AMMONIA-UREA AND SYNGAS-BASED PRODUCTS

ONSHORE ENGINEERING AND CONSTRUCTION PROJECT REFERENCES

AMMONIA-UREA AND SYNGAS-BASED PRODUCTS

INDEX

SAIPEM TODAY SAIPEM ONSHORE AMMONIA-UREA AND SYNGAS-BASED PRODUCTS SYNGAS PRODUCTION CAPACITY SNAMPROGETTITM UREA TECHNOLOGY IN THE WORLD AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES SNAMPROGETTITM UREA TECHNOLOGY REVAMP REFERENCES UREA PLANTS BASED ON CONVENTIONAL AND I.D.R. PROCESSES OTHER FERTILIZERS, RELATED UNITS AND GAS-BASED PRODUCTS

4 6

8 12

14

16

44

50

56
3

SAIPEM TODAY
SAIPEM TODAY IS A WORLD LEADER IN THE GLOBAL SUPPLY OF ENGINEERING, PROCUREMENT, PROJECT MANAGEMENT AND CONSTRUCTION SERVICES WITH DISTINCTIVE CAPABILITIES IN THE DESIGN AND EXECUTION OF LARGE-SCALE OFFSHORE AND ONSHORE PROJECTS.

4

Saipem has a strong bias towards oil & gas frontiers, namely activities in harsh and remote areas, in deep waters as well as in extremely cold and hot environments, applying significant technological competences in many diverse fields such as gas monetization and heavy oil exploitation.

Saipem, 43% owned by Eni, is organized in three Business Units: Offshore, Onshore and Drilling.

5

SAIPEM ONSHORE
FOLLOWING THE ACQUISITION OF SEVERAL ENGINEERING COMPANIES OVER THE LAST YEARS, MOST PROMINENTLY OF SNAMPROGETTI, BOUYGUES OFFSHORE AND SOFRESID, SAIPEM HAS BECOME ONE OF THE WORLD’S LARGEST AND MOST COMPLETE ENGINEERING AND CONSTRUCTION COMPANIES IN THE GLOBAL OIL & GAS MARKETS ONSHORE.

6

Saipem Onshore offers a complete range of project definition and execution services, particularly for the “mega-projects” required by the market today: from feasibility and conceptual studies to complex integrated solutions combining design, engineering, procurement and field construction. The integration of our engineering and project management centres in several continents has been completed recently, providing a consistent design and robust execution philosophy on all our projects worldwide. Through the involvement of our four global engineering centres for onshore projects in Milan and Fano (Italy), Paris (France) and Chennai (India), which operate in connection with a growing number of medium

size and smaller engineering centres, employing altogether over 7,000 engineers, Saipem balances high project execution quality with a competitive cost and – most importantly – with a major emphasis on local know-how and content. Saipem today operates in virtually every world market, often in remote locations with harsh environmental conditions and challenging logistics, leveraging on its proven experience across the most significant product lines in the oil & gas upstream, midstream, refining, chemicals, power generation, environmental industries and infrastructure. This new series, therefore, outlines Saipem integrated references in onshore markets, according to individual business and technology lines.
7

AMMONIA-UREA AND SYNGAS-BASED PRODUCTS
THE INDUSTRIAL APPLICATION OF SYNGAS-BASED CHEMICAL PROCESSES HAS BEEN ONE OF THE STALWARTS OF SNAMPROGETTI, RECENTLY INTEGRATED INTO SAIPEM, ALMOST SINCE ITS EARLIEST DAYS MANY DECADES AGO.

We have designed and built hundreds of plants, including more than twenty fully integrated complexes, in every remote corner of the world, mostly based on the world leading and proprietary licensed SnamprogettiTM Urea Technology as well as on third party syngas generation, ammonia and methanol synthesis technologies. In the Ammonia-Urea process sequence, Saipem is a recognized world leader: Over 110 Urea Technology licensed plants in operation. In the quest for the economies of scale, design and construction of the largest single train urea unit in operation today (Profertil, Bahia
8

Blanca Fertilizer Complex in Argentina), which achieved an average yearly production of 3,558 Tons per Day (T/D) in 2006 and has become the reference for the subsequent design and construction of today’s biggest single train urea plants, like the Daharki Ammonia-Urea Complex for Engro in Pakistan and the Qafco 5 Fertilizer Complex in Qatar with the capacity of 3,835 T/D and 3,850 T/D respectively. Design and construction in 20022005 of the largest ammonia-urea single project, namely Omifco in Oman, with the total urea design capacity of 5,060 T/D; in 2008 the plant achieved the capacity peak of 6,000 T/D.

Continuous Urea Technology improvements and upgrading. To name just a few most recent achievements: - the new OmegabondTM Advanced Tubing Technology (Ti/Zr metallurgically coextruded) for improved stripper performance developed in collaboration with ATI WahChang; - focus on plant reliability and availability concepts applied on the 5,000+ T/D single train; - the adoption of continuously improved environmental impact reduction and energy saving schemes.

