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temperatura

363.15

Acido

grupo
1
2

Alcano
1

3
4
5
6

Alqueno

CH2=C

8
9
10

11

CH=C
C=C
ACH
AC

4
5
6
7
8

12
13
14
15
16
17
18

ACCH3
ACCH2
ACCH
OH
CH3OH
H2O
ACOH

19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35

CH3CO
CH2CO
CHO
CH3COO
CH2COO
HCOO
CH3O
CH2O
CH-O
FCH2O
CH3NH2
CH2NH2
CHNH2
CH3NH
CH2NH
CHNH
CH3N

Aromatico

Alcohol

Cetona
Aldehdo

subgrupo
CH3
CH2
CH
C
CH2=CH
CH=CH

9
10

Ester

11
12

ter

13

Amino, 1st

14

Amino, 2nd

15

Amino, 3rd

16

Amino, 3rd

16

Anilina

17

Piridina

18

Nitrilo

19

Acido

20

Chloride

21

Dichloride

22
23

Other Chloride

Nitro

24
25
26

Disulfide

27
28

Thiol

29

Furfural
Ethanediol
iodo
bromo

30
31
32
33

alkyne

34

Dimetilsulfoxyde
Acrylonitrile
Trichloroethylene
Fluorobenzene

35
36
37
38

Formamide

39

Fluorides

40

36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74

CH2N
ACNH2
C5H5N
C5H4N
C5H3N
CH3CN
CH2CN
COOH
HCOOH
CH2Cl
CHCl
CCl
CH2Cl2
CHCl2
CCl2
CHCl3
CCl3
CCl4
ACCl
CH3NO2
CH2NO2
CHNO2
ACNO2
CS2
CH3SH
CH2SH
furfural
(CH2OH)2
I
Br
CH=-C
C=-C
DMSO
ACRY
Cl-(C=C)
ACF
DMF-1
DMF-2
CF3

Fluorides

40

Flexy Ester

41

Silane

42

Siloxane

43

Methylpyrrolidone

44

Chlorofluorocarbons

45

Amides

46

Glycol Ethers

47
48

Sulfides

49
50

75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108

CF2
CF
COO
SiH3
SiH2
SiH
Si
SiH2O
SiHO
SiO
NMP
CCl3F
CCl2F
HCCl2F
HCClF
CClF2
HCClF2
CClF3
CCl2F2
CONH2
CONHCH3
CONHCH2
CON(CH3)2
CONCH3CH2
CON(CH2)2
C2H5O2
C2H4O2
CH3S
CH2S
CHS
Morpholine
C4H4S
C4H3S
C4H2S

agua
373.15
58158

temperatura de fusion
calor de fusion

50

cambio de calores
exponente
base de calculo

0.5954407981
100

x1 acido

0.6310254566

x2 agua

0.3689745434

temperatura

gramos acido

gramos agua

90

94.6538184883

6.6415417814

INSTRUCCIONES:

1, Se introducen los valores de Temperatura de fusion, Calor de funcion, y los Cambios de calores e
Solido y Liquido en las casillas Azules

2, Se introduce los subgrupos de los dos componentes que se quiere analizar en las casillas
Verde

3, Se introduce la Temperatura Cy la fraccion molar del acido en las casillas Verdes


4,Se observa el valor obtenido en la celda de color Rojo

primer termino

-0.5162142019

segundo termino

-0.0022391086

0.94361
0.84050

1
2

solubilidad
Acido /100 ml de Agua)

(g

1425.1783938695

CIONES:

lor de funcion, y los Cambios de calores especificos para


las casillas Azules

ntes que se quiere analizar en las casillas de la columna


e

cion molar del acido en las casillas Verdes

do en la celda de color Rojo

calor como liquido metodo rusika y dolmanski


solubilidades g/ 100 ml de literatura
temperatura acido citrico

temperatura de fusion
acido citrico
156C
oxalico
101.5 C
tartarico
172.5 C loD 206 racemico 165 meso

15

composicion de las moleculas


oxalico
2 O-(H,CO)
2 CO-(O,CO)

tartarico
citrico
2 O-(H,CO)
3 O-(H,CO)
2 C-(H, 2C, O)O-(H,C)
2 O-(H,C)
2 C-(2H,2C)
2 CO-(O,C)
C-(3C,O)

