Professional Documents
Culture Documents
Structural Materials/
Electronic Ceramics
Structural Materials/
Electronic Ceramics
Carbon Based Materials . . . . . . . . . . . . . . . . . . . . . . .450 Engineering Polymers . . . . . . . . . . . . . . . . . . . . . . . . .462
Fullerenes & Carbon Nanotubes: Polyamides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .462
See Nanomaterials . . . . . . . . . . . . . . . . . . . . . . . .379 Polyesters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463
Ceramics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451 Polyimides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463
Carbides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451 Polysulfones . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463
Nitrides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451 Polysilsesquioxanes:
Oxides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .452 See Nanomaterials . . . . . . . . . . . . . . . . . . . . . .393
Ceramic Oxides . . . . . . . . . . . . . . . . . . . . . . . .452 Photooxidative Stabilizers for Polymers . . . . . . . . . . .464
Metallic Oxides . . . . . . . . . . . . . . . . . . . . . . . .453 HALS (Hindered Amine Light Stabilizers) . . . . . . . . . .468
Metal-Oxide Nanopowders:
See Ceramic Nanopowders . . . . . . . . . . . .376
Sulfides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .459
Ceramic Sulfides . . . . . . . . . . . . . . . . . . . . . . .459
Metallic Sulfides . . . . . . . . . . . . . . . . . . . . . . . .460
Wide Band-Gap Semiconductors:
See Materials for Thin Films/Microelectronics . . .348
450
Ceramics
Carbon Based Materials
Ceramics are nonmetallic, inorganic materials typically formed as
powders and often sintered into useful forms. They encompass a wide Activated charcoal
range of structures from amorphous to polycrystalline or even single (Charcoal activated)
crystals. They are typically very hard but rigid, and tend to break under CAS No. 7440-44-0
www.sigma-aldrich.com/safc
mechanical stress. Since they are nonmetallic, they are usually electrically C FW 12.01
nonconductive or wide band-gap semiconductors but can be doped to
decrease the band-gap to the semiconductor regime. They are often . . . . . . . . . . . . . . . . . . . . . . . . . . . .
noted for their thermal stability at high temperatures. 48,415-6 glassy, spherical powder, 10-40 mm, 10 g
99.99+% 50 g
S: 22-24/25
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Silicon carbide for example has excellent high-temperature
48,416-4 glassy, spherical powder, 2-12 mm, 10 g
characteristics but due to its brittleness has limited utility as a structural
99.99+% 50 g
material. Micron-thin coatings of alumina (Al2O3) on SiC platelets gives a S: 22-24/25
composite which is 2–3 times stronger than traditional SiC ceramics. The . . . . . . . . . . . . . . . . . . . . . . . . . . . .
result is a stress- and oxidation-resistant material for high-temperature 39,012-7 Purified by from resistive heating of 1g
structural applications.1 Silicon carbide is also used to enhance the graphite 5g
properties of other structural materials. Titanium composites inlaid with Fullerene yield 5-10% 25 g
SiC monofilaments yield a stiff, strong, thermally stable structural R: 10-36/37/38 S: 26-36
material used in aircraft components.2
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
Diamond
Alumina is a common and versatile structural ceramic due to its CAS No. 7782-40-3
R: 43 S: 36
chemical, electrical, mechanical, and thermal properties. It possesses . . . . . . . . . . . . . . . . . . . . . . . . . . . .
poor fracture resistance, however. The addition of yttria stabilized 48,357-5 natural monocrystalline powder, 1 mm, 1 g
zirconia to alumina significantly improves the fracture toughness of 99.9% 5g
Al2O3.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,359-1 synthetic monocrystalline powder, 1 mm, 1 g
99.9% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,360-5 synthetic monocrystalline powder, 1g
50 mm, 99.9% 5g
Engineering Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,358-3 synthetic polycrystalline powder, 1 mm, 1 g
Enginnering polymer are materials with exceptional mechanical 99.9% 5g
properties such as stiffness, toughness, and low creep that makes them
valuable in the manufacture of structural products like gears, bearing, Graphite
electronic devices, and auto parts.4-6 Typical engineering plastics include
CAS No. 7782-42-5
acetals, polyamides, poly(amide-imide)s, polyarylates, poly(ether
C FW 12.01
etherketone)s, poly(ether-imides)s, poly(phenylene oxide)s,
poly(phenylene sulfide)s, and polysulfones.7 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,246-1 flake 2.5 kg
R: 36/37 S: 22-26-36 12 kg
Polyamides are crystalline and have good impact strength, toughness, . . . . . . . . . . . . . . . . . . . . . . . . . . . .
and abrasion resistance. Polyesters are often used with fillers like 49,653-7 rod, length 150 mm, diam. 3 mm, 43.5 g
fiberglass, mica, and minerals to increase strength and stiffness. Sulfone- 99.999%, low density
R: 36/37 S: 26-36
containing polymers show high resistance to acids and alkalis. These . . . . . . . . . . . . . . . . . . . . . . . . . . . .
thermally stable polymers are used in electronic connectors, circuit 49,654-5 rod, diam. 3 mm, length 150 mm, 60 g
boards, sterilizable items, and appliance covers.8 Polyimides have 99.995%
outstanding thermal properties. Additionally, thermoplastics, R: 36/37 S: 26-36
thermosets, and rubbers have significant applications as engineering . . . . . . . . . . . . . . . . . . . . . . . . . . . .
polymers.9 49,655-3 rod, length 150 mm, diam. 6 mm, 180.7 g
99.999%
Density. . . . . . . . . . . . . . . . . . . . . . . . (low density) (lit.)
References (1) http://www.lbl.gov/msd/PIs/DeJonge/94Hi.html
R: 36/37 S: 26-36
(accessed 3/31/03). (2) Williams, J.C. The Production, Behavior and . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Application of Ti Alloys, pp 85-134; In High Performance Materials in 49,656-1 rod, length 150 mm, diam. 6 mm, 240.5 g
Aerospace; Flower, H.M., ed.; Chapman & Hall, London; 1995. (3) 99.995%
Mangalaraja, R.V. et al. Mat. Sci. Eng. A 2003, 343, 71. (4) Alger, Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2 g/mL (lit.)
