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Chapter 6

Saturation Pressure & Vapor Quality

Liquid-vapor phase change (evaporation and condensation) are extremely important to many, many
industries. Processes such as distillation and separation in petroleum refineries, electrical power
generation in steam power plants, and refrigeration cycles all depend upon control of evaporation
and condensation.



Evaporation (and boiling) is the process in which liquid becomes vapor and in doing so absorbs a
measure of thermal energy known as latent heat. As an example, to maintain a constant temperature the human body requires cooling to offset the thermal energy released during the metabolic
process. Perspiration, consisting primarily of salt water, evaporates thereby cooling the surface of
the skin. The process of evaporation occurs at a constant temperature. The cooling effect arises
from the loss of thermal energy; that is, the transfer of latent heat. The temperature at which evaporation and condensation occurs is known as the saturation temperature. The corresponding
pressure is known as the saturation pressure. The temperature at which evaporation or boiling
occurs varies with pressure. It is a common observation that water boils at a temperature less than
100 C at a high altitude, such as encountered on mountains, because the atmospheric pressure is
less at these elevations.

s o lid
p re ssu re

liq u id

c ritic a l
p o in t

v a p o r
trip le
p o in t

te m p e ra tu re
Figure 6.1. General pressure-temperature relationship.

Figure 6.1 illustrates the relationship between pressure and temperature for the solid, liquid,
and vapor phases of a substance. The triple point is the temperature and pressure at which all three
phases can coexist. The line separating the solid-liquid regions represents a set of temperatures



and pressures at which the solid and liquid phases (ice and water) may coexist. Similarly, the
line separating the liquid-vapor regions represents a set of temperatures and pressures at which
the liquid and vapor phases (water and steam) may coexist. The critical point is the pressuretemperature state beyond which there is no distinction between liquid and vapor phases.

Quality of Vapor

The thermodynamic state of a single phase fluid (gas or liquid) can be determined if two properties
are known. So, if the pressure and temperature are measured and the system is in thermal equilibrium, then all of the other properties at this state can be determined. If two phases are present (vapor and liquid),
then three thermodynamic states must be known.
example, consider a liquid is in
equilibrium with its vapor in a
v a p o r
v a p o r
closed system at some temperature and pressure as illustrated.
sa t
sa t
Since the two phases coexist in
sa t
equilibrium, the temperature is
v a p o r
the saturation temperature, Tsat .
liq u id
liq u id
The exact same saturation temperature and pressure can be obx 1
x 3 = 1
x 2 > x 1
tained with less liquid in the system. In fact, the exact same temperature and pressure can be obtained without any liquid in the
system. Just knowing the temperature and pressure is insufficient to determine the systems state
because the mass, density, and specific volume are not a unique to this temperature and pressure.
Any three properties may be used in specifying the thermodynamic state of a two-phase mixture.
One property typically used, in addition to temperature and pressure, is quality. Quality, x, is
the ratio of vapor mass, mg , to mixture mass, mg + mf :1


mg + mf


Therefore, x1 < x2 < x3 = 1. The quality of saturated liquid is 0 an the quality of saturated
vapor is 1. The thermodynamic properties of the mixture which are dependent upon mass can be
expressed using quality. The specific volume (volume per mass) of the systems in the illustration is
v = (1 x)vf + xvg . Other properties dependent upon mass such as internal energy, enthalpy, and
entropy can be determined in a similar manner.

Pressure, Temperature and Density of a Saturated Mixture

Three properties are required to specify the thermodynamic state of a two-phase mixture. Of
the numerous fluid properties, there are three which are relatively easy to determine; pressure,
temperature, and density. The specific volume, v, is an intensive property which is the inverse of
density, v = 1/.
Figure 6.2 illustrates the relationship between pressure, temperature and specific volume for a
liquid-vapor system. The diagram is of pressure versus specific volume (P -v diagram) and lines of
constant temperature (isotherms) are shown. The saturated state, that is the state at which vapor
and liquid coexist, is defined by the saturation curve. The region to the right of the saturation
curve is superheated vapor and the region to the left of the saturation curve is subcooled liquid. In

By convention, a subscript f is used to denote the liquid phase and a subscript g to denote the vapor phase.
The subscript f g denotes the difference between the vapor and liquid, i.e. hf g = hf hg .



