CAREER POINT
CAREER
POINT
KVPYQUESTIONPAPER2014(STREAMSX)
Part I
One  Mark Questions
Date : 02 / 11 / 2014
MATHEMATICS
1.
Let C0 be a circle of radius 1. For n 1, let Cn be a circle whose area equals the area of a square inscribed in
Cn 1. Then
i 0
(A) 2
Ans.
(B)
(C)
(D)
2
2
[D]
Sol.
Area(C ) = r
i
2
0
i =0
2 rn 1
Cn1
2
2
so r12 = r02, r22 = r12
22
= r02
2
2
2
2
r32 =
r22 =
r02
( )
So
Area(C ) = r
i
i =0
2
0
2 2 2 2 2
r0 + . r0 + ....
2 r02
r02
r0 = 1
=
2
2
1
=
2
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CAREER POINT
For a real number r we denote by [r] the largest integer less than or equal to r. If x, y are real numbers with
x, y 1 then which of the following statements is always true?
(A) [x + y] [x] + [y]
x [x ]
(D)
[ y]
y
Ans.
[D]
Sol.
wrong
1
2
1
1
2. 2 [2] 2
1 0 wrong
(C) [2x] 2[x]
x = 0.99 [20.99] 2[0.99]
[20.99] 2 = 1 wrong
x [x ]
(D)
[ y]
y
given x, y 1
x
if x < y = 0
y
[x ]
true
[ y]
x [x ]
if x y
always true
[ y]
y
3.
For each positive integer n, let An = max  0 r n . Then the number of elements n in {1,2,,20} for
r
which 1.9
(A) 9
Ans.
An
2 is
A n 1
(B) 10
(C) 11
(D) 12
[C]
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CAREER POINT
n
n 1
Cn / 2
=2
C n 11
2
An
=
A n 1
C n 1
n 1
C n 1
2n
n +1
4.
Let b, d > 0. The locus of all points P(r, ) for which the line OP (where O is the origin) cuts the line r sin = b
in Q such that PQ = d is
Ans.
Sol.
(A) (r d) sin = b
(B) (r d) sin = b
(C) (r d) cos = b
(D) (r d) cos = b
[B]
(x, y)
P(r, )
y
d
Q
y=b
r
O
(0, 0)
equation of OP
y = x tan
point Q is (b cot , b)
point P is y = b d sin
r sin = b d sin
(r m d) sin = b
5.
Let C be the circle x2 + y2 = 1 in the xyplane. For each t 0, let Lt be the line passing through (0, 1) and
(t, 0). Note that Lt intersects C in two points, one of which is (0,1). Let Qt be the other point. As t varies
between 1 and 1 +
2 , the collection of points Qt sweeps out an arc on C. The angle subtended by this arc at
(0, 0) is
(A)
Ans.
(B)
(C)
(D)
3
8
[B]
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CAREER POINT
x2 + y2 = 1
x
y
+
=1
Lt
t
1
x
y=1
t
x2 + 1 +
2x
x2
=1
2
t
t
1 2x
x2 1 + 2
=0
t
t
x = 0,
2
1
x 1 + 2 =
t
t
y=1
x=
2
2t
; y=1 2
t2 +1
t +1
(0, 1)
y=
t2 1
t2 +1
2t
t2 1
Qt
,
2
2
1
+
t
t
+
1
1t1+
t = tan
Qt (sin 2, cos 2)
45 , 67
2
lies on circle C
1 1
,
2 2
/4
so angle at centre =
6.
Ans.
Sol.
(1, 0)
Q
In an ellipse, its foci and the ends of its major axis are equally spaced. If the length of its semiminor axis is
2 2 , then the length of its semimajor axis is
(A) 4
[D]
(C) 10
(B) 2 3
(D) 3
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CAREER POINT
AS = SS = SA
2ae = a ae
3ae = a
e = 1/3
7.
1
8
b2
b2
=
=
2
2
9
9
a
a
8
8
=
a=3
2
9
a
Let ABC be a triangle such that AB = BC. Let F be the midpoint of AB and X be a point on BC such that FX
is perpendicular to AB. If BX = 3XC then the ratio BC/AC equals
(A)
Ans.
(B)
(C)
3
2
(D) 1
[C]
Sol.
A
2y
F
2y
B
3y
Q cos B =
2
3
Also cos B =
16 y 2 + 16 y 2 AC 2
2.4 y.4 y
32 y 2 AC 2
2
=
3
32 y 2
64y2 = 96y2 3AC2
3AC2 = 32y2
AC =
4 2
3
4y
BC
=
=
AC
4 2y
3
2
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1
2
cos x
(A) 6
(B) 4
(C) 2
(D) 0
Ans.
[B]
Sol.
cos4x sin4x =
= sin4 x +
1
sin 2 x
1
1
2
sin x
cos 2 x
(cos2x sin2x) =
cos 2x =
CAREER POINT
(cos 2 x sin 2 x )
sin 2 x cos 2 x
4 cos 2x
sin 2 2x
cos 2x (1 4 cosec22x) = 0
cos 2x = 0
2x = 2n
x = n
At n = 0, x =
9.
n = 1; x =
5 3
,
4
4
n = 2, x =
7
4
x + 5
if x 2
. Then f (f (x)) is discontinuous
if x = 2
Ans.
[B]
Sol.
discontinuous at x = 2
x +5
f(f(x)) = f
x 2
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CAREER POINT
x+5
+ 5
x2
= 6x 5
=
x+9
x+5
x2
6x 5
9x
At x = 9 it is discontinuous
10.
For a real number x let [x] denote the largest number less than or equal to x. For x R let f (x) = [x] sin x.
Then
(A) f is differentiable on R.
(B) f is symmetric about the line x = 0.
(C)
f ( x )dx = 0 .
(D) For each real , the equation f (x) = 0 has infinitely many roots.
Ans.
[D]
Sol.
f (x)dx 0
(B) 4
(C) 2
(D) 0
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[B]
Sol.
sin x x Q
f(x) = 2
tan x x Q
CAREER POINT
if is continuous at x = 0,
so 2 points
sinx = tan2x sin x(cos2x sin x) = 0
sin x = 0
x = 0,
sin2x + sinx 1 = 0
1 5
2
sinx =
5 1
2 values
2
sinx =
Total 4 points
1
12.
(A)
e x f ( x )dx 10
(B)
f (x )
(1 + x)
dx 10
(C) 10
sin(100x ) f (x) dx 10
(D)
Ans.
[D]
Sol.
Q f(x) 0
f (x)
dx 100
f (x)
because (f(x))2 can take very high values then area bounded by (f(x))2, xaxis & x = 0 to 1 may cross 100.
13.
true?
(A) f (x + y) = f (x) + f (y)
(D) f (x + y) = f (xy)
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CAREER POINT
[C]
x
Sol.
(x) = x +
(t)dt
0
(x) = 1 + (x)
(x) (x) = 1
ex(x) (x) ex = ex
d
((x) ex) = ex
dx
(x) ex =
ex
+c
1
(x) = 1 + cex
(0) = 0 = 1 + ce0 c = 1
(x) = ex 1
(x) + (y) + (x) (y) = ex 1 + ey 1 + (ex 1) (ey 1)
= ex 1 + ey 1 + ex.ey ey ex + 1
= ex.ey 1 = ex + y 1
= (x + y)
14.
For a real number x let [x] denote the largest integer less than or equal to x and {x} = x [x]. Let n be a
n
cos(2[x]{x}) dx is equal to
0
(A) 0
Ans.