M.S.M., Ed. Polymer Science Dictionary; Elsevier Science: New York, R: 36/37 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1989. (5) Seymour, R.B.; Carraher, C.E., Jr. Polymer Chemistry: An
49,659-6 powder, -325 mesh, 99.999% 113.4 g
Introduction, 3rd ed.; Marcel Dekker: New York, 1992; p 243. (6) Odian, R: 36/37 S: 22-26-36
G. Principles of Polymerization, 3rd ed.; John Wiley & Sons, 1991; p100. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(7) Stevens, M.P. Polymer Chemistry: An Introduction, 2nd ed.; Oxford 49,658-8 powder, -100 mesh, 99.99+% 113.4 g
R: 36/37 S: 22-26-36
451
Carbon Based Materials
Structural Materials/
Electronic Ceramics
Fullerenes Page 379 CAS No. 409-21-2
SiC FW 40.10
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.22 g/mL (lit.)
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ceramics 35,739-1 -400 mesh 250 g
hexagonal phase 1 kg
For wide band-gap semiconductors See: Semiconductors Page 348 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
For an application overview and listing of ultra-pure inorganics and 37,809-7 200-450 mesh 250 g
metals for high-technology please request your copy of the AAPL, 1 kg
Aldrich-APL brochure.
Tantalum carbide
800.558.9196 (USA)
27,029-6 CAS No. 75-20-7 25 g
33,635-1 CAS No. 12070-14-3 50 g
C2Ca FW 64.10 500 g
CHZr FW 104.2 250 g
~80%, pieces, Technical Grade, 2 kg
powder, 5 mm, 99%
thickness ca. 8 mm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.22 g/mL (lit.) cubic phase
R: 15 S: 8-43 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.73 g/mL (lit.)
R: 11-20/21/22 S: 16-27-33-36/37/39
Chromium carbide
40,268-0 CAS No. 12012-35-0 50 g
Nitrides Ordering/Pricing: www.sigma-aldrich.com
Cr3C2 FW 180.0 250 g Aluminum nitride nanopowder See: Ceramic Nanopowders Page
376
-325 mesh
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ceramic Oxides 34,275-0 Primarily a-phase, sintered, pieces, 50 g
3 mm, 99.8% 250 g
Aluminum oxide Suitable for vacuum deposition.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.)
(Alumina) R: 37 S: 22-36
CAS No. 1344-28-1 Other aluminum oxides See: Mesoporous Molecular Sieves Page 377
Al2O3 FW 102.0
For column chromatography Calcium carbonate
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,260-6 99.998% 5g
Density. . . . . . . . . . . . . . . 3.97 g/mL (lit.) 20 g
CAS No. 471-34-1
R: 37 S: 22-36 CaCO3 FW 100.1
100 g R: 37/38-41 S: 26-39
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,271-8 calcined, powder, Primarily a-phase, 100 g 48,180-7 99.999+% 5g
99+%, 100-325 mesh solid 25 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.)
mp . . . . . . . . . . . . . . . ~800 C (dec.) (lit.)
R: 37 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.93 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,272-6 calcined, powder, Primarily a-phase, 100 g 20,293-2 99.995+% 5g
150-325 mesh Density. . . . . . . . . . . . . . . 2.93 g/mL (lit.) 25 g
R: 37 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,269-6 Primarily a-phase, calcined, 100- 100 g
39,810-1 chelometric standard, ACS reagent, 100 g
400 mesh, 99+%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.)
99.95-100.05% as dry basis 500 g
NH4OH pptd.. . . . . . . . . . . . . . . . £0.01%
R: 37 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . insol. dil. HCl. . . . . . . . . . . . . . . . . . . . . . . . . . .£0.01%
23,474-5 Corundum, a-phase, -100 mesh, 99% 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.93 g/mL (lit.)
Density. . . . . . . . . . . . . . . 3.97 g/mL (lit.) 500 g Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
R: 37 S: 22-36 F-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.0015%
2.5 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
34,274-2 fused, 99.99%, 6-12 mesh 25 g Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
Suitable for vacuum deposition. 250 g
Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Primarily a-phase K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.)
Mg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
R: 37 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
34,276-9 fused, pieces, 3-12 mm, 99.99% 25 g Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.1%
Suitable for vacuum deposition.
Primarily a-phase
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.)
R: 37 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,268-8 fused, powder, Primarily a-phase, - 100 g
325 mesh, 10 mm, 99+% 1 kg
Density. . . . . . . . . . . . . . .3.97 g/mL (lit.)
R: 37 S: 22-36
453
Ceramics
Oxides: Ceramic Oxides
25,650-1 low in alkalies, 99+%, ACS reagent 100 g 34,277-7 fused, chips, -4 mesh, 99.9% 25 g
99.0+% 500 g Suitable for vacuum deposition. 100 g
NH4OH pptd.. . . . . . . . . . . . . . . . £0.01% Density. . . . . . . . . . . . . . . 3.58 g/mL (lit.)
Structural Materials/
Electronic Ceramics
Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
F-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.0015% 34,279-3 -325 mesh, 99+% (Purity based on 250 g
SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% metallic impurity content.) 1 kg
Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% Weight of unit is 10% in excess of stated
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002% weight
Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . £0.001% Loss on ignition. . . . . . 10%, 1000C (absorbed H2O and CO2)
K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Mg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% 34,282-3 fused, -40 mesh, 99+% 100 g
Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% Density. . . . . . . . . . . . . . . .3.58 g/mL (lit.)
Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.1% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
insolubles (6.67% dil. HCl). . . . . . . . . . . . . . . . . . £0.01% 34,281-5 fused, 95+%, 150-325 mesh 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Suitable for plasma spraying
23,921-6 powder, ‡99.0%, ACS reagent 100 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.58 g/mL (lit.)
insol. dil. HCl. . . . . . . . . . . . £0.01% 500 g
water-soluble titr. Base. . .£0.002 meq/g 6 · 500 g Silicon dioxide
800.558.9196 (USA)
solid
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.22 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 22 38,126-8 99.8% 100 g
May contain adsorbed H2O and CO2 500 g
Indium(III) oxide which is removable by calcining at >900C
surface area. . . . . . . . . . . . . . . . . . . . . . . . . . 380 m2/g
CAS No. 1312-43-2
In2O3 FW 277.6
Vapor pressure. . . . . . . . . . . . . . . . . . . . <0.01 mm Hg ( 25 C) Silicon monoxide
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 33,682-3 CAS No. 10097-28-6 10 g
Ordering/Pricing: www.sigma-aldrich.com
20,342-4 99.999% 5g SiO FW 44.08 100 g
Density. . . . . . . . . . . . . . . 7.179 g/mL (lit.) 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . pieces, 3-6 mm, 99.99%
R: 36/37/38 S: 26-36
28,941-8 99.99% 10 g
50 g
Thallium(III) oxide
Magnesium oxide 21,474-4 CAS No. 1314-32-5 50 g
CAS No. 1309-48-4 Tl2O3 FW 456.8 250 g
MgO FW 40.30 99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 717 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 26/28-33-51/53 S: 13-28-45-61
52,969-9 99.999% 10 g
solid 50 g
Density. . . . . . . . . . . . . . . . 3.58 g/mL (lit.) Metallic Oxides
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Metal-oxide nanopowders See: Ceramic Nanopowders Page 376
20,371-8 99.99% 5g
Density. . . . . . . . . . . . . . . 3.58 g/mL (lit.) 25 g
100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,278-5 fused, pieces, 3-12 mm, 99.95% 25 g
454
Ceramics
Oxides: Metallic Oxides
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,834-1 90% 100 g
28,849-7 97% 5g Density. . . . . . . . . . . . . . . .7.13 g/mL (lit.) 500 g
adsorbed H2O/CO2. . . . . . . . . . . . . . 1-4% 50 g
250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Chromium(III) oxide
22,360-3 Technical Grade, 90% 25 g
500 g CAS No. 1308-38-9
2 kg Cr2O3 FW 152.0
Used in a solid-state reaction to form the new ternary oxide,
Barium strontium tungsten oxide CrVMoO7, which should find application in selective oxidation.
Its crystal structure was also determined.
41,516-2 CAS No. 14871-56-8 25 g R: 20/21/22-36/37/38-43 S: 26-37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ba2SrWO6 FW 642.1 100 g 20,306-8 99.9% 5g
99.8% Density. . . . . . . . . . . . . . . . 5.21 g/mL (lit.) 25 g
R: 20/22 S: 28 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
Structural Materials/
Electronic Ceramics
CAS No. 1317-38-0 HfO2 FW 210.5
CuO FW 79.55 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9.68 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . S: 22-24/25
45,080-4 powder, 99.995% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . 6.315 g/mL (lit.) 50 g 20,339-4 99.95+% 1g
5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,545-7 99.99+% 10 g 20,211-8 powder, 98% 25 g
Density. . . . . . . . . . . . . . . 6.32 g/mL (lit.) 100 g 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,081-2 powder, 99.99% 25 g Holmium(III) oxide
Density. . . . . . . . . . . . . . .6.315 g/mL (lit.) 100 g
(Rare earth)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 12055-62-8
800.558.9196 (USA)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36
28,922-1 99.9% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5g 19,992-3 99.99% 5g
25 g Density. . . . . . . . . . . . . . . 6.51 g/mL (lit.) 100 g
500 g
Gadolinium oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,161-3 99.9% 250 g
CAS No. 12064-62-9 Density. . . . . . . . . . . . . . .6.51 g/mL (lit.) 1 kg
Gd2O3 FW 362.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
S: 22-24/25 28,920-5 meets analytical specification of 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Ph Eur, BP, USP, FCC, E252, 99.9+% 250 g Ordering/Pricing: www.sigma-aldrich.com
20,329-7 99.99+% 5g Suitable for use as atomic absorption
Density. . . . . . . . . . . . . . . 7.407 g/mL (lit.) 25 g standard.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
27,851-3 99.9% 10 g Lead(IV) oxide
25 g
100 g 51,813-1 (Lead dioxide; Lead (su)peroxide; Lead 10 g
peroxide) 50 g
Gold(III) oxide hydrate CAS No. 1309-60-0
PbO2 FW 239.2
33,405-7 CAS No. 1303-58-8 500 mg
99.999%
Au2O3 xH2O FW 441.9 2.5 g
solid
Au 85-86% R: 61-20/22-33-50/53-62 S: 53-45-60-61
R: 36/38 S: 26-36
456
Ceramics
Oxides: Metallic Oxides
Structural Materials/
Electronic Ceramics
surface area. . . . . . . . . . . . . . . . . . . . . . . . . .~800 m2/g
Rhenium(IV) oxide
Osmium tetroxide
CAS No. 12036-09-8
20,103-0 (Osmium(VIII)-oxide; ’Osmic acid’) 250 mg O2Re FW 218.2
CAS No. 20816-12-0 500 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
OsO4 FW 254.2 1g 51,572-8 99.995% 1g
99.8% solid
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Promotes oxidative cleavage of graphene layers in carbon 34,225-4 99.7% 1g
nanotubes creating the possibility of opening ¢windows¢ in 5g
fullerene cages.
Packaged in ampules Rhenium(VI) oxide
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 8.8 (vs air)
Vapor pressure. . . . . . . . . . . . . . . . . . . 7 mm Hg ( 20 C)
800.558.9196 (USA)
5g CAS No. 12036-35-0 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
52,074-8 Engelhard code S3154, 99.9+% 1g Rh2O3 FW 253.8
solid 5g 99.8%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.2 g/mL (lit.)