Moron Fertilizer Complex - Venezuela 1972

9

10

In addition to a large number of integrated ammonia-urea complexes based on natural gas and light naphthas as feedstocks, in 2002 Saipem has placed on stream in Nanjing, P.R. China, a complex utilizing coal-like Eureka pitch as feedstock. This feedstock is gasified by means of a GE (former Texaco) gasification technology to produce syngas, subsequently converted into 1,000 T/D of ammonia and 1,700 T/D of urea. Our project reference list has been enriched with the award a few years ago of the multibillion Gas-to-Liquids project in Escravos, Nigeria from Chevron Nigeria Ltd. The goal of this new investment is the conversion of natural gas into 33,000 BPSD of top quality middle distillates for transportation fuels via the new process technology licensed by Sasol. The first steps in the process sequence, namely the syngas production, are based on a technology which is very similar to the one applied in large scale ammonia and methanol synthesis.

Among other technological novelties, this project will see one of the first applications on a very large scale of Haldor Topsøe’s ATR – Auto Thermal Reformer – process technology. With a capacity of 560,000 Nm3/h of each of the two ATRs, this will be one of the largest syngas production units in the world. Saipem has been traditionally a leading player in the design and execution of Methanol Synthesis plants, based on different process technologies, with the more recent focus on Haldor Topsøe’s – e.g. the 3,000 T/D Bandar Imam plant in Iran – a world class plant at the time of its start-up in 2004 and, more recently, the Front End Design of the 10,000 T/D VIVA Methanol Project in Nigeria. This last one could become the largest methanol synthesis and syngas generation plant ever built.

11

SYNGAS PRODUCTION CAPACITY
SYNGAS PRODUCTION CAPACITY IN RECENT SAIPEM DESIGNS.

Project

Syngas Production Capacity per Train (dry basis), kNm3/h

Syngas Generation Technology
N. Type

VIVA METHANOL,(b) NIGERIA ESCRAVOS GTL,(c) NIGERIA QAFCO 5,(a) QATAR ENGRO,(a) PAKISTAN OMIFCO,(a) OMAN FERTINITRO,(a) VENEZUELA PROFERTIL,(a) ARGENTINA BANDAR IMAM,(b) IRAN NANJING,(a) CHINA
0 100 200 300 400 500 600 700 800 900 1000 1100

1

ATR

2

ATR

1

Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer One step reformer

2

1

2

1

1

2

Gasifier

(a) Ammonia (b) Methanol

Synthesis including Nitrogen

Synthesis (c) Gas-to-Liquids
12

13

SNAMPROGETTI UREA TECHNOLOGY IN THE WORLD

TM

CANADA

U.S.A.

SPAIN ALGERIA

MEXICO

TRINIDAD & TOBAGO

VENEZUELA

SAIPEM TODAY IS A MARKET LEADER IN THE AMMONIA-UREA PROCESS CHAIN, WITH OVER 110 SNAMPROGETTITM UREA TECHNOLOGY LICENSES WORLDWIDE, WITH MORE THAN 20 INTEGRATED AMMONIA-UREA COMPLEXES AND NUMEROUS INDIVIDUAL PROCESS UNITS DESIGNED AND BUILT IN EVERY CONTINENT. SAIPEM HOLDS A LEADING SHARE OF THE TOTAL INSTALLED CAPACITY WORLDWIDE.

ARGENTINA

14

RUSSIA

GERMANY AUSTRIA ITALY BULGARIA PAKISTAN IRAQ SAUDI ARABIA OMAN SOMALIA MALAYSIA IRAN BAHRAIN QATAR INDIA P.R. CHINA BANGLADESH VIETNAM

INDONESIA

15

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES
SAIPEM IS THE OWNER OF THE SNAMPROGETTITM UREA TECHNOLOGY. LOCATION
Country, Location Algeria, Arzew China, Fugu, Shaanxi China, Jungar, Inner Mongolia China, Korla, Xinjiang Uyugur Nigeria, Escravos ALGERIA OMAN FERTILIZER COMPANY SHAANXI POPULAR JURASSIC (GROUP) Co., Ltd. INNER MONGOLIA TALENT CHEMICAL FERTILIZER Co., Ltd. PETROCHINA TARIM PETROCHEMICAL COMPANY CHEVRON NIGERIA Ltd. (CNL)

Technologies
AMMONIA
License Capacity T/D

CLIENT

UREA
SnamprogettiTM Technology Capacity T/D 2x 3500 1760 1760 2640

ESCRAVOS GAS-TO-LIQUIDS PROJECT - NIGERIA
In addition to being one of the first applications of the Gas-to-Liquids technology on a world-class scale (process technologies by Sasol, Chevron, Haldor Topsøe and others), the design and construction of this complex had several elements of originality, such as the harsh and remote site environment. In order to simplify local construction on the site in Escravos, Nigeria, many plant sections were designed and built in an U.A.E. fabrication yard as modules, then shipped to the site. • Modularization design: the biggest Saipem modularized plant of all times (pipe rack modules of over 1,000 tons each, process modules of over 2,000 tons each) • Erection - Reactors Size: World Class Record 2008

16

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance

ON STREAM
Under Exec. Under Exec. Under Exec. Under Exec.

