aerospace, biomedical, and microelectronics industries. A nanostructured shape memory alloy is on the leading edge of materials development and will allow fur95

Figure 5.11: Magnetically controlled shape memory materials (MSM) replace machines. ther advances in the application of shape memory alloys to microscopic structures and miniaturized devices. Foils of nickel-titanium alloy with nanoscale structure have been successfully fabricated. Preliminary characterization testing has been conducted which confirms that the primary phase present in the material is NiTi which is the phase displaying shape memory behavior. 5.3.7. Magnetic Shape Memory (MSM) Materials Magnetic Shape Memory effect is a new invention in actuator materials field, allowing even 50 times greater strains than in previous magnetically controlled materials (magnetostrictive materials). In MSM materials the magnetic field moves microscopical parts of the material (so called twins) that creates a net shape change of the material. The mechanism enables also more complicated shape changes than conventional linear strain, such as bending and shear. Strains can be even 5 % (depending on the material). Typically, present MSM materials produce 2 % strain at 0 to 2 MPa stress in actuator use. AdaptaMat is developing a commercial grade MSM alloy. MSM material samples can be produce for research use. MSM materials field of application seems to be very wide, ranging from automotive applications to home electronics. They can simplify complicated mechanical structures. Consider a sewing machine, as in Figure 5.11: traditional sewing machine has a rotating electric motor and a large number of parts in a rather complicated mechanical transmission system, although the desired motion of the needle is up and down. A sewing machine based on MSM technology could consist 96

of an electromagnet (coil) and a needle made of MSM-material. 5.4. Temperature Changing Materials Temperature changing materials are materials that change temperature in some way, when exposed to some sort of external source. 5.4.1. Thermoelectric materials Thermoelectric materials are special types of semiconductors that, when coupled, function as a ”heat pump”, see Figure 5.12. By applying a low voltage DC power

Figure 5.12: Thermoelectric materials. source, heat is moved in the direction of the current (+ to -). Usually, they are used for thermoelectric modules where a single couple or many couples (to obtain larger cooling capacity) are combined. One face of the module cools down while the other heats up, and the effect is reversible. Thermoelectric cooling allows for small size and light devices, high reliability and precise temperature control, and quiet operation. Disadvantages include high prices and high operating costs, due to low energy efficiency.

97

Figure 6.1: Aluminium foam / functional gradient material in car.

6. Functional Gradient Materials
Functional (FGM) gradient materials are materials that have a gradual variation of material properties from one end to another, as shown in Figure 6.1. The concept of Functionally Gradient Materials (FGM) was first put forward for reducing thermal stress. A kind of special materials which can be used long-term in high temperature and large difference of temperature is needed as aerospace industry is developing at high speed. The thermal stress in materials is so large that neither pure metals, pure ceramics nor cladding materials can meet this strict condition. Man-made functionally graded materials (FGMs) copy natural biomaterials, such as bamboo, teeth and shell etc., with a gradient in chemical composition or microstructure from one side to the other side in the material. Materials with a gradual change in chemical composition or microstructure are expected to have advanced or new properties. The concept of functionally graded materials was proposed in 1984 by material scientists in the Sendai area in Japan. Since then studies to develop high-performance heat-resistant materials using functionally graded technology have continued. In recent years, another attempt to apply the FGM concept to the functional materials has been initiated. The typical design of the FGMs is that the varying composition of the FGMs from high ceramic content on one side of bulk material to high metal content on the other side. This may lead to good wear resistance, good corrosion resistance, good heat resistance on the high ceramic content side and good fracture resistance, 98

Figure 6.2: Functional (FGM) gradient materials. good thermal conductivity on the high metal content side. The joining of ceramics to metals is of great engineering significance for various advanced technologies, including high-temperature structural applications in, e.g., turbine airfoils and combustors. A crucial matter in the ceramic-metal joint system is to develop an efficient means to suppress the damage to be induced by thermal stresses (cracking, interfacial decohesion, etc.), see Figure 6.2.

99

Figure 6.3: Functional (FGM) gradient materials.

100

Figure 7.1: The picture shows a solar cell which is made from a monocrystalline silicon
wafer.

7. Solar Cell Materials
A solar cell or photovoltaic cell is a device that converts light energy into electrical energy. Sometimes the term solar cell is reserved for devices intended specifically to capture energy from sunlight, while the term photovoltaic cell is used when the light source is unspecified. Fundamentally, the device needs to fulfill only two functions: photogeneration of charge carriers (electrons and holes) in a light-absorbing material, and separation of the charge carriers to a conductive contact that will transmit the electricity (simply put, carrying electrons off through a metal contact into a wire or other circuit). This conversion is called the photovoltaic effect, and the field of research related to solar cells is known as photovoltaics. Solar cells have many applications. They have long been used in situations where electrical power from the grid is unavailable, such as in remote area power systems, Earth-orbiting satellites and space probes, consumer systems, e.g. handheld calculators or wrist watches, remote radiotelephones and water pumping applications. More recently, they are starting to be used in assemblies of solar modules (photovoltaic arrays) connected to the electricity grid through an inverter, often in combination with a net metering arrangement (ref. wikipedia). 7.1. Light-absorbing materials All solar cells require a light absorbing material contained within the cell structure to absorb photons and generate electrons via the photovoltaic effect. The materials used in solar cells tend to have the property of preferentially absorbing the wavelengths of solar light that reach the earth surface; however, some solar cells are optimized for light absorption beyond Earth’s atmosphere as well. Light absorbing materials can often be used in multiple physical configurations to take 101

advantage of different light absorption and charge separation mechanisms. Many currently available solar cells are configured as bulk materials that are subsequently cut into wafers and treated in a "top-down" method of synthesis (silicon being the most prevalent bulk material). Other materials are configured as thinfilms (inorganic layers, organic dyes, and organic polymers) that are deposited on supporting substrates, while a third group are configured as nanocrystals and used as quantum dots (electron-confined nanoparticles) embedded in a supporting matrix in a "bottom-up" approach. Silicon remains the only material that is wellresearched in both bulk and thin-film configurations. The following is a current list of light absorbing materials, listed by configuration and substance-name: 7.2. Silicon By far, the most prevalent bulk material for solar cells is crystalline silicon (abbreviated as a group as c-Si), also known as "solar grade silicon". Bulk silicon is separated into multiple categories according to crystallinity and crystal size in the resulting ingot, ribbon, or wafer. • monocrystalline silicon (c-Si): often made using the Czochralski process. Single-crystal wafer cells tend to be expensive, and because they are cut from cylindrical ingots, do not completely cover a square solar cell module without a substantial waste of refined silicon. Hence most c-Si panels have uncovered gaps at the corners of four cells. • Poly- or multicrystalline silicon (poly-Si or mc-Si): made from cast square ingots – large blocks of molten silicon carefully cooled and solidified. These cells are less expensive to produce than single crystal cells but are less efficient. • Ribbon silicon: formed by drawing flat thin films from molten silicon and having a multicrystalline structure. These cells have lower efficiencies than poly-Si, but save on production costs due to a great reduction in silicon waste, as this approach does not require sawing from ingots. • New Structures: These new compounds are special arrangements of silicon that can dramatically improve efficiency such as ormosil. [edit]

102

7.3. Thin films The various thin-film technologies currently being developed reduce the amount (or mass) of light absorbing material required in creating a solar cell. This can lead to reduced processing costs from that of bulk materials (in the case of silicon thin films) but also tends to reduce energy conversion efficiency, although many multi-layer thin films have efficiencies above those of bulk silicon wafers. • CdTe: Cadmium telluride is an efficient light-absorbing material for thinfilm solar cells. CdTe is easier to deposit and more suitable for large-scale production. Despite much discussion of the toxicity of CdTe-based solar cells, this is the only technology (apart from amorphous silicon) that can be delivered on a large scale. • CIGS: are multi-layered thin-film composites. The abbreviation stands for copper indium gallium diselenide. The best efficiency of a thin-film solar cell as of December 2005 was 19.5% with CIGS absorber layer. Higher efficiencies (around 30%) can be obtained by using optics to concentrate the incident light. • CIS: CIS is an abbreviation for general chalcopyrite films of copper indium selenide (CuInSe2), CIGS mentioned above is a variation of CIS. While these films can achieve 13.5% efficiency, their manufacturing costs at present are high when compared with a silicon solar cell but continuing work is leading to more cost-effective production processes • Gallium arsenide (GaAs) multijunction:High-efficiency cells have been developed for special applications such as satellites and space exploration. These multijunction cells consist of multiple thin films produced using molecular beam epitaxy. A triple-junction cell, for example, may consist of the semiconductors: GaAs, Ge, and GaInP2. GaAs multijunction devices are the most efficient solar cells to date, reaching a record high of 40.7% efficiency under solar concentration and laboratory conditions. In production, GaAs triple-junction cells reach efficiencies above 28.3%. They are also some of the most expensive cells per unit area (up to US$40/cm2 ). • Dye-sensitized solar cells are a relatively new class of low-cost solar cells. They are based on a semiconductor formed between a photo-sensitized anode and an electrolyte, a photoelectrochemical system. Typically a ruthenium metalorganic dye (Ru-centered) used as a monolayer of light-absorbing 103

material. The dye-sensitized solar cell depends on a mesoporous layer of nanoparticulate titanium dioxide to greatly amplify the surface area (200300 m2 /gram TiO2, as compared to approximately 10 m2 /gram of flat single crystal). • Organic solar cells and Polymer solar cells are built from thin films (typically 100 nm) of organic semiconductors such as polymers and small-molecule compounds like polyphenylene vinylene, copper phthalocyanine (a blue or green organic pigment) and carbon fullerenes. Energy conversion efficiencies achieved to date using conductive polymers are low at 6% efficiency for the best cells to date. • Silicon: Silicon thin-films are mainly deposited by Chemical vapor deposition (typically plasma enhanced (PE-CVD)) from silane gas and hydrogen gas. Depending on the deposition’s parameters, this can yield: Amorphous silicon (a-Si or a-Si:H), protocrystalline silicon or nanocrystalline silicon (ncSi or nc-Si:H). • Nanocrystalline solar cells: These structures make use of some of the same thin-film light absorbing materials but are overlain as an extremely thin absorber on a supporting matrix of conductive polymer or mesoporous metal oxide having a very high surface area to increase internal reflections (and hence increase the probability of light absorption). • CPV: Concentrating photovoltaic systems use a large area of lenses or mirrors to focus sunlight on a small area of photovoltaic cells. If these systems use single or dual-axis tracking to improve performance, they may be referred to as Heliostat Concentrator Photovoltaics (HCPV). 7.4. Silicon solar cell device manufacture Because solar cells are semiconductor devices, they share many of the same processing and manufacturing techniques as other semiconductor devices such as computer and memory chips. However, the stringent requirements for cleanliness and quality control of semiconductor fabrication are a little more relaxed for solar cells. Most large-scale commercial solar cell factories today make screen printed poly-crystalline silicon solar cells. Single crystalline wafers which are used in the semiconductor industry can be made into excellent high efficiency solar cells, but they are generally considered to be too expensive for large-scale mass production. 104

Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin (180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p-n junction a few hundred nanometers below the surface. Antireflection coatings, which increase the amount of light coupled into the solar cell, are typically applied next. Over the past decade, silicon nitride has gradually replaced titanium dioxide as the antireflection coating of choice because of its excellent surface passivation qualities (i.e., it prevents carrier recombination at the surface of the solar cell). It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition (PECVD) (which is process that REC Scancell AS in Narvik uses). Some solar cells have textured front surfaces that, like antireflection coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually only be formed on singlecrystal silicon, though in recent years methods of forming them on multicrystalline silicon have been developed. The wafer is then metallized, whereby a full area metal contact is made on the back surface, and a grid-like metal contact made up of fine "fingers" and larger "busbars" is screen-printed onto the front surface using a silver paste. The rear contact is also formed by screen-printing a metal paste, typically aluminium. Usually this contact covers the entire rear side of the cell, though in some cell designs it is printed in a grid pattern. The metal electrodes will then require some kind of heat treatment or "sintering" to make Ohmic contact with the silicon. After the metal contacts are made, the solar cells are interconnected in series (and/or parallel) by flat wires or metal ribbons, and assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the front, and a polymer encapsulation on the back. Tempered glass cannot be used with amorphous silicon cells because of the high temperatures during the deposition process. References: http://en.wikipedia.org/wiki/Solar_cell#Light-absorbing_materials.

105

Figure 8.1: A ”nano-tube”, 1nm in diameter and may be 1000nm long. Carbon-atoms
in a ”periodic tube”.

8. Nano - materials - and technology
Nanoelectronics, Nanotechnology, Nanoconductor, Nanocomputer, Nanobots, from [13] are all technology based on nanoparticles which is a new functional material with length from 1 to 100nm, where 1 nanometer is 1·10−9 meter. In recent years, it has attracted worldwide attention in research and development of nano materials. The immediately available applications for these materials range from transparent skin-care products to microelectronic components and high-stress engine parts. In this near to atomic size range, the particles and dynamic properties of surface atoms can be exploited to modify and enhance the performance of basic raw materials (e.g. iron, aluminum and titanium). These materials have unique electrical, optical, chemical, structural and magnetic properties with potential applications including information storage, color imaging, bioprocessing, magnetic refrigeration, and ferrofluids. This type of new composite materials can be molecularly engineered. The capabilities allow products to achieve levels of strength and durability. It can also be use to produce designer materials with electronic, mechanical, chemical, magnetic, and optical behavior, beyond the capability of traditional materials. New generations of products and processes become possible. Nanoparticles are also widely applied in such fields as astronavigation, national 106

defense, magnetic recording devices, computerization, environmental protections, surface modification and medical/biological engineering etc. Manufactured products are made from atoms (see [17]). The properties of those products depend on how those atoms are arranged. If we rearrange the atoms in coal we can make diamond. If we rearrange the atoms in sand (and add a few other trace elements) we can make computer chips. If we rearrange the atoms in dirt, water and air we can make potatoes. It’s like trying to make things out of LEGO blocks with boxing gloves on your hands. Yes, you can push the LEGO blocks into great heaps and pile them up, but you can’t really snap them together the way you’d like. In the future, nanotechnology will let us take off the boxing gloves. We’ll be able to snap together the fundamental building blocks of nature easily, inexpensively and in almost any arrangement that we desire. This will be essential if we for instance want to continue the revolution in computer hardware. The greatest problem of nanocrystalline materials have been to move the technology out of the laboratory and put into commercial applications by developing means to produce quality materials in commercial volume at affordable cost. However, these difficulties have been overcome. Todays manufacturing methods have been very crude at the molecular level. Casting, grinding, milling and even lithography move atoms in great thundering statistical herds. 8.1. Carbon Nanotubes (CNT) Figure 8.1 gives a picture of a carbon nanotube (CNT), see ref. Aftenposten (graphics: J. P. MÆHLEN ). One gram of these tubes costs about 5000 NOK, and is produced by Carbon Nanotechnology Inc. (CNI) which founder is Richard Smalley who got the Nobelprize for the invention of the technology of the nanotubes in 1996. It’s worth pointing out that the word nanotechnology has become very popular and is used to describe many types of research where the characteristic dimensions are less than about 1,000 nanometers. For example, continued improvements in lithography have resulted in line widths that are less than one micron: this work is often called nanotechnology. Sub-micron lithography is clearly very valuable but it is equally clear that lithography will not let us build semiconductor devices in which individual dopant atoms are located at specific lattice sites. Many of the exponentially improving trends in computer hardware capability have remained steady for the last 50 years. There is fairly widespread confidence that these

107

trends are likely to continue for at least another ten years, but then lithography starts to reach its fundamental limits. Whatever we call it, nano-technology should let us: • — Get essentially every atom in the right place. — Make almost any structure consistent with the laws of physics and chemistry that we can specify in atomic detail. — Have low manufacturing costs (not greatly exceeding the cost of the required raw materials and energy). There are two more concepts commonly associated with nanotechnology: • — Positional assembly. — Self replication.

Clearly, we would be happy with any method that simultaneously achieved the first three objectives. However, this seems difficult without using some form of positional assembly (to get the right molecular parts in the right places) and some form of self replication (to keep the costs down). The need for positional assembly implies an interest in molecular robotics, e.g., robotic devices that are molecular both in their size and precision. These molecular scale positional devices are likely to resemble very small versions of their everyday macroscopic counterparts. Positional assembly is frequently used in normal macroscopic manufacturing today, and provides tremendous advantages. The requirement for low cost creates an interest in self replicating manufacturing systems. These systems are able both to make copies of themselves and to manufacture useful products. If we can design and build one such system the manufacturing costs for more such systems and the products they make (assuming they can make copies of themselves in some reasonably inexpensive environment) will be very low. 8.1.1. Strength Carbon nanotubes are one of the strongest and stiffest materials known, in terms of tensile strength and elastic modulus respectively. Multi-walled carbon nanotube was tested in 2000, and was found to have a tensile strength of 63 GPa. (highcarbon steel has a tensile strength ≈ 1.2 GPa). CNTs have very high elasticmoduli, on the order of 1 TPa. Since CNTs have a low density for a solid (1.3-1.4 108

Figure 8.2: Picture from http://www.forskning.no. g/cm3 ), its specific strength of up to 48462 kN·m/kg is the best of known materials, ( the specific strength of high-carbon steel is 154 kN·m/kg). The tubes will undergo plastic deformation under excessive tensile strain, which starts at strains of approximately 5%. CNTs are not so strong under compression. Due to their hollow structure and high aspect ratio, they tend to undergo buckling when placed under compressive, torsional or bending stress. 8.2. Nanocomposites Materials with features on the scale of nanometers often have properties dramatically different from their bulk-scale counterparts. For example, nanocrystalline copper is five times harder than ordinary copper with its micrometer-sized crystalline structure. The development of such materials is currently a research area of great interest. Nature makes fabulous nanocomposites, and scientists are trying to emulate such processes. The abalone shell, for example, has alternating layers of calcium carbonate and a rubbery biopolymer; it is twice as hard and a thousand times tougher than its components. The study of nanocomposite materials requires a multidisciplinary approach, involving novel chemical techniques and an understanding of physics, mathematics, material science and surface science. It is a field of broad scientific interest with impressive technological promise.

109

Figure 8.3: (Left) This transmission electron micrograph of the cubic structure of
the new hybrid material shows pores of about 10 nanometers across. (Right) This diagram shows molecular architecture of the flexible ceramic phase called a ”plumber’s nightmare.” Wiesner Research Group

8.3. Flexible ceramics Using nanoscale chemistry, researchers at Cornell developed in 2002 a new class of hybrid materials that they describe as flexible ceramics, , see Figure 8.3 . The new materials appear to have wide applications, from microelectronics to separating macromolecules, such as proteins. The Cornell researcher reasoned that the simplest way to mimic nature’s pathways was to use organic (or carbon-based) polymers — more particularly materials known as diblock copolymers — that have the ability to self-assemble chemically into nanostructures with different symmetries. If the polymer could somehow be melded with an inorganic material — a ceramic, specifically a silica-type material — the resulting hybrid would have a combination of properties: flexibility and structure control from the polymer and functionality from the ceramic. This, Wiesner’s group has now achieved. ”The resulting material has properties that are not just the simple sum of polymers plus ceramic, but maybe something quite new,” said Wiesner. Thus far the Cornell researchers have made only small pieces of the flexible ceramic, weighing a few grams, in petri dishes, but that is enough to test the material’s properties. It is transparent and bendable but with considerable strength, and

110

Figure 8.4: Flexible ceramics, from http://www.polytec.com/default.asp. unlike pure ceramic will not shatter. In one form the hybrid material is an ion conductor (an ion is an electrically charged atom), with great promise as highly efficient battery electrolytes. There also is the possibility that the new material could be used in fuel cells, he said. Published March 21, 2002, http://www.news.cornell.edu/Chronicle/02/3.21.02/ Wiesner-ceramics.html For example, Cotronics´ Flexible Ceramics, see Figure 8.4 are easy to use to 1650◦ C, highly efficient insulation products. They are available as: Fiber blankets, Ceramic Papers, Moldable Sheets, Ceramic Boards, Cloths and Sleevings, Tapes, Ropes and Fabrics. They have advantages as: high purity, outstanding thermal insulation, low heat storage, lightweigh, high resilienc, high mechanical and thermal shock resistance and are resistant to oxidizing. 8.4. New type of High-performance Ceramic When a racing driver brakes, the discs and linings become red-hot. These parts are commonly made of carbon-fiber-reinforced carbon and are black at moderate temperatures. Car manufacturers and their suppliers would dearly like to extend the use of these special brake pads and other hard-wearing parts developed for racing vehicles to perfectly normal family cars - if only the cost was not prohibitive. This may now be possible using a new fiber-composite material that could almost be referred to as a renewable ceramic. Its carbon matrix is made of carbonized flax, hemp or wood fibers, which are then permeated with liquid silicon to form a high-strength, wear- and temperature-resistant silicon carbide. 111

A great deal of know-how is needed even to produce the sheets of carbon fiber, reveals Dr. Stefan Siegel, team leader at the Fraunhofer Institute for Ceramic Technologies and Sintered Materials IKTS. Our starting material are boards of resin-coated plant fibers, which are produced for us by our colleagues at the Fraunhofer Institute for Wood Research WKI. These sheets then undergo a process called carbonization, in which the natural-fiber composite is heated in a nitrogen flooded furnace to temperatures of over 1000◦ C. This process has to be carefully controlled to ensure that the shrinkage of the material - i.e. its reduction in volume - proceeds homogeneously and without distortion. All that is left in the end is carbon; practically all other compounds present in the original material have decomposed and evaporated. The black sheets resulting from the carbonization of the raw natural fiber can be used, for example, as structural elements or as an insulating lining for furnaces. Alternatively, this intermediate product can be shaped into components using standard industrial machining techniques such as sawing, drilling or milling. But let us return to the ceramics. At temperatures above 1410◦ C, silicon liquefies, and is soaked up like a sponge by the sheets of carbon (at present up to one square meter in size) or the pre-shaped components. The silicon undergoes a fast-acting reaction with the carbon, forming a fiber-composite ceramic material. This stage of the process, unlike carbonization, does not alter the shape or size of the parts. The post-processing of hard ceramic materials like silicon carbide is relatively difficult. The new wood ceramic, by contrast, can be shaped before it is hardened, thus presenting manufacturers who use machine tools to produce parts subject to high mechanical and thermal stress with a simple-to-use, low-cost alternative. (published nov. 2002). 8.5. Back to square one? Published in : http://www.forskning.no/Artikler/2002/oktober/1034170456.0 10. October 2002 An up-and-coming young physicist at Bell Labs in Murray Hill, New Jersey, has been dismissed after being found guilty of 16 counts of scientific misconduct by a review panel charged with investigating his research. Formerly a rising star in the field of nanotechnology, Schön was renowned for creating field-effect transistors, the backbone of modern electronics, out of tiny molecules. His work won him numerous awards from magazines and scientific organizations, and colleagues were beginning to tip him for a Nobel Prize. 112

But not everything was as it seemed. Many scientists were unable to reproduce Schön’s results. In April, a small group of physicists noticed that graphs in three unrelated papers appeared identical down to what should have been random noise. Bell Labs rapidly launched an independent investigation, which soon expanded to include two dozen papers. What they found, according to Malcolm Beasley, a professor of electrical engineering at Stanford University, who chaired the panel, was that Schön substituted whole figures from other papers, removed data points that disagreed with predictions, and even used mathematical functions in place of real data points. References: Nano SMM: http://mrsec.wisc.edu/Seed_shape_memory/seed_shape_memory_alloys.htm http://en.wikipedia.org/wiki/Carbon_nanotube Aerogel: http://eande.lbl.gov/ECS/aerogels/aerogels.htm http://www.ntnu.no/gemini/2002-05/16-19.htm FGM: http://kenwww.pi.titech.ac.jp/Current_Subjects#Topic-3 http://www.grc.nasa.gov/ http://WWW/RT2000/5000/5920arnold3.html http://www.lucifer.com/~sean/Nano.html http://www.zyvex.com/nano/ http://web.mit.edu/tdp/www/composite.html CVD: http://chiuserv.ac.nctu.edu.tw/~htchiu/cvd/home.html http://www.ultramet.com/4.htm nano: http://www.aftenposten.no/nyheter/iriks/article.jhtml?articleID=199118 http://www.aftenposten.no/nyheter/iriks/article.jhtml?articleID=198172 http://www.aftenposten.no/nyheter/iriks/article.jhtml?articleID=198173 http://www.dr.dk/videnom/12nano/nano2.htm http://www.dr.dk/orbitalen/artikler/aktnat/nanoroer.shtm http://www.tekblad.no/show_article.asp?id=4112 http://www.pa.msu.edu/cmp/csc/nanotube.html 113

http://www.sciencesite.dtu.dk/nano/ http://www.sciam.com/nanotech/ http://www.forskning.no/Artikler/2003/juni/1055493430.67 http://www.forskning.no/Artikler/2003/september/1063028534.1 Nanocomposites: http://www.mse.cornell.edu/materials_science_discovering/nanocomposites.html http://www.nanocor.com/nclays/nanocomposites.htm http://www.pnl.gov/nano/conferences/smart.html http://www.ntnu.no/gemini/2002-05/16-19.htm Flexible cramics: http://www.news.cornell.edu/Chronicle/02/3.21.02/ Wiesner-ceramics.html Solar Cell materials: http://en.wikipedia.org/wiki/Solar_cell#Light-absorbing_materials Misconduct in nanotechnology: http://www.smalltimes.com/document_display.cfm?document_id=4079 http://www.nature.com/nsu/020923/020923-9.html http://www.nanoelectronicsplanet.com/briefs/ http://nanotechweb.org/articles/news/1/9 Questions • What is the difference between a material and a structure? • What is a smart material? • What kind of smart materials are there, and how do they act? • What is a FGM? • What is the advantage of a functional gradient material compared with traditional ”solid” materials? • What kind of products do you think could be made from a functional gradient material? • What kind of products is FGM used in today? Who make them? What kind of materials are they made of? •What kind of Solar cell materials are there? • What is nano-technology? • What future is there in nano-technology? • What is a nanotube? What is the principle of fabrication of the nanotubes? • What kind of commercial nano-tube-based products are available in the market, and what can they be used as? 114

• What is a flexible ceramic?

