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Max Marks:360

JEE-MAIN

IMPORTANT INSTRUCTIONS:

1) 35.5NC 1
2.

.i

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The amplitude of electric field in a parallel light beam of intensity 4 W / m 2 is:


2) 45.5NC 1

3) 49.5NC 1

4) 55.05NC 1

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1.

PHYSICS

There are three parts in the question paper A, B, C consisting of Physics, Maths and
chemistry having 30 questions in each part of equal weightage. Each question is allotted 4
(four) marks for each correct response.
Candidates will be awarded marks as stated above in instruction for correct response of each
question. 1/4 (one fourth) marks will be deducted for indicating incorrect response of each
question. No deduction from the total score will be made if no response is indicated for an
item in the answer sheet.
There is only one correct response for each question. Filling up more than one response in
each question will be treated as wrong response and marks for wrong response will be
deducted accordingly as per instruction

Avalanche break down in a semiconductor diode occurs when:

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1) forward current exceeds a certain value

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2) reverse biasing exceeds a certain value

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3) forward biasing exceeds a certain value

3.

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4) the potential barrier reduce to zero

The real time variation of input signals A and B are as shown ahead. If the inputs are
fed into NAND gate, then select the output signal from the following:
5V

5V

1)

2)

5V

5V
0

3)

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4) Y

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t

Truth table for system of four NAND gates as shown in figure is :

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4.

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ps

5.

A man can swim in still water at a speed of 5 km/hr. He wants to cross a river 6 km
wide, flowing at the rate of 4 km/hr. If he heads in a direction making an angle of 127 0
with stream direction, then he will reach a point on the other bank :

1) upstream at a distance of 1.5 km

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2)downstream at a distance of 1.5 km

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3)directly on the other side of the bank

In figure particle is shown travelling counterclockwise in circle of radius 10 m.The


The acceleration vector is indicated at a specific time. Find the value of v at this
time.

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6.

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t

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4) downstream at a distance of 2 km

1)10 m/s
7.

2) 15 m/s

3)20 m/s

4)7 m/s

Path followed by two rays through a thin lens in air are shown.(assume value of of
lens for both rays) optical path followed for two rays from A to B is:

2)greater in case 1 than 2

3) equal in both the cases

4)value of is needed to compare

8.

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1) greater in case 2 than 1

AB is boundary separating two media of different refractive indices . A ray is incident


on the boundary is partially reflected and partially transmitted. Choose the correct
statement.

1) 3 is incident ray and 1 is refracted ray


2) 2 is incident ray and 1 is partially reflected ray
3) 1 is incident ray and 3 is refracted ray
4) 3 is incident ray and 2 is partially reflected ray
9.

In the circuit shown in figure, A is a sliding contact which can move over a smooth
rod PQ. Resistance per unit length of the rod PQ is 1 ohm per meter .Initially slider is

left to the point P and circuit is in the steady state. At t=o slider starts moving with

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constant velocity v=5m/s towards right. Current in the circuit at t= 2sec is

10.

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3) more than 1 amp

2) less than 0.5 amp

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t

1) 1 amp

4) in between 0.5 to 1.0 amp

Select the correct circuit diagram for a phasor diagram as shown in the adjacent fig.

2)

3)

4)

category known as back lash error

(iv) Vernier callipers


1) (i) and (ii) only
3)(i) only

12.

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t

(ii) Micrometer

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(i) Screw gauge

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In which of the following instrument used in the lab there exists an error of random

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11.

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1)

(iii) Searles apparatus

2)(i) ,(ii) and (iii) only


4) All four

On the basis of details given about two measuring instruments, select the correct
statement .

(i) vernier callipers having main scale division=0.05 cm and vernier scale
division =

2.45
cm
50

(ii)screw gauge having pitch 0.5 mm and its circular scale has 50 divisions
1)Both the instrument have same least count
2)Least count of screw gauge is lesser than that of vernier callipers.
3)Both the instrument have same least count but screw gauge can be more precise.
4) Both the instrument have different least count and screw gauge is more precise.
On a T-P diagram ,two moles of ideal gas perform process AB and CD. If the work

13.

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done by the gas in the process AB is two times the work done in the process CD then

1) 3
14.