Gas-to-Liquids (Sasol, Chevron, Haldor Topsøe A/S) 2x 17000 BPSD

Engineering / Procurement / Construction

Under Exec.

17

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Iran, Assaluyeh Pakistan, Daharki HENGAM PETROCHEMICAL COMPANY ENGRO CHEMICAL PAKISTAN LIMITED (ECPL) Haldor Topsøe A/S 2194

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 3250 3835

DAHARKI AMMONIA-UREA COMPLEX - PAKISTAN
The Daharki Ammonia-Urea Complex, with an ammonia capacity of 2,194 T/D and an urea capacity of 3,835 T/D, will be one of the two largest single train urea plants in the world. The complex is characterized by the world tallest urea prilling tower.

18

GRANULATION
License Capacity T/D UFT 3250

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / PDP / Tech. Assistance License / Engineering / Procurement / Supervision

ON STREAM
Under Exec. Under Exec.

19

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Qatar, Mesaieed QATAR FERTILIZER COMPANY QAFCO-5 Project

CLIENT

AMMONIA
License Capacity T/D Haldor Topsøe A/S 2x 2300

UREA
SnamprogettiTM Technology Capacity T/D 3850 2385 1760

Vietnam, Ca Mau Vietnam, Ninh Binh Nigeria, Lekki Peninsula (Lagos)

PETROVIETNAM VIETNAM NATIONAL CHEMICAL CORP. (VINACHEM) VIVA METHANOL

QAFCO 5 FERTILIZER COMPLEX - QATAR
The Qafco 5 Fertilizer Complex, with a total capacity of 4,600 T/D of ammonia partially converted into 3,850 T/D of granular urea, will be the largest single train urea project inside the largest fertilizer complex in the world. The project is also characterized by a common utilities and offsites complex to feed subsequent development of Qafco as fertilizer producer as well as by an excess of ammonia production capacity for other applications.

20

GRANULATION
License Capacity T/D UFT 3850

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

License / Engineering / Procurement / Supervision License / PDP / Tech. Assistance License / PDP / Tech. Assistance Methanol (Haldor Topsøe A/S)

Under Exec. Under Exec. Under Exec.

10000

Front End Engineering

-

21

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Oman, Sohar Oman, Sur Sohar International Urea & Chemical Industries SAOC (SIUCI) OMIFCO Haldor Topsøe A/S, Giammarco Vetrocoke

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 2x 1750

2x 1750

2x 2530

Iran, Bandar Imam (Razi)

PETROCHEMICAL INDUSTRIES DEVELOPMENT MANAGEMENT Co.

OMAN INDIA FERTILIZER COMPLEX - OMAN
At the time of the start-up in 2005, the Omifco Fertilizer Complex was the largest ammonia-urea project in the world, supplying granular urea. The plant was implemented under limited recourse of project financing, including the involvement of Italian and French ECA. The project was built quickly and started up smoothly: • First gas into the ammonia plant 32 months after project financial closure, 35 months after EPC contract signature • First production in 18 days and 1 day for ammonia-urea train one; 12 days and 1 day for train two

22

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / PDP / Tech. Assistance

ON STREAM
2009

UFT HydroAgri

2x 2530 1800

Utilities & Offsites

License / Engineering / Procurement / Construction Engineering / Procurement / Construction

2005 2004

23

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Iran, Bandar Imam FANAVARAN PETROCHEMICAL Co.

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D

Vietnam, Phu-My China, Nanjing, Jiangsu

PETROVIETNAM SINOPEC NANJING CHEMICAL INDUSTRIAL Co., Ltd. Haldor Topsøe A/S, Texaco, Linde, Ici

2200

1000

1750 1725

Indonesia, Bontang-Utara

P.T. PUPUK KALIMANTAN TIMUR

BANDAR IMAM THIRD METHANOL PLANT - IRAN
At the time of the design in 2001, the Bandar Imam Third Methanol was the largest methanol project in the world, supplying methanol high quality grade (AA).

24

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D Methanol (Haldor Topsøe A/S) 3030

SCOPE OF WORK

ON STREAM

License / Engineering / Procurement License / Basic / Tech. Assistance

2004 2004

License / Engineering / Procurement License / Basic / Tech. Assistance

2002 2002

25

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Bahia Blanca, Argentina PROFERTIL S.A.

