Mevandeia University a Januayy, 2009 Ph.D. MSc. and diploma Course title: Advanced thermodynamics ‘Open book exam Time allowed: 180 minutes (1) For methyl chloride at 373.15 K (100°C) the second end third virial coollictenis are B=-242.5 em'mol"! C= 25200 emo!” Calculate the work of mechanically reversible. isothermal compression of | mol of methyl chloride from 1 bar to $5 bar at 373.15 K (100°C). Base calculations on the following forms of the virial equation: ive (ay ty (b)Z = 14 BP + CP Where. ws 67 BP (RTE Why don't both questions give exactly the same result? (2) Caleviate Zand V for ethylene at 298.15 K (25°C) B= -140 emmol! C= 7200 cm’mol? (a) The truncated virial equation [Fq, (3.39)] with the following experimental values of virial coefficients: (b) The truncated virial equation Eq, (3.37)], correlation (Eq. (3.59)] (0) The RedlicWK wong equation. (d) The Soave/Redlich’K wnng equation (¢) The PengJRobinson equation. and 12 bar by the following equations: with a value of B from the generalized Pitver (3) Water is the working Muid in an ideal Rankine eyele vapor enters the turbine at (a) 18 MPa and (4 MPa. The net power output of the eycle is 100 MW Determine for each ease the mass flow rate of steam. in kiyh, the heat transfer rates for the working uid passing through the boiler and condenser, each in kW.and the thermal efficieney (4) Superheated steam at 18 MPa, 360°C, enters the turbine of a vapor power plant. The pressure at the exit of the turbine is 0.06 bar. and liquid leaves the condenser at 0,043 bar. 26°C. The pressure is increased to 18.2 MPa ueross the pump, ‘The turbine and pump have isentropic efficiencies of 82 and 77%, respectively. For the cycle, determine (a) The net work per unit mass of steam flow, in kJ/kg (b) The heat transfer to steam passing through the boiler. in kJ per ky of (©) The thermal efficiency. (d) The heat transfer to cooling water passing through the condenser, condensed, (5) A direct-fired dryer bums a fuel oil with a net heating value of 44200 kJ ke! [The net heating value is obtained when the products of combustion are COs(g) and H0(g).,The composition of the oil is 859% carbon, 12% hydrogen, 2% nitrogen, and 1% water by weight. The flue gases leave the dryer at 477.15 (204°C), and a partial analysis shows that they contain 3 mole-% COs and 11.8 mole-% CO on a dry basis. The fuel, air, and material being dried enter the dryer at 298.15 K(25°C). If the entering air is saturated with water and if 30% of the net heating value of the oil is allowed for heat tosses (including the sensible heat carried out with the dried product), how much water is evaporated in the dryer per kg of cil burned? hte vor-lenser pressure is 8 kPa, and saturated steam flowing in kJ per kg of steam (8x 10) ‘ Examiner: Dr. Moustapha Salem vi Best of luck #!!