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what is the value of T1 / T2

2)5/2

3)2

4)4

A sphere , a cube and a thin circular plate all made of same material and having the
same mass are initially heated to a temperature of 2000 C . Which of these objects will

cool fastest and which will cool slowest when left in air at room temperature,
respectively ?

15.

1)Sphere, cube

2)Cube, thin circular plate

3) Thin circular plate,sphere

4) All will cool at the same rate

A soap bubble is being blown on a tube of radius 1cm. The surface tension of the soap
solution is 0.05 N/m and the bubble makes an angle of 600 with the tube as shown.
The excess of pressure in the tube is :
600

3)10Pa

4) 20Pa

Shown in figure , a conical container of half-apex angle 370 filled with certain

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16

2)1 Pa

1)5Pa

600

ps

quantities of kerosene and water. The force exerted by the water on the kerosene is

17

2) 4 107 N

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1) 3 107 N

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t

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approximately. (Take atmospheric pressure 105 Pa )

3) 2 107 N

4) 5 107 N

A point charge is placed at a distance 2a from the centre of a thin conducting


uncharged spherical shell A of radius a as shown in the figure. Then the charge on
the shell will be

1)

2)Q

3)-Q

4)zero

A hollow conducting sphere of inner radius R and outer radius 2R is given a charge Q

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on its outer surface as shown in the figure, then the

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1)Potential at A and B is different

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3) potential at O and C is different

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2) Potential at O and B is different

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4) potential at A,B,C and O is same

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18

Q
2

19

Charge Q coulombs is uniformly distributed through out the volume of a solid


hemisphere of radius R meters. Then the potential at centre O of the base of
hemisphere in volts is

1)

2)

1 3Q
4 0 4 R

3)

1 Q
4 0 4 R

4)

1 Q
4 0 8 R

String 1 is connected with string 2. The mass per unit length in string 1 is 1 and the

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20

1 3Q
4 0 2 R

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mass per unit length in string 2 is 41 . The tension in the strings is T.A travelling wave

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is coming from the left. What fraction of the energy in the incident wave goes into

1) 1/9

3)2/3

4)8/9

A wave with a frequency of 30 Hz travels along a string at speed of 36 meters per

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2) 4/9

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t

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string 2?

second and reflects off a free end. How far is the first node from the end of the string
1) 0.2 meters

2) 0.3 meters

3)0.4 meter

4) 0.6 meter

22

A thin rod of mass M and length l stands along z-axis. Its lower end is hinged at the
centre of a disc of same mass M and radius R. The disc is on XY plane with its centre
at the origin. The whole arrangement is rotating freely about z-axis with an angular
velocity 0 .If the rod falls on disc and rotates with the disc. Find the angular speed of
the arrangement
1)

23

0 R 2
l 2 R2

2)

30 R 2
2l 2 3R 2

3)

60 R 2
l 2 6R2

4)

60 R
l 6R

The maximum kinetic energy of photoelectron liberated from the surface of lithium

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(work function =2.35eV) by electromagnetic radiation whose electric component


is a constant ,

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varies with time as E a 1 cos 2 f1t cos 2 f 2t where a

hydrogen atom makes

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A moving

3) 12.5eV

4) 17.45eV

a head- on collision with another stationary

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t

hydrogen atom. Before collision both atoms are in their ground states, and after
collision they move together. The minimum value of the kinetic energy of the moving

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2) 7.55eV

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1) 2.6ev

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f1 3.6 1015 Hz and f 2 1.2 1015 Hz is [ Take : h 6.6 10 34 J s ]

hydrogen atom (in eV), such that one of the atom reaches the 1st excited state will be
1) 10.2

2)20.4

3) 5.1

4) 40.8

25

Half lives of two isotopes X and Y of a material are known to be 2 109 years and
4 109 years respectively. If a planet

forms with equal number of these isotopes ,

estimate the current age of the planet, given that currently the material has 20% of X
and 80% of Y by number
1) 2 109 years
26

2) 4 109 years

3) 6 109 years

4) 8 109

years

Consider the optical system shown in the figure that follows. The point source of light
S is having wavelength equal to . The light is reaching screen only after reflection.

