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A polyethylene sample neckingunder tension.
The bulk properties of a polymer are those most often of end-use interest. These are the properties that dictate how the polymer actually behaves on a macroscopic scale. Tensile strength The tensile strength of a material quantifies how much stress the material will endure before suffering permanent deformation. This is very important in applications that rely upon a polymer's physical strength or durability. For example, a rubber band with a higher tensile strength will hold a greater weight before snapping. In general, tensile strength increases with polymer chain length and crosslinking of polymer chains. Young's modulus of elasticity Young's Modulus quantifies the elasticity of the polymer. It is defined, for small strains, as the ratio of rate of change of stress to strain. Like tensile strength, this is highly relevant in polymer applications involving the physical properties of polymers, such as rubber bands. The modulus is strongly dependent on temperature. Transport
Transport properties such as diffusivity relate to how rapidly molecules move through the polymer matrix. These are very important in many applications of polymers for films and membranes. Phase
Melting point The term melting point, when applied to polymers, suggests not a solid-liquid phase transition but a transition from a crystalline or semi-crystalline phase to a solid amorphous phase. Though abbreviated as simply Tm, the property in question is more properly called the crystalline melting temperature. Among
which describes the temperature at which amorphous polymers undergo a transition from a rubbery. to a brittle. This effect results from the fact that the driving force for mixing is usually entropy. viscous amorphous solid. Mixing behavior Phase diagram of the typical mixing behavior of weakly interacting polymer solutions. glassy amorphous solid. In general. but because of an increase in entropy and hence free energy associated with increasing the amount of volume available to each component. This increase in entropy scales with the number of particles (or moles) being mixed.synthetic polymers. Glass transition temperature A parameter of particular interest in synthetic polymer manufacturing is the glass transition temperature (Tg). miscible materials usually form a solution not because their interaction with each other is more favorable than their self-interaction. the number of molecules involved in a polymeric mixture is far smaller than the number in a small molecule mixture of equal volume. The energetics of mixing. is comparable on a per volume basis for polymeric . Since polymeric molecules are much larger and hence generally have much higher specific volumes than small molecules. as thermosetting polymers will decompose at high temperatures rather than melt. on the other hand. In other words. not interaction energy. The glass transition temperature may be engineered by altering the degree of branching or crosslinking in the polymer or by the addition of plasticizer. polymeric mixtures are far less miscible than mixtures of small molecule materials. crystalline melting is only discussed with regards to thermoplastics.
for example. or the state of the polymer solution where the value of the second virial coefficient becomes 0. In this scenario. at which phase separation occurs with heating. Plasticizers are generally small molecules that are chemically similar to the polymer and create gaps between polymer chains for greater mobility and reduced interchain interactions. The transition between the states is known as a coil-globule transition. concentrated solutions of polymers are far rarer than those of small molecules. A uPVC. Thus. Chemical properties The attractive forces between polymer chains play a large part in determining a polymer's properties. The intermolecular forces in polymers can be affected by dipoles in the monomer units. Whereas most small molecule solutions exhibit only an upper critical solution temperature phase transition. the properties of the polymer are characterized by the interaction between the solvent and the polymer. polymer mixtures commonly exhibit a lower critical solution temperaturephase transition. In a bad solvent or poor solvent. intramolecular forces dominate and the chain contracts. Polymers containing amide or carbonyl groups can form hydrogen bonds between adjacent chains. at which phase separation occurs with cooling. . the polymer behaves like an ideal random coil. or unplasticized polyvinylchloride. In the theta solvent. Under the theta condition (also called the Flory condition). the phase behavior of polymer solutions and mixtures is more complex than that of small molecule mixtures. is used for things such as pipes. Furthermore. In dilute solution. These strong hydrogen bonds. intermolecular forces between the solvent and monomer subunits dominate over intramolecular interactions. because it needs to remain strong and heat-resistant. In a good solvent. the partially positively charged hydrogen atoms in N-H groups of one chain are strongly attracted to the partially negatively charged oxygen atoms in C=O groups on another. A good example of the action of plasticizers is related to polyvinylchlorides or PVCs. These stronger forces typically result in higher tensile strength and higher crystalline melting points. Inclusion of plasticizers Inclusion of plasticizers tends to lower Tg and increase polymer flexibility.and small molecule mixtures. these interchain forces are amplified far beyond the attractions between conventional molecules. Plasticizers are also put in some types of cling film to make the polymer more flexible. This tends to increase the free energy of mixing for polymer solutions and thus make solvation less favorable. Because polymer chains are so long. Different side groups on the polymer can lend the polymer to ionic bonding or hydrogen bonding between its own chains. Plasticized PVC is used for clothing for a flexible quality. A pipe has no plasticizers in it. the polymer appears swollen and occupies a large volume. the intermolecular polymer-solvent repulsion balances exactly the intramolecular monomermonomer attraction.