10
20

117.43
147.76

30
40
80
100

188.9
220.19
382.48
547

factores de correlacion
a
O-(H,CO)
C-(H, 2C, O)
O-(H,C)
C(3C,O) (alcohol)
C(2H,2C)
CO-(O,C)

b
-27.434
2.2209
12.95
-44.69
2.7972
29.246

d
-0.16485
-1.435
-10.145
31.769
-0.054967
3.4261

2.7483
0.69508
2.6261
-4.8791
0.10679
-2.8962

parametros
oxalico
A
B
D

tartarico
citrico
3.624
33.9658
-108.4476
6.5225
-16.6375
21.019516
-0.2958
6.34656
6.20548

calores especificos como solidos de 0 a 100 C j/(mol k )


oxalico
tartarico
citrico

118
184.5
226.51

Calor de Fusion
sigma
sp3
sp2
anillos
tau

tartarico
2 (OH)

oxalico
0 (metilos)
2
2
0
2

citrico
1 (OH)
0
2
0
0

3
2
0
3

Delta s (j/mol k
deltah pred (kJ/mol)
deltah expe

61.64
27.43
32.3

25.09
9.401

76.114
32.66

00 ml de literatura
oxalico

tartarico

datos experimentales reportados y utilizados


calor de fusion (kj/ mol)
oxalico
58.158
ascorbico
29.2
citrico
26.7
tartarico
30.1

ascorbico

9.5

133

33

PARTICION UNIFAC
tartarico
oxalico
citrico
ascorbico

= 2 OH + 2 COOH + 2CH alcano


2 COOH
3COOH + OH + 2 CH2 alcano + C alcano
4 OH + 1 CH2 +2 CH + 1 C=C + 1 COO(flexiester )

y utilizados
diferencias de calores (j/mol)

CION UNIFAC

50
60
70
70

temperatura de fusion k
373.15
465.15
426.15
433.15

Acido citrico
Solubilidad reportada

S o lu b ilid a d g A c id o /1 0 0 m l A g u a

600

10
20
30
40
80
100

7.637228441
12.02967837
17.4481412
23.67394843
56.52475792
79.71413067

125.22
188.9
220.19
382.48
547

S o lu b ilid a d g A c id o /1 0 0 m l A g u a

gramos agua
predicho

gramos acido predicho

17.2840098
16.8722177
16.3642368
15.7805673
12.7008039
10.5268002

Acido Ctrico: Solu


800
Acido Ctrico: Solubilidad Experim ental vs Temperatura
700

500

600
400

500

300

400

200

300
200

0
10

20

30

S o lu b ilid a d g A c id o / 1 0 0 m l A g u a

100

100
40

Temperatura C
50
60

800

70

80

90

100

0
10

20

30

40

Temperatur
50
60

Acido Ctrico: Solubilidad vs Tem peratura

700
600
500
400
300
200
100
0
10

20

30

40

50
60 C
Temperatura

70

80

90

300
200
100
0
10

20

30

40

50
60 C
Temperatura

70

80

90

Acido oxalico
gramos acido predicho
0.011318152
0.02646121
0.058242094
0.121401721
0.240926687
0.457451297
0.834849896
1.470882822

17.99773637
17.99470776
17.98835158
17.97571966
17.95181466
17.90850974
17.83303002
17.70582344

Acido Oxlico: Solubilidad Experimental vs Temperatura


40
35

25

20

15

10

0
10

20

30

40

Temperatura C
50
60
70

80

90

100

1
0
10

40
35
30
25
20
15
10

Acido Oxlico

30

S o lu b ilid a d g A c id o / 1 0 0 m l A g u a

Solub ilid a d g A c id o /1 00 m l A g ua

20
30
40
50
60
70
80
90

gramos agua p

S o lu b ilid a d g A c id o /1 0 0 m l A g u a

temperatura

20

30

40

Acido Oxlico: Solubilidad vs Tem pe

35
30
25
20
15
10
5
0
10

20

30

40

50
60
Temperatura C

70

80

do citrico
solubilidad predicha

T
10
20
25
30
40
50
60
70
80

Acido Ctrico: Solubilidad Predicha vs Tem peratura

S o lu b ilid a d g A c id o /1 0 0 m l A g u a

44.186
71.298
106.623
150.019
445.048
757.249

Acido Tartric

350

300

250

200

0
10

20

30

40

Temperatura C
50
60
70

150
80

90

100

100
50
0
10

ad vs Tem peratura

Solubilidad
Experimental
Solubilidad
Predicha

70

80

90

100

20

30

Predicha

70

80

90

100

o oxalico
solubilidad predicha

Solubilidad medida

S o lu b ilid a d g A c id o /1 0 0 m l A g u a

temperatura
0.062886529
0.147049957
0.323776716
0.675365012
1.34207428
2.554379477
4.681480909
8.307339264

6.24
7.25
10.12
14.71
20.1
22.1
27.12
33.98

10
20
30
40
50

Acido Oxlico: Solubilidad Predicha vs Tem peratura

8
7
6
5
4
3
2
1
0
10

20

30

40

Temperatura C
50
60
70

80

olubilidad vs Tem peratura

Solubilidad
Experimenta
l
Solubilidad
Predicha

90

100

60
peratura C

Solubilidad
Experimenta
l
Solubilidad
Predicha

70

80

90

100

Acido Tartarico
temperatura
Solubilidad medida

solubilidad predicha
16.15666566
32.81801234
45.17685349
60.9336464
99.4843071
137.6169168
185.0099257
244.6364814
321.4681369

