SO GIAO DUC VA DAO TAO NGHE AN DE THI THU QUOC GIA 2015 - Lin 2 TRUONG THPT QUYNH LUU 1 MON: HOA HOC. Théi gian lam bai: 90 phi; (50 cau treic nghiém) Ma dé thi 209 Ho, tén thi sinh Lép. Trung (Cfiu 1: Phan img téng hop glucoze trong cdy xanh edn duce cung edp nang hong 6CO; + 610 —# Cilli206+ 602, AI =2813K0 Trong mot phat, mdi em” 1é xanh nhdn duge khoang nang luong 2,09 J ning luong Mat trai, nhung chi 10% duge sit dung véo phan img ting hop glucozo. V6i mét ngay nang (tir 6 gid dén 17 gids), dién tich 1a xanh la Im? thi khdi lugng glucozo tong hop duoc la A. 80,70 gam. B. 88.27 gam C. 78,78 gam D. 93,20 gam. ‘Cu 2: Cho cic chat sau: CuO (1), Zn (2), Ag (3), Al(OH) (4), KMnO, (5), PbS (6), MgCO; (7), AgNOs (8), MnO, (9), Fe(NOs); (10). Axit HCI khéng tac dung duge vai chat sé: A. (3), (10). B. (5), (6). C8), D.(1), 2). Cu 3: Dot chay hoan toan 18 gam mét este X don chére thu duge 20,16 lit CO; (dkte) va 12,96 gam mude. Mat khée néu cho 21g X tac dung véi 200ml dung dich KOH 1.2M sau dé e6 can dung dich thu duge 34,44 gam chat rin khan. Céng thie phan eua axit tao ra X 1a A. CsHyOr B. CHO: C. CHO D. C503, Cu 4: Nguyén tir nao sau day khdng e6 di 3 loai hat co ban: AL'H B. “Ca C.F D.“N (Cfiu 5: Nguvi ta c6 thé sir dung nude dé khé (CO; rin) dé tao moi trudng lanh va khé trong vige bdo quain thye phim va hoa qua vi A. Nude da kh6 6 kha nang thang hoa B, Nude da kh6 c6 kha nang hiit Am. C. Nuée da khé 6 kha niing khir tring D. Nude dé khd 6 kha ning dé hod long, Cf 6: Chon edu ding khi néi vé flo, clo, brom, iot A Tot c6 tinh dxi hod yéu hon flo, clo, brom nhung né eting Oxi hod duce nude B. Brom c6 tinh 6xi hod manh, tuy yéu han clo, flo nhung né cing 6xi hod duge nude C. Clo 6 tinh 6xi hoa man, 6xi hoa duge nude D, Flo c6 tinh 6xi hoa rat manh, 6xi hod manh ligt muse CA 7: Cho sor dd phan tmg: Fe 208" (xy HO, cyy aK, (7880.8 yy X va Z lan luot la A. Fes, va FeSOx, B. Fey($0,); va FeSO, C, FeO va FeSO, D. FeO va Fex(SO.)s. Cfiu 8: Amino axit X c6 céng thie H,N-C,H,(COOH);. Cho 0,1 mol X vao 0,2 lit dung dich H2S0, 0,5M, thu duge dung dich Y. Cho Y phan img vica dit véi dung dich g6m NaOH IM va KOI 3M, thu dusge dung dich chita 36,7 gam mudi, Phin trim etia nguyén t6 nite trong X 1a A. 11,966% B. 10,526% C.9,524% D, 10,687% (Cu 9: Cho eae phan img ha hoe (1) CHLOH + H,S0, die > C,HsOSOsH + H,0 (2) GH,OH ES2ateet0'C 5 CH, + HO. (3) GH(OH + CH,COOH = CH,COOGH;+H;0 (4) GHsBr+NaOH > C)H,OH+NaBr (5) CH, + H,0 —> CH.OH ‘Cac phan img thé la: A145 Bu C14 D.4 (Cau 10: Cho m gam Fe téc dung vira hét voi 200 ml dung dich HINO 0,1M, két thie phan tig thu duge V lit khi NO (dktc, san phdm khir duy nhdt) va dung dich chira 1,28 gam mudi sit. Tim gid tri cla m va V? A. 0,35 g: 0,112 lit B.0,135 g50,224 lit C.0,7 8: 0,112 lit D. 0,7 g; 1,12 lit (Cf 11: Kim loai nao sau day téc dung manh véi nude & nhiét d6 thutmg: A.AL B.Fe Ccu D.Ca Cfu 12: Hén hop X gém tripeptit R va tetrapeptit T déu duge cdu tao béi glyxin va alanin. % khdi long nito trong