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Max Marks:360

KEY SHEET

MATHEMATICS:-

1)1

2)1

3)2

4)3

5)1

6)2

7)3

8)4

9)2

10)3

11)2

12)1

13)4

14)3

15)3

16)4

17)2

18)1

19)1

20)3

21)4

22)4

23)2

24) 3

25)1

26)2

27) 2

28)1

29)4

30)1

PHYSICS :32)4

33)2

34)3

35)2

36)1

37)1

38)3

39)2

40)4

41)3

42)2

43)2

44)3

45)2

46)4

47)1

48)4

49)1

50)3

51)1

52)3

53)1

54)4

55)1

56)1

57)1

58)1

59)3

60)1

.i

31)3

62)4

63)1

64)3

65)4

66)3

71)3

72)1

73)3

74)3

75)3

76)1

81)3

82)2

83)2

84)4

85)3

86)2

ww
w

.s
t

ud

ys

te

61)3

67)4

68)3

69)1

70)4

77)3

78)2

79)3

80)3

87)2

88)3

89)3

90)1

ps

CHEMISTRY:-

MATHEMATICS
1.

OM1 OM MA OM MB OM MC OM MD

= 4OM MA MC MB MD
= 4OM O O
1
4

= OM OM 1
D

M
A

2.

5 7 0
2

4
v r3
3
dv
dr
4 r 2
dt
dt
50
1
50
dr dr

cm / min
,
2
4 (10 5)
dt dt 4 225 18
To make reflexive (2,2) (3,3)(4,4) symmetric (3,2) (4,3) Transitive (2,4) (4,2)
7 must be added
Point on the line (2,1,-2) lies on the plane 2 5
Normal perpendicular to the given line
3(1) (5)(3) 2( ) 0

6.

7.

8.

te

ys

ud

6, 7
v a
v 8

.s
t

5.

v 3 3 v
3(2)
6
(1 1 2 2 ...... n n) 2
2(12 2 2 ......n 2 ) 2 S
S is the required product
n n 1 2n 1
0
S
6
n n 1 2n 1
S
6
2
f ( x ) lx mx 5 does not have
Distinct real roots f ( x) 0 or 0x R
f (0) 5 0

ww
w

4.

ps

.i

3.

x 2 y 3z

f (5) 0
25l 5m 5 0
5l m 1

-1 is the minimum

9.

10.

5
3
C 2, r
2
2
3
3 3
5
9
m , y x 2
1
4
2 4
2
16
1
A tan 1
tan 1 tan
tan
1 tan
A tan 1

2 tan

A
2
1 cos( / 2 A), 1 sin A
tan
2
1 cos( / 2 A),
1 sin A

(1 tan )
(1 tan )

(1 tan )
1
(1 tan )

.i

tan
L11 , L22 will have with the same sign
L11 0 0 1 0

ps

11.

te

L22 a 2 ab 1 0

ys

b2 4 0
2 b 2 but b 0

ud
.s
t

APT Q Q 2003 P

ww
w

12.

b (0, 2)
PT P I
PT Q PT PAPT APT
PT QQ 2004 P APT Q 2004 P

A2 PT Q 2003 P( so on likethis)
A2005 PT P
A2005

10

13.
14.

q
From truth table, r is not equivalent to q or p and p
2005
1

3x 4
y
3x 4
6x y 1

8 y 1
4 y 1
x

3 y 1

f ( y)

4 y 1

2
3 y 1

2 y 10
3( y 1)

2 x 1

f ( x)dx 3 x 1 3 x 1

1 cos x
2

2
2 x

16.

b2 k 2 h2
x
tan
4 2
Lt
x /2
2x

.i

15.

