1H

NMR Spectroscopy
Advanced Topics

Fourier Transformation

Ferromagnetic Impurity (above)

300 vs. 600 MHz

Induced Fields

Benzene Deshielding

Carbonyl Deshielding

Alkyne Shielding

cis or trans?
Look at J value for vinyl doublets

E- and F-Glucopyranose

First-Order Doublets
(R/J > 8

Non First-Order Doublets
(R/J = 2

%&coupling (RJ in Hz
Ha C C Hb

Butanal

O CH3CH2CH2CH td

offset 8 ppm

Styrene

Allyl Alcohol

Cumene

Methine H in Isopropyl Group
a quartet of quartets

qq results in 7 lines
ignal rea t 6J

Triplet of triplets (J = 10; J = 5)
Intensity Ratios are Different

dqd (J = 12; J = 7; J = 4)

Quartet at H 25.0, 300 MHz
each ppm is 75 Hz
H 25.0

150

150

150

H 22.0 (q, J=150), H 25.0 (q, J=150)
(at 300 MHz)
H 25.0
(R = 225

H 22.0
z

150

150

150

At 600 MHz«
H 25.0 (R = 450 z H 22.0

150

150

150

150

150

150