71.2
89.53
107.02
135.35
176.36
210.56
258.16
315.6

10
20
30
40
50
60
70
80
90

Acido Tartrico: Solubilidad Experim ental vs Tem peratura

350

300

250

200

150

50
0
10

20

30

40

S o lu b ilid a d g A c id o / 1 0 0 m l A g u a

100

Temperatura C
50
60

350

70

80

90

100

Acido Tartrico: Solubilidad vs Tem p

300
250
200
150
100
50
0
0

10

20

30

T
emperatura
C
40
50
60

70

80

90

10

200
150
100
50
0
0

10

20

T
emperatura
C
40
50
60

30

70

80

90

10

ascorbico
gramos acido

gramos agua
17.6515527
17.4190579
17.1063424
16.7295146
16.3033727

Solubilidad

3.407040528
5.680323057
8.737985509
12.4225244
16.58924481

solubilidad predicha
19.3016478
32.60981793
51.08038474
74.25513967
101.7534539

Acido Ascrbico solubilidad p


120
100
80
60
40
20
0
5

10

15

20

25 30 35 40
temperatura

45

50

55

Acido Tartarico
gramos acido
predicho

gramos agua
predicho

S o lu b ilid a d g A c id o / 1 0 0 m l A g u a

2.85288803
4.845491878
7.713659016
11.46007467
15.99738836
21.26013925
27.2516056
34.04127992
41.75628606

17.65765344
17.41854097
17.07436092
16.62479104
16.0803134
15.44878329
14.72980733
13.91504641
12.98924567

solubilidad
predicha
16.1566656617
27.8180123487
45.1768534831
68.9336463985
99.4843070658
137.6169168206
185.0099257205
244.6364813813
321.4681369561

Acido Tartrico: Solubilidad Predicha vs Tem peratura

350
300
250
200
150
100
50
0
10

20

30

40

olubilidad vs Tem peratura

ra60
C

Solubilidad
Experimenta
l

70

80

90

100

Temperatura C
50
60

70

80

90

100

Solubilidad
Experimenta
l

ra60
C

70

80

90

100

ascorbico

co solubilidad predicha

35 40
tura

45

50

55

peratura

100

temperarura

363.15

grupo
Alcano
1

Alqueno
2
3
Aromatico

Alcohol

Cetona
Aldehido

4
5
6
7
8
9
10

Ester

11
12

Ether

13

Amine, 1st

14

Amine, 2nd

15

Amine, 3rd

16

Aniline

17

Pyridine

18

subgrupo
CH3
CH2
CH
C
CH2=CH
CH=CH
CH2=C
CH=C
C=C
ACH
AC
ACCH3
ACCH2
ACCH
OH
CH3OH
H2O
ACOH
CH3CO
CH2CO
CHO
CH3COO
CH2COO
HCOO
CH3O
CH2O
CH-O
FCH2O
CH3NH2
CH2NH2
CHNH2
CH3NH
CH2NH
CHNH
CH3N
CH2N
ACNH2
C5H5N
C5H4N

Rk

k
1
2
3
4
5
6
7
8
7
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38

0.9011
0.6744
0.4469
0.2195
1.3454
1.1167
1.1173
0.8886
0.6605
0.5313
0.3652
1.2663
1.0396
0.8121
1.0000
1.4311
0.9200
0.8952
1.6724
1.4457
0.9980
1.9031
1.6764
1.2420
1.1450
0.9183
0.6908
0.9183
1.5959
1.3692
1.1417
1.4337
1.2070
0.9795
1.1865
0.9597
1.0600
2.9993
2.8332

Pyridine

18

Nitrile

19

Acid

20

Chloride

21

Dichloride

22
23

Other Chloride

Nitro

24
25
26

Disulfide

27
28

Thiol

29

Furfural
Ethanediol
iodo
bromo

30
31
32
33

alkyne

34

Dimetilsulfoxyde
Acrylonitrile
Trichloroethylene
Fluorobenzene

35
36
37
38

Formamide

39

Fluorides

40

Flexy Ester

41

Silane

42

Siloxane

43

C5H3N
CH3CN
CH2CN
COOH
HCOOH
CH2Cl
CHCl
CCl
CH2Cl2
CHCl2
CCl2
CHCl3
CCl3
CCl4
ACCl
CH3NO2
CH2NO2
CHNO2
ACNO2
CS2
CH3SH
CH2SH
furfural
(CH2OH)2
I
Br
CH=-C
C=-C
DMSO
ACRY
Cl-(C=C)
ACF
DMF-1
DMF-2
CF3
CF2
CF
COO
SiH3
SiH2
SiH
Si
SiH2O

39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
71
72
73
74
75
76
77
78
79
80
81
82

