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Question1.
When1moleofanidealgasiscompressedtohalfofitsinitialvolume,itstemperaturebecomesdouble.Thenthechangeinentropy
wouldbe:
[A]
[B]
[C]
[D]

Question2.
Theprecipitateof

isobtainedwhenequalvolumesofthefollowingaremixed:

[A]
[B]
[C]
[D]

Question3.
Thegeometrywithrespecttothecentralatomofthefollowingmoleculesare:

[A]
[B]
[C]
[D]

Planar,pyramidal,planar
Planar,pyramidal,pyramidal
Pyramidal,pyramidal,pyramidal
Pyramidal,planar,pyramidal

Question4.
Amongst

thecompoundswithgreatestandleastioniccharacterrespectivelyare:

[A]
[B]
[C]
[D]

Question5.
Oxygenismoreelectronegativethansulphur,yet

isacidicinnaturewhile

[A]

moleculeareassociatedduetointermolecularhydrogenbonding

[B]

hashigherboilingpointthan

[C]

bondisweakerthan

[D]

isneutral,because:

bond

isgasatordinarytemperaturewhile

isliquid

Question6.
FromseparatesolutionoffoursodiumsaltsNaW,NaX,NaYandNaZhadpH7.0,9.0,10.0and11.0respectively.Wheneachsolution
was0.1M,thestrongestacidis:
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[A]
[B]
[C]
[D]

QuestionRevision

HW
HX
HY
HZ

Question7.
AsampleofanidealgaswithinitialpressurePandvolumeVistakenreversiblythroughanisothermalprocessduringwhichentropy
changeisfoundtobe
.TheuniversalgasconstantisR.Thentheworkdonebythegasisgivenby:
[A]
[B]
[C]
[D]

Question8.
Sodiumperoxideisusedtopurifytheairinsubmarinesandconfinedspacesbecause:
[A]

Itremoves

andproduces

[B]

Itdecomposestoform

[C]
[D]

Itreactswithoxygentoformsodiumsuperoxide
Allofthese

Question9.
ThespecieshavingbondorderdifferentfromthatinCOis:
[A]
[B]
[C]
[D]

Question10.
AnammoniaammoniumchloridebufferhasapHvalueof9with
KOHbeaddedto200mLbuffersolution
[A]
[B]
[C]
[D]

.ByhowmuchthepHwillchangeif75mLof0.1M

0.2
0.3
0.1
0.4

Question11.
When200mLof1MNaOHsolutionismixedwith100mLof1MHCland100mLof1M
temperature,thetemperaturesoftwomixturesriseby

solutionsseparatelyataconstant

oC.Then,

[A]
[B]
[C]
[D]

Unpredictable

Question12.
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Thetwoequilibria

aresimultaneouslywithequilibriumconstant

respectively.theratioof

inthesolutionis:

[A]

Directlyproportionaltotheconcentrationof

[B]

Inverselyproportionaltotheconcentrationof

[C]

Directlyproportionaltothesquareoftheconcentrationof

[D]

Inverselyproportionaltothesquareoftheconcentrationof

Question13.
Selectthecorrectstatement:
[A]

Perxenateionis

withoctahedralgeometry

isbentmoleculewith3lonepairs(I.p)

[B]

allcontainsonelonepaironly

[C]
[D]

Noneofthese

Question14.
Thermalstabilityof

isinorder:

[A]
[B]
[C]
[D]

Question15.
Whichofthefollowingrepresentscorrectrelationshipofbondlengths?
[A]
[B]
[C]
[D]

Question16.
Calculatetheratioof

and

inamixtureof

and0.1MHF

:
[A]
[B]
[C]
[D]

Question17.
Assumethatareactionhas

.Atwhattemperaturerangewillitchangefromspontaneousto

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nonspontaneous?
[A]
[B]
[C]
[D]

Question18.
TheratioofdissociationconstantoftwoweakacidsHAandHBis4.Atwhatmolarconcentrationratio,thetwoacidswillhavesamepH:
[A]
[B]
[C]
[D]

2
0.5
4
0.25

Question19.
Amongthefollowing,theparamagneticcompoundis:
[A]
[B]
[C]
[D]