Pd 85-87%
20,629-6 Rhodium(III) oxide hydrate 1g
52,075-6 Palladium(II) oxide hydrate 1g
CAS No. 123542-79-0
CAS No. 64109-12-2 5g
Rh 55%
PdO aq FW 122.4
Engelhard code S3115, 99.9+%
Rhodium(IV) oxide
solid Ordering/Pricing: www.sigma-aldrich.com
5g Tm2O3 FW 385.9
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/37/38 S: 26-36
47,091-0 fused, tablet, diam. 10 mm, 99.99+% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5g 20,467-6 99.99% 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5g
30,787-4 99.9% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5g 28,916-7 99.9% 1g
5g
Silver(I) oxide
Tin(II) oxide
CAS No. 20667-12-3
Ag2O FW 231.7 51,817-4 CAS No. 21651-19-4 5g
R: 37 S: 36 SnO FW 134.7 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
99.99%
22,683-1 99.99+% 1g
Density. . . . . . . . . . . . . . . 7.143 g/mL (lit.)
solid
5g
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,116-3 99% 10 g Tin(IV) oxide
Density. . . . . . . . . . . . . . . 7.22 g/mL (lit.) 50 g
24,465-1 (Stannic oxide) 100 g
250 g
CAS No. 18282-10-5 500 g
Silver(II) oxide SnO2 FW 150.7 2 kg
-325 mesh, 99.9%
22,363-8 CAS No. 1301-96-8 10 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.95 g/mL (lit.)
AgO FW 123.9 50 g
Density. . . . . . . . . . . . . . . 7.483 g/mL (lit.)
R: 8-36/37/38 S: 26-36 Tungsten(IV) oxide
Structural Materials/
Electronic Ceramics
V2O5 FW 181.9 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.)
Selective ammoxidation catalysts for such reactions as R: 36/37/38 S: 26-36
conversion of toluene to benzonitrile or propylene to
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
49,925-0 pore 18 Å, 99% (Purity determined on 1g
acrylonitrile were prepared by a sol-gel method from V2O5,
Sb2O3 and high purity hydrogen peroxide. Preparation of new metals basis)
solid
stabilized, oxide ion-conducting, bismuth vanadate phases by a . . . . . . . . . . . . . . . . . . . . . . . . . . . .
microwave assisted method, fromV2O5, Bi2O3 and other solid 49,924-2 pore 32 Å, 99% (Purity determined on 1g
oxides, was reported. These ceramics show promise in solid metals basis)
oxide fuel cells, water-vapor electrolyzers and oxygen sensors. solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 690 C (lit.)
R: 20/22-37-48/23-51/53-63-68 S: 36/37-38-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,189-9 99.6+% 5g
Sulfides
Density. . . . . . . . . . . . . . 3.357 g/mL (lit.) 250 g
800.558.9196 (USA)
Density. . . . . . . . . . . . . . . 5.61 g/mL (lit.) 125 g R: 20/21/22-36/37/38-40 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
25,575-0 99.99% 100 g 22,946-6 99.995% 5g
Density. . . . . . . . . . . . . . . 5.67 g/mL (lit.) 500 g 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,553-2 powder, 1 mm, 99.9% 100 g 24,456-2 powder 100 g
Density. . . . . . . . . . . . . . 5.606 g/mL (lit.) 1 kg 500 g
5 kg
Arsenic(II) sulfide
47,531-9 Zinc oxide hydrate 25 g
CAS No. 55204-38-1 100 g 51,911-1 CAS No. 1303-32-8 25 g Ordering/Pricing: www.sigma-aldrich.com
97% As2S2 FW 214.0
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >390 C (lit.) 98%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.05 g/mL (lit.) solid
R: 20-36/37/38 S: 36 R: 23/25-50/53 S: 20/21-28-45-60-61
As2S5 FW 310.2
99.99+% 52,343-7 CAS No. 21109-95-5 10 g
solid BaS FW 169.4 50 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) 99.9%
R: 23/25-50/53 S: 20/21-28-45-60-61 solid
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.25 15 C
Cerium(III) sulfide R: 20/22-31-50 S: 28-61
Structural Materials/
Electronic Ceramics
Ho2S3 FW 426.1 5g Re2S7 FW 596.9 5g
99.9%
Iron(II) sulfide
Ruthenium(IV) sulfide
(Ferrous sulfide)
CAS No. 1317-37-9 58,742-7 CAS No. 12166-20-0 1g
FeS FW 87.91 RuS2 FW 165.2 5g
R: 31-50 S: 60-61 99.9%
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,316-1 -100 mesh, 99.9% 10 g solid
R: 36/37/38 S: 26-36
Density. . . . . . . . . . . . . . . . 4.84 g/mL (lit.) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,870-4 Technical Grade 5g Scandium(III) sulfide
Non-stoichiometric, inhomogeneous 250 g
Manganese(II) sulfide
43,164-8 Sodium sulfide nonahydrate 50 g
800.558.9196 (USA)
40,094-7 CAS No. 18820-29-6 5g CAS No. 1313-84-4 250 g
MnS FW 87.00 25 g Na2S 9H2O FW 240.2
99.9%, -325 mesh ReagentPlus, ‡98.0%, 99.99+%
R: 36/37/38 S: 26-36 Meets A.C.S. reagent specifications.
Applied in the formation of surface functionalized
Mercury(II) sulfide red cadmium sulfide quantum dots. Veinot, J.G.C. et al.
Chem. Mater. 1997, 9, 2117.
CAS No. 1344-48-5 total metallic impurities. . . . . . . . . . . . . . . . . . . <100 ppm
HgS FW 232.7 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.427 g/mL (lit.)