2
8
x log( x 1) c
3
3
B(0, b)
Focal distance a+e(o)=k
a=k
2ae =2h
ae=h
b 2 a 2 (1 e 2 )

2 /2

2 I 2

/2

19.

k
1
p
2
2
q
6

f (sin 3 x cos 2 x )dx

ys

.s
t

2I

18.

te

ud

I ( x) f (sin 3 x cos 2 x )dx


f sin 3 x cos 2 x dx

ww
w

17.

ps

tan 1 cos x
4 2
2

4
4 x
4 2
2

1
1 1
(1)
16 2 32

1
p
P( E ) p p q p p q p q p
2
1 pq 1 1 4
26
3

4
A,B,C are collinear
AC
B
2
2 y, 2( z x ( x z, 2 y z x), 2 y x z ,

z x 2 y x ,y , z are in A.P

2z 2x 2 y z x

n 1

20.

nc1 a 13 (a a )1 14a 2

If n=14
The above is true
nc3
4
nc2
21.

p=1,
q=2 or 3 or 4 or 5 = 4
P=2
q=3,4,5
=3
P=3
q=4 or 5
=2
P=4
q= 5
=1
m = (4+3+2+1)-1=9
[2/4=1/2]
3
n 2 26

mn 96 3
A
300

900

600

te
ys
ud
.s
t

ww
w

AG
BG
2(4)

BG
1
3/2
3 3
2
8
BG
3 3
3(area of AGB)
1
3 ( BG )( AG )
2
1 8 2
32
3
(4)
23 3 3
3 3

ps

22.

.i

23.

(2,0)
x=1

4 x2 x 3
x 1
Area

3x

4 x 2 dx

2
3 2 x
4 1 x
2

x
4 x sin
2
2 1
2
0 2
2

24.

z 1 z 3 8
Z lies inside or on the ellipse with foci (-3,0)(1,0)
2a=8
a=4
Centre = (-1,0)
Vertices (3,0) (-5,0)
z 4 is the distance from Z to (4,0)
Max = 9 Min = 1
A' (-5,0) S'(-3,0) C(-1,0) S(1,0) A(3,0) P(4,0)

A 10

2
5
3

te

ps

.i

2

3

op x 2 y 2
at
a 2 b 2 2ab cos t
b

at
a 2 b 2 2ab , cos t 1
b

ab
Equation of parabola
2
2
2 x 5

3
2

x y 3
2
4

ww
w

27.

.s
t

ud

26.

4 2
adjA 5 0
1 2
1
A1 adjA
10
4 2
1
B 5 0
10
1 2
5

ys

25.

y 3

2 x 2

1
x 2 t2
2
2
t
2
2
2

t
t

x 2 2 let is some t
2
2

2
x 2t 2
1
y3 2 t
2
t
y 2 3
2

Let

y 1

.i

1
1 y1 2 xy1 y
x y
if x 0, y 1

ps

1(1 y1 ) 2 0 1

ys

te

y1 2 1 1

ud

30.

.s
t

29.

xi
78.4
25
xi 1960
Correct value of xi 1960 96 69 1987
1987
Correct mean
79.48
25
1
x 2 or 2
x
cos is not possible for any value of
log x y 2 xy 0
x 0 log y 0

ww
w

28.

t
is some t .y=2t-3
2

PHYSICS
31.

(3)

Net force acting on the rope = (acceleration) system x (mass) rope =


asystem

Fm
M m

F
M m

1
1
1
1 1 1 1
1 and

f
F f1 f 2 f 3
R1 R2

32.

(4)

33.

(2) The rate at which total mechanical energy dissipates with time is equal to the work done
by the
dissipative force per unit time.
Pdissipative fV f at

Pdissipative mtg cos g sin cos

300m / s, V 600m / s
u 300 1
cos
cos 600
V0 600 2

600

Angle with the vertical = 900 300

te

D

d
2
3
So, decreases by a factor so no. of fringes in the same segment increases by a factor
3
2
2
K
6cm
(1)

3
6
Distance between adjacent nodes 3cm
2 2
(1) Compare the given equation from
(2) Fringe width

37.

ww
w

.s
t

36.

ud

ys

35.

Let the shell hit the plane at P and t be the time taken for the shell to hit the plane.
The horizontal distance traveled by the shell = EP u t Vx .t V0 cos t as Vx V cos

.i

(3)

ps

34.

