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Max Marks:360

KEY SHEET
PHYSICS

1)4

2)2

3)2

4)1

5)2

6)3

7)3

15)3

16)3

17)1

18)4

19)1

20)4

21)2

8)3

22)2
29)2

9)3

23)4
30)3

10)3

11)2

24)2

12)3

25)4

13)3

26)1

27)1

14)3
28)2

MATHEMATICS
31)2

32) 1

33) 2

34)1

35)1

36)4

37) 4

45)1

46)2

47)2

48)3

49)1

50)4

51)4

59)4

53)1

60)3

40)3

41)2

54)1

42)1

55) 4

56)2

43)3

52)4

39)1

57)1

44)1
58)1

.i

38) 1

62)4

63)2

64)4

75)2

76)4

77)2

78)4

90)2

84)4

85)1

66)4

67)1

79)3

80)1

81)2

72)4

ys

71)3

ud

89)3

83)1

70)3

.s
t

82)1

69)1

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w

68)4

65)3

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61)4

ps

CHEMISTRY

86)4

73) 3
87)4

74)3
88) 2

HINTS &SOLUTIONS
PHYSICS
1

1
2I
I 0 E02C or E0
2
0C

2 4
8.8 1012 3 108
55.5NC 1
Conceptual
from input signals , we have
A

0
1
0
1
0

0
0
0
1
0

OUTPUT nand
GATE
1
1
1
0
1

.i

2
3

ps

The output signal is shown at (b)

ww
w

5
t

6
and drift 1 t 1.5km
4

v2
R

50 cos 370

v2
40 ; v 20 m / s
10
conceptual

Y1
1
1
0
1

ys
ud

Y
1
1
1
0

.s
t

B
0
1
0
1

te

4
A
0
0
1
1

E0

Y2
1
0
1
1

Y
0
1
1
0

10
11
12

di
di
i 20 5t ve
dt
dt
di
30 L 30 at t 2sec; i 1amp
dt
Basic concept of phasor
This error occur in all the instruments which utilizes screw or nut-bolt system
L.C of vernier =M.S.D V.S.D
5 4.9104 m 0.01mm
30 l

ys

te

ps

.i

L.C. of screw gauge =0.01mm

ww
w

.s
t

ud

13

14

15

16

Let slope of line AC is m1 & that of line DB is m2 , then


m
m
nRT1 ln 2 2nRT2 ln 2
m1
m1
T1
2
T2
The temperature of these objects being identical the cooling rate will depend upon surface area. The
circular pate has the largest area and hence will cool faster than cube and sphere, Sphere having less
surface area than a cube will cool at the lower rate
4 S 4 0.05
R 2cm; P

10 Pa
R 2 102

r
3
tan 37 0
8
4
r 6m
F P0 h g r 2

105 10 8000 10 36

18

n
.i

17

1.8 36 105 2 10 7
since it is a conductor
V0 = potential at surface=0
q
Q

0
4 0 a 4 0 2a
Q
q
2
VA Vat surface VB VC VO

ud

The potential at centre of sphere in which q charge is uniformly distributed throughout the volume is
1 3q
VC
4 0 2 R
By symmetry the potential at centre due to half sphere will be half of the complete sphere
1 3q / 2
VC
4 0 2 R

20

1 3Q
4 0 2 R

2 Q

ww
w

.s
t

19

ys

te

ps

Charge is on the outer surface hence Vinside remains constant

v v
v
Ar 1 2 A; v2 1
2
v1 v2
1
energy reflected energy incident
9

21

36m / s
1.2m
30
0.3m

22

Conservation of angular momentum


mR 2 ml 2
mR 2
Li L f 0
'

2
2
3

30 R 2
3R 2 2l 2
E a(1 cos f1t ) cos 2 f 2t a cos 2 f 2t a cos 2 f1t cos 2 f 2t
1
1
E a cos 2 f 2t a cos 2 f1 f 2 t a cos 2 f1 f 2 t
2
2
This is a complex vibration consists of harmonic vibrations of frequencies f 2 , f1 f 2 and f1 f 2
'

23

The highest is f1 f 2 .So hv Tmax

Tmax h f1 f 2

24

6.6 1034
3.6 1015 1.2 1015 2.35
19
1.6 10
17.45ev
Apply conservation of momentum & energy

25

Let total sum of number of isotopes at the formation of the planet was N 0 and currently is N

