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01/06/2013
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), New Delhi  16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
Note: For the benefit of the students, specially the aspiring ones, the question of IITJEE, 2003 Screening are also
given in this paper. Keeping the interest of students studying in class XI, the questions based on topics from
class XI have been marked with ‘*’, which can be attempted as a test. For this test the time allocated in
Physics, Chemistry and Mathematics are 25 minutes, 25 minutes and 25 minutes respectively.
I
I
I
I
T
T
−
−
J
J
E
E
E
E
,
,
2
2
0
0
0
0
3
3
S
S
c
c
r
r
e
e
e
e
n
n
i
i
n
n
g
g
1. A metallic shell has a point charge ‘q’ kept inside its cavity. Which one of the following diagrams
correctly represents the electric lines of forces?
(A)
(B)
(C)
(D)
2*. What is the maximum value of the force F such that the
block shown in the arrangement, does not move?
(A) 20 N (B) 10 N
(C) 12 N (D) 15 N
u =
3 2
1
m=√3kg
F
60°
3*. Consider a body, shown in figure, consisting of two
identical balls, each of mass M connected by a light rigid
rod. If an impulse J = MV is imparted to the body at one of
its ends, what would be its angular velocity?
J = MV
M
M
L
(A) V/L (B) 2V/L
(C) V/3L (D) V/4L
4*. If W
1
, W
2
and W
3
represent the work done in moving a particle from A to
B along three different paths 1, 2 and 3 respectively (as shown) in the
gravitational field of a point mass m, find the correct relation between
W
1
, W
2
and W
3
.
(A) W
1
> W
2
> W
3
(B) W
1
= W
2
= W
3
(C) W
1
< W
2
< W
3
(D) W
2
> W
1
> W
3
m
2
1
A
B
3
5. A cube has a side of length 1.2 × 10
−2
m. Calculate its volume.
(A) 1.7 × 10
−6
m
3
. (B) 1.73 × 10
−6
m
3
.
(C) 1.70 × 10
−6
m
3
. (D) 1.732 × 10
−6
m
3
.
6*. The graph, shown in the adjacent diagram, represents the variation of
temperature (T) of two bodies, x and y having same surface area, with time (t)
due to the emission of radiation. Find the correct relation between the emissivity
and absorptivity power of the two bodies.
(A) E
x
> E
y
& a
x
< a
y
(B) E
x
< E
y
& a
x
> a
y
(C) E
x
> E
y
& a
x
> a
y
(D) E
x
< E
y
& a
x
< a
y
T
t
x
y
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7*. The adjacent graph shows the extension (∆l) of a wire of length 1 m
suspended from the top of a roof at one end and with a load W
connected to the other end. If the crosssectional area of the wire is
10
−6
m
2
, calculate the Young’s modulus of the material of the wire.
(A) 2 × 10
11
N/m (B) 2 × 10
−11
N/m
(C) 3 × 10
−12
N/m (D) 2 × 10
−13
N/m
1
2
3
20 40 60
∆l(×10
−4
m)
W (N)
4
80
8. In the adjacent diagram, CP represents a wavefront and AO & BP,
the corresponding two rays. Find the condition on θ for constructive
interference at P between the ray BP and reflected ray OP.
(A) cosθ=3λ/2d
(B) cosθ = λ/4d
(C) secθ − cosθ =λ/d
(D) secθ−cosθ=4λ/d
θ
θ
O
Q R
P
B
A
C
d
9*. Two rods, one of aluminum and the other made of steel, having initial length l
1
and l
2
are
connected together to form a single rod of length l
1
+ l
2
. The coefficients of linear expansion for
aluminum and steel are α
a
and α
s
respectively. If the length of each rod increases by the same
amount when their temperature are raised by t°C, then find the ratio ( )
2 1 1
l l l + .
(A) α
s
/α
a
(B) α
a
/α
s
(C) ( )
s a s
α + α α (D) ( )
s a a
α + α α
10. The size of the image of an object, which is at infinity, as formed by a convex lens of focal length
30 cm is 2 cm. If a concave lens of focal length 20 cm is placed between the convex lens and the
image at a distance of 26 cm from the convex lens, calculate the new size of the image.
(A) 1.25 cm (B) 2.5 cm