2.6670
1.8701
1.6434
1.3013
1.5280
1.4654
1.2380
1.0060
2.2564
2.0606
1.8016
2.8700
2.6401
3.3900
1.1562
2.0086
1.7818
1.5544
1.4199
2.5070
1.8770
1.6510
3.1680
2.4088
1.2640
0.9492
1.2929
1.0613
2.8266
2.3144
0.7910
0.6948
3.0856
2.6322
1.4060
1.0105
0.6150
1.3800
1.6035
1.4443
1.2851
1.0470
1.4838

Siloxane
Methylpyrrolidone

43
44

Chlorofluorocarbons

45

Amides

46

Glycol Ethers

47
48

Sulfides

49
50

SiHO
SiO
NMP
CCl3F
CCl2F
HCCl2F
HCClF
CClF2
HCClF2
CClF3
CCl2F2
CONH2
CONHCH3
CONHCH2
CON(CH3)2
CONCH3CH2
CON(CH2)2
C2H5O2
C2H4O2
CH3S
CH2S
CHS
Morpholine
C4H4S
C4H3S
C4H2S

83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108

1.3030
1.1044
3.9810
3.0356
2.2287
2.4060
1.6493
1.8174
1.9670
2.1721
2.6243
1.4515
2.1905
1.9637
2.8589
2.6322
2.4054
2.1226
1.8952
1.6130
1.3863
1.1589
3.4740
2.8569
2.6908
2.5247

Qk
0.8480
0.5400
0.2280
0.0000
1.1760
0.8670
0.9880
0.6760
0.4850
0.4000
0.1200
0.9680
0.6600
0.3480
1.2000
1.4320
1.4000
0.6800
1.4880
1.1800
0.9480
1.7280
1.4200
1.1880
1.0880
0.7800
0.4680
1.1000
1.5440
1.2360
0.9240
1.2440
0.9360
0.6240
0.9400
0.6320
0.8160
2.1130
1.8330

r1/parcial
cantidad 1
cantidad 2
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

r2/parcial
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

q1/parcial
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.92
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

1.5530
1.7240
1.4160
1.2240
1.5320
1.2640
0.9520
0.7240
1.9880
1.6840
1.4480
2.4100
2.1840
2.9100
0.8440
1.8680
1.5600
1.2480
1.1040
1.6500
1.6760
1.3680
2.4810
2.2480
0.9920
0.8320
1.0880
0.7840
2.4720
2.0520
0.7240
0.5240
2.7360
2.1200
1.3800
0.9200
0.4600
1.2000
1.2630
1.0060
0.7490
0.4100
1.0620

0.0000
0.0000
0.0000
2.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0
0
0
2.6026
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
2.448
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0.7640
0.4660
3.2000
2.6440
1.9160
2.1160
1.4160
1.6480
1.8280
2.1000
2.3760
1.2480
1.7960
1.4880
2.4280
2.1200
1.8120
1.9040
1.5920
1.3680
1.0600
0.7480
2.7960
2.1400
1.8600
1.5800

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

v (ik ) Q k
e ki=
qi
eki i=1

q2/parcial
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

r i= v k Rk

qi = v k

(i )

eki i=2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

R1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

R2
2.6026

0.92

J1

J2
1.3132748119 0.464233008
ln c1
ln c1
0.0233113533 0.21652849
1

0.943608205

0.840497489

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

(i)

qi = v k Q k
k

Q1
2.448

Q2
1.4

L1
L2
1.1875916014 0.6791782
ln r1
ln r2
-0.0813555898 -0.39029

UNIFAC:
Parmetro
s aij

GRUPO
PRINCIPAL

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

Alcano

Alqueno

Aromatico

Alcohol

0.000
-35.360
-11.120
-69.700
156.400
16.510
300.000
275.800
26.760
505.700
114.800
329.300
83.360
-30.480
65.330
-83.980
1139.000
-101.600
24.820
315.300
91.460
34.010
36.700
-78.450
106.800
-32.690
5541.000
-52.650
-7.481
-25.310
139.900
128.000
-31.520
-72.880
50.490
-165.900
47.410
-5.132
-31.950
147.300

86.020
0.000
3.446
-113.600
457.000
-12.520
496.100
217.500
42.920
56.300
132.100
110.400
26.510
1.163
-28.700
-25.380
2000.000
-47.630
-40.620
1264.000
40.250
-23.500
51.060
160.900
70.320
-1.996
0.000
16.620
0.000
82.640
0.000
0.000
174.600
41.380
64.070
573.000
124.200
-131.700
249.000
62.400

61.130
38.810
0.000
-146.800
89.600
-50.000
362.300
24.340
140.100
23.390
85.840
18.120
52.130
-44.850
-22.310
-223.900
247.500
31.870
-22.970
62.320
4.680
121.300
288.500
-4.700
-97.270
10.380
1824.000
21.500
28.410
157.300
221.400
58.680
-154.200
0.000
2.504
-123.600
395.800
-237.200
-133.900
140.600