p re ssu re

c ritic a l
p o in t

s a tu ra tio n c u rv e
s u p e rh e a te d
v a p o r re g io n

s u b c o o le d
liq u id re g io n

is o
th e

c o e x is ta n c e
re g io n
(v a p o r d o m e )

1 f

1 g


s p e c ific v o lu m e

Figure 6.2. Pressure vs Specific Volume (P-v) diagram for a fluid illustrating the relationship between
the saturation curve, isotherms (T2 > T1 ), and regions of subcooled liquid and superheated vapor.

order to condense superheated vapor at a constant pressure, the temperature must be reduced until
the vapor reaches the saturation curve. Similarly, evaporation of a subcooled liquid at a constant
pressure requires increasing the liquid temperature until the saturation curve is reached.
At a saturation temperature of T1 and saturation pressure of P1 , the liquid specific volume is
v1f and the vapor specific volume is v1g . The specific volume of the mixture is a ratio of the liquid
and vapor specific volumes based on the mass ratio of liquid and vapor as defined by the quality.
v1 = (1 x)v1f + xv1g
Note, however, that there is no saturated fluid, vapor or liquid, which has a specific volume between
these two values. All of the liquid is at v1f and all of the vapor is at v1g . When a portion of the
liquid evaporates, the specific volume immediately jumps to v1g . There is no stable thermodynamic
state under the saturation curve. The saturation curve delineates the stable liquid thermodynamics
states from the stable thermodynamic states of the vapor.

Thermodynamic Property Data

The relationship between saturation pressure, saturation temperature and other thermodynamic
properties such as specific volume, internal energy, enthalpy, specific heats, and entropy for water
and common refrigerants can be found in most standard thermodynamic textbooks [1, 10]. More
extensive property data bases for a wide variety of fluids is available in software programs [9] and
online data bases such as that provided by the National Institute of Standards and Technology
(NIST). The saturation tables generally list temperature, pressure, and then saturated liquid and
vapor values for specific volume (vf , vg ), internal energy (uf , ug ), enthalpy (hf , hg ), and entropy
(sf , sg ). The specific volume, internal energy, enthalpy and entropy of the liquid-vapor mixture
can only be determined once the quality is known.
If the calculated quality is greater than 1, then the fluid is not in a saturated state. There
is no liquid present and the thermodynamic state is that of superheated vapor. A separate sett
of property tables and data bases are required to determine the properties of superheated vapor.
Likewise, if the quality is calculated to be less than 0, then there is no vapor present and the system



is a subcooled liquid. Still another property table or data base is required for subcooled liquid.
Quality is only a property of saturated liquid-vapor and must have a value between zero and one
(0 x 1).

Measuring Quality

Measuring quality directly is extremely difficult, especially in an open system where fluid is flowing
in and out of a process. To measure quality, a two-phase mixture with two known properties such
as pressure and temperature is passed through a constant temperature process where all of the
liquid evaporates so that only vapor exists. This is known as throttling a mixture.
Figure 6.3 illustrates the process. Saturated liquid and vapor at high pressure (Psat ) is allowed
to expand through a flow restriction resulting in a sharp decrease in pressure. If the temperature
can be held constant and the pressure is decreasing, then the vapor moves from a saturated state
to a superheated state. This process can be seen in Fig. 6.2. Starting with saturated vapor at T1 ,
P1 , and v1g , if the pressure drops but the temperature remains constant then the vapor will travel
downward on the isotherm T1 into the superheated region. As this occurs, any liquid present will
flash to vapor in order to follow the drop in pressure. If the process illustrated in Fig. 6.3 can be
thoroughly described, then there should be sufficient information to determine the quality of the
liquid-vapor mixture prior to throttling.


sa t

sa t

liq u id -v a p o r
m ix tu re , x = ?

th ro ttle

< P

sa t

v a p o r, x = 1

sa t

Figure 6.3. Throttling process for a liquid-vapor mixture.