(B) 1
(C) n
(D) 2n 1
[B]
n
Sol.
cos(2[x]{x}) dx
0
cos(0) dx +
= (1 0) +
cos(2( x 1)) dx +
cos(4( x 2)) dx + +
cos(2(n 1) (x (n 1))) dx
n 1
n 1
sin 2x
sin 4x
+
=1+
2 1
4
sin 2(n 1) x
+ +
2(n 1)
n 1
=1+0=1
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Ans.
Sol.
16.
Ans.
Sol.
CAREER POINT
Two persons A and B throw a (fair) die (sixfaced cube with faces numbered from 1 to 6) alternately, starting
with A. The first person to get an outcome different from the previous one by the opponent wins. The
probability that B wins is
5
6
7
8
(A)
(B)
(C)
(D)
6
7
8
9
[B]
6 5
6 1 1 5
6 1 1 1 1 5
P= . + . . . + . . .
. . + ..
6 6
6 6 6 6
6 6 6 6 6 6
5
5
5
=
+ 3 + 5 +
6
6
6
30
6
5/6
=
=
=
1
35
7
1
36
Let n 3. A list of numbers x1, x2,, xn has mean and standard deviation . A new list of numbers
x + x2
x + x2
y1, y2,, yn is made as follows: y1 = 1
, y2 = 1
and yj = xj for j = 3,4,, n. The mean and the
2
2
standard deviation of the new list are and . Then which of the following is necessarily true?
(A) = and
(B) = and
(D)
(C) =
[B]
x + x 2 + ...... + x n
= 1
n
x1 + x 2 x1 + x 2
+
+ x 3 + .... + x n
y1 + y 2 + ...... + y n
2
2
=
=
n
n
x + x 2 + x 3 + ..... + x n
= =
= 1
n
x i2
2 =
2
n
x 2 + x 22 + .... + x 2n
2 = 1
2
n
.... (1)
x + x2
x1 + x 2
+ x 32 + .....x 2n
+ 1
2
2
2
y1 + y 2 + .... + y n
2
2
2
2
=
=
2
n
n
x 12 + x 22
+ x 1 x 2 + x 32 + ... + x 2n
2
2
=
2
...(2)
n
x 2 + x 22 x 12 + x 22 + 2x 1 x 2
x 2 + x 22 2x 1 x 2
= 1
2 2 = 1
n
2n
2n
2
(x 1 x 2 )
=
0 & =
2n
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Ans.
Sol.
CAREER POINT
(B) cos1
2
1
(C) cos1
3
(D) cos1
3
[C]
r
C (c)
r
A (a )
r r r
a , b, c are unit vectors
r
B ( b)
r r r r r r
a ^b = b^c =c^a =
3
r r r r
o + a +b +c
centre p
a
b
4
4
AP BP
= r r r
cos =
r r r r
a +b +c r a +b +c
 AP   BP 
a
b
4
4
r r r r r r
(b + c 3a ) (a + c 3b)
= r r r r r r
 b + c 3a   a + c 3b 
r r
r
r r r
r
r r
r r
r r r r
a b + b c 3b 2 + a c + c 2 3b c 3a 2 3a c + 9a b
=
r
r r
r
r
r r
r r
(b 2 + c 2 + 9a 2 + 2b c 6a c 6a b)
1 1
1
3
3 9
+ 3 + +1 3 +
2
2
2
2
2 2
=
1+1+ 9 +1 3 3
=
5 + 3
1
=
6
3
1
= cos 1
3
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Let S = {(a, b) : a, b Z, 0 a, b 18}. The number of elements (x, y) in S such that 3x + 4y + 5 is divisible
by 19 is
(A) 38
Ans.
Sol.
CAREER POINT
(B) 19
(C) 18
(D) 1
[B]
3x + 4y + 5 = 19 I
5 (3x + 4y + 5) 131
5 19 I 131
Case (i)
3x + 4y + 5 = 19
3x + 4y = 14
y=
14 3x
4
Case (ii) 3x + 4y + 5 = 38
3x + 4y = 33
4y = 33 3x
y=
x=2
Case (iii)
3x + 4y = 52
x=
52 3x
4
x = 0, 4, 8, 12, 16
33 3x
4
x = 3, 7, 11
Case (iv) 3x + 4y = 71
4y = 71 3x
y=
Case (v) 3x + 4y = 90
71 3x
4
y=
Case (vi)
90 3x
4
x = 6, 10, 14, 18
3x + 4y = 109
y=
109 3x
4
x = 15 is only possibility.
x = 1, 5, 9, 13, 17
Total Solution = 19
19.
For a real number r let [r] denote the largest integer less than or equal to r. Let a > 1 be a real number which
is not an integer and let k be the smallest positive integer such that [ak] > [a]k. Then which of the following
statements is always true?
(A) k 2 ([a] + 1)2
(B) k ([a] + 1)4
1
+1
(C) k 2[a]+1
(D) k
a [a ]
Ans.
Sol.
[B]
By taking different values of a & k.
option (B) is possible.
20.
Let X be a set of 5 elements. The number d of ordered pairs (A, B) of subsets of X such that A , B ,
A B = satisfies
(A) 50 d 100
(B) 101 d 150
(C) 151 d 200
Ans.
[C]
Sol.
(D) 201 d
3!
4!
4! 2! 5 5!
5!
2! + 5C4
C2 . 2! + 5C3
2!+
+ C5
2!+
2!
2! 2! 2!
2! 3!
1! 2!
1! 3!
1! 4!
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CAREER POINT
PHYSICS
21.
A uniform thin rod of length 2L and mass m lies on a horizontal table. A horizontal impulse J is given to the
rod at one red. There is no friction. The total kinetic energy of the rod just after the impulse will be
(A)
Ans.
Sol.
J2
2m
(B)
J2
m
(C)
2J 2
m
(D)
6J 2
m
[C]
2L
CM
J = mv
where v is the velocity of centre of mass.
After impulse rod get angular velocity
Angular impulse = I
.... (1)
m( 2 L) 2
12
mL
J=
3
JL =
....(2)
3J
mL
J
m
1
1
Kinetic energy = KE = mv 2 + I2
2
2
from equation (1); v =
22.
1 J 2 1 m 4L2
9J 2
m 2 +
2 2
2 m
2
12
m L
J 2 36J 2
+
2m 24m
48J 2
2J 2
24m
m
A solid cylinder P rolls without slipping from rest down an inclined plane attaining a speed vP at the bottom.
Another smooth solid cylinder Q of same mass and dimensions slides without friction from rest down the
vQ
inclined plane attaining a speed vQ at the bottom. The ratio of the speeds
vP
(A)
Ans.
Sol.
3/ 4
(B)
(C)
3/ 2
2/ 3
is
(D)
4/ 3
[B]
If perfect rolling (solid cylinder P)
According to energy conservation law
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1
1 v
mgh = mv 2P + I P
2
2 R
CAREER POINT
Here,
I moment of inertia, R Radius
I=
mR 2
2
vP
R
mgh =
1
1 mR 2 v 2P
mv 2P +
2
2 2 R2
mgh =
1
3
1 1
mv 2P 1 + = mv 2P
2
2
2 2
mgh =
3
mv 2P
4
v 2P =
4
gh
3
.... (1)
1
mv Q2
2
v Q2 = 2gh
.... (2)
23.
3
2gh
=
2
4
gh
3
3
2
A body moves in a circular orbit of radius R under the action of a central force. Potential due to the central
force is given by V(r) = kr (k is a positive constant). Period of revolution of the body is proportional to(A) R1/2
Ans.
[A]
Sol.
