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DATOS

TA, Metanol=
TB, Agua=
X1=
X2=

64.7
100
0.1
0.9

V1=
V2=
a12=
a21=

1. Proponer una T entre TA y TB
T= 87.1463227108 °C
360.2963227108
∆12=
0.4415381906
∆21=
2.2073981378

40.73
18.07
107.38
469.55

Ptotal, mmHg

2. Calcular ϒi con ecuación de Wilson
Ln ϒ1=
0.5406792729
Lnϒ2= -0.0058020241

R=

715

ϒ1=
ϒ2=

1.7171728951
0.9942147751

3. Calcular Presión de Vapor con ecuación de Antoine
Log(10)PV1=
Log(10)PV2=

PV1= 1737.595690555
PV2= 470.7026315596

3.2399487308
2.6727466263

4. Calcular Ki con ecuación de Raoult modificado
K1=
4.1730800314
K2=
0.6545167986
5. Calcular Yi con ecuación de raoult
Y1=
0.4173080031
Y2=
0.5890651187
6. Calcular si la sumatoria de y es 1
Sumatoria de Y
=

1.0063731219

Función
Objetivo

T (k)
371.45
361.2
354.85
350.4
347.1
344.55
342.45
340.65
339.05
337.55
336.09

MODELO TALLER
T °C
98.3
88.05
81.7
77.25
73.95
71.4
69.3
67.5
65.9
64.4
62.94

MODELO TALLER
120
100
80
T °C

60
40

T vs X
T vs Y

8 1 1.2 .4 0.MODELO TALLER 120 100 80 T °C T vs X 60 T vs Y 40 20 0 0 0.2 0.6 X. Y 0.

7488 0.36367 L.mmhg/K.5 0.72 66.lbmol 83.1 0.37 74.8 0.08205746 L.4 0.mol 62.63 C= 233.7231 0.6 0.8473 0.8718 0.2 0.atm/K.03 63.8262 0.7775 0.mol METANOL A= B= C= MODELO TALLER X1 0 0.77 70.4294 0.mol 8.psi/R.1 0.8 0.5683 0.02 MODELO WILSON x1 0 0.426 t °C 98.76 77.7 0.08097 1582.9223 0.9593 1 AGUA A= 8.07131 B= 1730.6577 0.87 72.8033 0.3818 0.9999 MODELO WILSON 120 100 80 T vs X T vs Y T °C 60 40 T vs X T vs Y .99 65.3144621 J/K.7 Y1 0 0.9581 0.9 1 8.7316 ft3.6755 0.3 0.8859 0.2 0.9 1 y1 0 0.314472 L.14472 L.3 0.8.5 0.7 0.mol 0.4 0.Kpa/K.31 80.27 239.29 86.6 0.87 68.9155 0.5664 0.mol 10.mbar/K.

Y 0.MODELO WILSON 120 100 80 T vs X T vs Y T °C T vs X 60 T vs Y 40 20 0 0 0.4 0.8 1 1.6 X.2 0.2 .

T vs X T vs Y .

2 .T vs X T vs Y 1.

5 65.9 64.785195882 5.7066762938 6.2 354.65 339.4 69.55 342.1 0.07 107. mmHg 3 Calcular ϒi con ecuación de NRTL Ln ϒ1= 0. Calcular Ki con ecuación de Raoult modificado K1= 2.7493394658 4.7 77.4866900093 3.45 340. Calcular Yi con ecuación de raoult Y1= 0.4 347.95 71.1 344. Metanol= TB.38 469.9998724201 3.4 62.230195255 PV2= 561.05 337.09 T °C 98.3073313161 2.4415648696 ∆21= 2.9099417262 ∆12= 0.000127588 R= 715 ϒ1= ϒ2= 1.7599417262 °C 364.55 Ptotal.0335260739 0.9332340095 K2= 0.05 81.94 MODELO TALLER 120 100 80 T °C 60 40 T vs X T vs Y .2933234009 Y2= 0.25 73. Calcular Presión de Vapor con ecuación de Antoine Log(10)PV1= Log(10)PV2= PV1= 2029. Agua= X1= X2= 64.0329763286 Lnϒ2= -0. Calcular si la sumatoria de y es 1 Sumatoria de Y = 0.45 361. Proponer una T entre TA y TB T= 91.2079814276 40.55 336.73 18.3 88.85 350.3 67.7 100 0.9 V1= V2= a12= a21= 1.DATOS TA.9999996947 Función Objetivo MODELO TALLE T (k) 371.

MODELO TALLER 120 100 80 T °C T vs X 60 T vs Y 40 20 0 0 0. Y 0.2 .6 X.8 1 1.4 0.2 0.

02 MODELO WILSON x1 0 0.5664 0.08097 1582.1 0.08205746 L.0111560674 0.2 0.29 86.37 74.21 0. Modelo de NRTL -0.6755 0.8033 0.6 0.36367 L.4 0.7488 0.88 845.8 0.9 1 8.62.9223 0.76 77.87 68.03 63.7 0.9 1 MODELO WILSON 120 100 80 T vs X T vs Y T °C 60 40 T T .2994 AGUA A= 8.lbmol 83.mol 10.07131 B= 1730.426 t °C 98.1 0.037140459 1.atm/K.8859 0.14472 L.5 0.6 0.003345711 0.7316 ft3.mol 8.77 70.4 0.31 80.psi/R.99 65.7 Y1 0 0.5 0.9593 1 b12= b21= α= -253.314472 L.3 0.27 239.8 0.2 0.3818 0.8473 0.3 0.mmhg/K.87 72.mol 0.mbar/K.9889417436 METANOL A= B= C= MODELO TALLER X1 0 0.mol Tao12=b12/RT Tao21=b21/RT G12=EXP(-α*Tao12) G21=EXP(-α*Tao21) 2.Kpa/K.63 C= 233.7 0.72 66.

Y 0.8 1 1.2 0.6 X.MODELO WILSON 120 100 80 T vs X T vs Y T °C T 60 T 40 20 0 0 0.4 0.2 .

LO WILSON y1 0 0.9581 0.8718 0.9999 ON T vs X T vs Y .6577 0.9155 0.7775 0.8262 0.4294 0.7231 0.5683 0.

2 .ON T vs X T vs Y 1 1.