27

6d 2
D

3)

3d 2
D

4)

24d 2
D

ps

2)

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2
1) 12d

For point P to be 2nd maxima, the value of would be (D>>d and d )

Three rings, each having equal radius R, are placed mutually perpendicular to each

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other and each having its centre at the origin of coordinate system. If current I is

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flowing through each ring, then the magnitude of the magnetic filed at the common

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t

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centre is :

1) 3
28

0 I
2R

2)zero

3)

2RI

2 1

4)

3 2

2RI
0

For the circuit shown in the figure, determine the charge on capacitor in steady state

1) 4 C
29

2) 6 C

3) 1 C

4)Zero

In the given circuit galvanometer shows zero deflection in steady state. Then the

2)

R1 C2

R2 C1

3) R1C1 R22C2

4) R1C12 R2 C22

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A block of a mass m kg moving with kinetic energy 3J on a smooth horizontal surface

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hits the free end of a spring, whose other end is attached to a rigid wall as shown in

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the figure. If restoring force applied by the spring is given by f x 2 x x3 N

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t

Then the maximum compression in the spring approximately

1)2.20m

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30

R1 C1

R2 C2

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1)

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condition for zero deflection in steady state is :

2)1.51m

3)1.41m

MATHEMATICS

4) 1.67m

31

32

If the points z, -iz and 1 are collinear then z lies on


1)a straight line

2) a circle

3) an ellipse

4) a pair of straight lines

If A z1 , B z2 and C z3 are the vertices of a triangle such that z1 z2 z3 0 , then


orthocentre of ABC is
1) z1 z2 z3

33

2) z1 z2 z3

4) z1 z2 z3

3)0

Suppose that the quadratic equations


3 x 2 px 1 0 and 2 x 2 qx 1 0 have a common root then the value of 5 pq 2 p 2 3q 2

equals
1 cos 2nx
dx, then a1 , a2 , a3 ,.... an n N are in
1 cos 2 x

1)A.P

2)G.P

3)H.P

4) All of these

The number of ways in which we can select four numbers from 1 to 30 so as to

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4)2

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/2

If an 0

3) -1

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34

2) 1

1)0

1) 27378

2)27405

3)27397

The greatest value of the term independent of x, as varies over R, in the expansion
sin
of x cos
is
20

1 ) C10

20

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t

20

37

4) 5329

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36

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exclude every selection of four consecutive numbers is

2) C15

The value of x for which the matrix

10

20

3) C19

4)

20

1
C10
2

2 0 7
A 0 1 0 is inverse of
1 2 1
x 14 x 7 x
B 0 1
0
x 4 x 2 x

is

1)
38

2)1/3

3)1/4

4)1/5

If the system of equations


ax ay z 0
bx y bz 0
x cy cz 0

(where a,b,c 1 ) has a non-trivial solution, then value of

3)-2

4)0

2n boys are randomly divided into two subgroups containing n boys each. The

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39

2)-1

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1)2

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1
1
1
is

1 a 1 b 1 c

2)

The equation
1) 0

42

3)

2n 1
4n 2

4)

1
2n 1

.s
t

If / 2 and , then tan equals


1) 2 tan tan

41

n 1
2n 1

t
x

2) tan tan
2

3) tan 2 tan

4) 2 tan tan

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40

n
2n 1

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1)

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probability that the two tallest boys are in different groups is

a
a
8t 13dt x sin has a solution if sin is equal to
x
6

2) 1

3)

4) 2/3

If sin x sin 2 x 1 , then the value of cos12 x 3 cos10 x 3cos8 x cos6 x 1 is equal to

1) 0
43

2)1

4)2

If x1 , x2 , x3 , x4 are roots of the equation x 4 x3 sin 2 x 2 cos 2 x cos sin 0 then


4

tan

i 1

xi is equal to

1)
44

3)-1

3)
2

2) 2

4) 2
2

A straight line passing through the point (87,33) cuts the positive direction of the
coordinate axes at the points P and Q. If O is the origin then the minimum area of the
triangle OPQ is
1)5742

3)4972

4)3600

Three concentric circles of which the biggest is x 2 y 2 1 have their radii in A.P with

45

2)5600

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common difference d(>0). If the line y=x+1 cuts all the circles in real distinct points,
2 2
4