.i

te
ys
ud

ln 2 1 1
t 2 ln 2
109 2 4
t 8 109 years

ps

N t
N X 0 e 1 0.2 N .(i)
2
N
N y 0 e 2t 0.8 N ..(ii)
2
Dividing equation (ii) by (i)
t
e 1 2 4
1 2 t ln 4

ww
w

26

.s
t

At P, x,

D
For 2 maxim,
24d 2
x 2
2
D

I I I
B 0 i 0 j 0 k
2R 2R 2R

I
B 0 3
2R
nd

27

8d 3d

28

Potential difference across capacitor in steady state


V 6 V 6V
(-ve sign signifies that left hand plate is of negative polarity )
Charge CV 1 6 6 C
In steady state current through capacitor is zero. For zero deflection VA VB
q
So, IR1
C1
q
R C
And IR2
1 2
C2
R2 C1

x4
0
4
Since there is no loss energy , so
x4
1
x 2 E1 mv 2 3
4
2
4
2
x 4 x 12 0
4 16 48
x2
2
4 8

6, 2
2
x 2
U 2 x x 3 dx x 2

.s
t

ud

ys

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ps

ww
w

30

.i

29

In steady state the capacitor is fully charges and is treated as open circuit, so no current flows
through branch containing capacitor in steady state, So, the circuit can be redrawn as

MATHEMATICS
31

As z,iz 1 are collinear

z 1

z 1

0 iz iz 1 i z z i
1 1 1
1 1 1

[taking I common from R2 ]

z 1 z1

z i
0

z i i 0
0
1

[Using C1 C1 C3 and C2 C3 ]


z 1 z i z i z 1 0

z z z iz i z z i z z i 0

.i

2 z z 1 i z 1 i z 0
1 i
1 i
z
z0
2
2
1 i
1
z

2
21
Thus , z lies on a circle

ys

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ps

z z

32

1
z H 2 zS
3

1
1
z1 z2 z3 zH 2 0
3
3
z H z1 z2 z3
Let common root be , then
3 2 p 1 0 and 2 2 q 1 0
Multiply the second expression by 3/2 and subtract from the first to obtain
3
1
1

p q
2
2
2 p 3q

33

.s
t

zG

1
z1 z2 z3 . If zH denotes the orthocentres of ABC , then
3

ww
w

centroid of ABCis zG

ud

As z1 z2 z3 , circum centre of ABC is zs 0 .Also, centriod of ABC is zs 0 . Also

Thus, 3 p 2 p 3q 2 p 3q 0
2

34

an 2 an 2an 1

/2

/2

2 cos 2n 4 x cos 2nx cos 2n 2 x


dx
1 cos 2 x

2 cos 2n 2 x dx 0

C4 27

35

30

36

conceptual

37

We have
0 1 0 0
5 x 0

AB 0 1
0 0 1 0
0 10 x 2 5 x 0 0 1
x 1/ 5
a a 1

38

b 1 b 0
1 c c

39

Two tallest boy can be different groups in

40

, 2

2 n 1

te

t3
a
4t 2 13t |0x x sin
3
x
2
x 12 x 39 3sin a / x
a
x 2 12 x 39 3sin
x
a
2
x 6 3 sin 1
x

a
sin 1, x 6
6
From sin x sin 2 x 1, we get sin x cos 2 x . Now, the given expression is equal to

ud

.s
t

ww
w

42

cos 6 x cos 6 x 3cos 4 x 3cos 2 x 1 1

cos 6 x cos 2 x 1 1
3

sin 3 x sin x 1 1
3

sin 2 x sin x 1 1 1 0
3

43

Cn 1 ways

ps

ys

41

.i

Divide by a 1 b 1 c 1

Applying C2 C2 C1 and C3 C3 C1
And expand to obtain
a b 1 c 1 b a 1 c 1 a 1 b 1 0

We have S1 x1 sin 2

S2 x1 x2 cos 2

S3 x1 x2 x3 cos

S 4 x1 x2 x3 x4 sin
4

So that

tan
i 1

tan 1

xi tan 1

sin 2 cos
1 cos 2 sin

S1 S3
1 S2 S4

tan 1

44

cos 2 sin 1
sin 2sin 1

tan 1 cot tan 1 tan / 2


/2
y 33 m x 87
1 87 m 33
A
33 87 m
2
m

2
dA
d A
0
0
dm
dm 2

45

Perpendicular distance from centre to the line

.i

Common tangent nearer P is x=1


directrix of ellipse is x=1
e=1/2
1
s ,1
2
Perpendicular bisector of the base must meet the parabola at the vertex of the triangle.
Let P( a,b,c) be the foot of the perpendicular from the origin to the plane, then direction rations of
OP are
a 0, b 0, c 0 i.e, a,b,c
So the equation of the plane passing through P(a,b,c) the direction ratios of the normal to which are
a,b,c is
a x a b y b c z c 0

