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BINARY VAPOR LIQUID EQUILIBRIUM

Date
By

CheCalc.com

Chemical Engineering Calculations

10/08/14
CheCalc

User Input

Enter Binary Pair


Components
Antoine Equation Parameters
A
B
C
cm3/gmol
cal/gmol

Molar Volume, V
Aij, Wilson Binary parameter
T x-y Diagram
Pressure

1
1-Propanol + Water
1
2
17.54
18.30
3166.38 3816.44
-80.15
-46.13

PSIA

219
906.53

20.0

Bubble

56
1396.64
P x-y Diagram
Temperature

Dew

220

Pressure, PSIA

Temperature (Deg F)

225

215
210
205

200
0.20

0.40

0.60

0.80

250.0

Bubble

230

0.00

Dew

50.0
45.0
40.0
35.0
30.0
25.0
20.0
15.0
10.0
5.0
0.0

1.00

0.00

0.20

0.40

0.60

Change the vertical axis manually if graph does not appear properly
T x-y Chart Data
X

P x-y Chart Data


Y

0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

0.00
0.37
0.41
0.43
0.45
0.47
0.50
0.55
0.62
0.75
1.00

Temperature
F
228.0
206.3
204.6
203.9
203.5
203.5
203.9
205.1
207.5
212.4
222.2

Basis
- Vapor pressure is calculated using Antoine Equation :
Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( K ) + C )
- Flash calculations are based on Modified Raoult's Law

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

0.00
0.36
0.40
0.42
0.45
0.48
0.51
0.57
0.64
0.77
1.00

Pressure
PSIA
29.8
44.5
46.3
47.0
47.4
47.5
47.0
46.0
43.8
40.0
33.7

0.80

1.00

BINARY VAPOR LIQUID EQUILIBRIUM


Date
By

CheCalc.com

Chemical Engineering Calculations

10/08/14
CheCalc

User Input

Enter Binary Pair


Components
Antoine Equation Parameters
A
B
C
cm3/gmol
cal/gmol

Molar Volume, V
Aij, Wilson Binary parameter
T x-y Diagram
Pressure

1
1-Propanol + Water
1
2
17.54
18.30
3166.38 3816.44
-80.15
-46.13

Bar Abs
Bubble

219
906.53

1.4

56
1396.64
P x-y Diagram
Temperature

Dew

121.1

Bubble

110

Dew

0.25

0.20

106
Pressure, Bara

Temperature (Deg C)

108
104

102
100
98

0.15

0.10
0.05

96

94

0.00

0.00

0.20

0.40

0.60

0.80

1.00

0.00

0.20

0.40

0.60

Change the vertical axis manually if graph does not appear properly
T x-y Chart Data
X

P x-y Chart Data


Y

0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

0.00
0.37
0.41
0.43
0.45
0.47
0.50
0.55
0.62
0.75
1.00

Temperature
C
108.9
96.8
95.9
95.5
95.3
95.3
95.5
96.1
97.5
100.2
105.6

Basis
- Vapor pressure is calculated using Antoine Equation :
Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( K ) + C )
- Flash calculations are based on Modified Raoult's Law

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

0.00
0.38
0.41
0.42
0.43
0.45
0.47
0.51
0.57
0.68
1.00

Pressure
Bar A
0.1
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.1

0.80

1.00