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EXOTHERMIC REACTIONS
To determine the maximum conversion that can be achieved in
an exothermic reaction carried out adiabatically, we find the
intersection of the equilibrium conversion as a function of
temperature:
KC
Xe
1 KC
with temperature-conversion relationships from the energy
balance (eq. 1.46). For Ti0 = T0,
n T
iCpidT
i1 T0
T
0
HRx TR Cp dT
T
(1.57)
EXAMPLE 1.5
For the elementary solid-catalyzed liquid-phase reaction:
A B
make a plot of equilibrium conversion as a function of
temperature. Determine the adiabatic equilibrium
temperature and conversion when pure A is fed to the
reactor at a temperature of 300 K.
Additional information:
H0A 298 K 40,000 cal mol
Cp 50 cal mol.K
Cp 50 cal mol.K
K e 100,000 at 298 K
SOLUTION
Rate law:
CB
rA k C A
Ke
(a)
Equilibrium, rA = 0, so:
CBe
C Ae
KC
(b)
Equilibrium constant:
0
HRx
K e T K e T1 exp
R
1 1
T1 T
0
HRx
HB0 H0A 20,000 cal mol
20 ,000 1 1
1.987 298 T
T 298
(c)
(d)
T (K)
Ke
Xe
298
100000.00
1.0000
300
79835.65
1.0000
325
6042.58
0.9998
350
661.28
0.9985
375
97.20
0.9898
400
18.16
0.9478
425
4.13
0.8051
450
1.11
0.5257
475
0.34
0.2545
500
0.12
0.1058
i C pi T T0 Cp T T0
HRx T
HRx T
50 T 300
X
2.5 10 3 T 300
20 ,000
T
300
350
400
450
500
Xe
0.0000
0.1250
0.2500
0.3750
0.5000
(e)
1.20
Ke T
Xe
1 Ke T
1.00
0.80
0.60
0.40
0.40
Cp T T0
Xe
HRx T
A
0.20
460
0.00
300
350
400
450
T (K)
500
550
600
EXAMPLE 1.6
What conversion could be achieved in Example 1.5 if two
interstage coolers were available that had the capacity to cool
the exit stream to 350 K? Also determine the heat duty of
each exchanger for a molar feed rate of A of 40 moles. Assume
that 95% of equilibrium conversion is achieved in each reactor.
The feed temperature to the first reactor is 300 K.
SOLUTION
In Example 1.5, for an entering temperature of 300 K the
adiabatic equilibrium conversion was 0.40.
For 95% of equilibrium conversion, the conversion exiting
the first reactor is 0.38.
(f)
(g)
1.20
1.00
0.80
X 0.60
0.40
0.20
0.00
300
350
400
450
T (K)
500
550
600
ENDOTHERMIC REACTIONS
Another example of the need for inter-stage heat transfer in a
series of reactors can be found when upgrading the octane
number of gasoline. The more compact the hydrocarbon
molecule for a given number of carbon atoms, the higher the
octane rating. Consequently, it is desirable to convert straightchain hydrocarbons to branched isomers, naphthenes, and
aromatics.
The reaction sequence is
V or W