CLIENT

AMMONIA
License Capacity T/D Haldor Topsøe A/S, Basf 2050

UREA
SnamprogettiTM Technology Capacity T/D 3250 400 400

China, Hefei, Anhui China, Qingzhen, Guizhou

HEFEI SIFANG GROUP GUIZHOU FERTILIZER Co., Ltd.

BAHIA BLANCA FERTILIZER COMPLEX - ARGENTINA
At the time of completion in 2001, the Bahia Blanca Fertilizer Complex included the largest single train urea plant in the world, with the design granular urea production capacity of 3,250 T/D. It was the first plant to break the 3,000 T/D production target in single stream urea. In 2006 it produced 1,280,718 tons in a full year of operation, achieving in 360 days of operation an average daily production of 3,558 T/D, with a maximum peak of 3,700 T/D.

26

GRANULATION
License Capacity T/D HydroAgri 2x 1850

OTHERS
Plant (License) Capacity T/D Utilities & Offsites

SCOPE OF WORK

ON STREAM

License / Engineering / Procurement / Construction License / Basic / Tech. Assistance License / Engineering / Procurement

2001 2001 2001

27

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Venezuela, Jose FERTINITRO C.E.C.

CLIENT

AMMONIA
License Capacity T/D Haldor Topsøe A/S, Giammarco Vetrocoke

UREA
SnamprogettiTM Technology Capacity T/D

2x 1800

2x 2200 900 600 400 400 400

China, Huainan, Anhui China, Anyang, Henan China, Hechi, Guangxi China, Huaxian, Shaanxi China, Pingdingshan, Henan

ANHUI HUAINAN CHEMICAL GROUP Co., Ltd. ANYANG CHEMICAL INDUSTRIAL GROUP Co., Ltd. GUANGXI HECHI CHEMICAL Co., Ltd. SHAANHUA FERTILIZER Co., Ltd. PINGDINGSHAN FEIXING CHEMICAL GROUP Co., Ltd.

JOSE FERTILIZER COMPLEX - VENEZUELA
With the design production of 4,400 T/D of urea in two lines, the Jose Fertilizer Complex is still today the largest ammonia-urea complex in Latin America.

28

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

HydroAgri

2x 2200

Utilities & Offsites

License / Engineering / Procurement / Construction License / Engineering / Procurement License / Engineering / Procurement License / Engineering / Procurement License / Engineering / Procurement License / Basic / Tech. Assistance

2001 2000 1999 1999 1999 1999

29

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Malaysia, Gurun, Kedah Bahrain, Sitra Island PETRONAS FERTILIZER Sdn Bhd GULF PETROCHEMICAL INDUSTRIES Co.

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 1800 1700 (941 uninterrupted production days between turnarounds) 400

China, Zhanyi, Yunnan India, Kakinada, A.P.

YUNNAN ZHANYI CHEMICAL Co., Ltd. NAGARJUNA FERTILIZERS AND CHEMICAL CORP. Haldor Topsøe A/S, Giammarco Vetrocoke

900

1500

Venezuela, Jose

SUPERMETANOL CA

China, Lanzhou, Gansu India, Phulpur, U.P. India, Vijaipur, M.P. China, Chishui, Guizhou China, Dongfang, Hainan China, Hejiang, Sichuan

PETROCHINA LANZHOU PETROCHEMICAL Co. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. NATIONAL FERTILIZERS Ltd. GUIZHOU CHITIANHUA GROUP Co., Ltd. CNOOC CHEMICAL Ltd. SICHUAN TIANHUA Co., Ltd.

1760 2x 1100 2x 1100 500 1765 1765

30

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Basic / Tech. Assistance

ON STREAM
1999

License / Basic / Tech. Assistance License / Basic / Tech. Assistance

1998 1998

License / Engineering / Supervision Methanol (Kvaerner) from 2000 to 2250

1998

Engineering / Procurement / Constr. Mngmt License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Procurement License / Engineering / Procurement

1998 1997 1997 1997 1996 1996 1996

31

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location China, Hohhot, Inner Mongolia China, Jining, Shandong China, Jiujiang, Jiang-Xi India, Aonla, U.P. China, Baoji, Shaanxi India, Babrala, U.P. INNER MONGOLIA TIANYE CHEMICAL GROUP Co., Ltd. JINING CHEMICAL FERTILIZER PLANT SINOPEC JIUJIANG PETROCHEMICAL COMPANY (JPC) INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. SHAANXI BAOJI NITROGEN FERTILIZER PLANT TATA (FERTILIZER DIVISION) CHEMICALS Ltd. Haldor Topsøe A/S, Giammarco Vetrocoke

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 1760 400 1760 2x 1100 400

1350

2x 1125 2x 1100

India, Shahjahanpur, U.P. India, Gadepan, Ra.