R: 23/24/25-33-36-50/53 S: 26-28-36/37/39-45-60-61 SO32- and S2O32-. . . . . . . . . . . . . . . . . . . . . . . . . £0.1%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Ordering/Pricing: www.sigma-aldrich.com
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Passes test
57,410-4 99.999% 25 g NH4+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
mp . . . . . . . . . . . . . . . . . . 583.5 C (lit.) 100 g
Trademark of Sigma-Aldrich Biotechnology LP.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
24,356-6 99% 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
40,073-4 50 g Strontium sulfide
Molybdenum(IV) sulfide See: Other Inorganic Compounds Page 162
57,571-2 CAS No. 1314-96-1 5g
SrS FW 119.7 25 g
Palladium(II) sulfide 99.9+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >2000 C
39,830-6 CAS No. 12125-22-3 1g R: 31-34 S: 26-36/37/39-45
PdS FW 138.5 5g
99.9% Terbium(III) sulfide
R: 36/37/38 S: 26-36
58,752-4 CAS No. 12138-11-3 1g
Platinum(IV) sulfide Tb2S3 FW 414.0 5g
99.99%
39,848-9 CAS No. 12038-21-0 1g solid
PtS2 FW 259.2 5g
99.9%
462
Ceramics
Sulfides: Metallic Sulfides
Nylon 6/12
Tin(II) sulfide 42,927-9 CAS No. 24936-74-1 250 g
(C18H38N2O4)n 1 kg
36,716-8 (Stannous sulfide) 10 g pellets 5 kg
CAS No. 1314-95-0
SnS FW 150.8 Nylon 6/66
96%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.22 g/mL (lit.) 42,924-4 (poly(hexamethylene adipamide-co- 250 g
R: 36/37/38 S: 26-37/39 caprolactam)) 1 kg
CAS No. 24993-04-2
Titanium(IV) sulfide (C18H37N3O5)n
pellets
33,349-2 CAS No. 12039-13-3 10 g
S2Ti FW 112.0 50 g General purpose thermoplastic polyamide.
Fibers for textiles, brushes and sutures cable sheathing
powder, 1 mm, 99.9%
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
R: 36/37/38 S: 26-37/39 and tubing and bearings, cams, gears and casings for tools
and appliances.
Tungsten(IV) sulfide Stiff and strong over a wide range of temperatures,
excellent toughness and chemical and abrasion resistance.
24,363-9 CAS No. 12138-09-9 50 g Attacked by strong acids and strong bases at elevated
WS2 FW 248.0 temperatures. Oxidized by chlorine and hydrogen
powder, 2 mm, 99% peroxide.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.5 g/mL (lit.) Abrasion resistance (Taber, CS-17 wheel, 1kg, 50% RH,
R: 36/37/38 S: 26-37/39 1,000 cycles) 5 mg
Hardness (Rockwell R, ASTM D 785) 100 (50% RH)
Yttrium(III) sulfide Hardness (Rockwell R, ASTM D 785) 122 (DAM)
contains Heat stabilizer, nucleating agent and lubricant
58,757-5 CAS No. 12039-19-9 1g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 250-260 C (lit.)
Y2S3 FW 274.0 5g Tm. . . . . . . . . . . . . . . . . . . . . . . . 250 C (ASTM D 2117)
99.99+% Solubility
solid strong proton donor solvents, acetic acid and phenols. . soluble
R: 36/37/38 S: 26-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3 g/mL (lit.)
[-NH(CH ) NHCO(CH ) CO-] [-NH(CH ) CO-]
26 24 x 25 y
Zinc sulfide
CAS No. 1314-98-3
Nylon 12
ZnS FW 97.46
R: 31
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 18,116-1 (polylauryllactam) 5g
24,462-7 99.99%, powder, 10 mm 25 g CAS No. 24937-16-4 250 g
Density. . . . . . . . . . . . . . . . 4.1 g/mL (lit.) 100 g (C12H23NO)n
500 g pellets, 5 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Tm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .178 C
33,327-1 pieces, 3-12 mm, 99.9% 50 g Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 C
Suitable for vacuum deposition. 250 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.01 g/mL (lit.)
Density. . . . . . . . . . . . . . . 3.98 g/mL (lit.) O
NHCH (CH ) CH C
2 29 2
n
Engineering Polymers
Polyamides
Nylon 4/6
44,299-2 CAS No. 50327-22-5 250 g
(C10H22N2O4)n 1 kg
463
Engineering Polymers
Polyamides
Structural Materials/
Electronic Ceramics
(C14H14N2O2)n 500 g (C10H12O6)n
Used in heat and flame protective . . . . . . . . . . . . . . . . . . . . . . . . . . . .
clothing. Electrical insulating paper requiring high 42,925-2 granules 250 g
temperature stability. Abrasion resistance (Taber, CS-17 wheel, 1 kg
Does not melt. 1kg, 50% RH, 1,000 cycles) 30 mg
decomposes. . . . . . . . . . . . . . . . . . . . . . . . . . . >371 C Hardness (Rockwell R, ASTM D 785) 120
Solubility contains 30% glass particles as reinforcer
dimethylformamide-lithium chloride.. . . . . . . . . . . . soluble mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 250-255 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.38 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.68 g/mL (lit.)
O R: 36/37/38 S: 26-36
C NH
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
n 42,926-0 granules 250 g
NH C R: 36/37/38 S: 26-36 1 kg
O
5 kg
Poly(1,4-butylene terephthalate)
CAS No. 24968-12-5 Polyimides
(C12H16O6)n
Molded into auto parts, electrical components and domestic Poly(trimellitic anhydride chloride-co-4,4¢-
appliance assemblies. methylenedianiline)
Chemical resistance similar to PET. Low water absorption giving
improved dimensional stability and electrical insulating 42,827-2 powder 25 g
properties. Used in conformal coatings, passivation 100 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.31 g/mL (lit.) agent, insulating varnish, LCD alignments,
O O and corrosion resistant coatings.
O CH CH CH CH O
2 2 2 2
C C Reactive, low molecular weight, soluble polymer.
n
Undergoes imide formation at 100-150C. Continued
heating to 150C removes residual solvent.