R va T theo thir tr lé 19,36% va 19.44%, Thuy phan hoan 0,1 mol hén hop X bing mét long dung dich NaOH vira di, thu duge dd Y. Cé can dung dich ¥ thu durgc 36,34 gam hn hop mudi Ti mol gitta R va T trong hén hop X A.73 B.23 C32 D.3:7 Cfu 13: Hén hop khi R gém hai hidrocacbon mach thing X, Y c6 thé tich 0,672 lit (dkte). Chia hén hop R thanh 2 phan bang nhau. Phan | cho qua dung dich Br, du, thay khoi lugng binh dung dich brom tang m, gam, lugng Br; tham ‘Trang 1/5 - Ma dé thi 209gia phan tmg la 3,2 gam va khOng c6 khi thodt ra khdi dung dich brom, Phan 2 dem dét hodn toan, sin phim ehay Lin Iuot din qua binh P,Os rdi dén binh chira KOH du, sau thi nghiém binh P;Os tang m) gam con binh KOH tang 1,76 gam. Gia tri m), m, lan luot la A. 0, 53; 0,57 B. 0,55, 0,63, €. 0,63; 0,57 D. 0,59; 0,63 CAu 14: Cho m gam hén hop X (g6m Mg, Al, Zn,Cu) téc dung hét véi dung dich HINO; thu duge dung dich Y (khong 6 mudi amoni) va 11,2 lit (dkte) hén hop khi Z (g6m Nz, NO, N20 va NOx; trong dé NO va NzO ¢6 s6 mol bing rnhau) ¢6 ti KhOi so vai heli bing 9,25. $6 mol HNO; phan ting la A. 2,8 mol B. 3,0 mol €.3,5 mol D. 3,4 mol Cfiw 15: Cho ede phan img sau (1) X-+ 2NaOH > 2¥+ H;0; (2) ¥ + HClom, > Z * NaCl Biét X 1a hop chat hau co ¢6 céng thie phén ttt C4H1;pOs. Khi cho 0,1 mol Z tac dung hét v6i Na (du) thi s6 mol ctia Hh thu due la A.0,20 B.0,15 €.0,05 D.0,10 ‘CAu 16: Dién phan 200 ml dung dich hin hop gdm NaCl 0,5M va Cu(NOs); 0,75M (dién cue tro, 6 mang ngan) dén hi khdi Iuong dung dich gidm 11,65 gam thi dimg lai, Dung dich thu duge sau dign phan chtta céc chat tan la ‘A, NaNO, HINOs va Cu(NOs)z B. NaNO, NaCl va Cu(NOs), C. NaCl vi Cu(NO3)2 D. NaNO; vi Cu(NOs), Cfu 17: Nhiét d6 thang v6i 16 Ién t6i 150°C va e6 pH = 13,1. Vi vay gui d6 vita bi bong do nhiet, vita bi bong do kié rat xdu, Nhung néu duge so citu kip thoi thi hau qua dé lai s® duoe giém nhe rit mhiéu. Hay Iya chon mét phuong phap so tu ma em cho la c6 higu qua nbat trong cae phuong phap sau A. Déi nude lanh lign tuc vao vét bong cho sach v6i rdi ding nude mam dé lén (nude mam cé d6 pH < 7,0). B. Chi d6i nude lanh lién tue vao vét bong cho sach voi C. Déi nude lanh lign tue vao vét bong cho sach véi rdi dung dam an déi lén, D. Déi nude anh lign tue vao vet bong cho sach v6i rdi pha kem danh rang lén. CAu 18: Thuy phan triglixerit X tong NaOH nguii ta thu duge hn hop 3 mudi natri oleat, natri sterat va natei linoleat, Khi dot chay a mol X thu duoc b mol COs va ¢ mol Hs, Lién hé gitta a, b,c la C.b-¢=5a D. b-e= 6a. :: Hén hop M g6m 2 axit cacboxylic déu no, mach hé X,Y (Y hon X mét nhém chit), Héa hoi hoan toan m gam M- ‘thu duge thé tich hoi bing thé tich ctia 7 gam nito do cing diéu kién nhiét d6, 4p suat. Néu cho m gam M tac dung voi Na dur thu duge 4,48 lit H (dite). Khi dét chay hodn toan m gam M thu duroe 28,62 CO,, Céng thite phan tir ciia X va ¥ le A. CH,03 va CHO, B, CHO; vaCH:Oy,—C, CaH:O3 vA CHO, CaH,O3 va CHy Cfu 20: Cho m gam hén hop X gm axit fomic, axit benzoic, axit