, x ct x 1
2

b x ct

Ct = 1 for t = 2 sec, so, C =


38.

5g
11b

(2) f open = n 1
f open
f closed

40.

1
cm/sec
2

2
(3) 2mgb mg 3b 2m b 2 m 3b u sin g I system

39.

(4)

2 n 1
2n 1

c
c
, f closed = (2n + 1)
2l
4l

2GM star
R

3 10
8

2 6.67 1011 3 2 1030


R

R 9 km
41.

(3) Since V 2 12 2 g 0.15

u 2 2as

v2 4
v 2ms 1
Further according to equation of continuity
A1u A2v
104 1 A2 2

A2 5 105 m 2
2cvs
c
c

n f beats f beats 2
c vs 2
c vs c vs

43.

(2) v u at , 0 9 2t , t 4.5sec

2 330 2
330 4
2
330 4

n=

.i

(2)

42.

(3)

( Z1 1)
(11 1)

te

44.

1 2
gt
2

ps

velocity will be zero at 4.5 sec. Then use s ut

Here 2n and

dr
nd
dt

dv d
dr
(r)
dt dt
dt

.s
t

Tangential acceleration , a

ud

45. (2) Tangential velocity of the rope, v r

ys

Z1 6

ww
w

a 2n 2 d
2n 2 d
a
T w 1 w 1

g
g

(4) A 100k

E. A 3i 4 j 8k .100k 800 Nm 2 c 1

46.
47.

(1)

For the charges to be in equilibrium, net force on any point charge should be zero
x1

x
-Q

+9q

x1

x1

+q

d
Q1
1
Q
d
d

4
9q
1
q

x d x1 d

d 3d

4
4

48.

(4)

2qV
m
o Iv b
ln
2
a
a
2

E
E2

Power dissipated =
F.v F
R
vR
b

49.

(1) Induced emf = Bvdt

50.

1 2 1 E
1 E2
(3) Energy stored in the inductor = heat produced Li0 L L 2
2
2 R1
2 R1

51.

(1)

52.

(3)

53.

(1)

vA0 0
l1 3

l2 2
VA1
3
3

VA 2 3 2 5
v
v A1 3x 0.6v
5

54.

(4)

Limiting friction between the blocks 4mg 0.5 5 10 25N

dv a n n 0

25 15
2m / s 2
5

ud

Acceleration of upper block

ys

te

ps

.i

v 2
dx
1
dt
dx
dx
d2x
2a
v

2ax b
2
2av3
3
dt 2ax b
dx
dt
dt
dt
2ax b

.s
t

Lower block will also move the same acceleration

ww
w

F 25 10 2
F 45N

55.

(1)

56.

(1)

MV 2
qVB
r
MV
M V 2
2
r
r
qB
qB
2M KE
r2
qB

d T
dT
1
=
KA
dt
C
dx
= 24 0 C / sec

x =A

dT
dx

x = B

(1) CP

P
dT
dt

where
(1)

Total decay constant is

n
.i
ps
te
ys

60.

(3)
Invar steel is used to prepare pendulum clock because its coefficient of linear
expansion is very low.
(1)
Platinum is used to fuse into glass because both have almost the same coefficient of
linear expansion.

ud

59.

1
1
1

1620 405 324


No
N 0 e t t = 449 years
4

.s
t

58.

dT a 4

dt 4T3

ww
w

57.

CHEMISTRY
61.

Meq of salt = Meq of Na 2SO3


50 0.1 n 25 0.1 2

n 1
changein O.N.

63.
64.
65.
66.
67.

Allotropes of an element have the same chemical properties but have different arrangement
of atoms and physical properties.
It undergoes dehydration easily as the product obtained is conjugated, and is more stable.
Polarity in a molecule gives rise to an increase in forces of attraction among molecules and
thus, the boiling
point increases.
Being amphoteric , Al OH 3 is soluble in NaOH solution whereas Fe OH 3 is insoluble.
H2O
H2O
H2
CaC 2
C 2 H 2
CH 3 CHO
CH 3 CH 2 OH
Ni
Hg 2 catalyst

w
w
;molof Q
10
20
4w1
Final mole of Q
20 5
Q N0
For Q
e2 t
QN

Let w g of each be taken, then initial mole of P


Final mole of P

w1
5 10

PN0

62.

