BI 1: TI SINH GIY CARTON T GIY THU HI

Mc ch th nghim
Hiu v phng php sn xut giy th cng
Tnh cht c l c bn ca giy
nh hng ca ph gia n tnh cht c l ca giy
Vai tr ca nguyn liu giy thu hi
Thit b ha cht
Khun xeo giy (1 b) : 01

bp cao su: 01

B cha dd xeo : 01

a thy tinh : 02

Bn i phillip : 01

ni nhm: 01

T sy memert : 01

bp in: 01

Becher 600ml :01

giy ba bi : 02

Nhit k 1000C :01

buret : 01

(AL2SO4)3.18H2O( 3%)

dung dch AKD 4%

Tinh bt

H2O

Thc nghim
S khi

Sy

Giy kh t

Nc

Ngm giy

Giy qua s dng

Tinh bt, Nc, AL2SO4)3.18H2O

Dd gia keo

nh ti

Phi trn ph gia

Xeo giy

To hnh

Nc thi

To hnh

Nc thi

Sy kh

Nc thi

Giy carton

Kt qu thc nghim

Kho st nh hng ca hm lng tinh bt

Hnh nh

Hnh 1. Giy vi hm lng tinh bt 10 v 30 (g/kg bt)

Hnh 2. Giy vi hm lng tinh bt(2%) l 40 v 50 (g/kg bt)

Kho st nh hng ca hm lng dung dch gia keo

Hnh 3. Giy vi dung dch gia keo 5 v 15 (g/kg bt)

Hnh 4. Giy vi dung dch gia keo 20 v 30 (g/kg bt)

Kim tra nh lng giy

p dng cng thc sau:

m
g
g= 1000( 2 )
A
m
Bng kt qu
Th nghim

Mu

nh hng

ca tinh bt

Khi lng

Din tch

nh lng

2
3
4

nh hng
ca dung dch
gia keo

1
2
3
4

Kim tra khng nc

Khi lng (g)

Thi gian thm nc

TN 1.1

3.21

2s40

TN 1.2

3.55

3s13

TN 1.3

3.16

4s42

TN 1.4

3.97

3s94

TN 2.1

3.02

2s38

TN 2.2

3.85

3s99

TN 2.3

3.65

3s06

TN 2.4

3.88

2s90

Cu hi cui bi

1. Gii thch ti sao Cellulose li c tnh cht si?

V l 1 loi polysaccarit c to thnh t monome l

- glucose. Trong cellulose

c cha hemicellulose v lignin ( cc b si c bao bc, kt ni vi nhau bi cht

nha nhit do c cu trc phc tp ny). Ngoi ra cn do nh hng ca lc lin kt
hidro v lin kt vanderwan
2. Trnh by cng dng ca cc cht trong n cng ngh ti sinh giy carton t giy thu
-

hi?
Phn n aluminium sulfate: khi aluminium sunfate cho vo bt giy cng mui n s
to nn nhm clorua, b thy phn mnh hn to nhm hydroxit, chnh hydroxit ny s

kt dnh nhng si cellulose li lm giy khng b nhe mc khi vit.

Keo AKD:
m bo Cobb tiu chun
Tng kh nng chng thm nc b mt giy, to cho b mt x si 1 lp ngn cn s
phn tn ca nc
Tng bn, tng lin kt gia x si t. To bng cho giy.

3. Ti sao phi s dng nguyn liu giy thu hi trng thi kh tuyt i?
V trnh b sai s v th tch
t hiu sut thu hi bt giy cao.
BI 4: TI SINH ACID TEREPHTHALIC V ETHYLENE GLYCOL T CHAI
NHA
Mc ch th nghim
-

Hiu v vn dng l thuyt v ti sinh rc thi nha

Ti sinh acid terephthalic v ethylene glycol t chai nha pet
Kho st cc yu t nh hng n vic ti sinh acid terephthalic v ehylene

glycol
Xc nh cu trc v tinh khit ca sn phm bng phn tch ha ly

Thc nghim
Dng c v ha cht
-

Bp in
Bercher 250ml
Bercher 500ml
Giy lc
Phu lc
Nhit k
Pipet 10ml
Pipet 20ml

a thy tinh
Bp cao su
NaOH rn
Nha pet
HCl m c
Nc ct

Nha pet

Thc nghim

un

NaOH, 5ml nc

Lc ly dung dch

HCl m c

Lc v ly kt ta

Nc lc

Sy kh

Chng ct chn khng

S khi

Acid terephtalic
Ethylene glycol

Kt qa
Hnh nh

Hnh 3. Acid terephtalic

Xc nh hm lng NaCl bng phng php chun

10ml dung dch lc

100ml nc ct, 3 git K2CrO4 10%

Chun bng AgNO3 n khi xut hin gch

V AgNO3(ml)

Hm lng NaCl c trong mu tnh bng cng thc sau:

g 0.00585. V dm . a
=
.1000
l
V mu .V 1

()

Trong :

: th tch AgNO3 0.1N tiu tn khi chun

V1: th tch dung dch em chun

Vmu: th tch dung dch mu
Vdm: th tch bnh nh mc(ml)
0.00585 l s gam NaCl tng ng vi 1ml dd AgNO3 0.1N
Bng kt qu
Erlen

V1

Vdm

Vmu

4.7

110

100

100

42.7272

5.1

110

100

100

46.3636

4.9

110

100

100

44.5455

X
44.5454

nh gi kt qu
-

Lng acid terephtalic ti sinh t hiu sut khng cao nguyn nhn v thi gian
thy phn cha t, cn qu ngn.

Tr li cu hi

1. iu kin ti u ca phn ng ti sinh acid terephthalic? V sao?

Thi gian thy phn v nu khng t c thi gian cho acid terephtalic tch ra
th hiu sut thu c s rt thp, ngoi ra cn k nng ca ngi thc hin th
nghim.
Nng dung dch NaOH khi a vo lm xc tc
Nhit phn ng, ti u l 70oC, nhit qu cao s lm chy nha
2. Trnh by c ch ca phn ng thy phn pet?
3.