(C) 1.05 cm (D) 2 cm
11. A ray of light is incident at the glasswater interface at an angle i, it
emerges finally parallel to the surface of water, then the value of u
g
would be
(A) (4/3)sini (B) 1/sini
(C) 4/3 (D) 1
i
Air
Water
Glass
r
r
uW = 4/3
12. The electric potential between a proton and an electron is given by V = V
0
ln
0
r
r
, where r
0
is a
constant. Assuming Bohr’s model to be applicable, write variation of r
n
with n, n being the
principal quantum number?
(A) r
n
∝ n (B) r
n
∝ 1/n
(C) r
n
∝ n
2
(D) r
n
∝ 1/n
2
13. If the atom
100
Fm
257
follows the Bohr model and the radius of
100
Fm
257
is n times the Bohr radius,
then find n.
(A) 100 (B) 200
(C) 4 (D) 1/4
14. When an AC source of emf e = E
0
sin(100t) is connected across a
circuit, the phase difference between the emf e and the current i in the
circuit is observed to be π/4, as shown in the diagram. If the circuit
consists possibly only of RC or RL or LC in series, find the
relationship between the two elements.
(A) R = 1 kΩ, C = 10 uF (B) R = 1 kΩ, C=1 uF
(C) R = 1 kΩ, L = 10 H (D) R = 1 kΩ, L = 1 H
i e
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IITJEE2003S3
15. For a positively charged particle moving in a xy plane initially along the
xaxis, there is a sudden change in its path due to the presence of
electric and/or magnetic fields beyond P. The curved path is shown in the
xy plane and is found to be noncircular.
Which one of the following combinations is possible?
(A) E
r
= 0; B
r
= b i
ˆ
+ ck
ˆ
(B) E
r
= a i
ˆ
; B
r
=ck
ˆ
+ a i
ˆ
(C) E
r
= 0; B
r
= c j
ˆ
+ bk
ˆ
(D) E
r
=a i
ˆ
; B
r
= ck
ˆ
+ b j
ˆ
P
x
y
16. Express which of the following setups can be used to verify Ohm’s law?
(A)
V
A
(B)
V A
(C)
V
A
(D)
A
V
17*. The PT diagram for an ideal gas is shown
in the figure, where AC is an adiabatic
process, find the corresponding PV
diagram.
P
T
C
A
B
(A)
P
V
B
A
C
(B)
P
V
C
A
B
(D)
P
V
C
A
B
(D)
P
V
B
A
C
18*. A police car moving at 22 m/s, chases a
motorcyclist. The police man sounds his horn at
176 Hz, while both of them move towards a
stationary siren of frequency 165 Hz. Calculate the
speed of the motorcycle, if it is given that he does
not observes any beats.
22 m/s
176 Hz
V
Stationary
Siren
(165 Hz)
Police Car Motorcycle
(A) 33 m/s (B) 22 m/s
(C) zero (D) 11 m/s
19. For uranium nucleus how does its mass vary with volume?
(A) m ∝ V (B) m ∝ 1/V
(C) m ∝ √V (D) m ∝ V
2
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IITJEE2003S4
20. For a particle executing SHM the
displacement x is given by x = A cosωt.
Identify the graph which represents the
variation of potential energy (PE) as a
function of time t and displacement x.
t
PE
I
III
IV
x
II PE
(A) I, III (B) II, IV
(C) II, III (D) I, IV
21*. In the experiment for the determination of the speed of sound in air using the resonance column
method, the length of the air column that resonates in the fundamental mode, with a tuning fork is
0.1 m. When this length is changed to 0.35 m, the same tuning fork resonates with the first
overtone. Calculate the end correction.
(A) 0.012 m (B) 0.025 m
(C) 0.05 m (D) 0.024 m
22*. A particle undergoes uniform circular motion. About which point on the plane of the circle, will the
angular momentum of the particle remain conserved?
(A) centre of the circle (B) on the circumference of the circle.
(C) inside the circle. (D) outside the circle.
23. A conducting loop carrying a current I is placed in a uniform magnetic field
pointing into the plane of the paper as shown. The loop will have a tendency to
(A) contract (B) expand
(C) move towards +ve xaxis (D) move towards −ve x axis.
Y
X
×
B
I