115

Figure 9.1: Cellular structure.

9. Cellular Solids, Structures & Foams
When modern man builds large load-bearing structures, he uses dense solids; steel, concrete, glass. When nature does the same, she generally uses cellular materials; wood, bone, coral. There must be good reasons for it ref: (Prof. M. F. Ashby, University of Cambridge) Cellular solids are defined as ”...an assembly of cells with solid edges of faces, packed together so that they fill space...”, see [5], p. 1, and see Figure 9.1. Such materials can be found in nature, for instance cork and wood. Man-made cellular structures will in the future replace conventional materials because of the possibility to construct structures with tailored properties. Cellular structures can either consist of two-dimensional structures, like honeycombs, or three-dimensional structures, like foam-structures. Honeycombs are usually thought of as cells in a hexagonal form, but they can also be in a triangular, square or rhombic form. We can find honeycombs in the nature, like the bee-honeycomb and as the cross-section of the bambootree. Honeycombs are often used as a core material in sandwich-constructions. The very good stiffness-to-weight ratio and strength-to-weight ratio and the good shock absorption ability in addition to the possibility for man-made tailored properties of the structures are some of the answers to why the honeycomb-structures have become so interesting as material structures. Foams can now also be made of almost any material, like polymers, metals, ceramics, glasses, and composites. The properties of a foam are related to 116

its structure and the material of which the cell walls are made. Cellular solids are often used for thermal insulation, packaging, filtering, structural applications or for their buoyancy property among many other applications. Recently, there has been an increased interest in the use of cellular solids that perform more than just one function. These multi-functional materials would possess unique combinations of thermophysical and mechanical properties. For example, a load bearing cellular solid could also provide for additional things such as impact/blast absorption, thermal management, conductance of electricity and/or shielding of electromagnetic waves, electrical power storage, filtering or impeding of fluid flow, retardation of chemical reactions and fire or in-growth of biological tissue. The largest obstacle in creating these materials thus far has been the inability for many manufacturers (using foaming or other methods) to gain control over the distribution of material/pores at the cell level. In addition, the limited choice of base material types has slowed the introduction of cellular solids as materials of choice for multifunctional applications. The foam industry grows because cellular materials offer unique advantages over traditional materials and non-cellular polymers. 9.1. Metal Foams Metal foams are a new type of materials, that is unknown to most engineers. They are not perfectly characterized, but generally we say that they have low densities and new type of physical, mechanical, thermal, electrical and energy absorption. In recent years there has been an increased interest in metal foams in the field of material science. The stress absorbing potential is one of the most interesting properties for the application of aluminium foam (e.g. car manufacturing). Material scientists need to investigate the structure of metal foams in order to optimize their deformation behavior. Most available metal foams are based on aluminium or nickel, but there also exist methods for foaming magnesium, lead, zinc, copper, bronze, titanium, steel and even gold. The methods are still imperfectly controlled. Metallic foams (metfoams) offer significant performance gains in light, stiff structures since they have an excellent stiffness-to-weight ratio. They can also be used as core materials in sandwich constructions since they have low density with good shear and fracture strength. The damping capacity of metal foams is larger than that of solid metals by up to a factor of 10. The most promising applications for metal foams appear to be as cores for

117

Figure 9.2: Example of aluminium foam. light-stiff sandwich panels; as stiffeners to inhibit buckling in light shell structures; as energy absorbing units, both inside and outside of motor vehicles and trains; as efficient heat exchanges to cool high powered electronics (by blowing air through the open cells of the aluminium foam, , attached to the heat source) and as light cores for shell casting. Several industrial designers have seen potential in exploiting the reflectivity and light-filtering of open cell foams, and the interesting textures of those with closed cells. 9.1.1. Aluminium foam: Also aluminium foam, see Figure 9.2, is beginning to be a large group of foam cores. It can be difficult to distinguish between aluminium foam as core material or as a functional gradient material, which is used in for instance car production. The properties (mechanical, thermal et.) of foam materials is studied in the field of cellular solids. Blocks of foam can be used as energy absorbers in various transportationrelated applications, such as automobiles, trucks and trains and highway crash barriers. Cymat is capable of producing aluminum foam panels up to four feet wide and 50 feet long with thickness ranging from 1 inch to 4 inches. The densities available are from 2.5% dense aluminum (0.0675 g/cc) to 20% dense aluminum (0.54 g/cc).

118

9.2. Polymeric foam Polymeric foams have important economic impact on nearly every aspect of life today. High-density cellular plastics are used in furniture, transportation, and building products. Low-density foams are used as shock mitigation, insulation, and rigid packaging. Foams can be manufactured from a variety of synthetic polymers including polyvinyl chloride (PVC), polystyrene (PS), polyurethane (PU), polymethyl methacrylamide (acrylic), polyetherimide (PEI) and styreneacrylonitrile (SAN). Polyvinyl chloride PVC - Often used in the manufacture of racing boats, as the linear construction foams are flexible, and can be heat moulded around curves. Closed-cell polyvinyl chloride (PVC) foams are one of the most commonly used core materials for the construction of high performance sandwich structures. Although strictly they are a chemical hybrid of PVC and polyurethane, they tend to be referred to simply as ’PVC foams’. PVC foams offer a balanced combination of static and dynamic properties and good resistance to water absorption. They also have a large operating temperature range of typically -240◦ C to +80◦ C , and are resistant to many chemicals. Although PVC foams are generally flammable, there are fire-retardant grades that can be used in many fire-critical applications, such as train components. When used as a core for sandwich construction with fiber reinforced polymer (FRP) skins, its reasonable resistance to styrene means that it can be used safely with polyester resins and it is therefore popular in many industries. It is normally supplied in sheet form, either plain, or grid-scored to allow easy forming to shape. There are two main types of PVC foam: crosslinked and uncrosslinked with the uncrosslinked foams sometimes being referred to as ’linear’. The uncrosslinked foams are tougher and more flexible, and are easier to heat-form around curves. However, they have some lower mechanical properties than an equivalent density of cross-linked PVC, and a lower resistance to elevated temperatures and styrene. Their cross-linked counterparts are harder but more brittle and will produce a stiffer panel, less susceptible to softening or creeping in hot climates. Typical cross-linked PVC products include the Herex C-series of foams, Divinycell H and HT grades and Polimex Klegecell and Termanto products. A new generation of toughened PVC foams is now also becoming available which trade some of the basic mechanical properties of the cross-linked PVC foams for some of the improved toughness of the linear foams. Typical products 119

include Divincell HD grade. Owing to the nature of the PVC/polyurethane chemistry in cross-linked PVC foams, these materials need to be thoroughly sealed with a resin coating before they can be safely used with low-temperature curing prepregs. Although special heat stabilisation treatments are available for these foams, these treatments are primarily designed to improve the dimensional stability of the foam, and reduce the amount of gassing that is given off during elevated temperature processing. Applications of PVC foam are in maringe, aerospace, transportation, military and defence, and industry. Polystyrene (PS)- Very light - around 40kg/m3 , inexpensive and easily shaped. Although polystyrene foams are used extensively in sail and surf board manufacture, where their light weight (40kg/m3), low cost and easy to sand characteristics are of prime importance, they are rarely employed in high performance component construction because of their low mechanical properties. They cannot be used in conjunction with polyester resin systems because they will be dissolved by the styrene present in the resin (ester-based matrices cannot be used as adhesives). PS or EPS (extruded PS) is primary used as thermal insulation materials but also in some load carrying structures. Extruded polystyrene insulation offers a service temperature range of (-183◦ C to +74◦ C). Polyurethane (PU) (PUR earlier)- Is very rigid and has and good mechanical properties, but tends to deteriorate with age and become delaminated. Polyurethane foams exhibit only moderate mechanical properties and have a tendency for the foam surface at the resin/core interface to deteriorate with age, leading to skin delamination. Their structural applications are therefore normally limited to the production of formers to create frames or stringers for stiffening components. However, polyurethane foams can be used in lightly loaded sandwich panels, with these panels being widely used for thermal insulation. The foam also has reasonable elevated service temperature properties (150◦ C), and good acoustic absorption. The foam can readily be cut and machined to required shapes or profiles. Polymethyl methacrylamide (PMI) For a given density, polymethyl methacrylamide (acrylic) foams such as Rohacell offer some of the highest overall strengths and stiffnesses of foam cores. Their high dimensional stability also makes them unique in that they can readily be used with conventional elevated temperature curing prepregs. However, they are expensive, which means that their use tends to be limited to aerospace composite 120

parts such as helicopter rotor blades, and aircraft flaps. Acrylics has the highest specific strength and stiffness for a given density. High stability makes them ideal for use with prepregs, but they do not fit curves well. Maximum service temperature of PMI is 180◦ C. Styrene acrylonitrile (SAN) co-polymer Foams SAN foams behave in a similar way to toughened cross-linked PVC foams. They have most of the static properties of cross-linked PVC cores, yet have much higher elongations and toughness. They are therefore able to absorb impact levels that would fracture both conventional and even the toughened PVC foams. However, unlike the toughened PVC’s, which use plasticisers to toughen the polymer, the toughness properties of SAN are inherent in the polymer itself, and so do not change appreciably with age. SAN foams are replacing linear PVC foams in many applications since they have much of the linear PVC’s toughness and elongation, yet have a higher temperature performance and better static properties. However, they are still thermoformable, which helps in the manufacture of curved parts. Heat-stabilised grades of SAN foams can also be more simply used with low-temperature curing prepregs, since they do not have the interfering chemistry inherent in the PVC’s. Maximum service temperature of PMI is 125◦ C. Polyethylene (PET)- A crystalline polyethylene terephthalate (PET) foam by applying high-expansion foam extrusion and thermoforming to PET resin. The PET foam combines light weight and outstanding shock resistance with good thermal insulation. Because it withstands temperatures up to 220◦ C, PET foam is an excellent material for oven-proof food containers. And because of its superior shock absorption and moldability, it makes an ideal packing material for multiple products. Other thermoplastics As new techniques develop for the blowing of foams from thermoplastics, the range of expanded materials of this type continues to increase. Typical is PEI foam, an expanded polyetherimide/polyether sulphone, which combines outstanding fire performance with high service temperature. PEI is expensive, but can be used in temperatures from -194◦ C - +180◦ C, and can be used in structural, thermal and fire protection applications, for instance in aircrafts and train interiors, as it can meet some of the most stringent fire resistant specifications.

121

9.3. Refractory foams / Ceramic foam Refractory materials are ceramics that have been designed to provide acceptable mechanical or chemical properties while at high temperatures. Refractory foams are a new class of open cell, low density materials which Ultramet has developed to produce lightweight refractory structures for a variety of aerospace and industrial applications including thermal insulation, lightweight, precision mirrors, impact absorption, catalyst support, and metal and gas filtration. By pyrolyzing a polymer foam, a reticulated vitreous carbon (RVC) foam is created which has substantial mechanical and thermal properties. By further CVI (chemical vapor infiltration) processing, ceramic (e.g. silicon carbide [SiC]) and/or metal or mixed material foams can be fabricated. These cellular materials can be simultaneously optimized for stiffness, strength, thermal conductivity, active surface area, and gas permeability. They are thermally stable, low in weight and density, chemically pure, resistant to thermal stress and shock, and are relatively inexpensive. June 2001: A team of scientists from Technion, Israel, has succeeded in manufacturing the worlds lightest ceramic foam material, implementing a unique mechanism its members have developed. The new material is a ceramic foam that contains 94% to 96% air by volume, but can resist temperatures above 1700◦ C. The material is made of aluminum oxide, a common high-temperature ceramic, but gets its extraordinary insulating powers from the many tiny air bubbles within the material. The foam is generated from special crystals that contain the metal components and all the foaming ingredients. Upon heating, the crystals form a solution. Within this solution a reaction takes place, forming polymer chains. After the chains grow sufficiently, the solution suddenly separates into a pure solvent and the polymer. At this point, the solvent begins to boil, forming trillions of tiny bubbles that blow the polymer into a foam, stabilized by the polymer chains. Subsequent heating to high temperatures leaves behind the ceramic, metal oxide foam. The material will be used for a wide variety of advanced applications such as acoustic insulation, thermal insulation, adsorption of environmental pollutants or as a platform for bio-technology applications. The estimated market for this product is worth billions of dollars.

122

Figure 9.3: Human bone is a hierarchical structure. 9.3.1. Carbon foam Touchstone makes thee carbon foam product, CFoam by transforming high-sulfur bituminous coal into a strong but lightweight, fire-resistant, and thermally insulating material. A slice of Carbon foam that is exposed to a 3000◦ flame, can be held by a hand in the other end due to its conductivity which makes that the end remains cool enough to touch. The carbon foam material can be used as for instance lightweight thermal protection in aircraft and spacecraft, as a fire blocking material in military vehicles, as a porous electrode for lightweight energy storage, and to provide insulation and fire protection in home construction. 9.4. Hierarchical structures (multiscale structures) Some cellular structures are made up in a different matter than the previous ones. The hierarchical structures (also called multiscaled structures) are structures that consist of structures in many size scales or levels. They are also called multiscaled structures. Many such structures can be found in nature, and humans have begun to imitate the nature and build man-made hierarchical structures. Weight-savings and tailored properties are some of the benefit of such structures. Human bone (bones in general) is for instance a natural hierarchical structure, see Figure 9.3. 123

Figure 9.4: The Eiffel tower is also a hierarchical structure. Eiffel-tower, on the other hand, is an example of an artifical/man-made hierarchical structure, see Figure 9.4, is a hierarchical structure. Most common materials or structures have a Poissons ratio 0.5 > ν > 0 (approximately 0.5 for rubbers and for soft biological tissues, 0.45 for lead, 0.33 for aluminum, 0.27 for common steels, 0.1 to 0.4 for cellular solids such as typical polymer foams, and nearly zero for cork). In an isotropic material (a material which does not have a preferred orientation) the allowable range of Poisson’s ratio is from -1.0 to +0.5. Hierarchical structures and foams have also been made with negative Poissons ratio (ν < 0), and Poisson’s ratio > 1, which give exciting respond to loads. The applications for such structures/materials are not widely known, but will certainly increase in future when the fabrication of such structures will be easier. Rod Lakes (at: http://silver.neep.wisc.edu/~lakes/sci87.html) is maybe the person who has done most in this field. 9.5. Biomaterials A biomaterial is any material, natural or man-made, that comprises whole or part of a living structure or biomedical device which performs, augments, or replaces a natural function. References: 124

Cellular structures: http://ansatte.hin.no/dl//homo.html http://web.mit.edu/dmse/csg/Research.htm http://silver.neep.wisc.edu/~lakes/ Metal foam: http://www.metalfoam.net/ http://www.porvair.com/fuelcell/metalfoam.htm http://www.porvair.com/fuelcell/ http://www.ultramet.com/foamtech.htm http://www.cymat.com/ http://www.npl.co.uk/npl/cmmt/metal_foams/index.html http://www.grantadesign.com/solutions/metalfoams.htm Polymer foam: http://www.vitec.org.uk/ http://www.foamandform.com/seminars/foam/ Ceramic foams: http://www.emgroup.nl http://www.solgel.com/articles/june01/news06_101.htm Refractory foams: http://www.ultramet.com/ http://voyager.cet.edu/iss/techcheck/techcheck3/wvproduct.html General: http://www.npl.co.uk/npl/cmmt/metal_foams/applications.html Hierarchical structures http://silver.neep.wisc.edu/~lakes/Hierarch.html Negative Poissons ratio materials http://silver.neep.wisc.edu/~lakes/sci87.html Biomaterials: http://www.engr.sjsu.edu/WofMatE/Biomaterials.htm Questions • What is the definition of ”cellular solids”? • What types of foams are there, and what products are they used in? 125

• What is the advantages of foam materials compared to conventional solid materials? • What are the applications of foam materials? • What is a refractory material/structure? • What is hierarchical structures? • Find two examples of man-made hierarchical structures and two examples of natural hierarchical structures. • Does foam with negative Poissons ratio exist? How does such a material act? • Does foam with Poissons ratio >1 exist?

126

Part II

Sandwich Constructions
Composite materials used today are often in the form of a sandwich construction, see Figure 9.5.A sandwich panel is built up by two thin skins, also called the
Face sheet

Honeycomb core (metal, composite or paper)

Adhesive

Face sheet

Figure 9.5: A sandwich construction. facings, separated by a lightweight core. The core helps to increase the moment of inertia such that the structure becomes efficient for resisting bending and buckling loads. This is why sandwich panels are being used in applications where weightsaving is critical, for instance in aircraft and in portable structures. Sandwich designs are also used by nature itself for instance in a human skull and in plants. While nature often uses the same material in the facings as in the core and only vary the density, man-made sandwich panels usually consist of different materials, or even structures, in the facings and in the core.A sandwich construction is built up by different face- and core materials and forms, see Figure 9.6 and [36, p.18].

127

Figure 9.6: Sandwich materials and forms.

10. Why use sandwich constructions?
The mechanical behavior of a sandwich panel depends on the properties of the face and the core materials and on its geometry. The Figure 10.1 shows how the sandwich design works, the so-called sandwicheffect. In Figure 10.2 we see the sandwich-effect in and aluminium-sandwich compared to solid aluminium plates of different thickness.

128

Figure 10.1: The sandwich effect.

Figure 10.2: Aluminium foam used as core material compared with aluminium plate.

129

10.1. Face materials The face material in a sandwich panel can be made of almost any material that can be formed into thin sheets. The properties we seek for in a face material are: • high stiffness, which gives high flexural rigidity • high tensile and compressive strength • impact resistance • surface finish • environmental resistance (chemical, UV, heat etc.) • wear resistance The most usual type of material used as facings are listed in the Table with a summary of face materials. Material Metals: Mild steel Stainless steel Aluminium Alloy Titanium Alloy Wood: Pine Plywood Unidirectional fibre composites Carbon/Epoxy , (vf = 0.6 − 0.7) Glass/Epoxy Kevlar/Epoxy Bi-directional fibre composites Kevlar/Polyester (vf = 0.3 − 0.4) Glass weave/Polyester Glass WR /Polyester Random fibres Glass CSM (vf = 0.15 − 0.25) SMC

(10.1)

where WR=(woven roving), CSM= chopped strand mat, SMC = sheet moulding compound and vf is the volume fraction of fibers. The most used group of face-materials is the fibre composites since they have a similar or even higher strength properties than metals, and are much easier to fabricate. Also, the possibility to tailor the face materials because the anisotropic behavior of the fibres offer a very interesting addition. In this way fibres can be placed in the direction where the loadcarrying is most important.

130

Figure 10.3: Core exposed to shear. 10.2. Core materials and structures The essential property of any core material is that it increases the thickness of the laminate, without causing a great weight increase (engineering theory shows that the flexural stiffness of any panel is proportional to the cube of its thickness). The purpose of a core in a composite laminate is therefore to increase the laminate’s stiffness by effectively ’thickening’ it with a low-density core material. This can provide a dramatic increase in stiffness for very little additional weight. Figure 10.3 shows a cored laminate under a bending load. Here, the sandwich laminate can be likened to an I-beam, in which the laminate skins act as the I-beam flange, and the core materials act as the beam’s shear web. In this mode of loading it can be seen that the upper skin is put into compression, the lower skin into tension and the core into shear. It therefore follows that one of the most important properties of a core is its shear strength and stiffness. In addition, particularly when using lightweight, thin laminate skins, the core must be capable of taking a compressive loading without premature failure. This helps to prevent the thin skins from wrinkling, and failing in a buckling mode. The properties of primary interest for the core: • Low density (add little weight to the total weight of the sandwich) • Shear modulus (prevents wrinkling) • Shear strength (prevents wrinkling) • Stiffness perpendicular to the faces (prevents decrease in core thickness and therefore a rapid decrease in the flexural rigidity) • Thermal insulation • Acoustic insulation There are four main groups of core material used, 131

Figure 10.4: Honeycomb core. • • • • Foams Honeycombs Corrugated Wood

10.2.1. Foam Cores Foams are one of the most common forms of core material. They can be manufactured from a variety of synthetic polymers including polyvinyl chloride (PVC), polystyrene (PS), polyurethane (PU), polymethyl methacrylamide (acrylic), polyetherimide (PEI) and styreneacrylonitrile (SAN). They can be supplied in densities ranging from less than 30kg/m3 to more than 300kg/m3 , although the most used densities for composite structures range from 40 to 200 kg/m3 . They are also available in a variety of thicknesses, typically from 5mm to 50mm. 10.2.2. Honeycomb Cores Honeycomb cores are available in a variety of materials for sandwich structures, which ranges from paper and card for low strength and stiffness, low load applications (such as domestic internal doors) to high strength and stiffness, extremely lightweight components for aircraft structures. Honeycombs can be processed into both flat and curved composite structures, and can be made to conform to curves without excessive mechanical force or heating. Figure 10.4 shows the usual honeycomb shape. The cells can be triangular, square or hexagonal cells which also can be filled with a rigid foam in order to 132

provide a greater bond area for the skins, increases the mechanical properties of the core by stabilizing the cell walls and increases thermal and acoustic insulation properties. The following materials are commonly used in honeycomb structures. • Aluminium - Has been used since 1950, several alloys can be used, but in comparison it is old and heavy. • Glass fibre reinforced plastic - Has a high temperature resistance and good insulating properties, but is denser than other materials. • Kraftpaper honeycombs - impregnated paper with resin to make it water resistant. Good strength at low cost. • Nomex honeycomb which is made from Nomex paper - a form of paper based on KevlarTM (Aramid fibre), rather than cellulose fibres. High strength and toughness with a low density makes it the most widely used honeycomb core. The initial paper honeycomb is usually dipped in a phenolic resin to produce a honeycomb core with high strength and very good fire resistance. It is widely used for lightweight interior panels for aircraft in conjunction with phenolic resins in the skins. Nomex honeycomb is becoming increasingly used in high-performance non aerospace components due to its high mechanical properties, low density and good long-term stability. Figure 10.5 shows the shear strength and compressive strength of some of the core materials described, plotted against their densities. Figure 10.6 shows the prices of some core materials. Honeycombs can be made with several different cell shapes: Hexagonal The most common shape is the one shown at Figure 10.4, but this can only be used in flat components. Overexpanded The honeycomb in Figure 10.7 is over expanded, so that the cells are rectangular. This gives better properties in the web direction, but worse in the other, it can therefore be curved in the ribbon direction only. This shape is used for single curvature components. 133

Figure 10.5: Compressive strength and shear strength of some of the core materials plotted against their densities.

Figure 10.6: Comparative prices of some core materials.

134

Figure 10.7: Overexpanded honeycomb structure. Negative Poisson’s Ratio Honeycombs can be made with negative Poissons Ratio, when the cell walls are inverted as in Figure 10.8.

Figure 10.8: Honeycombs with negativ Poisson’s ratio.