1
2

4) d is any real number

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An ellipse has eccentricity and a focus at the point P(1/2,1). One of its directrix is

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t

the common tangent near to the point P, to the circle x 2 y 2 1 and the hyperbola
x 2 y 2 1 , the equation of the ellipse is

1) 3x 2 4 y 2 6 x 8 y 4 0

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46

2 2
4

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3) d 1

2) d

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1) d

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then

3) 4 x 2 3 y 2 8 x 6 y 4 0

2) 3x 2 4 y 2 2 x 8 y 4 0
4) 4 x 2 3 y 2 8 x 2 y 4 0

47

An isosceles triangle is inscribed in the parabola y 2 4ax with its base as the line
joining the vertex and positive end of the latus rectum of the parabola . If at 2 , 2at is
the vertex of the triangle then

48

1) 2t 2 8t 5 0

2) 2t 2 8t 5 0

3) 2t 2 8t 5 0

4) 2t 2 8t 5 0

If the foot of the perpendicular from the origin to a plane is (a,b,c) then the equation of
the plane is
1)

x y z
3
a b c

2) ax by cz 3

3) ax by cz a 2 b 2 c 2

2)one to-one not onto

3)onto but not one-to one

4)neither one-to-one nor onto

If

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1)one to one and onto

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50

Let a function f : R R be defined by f x 2 x sin x for x R . Then f is

f x 1/ 2 x , then the points of discontinuity of the composite function

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4) ax by cz a b c

3)2,3, 4/3

4) 2,3/2, 4/3

.s
t

Let f and g be real functions satisfying

f x e x g x , f x y f x f y , g 0 0, g ' 0 4. g and g '

then
1) f x 0 x R
3) f x x 4 x R

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2)1,2, 4/3

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1) 2,3/4,4/3

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y f f f x are

2) f x x x R
4) f x 4 x x R

are continuous at x = 0

52

The set of all values a for which the function


x
x

f x a 2 3a 2 cos 2 sin 2 a 1 x sin1 does not possess critical points is


4
4

1) 1,
Let f x

1 x

n 1/ n

3) 1,3 3,5

for n 2 and g x

1
1
1
1 nx n n K

n n 1

1
1
1
1 nx n n K

n 1

n
.i

3) h x h

ps

2) h x h

4) h x / h

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The curve y e x y x 0 has a vertical tangent at the point


2) at no point

4) (1, 0)

3)64

4) 5

3) (0, 1)

2) 32

1 x

1
e ex
2
is
2
x

1)

11
e
24

2)

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1/ x

The value of lim


x 0

ud

If f ' x g x and g ' x f x for all x R and f 2 4 f ' 2 then f 2 16 g 2 16 is


1) 16

57

x n2 g x dx equals

1) (1, 1)
56

4)

If h x 0 sin 4 t dt , then h x equals


1) h x h

55

1
1
n 1 n
2)
1 nx K
n 1

.s
t

54

f o f o f ....o f x . Then

ntimes

1
1
n 1 n
1)
1 nx K
n n 1

3)

4) 0,1 1, 4

ys

53

2) 2, 4

11
e
24

3)

e
24

4)

e
2

x 1
x x 1
If f x 2 x
then f 50 f 51 ..... f 99
x 1 x
3 x x 1 x x 1 x 2 x x 1 x 1
1

58

Is equal to
1) 0

2)1275

3)3725

a a 2 1 a3
c

c2

1 c3

1) a b c 0

2) abc 0

3) a b c 1

4) abc 1

2)(-3/2,1)

3) (-3/2,2)

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1) (-2,1)

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2 x 2 , which does not lie on the line 2 x y 3 0 are

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y 1

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The coordinates of the end point of the latus rectum of the parabola

.s
t

60

If b b 2 1 b3 0 and the vectors a (1, a, a 2 ), b (1, b, b 2 ), c (1, c, c 2 ) are non-coplanar then

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4) 5

4)(-3/2,0)

CHEMISTRY
61.

Equimolal solutions of KCl and compound X in water shows depressions in freezing


point in the ratio of 4:1. Assuming KCl to be completely ionized
The compound X in the solution must

62.