24. A current carrying loop is placed in a uniform magnetic field in four different orientations, I, II, III & IV,
arrange them in the decreasing order of Potential Energy.
I
nˆ
B
II
nˆ
B
III
nˆ
B
IV nˆ
B
(A) I > III > II > IV (B) I > II > III > IV
(C) I > IV > II > III (D) III > IV > I > II
25*. 2 kg of ice at −20°C is mixed with 5 kg of water at 20°C in an insulating vessel having a negligible
heat capacity. Calculate the final mass of water remaining in the container. It is given that the
specific heats of water & ice are 1 kcal/kg/°C & 0.5 kcal/kg/°C while the latent heat of fusion of ice
is 80 kcal/kg.
(A) 7 kg (B) 6 kg
(C) 4 kg (D) 2 kg
26. In the shown arrangement of the experiment of the meter bridge if
AC corresponding to null deflection of galvanometer is x, what
would be its value if the radius of the wire AB is doubled?
(A) x (B) x/4
(C) 4x (D) 2x
R1 R2
G
A B C
x
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IITJEE2003S5
27. The three resistance of equal value are arranged in the different combinations shown below.
Arrange them in increasing order of power dissipation.
I
i
II
i
III
i
IV
i
(A) III < II < IV < I (B) II < III < IV < I
(C) I < IV < III < II (D) I < III < II < IV
28. A nucleus with mass number 220 initially at rest emits an αparticle. If the Q value of the reaction
is 5.5 MeV, calculate the kinetic energy of the αparticle.
(A) 4.4 MeV (B) 5.4 MeV
(C) 5.6 MeV (D) 6.5 MeV
29*. Among the following, the molecule with the highest dipole moment is:
(A) CH
3
Cl (B) CH
2
Cl
2
(C) CHCl
3
(D) CCl
4
30*. Which of the following are isoelectronic and isostructural?
NO
3
–
, CO
3
2–
, ClO
3
–
, SO
3
(A) NO
3
–
, CO
3
2–
(B) SO
3
, NO
3
–
(C) ClO
3
–
, CO
3
2–
(D) CO
3
2–
, SO
3
31.
HOOC
OH
O
2
N
CH
OH
A
2
NaNH moles 2
÷ ÷ ÷ ÷ ÷ → ÷
The product A will be
(A)
OOC
OH
O
2
N
CH
O
(B)
OOC
OH
O
2
N
C
OH
(C)
O
O
2
N
CH
HOOC
O
(D)
OH
O
2
N
C
HOOC
O
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IITJEE2003S6
32. [X] + H
2
SO
4
÷→ [Y] a colourless gas with irritating smell
[Y] + K
2
Cr
2
O
7
+ H
2
SO
4
÷→ green solution
[X] and [Y] is:
(A) SO
3
2–
, SO
2
(B) Cl
–
, HCl
(C) S
2–
, H
2
S (D) CO
3
2–
, CO
2
33*. For H
3
PO
3
and H
3
PO
4
the correct choice is:
(A) H
3
PO
3
is dibasic and reducing (B) H
3
PO
3
is dibasic and non−reducing
(C) H
3
PO
4
is tribasic and reducing (D) H
3
PO
3
is tribasic and non−reducing
34. When MnO
2
is fused with KOH, a coloured compound is formed, the product and its colour is:
(A) K
2
MnO
4
, purple green (B) KMnO
4
, purple
(C) Mn
2
O
3
, brown (D) Mn
3
O
4
black
35. Rate of physiorption increases with
(A) decrease in temperature (B) increase in temperature
(C) decrease in pressure (D) decrease in surface area
36*. Which of the following represents the given mode of hybridisation sp
2
–
sp
2
– sp – sp from left to
right?
(A)
C H
2
CH C N
(B) C H C C CH
(C)
C H
2
C C CH
2
(D)
C H
2
CH
2
37.
: is B ). B ( ) A (
Ni /
2
H ) ii
C 5 0
HCl /
2
NaNO ) i
, DMF
NH
2
)
3
CH (
° − ° ∆
÷ ÷ ÷ ÷ ÷ → ÷ ÷ ÷ ÷ ÷ → ÷ F NO
2
(A)
N H
2
N
CH
3
CH
3
(B)
N H
2
NH
2
(C)
O
2
N N
CH
3
N H
2
(D)
O
2
N NH
2
38. The product of acid hydrolysis of P and Q can be distinguished by
C H
2
CH
3
OCOCH
3
C H
3
OCOCH
3
P =
Q =
(A) Lucas Reagent (B) 2,4−DNP
(C) Fehling’s Solution (D) NaHSO
3
39.
) OH H C ( Anhydrous
H C O
5 2
5 2
5 2
I H C ÷ ÷ ÷ → ÷ +
−
OH
(A) C
6
H
5
OC
2
H
5
(B) C
2
H
5
OC
2
H
5
(C) C
6
H
5
OC
6
H
5
(D) C
6
H
5
I
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IITJEE2003S7
40*. Which has maximum number of atoms?
(A) 24g of C (12) (B) 56g of Fe (56)
(C) 27g of Al (27) (D) 108g of Ag (108)
41.
: is Product Major
O
2
H / H ) ii (
C 100 / NaOH ) i (
+
°
÷ ÷ ÷ ÷ ÷ ÷ → ÷
CHO
CHO
OHC
OHC
(A)
COOH
COOH
HOOC
HOOC
(B)
COOH
HOOC
O H
OH
(C)
O
O
O
O