10.2.3. Corrugated Cores A corrugated core is shown in Figure 10.9.

135

Figure 10.9: Corrugated core. 10.2.4. Wood Cores Wood can be described as ’nature’s honeycomb’ because on a microscopic scale you find that it consists of closed-cell structure. It has a similar structure to that of a hexagonal honeycomb, and consequently good mechanical properties. When used in a sandwich structure with the grain running perpendicular to the plane of the skins, the resulting component shows properties similar to those made with man-made honeycombs. However, despite various chemical treatments being available, all wood cores are susceptible to moisture attack and will rot if not well surrounded by laminate or resin. Wood is only used in large projects, as it has a relatively high density, of at least 100kg/m3 . Balsa The most commonly used wood core is end-grain balsa. Balsa wood cores first appeared in the 1940’s in flying boat hulls, which were aluminium skinned and balsa-cored to withstand the repeated impact of landing on water. This performance led the marine industry to begin using end-grain balsa as a core material in FRP construction. Apart from its high compressive properties, its advantages include being a good thermal insulator offering good acoustic absorption. The material will not deform when heated and acts as an insulating and ablative layer in a fire, with the core charring slowly, allowing the non-exposed skin to remain structurally sound. It also offers positive flotation and is easily worked with simple tools and equipment. Balsa core is available as contoured end-grain sheets 3 to 50mm thick on a backing fabric, and rigid end-grain sheets up to 100mm thick. These sheets can be provided ready resin-coated for vacuum-bagging, prepreg or pressure-based manufacturing processes such as RTM. One of the disadvantages of balsa is its 136

high minimum density, with 100kg/m3 being a typical minimum. This problem is exacerbated by the fact that balsa can absorb large quantities of resin during lamination, although pre-sealing the foam can reduce this. Its use is therefore normally restricted to projects where optimum weight saving is not required or in locally highly stressed areas. Balsa was the first material used as cores in load bearing sandwich structures and is still often used as a core material. Cedar Another wood that is used sometimes as a core material is cedar. In marine construction it is often the material used as the ’core’ in strip-plank construction, with a composite skin on each side and the grain of the cedar running parallel to the laminate faces. The cedar fibres run along the length of the boat giving fore and aft stiffness while the fibres in the FRP skins are laid at ±45◦ giving torsional rigidity, and protecting the wood. 10.3. Adhesives Bonding of sandwich construction involve bonding of two very dissimilar constituents, one solid and one softer cellular component, and the requirements concerning bonding are therefore somewhat different than normal use. The adhesive must be stronger than the tensile strength of the core. Some of the requirements of the adhesives are: Surface preparation The core and the face material have to be prepared before bonding, which involves mechanically or chemically cleaning and sometimes priming. Solvents Core materials are often very sensitive to certain solvents. For instance: Polystyrene foams are sensitive to styrene (polyester and vinylester contains styrene), while epoxies and polyurethanes may be used. Similar combinations needs to be investigated before bonding components. Curing vapors When curing, some adhesives (as phenolics) give off vapor when curing, which can give rise to several bonding problems. Bonding pressure

137

When pressure is needed to prevent pores to appear, be careful so that the core will not fail due to the compression. Adhesive viscosity The adhesive must have exactly the right combination of surface wetting and flow. In the case of foam or balsa core, the viscosity should be low enough to enable the adhesive to fill the surface cells properly and leave as little as possible trapped air. But the viscosity must not be too low,the adhesive could be squeezed out leaving too thin bonding line. Bond thickness If the bond is too thick, it adds extra unnecessary weight to the part. If it is too thin, bonding will not be one properly. Strength The bond must be able to transfer the design loads, which means it must have the desired tensile and shear strength, at the temperatures that might occur. Thermal stresses A frequent cause of debonding failures are thermal stresses. If for instance one side is heated from sunlight it will deform due to thermal expansion. Most core materials are very good insulators, and therefor it will be a very high thermal gradient over the bond line. This lead to very high shear stresses in the bond which may lead to debonding. In such environment, very ductile adhesives should be chosen (high strain to failure). Toughness Toughened adhesives which resist cracks better (improved impact resistance) are on the market. They are ordinary resins which have elastomer particles added. Viscoelastic properties Highly viscoelastic adhesives may be advantageous for example where there are high thermal gradients. Curing shrinkage As much as 7% decrease in volume can an adhesive (as polyesters) shrink when its curing. This leads to high interface (bond) shear stresses and may decrease the strength of adhesive joints. Curing exotherm Most adhesives exhibit an exotherm (curing process gives off heat) curing. This is seldom a problem in thin bondings spread over a large area. 138

Different types of adhesives are for instance: • Epoxy resins • Modified epoxies • Phenolics • Polyurethanes Urethane acrylates • Polyester and vinylester resins References: Alulight products:
http://www.alulight.com/en/products/products.html

Composites:
http://www.users.globalnet.co.uk/~weeks/ Composite%20Materials.htm http://www.netcomposites.com/education.asp http://www.baltek.com/

Fibres
http:// www.netcomposites.com/education.asp?sequence=45

Foam cores:
http://www.netcomposites.com/education.asp http://www.polymer-age.co.uk/techlink.htm http://www.hexcelcomposites.com

Adhesives:
http://www.hexcelcomposites.com/products/honeycomb/ sand_design_tech/hsdt_p04.html http://www.hexcelcomposites.com/products/

Questions •Why are sandwich constructions used? •What kind of face and core materials are used in sandwich constructions? •What is the essential property of any core material •Is End Grain Balsa used as core material in sandwich construction? If yes, what kind of products, and what are the advantages of this product? (http://www.baltek.com/) •What requirements must be taken into consideration when it comes to bonding sandwich-constructions with adhesives?

139

11. Design of sandwich constructions
When we use sandwich panels in different applications we have to know the mechanical properties of the face and core materials and the geometry of the panel. Often we formulate the design of a sandwich panel as an optimization problem where the goal is to minimize the weight of the panel that meet the constraints on stiffness and strength desired. With respect to the core and skin thickness, or the materials, or the density of the core, the optimization can be carried out. 11.1. Design of sandwich beams Design of sandwich beams are the basis for understanding more complicated panels and constructions. Beams are defines as a long, slender, one dimensional structural element that carries load primarily in bending (flexure). In classical engineering beam theory where the cross-section of the beam is a homogenous material the transverse shear deformations are neglected. In sandwich beam theory we cannot neglect the transverse shear deformations. An example of a sandwich beam can be seen in Figure 11.1. Here, the beam has a given point load P at the middle of the length.l We use the subscripts ”f”,

Figure 11.1: A sandwich beam. and ”c” which refer to the facings, and core, respectively.

140

Figure 11.2: A curved beam. 11.2. Preliminaries Let us start with recalling the problem of a straight beam subjected to a constant bending moment giving the beam a curvature 1/Rx . The length of the curve, lc at the neutral axis (N.A.), that has radius Rx and angle α, see Figure 11.2, is found by the formula lc = Rx α. The strain εx in a new curveline at a distance z from the N.A. (where εx = 0) can be found as follows: εx = (new curve length)-(old curve length) (Rx + z) α − Rx α = (old curve length) Rx α z Rx α + zα − Rx α = . = Rx α Rx

The stress σ x in the beam is then given by σ x = Eεx = E z . Rx

The applied bending moment dMx , with respect to the x-axis, caused by the force dF acting on a small element, see Figure 11.3, of area dA = dydz at a point x is dMx = zdF = zσ x dA = zσ x dydz . | {z } | {z }
dF dA

141

Figure 11.3: A small element dA. The total moment at the point x of the beam with height h and depth b is Mx = X Z dMx = Z
b/2

¶ µ Z z z2 = dydz = z E E dydz Rx Rx −h/2 −b/2 −h/2 −b/2 Z h/2 Z b/2 Z h/2 Z b/2 1 1 = Ez 2 dydz = Ez 2 dydz Rx −h/2 −b/2 Rx −h/2 −b/2 Z h/2 1 1 1 = bEz 2 dz = (EI)eq = D, Rx −h/2 Rx Rx
h/2

Z

h/2

−h/2

Z

b/2

dMx =

−b/2

Z

h/2

−h/2 −b/2 h/2 Z b/2

Z

b/2

zσ x dydz

where (EI)eq = b

Z

h/2

Ez 2 dz

(11.1)

−h/2

(often also denoted D) is called the equivalent flexural rigidity, also called the bending stiffness. The general expression for the strain will then be ! Ã ¶ µ z 1 Mx Mx z. (11.2) z= = z= εx = Rx Rx D (EI)eq The strain will vary linearly with z over the cross-section. The basic equations for the sandwich beam are now established, and this makes it possible to find the cross-sectional properties and stresses in such a beam.

142

11.3. The Flexural Rigidity and Shear Rigidity The theory for engineering stresses in beams is easily adapted to sandwich beams if we modify it slightly. Flexural rigidity In an ordinary beam the flexural rigidity, denoted EI, where E is the modulus of elasticity (Young’s modulus) and I is the second moment of area. The equivalent flexural rigidity of a cross-section of a sandwich (see Allan 1969) is the sum of flexural rigidities of the different parts in the sandwich and can be found from (11.1) and is (EI)eq = Ef bt3 btf d2 bt3 f + Ef + Ec c = 2 (EI)f + (EI)o + (EI)c , 6 2 12 (11.3)

where d (= tf + tc ) (see Figure 11.1) is the distance between the centroids of the faces. The first term, 2 (EI)f , represents the flexural rigidity of the faces alone when they are bending about their own neutral axes, and the third term, (EI)c , represents the flexural rigidity of the core. The first and the third term are small compared to the second term, (EI)o , which corresponds to the stiffness of the faces associated with bending about the centroid axis of the whole sandwich. The faces in a sandwich are thin compared to the core (tf << tc ), hence the first term in (11.3) is less than 1% of the second term if µ ¶2 d d 3 > 100 or > 5.77 (11.4) tf tf because ⎛
bt3 Ef 6f ⎝ bt d2 Ef f 2

The first term can therefor be neglected and (11.3) is the reduced to btf d2 bt3 + Ec c = (EI)o + (EI)c . (EI)eq = Ef 2 12 If the core is weak, then Ec << Ef , the third term of (11.3) is less than 1% of the second term if 6Ef tf d2 > 100, (11.5) Ec t3 c 143

⎠ 100 < 1.

because

Ã

Ec btc 12 Ef

3

btf d2 2

!

100 < 1.

The third term and can therefore be neglected, and (11.3) is reduced to the approximated simple formula (EI)eq = Ef btf d2 = (EI)o . 2 (11.6)

Shear rigidity The shear rigidity AG (shear stiffness) for a beam with a homogeneous crosssection is given by bhG AG = , k where h is the height, G is the shear modulus, and k is a shear factor, which for rectangular homogenous cross-sections equals 1.2. The equivalent shear rigidity (shear stiffness) for a sandwich beam when Ec << Ef and tf << tc is given as bd2 Gc (AG)eq = , tc where Gc is the shear modulus of the core. We will come back to this later. 11.4. Tensile and Compressive Stresses In a sandwich the faces carry bending moments as tensile and compressive stresses, while the core carries the transverse forces as shear stresses as illustrated in Figure 11.4. The distribution of stresses and shear stresses in a sandwich is shown in Figure 11.4. 11.4.1. Due to bending (transversal loading) From (11.2) the tensile and compressive stresses (also called direct stresses) in the sandwich due to bending shown in Figure 11.5 is given by ! Ã Mx z E. (11.7) σ = εE = (EI)eq 144

Figure 11.4: Stresses at different approximation levels in a sandwich. Thus, the stress in the face σ f of the sandwich due to bending can be written as σf = tc Mx zEf tc for < |z| < + tf . (EI)eq 2 2 (11.8)

Figure 11.5: A sandwich beam exposed to (transversal) bending load.

145

If Mx is positive then the maximum stress in the face appears when z = tc /2 + tf : ¡c ¢ ¡c ¢ Mx t2 + tf Ef Ef Mx t2 + tf Mx zEf ³ ´ = = σ f max = Ef btf d2 (EI)eq (EI)eq 2 ¡ tc ¢ 2Mx 2 + tf Mx tc 2Mx = = + 2 btf d btf d2 bd2 while the minimum stress (in the same face) appears when z = tc /2: ¡ c¢ ¡ c¢ Mx t2 Ef Ef Mx t2 Mx zEf M tc ´ = x 2. σ f min = = = ³ Ef btf d2 (EI)eq (EI)eq btf d
2

Hence

Mx tc Mx tc 2Mx ≤ σf ≤ + 2 btf d btf d2 bd2

in that face. When tf << tc this shows that we can use the following approximative formula: Mx tc Mx d Mx σf ≈ (11.9) ≈ = btf d2 btf d2 btf d (in order to see this we just use that
2Mx bd2 Mx tc btf d2

=2

tf ≈ 0). tc

(For the other face we obtain similarly that σf ≈ − Mx tc Mx d Mx ≈− =− .) 2 2 btf d btf d btf d

We obtain the opposite signs if Mx is negative. The stress in the core σ c of the sandwich due to bending is σc = Mx zEc tc for |z| < . (EI)eq 2 (11.10)

146

Figure 11.6: A sandwich beam exposed to (in-plane) axial load F. If Mx is positive then the maximum stress in the core appears when z = tc /2, i.e. ¡ c¢ ¡ c¢ Mx t2 Ec Mx t2 Ec Mx zEc ´ σcmax = = = ³ Ef btf d2 (EI)eq (EI)eq 2 ¡ tc ¢ 2Mx 2 Ec Mx tc Ec = = 2 Ef btf d Ef btf d2 while the minimum stress in the core appears when z = 0, σ cmin = Hence 0 ≤ σc ≤ Mx zEc Mx (0) Ec = = 0. (EI)eq (EI)eq

Mx tc Ec Mx tc Ec Mx Ec ≤ = . 2 2 Ef btf d Ef btf tc Ef btf tc

Thus when Ec << Ef we can use the following approximative formula: σc = Mx tc Ec Mx dEc Mx Ec ≈ 0. ≤ = Ef btf d2 Ef btf d2 Ef btf d (11.11)

The direct stress will vary linearly within each material constituent, but there will be a jump in the stress at the interface between the face and the core, see Figure 11.4. 11.4.2. Due to in-plane loading (axial) The direct strain and stress in a sandwich due to in-plane loading shown in Figure 11.6 is Fx εx0 = , b (2Ef tf + Ec tc ) 147

where Fx is the axial load (normal force) and εx0 is the strain at the neutral axis (N.A.) if the two facings are of equal thickness (in order to see this, we note that the strain εx0 will be the same in the core and faces so that Fx = Ef εx0 2tf b + Ec εx0 tc b = εx0 b (2Ef tf + Ec tc )). | {z }|{z} | {z }|{z}
σf Af σc Ac

The stresses will be

σ f = Ef εx0

and

σ c = Ec εx0 .

The stresses and strains due to bending and in-plane loading can be superimposed. 11.5. Shear stresses Consider a small volume element with sidelengths dx, dy and dz see Figure 11.7. P i i Using that Fx = 0 where Fx are the forces acting on the cell walls i in the x-direction, we obtain X ∂σ x i Fx = −σ x dydz + (σ x + dx)dydz ∂x ¶ µ ∂τ xy dy dxdz −τ xy dxdz + τ xy + ∂y ∂τ xz −τ xz dxdy + (τ xz dxdy + dz)dydx ∂z = ∂τ xy ∂τ xz ∂σ x dxdydz + dydxdz + dzdydx ∂x ∂y ∂z µ ¶ ∂σ x ∂τ xy ∂τ xz = + + dxdydz = 0. ∂x ∂y ∂z

Hence, ∂σ x ∂τ xy ∂τ xz + + = 0. (11.12) ∂x ∂y ∂z P i P i Fz = 0, we obtain the other two Similarly, by using that Fy = 0 and equations for equilibrium: X ∂τ yx ∂σ y ∂τ yz Fy = + + =0 (11.13) ∂x ∂y ∂z 148

Figure 11.7: A small element. and X

Fz =

∂τ zx ∂τ zy ∂σ z + + = 0. ∂x ∂y ∂z

(11.14)

It can also be verified that

τ xy = τ yx ,

τ xz = τ zx ,

τ yz = τ zy .

(11.15)

Equations (11.12), (11.13), (11.14), and (11.15) are called the equilibrium equations. We assume that the shear stress in (11.12) will not vary with y, and therefore ∂τ xy /∂y = 0 (in fact we assume τ xy = 0 in all points). Thus we get that X
i Fx =

∂σ x ∂τ xz + =0 ∂x ∂z

and the shear stress τ xz can therefore be found as follows: ∂σ x ∂τ xz =− . ∂x ∂z This gives Z (d+tf )/2
z

∂σ x dz = − ∂x

Z

(d+tf )/2

z

(when using the fact that τ xz at (d + tf )/2 = 0) i.e. Z (d+tf )/2 ∂σ x dz. τ xz (z) = ∂x z 149

∂τ xz dz = −(τ xz ((d + tf )/2) − τ xz (z)) = τ xz (z), {z } | ∂z
=0

From equation (11.7) σ = εE = and the fact that

Ã

! Mx z E (EI)eq

dMx = Tx dx where Tx is the shear force. We obtain that the shear stress τ xz (z) ³ ´ Z (d+tf )/2 Z (d+tf )/2 d Mx zE (EI)e q Ez dMx τ xz (z) = dz = dz = dx (EI)eq dx z z Z (d+tf )/2 Z (d+tf )/2 Tx Tx zE = Tx dz = zEdz = B(z), (EI)eq (EI)eq z (EI)eq z

where B(z) is the first moment of area Z (d+tf )/2 zEdz. B(z) =
z

We observe that for |z| < tc /2 Z Z (d+tf )/2 zEdz = B(z) =
z

tc /2

zEc dz +

= Ec = = = Ec 2 Ec 2 Ec 2

Thus, the shear stresses in the core of the sandwich is µ ¶¶ µ Ef tf d Ec t2 tc Tx c 2 for |z| < . + −z τc = (EI)eq 2 2 4 2 150

¸t /2 ∙ ¸(d+tf )/2 1 2 c 1 2 z + Ef z 2 2 z t /2 # "µ ¶ "cµ ¶2 µ ¶2 # 2 Ef tc d + tf tc − z2 + − 2 2 2 2 " # ¸ ∙ 2 Ef (d + d − tc )2 t2 tc 2 −z + − c 4 2 4 4 ¸ ¸ ∙ 2 ∙ 2 Ef Ef dtf Ec tc tc 2 2 −z + d[d − tc ] = −z + . 4 2 | {z } 2 4 2
=tf

z

Z

(d+tf )/2

zEf dz

tc /2

(11.16)

For tc /2 ≤ −z ≤ tc /2 + tf (in the upper face) Z −tc /2 Z tc /2 Z (d+tf )/2 Z (d+tf )/2 zEdz = zEf dz + zEc dz + zEf dz B(z) = z z −tc /2 tc /2 {z } | 1 2 1 + Ef z 2 z 2 2 z tc /2 # "µ ¶ "µ ¶2 µ ¶2 # 2 1 1 tc d + tf tc = Ef − z 2 + Ef − 2 2 2 2 2 ! "µ # õ ¸ ∙ 2 ¶2 ¶2 2 Ef Ef tc t d + tf Ef d + tf = − c = − z2 − z2 + 2 4 2 2 4 2 2 ! õ ¶ ¶2 µ Ef 1 2 (tf + tc ) + tf Ef 2 2 2 t + tf tc + tf − z . = −z = 2 2 2 4 c = Ef Z Z ∙ ¸−tc /2 ∙ ¸(d+tf )/2
=0

For tc /2 ≤ z ≤ tc /2 + tf (in the lower face)
(d+tf )/2 (d+tf )/2

# "µ ¶2 1 d + tf B(z) = zEdz = zEf dz = Ef − z2 2 2 z z ! õ ¶ ¶2 µ Ef 1 2 (tf + tc ) + tf Ef 2 2 2 t + tf tc + tf − z = −z = 2 2 2 4 c

(i.e. the same as for the upper face). Hence, the shear stress in the facings of the sandwich is µ ¶ 1 2 Tx Ef 2 2 t + tf tc + tf − z for tc /2 ≤ |z| ≤ tc /2 + tf . (11.17) τf = 2 (EI)eq 4 c Assume that Tx is positive (otherwise max is replaced by min and vice versa). Then the maximum shear stress in the core appears when the expression − z 2 ) in (11.16) is maximized, i.e. when z = 0 (the neutral axis N.A.), and is found in the following way: µ ¶¶ µ µ µ ¶¶ Ef tf d Ec t2 Tx Ef tf d Ec t2 Tx c c 2 τ c max = = + −z + −0 (EI)eq 2 2 4 (EI)eq 2 2 4 151

(t2 /4 c

Tx = (EI)eq

µ

Ef tf d Ec t2 c + 2 8

µ ¶ Ec t2 Tx c Ef tf d + . = (Ef btf d2 ) 4

Tx
Ef btf d2 2

´

µ

Ef tf d Ec t2 c + 2 8

¶ (11.18)

The minimum shear stress in the core appears when the expression (t2 /4 − z 2 ) c in (11.16) is minimized, i.e. when |z| = tc /2 (the face/core interface), i.e. µ ¶¶ µ µ µ ¶¶ Ef tf d Ec t2 Tx Ef tf d Ec t2 t2 Tx c c c 2 τ c min = = + −z + − (EI)eq 2 2 4 (EI)eq 2 2 4 4 Tx = (EI)eq µ Ef tf d 2 ¶ =³ Tx
Ef btf d2 2

´

µ

Ef tf d 2

=

Tx . bd

(11.19)

³ 2 The maximum shear stress in the face appears when the expression ´ tc + tc tf + t2 − z 2 in (11.17) is maximized, i.e. when z = tc /2 (the face/core f 4 interface) such that à ¶ µ 2 µ ¶2 ! Tx Ef tc t2 Tx Ef tc c τ f max = = + tc tf + t2 − z 2 = + tc tf + t2 − f f (EI)eq 2 4 (EI)eq 2 4 2 Tx Ef = (EI)eq 2 µ t2 t2 c + tc tf + t2 − c f 4 4 = ¶ = ¢ ¢ ¡ Tx Ef ¡ Tx Ef ´ tc tf + t2 = tc tf + t2 = ³ f f 2 E bt d 2 (EI)eq 2 f 2f (11.20)

Tx Tx Tx Ef (tc + tf ) = 2 (tc + tf ) = Ef bd2 bd bd

(this also shows that τ c min = τ f max ). ´ ³ 2 The minimum shear stress in the face appears when the expression tc + tc tf + t2 − z 2 in (11.17) is minimized, i.e. when |z| = tc /2 + tf f 4 τ f min Tx Ef = (EI)eq 2 µ t2 c + tc tf + t2 − z 2 f 4 ¶ Tx Ef = (EI)eq 2 Ã t2 c + tc tf + t2 − f 4

µ

tc + tf 2

¶2 !

152

Tx Ef = (EI)eq 2

µ

¶¶ µ Tx Ef t2 1 2 c 2 2 = + tc tf + tf − tf + tf tc + tc (0) = 0. 4 4 2 (EI)eq

The deviation between the maximum and minimum shear stress in the core from (11.18) and (11.19) will be less than 1 percent, i.e. τ c max − τ c min 1 , < τ c min 100 if µ ³ Ef tf d +
µ

τ c max − τ c min = τ c min

(Ef btf d2 )

|Tx |

Ec t2 c 4 |Tx |

´¶

Ef btf d2 2

³

Ã

µ

Ef tf d 2

´

|Tx | ¶ Ef btf d2 2

³

Ef tf d 2

! ´

<

1 . 100

This means that

1 Ec t2 c < , 4Ef tf d 100 100 < 4Ef tf d Ec t2 c

or

which is often satisfied for sandwich beams because we often have that the core is weak i.e. Ec << Ef and the faces are thin i.e. tf << tc . Thus we often use τ c min as an approximation for the shear stress in the core (see Figure 11.4). 11.5.1. Summary of approximations If we assume weak core i.e. Ec << Ef and thin facings i.e. tf << tc, the stresses in the face and core in the sandwich are σ f,max = from (11.9) since tc ≈ d, and Mx btf d (11.21)

σ cmax ≈ 0

(11.22)

from (11.11). As an approximation for the shear stress in the core τ c min we can use 153

τc = from (11.20).

Tx bd

(11.23)

154

11.6. Sandwich design: stiffness, strength and weight The deflection, δ of a sandwich beam in general is the sum of the bending and

Figure 11.8: Deflection of a cantilever sandwich beam with an end point load.. shear components, see Figure 11.8 (subscripts ”b” and ”s” denotes bending and shear, respectively), δ = δb + δs = P L3 PL + B1 (EI)eq B2 (AG)eq

where B1 and B2 are constants which depend on the geometry of the loading and the boundary conditions (type of support). Moreover, the maximum moment Mx and the maximum shear (transverse) force Tx are given by Mx = PL P , Tx = , B3 B4

155

where B3 and B4 also are constants which depend on the geometry of the loading and the boundary conditions. In Table 11.24 you can find the constans for several loading conditions and boundary conditions.

Mode of loading, (all beams are of length L) Cantilever, end load, P Cantilever, Uniformly distributed load, q = P/L Three-point bend, central load, P Three-point bend, Uniformly distributed load, q = P/L Ends built in, Central load, P Ends built in, Uniformly distributed load, q = P/L

B1 δ b = B1P L (EI) 3
3 eq

B2
PL δ s = B2 (AG)
eq

B3 Mx = P L B3 1

B4
P Tx = B4

1

1

8

2

2

1

48

4

4

2

384 5

8

8

2

192

4

8

2

384

8

12

2 (11.24)

In Table 11.24, Mx is the maximun bending moment and Tx is the maximum shear (transverse) force.

156

Figure 11.9: Cantilever beam with end point load. 11.7. Example of beam calculations A cantilever beam has Gc = 30 MPa (80kg/m3 PVC foam), Ef = 200000 MPa (steel), L = 500mm, tf = 1 mm, tc = 30 mm (d = tc + tf = 31 mm), b = 1 mm, as in Figure 11.9.

a) Find the total deflection, δ, and the deflection due to shear in percentage of the total deflection.
The total deflection is described as δ = δb + δs = where the bending contribution is δb = P L3 P · L3 P · (500)3 ´= ³ ´ = 0.43P (mm/N) = ³ 2 E bt d2 3 (EI)eq 3 f 2f 3 200000·1·1·(31) 2 PL PL P · 500 ´ = 0.52P (mm/N). =³ 2 ´=³ 1·(31)2 ·30 bd Gc (AG)eq
tc 30

P L3 PL + , 3 (EI)eq (AG)eq

and the shear contribution is δs =

The total deflection is

δ = δ b + δ s = 0.43P + 0.52P = 0.95P (mm/N).