KRIBHCO SHYAM FERTILIZERS Ltd. (KSFL) CHAMBAL FERTILIZERS AND CHEMICALS Ltd. Haldor Topsøe A/S, Giammarco Vetrocoke

1350

2x 1125

Venezuela, Jose China, Fuling, Sichuan China, Jinxi, Liaoning Pakistan, Goth Machhi

SUPERMETANOL CA CHONGQING JIANFENG CHEMICAL COMPLEX JINXI NATURAL GAS & CHEMICAL Co., Ltd. FAUJI FERTILIZER COMPANY Ltd. Haldor Topsøe A/S, Basf 1750 1760

1100

1925

32

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Engineering / Procurement License / Basic / Tech. Assistance License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance

ON STREAM
1996 1996 1996 1996 1995

License / Engineering / Supervision License / Basic / Tech. Assistance

1995 1995

License / Engineering / Supervision Methanol (Ici) 2000 Engineering / Procurement / Constr. Mngmt License / Basic / Tech. Assistance License / Basic / Tech. Assistance

1994 1994 1993 1993

Utilities & Offsites

License / Engineering / Procurement / Construction

1993

33

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Bangladesh, Tarakandi China, Luoyang, Henan China, Yuanping, Shanxi India, Kakinada, A.P. JAMUNA FERT. COMPANY Ltd. LUOYANG ZHONGHAO CHEMICAL INDUSTRIAL Co., Ltd. SHANXI YUANPING CHEMICAL INDUSTRY Co., Ltd. NAGARJUNA FERTILIZERS AND CHEMICALS Ltd. Haldor Topsøe A/S, Giammarco Vetrocoke

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 1700 400 400

900

1500

Italy, Ferrara

ENICHEM AGRICOLTURA S.p.A.

China, Beijing China, Xuanhua, Hebei China, Puyang, Henan Italy, Nera Montoro

BEIJING CHEMICAL EXPERIMENTAL PLANT HEBEI XUANHUA FERTILIZER GROUP Co., Ltd. HENAN ZHONGYUAN DAHUA GROUP Co., Ltd. TERNI INDUSTRIE CHIMICHE S.p.A.

400 400 1760

Saudi Arabia, Al Jubail Bahrain, Sitra Island

NATIONAL CHEMICAL FERTILIZER Co. (IBN AL-BAYTAR) GULF PETROCHEMICAL INDUSTRIES Co. Uhde from 1000 to 1200

1500

34

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance

ON STREAM
1992 1992 1992

License / Basic / Tech. Assistance Deep Hydrolysis (SnamprogettiTM)

1992

1700

Engineering / Procurement / Construction License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Procurement

1992 1991 1991 1990

Kaltenbach Thuring S.A.

400

Engineering / Procurement / Construction License / Basic / Tech. Assistance Methanol (Ici) from 1000 to 1200

1990 1990

License / Engineering / Procurement

1989

35

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Venezuela, Zulia PEQUIVEN

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D

India, Aonla, U.P.

INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd.

Haldor Topsøe A/S, Benfield (UC) Haldor Topsøe A/S, Giammarco Vetrocoke

1350

2x 1100

India, Jagdishpur, U.P.

INDO GULF Co., Ltd.

1350

2x 1100 2x 1100

India, Vijaipur, M.P. United Kingdom, Immingham

NATIONAL FERTILIZERS Ltd. NORSK HYDRO FERTILIZERS Ltd.

Pakistan, Multan Bahrain, Sitra Island India, Hazira, Gu. India, Thal Vaishet, Ma. Somalia, Mogadishu Mexico, Pajaritos

PAKARAB FERTILIZERS Ltd. GULF PETROCHEMICAL INDUSTRIES Co. KRISHAK BHARATI COOP. Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. MINISTRY OF NATIONAL PLANNING AGRO NITROGENADOS S.A. Uhde 1000

300

4x 1100 3x 1500 150 1500

36

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D Deep Hydrolysis (SnamprogettiTM) 2x 1200

SCOPE OF WORK

ON STREAM

1989

License / Engineering / Supervision

1988

License / Engineering / Procurement License / Engineering / Supervision Ammonium Nitrate (HydroAgri) Calcium Ammonium Nitrate Granulation (HydroAgri)

1988 1988

1800

3000

Engineering Services License / Basic / Tech. Assistance

1988 1986 1985 1985 1985 1985 1984

Methanol (Ici)

1000

Engineering / Procurement / Construction License / Engineering / Supervision License / Engineering / Supervision License / Basic / Tech. Assistance License / Basic / Tech. Assistance

37

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Bulgaria, Vratza Canada, Red Water, Alberta Spain, Castellon de la Plana CHIMCO AGRIUM U.S. Inc. PROQUIMED

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 600 1500

Trinidad and Tobago, Point Lisas India, Bharuch, Gu. India, Trombay, Ma.