(D)
CH
2
OH
CH
2
OH
HOH
2
C
HOH
2
C
42. In the electrolytic cell, flow of electrons is from
(A) Cathode to anode in solution
(B) Cathode to anode through external supply
(C) Cathode to anode through internal supply
(D) Anode to cathode through internal supply
43*. In a first order reaction the concentration of reactant decreases from 800 mol/dm
3
to
50 mol/dm
3
is 2 × 10
4
sec. The rate constant of reaction in sec
–1
is:
(A) 2 × 10
4
(B) 3.45 × 10
–5
(C) 1.386 × 10
–4
(D) 2 × 10
–4
44. During depression of freezing point in a solution the following are in equilibrium
(A) liquid solvent, solid solvent (B) liquid solvent, solid solute
(C) liquid solute, solid solute (D) liquid solute solid solvent
45. H
3
BO
3
is:
(A) Monobasic and weak Lewis acid (B) Monobasic and weak Bronsted acid
(C) Monobasic and strong Lewis acid (D) Tribasic and weak Bronsted acid
46*. : is A . A
H / Hg
2
÷ ÷ ÷ → ÷
+ +
Ph C C CH
3
(A)
Ph
O
C H
3
(B)
Ph
C H
3
O
(C)
Ph
OH
C H
3
(D)
Ph
C H
3
OH
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IITJEE2003S8
47. Ethyl ester
excess
MgBr CH
3
÷ ÷ ÷ ÷ → ÷ P. The product P will be
(A)
C H
3
OH
CH
3
C H
3
(B)
C H
3
OH
C
2
H
5
H
5
C
2
(C)
H
5
C
2
OH
C
2
H
5
H
5
C
2
(D)
H
5
C
2
OH
C
2
H
5
H
7
C
3
48. Mixture X = 0.02 mol of [Co(NH
3
)
5
SO
4
]Br and 0.02 mol of [Co(NH
3
)
5
Br]SO
4
was prepared in 2 litre
of solution.
1 litre of mixture X + excess AgNO
3
÷→ Y.
1 litre of mixture X + excess BaCl
2
÷→ Z
No. of moles of Y and Z are
(A) 0.01, 0.01 (B) 0.02, 0.01
(C) 0.01, 0.02 (D) 0.02, 0.02
49. Which of the reaction defines ∆H
f
0
(A) C
(diamond)
+ O
2(g)
÷→ CO
2(g)
(B)
2
1
H
2(g)
+
2
1
F
2(g)
÷→ HF
(g)
(C) N
2(g)
+ 3H
2(g)
÷→ 2NH
3(g)
(D) CO
(g)
+
2
1
O
2(g)
÷→ CO
2(g)
50*.
23
Na is the more stable isotope of Na. Find out the process by which Na
24
11
can undergo
radioactive decay
(A) β
–
emission (B) α emission
(C) β
+
emission (D) K electron capture
51. (Me)
2
SiCl
2
on hydrolysis will produce
(A) (Me)
2
Si(OH)
2
(B) (Me)
2
Si = O
(C) – [ –O – (Me)
2
Si – O – ]
n
– (D) Me
2
SiCl(OH)
52*. A solution which is 10
–3
M each in Mn
2+
, Fe
2+
, Zn
2+
and Hg
2+
is treated with 10
–16
M sulphide ion. If
K
sp
of MnS, FeS, ZnS and HgS are 10
–15
, 10
–23
, 10
–20
and 10
–54
respectively, which one will
precipitate first?
(A) FeS (B) MgS
(C) HgS (D) ZnS
53. In the process of extraction of gold,
Roasted gold ore + CN
–
+ H
2
O ÷ ÷→ ÷
2
O
[X] + OH
–
[X] + Zn ÷→ [Y] + Au
Identify the complexes [X] and [Y]
(A) X = [Au(CN)
2
]
–
, Y = [Zn(CN)
4
]
2–
(B) X = [Au(CN)
4
]
3–
, Y = [Zn(CN)
4
]
2–
(C) X = [Au(CN)
2
]
–
, Y = Zn(CN)
6
]
4–
(D) X = [Au(CN)
4
]
–
, Y = [Zn(CN)
4
]
2–
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IITJEE2003S9
54*. Positive deviation from ideal behaviour takes place because of
(A) Molecular interaction between atoms and PV/nRT > 1
(B) Molecular interaction between atoms and PV/nRT < 1
(C) Finite size of atoms and PV/nRT > 1
(D) Finite size of atoms and PV/nRT < 1
55*.
43 42 1
possible are
products such 5
2 8 4
4
CCl ,
2
r B
O
2
H
H
Br H C ] F [ ÷ ÷ ÷ → ÷ ÷→ ÷
−
+
C H
3
CH
3
OH
How many structures of F is possible?
(A) 2 (B) 5
(C) 6 (D) 3
56. An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral
carbon. The ester formed will be
(A) Optically active mixture (B) Pure enantiomer
(C) Meso compound (D) Racemic mixture
57. If f : [0, ∞) → [0, ∞), and f (x) =
x 1
x
+
then f is
(A) one−one and onto (B) one−one but not onto
(C) onto but not one−one (D) neither one−one nor onto
58. If P (B) =
4
3
, P (A ∩ B ∩C) =
3
1
and P ( A ∩ B ∩ C) =
3
1
, then P (B ∩ C) is
(A)
12
1
(B)
6
1
(C)
15
1
(D)
9
1
59. In [0, 1] Lagranges Mean Value theorem is NOT applicable to
(A) f(x) =
¦
¦
¹
¦
¦
´
¦
≥ 
.

