You are on page 1of 3

Tutorial heterocyclic compounds A) Choose the correct answer

1) The correct parent ring in the heterocycles below is:
N N N N N N (b) Quinoxaline N N H N N

N

(a) Pyrazine

(c) Triazole

2)

The correct parent ring in the heterocycles below is:
S
N

O N H N

N S (b) Oxazole

S O (c) thiophene

N

(a) Pyrazole

3)

The correct name of this heterocycle is: a) Pyrazino[4,5-c] pyridazine b) Pyrimido[4,5-c] pyridazine c) Pyridazino[3,4-d] pyrimidine
N N N N

4)

Pyrrole: a) Pyrrole is a π -deficient heterocyclic molecule. b) Nitrogen atom contributes its lone pair of electrons to the aromatic sextet. c) Nitrogen contribute only one p electron to the aromatic sextet.

N H

5)

The orbital structure of pyridine:

a) Pyridine is a π -deficient heterocyclic molecule. b) Nitrogen atom is sp3 hybridized. c) The π electrons of the ring carbons overlap with doubly filled p orbital of

1

6Z)-1.6.6) nitrogen.5]oxadiazepine 9H-purine-2.4. The compound which its name is written correctly is: H Cl NH N N H H Br N O 3-Chloroimidazole (a) 2H-pyrrolium cation (b) 2-Bromoisoxazole (c) B) Give the systemic name of the following: N S (a) N (b) O S N (c) ================= Answers N a) Br O OH N b) HO N N OH N N H 7-bromobenzo[b][1.5-oxathiazepine benzo[h]quinoline 2 .3.2-b]pyridine N (c) (4Z.8-triol S (a) N (b) S O N 4H-thiopyrano[3.

3-e]pyrazine (5) (6Z.3-g]quinoline (7) N N N N N N N [1.O H N N O N N O N 1H-pyrazolo[4.2.3-a]pyridine (8) pyrazino[2.2-b]pyran (2) 5H-pyrido[2.4]thiazine (6) 1.3-d]pyridazine (9) N H dibenzo[b.2]oxazine (3) O N N N N N 4) difuro[2.4]triazolo[4.3-d][1.2-b]benzo[e][1.5-diazaanthracene pyrido[2.5-a]azepine H N N N N S 10H-pyrido[3.3-d]oxazole (1) N O O 2H-furo[3.f]azipine (10) N 4H-dibenzo[d.e][g]quinoline (11) 3 .8Z)-5H-tetrazolo[1.3-b][2.