PCS NITROGEN GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. Haldor Topsøe A/S, Benfield (UC) Haldor Topsøe A/S, Benfield (UC)

1620 1800

900

1000

Libya, Marsa El Brega

NATIONAL PETROCHEMICAL Co. (NAPETCO)

1000 1500

Mexico, Pajaritos Pakistan, Goth Machhi

AGRO NITROGENADOS S.A. FAUJI FERTILIZER COMPANY Ltd. Haldor Topsøe A/S, Benfield (UC)

1000

1725 2x 1500 1550

CIS, Togliattigrad India, Phulpur, U.P. Pakistan, Mirpur Mathelo

TOGLIATTI AZOT INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. FAUJI FERTILIZER COMPANY Ltd. Haldor Topsøe A/S, Benfield (UC)

1000

1740

38

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Basic / Tech. Assistance License / Basic / Tech. Assistance

ON STREAM
1983 1983

Ammonium Sulphate (Struthers Wells)

366

Engineering / Procurement / Construction License / Engineering / Procurement Licence / Engineering / Procurement

1983 1983 1982

License / Engineering / Procurement

1982

Engineering / Procurement / Construction License / Basic / Tech. Assistance

1982 1982

License / Engineering / Supervision License / Engineering / Procurement License / Engineering / Supervision

1982 1980 1980

License / Basic / Tech. Assistance

1980

39

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location USA, Borger, Texas CIS, Novomoskovsk Germany, Bösterreichische Iraq, Khor Al-Zubair Italy, Manfredonia Austria, Linz Iraq, Basrah USA, Memphis, Tennessee USA, Lawrence, Kansas Italy, Ravenna AGRIUM U.S. Inc. NOVOMOSKOVSK AZOT YARA BÖSTERREICHISCHE GmbH MINISTRY OF INDUSTRY AND MINERALS ENICHEM AGRICOLTURA S.p.A. AGROLINZ MELAMIN GmbH MINISTRY OF INDUSTRY AND MINERALS PCS NITROGEN FARMLAND FERTILIZER/Ag CHEMICAL ANIC S.p.A.

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 250 1500 1000 2x 1600 1000 1000 1300 1000 600

Italy, Manfredonia

ENICHEM AGRICOLTURA S.p.A.

Haldor Topsøe A/S, Giammarco Vetrocoke

1200

1000 750

Venezuela, Moron

SERVIFERTIL

40

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Basic / Tech. Assistance License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Supervision License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance

ON STREAM
1980 1979 1979 1979 1978 1977 1976 1975 1974

Ammonium Sulphate (Ici) Calcium Nitrate (Pintsch Bamag)

1400 200 License / Basic / Tech. Assistance 1973

License / Engineering / Supervision NPK (Dorr Oliver) 920 Engineering / Procurement / Construction

1972

1972

41

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Italy, Nera Montoro Mexico, Minatitlan Spain, Puertollano Syria, Homs TERNI INDUSTRIE CHIMICHE S.p.A. FERTIMINA S.A. EMPRESA NACIONAL DE FERTILIZANTES S.A. GENERAL ORGANIZATION FOR EXECUTING INDUSTRIAL PROJECTS (GOEIP) Ici 150 MT/D

CLIENT

AMMONIA
License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 300 750 300

Italy, Gela Russia, Tula

ENICHEM AGRICOLTURA S.p.A. V/O TECHMASHIMPORT Air Liquide, Ammonia Casale

70

430

Italy, Pisticci

ANIC S.p.A.

Romania, Victoria

INDUSTRIAL IMPORT

42

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK
License / Engineering / Supervision License / Engineering / Procurement License / Engineering / Procurement

ON STREAM
1971 1971 1971

Engineering / Procurement / Construction

1971

License / Engineering / Procurement Methanol (Ammonia Casale) from 720 MT/D Methanol (Ammonia Casale) 170 Methanol (Ammonia Casale) 90 Engineering / Procurement

1966

Engineering / Procurement

1966

Engineering / Supervision

1964

1963

43

SNAMPROGETTI UREA TECHNOLOGY REVAMP REFERENCES
WITH THE OBJECTIVE OF IMPROVING THE ECONOMICS AND ENVIRONMENTAL IMPACT OF PLANTS BUILT EARLIER MOSTLY ON SNAMPROGETTITM UREA TECHNOLOGY, SAIPEM HAS INTRODUCED SEVERAL NEW SOLUTIONS IN ORDER TO EXPAND THEIR PRODUCTION CAPACITY, MODERNIZE THEIR HARDWARE AND ENHANCE THEIR OPERABILITY AND RELIABILITY.

TM

Main revamp undertakings: Updated process scheme Energy optimization Improvement of product quality Reduction of emissions Improved metallurgy Saipem has developed a successful revamp methodology to meet client’s expectations: Continuous assistance during the development of the project and the lifetime of the plant. Identification of client’s needs through feasibility studies. Definition of the appropriate and economically viable revamp process scheme.
44

Development of a process design package and supply of the relevant services (licensor technical assistance during detailed engineering, commissioning and start-up) to allow an effective implementation. Based on this approach, almost twenty revamps have been implemented during the last few years, mainly in India, Pakistan and P.R. China, resulting in a typical capacity increase between 30 and 70%, as well as in a significant reduction in energy consumption.