ys

ax by cz a 2 b 2 c 2

50
51

Since f ' x 2 cos x 0 for all x R, so f is one-to-one. Moreover,

ww
w

49

.s
t

ud

47
48

te

ps

46

1
2 or 2 1 or 2 2
2
2
4

common difference

1
2

f x as x and f x as x , hence the range of f is R. Therefore, f is onto as


well
Conceptual
f x h f x
f '9 x lim
h 0
h
f x f h f x
eh g h 0
lim
lim

h 0
h 0
h
h 0
lim e h g ' h e h g h
h 0

g ' 0 g 0 4
Hence f x 4 x c but f 10 g 10 0
So f x 4 x
52

Conceptual

53

f o f x

f x

f x 1 f x

Similarly f o f o f x

n2

g x dx

n 1/ n

1 2 x

1 3x

n 1/ n

x n 1

n 1/ n

and likewise f o f ..... o f n times x

dx.Put 1 nx n

1/ n 0

1 nx

n 1/ n

We get the above integral as


1 t n 1
1
dt
t n 1 K

n
t
n n 1
1
1
n 1 n

1 nx K
n n 1

54

h x h I
Where I

sin 4 t dt

Put t , so that
x

.i

I sin d
4

sin d h x
x

ps

te
ys

d
f 2 x g 2 x 2 f x f ' x g x g ' x 2 f x g x f x 0
dx
Hence f 2 x g 2 x is constant . Thus

ud

56

.s
t

55

h x h h x
conceptual

f 2 16 g 2 16 f 2 2 g 2 2 f 2 2 f ' 2 16 16 32
Let y 1 x

1/ x

ww
w

57

1
1
x 2 x3 x 4
log 1 x x ...
x
x
2 3 4

2
3
x x
x
1 ..
2 3 4

log y

ye

58

x x2
1
2 3

ee

x x2

..a ..
2 3

2
x x2

1 x x2

e 1 ..... ..... ....


2 3

2! 2 3

1
1 1

2 1
y e ex ex 0 x 0 x .....
2
2 2

(0,(x) in terms containing x)


1
y 2 ex
2 e 1 1 11 e
lim
2
3 8 24
x 0
x
Conceptual

1 nx

n 1/ n

.s
t

ud

ys

te

ps

.i

Conceptual
Vertex is (-2,1), length of the latus return =4a where a=1/2 latus rectum is
parallel to the tangent x+2=0 at the vertex, at a distance from it. So its
equation is x=-3/2,1+1) and (-3/2, 1-1) i.e (-3/2,2) and (-3/2,0). The point not
lying on 2 x y 3 0 is 3 / 2, 2

ww
w

59
60

CHEMISTRY
61

T f KCl
T f X

ix

4 i KCl
2

1
i x
i x

2
0.5
4

1
for association of 3 molecules i x 1 1
n
1
1 1 0.5
3
0.75

The boyles temperature of both H 2 and He is very low.

63
64
65
66
67

69
70
71
72

Along the body diagonal two B- ions and one A+ are removed
At high concentration of sulphide ions the cations of both II and IV groups are precipitated.
Follow CIP rules.
2p r = n l 2p rn = n 2 l 1
Depends on stability of carbocations
T
(i) Molecules move faster for which
greater. obviously H 2 molecule move faster.
M
Cannizzarrows reaction
Rate of reaction depends on leaving ability of the group
Nucleophilic substitution
In the partial hydrolisys of Xe F6 different products formed or Xe O F4 and Xe O2 F2

73
74

Tollens reagent oxidizes aldehyde group only


B = PH 3 A = NaH 2 PO2

75

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.s
t

68

62

Conductivity BaSO4 2 106 1 106 1 106


0
0
0
Molar conductivities = 60 2 20 100ohm 1cm 2 mol 1
BaSO
Ba
2
SO 2
4

ww
w

In the case of sparingly soluble salt

78
79
80
81

82

1000 K 1000 106

100
C
C

103
105 moles / litre
100
C1 epimers are called anomers
a) basic strength in vapour state depends on +I effect
c) +R group increase basic strength at para and decrease the basic strength at meta due to I.
d) Lesser the surface volume more the basic strength, hence NH3 is more basic. ROH > H2O due to
+I effect of R group
Conceptual
Conceptual
B = NH 3 C = N 2 D = Mg3 N 2
Conceptual
C

76
77

0
BaSO
V
4

83
84
85
86
87
88

Iodoform reaction
Teflon, polystyrene and PVC are formed by addition polymerization
Conceptual
Ratio of concentration of reactants and products is same in all three.
Kt = C0 - Ct
Follow the structure of dichromate ion.

89
CH 2

NaNO2 / HCl

.........
0.50 C

N2

NN
H

ps

.i

H2 N

.s
t

ud

Sod. Benzoate is metabolized to hippuric acid C6 H 5 CO NH CH 2COOH .

ww
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90

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or