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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 10/16/2009 Version: 1 Reviewed on 03/06/2009

1 Identification of substance
· Product details · Trade name: Aquacolor · Article number: 01100,01101,011... bis 01115 · Application of the substance / the preparation cosmetic (agent) · Manufacturer/Supplier: Kryolan GmbH Papierstraße 10 D-13409 Berlin Tel: 49 (0) 3049989250 Fax: 49 (0) 304914994 · Information department: Section Productsafty andreas.lueth@kryolan.de · Emergency information: 49 (0)304011577 oder 49 (0)30499892-20 o.-60

2 Composition/Data on components
· Chemical characterization · Description: cosmetic (agent) · Dangerous components: Void

3 Hazards identification
· Hazard description: The product contains no substances classified as hazardous to health or environment in concentrations,which should be taken into account according to directive 67/548/EEC. · Information pertaining to particular dangers for man and environment: The product does not have to be labelled due to the calculation procedure of international guidelines. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · NFPA ratings (scale 0 - 4)

0 0
HEALTH FIRE

0
0 0

Health = 0 Fire = 0 Reactivity = 0

· HMIS-ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0

REACTIVITY 0

· GHS label elements Void

4 First aid measures
· General information: No special measures required. · After eye contact: Rinse opened eye for several minutes under running water.
USA

(Contd. on page 2)

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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 10/16/2009 Version: 1 Reviewed on 03/06/2009
(Contd. of page 1)

5 Fire fighting measures
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.

6 Accidental release measures
· Person-related safety precautions: Not required. · Measures for environmental protection: No special measures required. · Measures for cleaning/collecting: Warm water and cleansing agent · Additional information: No dangerous substances are released.

7 Handling and storage
· Handling: · Information for safe handling: No special measures required. · Information about protection against explosions and fires: No special measures required. · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: Protect from heat and direct sunlight. Store in cool, dry conditions in well sealed receptacles.

8 Exposure controls and personal protection
· Additional information about design of technical systems: No further data; see item 7. · Components with limit values that require monitoring at the workplace: 56-81-5 glycerol PEL 15* 5** mg/m³ *total dust **respirable fraction TLV 10* ppm *Mist 7727-43-7 barium sulphate, natural PEL 15* 5** mg/m³ *total dust **respirable fraction REL 10* 5** mg/m³ *total dust **respirable fraction TLV 10 mg/m³ E · Additional information: The lists that were valid during the creation were used as basis. · Personal protective equipment: · General protective and hygienic measures: Do not eat or drink while working. · Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves Not required. · Penetration time of glove material Not required.
USA

(Contd. on page 3)

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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 10/16/2009 Version: 1 Reviewed on 03/06/2009
(Contd. of page 2)

9 Physical and chemical properties
· General Information Form: Color: Odor: Solid According to product specification Characteristic

· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point: · Auto igniting: · Danger of explosion: · Density: Not applicable. Product is not selfigniting. Product does not present an explosion hazard. Not determined.

· Solubility in / Miscibility with Soluble. Water: · Solvent content: VOC content: · Solids content: 15.4 % 70-85 %

10 Stability and reactivity
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Dangerous reactions No dangerous reactions known. · Dangerous products of decomposition: No dangerous decomposition products known.

11 Toxicological information
· Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us.

12 Ecological information
· General notes: Negative ecological effects are, according to the current state of knowledge, not expected. Due to available data on eliminability/decomposition and bioaccumulation potential a prolonged damage of the environment is unlikely. At present there are no ecotoxicological assessments.
USA

(Contd. on page 4)

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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 10/16/2009 Version: 1 Reviewed on 03/06/2009
(Contd. of page 3)

13 Disposal considerations
· Product: · Recommendation: Smaller quantities can be disposed of with household waste. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.