The throttling process can be analyzed by applying Conservation of Energy (the First Law of
Thermodynamics) to a Control Volume surrounding the throttle in Fig. 6.3. There will be flow
across the control surface into the left side and out of the right side so this is considered an
open system. A number of simplifying assumptions are appropriate for this control volume:
steady flow there is no accumulation of energy or mass within the
control volume
uniform flow there is no variation in properties over the flow areas;
there is no velocity profile to the inlet or outlet flow so
it is not necessary to integrate the property variation
over the flow area.
With these assumptions the Conservation of Energy for the control volume is reduced to:
= m e (he + Ve + gze ) m i (hi + Vi + gzi )


is the transfer of work across a control

where Q is the transfer of heat across a control surface, W
surface, m
is the mass flow rate across a control surface and (hi +V 2 /2+gz) is the energy associated
with the mass flow with the terms representing enthalpy, kinetic energy and potential energy,
respectively. If the throttle is well insulated, then there will be no heat transfer (adiabatic) and
there is no work which crosses the control surface. The change in kinetic energy and potential



energy across the throttle is nearly always negligible. Finally, since there is no accumulation of
mass (steady flow), m e = m i . Thus, equation (6.2) for the throttling process reduces to
hi = he


The enthalpy at the exit, he , can be determined if the pressure and temperature are known because
the exit condition is superheated vapor. This is a single phase so only two properties need to be
measured to define the thermodynamic state. The value of the enthalpy at the inlet, hi , is defined
by the amount of fluid in the liquid state and vapor state.
hi = (1 x)hf + xhg


The saturation enthalpies, hf and hg , can also be determined if the pressure and temperature are
known. Thus, by combining equations (6.3) and (6.4), the quality can be found:

he hf
hg hf


Empirical Correlation for Saturation Pressure and Temperature

There are times when tables of numbers for saturation properties are not convenient to use; such
as with spreadsheet programs like Excel, Lotus123, and Quattro. An empirical correlation between saturation pressure and temperature could be useful. When plotted on a graph of absolute
temperature, Tabs , against absolute pressure, Pabs , the result is a smooth curve (Fig. 6.4). The
saturation curve is not described completely by any single, simple equation, but over a limited
range of pressure it is possible to obtain a good fit using:
Pabs = b ea/Tabs


where a and b are empirically determined coefficients. This equation is not derived from any theory
or underlying physical laws. It only approximately describes the relationship between saturation
temperature and pressure. For any particular range of pressures, there will be specific values of
the coefficients a and b which minimize the differences between the measured values and the curve
described by equation (6.6). These differences arise both through experimental errors (random,
scale and zero errors) and because the real behavior does not perfectly match the equation.
Attempting to fit experimental data to equation (6.6) is extremely difficult and likely to result
in very large discrepancies in the calculated coefficients. A more accurate approach would be to
linearize equation (6.6) using logarithms.
ln Pabs = ln b + a (



Thus, plotting ln P vs T (semilog plot) results in a straight line and standard least squares methods
may be used to determine accurate values for the coefficients a and b which are the slope and the
intercept, respectively, of the plot of ln Pabs vs 1/Tabs . Rearranging equation (6.7) reveals that b is
a reference pressure and a is a reference temperature.
ln (


Holman [11, 3.17] provide a more detailed discussion on plotting data.




Figure 6.4. Saturation Temperature Plot for Water


Atmospheric Pressure

The pressure gauge you will be using in the saturation pressure and throttling experiments reads
a gauge pressure; that is, a differential pressure relative to the local atmospheric pressure measurement. As such, you must add atmospheric pressure to the pressure reading in order to develop
an accurate correlation between saturation temperature and pressure. It is not sufficient to add a
standard sea-level value of atmospheric pressure. You must measure the local atmospheric pressure.
Mercury Barometer
A barometer is a well-type manometer used to measure atmospheric pressure. The measurement
tube is sealed so that the pressure at the top of the liquid column is the vapor pressure. The height
of the liquid column is balanced by the difference between the vapor pressure in the measurement
tube and atmospheric pressure at the well. Mercury is used in barometers because of its high
density (SG = 13.58) and because its vapor pressure is extremely low.



v a p o r p re ssu re , P

~ 0

at 0 C (32 F)

Pv = 0.0247 Pa (3.58 106 psia)

at 20 C (68 F)

Pv = 0.16 Pa (2.32 105 psia)

The vapor pressure of mercury is so low that it can

be neglected in the calculation of atmospheric pressure.

s c a le

Patm = (Hg,liq Hg,vap )gh

a tm

m e rc u ry


An accurate measure of atmospheric pressure requires use

of the local value of the gravitational acceleration and the
mercury density at the current temperature. If the local
gravitational acceleration and/or the density of mercury
are not known, then standard values for both may be used
with correction factors added to the height:
Patm = (Hg at 0 C)(gstd ) (h + hg + hT )


where hg is the correction to the gravitational acceleration based on latitude. The standard gravitational acceleration is gstd = 9.80664 m/s2 (32.124 ft/s2 )
at 45.5 latitude. Houghton is at a latitude of 47 7.5. The temperature correction, hT , corrects
the observed height, h, to both the standard temperature of the measurement scale of 16.7 C
(62 F) and the standard density of mercury at 0 C (32 F) which is Hg = 13595.5 kg/m3 = 26.35
slug/ft3 . Correction tables for hg and hT are available in the laboratory.