\

−
< −
2
1
x , x
2
1
2
1
x , x
2
1
2
(B) f(x) =
¦
¹
¦
´
¦
=
≠
0 x , 1
0 x ,
x
x sin
(C) f(x) = xx (D) f(x) = x
60*. The area of the quadrilateral formed by the tangents at the end points of latus recta to the ellipse
5
y
9
x
2 2
+ = 1, is
(A) 27/4 sq. units (B) 9 sq. units
(C) 27/2 sq. units (D) 27 sq. units
61*. The number of integral points (integral point means both the coordinates should be integer)
exactly in the interior of the triangle with vertices (0, 0), (0, 21) and (21, 0), is
(A) 133 (B) 190
(C) 233 (D) 105
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IITJEE2003S10
62. If A =
α
1 1
0
and B =
1 5
0 1
, then value of α for which A
2
= B, is
(A) 1 (B) − 1
(C) 4 (D) no real values
63. The value of k such that
2
k z
1
2 y
1
4 x −
=
−
=
−
lies in the plane 2x − 4y + z = 7, is
(A) 7 (B) − 7
(C) no real value (D) 4
64*. If the angles of a triangle are in the ratio 4 : 1 : 1, then the ratio of the longest side to the
perimeter is
(A) 3 : (2 + 3 ) (B) 1 : 6
(C) 1 : 2 + 3 (D) 2 : 3
65. If
2
0 x
x
nx sin ) x tan nx ) n a ((
lim
− −
→
= 0, where n is nonzero real number, then a is equal to
(A) 0 (B)
n
1 n +
(C) n (D) n +
n
1
66. Two numbers are selected randomly from the set S = {1, 2, 3, 4, 5, 6} without replacement one by
one. The probability that minimum of the two numbers is less than 4 is
(A) 1/15 (B) 14/15
(C) 1/5 (D) 4/5
67*. For hyperbola 1
sin
y
cos
x
2
2
2
2
=
α
−
α
which of the following remains constant with change in ‘α’
(A) abscissae of vertices (B) abscissae of foci
(C) eccentricity (D) directrix
68. Range of the function f (x) =
1 x x
2 x x
2
2
+ +
+ +
; x ∈ R is
(A) (1, ∞) (B) (1, 11/ 7]
(C) (1, 7/ 3] (D) (1, 7/ 5]
69.
) 1 ( f ) 1 h h ( f
) 2 ( f ) h 2 h 2 ( f
lim
2
2
0 h
− + −
− + +
→
, given that f ′ (2) = 6 and f′ (1) = 4
(A) does not exist (B) is equal to − 3/ 2
(C) is equal to 3/ 2 (D) is equal to 3
70*. If f (x) = x
2
+ 2bx + 2c
2
and g (x) = − x
2
− 2cx + b
2
such that min f (x) > max g (x), then the relation
between b and c, is
(A) no real value of b and c (B) 0 < c < b 2
(C) c < b 2 (D) c > b 2
71*. The centre of circle inscribed in square formed by the lines x
2
− 8x + 12 = 0 and
y
2
− 14y + 45 = 0, is
(A) (4, 7) (B) (7, 4)
(C) (9, 4) (D) (4, 9)
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IITJEE2003S11
72*. The focal chord to y
2
= 16x is tangent to (x – 6)
2
+ y
2
= 2, then the possible values of the slope of
this chord, are
(A) {−1, 1} (B) {−2, 2}
(C) {−2, 1/2} (D) {2, −1/2}
73. Domain of definition of the function f(x) = ( )
6
x 2 sin
1
π
+
−
for real valued x, is
(A)
−
2
1
,
4
1
(B)
−
2
1
,
2
1
(C) 
.

\

−
9
1
,
2
1
(D)
−
4
1
,
4
1
74*. If z = 1 and ω =
1 z
1 z
+
−
( where z ≠ −1), then Re(ω) is
(A) 0 (B) 
2
1 z
1
+
(C)
2
 1 z 
1
1 z
z
+
⋅
+
(D)
2
 1 z 
2
+
75*. If α ∈ 
.

\
 π
2
, 0 then
x x
tan
x x
2
2
2
+
α
+ + is always greater than or equal to
(A) 2 tanα (B) 1
(C) 2 (D) sec
2
α
76. If I(m, n) = ( )
∫
+
1
0
n m
dt t 1 t , then the expression for I(m, n) in terms of I(m + 1, n  1) is
(A) ( ) 1 n , 1 m I
1 m
n
1 m
2
n
− +
+
−
+
(B) ( ) 1 n , 1 m I
1 m
n
− +
+
(C) ( ) 1 n , 1 m I
1 m
n
1 m
2
n
− +
+
+
+
(D) ( ) 1 n , 1 m I
1 n
m
− +
+
77. If f (x) =
∫
+
−
1 x
x
t
2
2
2
e dt, then f (x) increases in
(A) (2, 2) (B) no value of x
(C) (0, ∞) (D) (−∞, 0)
78. The area bounded by the curves y = x , 2y + 3 = x and x−axis in the I
st
quadrant is
(A) 9 (B) 27/4
(C) 36 (D) 18
79*. Coefficient of t
24
in (1 + t
2
)
12
(1 + t
12
) (1 + t
24
) is
(A)
12
C
6
+ 3 (B)
12
C
6
+ 1
(C)
12
C
6
(D)
12
C
6
+ 2
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IITJEE2003S12
80. The value of ‘a’ so that the volume of parallelopiped formed by k
ˆ
a j
ˆ
, k
ˆ
j
ˆ
a i
ˆ
+ + + and k
ˆ
i
ˆ
a +
becomes minimum is
(A) − 3 (B) 3
(C) 1/ 3 (D) 3
81. If the system of equations x + ay = 0, az + y = 0 and ax + z = 0 has infinite solutions, then the
value of a is
(A) − 1 (B) 1
(C) 0 (D) no real values
82. If y(t) is a solution of ( ) 1 ty
dt
dy
t 1 = − + and y(0) = 1, then y(1) is equal to
(A) − 1/2 (B) e + 1/2
(C) e − 1/2 (D) 1/2
83*. Tangent is drawn to ellipse 1 y
27
x
2
2
= + at ( ) θ θ sin , cos 3 3 (where θ ∈ (0, π/2)). Then the value
of θ such that sum of intercepts on axes made by this tangent is minimum, is
(A) π/3 (B) π/6
(C) π/8 (D) π/4
84*. Orthocentre of triangle with vertices (0, 0), (3, 4) and (4, 0) is
(A) 
.