Question20.
Thepairofcompoundswhichcannotexisttogetherinsolutionis:
[A]
[B]
[C]
[D]

Question21.
When1moleofgasisheatedatconstantvolume,temperatureisraisedfrom298to308K.Heatsuppliedtothegasis500J.Thenwhich
statementiscorrect?
[A]
[B]
[C]
[D]

Question22.
WhichofthefollowingstatementisincorrectforH3BO 3?
[A]
[B]
[C]
[D]

ItisaLewisacid
ItisatriproticArrheniusacid
Itinvolves
backbonding
Boronhasincompleteoctetofelectrons

Question23.
Whichofthefollowingalkalineearthmetalhydroxidesistheleastsolubleinwater?
[A]
[B]
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[C]
[D]

Question24.
isanunstableyelloworangesolidand
The

bondlengthin

and

isacolourlessliquid,bothhave

bond.

respectivelyis:

[A]
[B]
[C]
[D]

Question25.
Toacertainvolumeofaweakmonobasicacid,when20mLofNaOHsolutionisadded,pHoftheresultingsolutionwasfoundtobe3.7
whereaswhen30mLofthesameNaOHisaddedtothesamevolumeoftheacidfromsamestock,pHwasfoundtobe4.18.Determine
oftheacid.
[A]
[B]
[C]
[D]

Question26.
Forapuresubstance,aplotofGibb'sfreeenergy(G)againsttemperatureatconstantpressureis:

[A]

[B]

[C]

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[D]

Question27.
Onemoleofnonidealgasundergoesachangeofstate
internalenergy
[A]
[B]
[C]
[D]

to

withachangein

.ThechangeinenthalpyoftheprocessinLatm:

43
57
42
38

Question28.
Thecorrectsolubilityorderis(are):
[A]
[B]
[C]
[D]

Question29.
Amongst

,thenonplanarspeciesare:

[A]
[B]
[C]
[D]

Question30.
AnidealmonatomicgasistakenroundthecycleABCDAasshowninfigure.Theworkdoneduringcycleis:

[A]
[B]

PV
2PV

[C]
[D]

Zero

Question31.
Athickropeofdensity

andlengthLishungfromarigidsupport.Theincreaseinlengthoftheropeduetoitsownweightis:(Yis

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theYoung'smodulus)
[A]

[B]

[C]

[D]

Question32.
Young'smodulusofbrassandsteelare

and

respectively.Abrasswireandasteelwireofthe

samelengthareextendedby1mmunderthesameforce.TheradiiofthebrassandsteelwiresareRBandRS,respectively.Then:
[A]
[B]
[C]
[D]

Question33.
Twoblocksofmasses1kgand2kgareconnectedbyametalwiregoingoverasmoothpulleyasshowninthefigure.Thebreaking
stressofthemetalis

If

,thenwhatshouldbetheminimumradiusofthewireusedifitisnot

tobreak?

[A]
[B]
[C]
[D]

0.5mm
1mm
1.5mm
2mm

Question34.
TwometallicspheresS1andS2aremadeofthesamematerialandhavegotidenticalsurfacefinish.
ThemassofS1isthricethatofS2.Boththespheresareheatedtothesamehightemperatureandplacedinthesameroomhavinglower
temperaturebutarethermallyinsulatedfromeachother.TheratiooftheinitialrateofcoolingofS1tothatofS2is:
[A]

[B]
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[C]

[D]

Question35.
Adiatomicgasiscompressedadiabaticallyto

ofitsinitialvolume.IfinitialtemperatureisTKandfinaltemperatureisaTKthenthe

valueofais:
[A]
[B]
[C]
[D]

2
3
4
Noneofthese

Question36.
Startingwiththesameinitialconditions,anidealgasexpandsfromvolumeV1toV2inthreedifferentways,theworkdonebythegasis
W1iftheprocessispurelyisothermal,W2ifpurelyisobaricandW3ifpurelyadiabatic,then:
[A]
[B]
[C]
[D]

Question37.
Initially,thespringisunstretched.Thegasisallowedtoexpand.Atequilibrium,thecompressionofthespringis

gasisW,changeininternalenergyis

.Workdonebythe

.Then:

[A]

[B]

[C]

[D]

Question38.
Asealedtankcontainingaliquidofdensity
betweentwopointsAandBwillbe:

moveswithhorizontalaccelerationaasshowninthefigure.Thedifferenceinpressure

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[A]
[B]
[C]
[D]

Question39.
Ametalpieceofmass160gliesinequilibriuminsideaglassofwater.Thepiecetouchestheglassatsmallnumberofpoints.Ifthe
densityofthemetalis8000kg/m3,thenthenormalforceexertedbythebottomoftheglassonthemetalpieceis:

[A]
[B]
[C]
[D]

2N
8N
0.16N
1.4N

Question40.
AhollowsphereofmassM=50kgandradius

isimmersedinatankofwater(density

).

ThesphereistiedtothebottomofatankbytwowiresAandBasshown.TensioninwireAis:

[A]
[B]
[C]

125N

[D]

250N

Question41.
InacylindricalwatertanktherearetwosmallholesQandPonthewallatadepthof
of

fromtheupperlevelofwaterandataheight

fromthelowerendofthetank,respectively,asshowninthefigure.Watercomingoutfromboththeholesstrikethegroundat

thesamepoint.Theratioof

and

is:

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[A]
[B]
[C]

QuestionRevision

1
2

[D]

Question42.
Anidealfluidatthepipeasshowninthefigure.Thepressureinthefluidatthebottom
velocityofthetop

[A]
[B]
[C]
[D]

.Thentheratioofareas

isthesameasitisatthetop

the

is:

2:1
4:1
8:1
4:3

Question43.
AcylindricaltankofheightHisopenatthetopendandithasaradiusr.waterisfilledinituptoaheightofh.Thetimetakentoempty
thetankthroughaholeofradius

initsbottomis:

[A]

[B]
[C]
[D]

Noneofthese

Question44.
Apieceofmaterialweighing50.0giscoatedwith6.3gofwaxofspecificgravity0.9.Ifthecoatedpieceweighs16.3ginwater,thenthe
densityofthematerialis:
[A]
[B]
[C]
[D]

1.5
2.1
2.35
4.6

Question45.
AUtubeofuniformcrosssectionispartiallyfilledwithmercury.Waterispouredintoonelimbsothatmercurylevelgoesdownby1cm
onthatside.Theheightofthewatercolumnis:
[A]
[B]
[C]
[D]

13.6cm
27.2cm
0.136cm
0.272cm

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Question46.
Aconicalbodyofheighthisfloatinginbetweentwoliquidlayershavingdensity
theheight

.If

isthedensityofthecone,then

inthetopliquid:

[A]

[B]

[C]

[D]

Question47.
Atankfilledwithwaterhasfiveholesonitssides,spacedequallysuchthat1isatthetopand5isatbottom.Thetankisplacedona
standofequalheightasthetank.Whenthetankisfull,therangeonthegroundismaximumforoutflowfrom:

[A]
[B]
[C]
[D]

5
4
3
2or1

Question48.
Awoodenblockwithbaseareaaandheight

isfloatingonwaterinawatertankwithlength

Theblockcarriesnidenticalstoneseachofvolume

immersed.

timesthevolumeoftheblock.

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Thevalueofncanbe:
[A]
[B]
[C]
[D]

600
700
800
900

Question49.
Awoodenblockwithbaseareaaandheight

isfloatingonwaterinawatertankwithlength

Theblockcarriesnidenticalstoneseachofvolume

immersed.

timesthevolumeoftheblock.