The objectives of this laboratory exercise are to:

study the relationship between saturation pressure and temperature of a water-steam mixture,
use property tables (steam tables) to determine the thermodynamic state of a liquid-vapor
use linearization methods to obtain best fit correlations to non-linear data,
measure the quality of a liquid-vapor mixture via throttling, and
determine the atmospheric pressure using a mercury barometer.





The saturation and throttling experiments will be conducted on the Armfield TH3 Saturation
Pressure Units. Figure 6.5 is a schematic of the basic system. Refer to the Fig. 6.6, 6.7, and 6.8
and Table 6.1 for location and description of the part numbers.

Figure 6.5. Schematic of Saturation Pressure Rig.

The saturation pressure apparatus consists of a fluid loop with an insulated cylindrical boiler (2)
in one of the vertical lines. Distilled water in the boiler is heated to the boiling point using a pair of
cartridge heaters (11) that are located near the bottom of the boiler. A sight glass (10) on the front
of the boiler allows the internal processes to be observed, namely boiling patterns at the surface
of the water while heating or reducing the system pressure and cessation of boiling/condensation
during cooling. The sight glass also allows the water level in the boiler to be monitored. Saturated
steam leaving the top of the boiler passes around the loop before condensing and returning to the
base of the boiler for reheating. The operating range of the boiler and loop is 0 to 8 bar gauge.
A pressure relief valve (5) is set to open at 8 bar. NEVER lean over or place your hand
above the pressure relief valve! The top line of the loop incorporates an platinum RTD (3)
and a pressure transducer (9) to measure the properties of the saturated steam. A Bourdon tube
pressure gauge allows for monitoring of the boiler pressure even when there is no power to the unit.
A fill/vent tube (38) connected to the fill/vent valve (4) on the line allows the loop to be filled
with distilled water and allows all air to be vented safely before sealing the loop for pressurized
measurements. The bottom of the fluid loop has a drain valve (39).
A throttling valve (6) and a throttling calorimeter (7) are attached to the vapor line, the
purpose of which is to demonstrate the measurement of steam quality, x. The steam expands
to atmospheric pressure as it passes through the throttling calorimeter. A platinum RTD (14)
measures the temperature of the superheated vapor. A container (15) below the calorimeter collects
condensing vapor and allows it to be drained safely from the apparatus.


Review all of the experiment procedures prior to starting this experiment. Refer to the
Fig. 6.6, 6.7, and 6.8 and Table 6.1 for location and description of the part numbers.



1. Verify proper water level in the sight glass (10) of the boiler (2).
2. Verify that the fill/vent valve (4), the throttling valve (6), and the drain valve (39) are closed. The
throttling valve is closed when the valve handle is perpendicular to the tube; for this apparatus, the
valve is closed when the handle is vertical.
Saturation Pressure Experiment
3. Switch the heaters (36) ON and turn the heater power control (37) to MAXIMUM. Verify that the
throttling valve closed (6).
4. Observe the appearance of the fluid in the boiler (2) through the sight glass (10) as the temperature
5. Record in the saturation curve data table the pressure and temperature at approximately every 1 bar
(100 kPa) increment until the boiler reaches the maximum working pressure of 7 bars gauge. The
pressure can be read from the sensor readout display (26) on the console (20). The sensor selector
switch (27) on the console may be used to toggle the readout between the platinum RTD sensor,
PT100(1), and the pressure transducer. The pressure reading is gauge pressure so the atmospheric
pressure will have to be measured in order to convert the transducer reading to absolute pressure. The
temperature reading is the resistance of the RTD. The resistance can be converted to temperature
using Table 6.2.
Throttling Experiment
6. When a pressure of 7 bar gauge has been reached, turn off the heaters (36) and reset the heater power
control (37) to zero.
7. OPEN the throttling valve (6).
8. As the pressure decreases, record in the throttling process data table the pressure and both RTD
readouts at every 100 kPa decrement until the boiler reaches zero pressure. The pressure decreases
rapidly so plan in advance who will be switching the display and who will be recording each of the
sensor readouts. Note that since the throttling calorimeter insulation has been removed, the first
few seconds of throttling is not adiabatic. Heat is being transferred from the fluid to the throttling
calorimeter (7). Therefore, the assumption that the process is adiabatic is incorrect and equation (6.3)
is invalid. The temperature of the throttling calorimeter will increase quickly and after a few seconds
the process becomes adiabatic and equation (6.3) will be valid.
9. After the last set of readings SWITCH OFF the unit. LEAVE THE THROTTLING VALVE
OPEN to bleed some steam. Leaving the valve closed when the system is at high temperature may
produce a partial vacuum upon cooling which could damage the apparatus.