\

4
5
, 3 (B) (3, 12)
(C) 
.

\

4
3
, 3 (D) (3, 9)
Note: FIITJEE solutions to IIT−JEE, 2003 Screening Test is based on Screening Test paper created using
memory retention of select FIITJEE students appeared in this test. Every effort has been made to
reproduce the original paper in the interest of the aspirant students, yet FIITJEE does not guarantee
its authenticity.
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IITJEE2003S13
A
A
n
n
s
s
w
w
e
e
r
r
s
s
1. C 2. A 3. A
4. B 5. A 6. C
7. A 8. B 9. C
10. B 11. B 12. A
13. D 14. A 15. B
16. A 17. 18. B
19. A 20. A 21. B
22. A 23. B 24. C
25. B 26. A 27. A
28. B 29. A 30. A
31. A 32. A 33. A
34. A 35. A 36. A
37. A 38. C 39. A
40. A 41. B 42. C
43. C 44. A 45. A
46. A 47. A 48. A
49. B 50. A 51. C
52. C 53. A 54. A
55. D 56. A 57. B
58. A 59. A 60. D
61. B 62. D 63. A
64. A 65. D 66. D
67. B 68. C 69. D
70. D 71. A 72. A
73. A 74. A 75. A
76. A 77. D 78. A
79. D 80. C 81. A
82. A 83. B 84. C
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IITJEE2003S14
H
H
i
i
n
n
t
t
s
s
&
&
S
S
o
o
l
l
u
u
t
t
i
i
o
o
n
n
1. Electric field is perpendicular to the equipotential surfaces and is zero everywhere inside the
metal.
2. For no motion
Fcos60° ≤ u(mg + Fsin60°)
⇒ F/2 ≤
3 2
1
( 3 ×g +
2
3 F
)
⇒ F/2 ≤ g
⇒ F
max
= 20 N
F.B.D.
Fcos60°
mg
f
Fsin60°
3. Applying conservation of angular momentum about centre of the rod
I
cm
ω = J
2
L
⇒
2
2
L
M 2 
.

