Problem: Which wi lem: Which would you expect to have the higher boiling point? (@) Calla oF (CHy)CO (b) CAH, COs, CHSCN Ho — all hydrocarbons are non-polar “7 Dispersion Forces Only (a) Cy HS ee? polar molecule =7 Disperstor and dipole- chpole Forces Hf Gby.CO should have the higher bathing point because rt has more infec molecslar forces fo OVEreome. - a me, ne — youd “O=C=0; ler? y-l-0-C-H non polar roo h i u ~ Dispersion forces col a as g y ‘olat - (h dhocarlm) ~Total #e * 2ze non par ay gall, compact mole- | ~ DispesteO Forces = Dispersion Torcer ! wle - Prpule- dipole Forced Total He © 26 - Fave] large surface area lowest betling pt <> highest batting et CO, < GHys CHyN 5Problem: What intermolecular forces account substance (formula) surface (@) pentane (CsHH)2) (b) diethyl ether (C]HsOC>Hs) (©) ethanol (C;HsOH) (@) butanol (C4Hs0H) (e) water (HO) (®) mercury (Hg) Compand t for the following surface tension data? tension / Im” at 20°C 1.6% 102 o - ten paler 17x 10° ~ large organic 234102 Hee “aH od oF 25x 107 fee - Hlenbshhy fo 3 \ rfermolecular Forces 4) pentane (Hz) > hydrocer ber non-polar surface Dispersion G20) Ferstons cOGHL) > special case non-polar 0 ethanol (G Hood) > polar wilh -oH ©) ethyl ether GH 4) butarel (GyH_oH polar with -oH tel Dispersion (422) Jer 1 Dispersion, Dipole-Di pele and H-bonding (ve) Dispersion , Digole- Dipole and H-bonding U2€ e) water (40) > polar with 2 -oH £) mnercor] Ue) metal Dispersion (vé), Dioble- Dipole 4 H-bonching metallic Bond 1 Stronger reque moe p energy fo cvercome Yhan forces! infermolewlar 10Problem: How much energy is released when 0.459 g of H:O(g) is cooled from 136 °C to 85°C? Hog 2,0003-4-' "ct Crowe He Tg PY Hop = 4H.0LT ml ay A Heoed = —H4.0 Koel” emp gst giz MCAT PaAd 9 cat Time, rar gan 9 BHuond (0.464 )&. 06054" c)lloor- tee) | les / = (etsy )Q-0 2054'*C) E360) Cacige) C44 045 met) tS 2 12K ‘) @5%C-100) Peel git PP = mC OT 6 uy 2 Het 0-97 - eo (Ad 0) Cs) = (0.034 KS)'EL.I29 *C0%% 1) “es d os f= 118Ko] exothermic ei ~remonng Kinenc energy ~makng Jur k