45

SNAMPROGETTITM UREA TECHNOLOGY REVAMP REFERENCES

LOCATION
Country, Location China, Hejiang, Sichuan India, Babrala, U.P. India, Hazira, Gu. India, Aonla, U.P. India, Bharuch, Gu. India, Gadepan, Ra. India, Phulpur, U.P. India, Phulpur, U.P. Pakistan, Mirpur Mathelo India, Namrup India, Namrup India, Thal Vaishet, Ma. India, Hazira, Gu. India, Jagdishpur, U.P.

CLIENT

ORIGINAL PROCESS

SICHUAN TIANHUA Co., Ltd. TATA (FERTILIZER DIVISION) CHEMICALS Ltd. KRISHAK BHARATI COOP. Ltd. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. CHAMBAL FERTILIZERS AND CHEMICALS Ltd. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. FAUJI FERTILIZER COMPANY Ltd. HINDUSTAN FERTILIZER COMPANY Ltd. HINDUSTAN FERTILIZER COMPANY Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. KRISHAK BHARATI COOP. Ltd. INDO GULF Co., Ltd.

SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM Montedison Montedison SnamprogettiTM SnamprogettiTM SnamprogettiTM

46

ORIGINAL NOMINAL CAPACITY
(MT/D) 1765 2x 1125 4x 1300 4x 1100 2350 2x 1125 1550 2x 1100 1740 2x 500 1167 3x 1500 4x 1100 2x 1100

CAPACITY AFTER REVAMPING
(MT/D) 2300 2x 1900 4x 1660 4x 1515 2350 energy efficiency improvement 2x 1750 2115 2x 1515 2175 2x 500 1167 3x 1900 4x 1300 2x 1500

ON STREAM
Year Under Exec. Under Exec. Under Exec. 2008 2008 2008 2008 2008 2008 2005 2002 2002 2001 2001

47

SNAMPROGETTITM UREA TECHNOLOGY REVAMP REFERENCES

LOCATION
Country, Location Canada, Red Water, Alberta Pakistan, Goth Machhi Spain, Puertollano Germany, Brunsbüttel India, Bharuch, Gu. Pakistan, Multan USA, Memphis, Tennessee USA, Lawrence, Kansas Austria, Linz Italy, Nera Montoro

CLIENT

ORIGINAL PROCESS

AGRIUM U.S. Inc. FAUJI FERTILIZER COMPANY Ltd. EMPRESA NACIONAL DE FERTILIZANTES S.A. YARA BRUNSBUTTEL GmbH GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. PAKARAB FERTILIZERS Ltd. PCS NITROGEN FARMLAND FERTILIZER/Ag CHEMICAL AGROLINZ MELAMIN GmbH TERNI INDUSTRIE CHIMICHE S.p.A.

SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM Inventa SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM

48

ORIGINAL NOMINAL CAPACITY
(MT/D) 1500 1725 300 1000 1800 150 1000 600 1000 300

CAPACITY AFTER REVAMPING
(MT/D) 2100 2105 400 1400 2350 300 1250 720 1300 360

ON STREAM
Year 1996 1992 1991 1990 1990 1986 1983 1982 1980 1980

49

UREA PLANTS BASED ON CONVENTIONAL AND I.D.R. PROCESSES
SAIPEM IS THE OWNER OF THE FORMER MONTEDISON UREA TECHNOLOGY. COMPANY
ZAKLADY AZOTOWE PULAWY AGRIMONT C.N.C.C.C. TECHMASHIMPORT QUIMIGAL FERTIMONT. TECHMASHIMPORT THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. TECHMASHIMPORT THE FERTILIZER CORP. OF INDIA Ltd. MONTEDISON

LOCATION
Poland, Pulawy Italy, Ferrara China, Luzhou Russia, Berezniki Portugal, Lavradio Italy, San Giuseppe di Cairo Russia, Kemerovo India, Ramagundam India, Talcher India, Sindri India, Haldia Ukraine, Gorlovka India, Nangal Italy, Ferrara

CAPACITY T/D UREA
1700 1700 750 1500 Rev. to 270 300 1500 1500 1500 1000 500 1500 1000 1500

START-UP
1994 1989 1988 1982 1982 1981 1981 1979 1979 1979 1979 1979 1978 1977

50

COMPANY
THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. KIROVAKAN CHIM THE FERTILIZER CORP. OF INDIA Ltd. THE FERT. & CHEM. TRAVANCORE C.N.A. (Compagnie Neerlandaise de l’Azote) MONTEDISON C.N.A. (Compagnie Neerlandaise de l’Azote) MONTEDISON VETROCOKE NEYVELI LIGNITE C.N.A. (Compagnie Neerlandaise de l’Azote)