\

× = MV ×
2
L
⇒ ω = V/L
4. In a conservative field work done does not depend on the path.
∴ W
1
= W
2
= W
3
5. V = l
3
= (1.2 × 10
−2
m)
3
= 1.728 × 10
−6
m
3
Q l has two significant figure. Hence V will also have two significant figure.
6. E
x
> E
y
& a
x
> a
y
Q E/a = constant
7. Y =
4 6
10 10
1 20
A
F
− −
×
×
=
∆
l
l
= 2 × 10
11
N/m
2
8. For constructive interference ∆φ = (dsecθ + dsecθ cos2θ)
λ
π 2
+ π = 2nπ
⇒ cosθ =
( )
d 4
1 n 2 λ −
9. l
1
α
a
t = l
2
α
s
t
⇒
s
a
1
2
α
α
=
l
l
⇒
s
s a
1
1 2
α
α + α
=
+
l
l l
⇒
s a
s
2 1
1
α + α
α
=
+ l l
l
10. For concave lens
20
1
4
1
v
1
−
= − ⇒ v = 5 cm
 u 
 v 
h
h
1
2
= ⇒ h
2
= 2 ×
4
5
= 2.5 cm
11. Using Snell’s law
(1) sin90° = u
glass
sini
u
glass
= 1/sini
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IITJEE2003S15
12. F =
dr
dU
−
r
mv
2
=
⇒ v =
m
r v
0
which is a constant
mv
n
r
n
=
π 2
nh
r
n
∝ n
13. r
n
=
Z
m
2
(0.53)A°
(r
n
)
Fm
=
( )
100
A 53 . 0 m
2
°
= 0.53 A°×n
m is 5 for Z = 100
⇒ n = 1/4
14. Circuit is RC circuit
tan
4
π
=
ω RC
1
⇒ R =
C
1
ω
15. Plane of motion must be perpendicular to at least one of the component of the magnetic field.
16. Ammeter is always connected in series and voltmeter is always connected in parallel
17. Out of the alternatives provided, none appears completely correct.
18. f
1
= frequency of the police car heard by motorcyclist.
f
2
= frequency of the siren heard by motorcyclist.
f
1
= 176
22 330
v 330
×
−
−
;
f
2
= 165
330
v 330
×
+
Q f
1
− f
2
= 0
⇒ v = 22 m/s
19. Since nuclear density is constant hence mass α volume.
⇒ m ∝ V
21.
( ) x 4
v
1
+ l
=
( ) x 4
v 3
2
+ l
x = 2.5 cm
22. About the centre of circle the torque of the force causing the circular motion is zero.
24. U = −u
r
. B
r
25. m
ice
C
ice
[0 − (−20)] + m′L + m
water
C
water
[0−20] = 0
m′ = 1 kg
mass of water = 6 kg
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IITJEE2003S16
27. Power dissipated ∝ R
equivalent
28. Applying conservation of linear momentum and COE
∴KE
α
= 5.4 MeV
29. Methane molecule being symmetrical, has zero dipole moment. Replacement of one of the H−
atoms by Cl atom increases the dipole moment. The increase in dipole moment is rather more
than what can be expected because of the fact that the bond dipole moment of C – H bond and
that of C – Cl bond reinforce one another. Replacement of another H atom of Cl increases the
bond angle due to lone pair − lone pair repulsion between two Cl−atoms thereby reducing the
dipole moment of the molecule. Increase in angle is again caused by the introduction of third Cl−
atom. When the fourth Cl−atom is introduced, the molecule (CCl
4
) again becomes symmetrical
and dipole moment reduces to zero. So, CH
3
Cl will have the maximum dipole moment.
30.
−
3
NO and
− 2
3
CO both have same number of electrons (equal to 32) and central atom in each
being sp
2
hybridised, are isostructural too
31. Two moles of
2
H N
−
ions will abstract two moles of most acidic hydrogen out of the four moles of
hydrogen present per mole of the acidic compound. The acidic strength is in the order:
– COOH > – OH (phenolic deactivated by NO
2
group) > – OH (phenolic) > alkynic H.
32. SO
2
and H
2
S both being reducing agents, can turn acidified dichromate solution green. SO
2
can
be obtained by the action of acid upon sulphite while H
2
S is evolved by the action of acid upon
sulphide. However, SO
2
has a burning sulphur smell which is irritating. H
2
S has rotten egg like
smell.
33. The structure of H
3
PO
3
is as follows: There are only two –OH groups and hence
dibasic. The oxidation number of P in this acid is +3. Whereas P may have +5
oxidation state also. Therefore, H
3
PO
3
can be oxidised which means H
3
PO
3
is a
reducing agent.
P
H
O
OH
OH
34. Stable oxidation state of Mn in alkaline medium is +6. So, MnO
2
is oxidised to K
2
MnO
4
by
atomospheric oxygen in KOH medium.
2MnO
2
+ 4KOH + O
2
÷→ 2K
2
MnO
4
+ 2H
2
O
35. Rate of physiorsption increases with decrease of temperature
36.
C H
2
CH C CH
from left to right
2
sp
2
sp
sp
sp
37.
on substituti
aromatic
ic Nucleophil
NH ) CH (
2 3
÷ ÷ ÷ ÷ → ÷ F NO
2
° −
+
÷ ÷ ÷ ÷ ÷ → ÷
5 0 , Ni / H ) ii
HCl NaNO ) i
2
2
N NO
2
C H
3
C H
3
N NH
2
C H
3
C H
3
(A) (B)
38.
÷ ÷ ÷ → ÷
+
H / O
2
H
P C H
2
CH
3
OH
C H
3
CH
3
O
÷ ÷ ÷ → ÷
+
H / O
2
H
Q
C H
3
OH
C H
3
CHO
Ketone (non−reducing) and aldehyde (reducing) can be distinguished by Fehling solution.
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IITJEE2003S17
39. C
2
H
5
O
–
will abstract proton from phenol converting the latter into phenoxide ion. This would then
make nucleophilic attack on the methylene carbon of alkyl iodide. But C
2
H
5
O
–
is in excess.
C
2
H
5
O
–
is better nucleophile than C
6
H
5
O
–
(phenoxide) ion since while in the former the negative
charge is localised over oxygen and in the latter it is delocalised over the whole molecular
framework. So, it is C
2
H
5
O
–
ion that would make nucleophilic attack at ethyl iodide to give diethyl
ether (Williamson’s synthesis).
C H
3
O

−
+ I
I
C H
3
C H
3
O CH
3
+
40. 24g carbon amounts to 2 mole i.e. 2 × 6.023 × 10
23
atoms whereas all the rest amount to 1 mole
each only.
41.
CHO
CHO
OHC
OHC
reaction Cannizaro
ular intramolec
100 / OH
÷ ÷ ÷ → ÷
°
−
CH
2
OH
COO


