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Table 1: Constant parameters of CH4 and CO2 (Sloan and Koh 2008, 223)

Constant parameters
A
B
C
D
E
F
G
H
I
J
K
L
M
N
O
Q
R
S
Correlation Coefficient, R2

CH4
1.63636
0
0
31.6621
-49.3534
-5.31E-6
0
0
0.128525
-0.78338
0
0
0
-5.3569
0
-2.3E-7
-2.0E-8
0
0.999

CO2
9.0242
0
0
-207.033
0
4.66E-5
-6.992E-3
-2.89E-6
-6.223E-3
0
0
0
0.27098
0
0
8.82E-5
2.55E-6
0
0.996

Table 2: Hydrate phases boundaries for common gas components (John 2003, 34)

Q1: I-Lw-H-V
T(C)

P(MPa)

Methane

-0.3

2.563

Carbon dioxide

-0.1

1.256

Q2: Lw-LHC-V-H
P(MPa)

T(C)
No Q2
9.8

4.499

List of symbols and abbreviation


Q1
Q2
Lw
H
V
LHC
STEYX

Lower Quadruple Point


Upper Quadruple Point
Water Liquid Phase
Hydrate Phase
Vapor Phase
Hydrocarbon Liquid Phase
Standard Error for the Line of Best Fit