76.500
74.150
167.000
0.000
25.820
-44.500
377.600
244.200
365.800
106.000
170.000
428.000
65.690
296.400
223.000
109.900
762.800
49.800
-138.400
89.860
122.900
140.800
69.900
134.700
402.500
-97.050
-127.800
40.680
19.560
128.800
150.600
26.410
1112.000
0.000
-143.200
397.400
419.100
-157.300
-240.200
0.000

986.500
524.100
636.100
803.200
0.000
249.100
-229.100
-451.600
164.500
529.000
245.400
139.400
237.700
-242.800
-150.000
28.600
-17.400
-132.300
185.400
-151.000
562.200
527.600
742.100
856.300
325.700
261.600
561.600
609.800
461.600
521.600
267.600
501.300
524.900
68.950
-25.870
389.300
738.900
649.700
64.160
0.000

697.200
787.600
637.400
603.300
-137.100
0.000
289.600
-265.200
108.700
-340.200
249.600
227.800
238.400
-481.700
-370.300
-406.800
-118.100
-378.200
162.600
339.800
529.000
669.900
649.100
709.600
612.800
252.600
0.000
914.200
448.600
0.000
240.800
431.300
494.700
0.000
695.000
218.800
528.000
645.900
172.200
0.000

41
42
43
44
45
46
47
48
49
50

529.000
-34.260
110.200
13.890
30.740
27.970
-11.920
39.930
-23.610
-8.479

1397.000
0.000
0.000
-16.110
0.000
9.755
132.400
543.600
161.100
0.000

317.600
787.900
234.400
-23.880
167.900
0.000
-86.880
0.000
142.900
23.930

615.800
0.000
0.000
6.214
0.000
0.000
-19.450
0.000
274.100
2.845

88.630
1913.000
0.000
796.900
794.400
394.800
517.500
0.000
-61.200
682.500

171.000
0.000
0.000
0.000
762.700
0.000
0.000
420.000
-89.240
597.800

Cetona

Aldehido

Alcohol

10

11

12

13

677.000
448.800
347.300
586.800
-203.600
306.400
-116.000
-271.100
-37.360
0.000
185.100
-236.500
-7.838
0.000
0.000
0.000
0.000
0.000
0.000
-165.500
-47.510
190.600
242.800
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
245.900
0.000
0.000
0.000
354.000
183.800
0.000
13.890
0.000

232.100
37.850
5.994
5688.000
101.100
-10.720
72.870
-449.400
-213.700
-110.300
0.000
1167.000
461.300
0.000
136.000
2889.000
-294.800
0.000
-266.600
-256.300
35.380
-133.000
176.500
129.500
-171.100
129.300
0.000
243.800
0.000
-146.300
152.000
21.920
24.370
0.000
41.570
175.500
611.300
0.000
-82.120
0.000

507.000
333.500
287.100
197.800
267.800
179.700
0.000
0.000
-190.400
766.000
-241.800
0.000
457.300
0.000
0.000
0.000
0.000
554.400
99.370
193.900
0.000
0.000
235.600
351.900
383.300
0.000
0.000
0.000
201.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
134.500
0.000
-116.700
0.000

251.500
214.500
32.140
213.100
28.060
-128.600
540.500
-162.900
-103.600
304.100
-235.700
-234.000
0.000
222.100
-56.080
-194.100
0.000
-156.100
38.810
-338.500
225.400
-197.700
-20.930
113.900
-25.150
-94.490
0.000
112.400
63.710
-87.310
9.207
476.600
736.400
0.000
-93.510
0.000
-217.900
167.300
-155.200
0.000

1318.000 1333.000 476.400


270.600
526.100
182.600
903.800 1329.000
25.770
5695.000 884.900
-52.100
353.500
-259.700
84.000
-181.000 -101.700
23.390
0.000
324.500
-195.400
-601.800
0.000
-356.100
472.500
-133.100
0.000
480.800
-155.600
128.000
200.800
-36.720
372.200
0.000
0.000
385.400
-314.700 -178.500
191.100
-330.400
0.000
0.000
-448.200
0.000
394.600
-598.800
0.000
225.300
-341.600 -253.100 -450.300
-332.900 -341.600
29.100
242.800
0.000
-287.500
-66.170
-11.000
297.800
698.200
0.000
286.300
708.700
0.000
82.860
826.800
0.000
552.100
1201.000 10000.000 372.000
-274.500
622.300
518.400
417.900
0.000
-142.600
360.700
0.000
-101.500
1081.000 1421.000 303.700
0.000
0.000
160.600
23.480
0.000
317.500
-137.400
838.400
135.400
0.000
0.000
138.000
0.000
0.000
-142.600
0.000
0.000
443.600
-240.000
0.000
110.400
386.600
0.000
0.000
0.000
0.000
-40.900
0.000
0.000
0.000
-287.100
0.000
97.040
0.000
0.000
0.000