F=
(B) R1/2
(C) R3/2
dU
d
=
[qV]
dr
dr
(D) R5/2
q constant
dV
F=q
dr
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CAREER POINT
v = kr
dV
= k
dr
F = qk
m2R = qk
2
2
m R = qk
T
m ( 4 2 ) R
= qk
T2
2 R
R1/2
24.
A simple pendulum is attached to the block which slides without friction down an inclined plane (ABC)
having an angle of inclination as shown.
While the block is sliding down the pendulum oscillates in such a way that its mean position the direction of
the string is(A) at angle to the perpendicular to the inclined plane AC .
(B) parallel to the inclined plane AC.
(C) vertically downwards
(D) perpendicular to the inclined plane AC.
Ans.
[D]
Sol.
Block slides downward along the inclined plane with acceleration g sin .
mg sin
(pseudo force) C
T
mg
mg sin
2
mg sin
mg sincos
90
mg
At equilibrium
T = FNet
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CAREER POINT
mg sincos
FNet
mg[1 sin2 ] mgcos2
tan =
mg cos 2
mg sin cos
tan = cot
tan = tan (90 )
= (90 )
string is perpendicular to inclined plane .
90
25.
Water containing air bubbles flows without turbulence through a horizontal pipe which has a region of
narrow crosssection. In this region the bubbles
(A) move with greater speed and are smaller than in the rest of the pipe
(B) move with greater speed and are larger in size than in the rest of the pipe
(C) move with lesser speed and are smaller than in the rest of the pipe
(D) move with lesser speed and are of the same size as in the rest of the pipe
Ans.
[B]
Sol.
26.
A solid expands upon heating because(A) the potential energy of interaction between atoms in the solid is asymmetric about the equilibrium
positions of atoms.
(B) the frequency of vibration of the atoms increases.
(C) the heating generates a thermal gradient between opposite sides.
(D) a fluid called the caloric flows into the interatomic spacing of the solid during heating thereby expanding
it.
Ans.
[A]
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CAREER POINT
Consider two thermometers T1 and T2 of equal length which can be used to measure temperature over the
range 1 to 2. T1 contains mercury as the thermometric liquid while T2 contains bromine. The volumes of
the two liquids are the same at the temperature 1. The volumetric coefficients of expansion of mercury and
bromine are 18 105 K1 and 108 105 K1, respectively . The increase in length of each liquid is the same
for the same increase in temperature. If the diameters of the capillary tubes of the two thermometers are d1
and d2 respectively, then the ratio d1 : d2 would be closest to
(A) 6.0
(B) 2.5
(C) 0.6
(D) 0.4
Ans.
Sol.
[D]
Increase in length of each liquid is same
l = l
VHg
d12
VBro min e
d 22
(V ) Hg
d12
V Bro min e
d 22
Hg
d1
18 10 5
=
=
d
Bro min e
108 10 5
2
d1
=
d2
28.
1
~ 0.4
6
An ideal gas follows a process described by PV2 = C from (P1, V1, T1) to (P2, V2, T2) (C is a constant). Then
(A) if P1 > P2 then T2 > T1
(B) if V2 > V1 then T2 < T1
(C) if V2 > V1 then T2 > T1
Ans.
Sol.
[B]
PV2 = C
nRT 2
V = C
TV = C
T1V1 = T2V2
29.
A whistle emitting a loud sound of frequency 540 Hz is whirled in a horizontal circle of radius 2 m and at a
constant angular speed of 15 rad/s. The speed of sound is 330 m/s. The ratio of the highest to the lowest
frequency heard by a listener standing at rest at a large distance from the center of the circle is
(A) 1.0
(B) 1.1
(C) 1.2
(D) 1.4
Ans.
[C]
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CAREER POINT
Sol.
v2
O
r = 2m
(person)
A
v1
v vs
Minimum frequency heard
v
fmin = f
v + vs
f max v + v s
330 + 30 360
=
=
=
f min v v s
330 30 300
f max
6
=
= 1.2
f min
5
30.
Monochromatic light passes through a prism. Compared to that in air, inside the prism the light's
(A) speed and wavelength are different but frequency remains same.
(B) speed and frequency are different but wavelength remains same.
(C) wavelength and frequency are different, but speed remains same.
(D) speed, wavelength and frequency are all different.
Ans.
Sol.
[A]
On refraction of light, frequency remain unchanged. However speed and wavelength get change.
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CAREER POINT
31.
The flat face of a planoconvex lens of focal length 10 cm is silvered. A point source placed 30 cm in front
of the curved surface will produce a
(A) real image 15 cm away from the lens
(B) real image 6 cm away from the lens
(C) virtual image 15 cm away from the lens
(D) virtual image 6 cm away from the lens
Ans.
Sol.
[B]
f = 10 cm
After silvering of flat face lens behave as mirror of focal length feq.
(1)
(2)
(3)
1
1
1 1
= +
+
f eq
f1 f 2 f 3
1
2
1
= +
f eq
f1 f 2
2
1
1
=
+
10
f eq
feq = 5
30 cm
mirror formula
1
1 1
= +
f
u v
1
1
1
=
+
5
30
v
v = 6 cm
Image is real and 6 cm away from silvered lens.
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CAREER POINT
32.
Two identical metallic square loops L1 and L2 are placed next to each other with their sides parallel on a
smooth horizontal table. Loop L1 is fixed and a current which increases as a function of time is passed
through it. Then loop L2
(A) rotates about its center of mass
(B) moves towards L1.
(C) remains stationary
(D) moves away from L1
Ans.
Sol.
[D]
Fixed
L2
L1
When current through L1 increases then flux linked through L2 will increase.
According to lenz law L2 will move away.
33.
An electron enters a parallel plate capacitor with horizontal speed u and is fond to deflect by angle on
leaving the capacitor as shown. It is found that tan = 0.4 and gravity is negligible
r
u
++++++
Ans.
Sol.
(B) 0.2
(C) 0.8
(D) 1.6
[A]
vy
vnet
v
x
r
u
E
l
Horizontal displacement = l
t=
l
u
vy = uy + at
=0+
l
eE
m
u
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CAREER POINT
l
eE
m
u
vy
vx
eEl
eE l
1
=
m u
u
mu 2
1
u2
tan =
34.
Consider a spherical shell of radius R with a total charge +Q uniformly spread on its surface (center of the
shell lies at the origin x= 0). Two point charge, +q and q are brought, one after the other, from far away
and placed at x = a/2 and x = + a/2 (a < R), respectively. Magnitude of the work done in this process is
(A) (Q + q)2 /40a
Ans.
Sol.
1
th.
4
(C) q2 /40a
(B) zero
(D) Qq /40a
[C]
y
+
Q+
+
+
+
q
+q
+
+
+
+
+
+ + +
Q2
8 0 R
kQ(q)
q (q) kQ q
Q2
Q2
q2
+
+
+
R
R
8 0 R
4 0 a
8 0 R
4 0 a
q2
4 0 a
q2
4 0 a
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CAREER POINT
Two identical parallel plate capacitors of capacitance C each are connected in series with a battery of emf, E
as shown. If one of the capacitors is now filled with a dielectric of dielectric constant k, the amount of charge
which will flow through the battery is (neglect internal resistance of the battery)
C
C
E
(A)
Ans.
Sol.
k +1
CE
2(k 1)
(B)
k 1
CE
2(k + 1)
(C)
k2
CE
k+2
(D)
k+2
CE
k2
[B]
E
Initial charge on both C =
CE
2
kC
E
kC
New charge on each C =
E
k +1
Change in charge on C is supplied by battery
CE
kC
Charge supply by battery =
E
2
+
k
1
1
k
CE
k
+
1
2
k 1
CE
2(k + 1)
Charge passes through battery is change supply by battery
k 1
Ans. CE
2(k + 1)
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CAREER POINT
36.
