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INTRODUCTION
Air quality study in indoor spaces (IAQ) is a fundamental and applied research topic of ever-growing
interest, since the population of developed countries
spends an increasing proportion of lifetime within
confined spaces (homes, work, commercial and leisure
places, vehicles) and is thus exposed to a largely artificial environment, the air supply to which may be
mediated by mechanical devices, such as the ventilation system (HVAC) of buildings. The final quality of
air inside buildings is determined by the effect of three
main occurring phenomena: (i) pollution of the out-
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EXPERIMENTAL
Study design
Data were acquired within an extensive IAQ monitoring
campaign performed on Grattacielo Pirelli, a large office
building block, which is located in an open square with
a high density of urban traffic, within the city center of
Milan. The main building of the block is a tall (30-storey,
130 m) tower with fully mechanical ventilation, surrounded
by a partially independent three-storey building. The HVAC
air feed grid is located near ground, on a highly trafficked
square. Some preliminary study results have been disclosed
RESULTS
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Fig. 1. Time profile of CO concentration recorded between 12 January and 21 February 1995 in the
proximity of Grattacielo Pirelli. Dotted lines represent interruptions in data acquisition.
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Fig. 2. Time profile of CO concentration recorded over several days indoors at the 6th storey (#22 m from
ground) of Grattacielo Pirelli and outdoors. Solid trace: indoors, between 17 pm and 6 am, outside the
working hours of the HVAC system; Solid dashed trace: indoors, between 6 am and 17 pm, during the
working hours of the HVAC system; narrow trace: outdoors, at the same height of the monitored building
storey.
the mean environmental concentration simultaneously measured at the height of the same storeys, at
above-ground levels ranging from approx. 10100 m;
however, the relationship of (indooroutdoor) concentration differences with storey height above
ground suggested that the environmental outdoor CO
concentrationand possibly those of other airborne
pollutantsmight decrease with increasing height on
the ground-to-100m height scale in the proximity of
the tower building.
(c) Height gradient of airborne pollutants between
ground level and about 100 m height
The above suggested phenomenon appeared worthwhile a more detailed investigation, due to the applicative consequences (which will be highlighted in
greater detail in the following section) exerted on
indoor air quality policies by possible stratification of
pollutants in the urban air. Therefore, synchronized
height-resolved measurements of the concentration of
some pollutants were undertaken, as will be referred
of in the following. The pollutants selected for
measurement (carbon monoxide, airborne aromatic
compounds and PM airborne particulate matter)
10
are representative of the main classes of toxicologically relevant constituents of lower urban troposphere, i.e. non-condensable gases, airborne vapours
and inhalable solid matter. The vertical air temperature profile in the close proximity of the building was
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Fig. 3. Mean daily vertical air temperature profile in the close proximity of the tower building. Upper box:
temperature measured as a reference at ground level. Lower box: difference between the temperature
measured at higher levels (#22, #55 and #104 m) and the ground-level reference.
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F. M. RUBINO et al.
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Table 1. Concentration (kg m~3) of airborne aromatic hydrocarbons in the lower urban troposphere of Milan, measured by
point sampling and cryofocusing-gas chromatography-mass spectrometry
Sampling height
15105 m
1545 m
75105 m
Compound name
Mean
DS
Minmax
Mean
DS
Minmax
Mean
DS
Minmax
Benzene
Toluene
Ethylbenzene
Xylene (m-#p-)
Xylene (o-)
Sum of BTEX
28
28
28
28
28
28
25
45
8
31
11
119
8
13
3
13
6
40
1246
2377
417
1562
424
57225
16
16
16
16
16
16
28
50
9
36
13
136
8
14
3
12
6
42
1346
2377
517
1762
424
67225
12
12
12
12
12
12
21
38
6
23
8
97
7
8
3
12
4
31
1229
2445
410
1539
413
57132
Note: Concentration measured at the uppermost height significantly different vs. that at the lowermost: P(0.001 (t-test
for paired data).
Fig. 6. Total aromatic hydrocarbons (BTEX) measured simultaneously between 1545 m (lower group)
and between 75105 m (upper group) in the proximity of a tall tower building (individual compounds
measured by GC-MS; values in kg m~3).
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F. M. RUBINO et al.
Fig. 7. Mean decrease of carbon monoxide (CO) concentration with increasing height between ground and 100 m. The
solid lines represent the best-fit curves (r2*0.94) across
experimental data; the pair of narrow lines are the excursion
limits of the concentration.
Fig. 8. Time profile of the concentration of total airborne aromatic compound (TAAC) measured by
PAS-IR in the outdoor urban air in proximity of the air feed grids of the HVAC system of a refurbished
office building. The narrow line represents sampling at the former grid, at 4 m above ground solid line
represents that at the currently employed grid, at 11 m above street level. For the meaning of the asterisks
see text.