M3 e
M 2

te

ps

.i

e1t
PN
w 5 10
For P
e1 20
10 w 2
w 20 5
For Q
e2 20
20 w1 4

For P

By Eqs. (i) and (ii) 4 e 20


2

20 1 2 log e 4

ud

0.693 0.693
20

log e 4
t1/ 2
10
t

FeSO4 7H2 O
FeSO4 7H2 O;

.s
t

or

68.

ys

69.

ww
w

2FeSO4
Fe2 O3 SO2 SO3

C3 H 6O

KOH

aq

C3 H 6Cl2
A

or
KOH ( alc )

C3 H 4
C

Br2
CH 3C CH
CH 3COCH 3
CHBr3 CH 3COONa
NaOH
H2O
H .Hg 2

70.
71.
72.
73.
74.
75.

Since, B and D are different, thus B is CH3CH 2 CHO and so A is CH3CH 2 CHCl2 .
Higher vapour pressure of H 2 O in atomosphere will drive H 2 O vapours to the solute
particles.
HO SO2 OH PCl5
Cl SO2 Cl POCl3 2HCl

must be a tertiary alcohol as it gives alkene on treatment with Cu. Thus, C4 H8O is a ketone.
phenomenon of conversion of freshly precipitated mass into colloidal state by the action of
solute or solvent is called peptization.
The solubility of noble gases increases with increase in molecular weight due to increase in
van der Waals forces. However, these are sparingly soluble.
Follow applications of inductive effect. The negative charge on carboxylate ion is dispersed
more due to IE of F atom.

F
F

The carboxylate ion thus becomes more stable and the acid becomes more reactive.

76.

77.

d N 2 O 5

1 d NO 2 2d O 2

dt
2 dt
dt
k2
k1 N 2 O5 N 2 O5 2k 3 N 2 O5
2

According to Werners theory, only those ions are precipitated which are attached to the
metal atoms with ionic bonds and are present outside the coordination sphere.

78.
OCH 2CH CH 2

.i

ps

CH 2CH CH 2

te

OH

80.
81.

1 105

2
PbS is black and S2 reacts with K 2 Cr2 O7 to give Cr2 SO 4 3 solution which is green.

ww
w

79.

.s
t

2 103 / 2
NO 2

Kc

0.2
N 2O4

ud

ys

CH 2CH CH 2

H 3C

CH 3

CH

O .

AlCl

3
CICH 2CH 2CH3

CH3
CH3 CH OH
OH
H O

CH COCH 3
3

82.

For NaX,

X H 2O
HX

OH
1 h

Kw
Kh
1014

C
Ka C
105 0.1

10 8 10 4
%H 104 100 102 0.01
2

83.

E cell

H p H 2
0.059
RHS
=
log
2
2
p H 2 RHS H
LHS
LHS

Thus, for positive E cell , PH2 LHS PH2 RHS


84.
HO
CHO
(CHOH)3

H
C
(CHOH)3
CH

CH2OH

CH2OH

Conceptual

ps

85.

.i

CHOH

86.
Cl

Replacement of one Hatom

te

CH2

ys

C6 H 5 CHCl C6 H 5

ww
w

.s
t

ud

Cl

87.
88.
89.
90.

CH2

Cl
CH2

Cl

CH2

DNA has deoxyribose sugar; RNA has ribose sugar with three bases common as adenine,
guanine and cytosine, DNA has fourth base thymine; RNA has uracil
This gives rise to higher e nuclear charge in Na and the size of Na becomes smaller due to
more effective pull of valence shells towards nucleus.
In D-(+)-tartaric acid, the (+) is due to positive optical rotation and is derived from D
glyceraldehyde.
Bakelite is a step-growth polymer i.e., the condensation involving the reaction of functional
group e.g., terylene, Bakelite etc.