A certain pn junction, having a depletion region of width 20 m, was found to have a breakdown voltage of
100 V. If the width of the depletion region is reduced to 1 m during its production, then it can be used as a
Zener diode for voltage regulation of (A) 5 V
(B) 10 V
(C) 7.5 V
(D) 2000 V
Ans.
Sol.
[A]
Break down voltage is proportional to width of depletion region.
1
1
times then break down voltage also become
times thus it
When width reduce to 1 m thus become
20
20
become 5 volt. So Zener diode can used for voltage regulation of 5 volt.
37.
The half life of a particle of mass 1.6 1026 kg is 6.9 s and a stream of such particles is travelling with the
kinetic energy of a particle being 0.05 eV. The fraction of particles which will decay when they travel a
distance of 1 m is (A) 0.1
(B) 0.01
(C) 0.001
(D) 0.0001
Ans.
[D]
Sol.
KE =
1
mv2
2
1
1.6 1026 v2
2
0.05 2 107 = v2
106 = v2
v = 1000 m/sec
time taken to travel a distance of 1 m is
1
1
= 0.001 sec
v
1000
0.693
0.693
0.1
6.9
1
sec = 1 et
1000
1
0.1
1000
1
10000
0.0001
38.
A 160 watt light source is radiating light of wavelength 6200 uniformly in all directions. The photon flux
at a distance of 1.8 m is of the order of (Planck's constant 6.63 1034 Js)
(A) 102 m2 s1
(B) 1012 m2 s1
(C) 1019 m2 s1
(D) 1025 m2 s1
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CAREER POINT
Ans.
[C]
Sol.
P
4(1.8) 2
160
4 (1.8) 2
I
hc
I
hc
160 6200 10 10
4 (1.8) 2 6.63 10 34 3 108
1.22 1019
39.
The wavelength of the first Balmer line caused by a transition from the n = 3 level to the n = 2 level in
hydrogen is 1. The wavelength of the line caused by an electronic transition from n = 5 to n = 3 is (A)
375
1
128
Ans.
[B]
Sol.
1
1
1
=R 2 2
1
3
2
(B)
125
1
64
(C)
64
1
125
(D)
128
1
375
1
1 1
=R
1
4 9
1
5
=R
1
36
....(1)
1
1 1
=R
2
9 25
1
16
=R
2
9 25
....(2)
1
36 9 25
2 =
5
9 25 125
=
1
36
16
64
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CAREER POINT
40.
The binding energy per nucleon of 5B10 is 8.0 MeV and that of 5B11 is 7.5 MeV. The energy required to
remove a neutron from 5B11 is (mass of electron and proton are 9.11 1031 kg and 1.67 1027 kg,
respectively) (A) 2.5 MeV
(B) 8.0 MeV
(C) 0.5 MeV
(D) 7.5 MeV
Ans.
Sol.
[A]
neutron
5B
11
11
of 5 B
Breaking
energy given E1
5B
10
CHEMISTRY
41.
When 1.88 g of AgBr(s) is added to a 103 M aqueous solution of KBr, the concentration of Ag is 51010 M. If
the same amount of AgBr(s) is added to a 102 M aqueous solution of AgNO3, the concentration of Br is
(A) 9.4 109 M
(B) 5 1010 M
(C) 1 1011 M
(D) 5 1011 M
Ans.
Sol.
[D]
Ksp(AgBr) = [Ag+] [Br]
= (5 1010) (103)
= 5 1013
Now
5 1013 = (102) [Br]
[Br] = 5 1011 M
42.
NH2
Br
Br
Br
(B)
(A)
Ans.
Br
(C)
Br
Br
NH2
NH2
(D)
Br
Br
Br
Br
Br
[A]
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CAREER POINT
Sol.
Highly activating
NH2
NH2
Br2/H2O
Bromination
Br
Br
Br
2,4,6Tribromoaniline
43.
The metal with the highest oxidation state present in K2CrO4, NbCl5 and MnO2 is (A) Nb
(B) Mn
(C) K
(D) Cr
Ans.
[D]
Sol.
44.
Ans.
Sol.
[B]
Total 3 geometrical isomers are possible Cl
Cl
(1)
en
(2)
Cr
Cr
NH3
(3)
NH3
en
Cl
NH3
Cl
NH3
Trans
NH3
Cis
en
Cr
Cl
NH3
Cl
Trans
45.
Ans.
Sol.
The element that combines with oxygen to give an amphoteric oxide is (A) N
(B) P
(C) Al
(D) Na
[C]
Aluminium form amphoteric oxide with oxygen (Al2O3)
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CAREER POINT
In k
I/T
Ans.
Sol.
47.
Ans.
Sol.
The graph suggests that (A) EI > EII and AI > AII
(C) EI > EII and AII > AI
[A]
For plot between In k v/s 1/T yintercept is ln A
E a
& slope is
R
therefore; EII < EI and AI > AII
Ni(CO)4 is
(A) tetrahedral and paramagnetic
(B) square planar and diamagnetic
(C) tetrahedral and diamagnetic
(D) square planar and paramagnetic
[C]
Ni exist in zero oxidation state so its configuration is its configuration is 8
2
28Ni = [Ar] 3d 4s
3d8
4s2
4p0
48.
2. O H
Ans.
o

(B)
(C) o
(D)
[A]
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CAREER POINT
Sol.
O
(i) Ozonolysis
O
OH
Intramolecular
aldol reaction
6
5
4
49.
O
1
O
H2O
2
3
CH3
OH
CH3
CHO
H
HO
H
H
OH
H
OH
OH
CH2OH
HO
HO
(A)
H
H
H
H
OH
OH
HO
H
(B)
HO
HO
CH2OH
Ans.
Sol.
CHO
CHO
H
OH
H
H
H
HO
(C)
H
HO
CH2OH
OH
H
OH
H
CH2OH
CHO
HO
H
(D)
HO
H
H
OH
H
OH
CH2OH
[B]
CHO
H
HO
H
H
CHO
OH
H
OH
OH
HO
H
HO
HO
H
OH
H
H
CH2OH
CH2OH
D(+) Glucose
L() Glucose
Enantiomer
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Ans.
Sol.
In a cubic close packed structure, fractional contributions of an atom at the corner and at the face in the unit
cell are, respectively (A) 1/8 and 1/2
(B) 1/2 and 1/4
(C) 1/4 and 1/2
(D) 1/4 and 1/8
[A]
1
Corner
8
1
Face
51.
Ans.
[A]
Sol.
CAREER POINT
[B][C]
& KC = 0.5
[A 2 ]
(10 2 ) (10 2 )
= 100
[10 3 ]2
52.
Major products formed in the reaction of tbutyl methyl ether with HI are (A) H3C I and
(C) H3C OH and
OH
(B)
(D)
and H3C OH
and H3C OH
I
Ans.
Sol.
[C]
CH 3
CH 3


HI
CH 3 C O CH 3
CH 3 C I + CH 3OH
SN1


CH 3
CH 3
If one of the alkyl group is 3. Then mechanism is SN1 and nucleophile attach to the carbon where
carbocation more stable.
53.
Ans.
If the molar conductivities (in S cm2 mol1) of NaCl, KCl and NaOH at infinite dilution are 126, 150 and 250
respectively, the molar conductivity of KOH (in S cm2 mol1) is (A) 526
(B) 226
(C) 26
(D) 274
[D]
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CAREER POINT
Sol.