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.656 (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Viscosity. . . . . . . . . . . . . . . . . . . . . . . . . . . .800 cP (lit.)
43,514-7 Melt index (250C/2.16kg) 20 g/10 min 250 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.)
Impact strength (Izod, ASTM D 256, 1 kg Softening point. . . . . . . . . . . . . . . . . . . . . . 272 C (Film)
notched, 23 C) 0.9 ft-lb/in. Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.11 g/mL (lit.)
Dielectric constant (ASTM D 150, 100 Hz) 3.2 R: 45-46-20/21/22-63 S: 53-22-26-36/37/39-45
800.558.9196 (USA)
Hardness (Rockwell M, ASTM D 785) 78 O
contains no Fillers N CH
2
NH
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 C (lit.) C n
O
Tm. . . . . . . . . . . . . . . . . . . . . . . . . . 227 C (DSC, peak) O
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . 62 C (DSC, onset)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,515-5 Melt index (250C/2.16kg) 50 g/10 min 250 g
Impact strength (Izod, ASTM D 256, 1 kg
notched, 23 C) 0.6 ft-lb/in.
Dielectric constant (ASTM D 150, 100 Hz) 3.2 Polysulfones
Hardness (Rockwell M, ASTM D 785) 72 Ordering/Pricing: www.sigma-aldrich.com
contains no Fillers
Poly(oxy-1,4-phenylenesulfonyl-1,4-phenylene)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 C (lit.)
Tm. . . . . . . . . . . . . . . . . . . . . . . . . . 228 C (DSC, peak)
19,109-4 (Poly(1,4-phenylene ether-sulfone)) 50 g
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . 46 C (DSC, onset) CAS No. 25667-42-9 250 g
(C12H10O4S)
Poly(1,4-cyclohexanedimethylene terephthalate-co-ethy- pellets
lene terephthalate) Melt index (380C/2.16 kg) 75 g/10 min
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.37 g/mL (lit.)
R: 22-36/37/38 S: 26-36
43,533-3 CAS No. 25640-14-6 1 kg
O
Average Mn ~26,000
O S
O n
Poly(1,4-phenylene ether-ether-sulfone)
44,096-5 CAS No. 28212-68-2 250 g
pellets 1 kg
464
Engineering Polymers
Polysulfones
Polysulfone 2-(3-Allyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole
CAS No. 25135-51-7 55,985-7 (2-Allyl-6-(2H-benzotriazol-2-yl)-p-Cresol; 2- 1 g
Structural Materials/
Electronic Ceramics
(C27H26O6S)n (2H-Benzotriazol-2-yl)-4-methyl-6-(2- 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
propenyl)phenol)
42,830-2 Average Mn ~16,000 by MO, Average 5g
CAS No. 2170-39-0
Mw ~35,000 by LS, pellets 100 g
C16H15N3O FW 265.3
(Transparent) 500 g
99%
Thermoplastic engineering polymer.
Volatility (20C): nil
Melt index (ASTM D 1238, 343C/0.3 Mpa) 6.5 g/10 min
Reduced viscosity. . . 0.37-0.39 dL/g (0.2% w/v in CHCl3, 25 C)
solid
(lit.) Solubility
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.24 g/mL (lit.) water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . insoluble
www.sigma-aldrich.com/safc
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98-101 C
18,244-3 Average Mn ~22,000 by MO, beads 5g Transition temp. . . . . . . . . . . . . . . . . . . . . . . . . >270 C
Amorphous thermoplastic. 250 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3 g/cm3
S: 22-24/25
Melt index (ASTM D 1238, 343C/0.3 500 g
N
Mpa) 6.5 g/10 min OH
N CH CH CH
Hardness (Rockwell M, ASTM D 785) 69 N 2 2
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.633 (lit.)
Reduced viscosity. . . 0.43-0.46 dL/g (0.2% w/v in CHCl3, 25 C) CH
3
(lit.)
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 C
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.24 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,429-6 Average Mn ~26,000 by MO, pellets 20 g 4-Allyloxy-2-hydroxybenzophenone
Amorphous thermoplastic. 200 g
Melt index (ASTM D 1238, 343C/0.3 1 kg 41,583-9 CAS No. 2549-87-3 25 g
Mpa) 3.5 g/10 min
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
Visit www.sigma-aldrich.com/newproducts
for all of our newest products!
Structural Materials/
Electronic Ceramics
41,343-7 CAS No. 96478-09-0 25 g C14H11ClO2 FW 246.7
C18H17N3O3 FW 323.3 100 g 99%
99% R: 36/37/38 S: 26-37/39
Copolymerizable free radical stabilizer
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96-98 C (lit.) 2,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenol
R: 36-40 S: 22-26-36
O 42,332-7 CAS No. 3864-99-1 5g
H C C C O CH CH OH C20H24ClN3O FW 357.9 25 g
2 2 2
CH
3
98%
N N
UV absorber
N
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 150-153 C (lit.)
R: 36/37/38 S: 26-36
Cl
N OH CH
3
CH C CH
2-(2H-Benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phe- 3 3
CH
3
nol
32,280-6 (octrizole) 100 g
CAS No. 3147-75-9
C20H25N3O FW 323.4 3¢,5¢-Dichloro-2¢-hydroxyacetophenone
98%
UV absorber 38,339-2 CAS No. 3321-92-4 25 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 106-108 C (lit.) C8H6Cl2O2 FW 205.0
R: 36/37/38 S: 26-37/39 99%
N bp. . . . . . . . . . . . . . . . . . . . . 132-134 C/18 mm Hg (lit.)
OH
N
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94-97 C (lit.)
N
H
R: 36/37/38 S: 26-36
CH O
3
CH C CH C CH C CH
3 2 3 3
CH CH OH
3 3
Cl Cl
2-(4-Benzoyl-3-hydroxyphenoxy)ethyl acrylate
41,321-6 CAS No. 16432-81-8 25 g 2,4-Dihydroxybenzophenone
C18H16O5 FW 312.3 100 g
800.558.9196 (USA)
12,621-7 (DHB) 5g
98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77-80 C (lit.)