1) Trimerises to the extent of 50%

2) Dimerises to the extent of 80%

3) Dimerizes to the extent of 50%

4) Trimerizes to the extent of 75%

Which of the following gases always show positive deviation from ideal behaviour at
all pressures and 273 K
III. H 2

1) I and II only

2) II and III only

3) I and IV only

4) I and III only

IV. CH 4

An ionic compound A+ B- has ZnS(sphalarite) type structure If all the ions along one

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63.

II. CO2

I. He

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body diagonal line in the unit cell are removed. Then the formula of remaining

(3) A8 B27

(4) A2 B3

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In the precipitation of sulphides of second group of basic radicals, H2S is passed into

statement?

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t

the acidified salt solution. If the solution is not acidified, then which is the correct

1) Only the sulphides of second group get precipitated

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64.

(2) A4 B5

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(1) A12 B20

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structure is ?

2) Only the sulphides of fourth group get precipitated


3) Neither of the sulphides of second and fourth groups get precipitated
4) Sulphides of both second and fourth groups can get precipitated.

65.

Consider the following compound :

1) It is cis-2-Chloro-3-methylpent-2-enal
2) It is (E)-2-Chloro-3-methylpent-2-enal
3) It is (Z)- 2- Chloro- 3- methylpent-2- enal

(3) 6.8

Which

of the following dienes is

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(2) 27.2

1)

2)

expected

(4) 3.4
to be the least reactive towards

ud
.s
t

electrophilic addition?

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67.

(1) 13.6

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of an electron in that orbit is (in ev/per atom)

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Circumference of Bohrs orbit in a Hydrogen atom is 13.32A 0 .Calculate kinetic energy

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66.

4) It is trans- 2- Chloro- 3- methylpent-2-enal

3)

4)

68.

Two flasks A and B have equal volumes. Flask A contains hydrogen at 600 K while
flask B has same mass of CH 4 as that of hydrogen at 300 K. Which of the following
statements are correct ?
(I) In flask A the molecules move faster than B
(II) In flask B the molecules move faster than A.
(III) Flask A contains greater number of molecules than B.
(IV) Flask B contains more molecules than A.
1) III and IV

69.

2) I and II

3)II and IV

4) I and III

A mixture of benzaldehyde and formaldehyde are heated with NaOH solution then the
correct statements regarding the above reaction is

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(III) The reaction involves disproportionation

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(II) The products are formic acid and benzyl alcohol

(I)The products are CH 3 OH and C6 H 5 COOH

2) I,III,IV only

3) II only

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1) II ,IV only

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(IV) The order of the reaction depends on concentration of NaOH


4) I,II,III only

1) II III IV I
3) IV III I II

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t

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70. Among the following the correct order of reactivity towards SN 2 reaction is

2) III II I IV
4) I II III IV

71. The hydrolysis product (A) of the reaction is


+

H 3 O18

(A)

72.

During the partial hydrolysis of XeF6 the hybridization of Xe changes from to


2) sp3d3 - sp3

3) sp3 - sp3d

The correct reaction with respect to major product given

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73.

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2)

3)

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t

1)

4)
74.

4) sp3d3 - sp3d2

1) sp3d2 - sp3d

Conc . NaOH /
P4 white
A B
atmosphere of CO2

Which of the following is wrong for the above reaction?


1) The compound A is NaH 2 PO2
2) The compound B can be prepared by the hydrolysis of Ca3 P2
3) The compound A is Na2 H PO2
4) The above reaction involves disproportination
The conductivity of BaSO4 aqueous solution is 2 10 6 Ohm 1cm 1 . The conductivity of
water

used

to

prepare

above

solution

is

1 10 6 ohm 1cm 1

at

250 C .

0
1
2
1
SO 2 is 20 ohm1cm2equivalent 1 then the solubility of BaSO4 in
Ba
2 60 ohm cm mol
4

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pure water at 250 C is

2) 1 105 moles/litre

3) 2 10 5 moles/litre

4) 1 10 10 mole 2 /litre 2

.s
t

ud

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1) 5 10 6 moles/litre

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75.

76

II

III

IV

The correct relationship between above structures.


1) I and II are anomers; III and IV are epimers

4) I and III are anomers; I and II are epimers

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Which of the following basic strength order given is incorrect :

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1) (CH3)3N > (CH3)2NH > CH3NH2 > NH3 in vapour state.