Ester

Ether

284.400
180.200
0.000
832.200
0.000
-509.300
-205.700
0.000
-384.300
0.000

-167.300
0.000
0.000
-234.700
0.000
0.000
0.000
0.000
0.000
810.500

123.400
992.400
0.000
0.000
0.000
0.000
156.400
0.000
0.000
278.800

577.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-234.900
0.000
0.000
0.000
0.000
0.000
-3.444
0.000
0.000
0.000

145.400
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-247.800
448.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

Amine, 2nd

Amine, 3rd

14

15

16

391.500
240.900
161.700
19.050
8.642
359.300
48.890
0.000
0.000
0.000
0.000
0.000
-78.360
0.000
127.400
38.890
-15.070
0.000
-157.300
0.000
131.200
0.000
0.000
261.100
108.500
0.000
0.000
0.000
106.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
49.700
0.000

255.700
163.900
122.800
-49.290
42.700
-20.980
168.000
0.000
-174.200
0.000
-73.500
0.000
251.500
-107.200
0.000
865.900
0.000
0.000
-108.500
0.000
0.000
0.000
0.000
91.130
102.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-198.800
0.000
0.000

206.600
61.110
90.490
23.500
-323.000
53.900
304.000
0.000
-169.000
0.000
-196.700
0.000
5422.000
-41.110
-189.200
0.000
0.000
0.000
0.000
0.000
0.000
-141.400
-293.700
316.900
2951.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-257.200
0.000
0.000
116.500
-185.200
0.000

Aniline

Amine, 1st

Pyridine

Nitrile

Acid

17

18

19

20

920.700
749.300
648.200
664.200
-52.390
489.700
243.200
119.900
6201.000
0.000
475.500
0.000
0.000
-200.700
0.000
0.000
0.000
117.400
777.400
493.800
429.700
140.800
0.000
898.200
334.900
0.000
134.900
0.000
0.000
0.000
192.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
343.700
0.000

287.800
280.500
-4.449
52.800
170.000
580.500
459.000
-305.500
7.341
0.000
0.000
-233.400
213.200
0.000
0.000
0.000
89.700
0.000
134.300
-313.500
0.000
587.300
18.980
368.500
0.000
0.000
2475.000
0.000
0.000
0.000
0.000
0.000
-42.710
0.000
0.000
0.000
281.600
159.800
0.000
0.000

597.000
336.900
212.500
6096.000
6.712
53.280
112.600
0.000
481.700
0.000
494.600
-47.250
-18.510
358.900
147.100
0.000
-281.600
-169.700
0.000
0.000
54.320
258.600
74.040
492.000
363.500
0.283
0.000
335.700
161.000
0.000
169.600
0.000
136.900
329.100
0.000
-42.310
335.200
0.000
150.600
0.000

663.500
318.900
537.400
872.300
199.000
-202.000
-14.090
408.900
669.400
497.500
660.200
-268.100
664.600
0.000
0.000
0.000
-396.000
-153.700
0.000
0.000
519.100
543.300
504.200
631.000
993.400
0.000
0.000
0.000
0.000
570.600
0.000
616.600
5256.000
0.000
180.200
0.000
898.200
0.000
-97.770
0.000

0.000
961.800
-125.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000

284.500
1464.000
1604.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-22.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
221.400

-61.600
0.000
0.000
0.000
0.000
0.000
119.200
0.000
0.000
0.000

1179.000
0.000
0.000
0.000
0.000
-70.250
0.000
0.000
0.000
0.000

Chloride

Dichloride

Other Chloride

Nitro

21

22

23

24

25

26

27

35.930
-36.870
-18.810
-114.100
75.620
-38.320
325.400
0.000
-191.700
751.900
-34.740
0.000
301.100
-82.920
0.000
0.000
287.000
0.000
4.933
13.410
0.000
-84.530
-157.100
11.800
-129.700
113.000
1971.000
-7309.000
-27.940
0.000
0.000
0.000
-262.300
0.000
0.000
0.000
383.200
0.000
0.000
0.000

53.760
58.550
-144.400
-111.000
65.280
-102.500
370.400
0.000
-130.300
67.520
108.900
0.000
137.800
0.000
0.000
-73.850
-111.000
-351.600
-152.700
-44.700
108.300
0.000
0.000
17.970
-8.309
-9.639
0.000
0.000
0.000
0.000
0.000
-40.820
-174.500
0.000
-215.000
0.000
301.900
0.000
0.000
0.000

24.900
-13.990
-231.900
-80.250
-98.120
-139.400
353.700
0.000
-354.600
-483.700
-209.700
-126.200
-154.300
0.000
0.000
-352.900
0.000
-114.700
-15.620
39.630
249.600
0.000
0.000
51.900
-0.227
0.000
0.000
-26.060
0.000
48.480
0.000
21.760
0.000
0.000
-343.600
0.000
-149.800
0.000
0.000
0.000