157

The deflection due to shear in percentage of the total deflection is δs 0.52 (100) = 54.7% (mm/N). 100 = δb + δs 0.95

b) Compare a) with a homogenous steel beam with a rectangular cross-section of height h = 30 mm and width b = 1mm.
The total deflection is δ = δb + δs = where the bending contribution is δb = 4P L3 P L3 P L3 4P · 5003 = ¡ Ebh3 ¢ = = = 0.0926P 3 (EI)eq Ebh3 200000 · 1 · 303 3 12 PL PL P 500 ´ = ¡ ¢³ ´ = 0.00026P, = ¡ ¢³ bh E 1·30 200000 (AG)eq
k 2(1+ν) 1.2 2(1+0.3)

P L3 PL + , 3 (EI)eq (AG)eq

and the shear contribution is δs =

where k is a shear factor. For rectangular homogeneous cross-sections k is 1.2. Poissons ratio ν = 0.3. The total deflection δ = δb + δ s = 0.0926P + 0.00026P = 0.0 929P. The deflection due to shear in percentage of the total deflection is 0.00026 δs (100) = 0.28%. 100 = δb + δs 0.0 929 This explains why elementary beam theory usually neglects the contribution of the transverse shear deformation.

c) Compare a) with a homogenous steel beam with a rectangular cross-section of
height h = 2tf = 2 mm. Here, the bending contribution is δb = 4P L3 P L3 P L3 4P · 5003 = ¡ Eh3 ¢ = = = 312.5P 3 (EI)eq Eh3 200000 · 23 3 12 158

and the shear contribution is δs = PL PL P 500 ´ = ¡ ¢³ ´ = 0.0039P. = ¡ ¢³ bh E 1·2 200000 (AG)eq
k 2(1+ν) 1.2 2(1+0.3)

The total deflection

δ = δ b + δ s = 312.5P + 0.0039P = 312.5039P. The deflection due to shear in percentage of the total deflection is δs 0.0039 100 = (100) = 0.00125% . δb + δs 312.5039

159

Figure 11.10: A simply supported three-point bended beam. 11.8. Strength and stiffness design example A simply supported three-point bending beam, with uniform load case, has P = qL = 10000N, Gc = 40MPa (80kg/m3 PVC foam), (Ec = 100 MPa), shear strength τ c,cr = 1.5MPa, Ef = 20000MPa (GRP), strength σ f,cr = 100MPa, L = 1000mm, tc = 50mm, b = 100 mm, see Figure 11.10. The maximum allowed deformation of the beam is L/50.We assume Ec << Ef and tf << tc . Find the face thickness, tf . We know that (EI)eq = Ef btf d2 bd2 Gc , and (AG)eq = 2 tc

and from Table 11.24 we find that |Tx |max = P PL and |Mx |max = . 2 8 (11.25)

i) Strength design: Calculate the face thickness, tf , for maximum allowable stress.

160

We have the formulae σf ¡ 10000·1000 ¢ ¡PL¢ tc Ef 50 · 20000 Mx max tc Ef ´= ´ = ³8 = = ³8 Ef btf d2 20000·(100)·tf ·502 2 (EI)eq 2 2 2 2 ¡ 10000·1000 ¢ 50 · 20000 250.0 ´ = ³8 = , 20000·(100)·tf ·502 tf 2 2 tf = 250 250 = = 2.5 mm. σf 100

here d ≈ tc , thus the face thickness for maximum allowable stress

The maximum shear stress in the core is τc =
P Tx max P 10000 = 2 = = = 1MPa db db 2db 2 · 50 · (100)

(which is satisfactory since σ cr > σ f = 100 MPa ).

(which is satisfactory since τ c,cr = 1.5 MPa). Next, we want to check the wrinkling stress 12.1 √ p 3 σ cr = 0.5 3 Ef Ec Gc = 0.5 20000 · 100 · 40 = 215 MPa ii) Stiffness design Find the face thickness for allowable deformation. Total deflection is δ = δb + δs. We find that δb = P L3 PL and δ s = 384 8 (AG)eq (EI)eq 5 P L3 ³ PL ´+ ³ ´= 2 8 bdtcGc

such that δ = δb + δs = = P L3 PL + = 384 (EI)eq 8 (AG)eq 5
384 5 Ef btf 2 d2

10000 · 1000 52.1 10000 · 10003 ³ ´+ ³ ´= + 6.25. 20000·100·tf ·(50)2 100·(50)2 ·40 384 tf 8 5 2 50 161

Thus, when allowed deformation δ = L/50 tf = 52.083333 52.08333 3 ¢ = 3.8 mm = ¡ 1000 (δ − 6.25) − 6.25 50

which is the thickness we must use to fulfill the requirements! Check the requirements due to the approximations. Since ¶2 µ µ ¶2 53.8 d = 3 = 601.3 > 100 3 tf 3.8 53.8 d = 14.2 > 5.77) = (or tf 3.8

then the first term of 11.3 is less than 1% of the second, and can therefor be neglected, and since 6Ef tf d2 6 · 20000 · 3.8 · (53.8)2 = = 105. 6 > 100 Ec t3 100 · (50)3 c then the third term of 11.3 is less than 1% of the second , and can therefor be neglected such that we can use the reduced form of 11.3. The assumption (EI)eq = D = is valid! Ef btf d2 2

162

12. Failure modes of sandwich panel
A sandwich panel must have the strength to carry the design loads without failing in one of the possible failure modes. We have to design against and consider all the failure modes to be sure of that the structure will not fail. Examples on failure modes is shown in Figure 12.1. A sandwich construction will fail by the failure

Figure 12.1: Some failure modes; a)face yielding/fracture, b) core shear failure, c) and
d) face wrinkling, e) general buckling, f) face dimpling, and g) local indentation.

mode which occurs at the lowest load. The optimum design is when two or more failure modes occur at the same load. The failure modes can be found on the basis of when the mode occur. Some of the failure modes is described in the following chapter. The skin and core materials should be able to withstand the tensile, compressive and shear stresses induced by the design load. Also the adhesive must be capable of transferring the shear stresses between skin and core. The sandwich panel should also have sufficient bending and shear stiffness to prevent excessive deflection.

163

12.1. Failure loads and stresses (I) Face Yielding/fracture: Face yielding/fracture occurs when the normal stress in the face σ f equals or exceeds the (yield) strength of the face material, σ yf , such that: σf = PL Mx = ≥ σ yf . btf d B3 btf d

(II) Face wrinkling: Face wrinkling (local buckling) occurs when the normal stress in the face reaches the wrinkling stress (the local instability stress). Wrinkling occurs when the compressive stress in the face is σf ≥ p Mx PL = = 0.5 3 Ef Ec Gc . btf d B3 btf d (12.1)

Hence, the wrinkling load is independent of the sandwich geometry, and is only a function of the face and core properties. It is the core that has most influence on the wrinkling load. (III) Core shear failure: Core shear failure occurs in a foam with a plastic-yield point when the principal stresses satisfy the yield criterion. If the shear stress in the core is large compared to the normal stress, failure occurs when the shear stress, τ c , equals or exceeds the yield strength of the foam in shear, τ yc . The core failure is given by τ c max = P Tx = ≥ τ yc . bd B4 bd

(IV) Failure of the adhesive bond (debonding): Failure of the adhesive bond can occur due to overloading. Debonding (the adhesive between the skin and the core fail) is the most difficult of the mechanisms to analyze. The adhesive must have a strength equal or bigger than the shear stress in the bonding line under loading which is almost the same as τ c max . To avoid debonding therefore Tx ≤ τ ya τ c max = bd 164

where τ ya is the yield shear stress in the adhesive. High thermal stresses, fatigue, and aging are some of the reasons to debonding. (V) Core indentation: Core indentation is only a problem when loads are very localized and can be avoided if we ensure that the load is distributed over a minimum area of at least A≥ P , σ yc

where σ yc is the compressive strength of the core. (VI) General buckling: General buckling can occur in sandwich constructions due to the transverse shear deformation. The transverse shear deformation must be accounted for, since this decreases the buckling load compared with the ordinary Euler buckling cases. The critical buckling load for sandwich columns with thin faces is given by: 1 1 1 = + , Pcr Pb Ps where Pb is the buckling load in pure bending, and Ps in pure shear, and they are given as follows π 2 (EI)eq Pb = and Ps = (AG)eq , (βL)2 where β is the factor depending on the boundary conditions in Euler buckling, see Figure 12.2 (VII) Face dimpling (local buckling, or intercellular buckling): Face dimpling may occur in sandwich structures with honeycomb or corrugated as core material. For a square honeycomb this buckling stress equals µ ¶2 tf σ f = 2.5Ef for Poissons ratio ν f = 0.3, a where a is the length of the side of the cell. For hexagonal honeycombs the buckling stress equals à µ ¶2 µ ¶2 ! tf tf 2Ef , ≤ σ yf , when ν f = 0.3 then σ f ≈ 2. 2Ef σf = 2 1 − νf s s 165

Figure 12.2: Different cases for Euler buckling. where s is the radius of the inscribed circle in the honeycomb cell. (VIII) Fatigue: Fatigue is said to cause more than 90% of all structural failures. For the face material, a conservative way to use the fatigue limit under which the material can undergo an infinite number of load cycles without exhibiting any damage by taking the allowable face stress σ yf as the material fatigue stress at the given number of load cycles and stress ratio. For the core material the reasoning is similar; substitute the allowable shear stress τ yc with the fatigue limit. Be aware that there is not always data for all materials available. Hopefully, more data will be available in the future.

166

12.2. Failure-mode maps Failure-mode maps can be used to design sandwich constructions in a way that will improve the performance of the sandwich so that no single component is overdesigned. The designer can choose the anticipated failure mode, or making two different failure modes equally likely occur. Also, this is an advantage for cases where certain failure modes should be avoided. The dominant failure mode mechanism for a given design, is the one giving failure at the lowest load. A transition in failure mechanism takes place when two or more mechanisms have the same load. This information can be displayed as a diagram or map (failure-mode map).The most important transitions we get from equating pairs of the failure-mode equations are: face yielding - face wrinkling, face yield - core shear and face wrinkling - core shear, as shown in Figure 12.4. Failure-mode maps can be constructed from the failure-mode equations that comes out as a result of the analysis of the different failure modes. Some different failure modes with the corresponding failure loads for a rectangular sandwich beam are shown in the table below.

Summary of failure modes and failure loads:
Failure Mode Failure Load B bt d Face Yielding/fracture (I) P ≥ σ yf 3L f p B bt d Face Wrinkling (II) P ≥ 3L f 0.5 3 Ef Ec Gc bt Core shear failure (III) P ≥ B4L c Failure of the adhesive bond (debonding) (IV) Tx ≥ τ ya bd Core indentation (V) P ≥ σ yc A (12.2) 12.2.1. Transition equation between face yielding and face wrinkling Face yielding/fracture occurs when PL P Mx = = = σ yf . tf btf d B3 btf d B3 b L d hence the failure load P is given by µ ¶ tf P = σ yf B3 bd . L σf = 167

(12.3)

Face wrinkling (local buckling) occurs when σf = p PL |Mx | = = 0.5 3 Ef Ec Gc . btf d B3 btf d (12.4)

Thus the failure load P can be written as µ ¶ p tf P = 0.5B3 bd 3 Ef Ec Gc . L

i.e

Putting (12.3) and (12.4) equal to each other, we obtain that µ ¶ µ ¶ p tf tf σ yf B3 bd = 0.5B3 bd 3 Ef Ec Gc , L L
1 1 1 p 3 σyf = 0.5Ef3 Ec3 Gc = 0.5 3 Ef Ec Gc .

(12.5)

(12.6)

By using the fact that for most foams and honeycombs the mechanical properties vary with the density of the material in the following way Ec = CE ρn , c Gc = CG ρn , c σ yc = Cσ ρm and τ yc = Cτ ρm , c c (12.7)

where the constants CE , CG , Cσ , Cτ , n and m depend on the type of microstructure and the mechanical properties of the micromaterial in the core, we find that q p p 3 σ yf = 0.5 Ef Ec Gc = 0.5 3 Ef (CE ρn ) (CG ρn ) = 0.5 3 Ef CE CG ρ2n . c c c

Thus the transition between face yielding and face wrinkling is given by the equation s ³ σ ´3 1 yf ρc = 2n , (12.8) 0.5 Ef CE CG which is independent of tf /L and therefore will appear as a horizontal line in a failure mode map in Figure 12.4, where the variable tf /L is along the horizontal axis and ρc is along the vertical axis.

168

12.2.2. Transition equation between face yield and core shear Core shear failure occurs when τ c max = where P = τ yc B4 bd = (Cτ ρm ) B4 bd. c by the use of (12.7). Face yielding/fracture occurs when σf = PL Mx = = σ yf . btf d B3 btf d (12.9) P Tx = ≥ τ yc , bd B4 bd

Thus, we find that the failure load µ ¶ tf d. P = σ yf B3 b L Putting the two expressions in (12.9) and (12.10) equal to each other µ ¶ tf m (Cτ ρc ) B4 bd = σyf B3 b d, L we obtain that ρm c B3 = σ yf Cτ B4 µ ¶ tf . L (12.10)

Thus the transition equation between core shear failure and face yielding will be given by r 1 µ ¶m B3 tf m σ yf . (12.11) ρc = Cτ B4 L 12.2.3. Transition equation between face wrinkling and core shear Face wrinkling (local buckling) occurs when σf = p PL Mx = = 0.5 3 Ef Ec Gc . btf d B3 btf d 169

Hence, µ ¶ µ ¶ q p tf tf 3 P = 0.5B3 bd Ef Ec Gc = 0.5B3 bd 3 Ef (CE ρn ) (CG ρn ) c c L L µ ¶ p tf (12.12) bd 3 Ef CE CG ρ2n = 0.5B3 c L

by the use of (12.7). Core shear failure occurs when

τ c max = Hence,

Tx P = = τ yc . bd B4 bd (12.13)

P = τ yc B4 bd = Cτ ρm B4 bd c

by (12.7). Putting the two expressions in (12.12) and (12.13) equal to each other, we get that µ ¶ p 1 tf B3 bd 3 Ef CE CG ρ2n = Cτ ρm B4 bd. c c 2 L i.e. p µ ¶ ¡ ¢− 1 B3 3 Ef CE CG tf m− 2n = ρm ρ2n 3 = ρc 3 . c c 2Cτ B4 L Thus, the transition equation between face wrinkling and core shear failure will be s p µ ¶ 1 3 Ef CE CG tf m− 2n m− 2n B3 3 3 ρc = . (12.14) 2Cτ B4 L

Summing up:
The Face yield - Face wrinkling transition equation is given by s ³ σ ´3 1 yf 2n ρc = . (1) 0.5 Ef CE CG The Face yield - Core shear transition equation is r 1 µ ¶m B3 tf m ρc = σ yf . (2) Cτ B4 L 170

(12.15)

(12.16)

The Face wrinkling - Core shear transition equation is given by s p µ ¶ 1 3 2n B3 Ef CE CG tf m− 2n m− 3 3 ρc = (3) 2Cτ B4 L

(12.17)

The transitions of failure modes in (12.15), (12.16) and (12.17) are illustrated in the failure mode map in Figure 12.4. An example of a failure mode map To illustrate that the transition between the failure modes can form a failure mode map, we will have a look at a beam in three-point bending. The beam has faces with ultimate strength σ yf = 150MPa and Ef = 70000MPa. B3 = 4 and B4 = 2. We assume a linear relation between the core properties and the core density, which means that n = m = 1, and that CE = 1, CG = 0.4 and Cτ = 0.015. Then we obtain the following transition equations: The Face yield - Face wrinkling transition equation is given by s s ³ σ ´3 ³ σ ´3 1 1 yf yf 2n 2 ρc = = (1) 0.5 Ef CE CG 0.5 Ef CE CG sµ ¶3 1 150 2 = = 31.053. 0.5 (70000) (1) (0.4) The Face yield - Core shear transition equation is µ ¶ tf (4) ρc = (150) = 20000 . (0.015) (2) L The Face wrinkling - Core shear transition equation is given by s p µ ¶ 1 3 2n B3 Ef CE CG tf m− 2n m− 3 3 ρc = 2Cτ B4 L s p µ ¶1 3 1 (4) (70000) (1) (0.4) tf 1 3 3 = 2 (0.015) (2) L !3 µ ¶ Ã p 3 (4) 3 (70000) (1) (0.4) tf = 2 (0.015) (2) L µ ¶3 tf 9 = 8.296 4 · 10 . L 171

(12.18)

(12.19)

(12.20)

Summing up we obtain that: The Face yield - Face wrinkling transition equation is given by log10 ρc = log10 31.053 The Face yield - Core shear transition equation is µ ¶ tf . log10 ρc = log10 20000 + log10 L The Face wrinkling - Core shear transition equation is given by µ ¶ ¡ ¢ tf 9 . log10 ρc = log10 8.296 4 × 10 + 3 log10 L ³ ´ tf Thus, substituting x = log10 L and y = log10 ρc we obtain that The Face yield - Face wrinkling transition equation is given by y = log10 31.053 The Face yield - Core shear transition equation is y = log10 20000 + x. The Face wrinkling - Core shear transition equation is given by ¡ ¢ y = log10 8.296 4 × 109 + 3x.

The graphs of these expressions are illustrated in Figure 12.3, where we also have indicated the failure mechanisms which are pairwise dominating on the respective side of each graph (1,2 and 3 denote face yield, face wrinkling and core shear, respectively). For each failure mechanism we now find the region for which this mechanism is dominating all other mechanisms. This region must be the intersection of the regions where the failure mechanism is pairwise dominating the others. The resulting regions are shown in Figure 12.4.

172

Figure 12.3: The graphs of the three transisition equations.

Figure 12.4: Failure mode map for a sandwich beam in three-point bending, which has
faces made of aluminium and a core with properties that vary with the core density.

173

13. Design Procedures
Designing a sandwich element is very often an integrated process of sizing and material selection in order to get some sort of optimum design with respect to the objective you have chosen for instance weight, strength, or stiffness. Note that all material systems have both advantages and disadvantages. Therefore it is difficult to state some general terms about choosing materials. But, some material related properties can still be considered despite the choice of material, such as density of the core material. An optimum design of a sandwich construction is very difficult to obtain because there are so many different constraints that the problem becomes complex. But, considering the most important constraints and using a simple optimization technique could be very useful in the design process. An optimization on strength only does not ensure that the sandwich panel is stiff enough. In most studies done in optimization they do not take into account all possible failure modes as they should have. 13.1. The stiffness of sandwich structures and its optimization We will consider a sandwich beam given a load P in three-point bending see Figure 13.1. For several core microstructures it appears that the elastic moduli of the

Figure 13.1: A sandwich beam. core Ec and Gc vary with the relative density of the core ρc /ρs in the following

174

way Ec = C1 Es

µ

ρc ρs

¶2

, Gc = C2 Es

µ

ρc ρs

¶2

(13.1)

where ρc is the density of the core, ρs is the density of the solid material (cell wall) in the core, Es is the Youngs modulus of the solid material (cell wall) in the core, and C1 (≈ 1) and C2 (≈ 0.4) are proportionality constants. We will explain the concept of relative density ρc /ρs in more detail later. Recall that for most cases the flexural rigidity (EI)eq = is reduced to (EI)eq = and that the equivalent shear rigidity (AG)eq = when d ≈ tc , is reduced to Recall also that the deflection δ δ = δb + δs = P L3 PL + . B1 (EI)eq B2 (AG)eq (13.4) bd2 Gc tc (13.3) Ef bt3 Ec bt3 Ef btf d2 f c + + 6 12 2 Ef btf d2 , 2 (13.2)

(AG)eq = bdGc .

If we insert (13.2) and (13.3) in (13.4) we obtain that the compliance (the inverse of the stiffness) of the beam δ 2L3 L = + . 2) P B1 (Ef btf d B2 (bdGc ) (13.5)

In most sandwich design the key issue is to minimize the weight, W , (also called the ”objective function” ) given by W = mgV = 2ρf gbLtf + ρc gbLtc ≈ 2ρf gbLtf + ρc gbLd, | {z } | {z } | {z } | {z }
facings core facings core

(13.6)

175

for a given bending stiffness P/δ, where m is the mass, V is the volume, g is the acceleration due to the gravity and ρf and ρc is the density of the face and core material, respectively. The only free variables are d, tf and ρc . For simplicity we assume that the core density ρc , is fixed. Then the optimization problem is quiet easy. By using (13.5), we find that tf = 2L3 ³ δ B1 Ef bd2 P − ´ (13.7)

L B2 (bdGc )

and by substituting it into (13.6) we have that the objective function (W is to be minimized) ⎛ ⎞ 3 2L ³ ´ ⎠ + ρc gLd. W = 2ρf gL ⎝ (13.8) L 2 δ − B1 Ef bd P B2 (bdGc ) ⎞ 4ρf gL4 ³ ´ ⎠ + ρc gLd W =⎝ L 2 δ − B1 Ef bd P B2 (bdGc ) ⎛

We minimize the weight W with respect to the only other free variable, d, by setting ∂W/∂d = 0 and then we obtain the optimum core thickness, dopt . Rearranging (13.8) we get that W = = where k1 = Differentiating we get ∂W 2k1 d − k2 + ρc gL = 0 =− ∂d (k1 d2 − k2 d)2 i.e. ¡ ¢2 − (2k1 d − k2 ) + ρc gL k1 d2 − k2 d = 0, 176 1
B1 Ef bδ 2 d 4P gρf L4

k1

d2

1 + ρc gLd, − k2 d

B1 Ef bL d 4gρf L4 B2 (bGc )

+ ρc gLd =

B1 Ef bδ B1 Ef bL . , k2 = 4 4P gρf L 4gρf L4 B2 (bGc )

which is a 4th order equation in d. If the core density also should be treated as a variable the design optimization problem is more complex. 13.1.1. Example of minimum weight design for given stiffness This is a method for finding the optimum face and core thickness for a given stiffness, providing the materials included the core properties are predetermined. We assume that the core properties can be varied by choosing different densities. If the compliance δ/P from (13.5) is denoted C, and solving it with respect to tf as a function of d we obtain from (13.7) that tf = 2L3 ³ δ B1 Ef bd2 P − ´= 2L3 ³ B1 Ef bd2 C − ´

L B2 (bdGc )

L B2 bdGc

which when substituting into the weight equation, we obtain that the total weight W of the beam as a function of d (when d = tc ) Ã ! ¸−1 ∙ ¡ ¢ 4ρf L2 Cd2 d − W [g] = 2ρf tf + ρc d L = + ρc d L. (13.9) B1 Ef b L B2 bGc A simply supported beam in three-point bending should have a maximum mid-point deflection of δ = L/100. B1 is 48 and B2 is 4. Let L = 500mm, the width b = 1mm the faces are made of aluminium alloy with ρf = 2700kg/m3 and Ef = 70000MPa and the core has a density ρc = 100kg/m3 and a shear modulus Gc = 40MPa. Assume a point load of 10N is acting in the middle of the beam. 177

and by rearranging we get that ⎤ ⎤ ⎡ ⎡ 3 3 1 1 2L 2L ⎣ ⎣³ ´⎦ = ³ ´⎦ = tf = L dL B1 Ef bd2 B1 Ef b C − B2 bdGc Cd2 − B2 bGc ⎤ ⎡ ¸−1 ∙ 2 2 1 Cd d 2L ⎣ 2L2 ³ ´⎦ = − = Cd2 d B1 Ef b B1 Ef b L B2 bGc −
L B2 bGc

weight W [g] 2.625

2.5

2.375

2.25

2.125 20 25 30 35 40 45 d [mm] 50

Figure 13.2: Beam weight (g/mm thickness) as function of thickness d. The weight of the beam per unit thickness (eq. (13.9) times the length L) can then be plotted versus thickness d as illustrated in Figure 13.2. The weight ⎛ ⎞ ⎡ ³ 500 ´ ⎤−1 100 2 d2 −3 d ⎦ ⎜ 4 (2.7 · 10 ) (500) ⎣ 10 ⎟ W (d) [g] = ⎝ − + 0.1 · 10−3 d⎠ 500 48 (70000) 500 4 (40) simplifying and solving we get that µ ¶ 8.0357 × 10−4 W (d) [g] = + 0.0001d 500. 0.001d2 − 0.00625d

The weight of the beam per unit thickness (equation ) The curve in Figure 13.2 shows that the optimum design is when d ≈ 29mm. This value can be found more precisely by solving the equation W 0 (d) = 0

numerically, i.e. solving the equation 1 2.511 2 × 10−3 − 8.035 7 × 10−4 d + 0.05 = 0. d2 (0.001 d − 0.006 25)2 178

The solution of this equation turns out to be i.e. d = 28.617. Thus the minimum total weight W (28.617) = µ ¶ 8.0357 × 10−4 + 0.0001 (28.61729) 500 = 0.001 (28.61729)2 − 0.00625 (28.61729) = 2.058 6g. Substituting back gives the face thickness ¸−1 ∙ 2 2L2 Cd d tf = = − B1 Ef b L B2 bGc ⎡ ³ 500 ´ ⎤−1 100 2 (28.617)2 28.617 ⎦ 2 (500) ⎣ 10 − = = 48 (70000) 1 500 4 (40) 1 = 0.23249mm.