adipic, axit oxalic téc dung vira dit véi dung dich ‘NaOH, thu duge a gam mudi. Cling cho m gam hén hop X trén téc dung vira dit véi dung dich Ca(OH), thu duge b gam mubi, Bigu thitc lién h@ gitta m, a va b li A. 9m = 20a-LIb. B. 8m = 192-Ib. C. 3m =22b-19a D, 3m= 1 1b-10a Cfu 21: Phan img hod hoc gitta khi cacbonic véi vdi t6i la co sé sir dung vaa v6i trong xy dung. Tuy nhién, khi Iuomg cacbonic qua nhiéu céng trinh sé khéng bén ving vi tao ra sin phim Ca(HCOs)2. Cho khi CO» téc dung véi dung dich chita a mol Ca(OH). B6 thi nao sau day biéu dign mdi quan hé gitta s6 mol Ca(HCOs), véi s6 mol CO;? + B._ > 0 a 2a n(CO2) n(CO,) 4 a——> c. ! 50) D. > “D a 2a n(CO2) "0, 2a n(COr) a a Cfu 22: Day gbm céc kim logi duge diéu ché trong eéng nghiép bing phuong phdp dién phan hop chat néng chdy ca ching, la A. Na, Ca, Al B. Fe, Ca, Al C.Na, Cu, Al D. Na, Ca, Zn. ‘Trang 2/5 - Ma dé thi 209CAu 23: Cho 32,25 gam mét mudi c6 cOng thire phan tir 1a CH,O.NS tac dung hét véi 750 ml_dung dich NaOH IM dun néng thay thodt ra chit khi lam xanh quy tim am va thu dae dung dich X chi chita cdc chat v6 co. C6 can dung dich X thu due bao nhiéu gam chat rn khan’? A. 355. B. 50,0 €.30.0 D455, (Cu 24: Syrmé ta nao sau day khdng diing hign tuong héa hoc ? ‘A. Cho propilen dur vao nude brom thay nude brom bj mat mau va thu duge mot dung dich dng nat trong sud B. Cho quy tim vio dung dich benzyl amin thay quy tim chuyén sang mau xanh. . Cho tir tir dung dich CHCOOH loang vio dung dich Na;CO, va Khudy déu, ue diu Khéng thy hién twong gi, sau mot thai gian thay 6 sii bot khi D. Cho ti tir anilin vao dung dich HC! thay anilin tan dan yao dung dich HCl. CAu 25: Cho 4,96 gam hén hop Ca, CaC; tac dung hét v6i H,O thu duge 2,24 lit (dkte) hén hop X. un néng hén hop khi X c6 mat xii tac thich hop thu durge hdn hop khi Y. Chia Y thinh 2 phan bing nhau, Lay mot phan hén hop Y cho I6i tir tir qua binh nude Bry dur thay c6n lai 0,448 lit (dktc) hn hop khi Z e6 4, = 4,5. Kh6i long (gam) binh Br) tang la A. 0,98 gam. B. 0,6 gam. €.0,7 gam D. 0,4 gam. CA 26: Cho phan img: (CH=CH-C,He-CH,CH;CH, + KMn0, -> KxCO; + KOOC-CH.-COOK + CHCOOK + MnO; + KOH + H,0 Téng hé sé nguyén tdi gian cia cac chat trong san phdm tao thanh 1a: A. 42 B.23 C.65 D.46 Cfu 27: Hén hop X gém C:1OH, CHsCOOH, CHsCHO, trong dé CH.OH chiém 50% vé s6 mol. Khi_ dt chdy hoan toan m gam hén hop X thu duge 3,06 gam 11,0 va 3,136 lit CO, (6 dktc). Mat Khéc, Khi cho m gam hén hop X tée dung véi lugng dur dung dich AgNO; trong NH; thu duge a gam bac. Gid tri eda a le AL 8,64 B. 1,08 C.432. D. 2,16 ‘em mé hinh thi nghiém, X la chat rin, Y la chit khi it X roi xudng gap nude, tan ra thi chat ling tro dung trong éng chit U méi dich chuyén theo chigu mai tén cong. Chit X, ¥ la A. P:05 va COz B. Ca va NH, C.Na,0 va CO D, CuSO, va HS (Cfu 29: Tién hanh thi nghigm nhu hinh v8, Ban diu trong ede ehita nude véi trong. Sue rt tir tir khi COp vao cbc cho ti dur Hoi dé sng ca bong dén thay d6i nhu thé nao? A. Ban dau mé din