126 = Na + + Cl
150 = K + + Cl
250 = Na + + OH
(150 + 250 126) = K + + OH
KOH = 274
or
54.
4Formylbenzoic acid on treatment with one equivalent of hydrazine followed by heating with alcoholic
KOH gives the major product O
NNH2
(A)
(B)
(C)
(D)
NHNH2
Ans.
Sol.
OK
H2NN
OK
[B]
COOH
COOH
COOH
NH2NH2
CHO
AlC.KOH
CH=NNH2
CH3
C=O
55.
Ans.
Sol.
in
Two elements, X and Y, have atomic numbers 33 and 17, respectively. The molecular formula of a stable
compound formed between them is (A) XY
(B) XY2
(C) XY3
(D) XY4
[C]
Atomic no. 33 and 17 belongs to 15th & 17th group respectively therefore covalent bond form between both
elements
X+3
Y1 Atomic no. 33 = As
XY3
Atomic no. 17 = Cl
AsCl3
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CAREER POINT
56.
The number of moles of KMnO4 required to oxidize one equivalent of KI in the presence of sulfuric acid is (A) 5
(B) 2
(C) 1/2
(D) 1/5
Ans.
[D]
Sol.
v.f = 1
57.
Three successive measurements in an experiment gave the values 10.9, 11.4042 and 11.42. The correct way
of reporting the average value is (A) 11.2080
(B) 11.21
(C) 11.2
(D) 11
Ans.
[C]
Sol.
The correct way of reporting the average value should have exactly the same number of digit after decimal
which has least digit after decimal among the data given.
58.
The latent heat of melting of ice at 0 C is 6 kJ mol1. The entropy change during the melting in J K1 mol1
is closest to (A) 22
Ans.
[A]
Sol.
S =
(B) 11
H Melting
TF.P
(C) 11
(D) 22
6 1000 J
273
K
= 21.978 22J/k
59.
Cu,
is
(A)
(B)
I
I
(C)
(D)
I
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CAREER POINT
[A]
Cu,
I
This is example of
Ulman reaction which
gives product like Wurtz
reaction.
60.
The energies of dxy and d 2z orbitals in octahedral and tetrahedral transition metal complexes are such that (A) E (dxy) > E ( d 2z ) in both tetrahedral and octahedral complexes
(B) E (dxy) < E ( d 2z ) in both tetrahedral and octahedral complexes
(C) E (dxy) > E ( d 2z ) in tetrahedral but E (dxy) < E ( d 2z ) in octahedral complexes
(D) E (dxy) < E ( d 2z ) in tetrahedral but E (dxy) > E ( d 2z ) in octahedral complexes
Ans.
[C]
Sol.
Energy of d z 2 is greater than dxy in case of octahedral crystal field while energy of d z 2 is less than dxy in
case of tetrahedral splitting
d x 2 y2 d z2
eg
3/5 0
Average energy
of the dorbital in
spherical crystal field
2/5 0
t2 g
dxy dyz dzx
[Spliting in octahedral crystal field]
t2 g
2/5 t
Average energy
of the dorbital in
spherical crystal field
3/5 t
eg
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CAREER POINT
BIOLOGY
61.
In which of the following types of glands is the secretion collected inside the cell and discharged by
disintegration of the entire gland ?
(A) Apocrine
(B) Merocrine
(C) Holocrine
(D) Epicrine
Ans.
Sol.
[C]
Holocrine gland distingrate completely for discharge of secretion.
62.
Ans.
Sol.
[D]
Interspecific competition doesn't lead to coevolution
63.
Ans.
Sol.
[B]
Tropical rain forest shows vertical zonation i.e. stratification.
64.
(D) Diencephalon
Ans.
Sol.
[D]
Cavity of Diancephelon is called as diocoel or third ventricle.
65.
Ans.
Sol.
[C]
Gene is a segment of genetic material which produces either polypeptide or a RNA [rRNA or tRNA]
66.
Forelimbs of whales, bats, humans and cheetah are examples of which of the following processes ?
(A) Divergent evolution
(B) Convergent evolution
(C) Adaptation
(D) Saltation
Ans.
Sol.
[A]
Fore limbs of whale, bat, human & cheetah are homologous organ which represents divergent evolution.
67.
Ans.
Sol.
(D) Recombination
[D]
Conjugation in paramecium results in recombination
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Ans.
Sol.
69.
Ans.
Sol.
70.
Ans.
Sol.
71.
Ans.
Sol.
72.
Ans.
Sol.
73.
Ans.
Sol.
74.
Ans.
Sol.
75.
Ans.
Sol.
CAREER POINT
In an experiment investigating photoperiodic response, the leaves of a plant are removed. What is the most
likely outcome ?
(A) Photoperiodism is not affected
(B) Photoperiodic response does not occur
(C) The plant starts flowering
(D) The plant starts to grow taller
[B]
Leaves are the site for photoperiodic perception.
Testosterone is secreted by which endocrine part of testis ?
(A) Leydig cells
(B) Seminiferous tubules (C) Tunica albugenia
[A]
Leydig cells or Interstitial cells of testes secretes testosteron hormone.
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Ans.
Sol.
77.
Ans.
Sol.
CAREER POINT
Two tubes labelled 'P' and 'Q' contain food stuff. Tube 'P' gave positive test with Benedict's solution while
tube 'Q' gave positive test with Nitric acid. Which of the following is correct ?
(A) Tube 'P' contains sugar; tube 'Q' contains protein
(B) Tube 'P' contains protein; tube 'Q' contains sugar
(C) Both, tube 'P' and tube 'Q' contain sugar
(D) Both, tube 'P' and tube 'Q' contain protein
[A]
Nitric acid reacts with proteins to form yellow nitrated products.
Benedict test is used to test the presence of monosaccharide and reducing sugar.
How many linear DNA fragments will be produced when a circular plasmid is digested with a restriction
enzyme having 3 sites ?
(A) 4
(B) 5
(C) 3
(D) 2
[C]
1
restriction enzyme site
fragments of linear DNA
3
Plasmid
78.
Ans.
Sol.
79.
Ans.
Sol.
80.
Ans.
Sol.
If the humidity of the atmosphere suddenly increases substantially, the water flow in the xylem will (A) increase
(B) decrease
(C) remain unaltered
(D) increase sharply and then reduce slowly to the preexisting level
[B]
Humidity of atmosphere is inversely proportional to transpiration (water flow). Increase in humidity will
decrease the water flow in the xylem.
Which one of the following is the complementary sequence for the DNA with 5CGTACTA3
(A) 5TAGTACG3
(B) 5ATCATGC3
(C) 5UTCUTGC3
(D) 5GCUAGCA3
[A]
Double stranded DNA has antiparalllel strands and complementary Nbases
so, 5 CGTACTA 3
3 GCATGAT 5
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CAREER POINT
Part II
Two  Mark Questions
MATHEMATICS
81.
Ans.
Sol.
a n a n 1
a1
+
+ ....... +
S =
a1
a n 1
an
= a1 + a2 + ....... + an
1
1
1
S = (a 1 + a 2 + .... + a n ) +
+ .... +
an
a1 a 2
1
1
1
S = n (a 1 + a 2 + ... + a n ) +
+ .... +
an
a1 a 2
from A.M. H.M.
1
1
1
n 2
(a 1 + a 2 + .... + a n ) +
+ .... +
an
a1 a 2
S n (n 1)
82.
If n is a positive integer and 1 is a cube root of unity, the number of possible values of
n
nk k
e k =0
Ans.
(A) 2
[C]
n
Sol.