Whenoneamongthenstoneswasdroppedintothewater,thedepthofimmersionoftheblockbecomes:
[A]
[B]
[C]
[D]

Question50.
Twoadiabaticexpansionsofnmoleofsamegasareshown.If

then

is

[A]

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[B]

[C]

[D]

Question51.
AandBaretwoidenticalcylinders,thefirstwithamovablesmoothpistonandthesecondwithafixedone.Bothcontainthesame
amountofanidealmonoatomicgasat27oC.Whenequalamountofheatisgiventoeach,itisfoundthattheriseintemperatureofthe
gasinAisT.NowthetemperatureofBis:
[A]
[B]
[C]
[D]

T
Zero

Question52.
Theratioofrmsvelocityofmoleculesoftwosystemsofmonoatomicgaseschangesfrom1:2to3:4whenthefirstadiabatically
compressedandthesecondsystemisisothermallyexpanded.Theratiooffinaltoinitialvolumesintheadiabaticprocessis:
[A]

[B]

[C]

[D]

Question53.
IfworkdoneinprocessABisW,workdoneinprocessABCAis:

[A]
[B]
[C]

0.3W
0.7W

[D]

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Question54.
Onemoleofanidealgas(monoatomic)attemperature
expandsslowlyaccordingtolaw
(cisconstant).Iffinaltemperatureis
.Heatsuppliedtogasis:

[A]
[B]
[C]
[D]

Question55.
TheworkdonebyonemolegasinthecyclicprocessshowningraphisW.Then:

[A]
[B]
[C]
[D]

Question56.
Aheatedbodyemitsradiationwhichhasmaximumradiationnearawavelength

.Theemissivityofthematerialis0.75.The

absolutetemperatureofthebodyisdoubled:
I.Themaximumintensityofradiationwillbenearwavelength
II.Themaximumintensityofradiationwillbenearwavelength
III.Thetotalenergyemittedwillincrease16times
IV.Thetotalenergyemittedwillincrease12times
Whichoftheabovestatementsis/aretrue:
[A]
[B]
[C]
[D]

IandIII
IIandIII
IIandIV
IandIV

Question57.
Apendulumclockkeepscorrecttimeat20oC.Thecorrectiontobemadeduringsummerperdaywheretheaveragetemperatureis
40oC,
[A]
[B]
[C]
[D]

willbe:
5.64s
6.64s
7.64s
8.64s

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Question58.
Acalorimeter(ofwaterequivalent50g)contains250gofwaterand50goficeat0oC.30gofwaterat80oCisaddedtoit.Thefinal
conditionofthesystemwillbe:
[A]
[B]
[C]
[D]

Thetemperatureofthesystemwillbe4.2oC
Thetemperatureofthesystemwillstillbe0oCandtheentireicewillmelt
Thetemperaturewillbe0oCandhalfoftheicewillmelt
Thetemperaturewillbe0oCand30goficewillmelt

Question59.
AwallhastwolayersAandB,eachmadeofdifferentmaterials.Thethicknessofboththelayersisthesame.Thethermalconductivity
ofAis
.Thetemperatureacrossthewallis20oC.Inthermalequilibrium:
[A]
[B]
[C]
[D]

ThetemperaturedifferenceacrossA=150oC
RateofheattransferacrossAismorethanacrossB
Rateofheattransferacrossbothissame
TemperaturedifferenceacrossAis15oC

Question60.
Inthegivenfigure,twoconductingsheetswiththermalresistanceRand3Rareshown.Thetemperatureoftheinterface

[A]
[B]
[C]
[D]

is:

20oC
60oC
75oC
80oC

Question61.
Thenumberofwaysinwhichthelettersoftheword'PERSON'canbeplacedinthesquaresofthegivenfiguresothatnorowremains
emptyis:

[A]
[B]
[C]
[D]

Question62.
Thenumberofevendivisorsofthenumber
[A]
[B]
[C]
[D]

is:

72
54
18
36

Question63.
Thenumberofwaysofchoosingacommitteeoftwowomenandthreemenfromfivewomenandsixmen,Mr.Arefusetoserveonthe
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committeeifMr.BisamemberandMr.Bcanonlyserve,ifMissCisthememberofthecommitteeis:
[A]
[B]
[C]
[D]

60
84
124
120

Question64.
ABCDisaconvexquadrilateraland3,4,5and6pointsaremarkedonthesidesAB,BC,CDandDA,respectively.Thenumberof
triangleswithverticesondifferentsidesis:
[A]
[B]
[C]
[D]