LOCATION
India, Nampur India, Rarauni Russia, Kirovakan Chim India, Durgapur India, Cochin

CAPACITY T/D UREA
1000 1000 54 1000 1000

START-UP
1976 1976 1973 1973 1973

The Netherlands, Sluiskil Italy, Castellanza

1100 450

1970 1968

The Netherlands, Sluiskil Italy, San Giuseppe di Cairo Italy, Porto Marghera India, Neyveli

700 450 250 500

1968 1967 1967 1965

The Netherlands

330

1965

51

UREA PLANTS BASED ON CONVENTIONAL AND I.D.R. PROCESSES

COMPANY
NISSAN CHEM. IND. COLOMBIANA DE FERTILIZANTES OESTERREISCHICHE STICKSTOFFWERKE MINISTRY OF MINES FERT. CORP. MONTEDISON MONTEDISON UNIAO FABRIL AZOTO IST. VENEZOLANO DE PETROQUIMICA OFFICE NATIONAL IND. DE L’AZOTE PIERREFITTE STE’ GENERALE D’ENGRAIS ET PRODUITS CHIMIQUES AZOLACQ VETROCOKE C.N.A. (Compagnie Neerlandaise de l’Azote) C.N.A. (Compagnie Neerlandaise de l’Azote)

LOCATION
Japan, Toyama Colombia, Barranca Austria, Linz Iran, Shiraz Italy, Novara Italy, Novara Portugal, Lisboa Venezuela, Moron France, Toulouse

CAPACITY T/D UREA
60 30 80 120 70 43 150 50 200

START-UP
1965 1964 1963 1963 1963 1963 1963 1963 1962

France, Pierrefitte France, Pardies Italy, Porto Marghera

120 120 125

1962 1962 1962

The Netherlands, Sluiskil

200

1962

The Netherlands, Sluiskil

180

1962

52

COMPANY
ARMOUR SUN OLIN CHEM. SPENCER CHEM. FINALENS BEFU CHEM. OESTERREISCHICHE STICKSTOFFWERKE SINDRI FERTILIZERS MITSUBISHI CHEM. TOKAI AMM. SULPH. MITSUBISHI CHEM. UBE IND. NISSAN CHEM. SPENCER CHEM. OFFICE NATIONAL IND. DE L’AZOTE MONTEDISON

LOCATION
U.S.A., Cherokee U.S.A., North Claymont U.S.A., Henderson France, La Bassé Japan, Befu

CAPACITY T/D UREA
45 200 100 70 100

START-UP
1962 1960 1959 1959 1959

Austria, Linz India, Sindri Japan, Kurosaki Japan, Yekkaichi Japan, Kurosaki Japan, Ube Japan, Toyama U.S.A., Vicksburg France, Toulouse Italy, Ferrara

40 70 60 200 60 100 50 30 100 200

1958 1958 1958 1958 1957 1957 1957 1957 1956 1956

53

UREA PLANTS BASED ON CONVENTIONAL AND I.D.R. PROCESSES

COMPANY
MITSUBISHI CHEM. KIOWA HAKKO SHELL CHEM. NISSAN CHEM. MONTEDISON MONTEDISON STAATSMIJINEN HOLZVERZUCHERRUNGS MONTEDISON STOCK, SUPERFOSFAT MONTEDISON

LOCATION
Japan, Korodaki Japan, Ube U.S.A., Ventura Japan, Toyama Italy, Ferrara Italy, Novara The Netherlands, Lutterada Switzerland, Ems Italy, San Giuseppe di Cairo Sweden, Ljiungavark Italy, Novara

CAPACITY T/D UREA
60 80 100 50 100 120 2 10 30 2 6

START-UP
1956 1956 1956 1953 1953 1953 1945 1945 1939 1938 1935

54

55

OTHER FERTILIZERS, RELATED UNITS AND GAS-BASED PRODUCTS
SAIPEM HAS FURTHER REFERENCES IN DESIGNING AND BUILDING PLANTS TO PRODUCE OTHER FERTILIZERS AND ASSOCIATED PRODUCTS.

AMMONIUM NITRATE AMMONIUM SULPHATE GRANULATED CALCIUM AMMONIUM NITRATE CO PRODUCTION DIAMMONIUM PHOSPHATE (DAP) HYDROGEN PRODUCTION NITRIC ACID NPK PHOSPHATE GRANULATION PHOSPHATE ROCK GRINDING PHOSPHORIC ACID SULPHURIC ACID TRIPLE SUPER PHOSPHATE

56

People, ideas, energy.
Saipem S.p.A. Via Martiri di Cefalonia, 67 - 20097 San Donato Milanese, Milan - Italy Tel. +39.02.520.1 - Fax +39.02.520.44415 www.saipem.eni.it - A subsidiary of Eni S.p.A.

07.2009

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