(B) 3
(C) 4
(D) 6
k =0
= (1 + )n = (2)n
= (1)n 2n
= e
e ( 1)
2 n
= e (
4
4
cos i sin
3
3
2 n
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cos
n
n
+ i sin
3
3
cos
n
3
CAREER POINT
83.
Suppose a parabola y = ax2 + bx + c has two x intercepts, one positive and one negative, and its vertex is
(2, 2). Then which of the following is true?
(A) ab > 0
(B) bc > 0
(C) ca > 0
(D) a + b + c > 0
Ans.
Sol.
[B]
The graph according to the question is
2
x
(0, c)
2
84.
Let n 3 and let C1, C2, .., Cn, be circles with radii r1, r2, .., rn, respectively. Assume that Ci and Ci+1
touch externally for 1 i n 1. It is also given that the xaxis and the line y = 2 2 x + 10 are tangential to
each of the circles. Then r1, r2, .., rn are in (A) an arithmetic progression with common difference 3 + 2
(B) a geometric progression with common ratio 3 + 2
(C) an arithmetic progression with common difference 2 + 3
(D) a geometric progression with common ratio 2 + 3
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CAREER POINT
[D]
y
tan = 2 2
(0, 10)
r3
r2
r1
/2
y
O
5
,0
2
tan =
2 tan / 2
1 tan 2 / 2
2 2=
2 tan / 2
1 tan 2 / 2
2 tan2 /2 + tan 2 = 0
tan /2 =
1 3
1 1+ 8
2 2
1
2 2
or 2
2
3
tan /2 =
r1
ON
In OMN sin /2 =
ON =
sin /2 =
1
3
3r1
In OPQ sin /2 =
3r1 + r1 + r2 =
r2
ON + r1 + r2
r2
3r1 + r1 + r2
3r2
r1 ( 3 +1) = r2 ( 3 1)
r2
3 +1
=
r1
3 1
=
( 3 + 1) 2
=2+ 3
2
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CAREER POINT
The number of integers n for which 3x3 25x + n = 0 has three real roots is (A) 1
(B) 25
(C) 55
(D) infinite
[C]
x(3x2 25) = n
25
3x x 2 = n
3
25
25
= n
3x x
x+
3
3
250
9
y = n
x
25
25
3
250
0,
9
250 250
n
,
9
9
But n I
Total integer = 55
86.
An ellipse inscribed in a semicircle touches the circular arc at two distinct points and also touches the
bounding diameter. Its major axis is parallel to the bounding diameter. When the ellipse has the maximum
possible area, its eccentricity is (A)
(B)
Ans.
Sol.
1
2
(C)
1
3
(D)
2
3
[D]
x
(0, b)
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x2
y2
+
=1
a2
b2
and circle x2 + (y + b)2 = r2
CAREER POINT
Let ellipse
{let radius = r}
2 2
put x2 = a2
a y
b2
in circle a2
a 2 y2
+ (y + b)2 = r2
b2
a2
1 2 y2 + 2by + (a2 + b2 r2) = 0
b
D = 0 r2 =
a4
a b2
b = a 1
a2
r2
Area = = ab = a2 1
a2
r2
2r 2
2
d
= 0 a2 =
a=
r
3
da
3
b = a 1
a
2
2
e=
=
3
3
3
/2
87.
Let In =
I n 2
In
n! + (n 2)! equals 
Then
n =2
(A) e/2 1
Ans.
[A]
Sol.
In =
/ 2
(B) e/2 1
(C) e/2
(D) e/2
x n cos x dx
I
= x n sin x
/ 2
0
II
/ 2
n x n 1 sin x dx
= 0 n x n 1 ( cos x )
2
n
= 0 n(n 1)
2
/ 2
/2
0
/ 2
n (n 1) x n 2 ( cos x ) dx
x n 2 cos x dx
In = n(n 1)In2
2
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CAREER POINT
n (n 1)I
n2
In
2
In 2
In 2
=
+
+
n ! (n 2)! n =2
n!
(n 2)!
n =2
n 1
2 n !
n =2
1 1 1
=
+
+
+ ....
2 2! 2 3! 2 4!
= e/2 1
2
88.
For a real number x let [x] denote the largest integer less than or equal to x. The smallest positive integer n
n
Ans.
(A) 8
[B]
Sol.
Let I =
(B) 9
(D) [602/3]
(C) 10
[ x ][
x ] dx
[ x ]= 1
[ x ]= 2
[ x ]= 3
1x<4
4x<9
9 x < 16
Now,
2
10
11
I = dx + 2dx + 3dx + 8dx + 10dx + 12dx + 14dx + 16dx + 27dx + 30dx .....
1
10
I = 1 + 2 + 3 + 8 + 10 + 12 + 14 + 16 = 66
So n = 9
89.
Ans.
Sol.
90.
Ans.
Choose a number n uniformly at random from the set {1, 2, .., 100}. Choose one of the first seven days of
the year 2014 at random and consider n consecutive days starting from the chosen day. What is the
probability that among the chosen n days, the number of Sundays is different from the number of Mondays?
1
2
12
43
(B)
(C)
(D)
(A)
2
7
49
175
[*]
Let S = {(a, b)a, b Z, 0 a, b 18}. The number of lines in R2 passing through (0, 0) and exactly one
other point in S is (A) 16
(B) 22
(C) 28
(D) 32
[*]
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CAREER POINT
PHYSICS
91.
Ans.
Sol.
A solid sphere spinning about a horizontal axis with an angular velocity is placed on a horizontal surface.
Subsequently it rolls without slipping with an angular velocity of (A) 2/5
(B) 7/5
(C) 2/7
(D)
[C]
Initial sphere is slipping and finally it start rolling. During its motion about point of contact is zero.
Angular momentum of sphere about point of contact remain conserved.
Slipping
v = R
Rolling
I = (I + MR )
2
2
MR2 =
5
=
92.
2
2
2
MR + MR
5
2
7
A horizontal force F is applied to a block X of mass 8 kg such that the block Y of mass 2 kg adjacent to it
does not slip downwards under gravity. There is no friction between the horizontal plane and the base of the
block X. The coefficient of friction between the surfaces of blocks X and Y is 0.5. Take acceleration due to
gravity to be 10 ms2. The minimum value of F is
(A) 200 N
(B) 160 N
(C) 40 N
(D) 240 N
Ans.
[A]
Sol.
a
f = N
N'
Y
2g
8g
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F N = 8a
.(1)
N=2a
.(2)
f = 2g = 20
.(3)
CAREER POINT
N = 20
20
20
= 40
=
0.5
N=
.(4)
N = 2a
N
40
=
= 20 m/s2
2
2
a=
.(5)
93.
The maximum value attained by the tension in the string of a swinging pendulum is four times the minimum
value it attains. There is no slack in the string. The angular amplitude of the pendulum is
(A) 90
Ans.
(B) 60
(C) 45
(D) 30
[B]
Sol.
T2
T1
v=0
mg cos
mg
mg
mv 2
l
.(1)
At point B :
T2 = mg cos
.(2)
According to question
T1 = 4T2
mg +
.(3)
mv 2
= 4 mg cos
l
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mg (4 cos 1) =
CAREER POINT
.(4)
1
mv2 + 0 = 0 + mgl (1 cos )
2
.(5)
1
2
= 60
94.
One mole of a monoatomic ideal gas is expanded by a process described by PV3 = C where C is a constant.
The heat capacity of the gas during the process is given by (R is the gas constant).
(A) 2 R
Ans.
Sol.
(B)
5
R
2
(C)
3
R
2
(D) R
[D]
Monoatomic gas
5
3
n=1
PV3 = C
on comparing with PV = C
Here = 3
Heat capacity
C=
C=
R
R
1 1
R
R
( 2)
2
3
3 1
C=R
2 2
C=R
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Ans.