=

179

Part III

Cellular Solids
14. Some definitions of cellular solids
Cellular solids are described by the geometric structure of the cells, that is both shape and size of the cells and the way the cells are distributed. Foams are threedimensional cellular solids and are more complex than the two-dimensional structures like honeycomb-structures. But, by studying the two-dimensional structures we make a basis in understanding the more difficult and complex three-dimensional structures of for instance foams. One of the most important feature of a cellular solid is what we call the relative density, defined by ρ∗ ρ= (14.1) ρo where ρ∗ and ρo are the density of the cellular material and the outer (connected solid) material (which is the material that the cell-walls are made up of), respectively. When the relative density increases, the cell wall gets thicker. Relative density of the outer material is the same as the volume fraction of the outer material, po , defined by Vo volume of outer material (m3 ) = ∗ po = 3 V volume of foam (m ) (see Figure 14.1). In order to see this, we observe that the density of the foam mass of foam (kg) m∗ ρ = = ∗ V volume of foam (m3 )

and the density of the outer connected material ρo = mass of outer (kg) mo . 3 = Vo volume of outer (m )

For the case when the inner material in Figure 14.1 and 14.2 is air, we have that m∗ = mo . 180

Figure 14.1: Cellular solids.

Figure 14.2: Volume fraction of square honeycomb cells. Thus, the volume fraction of the outer material Vo po = ∗ = V
mo ρo m∗ ρ∗

=

m∗ ρo m∗ ρ∗

=

ρ∗ . ρo

(14.2)

Moreover, the volume fraction of the inner material is pI = Note also that volume of inner (m3 ) VI . 3 = V∗ volume of foam (m )

Vo V ∗ − VI VI = = 1 − ∗ = 1 − pI . ∗ ∗ V V V When the cells are square honeycombs, as in Figure 14.2, the volume fractions can also be expressed in the terms of side length l and wall thickness t in the following way po = 181

Materials ρ Special ultra-low-density foams 0,001 Polymeric foams (packaging and insulation) 0,05-0,20 Cork 0,14 Softwoods 0,15-0,40 Table 14.1: Relative density for some cellular solids. ¶2 µ µ µ ¶¶2 (l − t)2 l−t t po = 1 − pI = 1 − =1− =1− 1− = 2 l l l à µ ¶ µ ¶2 ! µ ¶ µ ¶2 t t t t 1− 1−2 =2 , + − l l l l which is approximately 2 (t/l) for small values of t/l. For a closed-cell structure, the relative density ρ∗ /ρo can be written as µ ¶ t ρ∗ = po = 2 . ρo l If the relative density ρ∗ /ρo (= po ) is is large, say po > 0.3, the structure will look more like a solid material with isolated pores than a cellular structure (see [5], p. 2). Gibson and Ashby refer to materials with relative density less than 0.3 as true cellular solids. Throughout we assume a low density, so that t << l (wall thickness<<wall-length), see Figure 14.3 and that all the walls have the same thickness. Simple beam theory is valid only when t/l < 1/4 (see [5], p. 110). Some examples of the relative density of some cellular solids are given in Table 14.1. In the same way we define the relative Young’s modulus as E∗ E= Eo where E ∗ and Eo are the Young’s modulus of the cellular material and the solid material, respectively.

182

l h t
x2 x3 x1

Figure 14.3: Honeycomb structure. 14.1. Mechanics of honeycombs The cells in a honeycomb-structure are usually hexagonal, but they can also be triangular or square or rhombic. We will mainly consider the regular square and regular hexagonal honeycombs. The honeycombs can be made of different types of materials, such as metal, wood, polymer and ceramics or a combination of two or more of these materials. For instance, foams of polymer inside the honeycomb and thin metal on the outside will give a much more stiff/stabile construction so that the wall thickness of the metal can be made even thinner to obtain an even more light-weight structure. When honeycombs are used in load-bearing structures it is important to understand the mechanical behavior of these two-dimensional structures, illustrated as hexagonal honeycomb-structures in Figure 14.3. Besides, many natural three-dimensional cellular solids (for instance wood) that normally are too complex to be treated can be idealized and analyzed as honeycomb-structures. 14.2. In-plane deformation properties, uniaxial loading of hexagonal honeycombs The study of the in-plane (also called transversal) properties will highlight the different deformation and failure mechanisms of the cellular solids. In-plane properties are defined as (the stiffness and strength) properties in the X1 − X2 plane, see Figure 14.4. 183

σ2 σ1

σ1 σ2

Figure 14.4: Honeycombstructure loaded in X1 or X2 −direction. In-plane compression of honeycombs gives us first a bending of the cell walls and we obtain a linear elastic deformation. If the compression increases beyond a critical strain the cell walls will undergo collapse by elastic buckling, plastic yielding, creep or brittle fracture depending on the type material the cell wall is made of. If the honeycomb is exposed for tension the cell walls first bend but they will not obtain elastic buckling. Instead the cell walls will show extensive plasticity and if the cells are brittle it will fracture. The in-plane stiffness and strength are the lowest ones because in this plane the cell walls will bend. We will study only the linear-elastic deformation case of a hexagonal honeycomb in uniaxial loading in detail. The study of in-plane properties highlights the mechanisms by which cellular solids deform and fail. 14.2.1. Linear-elastic deformation If the hexagonal honeycomb is regular (all angles θ are 30◦ , and wall thicknesses are equal as Figure 14.5 shows), then the in-plane properties are isotropic. This means that the in-plane properties of the honeycomb can be described by only two independent elastic moduli, for instance by Young’s modulus E ∗ and a shear modulus G∗ . The notation ∗ means the effective value. If the honeycomb is not ∗ ∗ regular, the in-plane properties is described with four moduli (e.g. E1, E2, G∗ 12 and ν ∗ ). Here, ν ∗ is the Poisson’s ratio. If the general hexagonal honeycomb 12 12 (arbitrary cell wall angle θ) has a low relative density, ρ∗ /ρo , (t/l is small) we have 184

Figure 14.5: A regular hexagonal honeycomb. that
t h ( + 2) ρ∗ l l . ≈ ρo 2 cos θ( h + sin θ) l

(14.3)

When the honeycomb is regular (h = l and θ = 30◦ ), see Figure 14.5, then (14.3) is reduced to µ1¶ t h t ( + 2) (1 + 2) t 2 ρ∗ l l l2 l = √3 = = √ 1 h ρo l 3 2 cos θ( l + sin θ) l2 2 2 (1 + 1 ) 2 which holds when strains are less than 20% or t/l is small. The response of the honeycomb when loaded in x 1 − or x 2 −direction (see Figure 14.4), is bending of the cell walls (see Figure 14.6), and is described by five ∗ ∗ moduli: two Young’s moduli E1 and E2 , a shear modulus G∗ and two Poisson’s 12 ratio ν ∗ and ν ∗ . The reciprocal relation (according to Ashby) 12 21
∗ ∗ E1 ν ∗ = E2 ν ∗ 21 12

(14.4)

where ν ∗ is the negative ratio of the strain in the x 2 − direction to that in the 12 x 1 −direction for normal loading in the x 1 −direction, reduces the five not independent moduli to four independent moduli. (According to Meidell & Lukkassen, ) ν∗ ν∗ 21 = 12 which gives that ν ∗ E2 = ν ∗ E1 21 12 E1 E2 185

σ2 σ1 σ1

x2
x1

x2

σ2

x1

Figure 14.6: Honeycomb deformed by normal stresss when loaded in X1 and X2 . When loading in x 1 − or x 2 − direction, respectively, the four independent moduli are described as µ ¶3 ∗ E1 cos θ t ¢ ¡h , (14.5) = Eo l + sin θ sin2 θ l ¢ µ ¶3 ¡ h ∗ + sin θ E2 t l = , (14.6) Eo l cos3 θ ν∗ = − 12 and ν∗ 21 ε2 cos2 θ ¢ = ¡h ε1 + sin θ sin θ l (14.7)

¢ ¡h + sin θ sin θ ε1 =− = l . (14.8) ε2 cos2 θ For regular hexagonal honeycombs, the two Young’s moduli will be reduced to µ ¶3 ∗ ∗ E1 E2 t = = 2.3 , Eo Eo l and the two Poisson’s ratio will be reduced to ν ∗ = ν ∗ = 1. The honeycomb 12 21 exposed to a shear stress is shown in Figure 14.7. It is possible to show that the shear moduli G∗ to be 12 ¢ ¡h µ ¶3 + sin θ t G∗ 12 , = ¡ h ¢2 l Eo l (1 + 2h/l) cos θ l 186

τ
x2

τ

x1

Figure 14.7: Honeycomb deformated by shear stress. which for regular honeycombs is reduced to µ ¶3 ∗ G∗ t 1 E1 12 = 0.57 = Eo l 4 Eo which correctly obeys the relation E 2 (1 + ν)

G= for isotropic solids.

14.3. Out-of-plane deformation properties Out-of-plane properties are defined as (the stiffness and strength) properties in the x 3 -plane, see Figure 14.8. The function of a honeycomb core in a sandwich panel is to carry the shear and normal loads in the x 3 -direction. When honeycombs are loaded either along the x 3 −plane or in out-of-plane shear they are much stiffer and stronger than if they are loaded in in-plane. Out-of-plane tension and compression loading of a honeycomb imply that the cell walls undergo only axial extension or compression and therefore the moduli, collapse stresses, and strength will be much larger. Also in the out-of-plane case we will only consider the linear-elastic deformation case, as we did in the in-plane case. The out-of-plane analysis gives the additional stiffness which is needed for the design of honeycomb cores in sandwichpanels, and for the description of the behavior of natural honeycomb-like material, such as wood.

187

Figure 14.8: A honeycomb with out-of-plane loads (faces normal to X3 − direction). 14.3.1. Linear-elastic deformation A total of nine moduli are needed to describe the out-of-plane deformation, that ∗ ∗ means five new ones in addition to the four already described (E1 , E2 , G∗ and 12 ∗ ∗ υ 12 ). We will now find the five new moduli. The Young’s modulus E3 , for normal loading in the x3 -direction is obviously the same as the Young’s modulus for the outer material, Eo , scaled by the loadbearing section area
∗ E3 ρ∗ t = ≈ . Eo ρo l

The next two Poisson’s ratio are equal to the solid itself υ∗ = υ∗ = υo , 31 32 and the Poisson’s ratio υ ∗ and υ ∗ are found from the reciprocal relations (see 13 23 [5], p. 498) E∗ E∗ υ ∗ = 1 υ o ≈ 0, υ ∗ = 2 υ o ≈ 0. 13 23 ∗ ∗ E3 E3 The shear moduli are more complicated to find because of the non-uniform deformation in the cell walls due to stress distribution in the honeycomb. The plane honeycomb may not remain plane, and exact calculations may only be done using numerical methods. But, we can obtain upper and lower bounds for the two shear moduli, with the help of the method in [23], by calculating the strain energy 188

which are identically, and therefor we have an exact solution. For the regular hexagon we obtain that µ ¶ G∗ t 13 . (14.9) = 0.577 Go l The upper and lower bounds for G∗ , respectively: 23 µ ¶ G∗ 1 h/l + 2 sin2 θ t 23 ≤ , Go 2 (h/l + sin θ) cos θ l µ ¶ G∗ h/l + sin θ t 23 ≥ Go (1 + 2h/l) cos θ l

associated first with the strain distribution and next by the stress distribution (see [5], p. 149). If the two coincide, the solution is exact, but if not the true solution lies somewhere in between the upper and lower bound. We will only give the results here, for more information see [5], p. 150. The upper and lower bounds for G∗ , respectively: 13 µ ¶ cos θ G∗ t 13 , ≤ Go h/l + sin θ l µ ¶ t G∗ cos θ 13 ≥ Go h/l + sin θ l

which are not identically. They will not coincide for a general, anisotropic honeycomb but for a regular hexagon they are reduced to µ ¶ G∗ t 23 . (14.10) = 0.577 Go l We see that (14.9) and (14.10) are identical, which confirms that regular hexagons are isotropic in the x 1 −x 2 plane. The out-of plane shear moduli vary linearly with the relative density (t/l) and are therefore larger that the in-plane moduli by the factor (t/l)2 . Now we have all the parameters describing the orthrotropic structure, and we can put them into the matrix 18.5 in order to find the compliance matrix (the inverse of the stiffness matrix). Questions • What is relative density? 189

• Show that relative density is the same as volume fraction. Assume air inside the cell. • Show that if the hexagonal honeycomb has a low relative density, ρ∗ /ρo , (t/l is small) then
t h ( + 2) ρ∗ l l . ≈ ρs 2 cos θ( h + sin θ) l

• If the relative density of a square honeycomb is 0.8, what is the wall-thickness of the honeycomb? • If the volume fraction of a hexagonal honeycomb is 0.8, what is the wall-thickness of the honeycomb? • When is simple beam theory valid, according to Ashby & Gibson? • What is the difference between in-plane and out-of-plane properties of a honeycomb structure? • If a hexagonal honeycomb is regular (wall thicknesses are equal), are the in-plane properties isotropic? • What does isotropic mean? • If the honeycomb is irregular and anisotropic, how many moduli for a complete description of the in-plane properties is needed? • What is the definition of Poisson’s ratio?

190

Part IV

Mechanics and Effective Properties of Composite Structures and Honeycombs
15. On effective Properties of Composite Structures
Strongly non-homogeneous structures have fascinated people for a very long time. Archaeological observations in Finland show that fibre- reinforced ceramics were made about 4000 years ago, and that people already at this time had ideas and theories for intelligent combinations of materials and structures. Analysis of the macroscopic properties of composites was initiated by the physicists Raleigh, Maxwell and Einstein. Around 1970 one managed to formulate the physical problems of material structures and composites in such a way that this field became interesting from a purely mathematical point of view. This formulation initiated a new mathematical discipline called homogenization theory. Independently of this development scientists within the field of micro-mechanics have developed their own theory concerning the mechanics of composites and structures. By using these theories we can determine locale and global (effective) properties of inhomogeneous structures which are too complex to be treated by conventional computational methods. The theories make it possible to design material structures with optimal properties with respect to weight, strength, stiffness, heat conductivity, electric conductivity, magnetic permeability, viscosity etc. Almost all literature on this field assumes relatively high knowledge in mathematics. However, in this paper we give a short introduction to the theory which require physical intuition rather than deep theoretical understanding. We hope this treatment makes it easier to understand some basic aspects of the theory for a broader audience, especially people with background in engineering.

16. The thermal problem
The heat flow in the direction of decreasing temperature. Moreover, for isotropic materiels, the velocity v of the heat flow is proportional to the gradient of the

191

temperature, i.e. ⎡ ∂u ⎤ ∙ ¸T λ ∂x1 ∂u ∂u ∂u ∂u v = −λ grad u (= − λ ,λ ,λ = − ⎣ λ ∂x2 ⎦), ∂x1 ∂x2 ∂x2 ∂u λ ∂x2

where u is the temperature and λ is called the conductivity. Assuming no heat source in the body and no dependence of time, a simple application of the divergence theorem (Gauss theorem) shows that div v = 0, (recall that div v = ∂v1 ∂v2 ∂v3 + + ). ∂x1 ∂x2 ∂x3

Some materials have different effective conductivities in each direction. This means that the velocity v of the heat flow can be written as ∙ ¸T ∂u ∂u ∂u v = − λ11 , λ22 , λ33 , ∂x1 ∂x2 ∂x2 or even more generally as v = −A grad u, where A a symmetric matrix of the form ⎤ ⎡ λ11 λ12 λ13 A = ⎣ λ12 λ22 λ23 ⎦ . λ13 λ23 λ33

(which is constant). This matrix is found as follows. Imagine that the composite is subjected to a homogeneous temperature-field, that is a temperature-field such that the average value hgrad ui of grad u is constant. Letting hvi be the average value of v = −A grad u we can obtain A∗ from the relation hvi = A∗ hgrad ui . 192

In a composite material we distinguish between the local conductivity A (which varies locally) and the effective conductivity ⎤ ⎡ ∗ λ11 λ∗ λ∗ 12 13 A∗ = ⎣ λ∗ λ∗ λ∗ ⎦ 12 22 23 λ∗ λ∗ λ∗ 13 23 33

The average is taken over some representative domain Y of the composite. In general this volume should be much larger than the typical length-scale of the material (e.g. fiber-diameter), but in the case of periodic materials we can as well let Y be the cell of periodicity. Roughly speaking the effective conductivity matrix A∗ is the matrix of a corresponding homogeneous material with the same ”effective” thermal properties as the actual composite. In particular, the ”the thermal energy” in Y of the actual composite is equal to ”the thermal energy” in the corresponding homogeneous material, i.e. Z 1 1 (16.1) (grad u · A grad u) dv = hgrad ui · A∗ hgrad ui |Y |. 2 Y 2 {z } {z } | |
thermal energy in the composite thermal energy in corresponding homogenized material.

For example, if we want to find λ∗ we impose the thermal field such that hgrad ui = 11 [1, 0, 0]T then measure the energy W inside Y and obtain λ∗ from (16.1): 11 λ∗ = 2 11 W . |Y |

17. Isotropic elastic materials
For an isotropic material the shear modulus G and bulk modulus K in plane elasticity (plane strain) are related to the well known Young’s modulus E and Poisson’s ratio ν as follows: K= E , 2 (1 + ν) (1 − 2ν) E . 2 (1 + ν)

G=

The bulk modulus k of the three-dimensional theory is given by k= E 1 . 3 1 − 2ν G . 3

Thus the plane strain bulk modulus K can be expressed as K =k+ 193

If the material is a thin plate, we consider the plane-stress problem. In this case the plane stress bulk modulus is expressed as µ ¶ E 1 K= . 2 1−ν The shear modulus G is independent of the dimension and also independent of whether we are dealing with the plane-strain -or plane stress problem.

18. Orthotropic composites
Consider a linear elastic composite material in R3 which is locally orthotropic, and globally orthotropic. This means that in each point of the structure we have that the stress-strain relation is given as ⎡ ⎤ ⎡ ⎤⎡ ⎤ σ 11 e11 C1111 C1122 C1133 0 0 0 ⎢ σ 22 ⎥ ⎢ C2211 C2222 C2233 0 0 0 ⎥⎢ e22 ⎥ ⎢ ⎥ ⎢ ⎥⎢ ⎥ ⎢ σ 33 ⎥ ⎢ C3311 C3322 C3333 0 0 0 ⎥⎢ e33 ⎥ ⎢ ⎥ ⎢ ⎥⎢ ⎥ ⎢ σ 12 ⎥ = ⎢ 0 0 0 C1212 0 0 ⎥⎢ γ 12 ⎥ ⎢ ⎥ ⎢ ⎥⎢ ⎥ ⎣ σ 23 ⎦ ⎣ 0 0 0 0 C2323 0 ⎦⎣ γ 23 ⎦ 0 0 0 0 0 C1313 σ 13 γ 13 | {z } | {z }| {z }
σ C e

and the average stress-strain relation of the form ⎡ ⎢ ⎢ ⎢ ⎢ ⎢ ⎢ ⎣ i.e. | hσ 11 i hσ 22 i hσ 33 i hσ 12 i hσ 23 i hσ 13 i {z
hσi

⎥ ⎢ ⎥ ⎢ ⎥ ⎢ ⎥=⎢ ⎥ ⎢ ⎥ ⎢ ⎦ ⎣ } |

∗ ∗ ∗ C1111 C1122 C1133 0 0 0 ∗ ∗ ∗ C2211 C2222 C2233 0 0 0 ∗ ∗ ∗ C3311 C3322 C3333 0 0 0 ∗ 0 0 0 C1212 0 0 ∗ 0 0 0 0 0 C2323 ∗ 0 0 0 0 0 C1313 {z C∗

⎤⎡ ⎥⎢ ⎥⎢ ⎥⎢ ⎥⎢ ⎥⎢ ⎥⎢ ⎦⎣ }|

he11 i he22 i he33 i hγ 12 i hγ 23 i hγ 13 i {z
hei

⎥ ⎥ ⎥ ⎥, ⎥ ⎥ ⎦

(18.1)

} (18.2)

σ = Ce, hσi = C ∗ hei .

194

Here we assume equilibrium of stresses in each direction: ∂σ 11 ∂σ 12 ∂σ 13 + + = 0, ∂y1 ∂y2 ∂y3 ∂σ 21 ∂σ 22 ∂σ 23 + + = 0, ∂y1 ∂y2 ∂y3 ∂σ 31 ∂σ 32 ∂σ 33 + + = 0. ∂y1 ∂y2 ∂y3 where σij = σ ji (obtained by applying Gauss theorem as for the heat problem) These equations follows if we assume that the net force is 0. The symbol h·i denotes the average taken over some representative domain Y of the composite. In general this volume should be much larger than the typical length-scale of the material (e.g. fiber-diameter), but in the case of periodic materials we can as well let Y be the cell of periodicity. Roughly speaking the effective stiffness matrix C ∗ is the matrix of a corresponding homogeneous material with the same ”effective” properties as the actual composite. In particular, the actual strain energy stored in Y is equal to the strain energy stored in the corresponding homogeneous material, i.e. Z 1 1 = (18.3) (e · Ce) dv hei · C ∗ hei |Y | . 2 2 {z } | {z } |Y
strain energy in the composite strain energy in corresponding homogenized material.

∗ Example 18.1. If we want to find C1111 we stretch the periodic structure in such a way that average strain hei = [1, 0, 0, 0, 0, 0]T , then measure (or compute) the average stress hσi = [hσ 11 i , hσ 22 i , hσ 33 i , hσ 12 i , hσ 23 i , hσ 13 i]T and finally compute ∗ ∗ the coefficient C1111 from (18.1) which gives us that C1111 = hσ 11 i . Equivalently, we can ask the FE-program to compute the strain energy W (the left side of ∗ (18.3)) and then compute C1111 from (18.3), i.e. we obtain Z 1 1 1 ∗ (e · Ce) dv = [1, 0, 0, 0, 0, 0]T · C ∗ [1, 0, 0, 0, 0, 0]T |Y | = C1111 |Y | , 2 2 2 {z } |Y strain energy in the composite

thus

∗ C1111 =

2(strain energy) . |Y | 195

The stiffness matrix is symmetric and the elements may be expressed as follows (see e.g. [32]):
∗ C1111 = ∗ C2222 ∗ C1212

1 − ν∗ ν∗ ν∗ + ν∗ ν∗ ν∗ + ν∗ ν∗ 23 32 ∗ ∗ , C1122 = 21 ∗ 31∗ 23 , C1133 = 31 ∗ 21∗ 32 ∗ ∗ ∆E2 E3 ∆E2 E3 ∆E2 E3 1 − ν∗ ν∗ ν∗ + ν∗ ν∗ 1 − ν∗ ν∗ 13 31 12 21 ∗ ∗ = , C2233 = 32 ∗ 12∗ 31 , C3333 = (18.4) ∗ ∗ ∗ ∗ ∆E1 E3 ∆E1 E3 ∆E1 E2 ∗ ∗ = G∗ , C2323 = G∗ , C1313 = G∗ , 12 23 13 ∆= 1 − ν ∗ ν ∗ − ν ∗ ν ∗ − ν ∗ ν ∗ − 2ν ∗ ν ∗ ν ∗ 12 21 23 32 31 13 21 32 13 . ∗ ∗ ∗ E1 E2 E3

where

Here, ’Ei∗ ’ are the effective Young’s moduli, ’G∗ ’ are the effective shear moduli ij and ’ν ∗ ’ are the effective Poisson’s ratios. The inverse of the effective stiffness ij matrix (the compliance matrix) which (certainly) also is symmetric is given by ⎤ ⎡ ν∗ ν∗ 1 − E12 − E13 0 0 0 ∗ ∗ ∗ 2 3 ⎥ ⎢ E1ν ∗ ν∗ ⎢ − 21 1∗ − E23 0 0 0 ⎥ ∗ ∗ ⎥ ⎢ E∗1 E2 ∗ 3 ⎥ ⎢ ν 31 ν 1 0 0 0 ⎥ ⎢ − E ∗ − E32 E ∗ ∗ 1 2 3 (18.5) ⎥. ⎢ 1 ⎢ 0 0 0 ⎥ 0 0 G∗ ⎥ ⎢ 12 1 ⎢ 0 0 0 0 0 ⎥ ∗ ⎦ ⎣ G23 1 0 0 0 0 0 G∗
13

19. Square symmetric unidirectional two-phase structure
In the case of square honeycombs with locally isotropic material properties (local shear moduli Go and GI and local plane strain bulk moduli Ko and KI with corresponding volume fractions po and pI , respectively, where the subscript o and I denote outer and inner material, respectively (see Figure 19.1), the stiffness matrix reduces to a matrix of the form: ⎤ ⎡ ∗ K + G∗ K ∗ − G∗ l∗ 0 0 0 T T ⎢ K ∗ − G∗ K ∗ + G∗ l∗ 0 0 0 ⎥ T T ⎥ ⎢ ∗ ⎢ l l∗ n∗ 0 0 0 ⎥ ⎥. ⎢ (19.1) ⎢ 0 0 0 G∗ 0 ⎥ T,45 0 ⎥ ⎢ ⎣ 0 0 0 0 G∗ 0 ⎦ L 0 0 0 0 0 G∗ L 196

Figure 19.1: The structure of square honeybombs with locally isotropic material properties.