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bon component of urban atmosphere (in Milan, concentrations of 12 mg m~3 have been measured)
anddue to its low molecular massit is expected to
be evenly distributed in the atmosphere. Despite the
sensitivity of its measurement by PAS-IR is not high
(about 300 ppbv), while that of the airborne trace
organics (present at ppbv concentrations) is higher by
two orders of magnitude (a few ppbv); therefore,
the analytical signal due to its high concentration may
overwhelm the contribution of airborne trace organics, thus possibly hampering the observation of
the (expected) concentration decrease of higher organics with increasing height. A different explanation
may be proposed to account for lack of an observable
height gradient of airborne carbonyl compounds: it is
in fact known that comparatively little emission is
generated from automotive exausts at ground level,
while production mainly occurs by secondary photooxidation of hydrocarbon precursors in the bulk urban atmosphere (Seinfeld, 1986; Atkinson, 1990). Lack
of a concentration difference within the narrow urban
height belt studied is therefore justified, also considered that formaldehyde, the most abundant airborne carbonyl compound is generated from the
evenly distributed methane precursor.
(b) Relevance of vertical pollutant gradient to Italian
urban building regulations
A key assumption of indoor air quality studies in
non-industrial buildings is thatdue to the expected
low level of indoor chemical emission in comparison
to industrial buildingsthe attainable level of indoor
air pollution strongly depends on a constantly
adequate air quality at the supply point to the mechanical ventilation system, and ultimately on environmental air quality in the appropriate surroundings
of the individual building (e.g. Basilico et al., 1996).
Since effective action for the reduction of the overall
level of urban airborne pollution is hardly achievable
outside the framework of a wide-scale urban
planning, local-scale intervention may result costeffective in improving IAQ especially in sensitive
buildings (e.g. hospitals, schools) located in the proximity of highly trafficked roads or near otherwise
polluted areas.
In the particular case reported in this paper, the
main purpose of the work was to determine the optimum height above ground of the HVAC air feed grid
of a specific urban office building, necessary to minimize the influence of local automotive pollution on
indoor air contamination. Measurement of the concentration difference between ground and higher
levels within building height of air pollutants in urban
atmosphere tracing different classes of airborne contaminants contributed to a toxicologically-oriented
rational advice, i.e. to evaluate the improvement of
indoor air quality in terms of a reduced exposure of
building occupants to urban airborne toxicants
brought indoors by the ventilation system. The
maximum decrease of the concentration of airborne
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a suitable tracer of the influence of urban environmental air pollution on the chemical air quality in
indoor spaces.
Since airborne organic vapours of automotive origin are within the toxicologically most relevant products of urban pollution from the point of view of
public health concern (Bostroem et al., 1994; Kagawa,
1994; Vostal, 1994; Hall, 1996), it may be also of
interest to obtain complementary information on the
behaviour of heavier molecular weight air pollutants,
such as volatile organics or airborne particulate: one
purpose would be a more detailed knowledge on the
persistence of the effects of fugitive pollutant emissions on the local scale, e.g. those due to startup of
engines, especially in confined outdoor spaces such as
courtyards. Aromatic compounds are crucial analytical targets to this regard, since at least some of them
are of recognized toxicological significance and, recently, regulatory monitoring of non-conventional
pollutants, such as airborne benzene, has been introduced in Italy as a further parameter to this regard
(Italian Parlament Decree No 285, 30 April 1992;
Italian Law No 146, 12 April 1995). The mixture of
airborne aromatic hydrocarbons (benzene, toluene,
ethylbenzene, xylenes; BTEX) may represent the
heavier component in the overall blend of organic
pollutant vapours in urban atmosphere. However, the
choice of suitable parameters for the measurement of
airborne organics with PAS-IR is a less straightforward task than selection of CO as a general-purpose
urban air quality tracer. The instrumental selectivity
of this analytical technique towards individual compounds or narrow compound classes is far from being
optimal and may suffer from (sometimes severe) interference from the more abundant organic constituents
of urban atmosphere. This limitation therefore constrains the interpretation of organics PAS-IR data to
a qualitative comparison level between different situations (e.g. indoor/outdoor; HVAC-on/HVAC-off).
However, due to the dynamic nature (both in time and
in space) of air pollution phenomena, this instrumental limitation may be, at least in part, traded-off by the
continuous monitoring and multipoint sampling features of the equipment, which would be outside the
possibility of the traditional investigation techniques
for airborne organics, based on enrichment sampling
and high-specificity off-line analysis (e.g. by chromatographic techniques). Therefore, measurement of
TAOC by PAS-IR may be considered as a continuous
analogue of the more commonly employed NMHC or
VOC chemical air quality parameters, which are most
often obtained as a point or time-averaged measurements. Another analytical advantage of TAOC
measurement in IAQ studies is its far higher sensitivity to higher molecular weight volatile organics
(which are released in closed environments either as
constituents of bio-effluents or from several indoor
pollution sources) than to the lower-mass ones (which
are the most abundant components of the airborne
organics mixture).
REFERENCES
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Weschler, C. J., Shields, H. C. and Naik, D. V. (1993) Interplay among ozone, nitric oxide and nitrogen dioxide in an
indoor environment: results from synchronized indooroutdoor measurements. Proceedings of Indoor Air
+93 3, 135140.
Wolkoff, P. (1993) Comparison of Volatile Organic Compounds from processed paper and toner from office copiers and printers; methods, emission rates and modeled
concentrations. Indoor Air 3, 113123.