Figure 6.6. Top view of Armfield TH3 Saturation Pressure Rig.

Figure 6.7. Side view of Armfield TH3 Saturation Pressure Rig.



Figure 6.8. Front and back panels of experiment control console.

Table 6.1. Component Description for the Armfield TH3 Saturation Pressure Apparatus

temperature probe, PT100 (1)
fill/vent valve
pressure relief valve
throttling valve
throttling calorimeter
Bourdon tube pressure gauge
pressure transducer
sight glass
cartridge heaters
temperature probe, PT100 (2)
condenser cup
RTD connector, PT100 (1)
RTD connector, PT100 (2)
pressure transducer connector
cartridge heater connector
TH3 control console


console power breaker, CONT

cartridge heater breaker, HEAT
auxiliary power breaker, O/P
power input
sensor readout
sensor selector switch
input/output data port, IFD3
power cable
power switch
heater connector
pressure transducer connector
PT100 (2) RTD connector
PT100 (1) RTD connector
auxiliary 120 A/C power
heater switch
heater power control
fill/vent tube
drain valve
pressure relief line




Data Sheet for Saturation Curve

mm Hg
Patm :










ln(Pabs )

Data Sheet for Throttling Process

mm Hg

Patm :
















LEAVE THE CALORIMETER VALVE OPEN when the lab is completed.

Table 6.2. RTD Resistance Temperature Conversion Table





Measuring Atmospheric Pressure

During this experiment you will determine the local value of the barometric pressure using a Fortin
barometer. Record all data in the table provided in 6.4.1. The basic procedures are as follows:
1. Set the fiducial point: The lower mercury surface in a Fortin barometer has
to be set to a datum level before adjusting its vernier and the accuracy of pressure measurement depends crucially upon proper setting. The mercury surface
should first be lowered until it is clearly below the fiducial point (F). Tap the
barometer lightly to stabilize the meniscus. Then very slowly turn adjusting
knob (A) until the gap between fiducial point and the reservoir mercury surface
just disappears when viewed horizontally. The point should make no more than
the slightest dimple in the mercury surface. If the mercury surface is bright
and the level correct, the tip of the fiducial point will coincide with the reflected
image on the mercury surface. The setting will only be correct if the mercury
surface is raised to the fiducial point, not lowered. If while raising the surface
the fiducial point penetrates the surface, the mercury level should be lowered
and the procedure restarted. A dirty mercury surface, poorly shaped fiducial
point or a partially clogged porous plug (P) can make proper and repeatable
setting very difficult.



2. Setting the Vernier: The vernier (V) should be lowered until both the front
and back edges of the vernier coincide with the apex of the mercury meniscus when viewing
exactly horizontal.

3. Reading the Vernier: There are two measurement scales (S); an English
unit scale (inches) and a SI unit scale (mm). The vernier has two gradations
corresponding to each scale. After setting the vernier, read both scales simultaneously.
4. Measure the Barometers Temperature: A thermometer is attached to
the barometer for measuring the temperature.
5. Apply the Gravitational and Temperature Corrections to the Observed Height: The barometer manual contains both English and SI correction factors for latitude and temperature.




Data Log for Atmospheric Pressure Measurement

Lab Partners:

Complete the table for both sets of units.

SI Units
Room Temperature

English Units


Mercury Height (observed)



temperature correction



latitude correction



mm Hg

in Hg



mm Hg

in Hg



Mercury Density (std)

atmospheric pressure

National Weather Service

Notes and Calculations:


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