SYLLABUS FOR CSIR (CHEMICAL SCIENCES

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PHYSICAL CHEMISTRY:1) BASIC PRINCIPLES AND APPLICATIONS OF QUANTUM MECHANICS HYDROGEN ATOM, ANGULAR MOMENTUM. 2) VARIATIONAL AND PERTURBATIONAL METHODS. 3) BASICS OF ATOMIC STRUCTURE, ELECTRONIC CONFIGURATION, SHAPES OF ORBITALS, HYDROGEN ATOMSPECTRA. 4) THEORETICAL TREATMENT OF ATOMIC STRUCTURES AND CHEMICAL BONDING. 5) CHEMICAL APPLICATIONS OF GROUP THEORY. 6) BASIC PRINCIPLES AND APPLICATIONS SPECTROSCOPY-ROTATIONAL, VIBRATIONAL, ELECTRONIC, RAMAN, ESR, NMR. 7) CHEMICAL THERMODYNAMICS. 8) PHASE EQUILIBRIA. 9) STATISTICAL THERMODYNAMICS. 10) CHEMICAL EQUILIBRIA. 11) ELECTROCHEMISTRY-NERNST EQUATION, ELECTRODE KINEETICS, ELECTRICAL DOUBLELAYER, DEBYEHUCKEL THEORY. 12) CHEMICAL KINETICS-EMPIRICAL RATE LAWS, ARRHENIUS EQUATION, THEORIES OF REACTION RATES, DETERMINATION OF REACTION MECHANISMS, EXPERIMENTAL TECHNIQUES FOR FAST REACTIONS. 13) CONCEPT OF CATALYSIS. 14) POLYMER CHEMISTRY-MOLECULAR WEIGHTS AND THEIR DETERMINATIONS, KINETICS OF CHAINPOLYMERISATION. 15) SOLIDS-STRUCTURAL CLASSFICATION OF BINARY AND TERNERY COMPOUNDS, DIFRACTION TECHNIQUES, BONDING, THERMAL, ELECTRICAL AND MAGNATIC PROPERTIES. 16) COLLIDS AND SURFACE PHENOMENA. 17) DATA ANALYSIS.

INORGANIC CHEMISTRY :18) CHEMICAL PERIODICITY. 19) STRUCTURE AND BONDING IN HOMO AND HETERO NUCLEAR MOLECULES, INCLUDING SHAPES OF MOLECULES. 20) CONCEPTS OF ACIDS AND BASES. 21) CHEMISTRY OF MAIN GROUPELEMENTS AND THEIR COMPOUNDS.ALLOTROPHY, SYNTHESIS, BONDING, AND STRUCTURE. 22) CHEMISTRY OF TRANSITION ELEMENTS AND COORDINATIOIN COMPOUNDS-BONDING THEORIES, SPECTRAL AND MAGNATIC PROPERTIES, REACTION MECHANISMS. 23) INNER TRANSITION ELEMENTS-SPECTRAL AND MAGNATIC PROPERTIES, ANALYTICAL APPLICATIONS.

NITROZEN FIXATATION. BONDING. PORPHYRINES. 29) NUCLEAR CHEMISTRY-NUCLEAR REACTIONS. FREE RADICAL REACTIONS. 28) PHYSICAL CHARACTERIZATION OF INORGANIC COMPOUNDS BY IR. 26) ANALYTICAL CHEMISTRY-SEPERATION TECHNIQUES. NQR. REGIOSELECTIVITY. CATALYSIS AND GREEN CHEMISTRY. CONFORMATIONAL ANALYSIS. REACTIONS INVOLVING NUCLEOPHOTIC CARBON INTERMEDIATES. RADIO ANALYTICAL TECHNIQUES. OXIDATION AND REDUCTION OF FUNCTIONAL GROUPS. NMR. 27) BIO INORGANIC CHEMISTRY-PHOTOSYSTEMS. UV. AND ACTIVATION ANALYSIS. STEREOSELECTIVITY. OXYGEN TRANSPORT. ALKALOIDS. ISOMERISM AND CHIRALITY. ORGANOMETALLICS IN HOMOGENIOUS CATALYSIS. INORGANIC AND ORGANOMETALLIC) IN ORGANIC SYNTHESIS. 43) CHEMISTRY OF AROMATIC AND ALIPHATIC HETEROCYCLIC COMPOUNDS. INTERDESIPLINARY TOPICS :45) 46) 47) 48) 49) CHEMISTRY IN NANOSCIENCE AND TECHNOGY. AND REACTIVITY. REACTIVE INTERMEDIATES AND ORGANIC REACTION MECHANISMS.24) ORGANO METALLIC COMPOUNDS-SYNTHESIS. PEPTIDES. NUCLEIC ACIDS AND LIPIDS. MS. CARBOHYDRATES. ENVIRONMENTAL CHEMISTRY. SPECTROSCOPIC. ELECTROCHEMICAL AND THERMO ANALYTICAL METHODS. CHEMISTRY OF NATURAL PRODUCTS SUCH AS STEROIDS. PROTECTING GROUPS. RAMAN. COMMON REAGENTS (ORGANIC. NMR. ELECTRON SPECTROSCOPY AND MACROSCOPIC TECHNIQUES. ELECTRON TRANSFER REACTIONS. . NAMED REACTIONS. 44) PHYSICAL CHARACTERIZATION OF ORGANIC COMPOUNDS BY IR. MEDICINAL CHEMISTRY. EPR. PRINCIPLES OF STEREO CHEMISTRY. TRANSFORMATIONS AND REARRANGEMENTS. 25) CAGES AND METAL CLUSTERS. AND. MS. METALLOENZYMES. PERICYCLIC REACTIONS. CONCEPTS OF AROMATICITY. AND STRUCTURE. FISSION. ORGANIC CHEMISTRY :30) 31) 32) 33) 34) 35) 36) 37) 38) 39) 40) 41) IUPAC NOMENCLATURE OF ORGANIC COMPOUNDS. 42) SELECTIVE ORGANIC TRANSFORMATIONS-CHEMOSELECTIVITY. PRINCIPLES AND APPLICATIONS OF ORGANIC PHOTOCHEMISTRY. UV. FUSION. ENANTIOSELECTIVITY. TERPHENES. SUPRAMOLECULAR CHEMISTRY. MOSSBAUER.

SYLLABUS FOR CSIR (CHEMICAL SCIENCES) .

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