Figure 19.2: The 4 moduli measure resistence against the indicated average strains. Here, K ∗ is the effective transverse (also called ”in-plane”) bulk modulus, G∗ , T G∗ are the effective transverse shear moduli and G∗ is the longitudinal (also T,45 L called ”out-of plane”) shear modulus, see Figure 19.2. In this case the compliance matrix reduces to

197

Using (18.4) and the symmetry we obtain the relations G∗ T
∗ ET = 2 (1 + ν ∗ ) T

⎢ ⎢ ⎢ ⎢ ⎢ ⎢ ⎢ 0 ⎢ ⎢ 0 ⎣ 0

1 ∗ ET ν∗ − ET ∗ T ν∗ L − E∗ L

− ET ∗

ν∗

T

1 ∗ ET ν∗ − EL ∗ L

− EL ∗ − EL ∗
1 ∗ EL ν∗

ν∗

0 0 0
1 G∗ T,45

0 0 0 0
1 G∗ L

0 0 0 0 0
1 G∗ L

L L

0

0 0 0

0 0

0 0

0

⎥ ⎥ ⎥ ⎥ ⎥ ⎥. ⎥ ⎥ ⎥ ⎦

(19.2)

(19.3) (19.4) (19.5)

4 1 1 4 (ν ∗ )2 L = ∗ + ∗+ . ∗ ∗ ET GT K EL
∗ l∗ = ν ∗ 2K ∗ , n∗ = EL + 4 (ν ∗ )2 K ∗ L L

Moreover, it has been proved by Hill [11] that 1 1 4(ν o − ν I )2 1 ∗ EL = po Eo + pI EI + ³ + pI − ∗ ), ´2 (po Ko KI K 1 1 − KI Ko ν ∗ = po ν o + pI ν I − L νo − νI 1 1 1 + pI − ∗ ). 1 1 (po Ko KI K − KI Ko (19.6)

(19.7)

These two formulae were proved in [11] for the case of transverse isotropy. However, by following the proof in [11] it is easy to check that the same facts hold in our case. 19.1. Calculation of stiffness and compliance matrix We remark that (19.3), (19.4), (19.5), (19.6) and (19.7) hold for all two-component unidirectional fiber composite (orientated in the direction x3 ) satisfying the property of square symmetry, i.e. the case when the stiffness matrix is of the form (19.1) (we say that the composite satisfies the property of transverse isotropy if G∗ = G∗ , see Figure 19.3). In order to compute all components stiffness maT T,45 trix (19.2) we only have to compute (e.g. numerically by using the finite element method) the four components G∗ , G∗ , G∗ , and K ∗ . The other two moduli L T T,45 198

Figure 19.3: Hexagonal honeycomb. Exampel of structure satisfying the property of transverse isotropy (i.e G∗ = G∗ ). T T,45
∗ l∗ and n∗ are the found by inserting the values of EL (19.6) and ν ∗ (19.7) into L ∗ ∗ (19.5). If we also want to know ET and ν T we can evaluate these values by first ∗ evaluating ET from (19.4) and finally ν ∗ from (19.3). T It is possible to show that G∗ can be found exactly as the effective conductivity L in the similar 2-dimensional problem by letting Go and GI play the same role as the local conductivity for that problem.

Exercise 19.1. Consider square symmetric unidirectional two-phase composite with volume-fractions pI = po = 1/2, Poissons ratios ν I = ν o = 0.3 and Youngs modulus EI = 0.5, Eo = 1.(no units) 1. Find KI , Ko , GI , Go . 2. By performing a FE-calculation it is possible to find the following effective moduli: K ∗ = 0.658455, G∗ = 0.273775, T ∗ GT,45 = 0.259418, G∗ = 0.274426. L Find the effective stiffness matrix C ∗
∗ ∗ 3. Find also ν ∗ , EL , ET and ν ∗ . and find the effective compliance matrix. L T

199

20. Numerical methods for periodic structures
In order to use conventional software to solve displacement field numerically for periodic structures, e.g. by the finite element method, it is often necessary to ”translate” the information of the average strain hei into equivalent boundary conditions for the on the cell of periodicity Y = h0, y1 i h0, y2 i h0, y3 i for the displacement ⎤ u1 u = ⎣ u2 ⎦ . u3 ⎡

This is obtained by letting each pair of points (xl− , xl+ ) (the latter point with the largest coordinates) on opposite faces with normal vector nl be coupled to each other in such a way that ⎤ ⎡ ⎤ ⎡ ⎤ ⎡ u1 (xl− ) c1l u1 (xl+ ) ⎣ u2 (xl+ ) ⎦ = ⎣ u2 (xl− ) ⎦ + ⎣ c2l ⎦ , (20.1) u3 (xl+ ) u3 (xl− ) c3l where ⎤ c1l ⎣ c2l ⎦ c3l ⎡

is a constant vector. By integrating along the normal vector nl we obtain that À ¿ uk (xl+ ) − uk (xl− ) ∂uk ckl = = , ∂xl yl yl thus, recalling that ekk = γ kl ∂uk ∂xk ∂uk ∂ul = + ∂xl ∂xk

we obtain the following useful relation ckk = hekk i yk 200

Figure 20.1: The Y -cell in the symmetric case. ckl clk + = hγ kl i . yl yk Hence ckk = yk hekk i . Observe that ckl and clk are not uniquely determined by this relation when k 6= l. Thus in this case these constants can be chosen independently (as long as (20.2) is satisfied). E.g. we can choose ckl = clk =
1 yl

(20.2)

hγ kl i . + y1k

(20.3)

If the material properties are symmetric in each coordinate with respect to the midpoint ((1/2)y1 , ..., (1/2)yn ) of the Y -cell problem (see Figure 20.1) then we can often use simpler boundary conditions than (20.1). For example, in the case when all average shear strains hγ kl i = 0, we can in (20.1) use the Dirichlet condition ul (xl− ) = 0, ul (xl+ ) = cll (= yl hell i), l = 1, 2, 3, (20.4)

and drop all the other boundary conditions. The latter is equivalent with setting a Neumann condition, ∂ui /∂xl = 0, i 6= l on the same faces. It is easy to see physically that these simplified boundary conditions hold by considering the deformation of the whole periodic structure, since it is obvious that the solution (which indeed represents the deformed body) must inherit the same symmetry as the material itself (see Figure 20.2). Moreover, in the case when all average normal strains hekk i = 0, we can in (20.1) use the Dirichlet condition ui (xl− ) = 0, ui (xl+ ) = cil (= 201
1 yl

hγ il i 1 ), + yi

i 6= l

(20.5)

Figure 20.2: Deformation of the periodic structure in the symmetric case. and drop all the other boundary conditions. The latter is equivalent with setting a Neumann condition, ∂ui /∂xi = 0, i 6= l for l = 1, 2, 3 on the same faces. The boundary conditions for the conductivity case can be simplified in the same way. 20.1. Coordinate transformation For the computation of effective moduli it is sometimes convenient to rotate the original coordinate system. Consider an orthonormal coordinate system with basis vectors n1 = [n11 , n12 , n13 ] n2 = [n21 , n22 , n23 ] n3 = [n31 , n32 , n33 ] . A vector with coordinates x = (x1 , x2 , x3 ) (relative to the usual coordinate system) will have coordinates x0 = (x01 , x02 , x03 ) (relative to the new coordinate system) given by the relation ⎤⎡ ⎤ ⎡ 0 ⎤ ⎡ x1 x1 n11 n12 n13 ⎣ x02 ⎦ = ⎣ n21 n22 n23 ⎦ ⎣ x2 ⎦ x03 n31 n32 n33 x3 (see Figure 20.3). It is possible to show that the following relation between the ¤T £ strain e = e11 , e22 , e33, γ 12 , γ 23, γ 13 , γ ij = 2eij (in the usual coordinate system) £ ¤T and e0 = e011 , e022 , e033, γ 012 , γ 023 , γ 013 , γ 0ij = 2e0ij (in the new coordinate system): e0 = Te, 202

Figure 20.3: The two coordinate systems. where ⎡ n2 n2 n2 n11 n12 n12 n13 n11 n13 11 12 13 2 2 2 n21 n22 n23 n21 n22 n22 n23 n21 n23 2 2 2 n31 n32 n33 n31 n32 n32 n33 n31 n33 2n11 n21 2n12 n22 2n13 n23 n11 n22 + n21 n12 n12 n23 + n22 n13 n11 n23 + n21 n13 2n21 n31 2n22 n32 2n23 n33 n21 n32 + n31 n22 n22 n33 + n32 n23 n21 n33 + n31 n23 2n11 n31 2n12 n32 2n13 n33 n11 n32 + n31 n12 n12 n33 + n32 n13 n11 n33 + n31 n13 ⎤

⎢ ⎢ ⎢ T=⎢ ⎢ ⎢ ⎣

Moreover, we can obtain a similar relation between the corresponding stresses σ and σ 0 : σ 0 = T−T σ, where T−T is obtained from T by changing the factors of 2 in T symmetrically about the diagonal, i.e. ⎡ n2 n2 n2 2n11 n12 2n12 n13 2n11 n13 11 12 13 2 2 ⎢ n2 n22 n23 2n21 n22 2n22 n23 2n21 n23 21 ⎢ ⎢ n2 n2 n2 2n31 n32 2n32 n33 2n31 n33 31 32 33 T−T = ⎢ ⎢ n11 n21 n12 n22 n13 n23 n11 n22 + n21 n12 n12 n23 + n22 n13 n11 n23 + n21 n13 ⎢ ⎣ n21 n31 n22 n32 n23 n33 n21 n32 + n31 n22 n22 n33 + n32 n23 n21 n33 + n31 n23 n11 n31 n12 n32 n13 n33 n11 n32 + n31 n12 n12 n33 + n32 n13 n11 n33 + n31 n13 The stress-strain relation in the new coordinate system can therefore be written as: σ0 = C 0 e0 , 203

⎥ ⎥ ⎥ ⎥. ⎥ ⎥ ⎦

⎥ ⎥ ⎥ ⎥. ⎥ ⎥ ⎦

where C = TT C 0 T. Concerning these facts we refer to e.g. [3, p. 212]. In the plane strain case we put all strains related to the x3 -variable equal to 0. If we also assume that the new coordinate system is obtained from the standard one by a rotation in the x1 -x2 -plane then we obtain the following simplified relations: ⎤ ⎡ C1111 C1122 C1112 C = ⎣ C2211 C2222 C2212 ⎦ , C1211 C1222 C1212 ⎤ ⎡ n2 n11 n12 n2 11 12 ⎦, n2 n21 n22 T = ⎣ n2 21 22 2n11 n21 2n12 n22 n11 n22 + n21 n12 ⎤ ⎡ n2 2n11 n12 n2 11 12 ⎦. n2 2n21 n22 T−T = ⎣ n2 21 22 n11 n21 n12 n22 n11 n22 + n21 n12 matrix is of the form ⎤ K ∗ + G∗ K ∗ − G∗ 0 T T ⎦ C ∗ = ⎣ K ∗ − G∗ K ∗ + G∗ 0 T T ∗ 0 0 GT,45 h√ √ i (c.f. (19.1)). Performing a rotation of 45◦ , i.e. [n11 , n12 ] = 22 , 22 and [n21 , n22 ] = h √ √ i − 22 , 22 , the corresponding stiffness matrix in the rotated coordinate system becomes ⎤ ⎡ ∗ ∗ ∗ K + G∗ T,45 K − GT,45 0 ∗ ∗ ⎦, C ∗0 = T−T C ∗ T−1 = ⎣ K ∗ − G∗ (20.6) T,45 K + GT,45 0 ∗ 0 0 GT ⎡ i.e. C ∗0 is the same as C ∗ except that the shear moduli G∗ and G∗ have changed T,45 T place. This explains the use of the index ”45” and shows that we can calculate G∗ exactly as we calculate G∗ except by rotating the coordinate system 45◦ . T,45 T 204

As an example, let us consider the square symmetric case, i.e. when the stiffness

Exercise 20.1. Verify (20.6) by calculating C ∗ = TT C ∗0 T Exercise 20.2. Let ⎤ K ∗ + G∗ K ∗ − G∗ 0 C ∗0 = ⎣ K ∗ − G∗ K ∗ + G∗ 0 ⎦ 0 0 G∗ ⎡ TT C ∗0 T =C ∗0 . (20.7)

By matrix-multiplication it is possible to obtain that

for any orthonormal coordinate system [n11 , n12 ] = [cos φ, sin φ] , [n21 , n22 ] = [− sin φ, cos φ] This is done by simplifying each of the elements of the matrix. For example we find that ¡ T ∗0 ¢ T C T 11 = n4 K ∗ + n4 G∗ + 2n2 n2 K ∗ + 2n2 n2 G∗ + n4 k + n4 G∗ 11 11 11 21 11 21 21 21

Verify that (20.7) holds for this element. (Note that (20.7) explains why composites with this type of effective stiffness matrixes are called transversely isotropic). Solution: ¡ ¡ ¢ ¢2 ¡ T ∗0 ¢ = T C T 11 = (K ∗ + G∗ ) n4 + 2n2 n2 + n4 = (K ∗ + G∗ ) n2 + n2 11 11 21 21 11 21 ¡ 2 ¢2 = (K ∗ + G∗ ) cos φ + sin2 φ = (K ∗ + G∗ ) 12 = (K ∗ + G∗ ) .

Exercise 20.3. Consider the same square symmetric unidirectional two-phase composite in Exercise 19.1. Suppose that the composite is used as core material in a sandwich construction. How should we direct the fibres in order to maximize the stiffness of the sandwich (compare the three alternatives in Figure 20.4). Solution: The deflection of the sandwich due to shear deformation in the core is dependent of G∗ (in alternative 1), G∗ (in alternative 2) and G∗ (in L T T,45 alternative 3), where these parameters correspond ti the same coordinate system as in 19.1). Using the values we see that alternative 1 is (insignificantly) better than alternative 2 which is better than alternative 3. (For example when calculating the deflection of a sandwich beam of type alternative 1 we use the same formulae as in the isotropic case by using G = G∗ as the shear modulus of the core and the L same goes for alt. 2 and alt. 3). 205

Figure 20.4: Sandwich plate with three alternative cores.

21. A computational example
In the case of square honeycombs with locally isotropic material properties (see Figure 19.1) the structure is symmetric with respect to the midpoint of the Y -cell Y = [−1, 1]3 in all the coordinates x1 , x2 , x3 , and also in the coordinates x01 , x02 , x3 in the coordinate system obtained by a rotation of 45◦ in the x1 -x2 -plane. The effective stress/strain-relation (18.1) reduces in this case to ⎡ ⎤ ⎡ ∗ ⎤ ⎤⎡ K + G∗ K ∗ − G∗ l∗ 0 0 0 he11 i hσ 11 i T T ⎢ hσ 22 i ⎥ ⎢ K ∗ − G∗ K ∗ + G∗ l∗ 0 0 0 ⎥ ⎢ he22 i ⎥ T T ⎢ ⎥ ⎢ ∗ ⎥ ⎥⎢ ⎢ hσ 33 i ⎥ ⎢ l l∗ n∗ 0 0 0 ⎥ ⎢ he33 i ⎥ ⎢ ⎥ ⎢ ⎥ . (21.1) ⎥⎢ ⎢ hσ 12 i ⎥ = ⎢ 0 0 ⎥ ⎢ hγ 12 i ⎥ 0 0 G∗ T,45 0 ⎢ ⎥ ⎢ ⎥ ⎥⎢ ⎣ hσ 23 i ⎦ ⎣ 0 0 0 0 G∗ 0 ⎦ ⎣ hγ 23 i ⎦ L hσ 13 i hγ 13 i 0 0 0 0 0 G∗ L

In order to compute the effective in-plane moduli K ∗ and G∗ we solve the cell T problem for hei = [1, 1, 0, 0, 0, 0, ]T and hei = [1, −1, 0, 0, 0, 0, ]T and compute the corresponding values K ∗ = hσ11 i /2 and G∗ = hσ11 i /2, respectively. Alternatively T we can compute the strain energy W and compute K ∗ and G∗ from the identity T W = 1 hei · C ∗ hei |Y | 2 206 (21.2)

(discussed in (18.3)). For the computation it is enough to solve the two-dimensional cell problem using plane strain. This is due to the fact that the solution of the three dimensional cell problem in both cases will be independent of the x3 -variable and we do not use any information of the strain or stresses in x3 -direction for the computation of K ∗ and G∗ . Because of the symmetries it suffices to solve the probT lem on 1/4 of the Y -cell, e.g. on the square Y = [0, 1]2 . Since |Y | = 1, we obtain from (21.2) that K ∗ = W/2 and G∗ = W/2. We can use uniform boundary conT ditions on each face of this square (see Section 20), i.e. for hei = [1, 1, 0, 0, 0, 0, ]T the boundary conditions are : u1 (0, x2 ) = u2 (x1 , 0) = 0, u1 (1, x2 ) = u2 (x1 , 1) = 1 and for hei = [1, −1, 0, 0, 0, 0, ]T : u1 (0, x2 ) = u2 (x1 , 0) = 0, u1 (1, x2 ) = 1 u2 (x1 , 1) = −1 (this follows from (20.4)). Due to symmetries the module G∗ can be found T,45 exactly as G∗ except that we must rotate the coordinate system 45◦ (see the last T part of Section 20.1). Alternatively we can compute G∗ more directly by solving the cell problem T,45 T for hei = [0, 0, 0, 1, 0, 0] and computing the corresponding value G∗ = hσ12 i · 1, T,45 or equivalently, compute the strain energy W and find G∗ from the identity T,45 (21.2) (with |Y | = 1), which gives G∗ = 2W . In this case we use the following T,45 boundary conditions on each face of the square ( according to (20.5)) u2 (0, x2 ) = u1 (x1 , 0) = 0, 1 u2 (1, x2 ) = u1 (x1 , 1) = . 2 The module G∗ can be found by using hei = [0, 0, 0, 0, 0, 1]T and computing L the corresponding value G∗ = hσ 13 i . The problem with doing this is that it often L requires a full 3D FE-computation regardless of the fact that the solution of the cell problem is independent of the x3 -variable. Therefore it is often easier to solve the corresponding 2D heat-conductivity problem (see Subsection 19.1) with

207

boundary conditions u(0, x2 ) = 0 u(1, x2 ) = 1 using Go and GI as ”thermal conductivities” and computing G∗ from the thermal L energy W (16.1), which gives G∗ = 2W. L Once we have computed the 4 moduli K ∗ , G∗ , G∗ , and G∗ we can easily T T,45 L obtain all the other moduli (see Subsection 19.1). As an example, consider a square honeycomb structure (see Figure 19.1) with volume fractions pI = po = 1/2 and locally isotropic material properties ν I = ν o = 0.3, EI = 0.5, Eo = 1 (or equivalently KI = 0. 48076923, Ko = 0. 96153846, GI = 0. 19230769, Go = 0.38461538). By performing a FE-calculation according to the above method we obtain the following effective moduli: K ∗ = 0.658455, G∗ = 0.273775, T ∗ GT,45 = 0.259418, G∗ = 0.274426. L Hence, by using (19.3), (19.4), (19.6) and (19.7) we obtain that ν∗ L ∗ EL ∗ ET ν∗ T and by (19.5) l∗ = 0. 39507, n∗ = 0.98704. Thus the effective stiffness matrix is written as = = = = 0.3, 0.75, 0.70779659, 0.29266111,

208

⎡ ⎢ ⎢ ⎢ ⎢ ⎢ ⎢ ⎣

0.932226 0.384677 0.39507 0 0 0 0.384677 0.932226 0.39507 0 0 0 0.395072 0.395072 0.98704 0 0 0 0 0 0 0.259418 0 0 0 0 0 0 0.274426 0 0 0 0 0 0 0.274426

and the effective compliance matrix (19.2) takes the form ⎡ ⎢ ⎢ ⎢ ⎢ ⎢ ⎢ ⎣ 1.41284 −0.413482 −0.4 0 0 0 −0.413482 1.41284 −0.4 0 0 0 −0.4 −0.4 1.33333 0 0 0 0 0 0 3.8548 0 0 0 0 0 0 3.64397 0 0 0 0 0 0 3.64397

⎥ ⎥ ⎥ ⎥. ⎥ ⎥ ⎦ ⎤

In this example we used the same Poisson’s ratios in both phases. Let us consider the case when ν I = 0.4, ν o = 0, EI = 0.5, Eo = 1 or equivalently KI = 0. 89285714, Ko = 0.5, GI = 0.17857143, Go = 0.5. In this case we obtain the following effective moduli: K ∗ = 0.66335 G∗ = 0.3038805 T G∗ = 0.269322 T,45 G∗ = 0.307502 L ν ∗ = 0.22386372 L ∗ EL = 0.79338859 . ∗ ET = 0.79193337 ν ∗ = 0.3030342 T

⎥ ⎥ ⎥ ⎥ ⎥. ⎥ ⎦

Remark 1. In the first example (where the Poisson’s ratios are the same in both ∗ phases) ν ∗ and EL equals the arithmetic mean of the corresponding phase propL erties (usually referred to as ”the law of mixtures”). From the last example we observe that this may not be true when the Poisson’s ratios of the phases are different. Exercise 21.1. Verify the above values for K ∗ , G∗ , G∗ , and G∗ by performing T T,45 L a FE-calculation according to the above method. Use e.g. the Finite Element Method programme ANSYS. For the calculation of K ∗ , G∗ , G∗ use Structural T T,45 problem, element type PLANE 82, element size 0.015, plane strain. For the calculation of G∗ use thermal problem, element type PLANE 77, element size L 0.015. 209

Part V

Fabrication processes
In this part we will study some of the fabrication processes concerning the materials and structures studied in Part I. In particular we consider the processes of fabricating polymers, plastics and composites. Moreover, we study some of the advanced manufacturing techniques of layer manufacturing technology (LMT). From [4], we have the rough definition of what a material processing is: ”all that is done to convert stuff into things”. Figure 21.1 gives an picture of the different general materials processing types (independent of the material types). Fabrication of an acceptable product involves the selection of both i) an appropriate material and ii) a companion method of processing, such that the resulting combination can provide the desired shape, properties, precision and finish.

22. Fabrication of plastics
The fabrication method depends on what raw material we have. Polymers are formed by many low temperature processes. It is important to know for instance whether the material is a thermoplastics or thermosetting. Thermoplastics can be heated and then formed by either a formable solid or a liquid. Thermosettings have far fewer options, because once the polymerization has occurred, the framework structure is established and no further deformation can occur. Thus the polymerization and the shape-forming are usually accomplished at the same time. We will have a closer look at some of most used fabrication processes: Casting In casting, no fillers or no pressure is required. The liquid polymer is poured into a container having the shape of the desired part. It is an inexpensive process, dimensional precision is quite high, but quality problems can occur due to inadequate mixing, air entrapment, gas evolution, and shrinkage. Typical products: sheets, plates, rods and tubes as well as small objects such as jewelry. 210

Figure 21.1: Materials processes.