CAS No. 131-56-6 100 g
O O
C13H10O3 FW 214.2 500 g
H C CH C O CH CH O C
99%
2 2 2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 144.5-147 C (lit.)
OH R: 36/37/38 S: 26-36
O
HO C
OH
5-Chloro-2-hydroxybenzophenone
C4,470-2 CAS No. 85-19-8 5g
C13H9ClO2 FW 232.7 25 g
99%
R: 36/37/38 S: 26-37/39
466
Photooxidative Stabilizers for Polymers
2¢,4¢-Dihydroxy-3¢-propylacetophenone
2-Ethylhexyl 2-cyano-3,3-diphenylacrylate
42,690-3 CAS No. 40786-69-4 5g
C11H14O3 FW 194.2 25 g 41,582-0 CAS No. 6197-30-4 50 mL
99% C24H27NO2 FW 361.5 250 mL
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 124-127 C (lit.) 97%
R: 36/37/38 S: 26-36 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.567 (lit.)
O bp. . . . . . . . . . . . . . . . . . . . . . . .218 C/1.5 mm Hg (lit.)
C CH
3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -10 C (lit.)
OH Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.051 g/mL (lit.)
CH CH CH
2 2 3
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
OH
CN
C C
C O CH CHCH CH CH CH
2 2 2 2 3
O CH CH
2 3
Diisodecyl phenyl phosphite
44,224-0 CAS No. 25550-98-5 250 mL
R: 23/24/25-34 S: 26-27-36/37/39-45 1L 2-Ethylhexyl trans-4-methoxycinnamate
CH O CH
3 3
2-Ethylhexyl salicylate
43,737-9 (Octyl salicylate) 100 mL
2-Dodecyl-N-(1,2,2,6,6-pentamethyl-4-piperidinyl)succini- CAS No. 118-60-5 500 mL
mide C15H22O3 FW 250.3
99%
41,318-6 CAS No. 106917-30-0 50 mL n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.502 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . 189-190 C/21 mm Hg (lit.)
C26H48N2O2 FW 420.7 250 mL
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Technical Grade Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.014 g/mL (lit.)
R: 22-23-35-48/22-50/53 S: 26-28-36/37/39-45-60-61
O CH CH
2-Dodecyl-N-(2,2,6,6-tetramethyl-4-piperidinyl)succini- C
2 3
O CH CHCH CH CH CH
2 2 2 2 3
mide OH
Structural Materials/
Electronic Ceramics
C31H54O3 FW 474.8 250 g C17H25NO2 FW 275.4 500 mL
98% 98%
R: 36/37/38 S: 26-36 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.542 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 177-179 C/3 mm Hg (lit.)
Hexahydro-2,6-bis(2,2,6,6-tetramethyl-4-piperidinyl)- Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
1H,4H,5H,8H-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]- Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.04 g/mL (lit.)
R: 36/37/38 S: 26-36
fluorene-4,8-dione
CH
3
CH CH
41,586-3 CAS No. 109423-00-9 50 g O
3
C26H46N8O2 FW 502.7 250 g C O CH
3
98% NH
2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 267 C (dec.) (lit.)
O
800.558.9196 (USA)
C21H26O3 FW 326.4 500 g
98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47-49 C (lit.)
R: 36/37/38 S: 26-36
O
CH (CH ) CH O C
Poly[2-(4-benzoyl-3-hydroxyphenoxy)ethyl acrylate]
3 26 2
P
O O
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
C H C H
R: 22-51/53 S: 36-61 9 19 9 19
O CH CH CH
2 2
N N
H C CH CH O N O CH CH CH
2 2 2 2
Tris(tridecyl) phosphite
44,222-4 CAS No. 68610-62-8 250 mL
1,3,5-Triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione R: 36/37/38 S: 26-36
as inhibitor phenol
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.513 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 149-152 C/4 mm Hg (lit.) 53,575-3 CAS No. 70321-86-7 100 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F C30H29N3O FW 447.6
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.159 g/mL (lit.) powder
R: 22 S: 23-24/25 Low volatile benzotriazole UV light absorber and stabilizer.
O Imparts outstanding light stability for polymers processed
H C C HCH CH CH CH
2 2 N N 2 2 at high temperatures such as polycarbonate, polyesters,
O O
polyacetal, polyamides, polyphenylene sulfide,
N
CH CH CH
polyphenylene oxide, aromatic copolymers, thermoplastic
2 2
polyurethane and polyurethane fibers also highly effective
for polyvinylchloride, styrene homo- and copolymers.
Volatility. . . . . . . . . . . . . . . . . . . . . . . 1.0 wt. %, 264C
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 139-143 C (lit.)
Triisodecyl phosphite mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 (lit.)
Solubility
44,225-9 CAS No. 25448-25-3 250 mL chloroform. . . . . . . . . . . . . . . . . . . . 35 wt. % at 20 C
R: 36/37/38 S: 26-36 1L methylene chloride. . . . . . . . . . . . . . . .34 wt. % at 20 C
toluene. . . . . . . . . . . . . . . . . . . . . . .20 wt. % at 20 C
Tris(2,4-di-tert-butylphenyl) phosphite water. . . . . . . . . . . . . . . . .<0.04 ppm at 20 C, insoluble
R: 36/37/38 S: 26-36
44,179-1 CAS No. 31570-04-4 100 g N CH
OH 3
C42H63O3P FW 646.9 500 g N C
N
98% CH
3
Processing stabilizer for polymers
CH C CH
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 181-184 C (lit.) 3 3
CH
3
CH C CH
3 3
H C
3
CH C
3 CH
CH O 3
3 CH C CH
P 3 3
O O
H C CH CH
3 3 3
CH C C CH C CH
3 3 3
CH CH CH
3 3 3
469
Photooxidative Stabilizers for Polymers
HALS (Hindered Amine Light Stabilizers)
Structural Materials/
Electronic Ceramics
C25H35N3O FW 393.6 C28H52N2O4 FW 480.7
Low volatile liquid benzotriazole UV light absorber/ Hindered amine UV light stabilizer.
stabilizer. Provides excellent stability for thick sections and articles
Imparts outstanding light stability and protection with high surface area.
efficiency without imparting any yellowness to the Volatility. . . . . . . . . . . . . . . . . . . . .0.7 wt. %, 150-175C
protected substrate. mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82-85 C (lit.)