NH 2
>

3)

OMe

NH 2
>

CH 3

.s
t

NH 2

4) NH3 > C2 H5OH > H 2O

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2) (CH3)2NH > (CH3)3N > CH3NH2 > NH3 in water.

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77.

ps

3) I and II are epimers; III and IV are anomers

2) I and III are epimers; II and IV are anomers

OMe

78. Which of the following never undergo dispraportionation


I. F2

79.

II. HNO2

III. H 2 S

IV . SO2

1) III only

2) II,III,IV only

3) I,II,III only

4) I and III only

If A is the central atom of the molecule containing A and X atoms and E is the number
of lone pairs around it then VSEPR notation AX3E1 will be for the molecules:
1) PCl5 , ICl4

IClF , ICl4

3) NF3 ,ClO3

4) ClF3 ,ClO3

Calcium amide Ca(NH 2 )2 on hydrolysis gives gas(B) which on oxidation by bleaching

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powder gives gas(C). Gas (C) on reaction with magnesium gives compound (D) which

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on hydrolysis gives again gas(B).Identify (B), (C) and (D) respectively


2) N 2 , NH3 , Mg ( NH 2 ) 2

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1) NH3 , N 2 , Mg 3 N 2

4) NH3 , NO2 ,Mg (NO2 )2

.s
t

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3) N 2 , N 2 O5 ,Mg(NH 2 )2

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80.

2)

81.

Column I

Column II

(A) Ortho-silicate

(P)

Formed by sharing two oxygen atoms by


each tetrahedral unit

(B) Pyro-silicate

(Q) Three oxygen atoms of each tetrahedra are


shared with adjacent SiO 44 tetrahedral unit
(R) Contains single descrete unit of SiO 44

(C) Single chain Silicate

tetrahedran
(D) Two dimensional sheet

(S)

silicate

Contain two units of SiO 44 joined along a


corner containing oxygen atom.

1)

2)

3)

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AB(S )

.s
t

AB dissolves as follows :

+
Aaq
+ Baq

for which K sp = 8 10- 12 M 2 and the

standard entropy change of dissolution is 104 Jmol - 1 K - 1 ,then the enthalpy of solution
H 0 at 298K is nearly ( in KJ mol 1 )

1) 94.31

ww
w

82.

ps

te

ys

.i

The correct match is

2)

3) 56

4)

CH2 CH CH3
OH

I2 /NaOH

CHI3

+ X

83.
X would be

3) PVC

4) Dacron

ps

te

The compound formed during tailing of mercury is


2) HgO

3) Hg Cl2

4) HgO.Hg Cl2

ys

1) Hg 2O

For the given three cells, which of the following is correct?


(i) Zn | Zn2 1M Cu 2 1M | Cu ; Ecell E1

ii Zn | Zn2 10M || Cu 2 10M | Cu

.s
t

86

2)Polystyrene

.i

1) Teflon

ud

85

Which of the following is formed by condensation polymerisation?

; Ecell E2

iii Zn | Zn2 0.1M || Cu 2 0.1 M | Cu ; Ecell E3


1) E1 E2 E3

ww
w

84.

2) E3 E2 E1

3) E2 E1 E3

4) E1 E2 E3

87

Which of the following is correct with respect to the following graphs?

1)I only represents zero order reaction


2) II only represents zero order reaction

ps

Incorrect statement regarding Cr2 O7- 2 is

te

1) All chromium oxygen bonds are not identical

ys

2) It has Cr - Cr bond

.s
t

4) It oxidizes I - to I 2

ud

3) One of the oxygen atom undergo sp 3 hybridization

ww
w

88

.i

4) All the three graphs represent zero order reaction

3 ) III only represents Ist order reaction

89
CH2
1. NaNO / HCl /05C

The major product is


2.

H 2N

2)

3)

4)

.i

Sodium benzoate used as preservative for acidic food and soft drinks is metabolized

ps

into..which is excreted with urine.

2) Hippuric acid

3) Salicylic acid

4) CO2 and H 2O

.s
t

ud

ys

te

1) Benzoic acid

ww
w

90

1)