211

Figure 22.1: Pressure die casting. Pressure die casting Pressure die casting (also called compression molding) is used for net-shape forming (dimensional accuracy and surface details) of high-quality parts with complex shapes. Thanks to the high pressures involved, very thin walled parts can be obtained, see Figure 22.1. Preformed thermosettings (now also thermoplastics) are introduced into an open, heated cavity. Pressure are applied. Products are: gaskets, seals, exterior automobile panels, aircraft fairings , and a wide variety of interior panels. Blow molding In blow molding, thermoplastics are converted into bottles or other hollowshape containers. The melted polymer is put into a mold, then compressed air is used to spread the polymer into the mold, see Figure 22.2.It is used to make many containers such as plastic soda containers and milk jugs. Cold molding In cold molding, raw thermosetting is pressed to shape while it is cold. Cured in a separate oven. It is a low cost process, but neither surface finish nor dimension precision is good. Injection molding 212

Figure 22.2: Blow molding. Injection molding is the most widely used process for high-volume production of thermoplastics parts. The resulting form is usually a finished product, no need for other work before assembly or use. If the process is applied to thermosettings, the process must be modified to provide the temperature and pressure required for curing (which is additional time in a heated mold). Similar to extrusion, the polymer is heated to the liquid state, but it is prepared in metered amounts, and the melt is forced into a mold to create the part, see Figure 22.3. This is not a continuos process. Many toys are made by injection molding. Transfer molding Transfer molding combines elements from compression and injection molding. Preformed raw thermosetting material is placed into a cavity, where it is heated until molten which is forced into the channels in the die. Thin sections can be made, with excellent detail, and good tolerance and finish. Inserts can be incorporated into the product. Products: switchgear and wiring devices, household appliances that require heat resistance, structural parts that require hardness and rigidity under load. 213

Figure 22.3: Injection molding. Reaction injection molding In reaction injection molding, two or more highly reactive liquid monomers are mixed and immediately injected into the mold cavity where the chemical reactions leading to solidification, occur, see Figure 22.4. Heating is not required. Polyurethane (thermosettings urethane-groups), polyamides (thermoplastics amids-group), composites with short fibers and flakes can be molded. Different formulations result in elastomeric or flexible, structural foam (foam core with a hard, solid outer skin), solid (no foam core), or composite products. The shapes can be quite complex (with variable wall thickness), and surface finish is excellent. Products: automobile products; steering wheels, instrument panels, door panels, armrests, household; refrigerators, water-skis. Insert molding Insert molding is an injection molding process whereby plastic is injected into a cavity and around an insert piece placed into the same cavity just prior to molding. The result is a single piece with the insert encapsulated by the plastic. The insert can be made of metal or another plastic. Like injection molding in general, insert molding can be accomplished with a wide variety of materials, including polyethylene, polystyrene, polypropylene, 214

Figure 22.4: Reaction injection molding. polyvinyl chloride, thermoplastic elastomers, and many engineering plastics. The primary factors that restrict the use of insert molding are not process related, but are determined by the strength and other properties required for the molded product. Processing Parameters: One of the chief causes of failure in an insertmolded part is the cleanliness of the insert. It is absolutely imperative that the insert be as clean as possible prior to molding. When molding with large metal inserts, the inserts may need to be preheated to minimize the stresses caused by differential thermal expansion and contraction. When inserts are manually loaded it is important that the operator maintain a consistent cycle time. Thermoforming In thermoforming, thermoplastic sheet material is heated to a working temperature and then formed into a finished shape by heat, pressure, or vacuum, see Figure 22.5. There are two main steps in the process: heating and forming. Products: range from panels for contoured skylights, large items such as bathtubs, to pages of text for the blind. The size of Thermo Pressure Formed parts is limited by the size of the thermoforming machines now in use and the size of plastic sheet stock which is available. 215

Figure 22.5: An example of thermoforming. Commercially available sheet stock is attainable in sizes of 120 inches wide and as long as required in thicknesses of up to .500 inches. Larger, thicker sheet stock is available in special cases. To date, the largest commercially available Thermo Pressure Formed parts are in the size range of 48 inches long by 24 inches wide and 18 inches deep. However, the size capabilities of the process increase almost daily. Rotational molding Rotational molding produce hollow, seamless products of a wide variety of sizes and shapes, including storage tanks, bins, and refuse containers, doll parts, footballs, helmets, and even boat hulls. Gravity is used inside a rotational mold to achieve a hollow form, see Figure 22.6. The polymer is heated and due to the rotation, distributed in the form of a uniform thickness all over the mold The process is principally for thermoplastics (thermosets and elastomers are more and more common). Extrusion By extrusion, long plastic products with uniform cross section are produced. Thermoplastic pellets or powder are the raw material. The polymer is heated to the liquid state and forced through a die under pressure resulting in an endless product of constant cross section, see Figure 22.7. Extrusion is a cheap and rapid method. Products: tubes, pipes, window frames, sheet and even coated wires and cables. 60% of polymers are prepared in this way.

216

Figure 22.6: Rotational molding. Film Blowing Film blowing uses the same method as extrusion: the material coming out of the die is blown into a film. An example is plastic wrap. Foam molding In foam molding, plastic foam is fabricated. Foaming agent is mixed with the plastic resin and releases gas or volatilizes when the combination is heated during molding. The materials expand to 2-50 times their original size. The process produce open-cell foams and closed-cell foams. Open cell-foams have interconnected pores that permit the permeability of gas or liquid. Closed-cell foams have the property of being gas- or liquid-tight. Both thermoplastics and thermosettings can be foamed. Polyurethane is one of the most versatile polymers in use today. It’s chemistry is based on the reaction of an isocyanate with a polyhydroxy compound (polyol). Therefore, a polyurethane foam-in-place system is a combination of the above two components which have been preformulated so they need to only be mixed and dispensed to make polyurethane foam, see Figure 22.8. North Carolina Foam Industries (NCFI) was awarded a Mission Success Medal on July 29, 1998 by Lockheed Martin Michoud Space Systems for production and delivery of a lightweight spray-applied foam insulation system that Lockheed Martin applies on the surface of the new super lightweight external fuel tank. 217

Figure 22.7: Extrusion.

Figure 22.8: Foaming in-place. From: http://www.ncfi.com/foam-in-place.htm Products: Rigid foams are useful for structural applications, packaging, shipping containers, interiors of thin-skinned metal components, and flexible foams are primarily used for cushioning.

22.1. Processing of Rubber and elastomers The simplest of the fabrication processes is dipping, where a master form of metal is first produced, which is dipped into the molten liquid of elastomers. Dipping produce relatively thin parts with uniform thickness, such as boots, gloves, balloons, swim caps, toys, and fairings. Adaptions of the previously discussed processes for plastics are also used to produce the shapes (injection, compression, and transfer molding, and extrusion). 218

Figure 22.9: Glovedipping, picture from: http://www.accautomation.com/prodsysc.htm. References: Fabrication Processes: http://islnotes.cps.msu.edu/trp/toc.html http://www/designinsite.dk Fabrication of plastics: http://www.mse.cornell.edu/courses/engri111/polymer4.htm Foam molding: http://www.ncfi.com/foam-in-place.htm Videos: http://www.gwplastics.com/capabilities/amto.html 3D Body scanner, see http://www.tc2.com/RD/RDBody.htm Design http://www.machinedesign.com/ Application of plastics: http://www.stug.com.au/Applications/Common.html Questions • What kind of main groups, subgroups and processes of fabrication processes are there? • How does the fabrication of a thermoplastic polymer differ from the processing of a thermosetting polymer? 219

• What are some of the ways that plastic sheets, plates and tubes can be fabricated? • What types of polymers are most commonly blow molded? • What type of products are produced by rotational molding? • How do we produce long plastic products with uniform cross-section? • How are foamed plastics produced? • What is the difference between open-cell foams and close-cell foams?

220

23. Fabrication of Fiber-Reinforced Composites (FRC)
Taking composite materials as a whole, there are many different material options to choose from in the areas of resins, fibres and cores, all with their own unique set of properties such as strength, stiffness, toughness, heat resistance, cost, production rate etc. However, the end properties of a composite part produced from these different materials is not only a function of the individual properties of the resin matrix and fibre (and in sandwich structures, the core as well), but is also a function of the way in which the materials themselves are designed into the part and also the way in which they are processed. In this section we compare a few of the commonly used composite production methods. 23.1. Manufacturing processes of Reinforcements Individual fibres or fibre bundles can only be used on their own in a few processes such as filament winding. For most other applications, the fibres need to be arranged into some form of sheet, known as a fabric, to make handling possible. Different ways for assembling fibres into sheets and the variety of fibre orientations possible lead to there being many different types of fabrics, each of which has its own characteristics. These different fabric types and constructions are explained later. Glass filaments are supplied in bundles either strands, rovings or yarns. A strand is a collection of more than one continuous glass filament. Roving generally refers to a bundle of untwisted strands wound in parallel to form a cylindrical, flat-ended package, similar to thread on a spool. Single-end roving contains only one continuous strand of multiple glass filaments. Multiple-end roving contains numerous wound strands. Yarns are collections of filaments or strands (usually smaller than rovings) that are twisted together. Carbon Fiber: Fiber produced by carbonizing precursor fibers based on PAN (polyacrylonitrile), rayon and pitch to eliminate non-carbon atoms. The term carbon fiber is often used interchangeably with graphite. Carbon fibres are produced by the PAN or the pitch methods. Pitch method pulls out graphite threads through a nozzle from hot fluid pitch. The PAN method separates a chain of carbon atoms from polyacrylnitrile (PAN) through heating and oxidation. The polymer is stretched into alignment parallel with what will eventually be the axis of the fiber. Then, an oxidation 221

Figure 23.1: Woven mat. treatment in air between 200 and 300◦ C transforms the polymer into a nonmeltable precursor fiber. This precursor fiber is then heated in a nitrogen environment. As the temperature is raised, volatile products are given off until the carbon fiber is composed of at least 92% carbon. The temperature used to treat the fibers varies between 1000◦ C and 2500◦ C depending on the desired properties of the carbon fiber. R Aramid: A high strength, high stiffness fiber derived from polyamide. Kevlar ° R ° are examples of aramids. and Nomex Fiberglass: Filaments made by drawing molten glass, commonly used to reinforce composite materials. Woven mats: For applications where more than one fibre orientation is required, a fabric combining 0◦ and 90◦ fibre orientations is useful. Woven fabrics, see Figure 23.1, are produced by the interlacing of warp (0◦ ) fibres and weft (90◦ ) fibres in a regular pattern or weave style. The fabric’s integrity is maintained by the mechanical interlocking of the fibres. Drape (the ability of a fabric to conform to a complex surface), surface smoothness and stability of a fabric are controlled primarily by the weave style. Filament winding: This is the automated process of wrapping resin impregnated filaments, see Figure 23.2, (rovings or tows) in a geometric pattern over a rotating male mandrel. The component is then cured under high pressure and temperature. Rovings: Rovings consist of one or more glass strands made up of varying numbers of continuous glass fibers of a specific filament diameter. These fibers are coated with a sizing designed to protect the fiber during processing and to couple with the customer’s resin to optimize laminate performance. 222

Figure 23.2: Filament winding rovings. Rovings, the most common form of glass, can be chopped, woven or processed to create secondary fiber forms for composite manufacturing, such as mats, woven fabrics, braids, knitted fabrics and hybrid fabrics. Rovings are supplied by weight, with a specified filament diameter. The term yield is commonly used to indicate the number of yards in each pound of glass fiber rovings. Mats: Mats are nonwoven fabrics that provide isotropic or equal strength in all directions. They come in two distinct forms: chopped and continuous strand. Chopped mats contain randomly distributed fibers cut to lengths typically ranging from 1.5 to 2.5 inches and held together with a chemical binder. Inherently weaker than continuous-strand mats, chopped-strand mats provide low-cost polymer reinforcement primarily in hand layup, continuous laminating and some closedmolding applications. Chopped Strand Mat: The chopped strand mats, see Figure 23.3, are made from cut fibers laid in a random pattern and bonded with a powdered, highly soluble resin binder. Continuous Filament Mat: In a different production step, strands formed below the bushings are treated with a binder and formed into a swirl pattern to make continuous filament mat. 23.2. Prepregs, Preforms and Compounds A prepreg is an intermediate composite form made by preimpregnating the reinforcement with resin prior to molding. Molding compounds prepared in this way 223

Figure 23.3: Chop strand mat. are mostly glass fiber mats or glass filament cloths processed to form molded parts or semi-finished products by hot-press molding Preforming is an intermediate molding process whereby the reinforcement is assembled in the shape of the part to be molded. This helps to ensure uniform properties in a composite product and speed the molding cycle. Glass fiber-reinforced thermoplastic compounds are typically in the form of pellets consisting of resin with fibers in it. They can have several different forms, i.e. sheets and billets/bulk form, also called bulk molding compounds (BMC) and sheet molding compound (SMC). The pre-mixed material has the consistency of molding clay and is injected into a mold cavity or placed on the bottom of two mold halves for compression molding. 23.3. Fabrication processes of FRC There are several processes that manufacture fiber-reinforced composites. Some of the processes are almost the same as we studied for manufacturing plastics, but somewhat modified in order to incorporate the reinforcements. We will consider some of the most widely used processes in manufacture FRCs. Centrifugal Casting This process makes cylindrical, hollow shapes such as tanks, pipes and poles. Chopped strand mat is placed into a hollow, cylindrical mold, or continuous roving is chopped and directed onto the inside walls of the mold. Resin is applied to the inside of the rotating mold. Cold press molding 224

Cold press molding is a semi-open molding process. Reinforcements, usually continuous filament mats (CFM), are placed into the tool and a highly filled polyester resin is poured onto them. The press is closed and the part is cured. The process requires lower pressures, 15 - 100 lb/in2, and temperatures averaging 55◦ C. Cycle times are in the range of 10 - 20 minutes. Other glass fiber fabrics, mats, veils and preforms are also used. Parts usually have a fair-to-poor surface, so uses are under-hood auto and truck components like fan shrouds, brackets and battery supports. Compression Molding (hot press molding) The composite is formed under pressure between matching male and female mold halves, at temperatures between 130 and 170◦ C. The material that is compressed is typically one of several combinations of glass fibers and resin. These combinations are: sheet molding compound, bulk molding compound, preform or glass fiber-reinforced thermoplastic sheet. Continuous Lamination This is a process for making composite in sheet form such as composite glazing, corrugated or flat construction panels, and electrical insulating materials. Reinforcement is combined with resin and sandwiched between two plastic carrier films. The sheet takes shape under forming rollers, and the resin is cured to form the composite. Filament Winding This process makes high strength, hollow and generally cylindrical products such as pipe, storage tanks, pressure vessels and rocket motor cases. The fiber is impregnated in a resin bath and pulled by the force of a rotating mandrel which gives the part its shape, see Figure 23.4.Veils are used for inner and/or outer surfaces to create a resin-rich surface for better corrosion resistance and aesthetics. Hand Lay-Up This process is suited for making large, high strength parts at low to medium volumes. A combination of reinforcements in roll form is laid into an open mold and impregnated with resin. When the resin cures, the surface of the mold is replicated on the side of the composite facing the mold.Resins are impregnated by hand, see Figure 23.5, into fibres which are in the form of woven, knitted, stitched or bonded fabrics. This is usually accomplished by rollers or brushes, with an 225

Figure 23.4: Filament winding.

Figure 23.5: Hand lay-up. increasing use of nip-roller type impregnators for forcing resin into the fabrics by means of rotating rollers and a bath of resin. Laminates are left to cure under standard atmospheric conditions. Infusion molding In infusion molding processes a single-sided mold which is covered with reinforcements and sealed with a flexible vacuum bag or film is used. A vacuum is drawn on the space between the mold and the seal containing the reinforcements, and a thermoset resin is allowed to infiltrate the reinforcements. The resin flows through the reinforcements and cures to form the finished composite. Large parts can be produced; such as boat hulls and windmill blades.

226

Figure 23.6: Pultrusion. Injection Molding A thermoplastic or thermoset molding compound made of glass fibers and resin is fed by a screw or plunger into a mold cavity. The mold halves are held under pressure until the resin cures. Short glass fibers are commonly used as reinforcements. Pultrusion This is a continuous process for making a lineal profile with a constant cross section (such as rod stock, beams, channels and tubing) of fibre reinforced profiles. After the reinforcement is impregnated with resin, the material is pulled through a heated die that gives the part its cross sectional shape, see Figure 23.6.The resin cures to create the composite profile. Reaction Injection Molding (RIM) This process uses a two-component resin system, see Figure 23.7. The two resin components are combined and mixed together, then injected into a mold cavity containing reinforcement. In the mold cavity, the resin rapidly reacts and cures to form the composite part. The reinforcement is added to both resin components before those components are reacted. The fiber-reinforced resin combination is injected into the mold cavity where the resin rapidly reacts and cures to form the composite part. 227

Figure 23.7: Reaction injection molding. RIM uses liquid raw materials unlike other methods (including injection and compression) where plastic raw materials are in solid forms must first be melted, then molded. Resin Transfer Molding (RTM) The reinforcement is placed in the bottom half of matching molds. After the mold is closed and clamped, resin is pumped under pressure into the mold cavity. The resin wets the reinforcement and cures to form the composite part.

Figure 23.8: Resin transfer molding. Spray-Up This is similar to and often combined with hand lay-up. With spray-up, glass fiber roving is fed into a chopper ”gun” that chops the roving into fibers of predetermined length. The fibers are directed to a resin stream. The combination 228

Figure 23.9: 3D woven sandwich fabric. material is directed to the mold cavity when the composite part takes shapes. 23.4. Fabrication of Functionally Gradient Materials Various techniques have been employed to the fabrication of FGMs, including Chemical Vapor Deposition (CVD) / Physical Vapor Deposition (PVD), powder metallurgy, plasma spraying, electro-plating and combustion synthesis. 23.5. Fabrication of sandwich constructions 3D woven sandwich New methods makes it possible to braid, weave or knit sandwich structures, as shown in Figure 23.9.The new research in this techniques and structures focuses on integrated core sandwich panels, based on 3D-Woven sandwich fabrics. Intensive research on the 3D woven sandwich panels has been carried out, proving the advantages of this material. The very high skin-core debonding resistance of the panels is in theory very beneficial in increasing the lifetime and damage tolerance of the structure. The application of 3D woven sandwich composites in (semi-) structural composites depends on the long-term behavior and the damage tolerance of the panels. These properties have not yet been investigated. Three load cases are considered to be essential for the further applicability of the panels: fatigue, impact and static concentrated loads. 229

1)

2) glue honeycomb material

3)

4)

Figure 23.10: Fabrication of aluminiun honeycombcore. Manufacturing of honeycomb cores There are two methods of constructing honeycombs; by Corrugation Process or by Expansion Process. • Corrugation Process Sheets of the material are passed through corrugating rolls, to give them shape, are then cut to length. The sheets are then bonded together to make a complete honeycomb. This process only works for denser materials, which will retain their shape after corrugation. • Expansion Process Sheets of the material are covered in thin strips of adhesive, and are stacked to form a block, see Figure 23.10. The block is sliced to the right thickness, and then pulled into an expanded form. This method is used for less dense materials. Both of these methods produce a honeycomb in which the original material runs in one direction. This is known as the web direction. The finished composite material will be twice as stiff in the web direction as it is in the other. Manufacturing of foams 230

A new, inexpensive method for manufacturing cellular solids of highly repeatable and uniform open cell geometry has been developed. Pore sizes as small as a few microns can be achieved. Materials choices include metals, ceramics, glasses, polymers, semiconductors and composites. A significant advantage to this method is that the distribution of material at the cell level is readily controlled. This creates the possibility for optimally designed cellular structures with exceptional thermophysical and mechanical properties. Multi-functional materials are envisioned. These could include load bearing structures which also provide for additional things such as impact/blast absorption, thermal management, conductance of electricity and/or shielding of electromagnetic waves, electrical power storage, filtering or impeding of fluid flow, retardation of chemical reactions and fire or in-growth of biological tissue. Thermoplastic foams are the result of deliberately adding at least one gasgenerating substance such as a chemical blowing agent, a soluble gas, or volatile liquid under pressure to the polymer melt, then altering the environment to cause the gas-generating substance to yield discrete bubbles. Foams offer unique processing challenges, ranging from the technical aspects of controlling bubble nucleation and growth to issues dealing with environmental concerns from diffusing blowing agent gases. Refractory foams can be fabricated from any material or materials combination (either homogeneously combined or layered) which can be deposited by CVD (chemical vapor deposition). Among the materials that can be deposited are the refractory metals (e.g. niobium, tantalum, tungsten, rhenium) and their ceramic compounds (e.g. the oxides, nitrides, carbides, borides, and silicides). Deposited material densities of up to 50% of theoretical values can be readily achieved. These materials can be furnished in various sizes and configurations, and are easy to machine. Face sheets of either the same of different material can be applied to enhance the flexural and tensile properties. References: Fabrication fiber-reinforced composites: http://www.owenscorning.com/owens/composites/about/fabrication.asp http://www.advancedcomposites.com/ http://www.giplastek.com/rim/ http://www.polymerprocessing.com/operations/rim/ http://www.raypubs.com/ctyp/ypoverview.html Composite applications: 231

http://www.owenscorning.com/composites/applications/index.asp About composites: http://www.mdacomposites.org/materials.htm http://www.netcomposites.com/ http://islnotes.cps.msu.edu/trp/toc.html http://me.lsu.edu/~composit/ Manufacturing of foams: http://www.uvapf.org/technology/viewInvention.cfm?inventionID=205 Fiber and Powder manufacturing http://powdermetinc.com/ http://www.reade.com/home_index.html http://www.wrigley-fibres.com/ http://www.claremontflock.com/ Design for Manufacturability http://www.galorath.com/tools_manuf.shtm http://www.npd-solutions.com/dfm.html Design and analyse of composite materals: Polymer Matrix Composites, http://mil-17.udel.edu/PMC/index.html 3D-woven sandwich: http://www.mtm.kuleuven.ac.be/Research/C2/poly/PhD_hj.htm http://www.muratec.net/braider/ Questions • What is Prepreg? • What is Preform? • What is Compound? • How is fiber manufactured? • What are woven mats? • How is carbon fiber manufactured? • What different processes of making fiber-reinforced composites are there? • How can honeycomb-cores be made?

232

Figure 24.1: Layer Manufacturing Technology.

24. Layer Manufacturing Technology (LMT)
Layer Manufacturing Technology (LMT), is based on the principle of adding material in 2D-layers to build a complete 3D-model, that is why it is called additive technologies. Figure 24.1 shows how the parts made from LMT looks like in 2D and 3D and close-up. There are several names of such processes: e.g. Rapid prototyping (RP), 3D-printing, solid freeform fabrication (SFF), freeform fabrication (FFF). The different technologies fabricate physical objects directly from CAD data sources. These methods are unique in that they add and bond materials in layers to form objects. Such systems offer advantages in many applications compared to classical subtractive fabrication methods (for instance milling or turning), such as • Objects can be formed with any geometric complexity or intricacy without the need for elaborate machine setup or final assembly. • Objects can be made from multiple materials, or as composites, or materials can even be varied in a controlled fashion at any location in an object. • Solid freeform fabrication systems reduce the construction of complex objects to a manageable, straightforward, and relatively fast process. • Small series of parts. The latter has resulted in their wide use as a way to reduce time to market in manufacturing. Today’s systems are heavily used by engineers to better understand and communicate their product designs as well as to make rapid tooling 233

to manufacture those products. Surgeons, architects, artists and individuals from many other disciplines also routinely use the technology. The names of specific processes themselves are also often used as synonyms for the entire field of LMT. Each of these technologies has its singular strengths and weaknesses. LMT is an acronym for a group of processes capable of producing prototypes of a complex geometry in various materials (wax, plastic, metal, etc.). The dominating types of LMT processes, that will be studied in more detail, are: • • • • • • • • • • Ballistic particle manufacturing (inkjet)- BPM Fused deposition modelling - FDM Laminated object manufacturing - LOM Selective laser sintering - SLS Stereo lithography - SLA Solid ground curing - SGC (cubital) Three dimensional printing (3DP) Laser Engineered Net Shaping (LENS) Inkjets Powder metallurgy (PM)

Price is generally proportional to the time consumption on the machine. This means that price increases with finer layer thickness, increased volume, as well as increased part height. The materials used in rapid prototyping are still pretty limited and dependent on the method chosen. However, the range and properties available are growing quickly. Numerous plastics, ceramics, metals ranging from stainless steel to titanium, and wood-like paper are available. At any rate, numerous secondary processes are available to convert patterns made in a rapid prototyping process to final materials or tools. The ever increasing range of materials and processes in the group of additive material processes make the processes possible to use in also fabrication of finished products and not only prototypes. In for instance the SLS process, metallic powder is the basis and the finished product has very good properties. Therefore, in addition to prototypes, RP techniques can also be used to make tooling (referred to as rapid tooling) and even production-quality parts (rapid manufacturing). For small production runs and complicated objects, rapid prototyping is often the best manufacturing process available. Of course, ”rapid” is a relative term. Most prototypes require from three to seventy-two hours to build, depending on the 234

Figure 24.2: Ballistic particle manufacturing. size and complexity of the object. This may seem slow, but it is much faster than the weeks or months required to make a prototype by traditional means such as machining. These dramatic time savings allow manufacturers to bring products to market faster and more cheaply. 24.1. Ballistic particle manufacturing (inkjet) BMP BMP uses CAD-generated three-dimensional solid model data to direct streams of material (waxes, plastics, photocurable polymers, ceramics, or metals) at a target, building three-dimensional objects in much the same manner an ink jet printer produces two-dimensional images. An object is built by a three-axis robotic system controlling a piezoelectric ink-jet mechanism ”shooting” particles of the material, producing multiple cross sections, onto a target, as shown in Figure 24.2. There are different inkjet techniques (deposition systems), but all rely on squirting a build material in a liquid or melted state which cools or otherwise hardens to form a solid on impact. 24.2. Fused deposition modelling - FDM FDM, see Figure 24.3 is another deposition method.The Titan machine from Stratasys creates models using high performance engineering materials such as polycarbonate, ABS and sulfones. Now with Titan, you can create prototypes that have superior impact strength and also resist heat and corrosive agents such 235

Figure 24.3: Fused deposition modelling. as oil, gasoline and even acids. Multiple materials, coupled with one of the largest build chambers in its class, make Titan a smart solution for building, large, strong and durable parts. Parts up to 355 x 406 x 406 mm can be built. 24.3. LOM - Laminated object manufacturing Laminated object manufacturing, see Figure 24.4 is a process suited for large and heavy parts, e.g. models for metal castings. The process makes use of foils, where the undersurface of this foil has a binder that when pressed and heated by the roller causes it to glue to the previous foil. The foil is cut by a laser following the contour of the slice. To help the removal of the excess material once the parts have been built, the exterior of the slice is hatched, as opposed to fluid-based processes (e.g. the SLA process), where the interior is hatched. Fine details cannot be produced, and surplus material has to be removed manually from the part. Helisys invented this process, but they ceased operation in 2000. However, there are several other companies with either similar LOM technology, or in early commercial stages. Maximum dimension was about 1600 * 1200 * 1200 mm. 24.4. Selective laser sintering - SLS SLS, see Figure 24.5 produces part from plastic, wax, or metal powders. Advantages include the use of industrial plastic types.

