C

O
N
H
2
C
H
3

C
O
N
H
2

C
O
N
H
2
O
C
H
3

C
O
N
H
2

1. Which of the following can undergo Hoffmann reaction most easily?

1)

2)

3)

4)
CN

H
2N
H
N
H
H
C
2
2N
3N
O
2N
C
H
3

2. The correct order of decreasing base strength among the amines given is

(II)

(I)

(III)

(IV)

1) III>I>IV>II
2) IV>III>I>II
3) I>IV>III>II
4)I>III>IV>II
3. Which of the following reaction can produce aniline as the main product?
A)
C)

C6 H 5 NO 2 Zn / KOH

B)

C6 H 5 NO 2 Li Al H 4

D)

C6 H 5 NO 2 Zn / NH 4Cl
C6 H 5 NO 2 Sn / HCl

4. Which will give positive isocyanide test

NH2
H3C

CH3
H3C

CH3

NH

H3C

H3C

CH3

NH CH3

N
CH3

1)
2)
3)
4)
5. An organic compound upon hydrolysis produces two compounds one product
gave silver mirror test, other product reacts with Hinsberg reagent to produce an
alkali insoluble product. The organic compound
3 is
1)

3)

O
||
CH 3 CH 2 C NHCH 3

O
N
H
H
C
H
3
2C
3C

O
C
H
H
C
N
3

2)

4)

O
H
H
N
H
C
C
3
2C

CN

6. The IUPAC name of

is

1) 2-methyl-3-(1-methylethyl)-4-oxopentanenitrile
2) 4-cyano3-(1-methylethyl)2pentanone
3) 3-acetyl2cyano4methylpentane
4) 3ethanoyl2methyl3(1methylethyl) pentanenitrile
7. Acid strength of the conjugate acids of the following are
(I)

(II)

(III)

NH

(IV)

NH

1) II > III > I > IV

2) II > IV > I > III

3) II > I > III > IV

4) II > IV > III > I

C
H
2O

C
H
2

O
H

8. Treatment of cyclobutylmethanamine with nitrous acid doesnt give

II

IV

III

1) I, II, IV

2) II, V, I

3) I, II, IV, V

4) III only