270
220
282
342

Question65.
ApersonbuyseightpacketsofTIDEdetergent.Eachpacketcontainsonecoupon,whichbearsoneofthelettersofthewordTIDE.Ifhe
showsallthelettersofthewordTIDE,hegetsonefreepacket.Ifhegetsexactlyonefreepacket,thenthenumberofdifferentpossible
combinationsofthecouponsis:
[A]
[B]
[C]
[D]

Question66.
Let
then

bethedivisorsofpositiveinteger'n'(including1andn).If

isequalto:

[A]

[B]

[C]

[D]

Question67.
Thetotalnumberofwaysinwhich

numberofidenticalballscanbeputinnnumberedboxes

suchthat

boxcontainsatleastinumberofballsis:
[A]
[B]
[C]

[D]

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Question68.
Let

denotethenumberofwaysinwhichkidenticalballscanbecolouredwithncolourssothatthereisatleastoneballof

eachcolour.Then

mustbeequalto:

[A]
[B]
[C]
[D]

Question69.
ThetotalnumberofwaysinwhichthreedistinctnumbersinA.P.canbeselectedfromtheset
[A]
[B]
[C]
[D]

isequalto:

66
132
198
99

Question70.
Thetotalnumberofwaysofselectingtwodistinctnumbersfromtheset

sothattheirsumisdivisibleby3is

equalto:
[A]

[B]
[C]
[D]

Question71.
Twopacksof52cardsareshuffledtogether.Thenumberofwaysinwhichamancanbedealt26cardssothathedoesnotgettwo
cardsofthesamesuitandsamedenominationis:
[A]
[B]
[C]
[D]

Question72.
nisselectedfromtheset

andthenumber

isformed.Totalnumberofwaysofselectingnso

thattheformednumberisdivisibleby4isequalto:
[A]
[B]
[C]
[D]

50
49
48
51

Question73.
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If
[A]
[B]
[C]
[D]

QuestionRevision

denotesthesumoffirst'n'termsofanA.P.and

,thenthevalueisnis:

21
15
16
19

Question74.
If
[A]

formtwoarithmeticprogressionsofthesamecommondifference,then
p,b,rareinA.P.
areinA.P.

[B]
[C]

areinA.P.if:

p,b,rareinG.P.
areinH.P.

[D]

Question75.
ConsideranA.P.
[A]
[B]
[C]
[D]

suchthat

and

,thenthevalueof

is:

5
7
9

Question76.
If

[A]
[B]
[C]
[D]

,thennisequalto:

256
255
254
257

Question77.
Concentriccirclesofradii1,2,3,...........,100cmaredrawn.Theinteriorofthesmallestcircleiscolouredredandtheangularregionsare
colouredalternatelygreenandred,sothatnotwoadjacentregionsareofthesamecolour.Then,thetotalareaofthegreenregionsin
sq.cmisequalto:
[A]
[B]
[C]
[D]

Question78.
If

denotesthesumoftheseries
,

and
,then

thesumoftheseries

intermsof

is:

[A]
[B]

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[C]

[D]

Question79.
Thevalueof

isequalto:

[A]
[B]
[C]

[D]

Question80.
If

[A]
[B]
[C]
[D]

for

and

,then

isequalto:

2001
0
1

Question81.
If

,then

isequalto:

[A]
[B]

2n

[C]
[D]

Question82.
Let

bethe

termandsumupto
,then

termofaseriesrespectively.Ifforanoddnaturalnumber

(mbeingevenis)is:

[A]

[B]

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[C]

[D]

Question83.
Thecoefficientof

intheexpressionof

is:

[A]
[B]
[C]
[D]

Question84.
Ifintheexpansionof

arethreeconsecutivecoefficients,thennequals:

[A]

[B]

[C]

[D]

Question85.
Thecoefficientof

intheexpansionof

are:

[A]
[B]
[C]
[D]

Noneofthese

Question86.
If
[A]
[B]
[C]
[D]

,then

equals:

10
20
210
Noneofthese

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Question87.
Thevalueof

is:[where

[A]
[B]
[C]
[D]

Question88.
Thevalueof

is:

[A]
[B]
[C]
[D]

Question89.
Thevalueof

is:

[A]

[B]
[C]
[D]

2
1

Question90.
Thevalueof

isequalto:

[A]
[B]
[C]
[D]

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