236

Figure 24.4: Laminated object manufacturing. Selective Laser Sintering is a thermal process and starts with a thin, evenlydistributed layer of powder. A laser is then used to sinter (fuse) only the powder that is inside a cross-section of the part. The energy added by the laser heats the powder into a glass-like state and individual particles coalesce into a solid. Once the laser has scanned the entire cross-section, another layer of powder is laid on top and the whole process is repeated. The hardened layer is lowered, a new layer of powder is spread, and the process is repeated. Maximum dimensions are about 500 * 500 * 500 mm. The SLS technology is known for its ability to process a variety of prototyping materials including thermoplastics, investment casting wax, and a powdered metal material for the production of prototype injection molds. 24.5. Laser Engineered Net Shaping (LENS) Laser-engineered net shaping (LENSTM ) builds on the SLS process with a few notable exceptions. Instead of bonding material in a bed of powder, the powder is delivered in a gas jet through nozzles. Solid material is formed by solidification of a molten pool, thus forming a fully dense, free-standing deposit. A variety of materials can be used such as stainless steel, Inconel (a special nickel material), copper, aluminum etc. Of particular interest are reactive materials such as titanium. Materials composition can be changed dynamically and continuously, leading to objects with properties that might be mutually exclusive 237

Figure 24.5: Selective laser sintering. using classical fabrication methods. The strength of the process lies in the ability to fabricate fully-dense metal parts with good metallurgical properties at reasonable speeds. 24.6. Stereo lithography - SLA Stereo lithography - SLA is the most common RPT technique, and produces acrylic and epoxy parts from a liquid. Initially, an elevator is located at a distance from the surface of the liquid equal to the thickness of the first, bottom-most layer, see Figure 24.7. The laser beam will scan the surface following the contours of the slice. The interior of the contour is then hatched using a hatch pattern. The liquid is a photopolymer that when exposed to the ultra-violet (uv) laser beam solidifies or is cured. The elevator is moved downwards, and the subsequent layers are produced analogously. Fortunately, the layers bind to each other. Finally, the part is removed from the vat, and the liquid that is still trapped in the interior is usually cured in a special oven. Almost unlimited geometry possibilities, fine geometric details and high accuracy. The required geometry is produced in thin layers (0.0254 mm layer thickness) that yields a smooth finish. A CNC-controlled laser beam cures a pattern in the surface of a fluid photosensitive polymer. The hardened layer is then stepwise lowered allowing the fluid to cover the part. 238

Figure 24.6: Laser Engineered Net Shaping. Typical applications are prototypes of injected moulded plastic parts and modelling of human bones and skulls. Maximum dimensions are about 500 * 500 * 600 mm. 24.7. Solid ground curing - SGC With the solid ground curing technique, see Figure 24.8, parts are produced from photosensitive polymers by hardening them in layers just as the SLA process. However, this is a significantly different process. The vat moves horizontally as well as vertically. The horizontal movements take the workspace to different stations in the machine. The light source a uv-lamp (mercury) is used to flood the chamber and expose and solidify the entire layer at once (instead of using a laser beam as in SLA). This avoids the need for post-curing the parts. To select the areas that should be cured, a mask is built on a glass plate, and subsequently, erased after begin used. The mask is built using a process similar to the one used in laser printers. The glass plate with the mask is placed between the lamp and the surface of the workspace. Parts are built surrounded by wax, eliminating the need for support structures (which is needed in SLA). Once a layer has been exposed to the uv-lamp, the uncured areas-those areas filled with residual, liquid polymer-are replaced by wax. This is done by wiping away the residual polymer and applying a layer of wax.

239

Figure 24.7: Stereo lithography. The wax is hardened by a cold metal plate, and subsequently, the layer is milled to the correct height. The milling station also allows for layers to be removed, i.e. an undo operation is possible. The new layer of polymer is applied when the workspace moves from the milling station back to the exposure chamber. The process is well suited for large and heavy parts. No separate part support is required during processing. Compared with SLA, it is more expensive and not as accurate. Machines from Cubital use SGC principle. 24.8. Three dimensional printing (3DP) Three dimensional printing, see Figure 24.9 was developed at Massachusetts Institute of Technology (MIT). It’s often used as a direct manufacturing process as well as for rapid prototyping. The process starts by depositing a layer of powder object material at the top of a fabrication chamber. To accomplish this, a measured quantity of powder is first dispensed from a similar supply chamber by moving a piston upward incrementally. The roller then distributes and compresses the powder at the top of the fabrication chamber. The multi-channel jetting head subsequently deposits a liquid adhesive in a two dimensional pattern onto the layer of the powder which becomes bonded in the areas where the adhesive is deposited, to form a layer of the object.

240

Figure 24.8: Solid ground curing. Once a layer is completed, the fabrication piston moves down by the thickness of a layer, and the process is repeated until the entire object is formed within the powder bed. After completion, the object is elevated and the extra powder brushed away leaving a ”green” object. No external supports are required during fabrication since the powder bed supports overhangs. Three dimensional printing offers the advantages of speedy fabrication and low materials cost. In fact, it’s probably the fastest of all RP methods. Recently color output has also become available. Parts can be made of any material (ceramic, metals, polymers and composites). 24.9. PowderProcessing/PowderMetallurgy Powder metallurgy is the process where both casting, forming and consolidation are involved. Fine powdered materials are blended, pressed into a desired shape, and then heated in a controlled atmosphere to bond the contacting surfaces of the particles and establish the desired properties. Some of the advantages with the process is that the material waste is very little, unusual materials or mixtures can be used and the porosity or permeability can be tailored. There are many different methods to manufacture products with powder metallurgy processes and in the future even more methods will be introduced to the marked. Almost any metal, metal alloy, or nonmetal such as ceramic, polymer or wax or graphite lubricant can 241

Figure 24.9: Three dimensional printing. be converted into powder and can thereby be produced by a powder metallurgy method. Powder metallurgy uses sintering process for making various parts out of metal powder. The metal powder is compacted by placing in a closed metal cavity (the die) under pressure. This compacted material is placed in an oven and sintered in a controlled atmosphere at high temperatures and the metal powders coalesce and form a solid. A second pressing operation, repressing, can be done prior to sintering to improve the compaction and the material properties. The properties of this solid are similar to cast or wrought materials of similar composition. Porosity can be adjusted by the amount of compaction. Usually single pressed products have high tensile strength but low elongation. Powder metallurgy is useful in making parts that have irregular curves, or recesses that are hard to machine. It is suitable for high volume production with very little wastage of material. Secondary machining is virtually eliminated. Typical parts that can be made with this process include cams, ratchets, sprockets, pawls, sintered bronze and iron bearings (impregnated with oil) and carbide tool tips. FGMs can be fabricated by for instance Powder Metallurgy (PM).

242

24.10. Vapor Deposition CVD/PVD Deposition is a process of depositing a thin layer of film onto the surface of the wafer. Vapor deposition processes usually take place within a vacuum chamber. There are two categories of vapor deposition processes: physical vapor deposition (PVD) and chemical vapor deposition (CVD). In PVD processes, the workpiece is subjected to plasma bombardment. In CVD processes, thermal energy heats the gases in the coating chamber and drives the deposition reaction. Chemical Vapor Deposition is done by putting the chemicals into a heated vacuum chamber containing a wafer. These chemical are fed into the chamber in a gas form. There are a couple of different forms of chemical vapor deposition. Each form has its own advantages and disadvantages. These forms are: APCVD Atmospheric Pressure CVD LPCVD Low Pressure CVD PECVD Plasma Enhanced CVD Physical vapor deposition does not use a chemical to deposit a film on the wafer but uses physical means. To do this a gas inside a vacuum is excited with a source , like RF (Radio frequency) energy. The molecules of the gas become so energetic that if they were to collide with some materials they might cause atoms of that material to break free. PVD uses this as a way to deposit layers of material onto a wafer. A ”target” is placed above the wafer and when the molecules of gas strike the target and cause the atoms to break free then a layer of atoms will fall onto the wafer. 24.11. Selection of a layered manufacturing process Selection of a layered manufacturing process depends on the basic application as well as material and accuracy requirements. Selection rules of thumb have evolved: Applications involving injection molded parts and/or good accuracy, often lead to stereolithography (SLA) as the best choice. If a prototype part needs to be in final materials and with mechanical properties that emulate injection molded parts, selective laser sintering (SLS) might be chosen. If the requirement is for large objects that will ultimately be sand cast, laminated object manufacturing (LOM) is often the way to go. 243

If the need is for a quick concept model and physical properties are of secondary importance, three dimensional printing (3DP) may be most economical. If the requirement is for extreme accuracy and very high resolution, such as in making jewelry or small parts, a good choice is often an inkjet system such as the ModelMaker Series from Solidscape, Inc. (formerly Sanders Prototypes). Direct fabrication of metal objects as tools or prototypes will require selective laser sintering (SLS), or one of the methods based on laser fusing such as laser engineered net shaping (LENS). In order to get the best finish of a product; rotate the geometry such that the laser "draws" the 2D geometry that is most critical, and not let that surface be step-wise. Of course, such rules of thumb risk offending every system manufacturer because there is tremendous overlap in capabilities and specifications. The majority of applications can probably be accomplished satisfactorily by several of the technologies. References about additive technologies: SLS- technology in action: http://www.dtm-corp.com/ http://home.att.net/~castleisland/ http://lff.me.utexas.edu/sls.html LMT Processes: http://home.att.net/~castleisland/ http://designinsite.dk http://www.efunda.com/processes/metal_processing/powder_metallurgy.cfm http://www.efunda.com/processes/processes_home/process.cfm http://www.efunda.com/home.cfm http://www.precitech.ca/pmproc.htm http://www.cs.hut.fi/~ado/rp/rp.html http://home.att.net/~castleisland/rp_int1.htm http://www-2.cs.cmu.edu/~rapidproto/manufacturing/mfgresources.html http://home.att.net/~castleisland/rp_int1.htm http://www-2.cs.cmu.edu/~rapidproto/manufacturing/mfgresources.html http://www-2.cs.cmu.edu/~rapidproto/manufacturing/mfguniversity.html http://emsh.calarts.edu/~mathart/R_Proto_ref.html http://home.att.net/~castleisland/com_lks.htm http://www.stratasys.com/ (also streaming video on FDM process) 244

Figure 24.10: Rapid Prototyping Technologies.

245

http://www.acceltechinc.com/nojava/sls.html http://www.prototype3d.com/ http://www.3dsystems.com/ http://web.mit.edu/tdp/www/whatis3dp.html http://www.myb2o.com/myb2ous/RapidPrototyping/Tools/Process/10265.htm http://www.mit.edu/~tdp/ (pictures)= next link http://web.mit.edu/afs/athena/org/t/tdp/www/ http://www.sandia.gov/media/lens.htm http://www.tms.org/pubs/journals/JOM/9907/Hofmeister /Hofmeister-9907.html (LENS) CVD/PVD http://www.corrosion-doctors.org/MetalCoatings/Physical.htm http://entcweb.tamu.edu/zoghi/semiprog/deposit.htm http://www.darpa.mil/dso/trans/fds_2.htm Questions • What are the different processes of LMT? • What are the advantages and disadvantages of LMT-processes compared to traditional processes? • How does SLA work? • Explain the powder metallurgy process

246

25. Design Considerations
The goals of reducing a large manufacturing cost and improving product quality has lead to certain processes and procedures that have come to be known as design for manufacturability or design for manufacture (DFM). The closely related is also the area of design for assembly (DFA).

25.1. Designing for Manufacturability (DFM) ) Design for Manufacturability (DFM) or Design for Fabrication (DFF) is a method and the theory for designing products that can be produced. In addition this method saves time compared to previous methods (or non-methods). In the past, products have been designed that could not be produced. Products have been released for production that could only be made to work in the model shop when prototypes were built and adjusted by highly skilled technicians. Clearly, there must be some other way to develop a product that is smarter than this. A product can be designed in many different ways. The designer’s objective must be to optimize the product design with the production system. A company’s production system includes its suppliers, material handling systems, manufacturing processes, labor force capabilities and distribution systems. Generally, the designer works within the context of an existing production system that can only be minimally modified. However in some cases, the production system will be designed or redesigned in conjunction with the design of the product. When design engineers and manufacturing engineers work together to design and rationalize both the product and production and support processes, it is known as integrated product and process design. The designer’s consideration of design for manufacturability, cost, reliability and maintainability is the starting point for integrated product development. A designer’s primary objective is to design a functioning product within given economic and schedule constraints. However, research has shown that decisions made during the design period determine 70% of the product’s costs while decisions made during production only account for 20% of the product’s costs. Further, decisions made in the first 5% of product design could determine the vast majority of the product’s cost, quality and manufacturability characteristics. This indicates the great leverage that DFM can have on a company’s success and profitability. 247

However, the application of DFM must consider the overall design economics. It must balance the effort and cost associated with development and refinement of the design to the cost and quality leverage that can be achieved. In other words, greater effort to optimize a products design can be justified with higher value or higher volume products. Design effectiveness is improved and integration facilitated when: • Fewer active parts are utilized through standardization, simplification and group technology retrieval of information related to existing or preferred products and processes. • Producibility is improved through incorporation of DFM practices. • Design alternatives are evaluated and design tools are used to develop a more mature and producible design before release for production. • Product and process design includes a framework to balance product quality with design effort and product robustness. 25.2. Product design guidelines Designers need to understand more about their own company’s production system, i.e., its capabilities and limitations, in order to establish company-specific design rules to further guide and optimize their product design to the company’s production system. For example, they need to understand the tolerance limitations of certain manufacturing processes. DFM Guidelines: • Minimize total number of parts • Standardize components • Use common parts across product lines • Design parts to be multifunctional • Design parts for ease of fabrication • Avoid secondary operations • Utilize the special characteristics of processes In addition, colors, tolerances and materials also limits the process that should be used. Design guidelines 248

There has been developed a number of rules for design. Briefly mentioned, the list looks like this: • Space holes in parts so they can be made in one operation without tooling weakness. There is a limit in how close holes may be spaced due to strength in the thin section between holes. • Notes on engineering drawings must be specific and clear. • Dimensions should be made from specific surfaces or points on the parts. • Dimensions should all be from a single datum line. • The design should aim for minimum weight consistent with strength and stiffness requirements (this means minimized material cost and reduction in labor and tooling costs). • Adjust the design to the manufacture process chosen (wall thickness, fillets, radii, dies etc.) • Rotation of geometry 25.3. Evaluation of design alternatives With the traditional approach, the designer would develop an initial concept and translate that into a product design, making minor modifications as required to meet the specification. DFM requires that the designer start the process by considering various design concept alternatives early in the process. At this point, little has been invested in a design alternative and much can be gained if a more effective design approach can be developed. Only through consideration of more than one alternative is there any assurance of moving toward an optimum design. Using some of the previous design rules as a framework, the designer needs to creatively develop design alternatives. Then alternatives are evaluated against DFM objectives. Design guide for composite materials, Part design concerns The very nature of composites allows designers and manufacturers to tailor fiber architecture to match performance requirements of a specific part. Fiber orientation can be varied to allow wall-thickness variations, development of complex shapes, and production of large parts with integral reinforcing members. Laminates may be designed to be isotropic or anisotropic, balanced or unbalanced, symmetric or asymmetric - depending on the in-use forces a component will endure. Understanding layered or laminate structural behavior is vital to designing effective composite components. Adhesion of laminate layers - called plies - is 249

critical; poor adhesion can cause delamination under multiple stress, strain, impact and load conditions. Ply layup designers must consider adhesion, strength, weight, stiffness, operating temperature and toughness requirements, as well as variables such as electromagnetic transparency and radiation resistance. Additionally, composite component design must encompass surface finish, fatigue life, overall part configuration, and scrap or rework potential, to name just a few of the many applicable factors. The intended fabrication method will also affect design. For instance, manufacturers of filament-wound or tape-layed structures use different reinforcement forms and build-up patterns than those warranted for hand laid up laminate panels or vacuum-bag-cured prepreg parts. RTM accommodates 3-D preforms more easily than do some other manufacturing techniques. The varying benefits and limitations of these fabrication techniques provide considerable flexibility to achieve part performance and economies. 25.4. The meaning of colors Are Colors Significant? Only for the sighted or only if one isn’t color-blind. For those of us blessed with sight, we’ve been taught that colors can make us feel good, excite us, generate fear and joy, or literally make us nauseated. As long as we attach a certain meaning to a particular color, the legends of colors will continue to persist. Color is a very important part to web design. As human beings we are very sensitive to color. We rely heavily on certain colors to give meaning to things. For example we associate the color red to love. Like hearts or roses. We also associate red to an emergency like fire trucks or exit signs. As North Americans we associate black to death however I bet you didn’t know that the Chinese culture associates black with happy and joyful. We associate white to purity or wholesomeness like a wedding dress, while in the Chinese culture a bride would never wear white on her wedding day because it symbolizes bad luck or death. So you can see by this simple example that color not only is symbolic for all cultures but NOT all cultures associate color the same way. How Are Colors Symbolic? Time and tradition have created strong, symbolic color connections. For example, we associate red with festivity, blue with distinction, purple with dignity, green with nature, yellow with sunshine, pink with health, and white with purity.

250

Context also gives color specific leaning, we know that red means stop, and green means go. White: White is associated with peace and purity such as in the white clouds and sparkling snowflakes. Two of the most popular peace symbols are the white dove and the truce flag. Red - Vitality, Courage, Self Confidence: When red is featured in a dream the tint or shade carries different meanings. A light tint of red - suggests the glory of success, hot reds - signify the stress of family quarrels, crimson hues - foretell of happy news from a friend and red hair on a beautiful woman suggests that you will receive unexpected good news. Yellow - Wisdom, Clarity, Self-esteem: Studies show that yellow is most often associated with words like cheerful, jovial and sunny, somewhat associated with exciting and stimulating and almost never associated with words like respondent, dejected, melancholy or unhappy. In short, a wonderful color for lifting the spirits and letting the sun shine in. Orange - Happiness, Confidence, Resourcefulness: The meaning of orange is inexorably linked to the sensations of radiant energy, heat and the glowing presence of the setting sun. The link between red and yellow, orange takes its traits from both. It is less passionate and intense than red, incorporating the sunny disposition of yellow. To the human eye, orange is seen as the hottest of all colors, both in temperature and appearance. Blue - Knowledge, Health, Decisiveness: The Russian artist Kadinsky captured the expansive essence of blue when he wrote that blue is ”the infinite penetration into the absolute essence - where there is, and can be, no end.” People who are strongly attracted to blue tend to be devoted and deliberate in their actions and since blue is everywhere, they feel a unity with the world. Purple - Beauty, Creativity, Inspiration: The purple family is the most enigmatic of all colors. Purple is a combination of the excitement of red and the tranquillity of blue, the marriage of two diametrically opposed emotions. Green - Balance, Love, Self control: Green is the most refreshing, restful color to the eye. The word ”green” comes from the same root as ”grow,” so green symbolizes that which grows: rebirth, regeneration, the renewal of life. Indian mystics see green as the marriage of balance and harmony, the ray that bridges cause and effect. 251

References: Design guidelines: http://www.devicelink.com/mddi/archive/96/04/008.html http://www.arrem.com/designguide/dgdesvsmat.htm http://www.tstar.com/pdf/quadrant-DF.pdf http://www.npd-solutions.com/dfmguidelines.html http://www.geplastics.com/webted/webted.html Colors: http://crumpledpapers.com/color.html http://www.wevehadit.com/Publications/Color/page3.html http://www.srsd.org/~arainone/color.html Questions • What is DFM? • What is DFF • What do we have to take into consideration when designing for fabrication? • What kind of design-considerations would you take into consideration in general? • How can colors affect our understanding of a product? • If you would like a product to make you feel good, (happy), what color would you choose on your product?

252

References
[1] Ashby M.F (1992), Materials Selection in Mechanical Design, Second edition,2000,
ISBN 0 7506 4357 9, Cambridge University Press, Cambridge.

[2] Alting Leo, (1994), Manufacturing Engineering Processes, ISBN-0-8247-9129-0, Series: Manufacturing engineering and materials processes, nr. 40, Marcel Dekker Inc., New York.

[3] Cook R. D. , Malkus D. S. and Plesha M.E. (1989),Concepts and applications of
finite element analysis, J. Wiley and Sons Inc.

[4] DeGarmo Paul E. (1997), Materials and processes in manufacturing, New York,
Prentice Hall..

[5] Gibson L.J and Ashby M.F (1997), Cellular solids, Second edition, Cambridge
University Press, Cambridge.

[6] Gregg Bruce (1997), Modern materials and manufacturing processes, New Yok,
Prentice Hall.

[7] Greengard L. and Helsing J. (1998), On the numerical evaluation of elastostatic
fields in locally isotropic two-dimensional composites, J. Mech. Phys. Solids, 46, 1441-1462.

[8] Hashin, Z. (1983) Analysis of composite materials. A survey, J. Appl. Mech., 50,
483-505.

[9] Hashin, Z. and Shtrikman, S. (1962) A variational approach to the theory of effective magnetic permeability of multi phase materials, J. Appl. Phys 33, 3125-3131.

[10] Helsing J. (1995), An integral equation method for elastostatics of periodic composites J. Mech. Phys. Solids 43, 815-828.

[11] Hill R. (1964), Theory of mechanical properties of fibre-strengthened materials-I.
Elastic behaviour, Journal of the Mechanics and Physics of Solids, Vol. 12, 199-212.

[12] http://amsl.mit.edu/research/Devices/afc/AFCcompare.html [13] http://www.chinanano.com/product.htm [14] http://www.designinsite.dk/htmsider/inspmat.htm 253

[15] http://209.226.65.103/ [16] http://intellimat.com/ [17] http://www.zyvex.com/nano/ [18] http://www.cranfield.ac.uk/sims/materials/processing/fsm.htm [19] http://www.ntu.edu.sg/home/mliuy/SMM.htm [20] http://whirlwind.aem.umn.edu/people/faculty/shield/shp-mem.html [21] http://www.plastics.com/definitions.php [22] Lukkassen D. ,. Persson L.-E and Wall P. (1995), Some engineering and mathematical aspects on the homogenization method, Composites Engineering 5, 5, 519-531.

[23] Kelsey, S., Gellatly, R.A. and Clark, B.W. (1958) The sear modulus of foil honeycomb cores, Aircraft Engineering, October, 294-302.

[24] Meidell, A. and Wall, P. (1997), Homogenization and design of structures with
optimal macroscopic behavior, in Hernández S. and Breddia C.A. (eds.), Computer aided optimum design of structures V, Computational Mechanics Publications, Southampton, 393-402.

[25] Meidell, A. (1997), Layer manufacturing Technology, HiN-manuscript, Høgskolen
i Narvik, Narvik.

[26] Meidell, A. (1998), Anvendt Homogeniseringsteori, ISBN-82-7823-037-4, HiNreport (51 p in Norwegian.), Høgskolen i Narvik, Narvik.

[27] Meidell, A. (1998), The out-of-plane shear modulus of two-component regular honeycombs with arbitrary thickness, in Mechanics of Composite Materials and Structures (eds. C.A. Mota Soares, C.M. Mota Soares and M.J.M. Freitas), NATO ASI, Troia, Portugal, Vol. III, 367-379.

[28] Meidell A. (1998), The out-of-plane shear modulus of two-component regular honeycombs with arbitrary thickness, in Mechanics of Composite Materials and Structures (eds. C.A. Mota Soares, C.M. Mota Soares and M.J.M. Freitas), NATO ASI, Troia, Portugal, Vol. III, 367-379.

254

[29] Meidell, A. (1999), Cellular Solids, HiN-report, Narvik Institute of Technology,
Narvik.

[30] Messler Robert W. Jr. (1993), Joining of Advanced Materials, ISBN-0-7506-9008-9,
Renesslaer Polytechnic Institute, Troy, New York.

[31] Persson L.E. ,Persson L. ,Svanstedt N. and Wyller J.(1993), The homogenization
method: An introduction, Studentlitteratur, Lund.

[32] Reddy J.N. (1984), Energy and variational methods in applied mechanics, John
Wiley and Sons, New York.

[33] http://en.wikipedia.org/wiki/Polymer#Morphological_Properties [34] Wakil El and Sherif D. (1998), Processes and design for manufacturing, Boston,
PWS Publ. Co.

[35] Wright John R. (1996), Introduction to materials and processes, New or, Delmar. [36] Zenkert Dan (1995), An introduction to Sandwich Constructions, Chameleon Press
Ltd., London.

255

Sign up to vote on this title
UsefulNot useful