104.300
109.700
3.000
-141.300
143.100
-44.760
497.500
1827.000
-39.200
0.000
54.570
179.700
47.670
-99.810
71.230
-262.000
882.000
-205.300
-54.860
183.400
62.420
56.330
-30.100
0.000
248.400
-34.680
514.600
-60.710
0.000
-133.200
0.000
48.490
77.550
0.000
-58.430
-85.150
-134.200
-124.600
-186.700
0.000

11.440
100.100
187.000
-211.000
123.500
-28.250
133.900
6915.000
-119.800
0.000
442.400
24.280
134.800
30.050
-18.930
-181.900
617.500
0.000
-4.624
-79.080
153.000
223.100
192.100
-75.970
0.000
132.900
-123.100
0.000
0.000
0.000
0.000
0.000
-185.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000

661.500
357.500
168.000
3629.000
256.500
75.140
220.600
0.000
137.500
0.000
-81.130
0.000
95.180
0.000
0.000
0.000
0.000
0.000
-0.515
0.000
32.730
108.900
0.000
490.900
132.700
0.000
-85.120
277.800
0.000
0.000
481.300
64.280
125.300
174.400
0.000
0.000
379.400
0.000
223.600
0.000

543.000
0.000
194.900
4448.000
157.100
0.000
399.500
0.000
548.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-139.300
2845.000
0.000
0.000
86.200
0.000
0.000
534.700
2213.000
533.200
0.000
0.000
0.000
0.000
0.000
2448.000
4288.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

182.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

305.400
0.000
0.000
0.000
0.000
0.000
-194.700
0.000
0.000
0.000

-193.000
0.000
0.000
196.200
0.000
0.000
0.000
-363.100
0.000
0.000

335.700
0.000
70.810
0.000
0.000
0.000
3.163
-11.300
0.000
-79.340

956.100
0.000
0.000
161.500
0.000
0.000
7.082
0.000
0.000
0.000

0.000
0.000
0.000
0.000
844.000
0.000
0.000
0.000
0.000
176.300

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

Disulfide

Thiol

Furfural

Ethanediol

iodo

bromo

alkyne

28

29

30

31

32

33

34

153.600
76.300
52.070
-9.451
488.900
-31.090
887.100
8484.000
216.100
0.000
183.000
0.000
140.900
0.000
0.000
0.000
0.000
0.000
230.900
0.000
450.100
0.000
116.600
132.200
0.000
320.200
0.000
0.000
0.000
0.000
0.000
-27.450
0.000
0.000
0.000
0.000
167.900
0.000
0.000
0.000

184.400
0.000
-10.430
393.600
147.500
17.500
0.000
0.000
-46.280
0.000
0.000
103.900
-8.538
-70.140
0.000
0.000
0.000
0.000
0.460
0.000
59.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
85.700
0.000
0.000
0.000
-71.000
0.000

354.600
262.900
-64.690
48.490
-120.500
0.000
188.000
0.000
-163.700
0.000
202.300
0.000
170.100
0.000
0.000
0.000
0.000
0.000
0.000
-208.900
0.000
0.000
-64.380
546.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

3025.000
0.000
210.700
4975.000
-318.900
119.200
12.720
-687.100
71.460
0.000
-101.700
0.000
-20.110
0.000
0.000
0.000
0.100
0.000
177.500
0.000
0.000
0.000
0.000
0.000
0.000
139.800
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
535.800
0.000
0.000
0.000
-191.700
0.000

335.800
0.000
113.300
259.000
313.500
212.100
0.000
0.000
53.590
117.000
148.300
0.000
-149.500
0.000
0.000
0.000
0.000
0.000
0.000
228.400
0.000
177.600
86.400
247.800
0.000
304.300
2990.000
292.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

479.500
183.800
261.300
210.000
202.100
106.300
0.000
0.000
245.200
0.000
18.880
0.000
-202.300
0.000
0.000
0.000
0.000
-60.780
-62.170
-95.000
344.400
315.900
0.000
146.600
593.400
10.170
-124.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-111.200
0.000
0.000
0.000
0.000
0.000

298.900
31.140
0.000
0.000
727.800
0.000
0.000
-246.600
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-203.000
0.000
0.000
0.000
0.000
0.000
0.000
-27.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
631.500
0.000
6.699
0.000

885.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
-274.100
0.000
0.000
0.000
6.971
0.000
0.000

-64.280
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-264.300
0.000
0.000
262.000
0.000
0.000
515.800
0.000
0.000
0.000

288.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

627.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

Acrylonitrile

Trichloroethylene

Fluorobenzene

Formamide

35

36

37

38

39

40

41

526.500
179.000
169.900
4284.000
-202.100
-399.300
-139.000
0.000
-44.580
0.000
52.080
0.000
128.800
0.000
0.000
243.100
0.000
0.000
0.000
-463.600
0.000
215.000
363.700
337.700
0.000
0.000
0.000
0.000
31.660
0.000
-417.200
0.000
32.900
0.000
0.000
0.000
0.000
0.000
136.600
0.000