Sol.
CAREER POINT
A concave mirror of radius of curvature R has a circular outline of radius r. A circular disc is to be placed
normal to the axis at the focus so that it collects all the light that is reflected from the mirror from a beam
parallel to the axis. For r << R, the area of this disc has to be at least
r 6
r 4
r 5
r 4
(A)
(B)
(C)
(D)
4R 4
4R 2
4R 3
R2
[A]
A
d G
d
R
2 cos
R/2
d = radius of disc
A = d2
From similar triangle
R
R
r
2 cos
=
R
R
d
R
2
2 cos
r
2 cos 1
=
d
cos + 1
cos + 1
d=
.r
2 cos 1
sin =
r
cos =
R
R2 r2
R
1/ 2
r2
cos = 1 2
R
1 r2
cos = 1
2 R2
r2
1 cos =
2R 2
r2 r
d=
r2
1
2R 2 21
2
2R
r3
r3
=
d=
2R 2
r2
2R 2 1
2
2R
r 6
A = d2 =
4R 4
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CAREER POINT
The angles of incidence and refraction of a monochromatic ray of light of wavelength at an airglass
interface are i and r, respectively. A parallel beam of light with a small spread in wavelength about a
mean wavelength is refracted at the same airglass interface. The refractive index of glass depends on the
wavelength as () = a + b/2 where a and b are constants. Then the angular spread in the angle of
refraction of the beam is
(A)
sin i
3
cos r
Ans.
[C]
Sol.
Snell law
(B)
2b
(C)
2b tan r
a3 + b
(D)
2b(a + b / 2 ) sin i
sin i = sin r
b
sin i = a + 2 sin r
a2 + b
2b
+ sin r
0 = cos r dr
d
2
3
d 2b sin r
= cos r dr (a2 + b)
97.
dr =
2b d tan r
(a2 + b)
r =
(2b tan r )
(a3 + b)
What are the charges stored in the 1 F and 2 F capacitors in the circuit below, once the currents become
steady ?
4 k
1 k
1F
2 k
4 k
2F
6V
(A) 8 C and 4 C respectively
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CAREER POINT
[B]
4 k
1 k
i
2 k
4 k
1F
i
2F
i
6V
At steady state current does not flow in the branch of capacitor.
we can replace all resistor connected in branch of capacitor with wire
new circuit is
1F
Q Q
1 k
2 k
2F
q q
i
6V
6
(2 + 1) 103
2 mA
Potential drop across 2k is same as potential drop across 1 F & 2 F.
Potential drop across 2 k = i 2 103 = 2 103 2 103 = 4 volt.
Charge on 1F = Q = 1 4 106 = 4 C
Charge on 2F = q = 2 4 106 = 8 C
i=
98.
Ans.
Sol.
A 1.5 kW (kilowatt) laser beam of wavelength 6400 is used to levitate a thin aluminium disc of same area
as the cross section of the beam. The laser light is reflected by the aluminium disc without any absorption.
The mass of the foil is close to
(B) 103 kg
(C) 104 kg
(D) 106 kg
(A) 109 kg
[D]
Power of light = P
Laser beam
mg
Force acting on Al disc =
2P
C
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CAREER POINT
2 1.5 103
3.0 108
= 105
Force acting on Al disc = mg
105 = m 10
m = 106 kg
99.
When ultraviolet radiation of a certain frequency falls on a potassium target, the photoelectrons released can
be stopped completely by a retarding potential of 0.6 V. If the frequency of the radiation is increased by 10%,
this stopping potential rises to 0.9 V. The work function of potassium is
(A) 2.0 eV
Ans.
[B]
Sol.
KEmax= e Vretarding
(B) 2.4 eV
(C) 3.0 eV
(D) 2.8 eV
= e 0.6
= 0.6 eV
Photon energy = hf = E
When frequency increase by 10% energy of photon also increases by 10%
New energy = E' = 1.1 E
New KEmax. = e Vretarding = e 0.9 = 0.9 eV
Einstein photoelectric equation
hf = KEmax +
E = 0.6 +
(1)
1.1 E = 0.9 +
(2)
1.1 =
0.9 +
0.6 +
The dimensions of StefanBoltzmann constant can be written in terms of Planck's constant h, Boltzmann
constant kB and the speed of light c as = h kB c. Here
(A) = 3, = 4 and = 3
(B) = 3, = 4 and = 2
(C) = 3, = 4 and = 2
(D) = 2, = 3 and = 1
Ans.
[C]
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CAREER POINT
= h kB c
Steffan boltzmann constant
h Plancks constant
kB Boltzmann constant
c speed of sight
According to stefans law
Q
= T4
At
=
1
Q
At T 4
[] =
[M1L2 T 2 ]
= [M1T3K4]
2
4
[L ][T][K ]
& E = h
h=
E
[M1L2 T 2 ]
[h] =
[T 1 ]
[h] = [M1L2T1]
[c] = [LT1]
E=
3
kBT
2
[kB] =
[M1L2 T 2 ]
[K ]
[kB] = [M1L2T2K1]
According to homogeneity principle of dimension
[M1T3K4] = [M1L2T1] [M1L2T2K1] [L1T1]
on comparing powers00000000 of M, L, T, K on both sides
+=1
.(1)
2 + 2 + = 0
.(2)
2 = 3
.(3)
=4
.(4)
=4
=3
Putting values is equation (2)
2 ( 3) + 2 (4) + = 0
=2
Ans :
=3
=4
=2
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CAREER POINT
CHEMISTRY
101.
NH2
. ( CH 3CO ) 2 O , pyridine
conc. NaOH
1
X Aqueous
Y
2. Br2 / CH 3CO 2 H
NH
O
NH2
NH
Br
(A)
NH2
Br
(B)
,
Br
Br
Br
Br
NH2 O
NH2 O
Ans.
Sol.
(D)
,
Br
O
NH
Br
(C)
Br
Br
,
NH
Br
HO
OH
OH
[A]
O
NH2
NHCCH3
(i) (CH3CO)2O, Pyridine
Acetylation
Br2/CH3COOH
Bromination
O
NH2
NHCCH3
Aq. Conc. NaOH
CH3COOH+
Br
Y
Hydrolysis
Deacetylation
Br
X
102.
The density of acetic acid vapour at 300 K and 1 atm is 5 mg cm3. The number of acetic acid molecules in
the cluster that is formed in the gas phase is closest to
(A) 5
(B) 2
(C) 3
(D) 4
Ans.
[B]
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CAREER POINT
PM = RT
5 0.0821 300
M=
= 123.15
1
103.
Ans.
Sol.
123.15
2
60
104.
Ans.
Sol.
[C]
2 HI ;
Kc = 50
H2 + I2
2 NH3 ;
N2 + 3H2
Kc = 1000
1000
N2 + 6HI
2NH3 + 3I2 ;
Kc =
(50) 3
Kc = 0.008
105.
Given that the bond energies of : NN is 946 kJ mol1, HH is 435 kJ mol1, NN is 159 kJ mol1, and NH
is 389 kJ mol1, the heat of formation of hydrazine in the gas phase in kJ mol1 is :
(A) 833
(B) 101
(C) 334
(D) 1268
Ans.
Sol.
[B]
N2 + 2H2 1 N2H4
; Hf
Hf = 1 E N N + 2 E H H 4 E N H 1 E N N
= [(1 946) + ( 2 435) 4 (389) 1 (159)] kJ
= 101 kJ/mol
106.