Dodecyl chain is branched and linear. Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 421 F
liquid Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 C (dec)
n20 Solubility
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.574 (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 (lit.) methylene chloride. . . . . . . . . . . . . . 56 % (w/w) at 20 C
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F chloroform. . . . . . . . . . . . . . . . . . . 45 % (w/w) at 20 C
Solubility methanol. . . . . . . . . . . . . . . . . . . . 38 % (w/w) at 20 C
acetone, chloroform, ethyl acetate, n-hexane, methylene ethyl acetate. . . . . . . . . . . . . . . . . . 24 % (w/w) at 20 C
chloride, and toluene. . . . . . . . . . . . . . 50 wt. % at 20 C acetone. . . . . . . . . . . . . . . . . . . . . 19 % (w/w) at 20 C
CH
3
2-(4,6-Diphenyl-1,3,5-triazin-2-yl)-5-[(hexyl)oxy]-phenol
53,582-6 CAS No. 147315-50-2 100 g
Bis(octadecyl)hydroxylamine C27H27N3O2 FW 425.5
powder
53,585-0 CAS No. 143925-92-2 100 g Very low volatile UV light absorber and stabilizer.
C36H75NO FW 538.0 Allows polycarbonates and polyesters to achieve a higher
powder, 65% resistance to weathering than conventional benzotriazole
UV light stabilizer. UV absorbers. Low tendency to chelate allows its use in
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 (lit.) polymer formulations containing catalyst residues.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96-99 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 147-151 C (lit.)
Solubility Solubility
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . insoluble chloroform. . . . . . . . . . . . . . . . . . . 254 mg/mL at 20 C
methylene chloride. . . . . . . . . . . . . . 169 mg/mL at 20 C
OH toluene. . . . . . . . . . . . . . . . . . . . . . 51 mg/mL at 20 C
H C
37 18
N C H
18 37 methylmethacrylate. . . . . . . . . . . . . . . 15 mg/mL at 20 C
R: 53 S: 61
800.558.9196 (USA)
OC H
6 13
Bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate OH
N N
53,576-1 CAS No. 129757-67-1 100 g
N
C44H84N2O6 FW 737.1
Hindered amine UV light stabilizer.
Low basicity reduces interactions with acidic paint
ingredients particularly effective in coatings based on
alkyds. Ordering/Pricing: www.sigma-aldrich.com
Easily emulsified in water borne systems. Miscible to
>50% with xylene, MEK, and other paint solvents.
liquid Have you seen the
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.479 (lit.)
Dynamic viscosity. . . . . . . . . . . . . . 3000 mPa.s (20 C) (lit.) "Cave of the Dogs"
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >150 C (dec)
or planted a
Solubility
water. . . . . . . . . . . . . . . . . . . . . . . . . <6 ppm at 20 C
"Chemical Garden"?
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.028 g/mL (lit.)
S: 23-24/25
For information on these
CH
3
CH
3 O O
CH
3 CH
3 and other NEW Chemical
H C O
17 8
N O C CH (CH ) CH
2 26 2
C O N OC H
8 17 Demonstration Kits,
CH CH
3 CH3 CH
3 3
contact the Technical
Services Department.
470
Photooxidative Stabilizers for Polymers
HALS (Hindered Amine Light Stabilizers)
decane
53,584-2 CAS No. 65447-77-0 100 g
(C15H29NO6)n 53,586-9 CAS No. 106990-43-6 100 g
Average Mn ~3,500, Average Mn 3,100-4,000 C132H250N32 FW 2285
Antioxidant. Antioxidant.
Oligomeric hindered amine UV light stabilizer with low Monomeric hindered amine UV light stabilizer for
volatility and minimal migration. More effective stabilizer polyolefins offering low volatility and high migration
than UV absorbers in pigmented systems. Works resistance.
synergistically with other HALS UV absorbers, for e.g., Advantage over other HALS is that it enhances the color
53,396-3. yield of pigmented polyolefin articles.
www.sigma-aldrich.com/safc
solid solid
Volatility. . . . . . . . . . . . . . . . . . . . . . . 0.1 wt. %, 200C volatility. . . . . . . . . . . . . . . . . . . . . . . . . . . 0.07 wt. %
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 146-150 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 428 F Solubility
Solubility chloroform, methylene chloride, and toluene. . . ‡20 % (w/w)
chloroform and methylene chloride.. . . . . . . . . .40 % (w/w) at 20 C
water. . . . . . . . . . . . . . . . . . . . . . . . 1.6 ppm at 20 C R: 43 S: 26-36
R R
CH CH
3 3 O O R NH CH CH CH N CH CH N CH CH CH NH R
2 2 2 2 2 2 2 2
O N CH CH O C CH CH C
2 2 2 2
CH CH
CH C H 3 3
CH 3 4 9
3
n N N N CH
3
R=
N N CH CH
3 3
H C N CH
3
Poly[[6-[(1,1,3,3-tetramethylbutyl)amino]-s-triazine-2,4- 9 4
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
CH
N 3
diyl]-[(2,2,6,6-tetramethyl-4-piperidyl)imino]-hexamethy- CH
CH CH 3
lene-[(2,2,6,6-tetramethyl-4-piperidylimino]] 3 3
H H
CH N CH CH N CH
3 3 3 3
CH CH CH CH
3 3 3 3
N N CH (CH ) CH N
2 24 2
N N CH CH
3 3
NH C CH C CH
2 3
CH CH
3 3
n