689.000
-52.870
383.900
-119.200
74.270
-5.224
160.800
0.000
0.000
-339.200
-28.610
0.000
0.000
0.000
0.000
0.000
0.000
0.000
81.570
0.000
0.000
0.000
0.000
369.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
837.200
0.000
5.150
0.000

-4.189
-66.460
-259.100
-282.500
225.800
33.470
0.000
0.000
-34.570
172.400
-275.200
11.400
240.200
0.000
0.000
0.000
0.000
160.700
-55.770
-11.160
-168.200
-91.800
111.200
1187.100
0.000
10.760
0.000
-47.370
0.000
0.000
0.000
0.000
0.000
2073.000
0.000
-208.800
0.000
0.000
137.700
0.000

125.800
359.300
389.300
101.400
44.780
-48.250
0.000
0.000
0.000
0.000
0.000
0.000
-274.000
0.000
570.900
-196.300
0.000
-158.800
0.000
0.000
0.000
0.000
0.000
215.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
185.600

485.300
-70.450
245.600
5629.000
-143.900
-172.400
319.000
0.000
-61.700
-268.800
85.330
308.900
254.800
-164.000
0.000
22.050
-334.400
0.000
-151.500
-228.000
0.000
0.000
0.000
498.600
0.000
-223.100
0.000
0.000
78.920
0.000
302.200
0.000
0.000
-119.800
-97.710
-8.804
255.000
0.000
0.000
55.800

-2.859
449.400
22.670
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-117.200
-5.579
0.000

387.100
48.330
103.500
69.260
190.300
165.700
-197.500
-494.200
-18.800
-275.500
560.200
-122.300
417.000
0.000
-38.770
0.000
-89.420
0.000
120.300
-337.000
63.670
-96.870
255.800
256.500
-71.180
248.400
0.000
469.800
0.000
43.370
347.800
68.550
195.100
0.000
153.700
423.400
730.800
0.000
72.310
0.000

Flexy Ester

Dimetilsulfoxyde

Fluorides

-29.340
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-53.910
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-198.000
0.000
0.000
-66.310
0.000
0.000
0.000
148.900
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

-28.650
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
-32.170
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
101.200
0.000
0.000
0.000

42

43

Chlorofluorocarbons

Amides

Glycol Ethers

Siloxane

Methylpyrrolidone

Silane

44

45

46

47

48

-5.869
0.000
-88.110
0.000
72.960
-52.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-218.900
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
111.800

390.900
200.200
0.000
0.000
-382.700
0.000
835.600
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-322.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

553.300
268.100
333.300
421.900
-248.300
0.000
139.600
0.000
37.540
0.000
151.800
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.230
0.000
0.000
361.100
0.000
423.100
434.100
0.000
0.000
0.000
0.000
0.000
-353.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
122.400

187.000
-617.000
0.000
0.000
0.000
37.630
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
565.900
63.950
0.000
0.000
0.000
0.000
-18.270
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2429.000
0.000
0.000
0.000

-450.400
252.700
220.300
0.000
0.000
86.460
-432.300
238.900
30.040
0.000
0.000
46.380
-817.700
0.000
-504.200
0.000
0.000
0.000
-363.800
0.000
-452.200
0.000
0.000
-659.000
-588.900
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1338.000
0.000
0.000
-664.400
275.900
0.000
448.100 -1327.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-35.680
0.000
233.100
0.000
0.000
0.000
-209.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1004.000
0.000
0.000
0.000
0.000
0.000
-262.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
26.350
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

Sulfides

0.000
0.000
745.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
-2166.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

Sulfides

49

50

216.100
62.560
-59.580
-203.600
104.700
-59.400
407.900
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

92.990
0.000
-39.160
184.900
57.650
-46.010
0.000
1005.000
-162.600
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-136.600
0.000
0.000
0.000
0.000
0.000
108.500
0.000
-4.565
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

amk
m/k

1
1

2
3

4
5
6
7
8
9
10
11
12
13

14

15
16
17
18
19
20
21

22
23

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
42
0
0
0
0
0
0
0
0
0

0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

2
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42

43
44

45

46

47
48
49
50

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

50

0
0

0
0

0
0

0
0

0
0

0
0

0
0

0
0

3
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

4
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

5
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

7
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-66.17
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0

0
0

0
0

0
0

0
0

0
0

0
0

0
0

0
0

0
0

8
0
0
0
0
0

9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

10
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

12
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

13
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
0
0
0
0
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0
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0
0
0
0
0
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0
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0
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48
0
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0
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0
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49
0
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0
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0
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0
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0
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0
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0
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50
0
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0
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0
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mk
m/k

mk =exp

amk
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0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

ik

ik= e mi mk

i=1

m/k
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

ik

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

i=2

m/k

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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