14 Transport information
· DOT regulations: · Hazard class: · Land transport ADR/RID (cross-border): · ADR/RID class: · Maritime transport IMDG: · IMDG Class: · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · UN "Model Regulation": -

15 Regulations
· Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenicity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) 14807-96-6 Talc (Mg3H2(SiO3)4) 91-64-5 Coumarin 5989-27-5 (R)-p-mentha-1,8-diene 3 3 3
(Contd. on page 5)
USA

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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 10/16/2009 Version: 1 Reviewed on 03/06/2009
(Contd. of page 4)

· NTP (National Toxicology Program) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) 14807-96-6 Talc (Mg3H2(SiO3)4) 1332-58-7 Kaolin · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Product related hazard informations: As a cosmetic preparation, the product is not subject to the provisions of the Chemical Law and the Ordinance on Hazardous Materials. However, general safety regulations should be observed. Although this product is not subject to identification regulations, we recommend that the safety suggestions are observed. A4 A4

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Section Product Safty · Contact: Mr.Lüth · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU)
USA

DR

European Center for Allergy Research Foundation: Seal of Quality Approval for KRYOLAN Products KRYOLAN PROFESSIONAL MAKE-UP is now the first range of color make-up products to receive the Seal of Quality Approval from the European Centre for Allergy Research Foundation (ECARF). The prevalence of allergies is dramatically increasing in industrialized countries. In Europe, around 30 % of the population already suffers from allergy. Under the motto, “Quality of Life Despite Allergy,” the European Centre for Allergy Research Foundation (ECARF) has set as its objective the enhancement of public awareness with respect to allergies, the raising of the level of knowledge of allergies, and the intensification of research activities. In addition, the Foundation aims at reducing the suffering of allergy patients from the consequences of their illness. Professor Dr. Torsten Zuberbier, M.D., Co-Director of the Clinic for Dermatology, Venerology, and Allergology at the Charité University Medical Center in Berlin, is an internationally recognized dermatologist and member of numerous scientific organizations. The focal points of his research include urticaria (hives), neurodermatitis, allergies of the respiratory system, food allergies, and allergic rhinitis. Since 2003 Professor Zuberbier has been the head of the European Centre for Allergy Research Foundation (ECARF). Seal of Quality Approval for cosmetic products ECARF awards product and services its Seal of Quality Approval for Allergy-Friendly Products if the related products and services have been evidenced to relieve and/or better the daily lives of allergy patients. Cosmetic products can receive the ECARF Seal of Quality Approval if they – on the basis of latest scientific knowledge, and as a result of laboratory and clinical tests – have proven to be especially well suited for sensitive skin and for patients with neurodermatitis. In autumn of 2009, an intensive test program was conducted on KRYOLAN cosmetic products on test persons suffering from neurodermatitis and eczema of the face. These tests especially concentrated on testing of the following products, particularly for their skin compatibility and for the patient problem of itching: HIGH DEFINITION smoothing fluid, HIGH DEFINITION matifying liquid, HIGH DEFINITION glamouring flow, HIGH DEFINITION on air, HIGH DEFINITION micro foundation cream, and HIGH DEFINITION cache. Additional tests were conducted on the product Aquacolor, a classic preparation from the KRYOLAN company. The skin of the test persons was examined before testing and after the course of a week’s use. The results: all products achieved “good” or “very good” test findings. After one week, the condition of the skin was evaluated as unchanged, or with a tendency of improvement. As a result, all KRYOLAN products can be classified as allergy friendly and are eligible in future to carry the ECARF Seal of Quality Approval. As Professor Torsten Zuberbier emphasized, “It is especially important to also test decorative cosmetic products, since they often have long and intensive contact with the skin. And it is particularly in this area that people with sensitive skin frequently experience problems.”

Info box The European Center for Allergy Research Foundation (ECARF) was founded in 2003 and awards throughout Europe, without cost, its non-commercial Seal of Approval for AllergyFriendly Products and Services. This non-profit, charitable foundation has its registered offices at the Charité University Medical Center in Berlin. It specializes in the research, diagnosis, and therapy of allergies. It is headed by Professor Dr. Torsten Zuberbier, M.D. ECARF is a member in the Global Allergy and Asthma European Network (GA2LEN) for the European Union.

Further information: info@ecarf.org / www.ecarf.org /

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