The radius of K+ is 133 pm and that of Cl is 181 pm. The volume of the unit cell of KCl expressed in
1022 cm3 is :
(A) 0.31
Ans.
(B) 1.21
(C) 2.48
(D) 6.28
[C]
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rK + + rCl =
a
2
133 + 181 =
a
2
CAREER POINT
a = 2 (133 + 181)
a = 628 pm
or
a = 628 1010 cm
and
volume = a3 = (6.28 108)3 cm3
= 2.4767 1022 cm3
2.48 1022 cm3
107.
The reaction, K2Cr2O7 + m FeSO4 + n H2SO4 Cr2(SO4)3 + p Fe2(SO4)3 + K2SO4 + q H2O when balanced,
m, n, p and q are, respectively :
(A) 6, 14, 3, 14
(B) 6, 7, 3, 7
(C) 3, 7, 2, 7
(D) 4, 14, 2, 14
Ans.
[B]
Sol.
( +6)
( +2 )
( +3)
( +3)
(3 2) = 6 (1 1) = 1
i.e. answer is m = 6, n = 7, p = 3, q = 7
108.
The standard free energy change (in J) for the reaction 3Fe2+ (aq) + 2Cr(s) = 2Cr3+(aq) + 3Fe(s) given
E 0Fe 2+ / Fe = 0.44 V and E 0Cr 3+ / Cr = 0.74 V is (F = 96500 C)
(A) 57,900
(B) 57,900
Ans.
[C]
Sol.
3 F2+ + 2 Cr
2Cr3+ + 3Fe
(C) 173,700
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CAREER POINT
Calcium butanoate on heating followed by treatment with 1,2ethanediol in the presence of catalytic amount
of an acid, produces a major product which is :
(A)
HO
(C)
OH
(D)
OH
HO
Ans.
OH
HO
(B)
[A]
(CH3CH2CH2COO)2 Ca
CH3CH2CH2CCH2CH2CH3

O
Sol.
HOCH2
H2O
HOCH2
CH3CH2CH2CCH2CH2CH3
O
110.
Ans.
XeF6 on complete hydrolysis yields X. The molecular formula of X and its geometry, respectively, are :
(A) XeO2 and linear
[C]
O
Xe
O sp3/Pyramidal geometry
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CAREER POINT
BIOLOGY
111.
Following the cell cycle scheme given below, what is the probability that a cell would be in Mphase at any
given time ?
G1phase
Mphase
4 hrs
2 hrs
6 hrs
G2phase
12 hrs
Sphase
Ans.
Sol.
(A) 1/24
(B) 1/12
[B]
Total time for cell cycle = 24 hrs.
Time for Mphase = 2 hrs
(C) 1/6
112.
(D) 1/2
2
1
24
12
A flower with Tt genotype is crosspollinated by TT pollens. What will the genotypes of the resulting
endosperm and embryo, respectively, be ?
(A) TTT, (TT + Tt)
Ans.
[A]
Sol.
(C) TTt, Tt
So,
TTT
So, either TT or Tt
113.
A new life form discovered on a distant planet has a genetic code consisting of five unique nucleotides and
only one stop codon. If each codon has four bases, what is the maximum number of unique amino acids this
life form can use ?
(A) 624
(B) 20
(C) 124
(D) 3124
Ans.
Sol.
[A]
No. of unique nucleotide = 5
No. of bases in codon = 4
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Ans.
Sol.
115.
Ans.
Sol.
CAREER POINT
A spontaneous mutation results in a couple having only female progeny. When the daughter marries and has
children, none of them are males. However, in the third generation there are few male offspring. What is the
most likely explanation of this observation (A) The mutation reverses spontaneously in the third generation
(B) The mutation occurs on the X chromosome and is both recessive and lethal
(C) The mutation occurs on the X chromosome and is both recessive and dominant
(D) The mutation occurs on an autosome and is dominant
[B]
The mutation that occurred is on xchromosome and is both recessive and lethal since, female is carrier it
survives but due to hemizygous condition male is unable to survive.
XXm carrier (survives)
XmY dies
While in third generation, the possibility of male child occurs.
A circular plasmid of 10,000 base pairs (bp) is digested with two restriction enzymes, A and B, to produce a
3000 bp and a 2000 bp bands when visualized on an agarose gel. When digested with one enzyme at a time,
only one band is visible at 5000 bp. If the first site for enzyme A (A1) is present at the 100th base, the order
in which the remaining sites (A2, B1 and B2) are present is (A) 3100, 5100, 8100
(B) 8100, 3100, 5100
(C) 5100, 3100, 8100
(D) 8100, 5100,. 3100
[C]
A1
3000 bp
2000 bp start
100
3100
B2
8100
5100
3000 bp
B1
A2
After meiosisII, daughter cells differ from the parent cells and each other in their genotypes. This can occur
because of which one of the following mechanism(s) ?
(A) Only synaptic crossing over
(B) Only crossing over and independent assortment of chromosomes
(C) Only crossing over and chromosomal segregation
(D) Crossing over, independent assortment and segregation of chromosomes
Ans.
Sol.
[D]
After meiosisII, daughter cells differ from the parent cells and each other in their genotypes due to Crossing
over, independent assortment and segregation of chromosomes
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CAREER POINT
117.
A desert lizard (an ectotherm) and a mouse (an endotherm) are placed inside a chamber at 15 C and their
body temperature [T(L) for the lizard and T(M) for the mouse] and metabolic rates [M(L) for the lizard and
M(M) for the mouse] are monitored. Which one of the following is correct (A)T(L) and M(L) will fall while T(M) and M(M) will increase
(B) T(L) and M(L) will increase while T(M) and M(M) will fall
(C) T(L) and M(L) will fall, T(M) will remain same and M(M) will increase
(D) T(L) and M(L) will remain same and T(M) and M(M) will decrease
Ans.
Sol.
[C]
Desert lizard is an ectotherm (poikilotherm) whose body temperature varies according to environmental
temperature.
So at 15C T(L) will fall due to fall in T(M)
While mouse is an endotherm (Homeotherm) whose body temperature remains constant always due to
variation is metabolic rate
In homeotherms metabolic rate is inversely proportional to environmental temperature.
So at 15C T(M) remain same and M((M) will increased.
118.
In Griffith's experiments mice died when injected with (A) heat killed Sstrain
(B) heat killed Sstrain combined with Rstrain
(C) heat killed Rstrain
(D) live Rstrain
[B]
In Griffith experiment, mice died when injected with combination
heat killed sstrain + Live R strain
which resulted in transformation of R II into S III form.
Ans.
Sol.
119.
Human height is a multigenic character. If the heights of all the individuals living in a metropolis are
measured and the percentages of the population belonging to a specific heat are plotted as shown below,
which of the plots would represent the most realistic distribution 
%age population
Height
(A) P
(B) Q
(C) R
(D) S
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[A]
Sol.
P plot
CAREER POINT
Height of human is multigenic character and shows bell shape curve as the occurance of extreme height
will be low but medium height will be maximum.
Maximum % of population will have average medium height
120.
If mitochondria isolated from a cell are first placed without carbon source in a buffer at pH 8.0 and then
transferred to a buffer at pH4 , it will lead to (A) an increase in intramitochondrial acidity
(B) a decrease in intramitochondrial acidity
(C) blockage of ATP synthesis
(D) synthesis of ATP
Ans.
Sol.
[D]
Mitochondria synthesizes ATP based on chemiosmosis when mitochondria is transferred from a buffer pH
8.0 to buffer pH 4.0
H+
ATP
Low H
H+
High H+
pH = 4
Low pH means
High H+ ions
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