di ri tai séng dan len [ B. Mé dan di sau dé van mé mo. C. Ma din di ri sau dé tit hin D. Ban dau khéng déi, sau dé sang din lén. CAu 30: Khang axcton bing phuong phip A. oxi héa ancol propylic bing CuO, dét néng, B. oxi héa ancol isopropylic bang CuO, dét néng. C. sue khi propin vio dung dich chita déng thi HgSO, va H:SO, lodng (dun néng), D. oxi héa cumen (isopropyl benzen) bing O» c6 xi tae va dot nong Cau 31: Hon hap X gém Fe, va. mot mudi sunfua cia kim loai M ¢6 s6 mol bing nhau, Cho 6,51 gam hin hop X tée dung véi lugng t6i thiéu dung dich HNO; dun néng, phan ting két thie duge dung dich Y va 13,216 lit (dkte) hn hop khi Z c6 khdi luomg 1a 26,34 gam gm NO;, NO. Kim loai Ma AZn B.Ca C.Mg D.cu Cfu 32: Dun néng m gam mét hop chat hitu eo e6 chita C, H, O mach hi véi 100 ml dung dich KOH 2M dén khi phan tmg xiy ra hoan toan ta thu duoc dung dich X. Dé trung hoa vira hét long KOH du can ding 80 ml dung dich HCI 0,5M, Lam bay hoi hén hop sau khi trung hoa mot céch edn than thu duoc 7,36 gam hdn hop hai ancol don chite va 18,34 gam hin hop hai mudi, Vay m bing A. 13,42, B. 13,76. €.21,12 Dz 12,68 Cfiu 33: Goi tén chit sau CH(CH;} COOH A. 3,3-diclo-2-metyl pentanoic. B. 3, 3-clo-2-metyl pentanoic. C. 3,3-diclo-3-metyl pentanoie. D. 3,3-diclo~ Cfu 34: Phat biéu nao sau day ding ? ‘A. Glucoze, mantozo, fructozo, fomandehit la nhiing cacbohidrat c6 phan img trang bac. B, Nhém ede chat: Val, Glu, Lys déu lam 46i mau quy tim am. C. Tinh baz ctia cde cht: NaOH, C2H;ONa, CHs-NH;, NH; gidm dan tir trai sang phai, D. Ftilen bi oxi hod boi brom Cfiu 35: Cho phan img: 2KCIOs(r) > 2KCI(r) + 3 Oa(k) metyl pentanic. ‘Trang 3/5 - Ma dé thi 209‘Yéu t6 kehdng lam anh hung 167 tc d6 phan img trén 1a: A. Ap suit B. Kich thude tinh C. Xue tae D. Nhigt 46 Cfu 36: Dung dich X chita HCI, CuSO,, Fex(SO,)s. Lay 400 ml dung dich X dem dign phan véi dién ewe tro, T= 7,724 dén khi 6 catot thu duge 5,12 gam Cu thi dimg lai, Khi 4) 6 anot c6 0,1 mol mot chat khi thoat ra. Thai gian dign phan va ndng dé [Fe""] lan lot la A. 2500 s va 0,15M. B, 2300 s va 0,15M. C. 2500 s va 0,1M. D. 2300 s va 0,1M Cfiu 37: Dich vi da day thudmg cé pH khodng tir 2-3, Nhiing ngudi ndo bi mae bénh viém loét da day, t@ tring thuong c6 pH <2. Dé chita cn bénh nay, trude bia an, nguéi bénh thuémg wong C105 A. mot it gidm an B. nude dun s6i dé nguéi . dung dich natri hidrocacbonat. D. nude duimg (Cfiu 38: Loai thue phim nao sau day ehtta it saccarozo nhat ‘A. mat mia. B. mat ong. C. dudng kinh, D. dudng phen. CAu 39: Cho 27,4 gam Ba tan hét vao made thu duge dung dich X. Cho dung dich X téc dung véi 150 ml dung dich FeSO, 1M, loc lay ket ta, ri nung trong khong khi dén khoi Ivong khéng doi cin lai chat ran c6 khdi luong la ‘A. 45,75 gam. B. 12 gam. C. 62.2 gam D, 46,95 gam ‘Cfu 40: Trung hoa hét 10,36 gam axit hitu co don chire bing dung dich Ba(OH), vira di thu dae 19,81 gam mudi khan. Xae dinh eéng thize cua axit? A. CH,COOH B.C.H,COOH C. GH,COOH D. CH,COOH CAu 41: Cho m, gam Al vao 