This has the effect of lowering the electron density on one side of a polymer chain. The attractive forces between polyethylene chains arise from weak van der Waals forces.result in the high tensile strength and melting point of polymers containing urethane or urea linkages. but polyesters have greater flexibility. Molecules can be thought of as being surrounded by a cloud of negative electrons. . so polyethylene can have a lower melting temperature compared to other polymers. has no permanent dipole. As two polymer chains approach. creating a slight positive dipole on this side. This charge is enough to attract the second polymer chain. Polyesters have dipole-dipole bondingbetween the oxygen atoms in C=O groups and the hydrogen atoms in H-C groups. however. Ethene. their electron clouds repel one another. however. so a polyester's melting point and strength are lower than Kevlar's (Twaron). Dipole bonding is not as strong as hydrogen bonding. Van der Waals forces are quite weak.
Plastic The Dilemma: It happens every time you buy groceries. let¶s dispense with the difference between paper and plastic bags. Plastic bags also take up less landfill space. on the other hand. People You Can Impress: It¶s not about impressing anyone so much as not letting your indecisiveness aggravate the people in line behind you. According to one study (and yes. But that seems like an awful lot of work just to slightly increase the chances that your children can live on a habitable planet. For sheer ease of use.which is better for the environment? Both paper and plastic have their drawbacks.Paper vs. requiring less total energy to create and producing less waste than paper. every study we found agreed plastic was the better bag. baggers are usually taught to pick plastic). people start looking at you funny. They¶re then molded into the bag-with-handles shape we¶ve known and loved at grocery stores since the mid-1980s. there are studies about this sort of thing) two plastic bags take up 72 percent less landfill space than one paper bag. The best option would be to use a canvas bag or a reusable bag. Paper And Plastic 'Paper' or 'plastic'. Paper bags. Although the average paper grocery bag holds more than a plastic bag. The Quick Trick: Plastic is probably better for the environment. Your bagger casually asks. paper isn¶t biodegradable either in modern American landfills. that plastic is derived from a nonrenewable resource. Proponents of paper are likely to point out that paper is easier to recycle. Instead. Most plastic bags are derived from crude oil or natural gas by-products that have been treated to form long chains of carbon and hydrogen molecules. are made (you¶ll never believe it) from trees²specifically. But it¶s a complex question requiring considerable analysis. All in all. . because landfills lack the water and soil needed for biodegrading. you could bring your own reusable bags to the grocery store. The Explanation: First. So which is better? We¶ll begin with the case for plastic. compressed wood pulp. Of course. the best solution is to use neither paper nor plastic. Also. A lot of health food stores have those available and they can be pretty inexpensive. I keep a bunch in the back of my car so that they're always available when I'm going to the store. And it¶s true that paper is easier to recycle (although plastic bags are recyclable). plastic certainly wins. Plastic is less energy to make but it doesn't break down easily. But as it happens. plastic bags¶ handles make them much easier to carry. paper is mostly better for the paper industry. ³Paper or plastic?´ And if you don¶t answer within three seconds. Paper uses trees and energy to make but it does break down easier. and that plastic is nonbiodegradable. plastic bags are cheaper (which is why when you respond to the paper-or-plastic question with an ambivalent shrug. Which is better for the environment? Easier to carry? Less likely to be a choking hazard? You could stand in that grocery line all day. but recycling itself takes energy and creates pollution.
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