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  • Kinetics of Iodination of Acetone in Acid Medium

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    Alecsa Duracika
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    This document describes the kinetics of acetone iodination in an acidic medium. It provides the density and volume of acetone used, the total volume of the reaction mixture, and calculates the mass, moles, and initial concentration of acetone. It also provides the initial concentration of iodine. A table shows the reaction time, volume of sodium thiosulfate used in titration, and fraction of acetone reacted. A graph plots the fraction reacted versus time, and calculates the rate constant from the slope of the line.

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    Original Title

    Cinetica Iodurarii Acetonei in Mediu Acid

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    This document describes the kinetics of acetone iodination in an acidic medium. It provides the density and volume of acetone used, the total volume of the reaction mixture, and calculates the mass, moles, and initial concentration of acetone. It also provides the initial concentration of iodine. A table shows the reaction time, volume of sodium thiosulfate used in titration, and fraction of acetone reacted. A graph plots the fraction reacted versus time, and calculates the rate constant from the slope of the line.

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    © All Rights Reserved
    Download as XLS, PDF, TXT or read online from Scribd
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    75 views2 pages

    Kinetics of Iodination of Acetone in Acid Medium

    Uploaded by

    Alecsa Duracika
    This document describes the kinetics of acetone iodination in an acidic medium. It provides the density and volume of acetone used, the total volume of the reaction mixture, and calculates the mass, moles, and initial concentration of acetone. It also provides the initial concentration of iodine. A table shows the reaction time, volume of sodium thiosulfate used in titration, and fraction of acetone reacted. A graph plots the fraction reacted versus time, and calculates the rate constant from the slope of the line.

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    © All Rights Reserved
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    of 2

    CINETICA IODURARII ACETONEI IN MEDIU ACID

    (CH3)2CO = 0.7906 g/cm3


    V(CH3)2CO = 1.8 cm3
    Vt = 50 cm3
    V=m/
    V(CH3)2CO = m(CH3)2CO/(CH3)2CO m(CH3)2CO = V(CH3)2CO * (CH3)2CO = 1.8*0.7906 =1.42 g
    m = n*M n = m/M
    n(CH3)2CO = m(CH3)2CO/M(CH3)2CO = 1.42/58 = 0.024 moli

    Concentratiile initiale
    Acetona: a = n(CH3)2CO/Vt = 0.024/50*10(-3) = 0.00048 mol/L
    Iod: b = 1*25/Vt = 1*25/50 = 0.5 mol/L

    t, min

    0
    5
    27
    36
    53
    68

    VNa2S2O3,
    mL
    25.35
    24.7
    23
    21.75
    21.6
    21

    x
    0
    0.026
    0.094
    0.144
    0.15
    0.174
    =

    k
    0.564237
    0.377775
    0.434055
    0.307116
    0.277676
    0.312271

    0.18
    0.16
    0.14
    0.12
    0.1
    0.08
    0.06
    0.04
    0.02
    0

    y = 0.003x + 0.0103
    R = 0.9379

    10

    20

    30
    t , min

    40

    50

    60

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