100 ml dung dich gém Cu(NO,), 0,3M va AgNO, 0,3M. Sau khi cée phan tmg xay ra ‘hoan toan thi thu duge m; gam chat rin X. Néu cho m, gam X tée dung véi lugng du dung dich HCI thi thu duge 0,336 lit khi (& dkte). Gia tri cia m; va m, lin luot Ia A. 1,08 va 5,43, B. 0,54 va 5,16. C. 1,08 va 5,16. D. 8,10 va 5,43. (Cfiu 42: Nguyén tir M cé 20 electron, vay cation M’ cé dign tich hat nhén la ALI B. 18+. €.20 D. 20+, (Cfiu 43: Polime nao sau day thude polime thién nhién: A, Cao su buna B. Poli etylen C. Bong D. nilon 6,6 (Cfiu 44: M6t thanh kim loai manh ngim véo mOt dung dich H;SO. loging nhur hinh vé, Sau m6t ther gian (dai) thanh kim loai bi gay tai ding ranh gidi tiép xiic gitta dung dich va khong khi, Thanh kim loai la A. Au B.Cu C.Ni D. Zn Cu 45: Hin hop X gm cae chat ¥ (CsHyyN,Q,) va chat Z (C,H,N,0;); trong dé Y 14 mudi ctta axit da chite, Z 1a dipeptit mach hé. Cho 28,08 gam X téc dung véi dung dich NaOH du, dun néng, thu duge 0,12 mol hdn hop Khi déu Jim xanh quy tim dm, Mit khée, 28,08 gam X tie dung véi dung dich HCI du, dun néng thu duge m gam chat hu ea Gia tricia m la A. 37.65, B. 36,54. C429 D. 38.85 CAu 46: Chit nao sau day 14 dng ding cia benzen ? «(dy 2) CiHy e) @ & ot & @ © A.(), 2,8), @. B.(1), 2), 3). C.@) D.2 Cu 47: Cho cae phan img héa hoe saw (1) 2Fe*3CuCl > 2FeCls + 3Cu (2) Fe + 3AgNOs (du) Fe(NO3)s + 3Ag (3) 2Fe + 6H,SO, (dic)*2°F Fe,($0,)s + 380, + 6H,O (4) 2NaCl (rin) + H,SO, (de) =P Na,S0, + 2HC1 (5) Cl + Ca(OH), (sita vai)?" F CaCl; + 1,0 Nhiing phan img hod hoe khéng ding 1a A. (1), 6). B. (1), (3), (4). C. (1), (4), (5) D. (2), (4). CAu 48: Cho dung dich Fe(NOs); lin luot tae dung véi ede dung dich Na;S, 11,80, long, 1:8, 180, de, NUL, AgNO}, NayCOs, Bra $6 trutmg hop xdy ra phn tng la B38 C7 D.6 tho m gam hn hop N gém 3 peptit X, Y, Z.déu mach ho ya c6 ti @ s6 mol ny: ny: nz =2: 3:5, Thay phan hon toan N, thu dive 60 gam Gly, 80,1 gam Ala, 117 gam Val. Biét sign két peptit trong X, Y, Z khée nhau va e6 tng la 6, Gid tri cua m la ‘Trang 4/5 - Ma dé thi 209AL1765. B. 22655 255.4 D, 257.1 Cau 5 ti Khi an todn duge sit dung trong cae xe hoi, Chiing chita natri azit (NaNj), kali nitrat (KNOs) va silie dioxxit (SiO). Khi xe hoi bj va cham, mét loat ba phan img héa hoc bén trong tii sé tao thinh khi nite (N2) lam day titi khi, chuyén cae san phim phy nguy hiém thanh vé hai va tao thanh hgp chat silicat 6n dinh (NajK,SiO,). Cac phuong trinh héa hoe ciia nhimg phan img nay 1a Phan tg 1: NaN; —> 2Na~3Nz Phan img 2: 10Na + 2KNO; —+ KO + SNaxO + Ns Phan img 3: K;0 + Na; + SiO + Na;K:SiO, Toain bé can bang cita phan img héa hoc tao thanh Khi tir eée phan img (1 va 2) la ‘A. 2NaN; + 10a + 2KNOs — 2Na + K,0 + SNa,O 4N3 B. 10NaN; + 2KNO, > K;0 + SNasO + 16N C, 10NaN; + 2KNO; + 10Na—> 2Na+K;0 + SNa0 + 16N2 D, 2NaN; + 2KNOs — KO + SNax0 + AN Cho biét NTK: H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Ni = 59; Cu = 64; Zn = 65; Br = 80; Ag = 108; 1 = 127; Ba = 137; Au = 197. HET -. ‘Trang 5/5 - Ma dé thi 209