OOC
HOH
2
C
÷ ÷ ÷ → ÷
+
O 2 H / H
CH
2
OH
COOH
HOOC
HOH
2
C
42. In an electrolytic cell electrons do not flow themselves. It is the migration of ions towards
oppositely charged electrons that indirectly constitutes the flow of electrons from cathode to
anode through internal supply.
43. K =
t
0
] A [
] A [
log
t
303 . 2
=
50
800
log
10 2
303 . 2
4
×
= 1.386 × 10
4
s
–1
44. At the freezing point liquid and solid remain in equilibrium. If a solution of a non−volatile solute is
cooled to a temperature below the freezing point of solution, some of liquid solvent will separate
as a solid solvent and thus the concentration of solution will increase.
45. The central boron atom in boric acid, H
3
BO
3
is electron−deficient i.e. boric acid is a Lewis acid
with one p−orbital vacant. There is no d−orbital of suitable energy in boron atom. So, it can
accommodate only one additional electron pair in its outermost shell.
B

OH
2
O H
OH
OH
+ −
+ H ] ) OH ( B [
4
÷→ ÷ +
•
•
Acid
3
Base
2
) OH ( B O H
46.
Ph
CH
3
÷→ ÷
+
H
Ph C
+
CH
3
Ph
O
+
CH
3
C H
3
C H
3
Ph
O H
C H
3
Ph
O
C H
3
H
2
O
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IITJEE2003S18
47.
R
OC
2
H
5
O
÷→ ÷ + MgBr CH
3
OC
2
H
5
O

R
CH
3
−
+ O H C
5 2
R
CH
3
O
÷→ ÷
CH
3
XMgO
R
CH
3
÷ ÷ ÷ ÷ ←
+
H / HOH
CH
3
O H
R
CH
3
CH
3
MgX
Thus, the choice with at least two methyl groups at the carbon linked with –OH group will be the
correct choice.
48.
mole 01 . 0
mole 01 . 0
Excess
AgBr Br Ag ÷→ ÷ +
− +
mole 01 . 0
4
mole 01 . 0
2
4
Excess
2
BaSO SO Ba ÷→ ÷ +
− +
50.
p
n
ratio of
24
Na nuclide is
11
13
i.e. greater than unity and hence radioactive. To achieve stability, it
would tend to adjust its
p
n
ratio to the proper value of unity. This can be done by breaking a
neutron into proton and electron.
−
−
+ β + ÷→ ÷ or e p n
0
1
1
1
1
0
The proton will stay inside the nucleus whereas electron which cannot exist in the nucleus, will be
emitted out as β−ray.
51. It appears at the first sight that Me
2
SiCl
2
on hydrolysis will produce Me
2
Si(OH)
2
which ultimately
upon loss of water, will form Me
2
Si = O. But silicon atom, because of its very large size in
comparison to oxygen, is unable to form π−bond. Thus, the product of hydrolysis is polymeric in
nature.
52. HgS having the lowest K
sp
among the lot will precipitate first.
53. 2Au + 4CN
–
+ H
2
O +
2
1
O
2
÷→ 2[Au(CN)
2
]
–
+ 2OH
–
2[Au(CN)
2
]
–
+ Zn ÷→ [Zn(CN)
4
]
2–
+ 2Au
54. For positive deviation: PV = nRT + nPb
Thus, the factor nPb is responsible for increasing the PV value above ideal value. b is actually the
effective volume of molecule. So, it is the finite size of molecules that leads to the origin of b and
hence positive deviation at high pressure.
55*.
O 2 H
H
−
+
÷→ ÷
C H
3
OH
OH
C H
3
CH
3
(cis and trans)
+
C H
3
CH
2
56. The optically active acid will react with d and l forms of alcohol present in the racemic mixture to
form two types of isomeric esters. In each the configuration of the chiral centre of acid will remain
the same. So the mixture will be optically active.
57. f′(x) =
2
) x 1 (
1
+
> 0 ∀ x ∈ [0, ∞) and range ∈ [0, 1) ⇒ function is one−one but not onto
58. From venn diagram, we can see that
P (B ∩ C) = P (B) − P (A ∩ B ∩ C ) − P ( A ∩ B ∩ C )
=
12
1
3
1
3
1
4
3
= − − .
A
B
C
C B A ∩ ∩
C B A ∩ ∩
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IITJEE2003S19
59. The function defined in (A) is not differentiable at x = 1/2.
60. By symmetry the quadrilateral is a rhombus. So area is four times the area of the right angled
triangle formed by the tangent and axes in the I
st
quadrant.
Now, ae =
2 2
b a − ⇒ ae = 2
⇒ tangent (in first quadrant) at end of latus rectum 
.

\

3
5
, 2 is
9
2
x +
3
5
5
y
= 1 i.e.
3
y
2 / 9
x
+ = 1
Area = 4.
2
9
2
1
⋅ .3 = 27 sq units.
61. Number of points exactly in the interior of the triangle =
2
20 20 20 − ×
= 190.
62. A
2
=
α
1 1
0
α
1 1
0
=
+ α
α
1 1
0
2
clearly, no real value of α.
63. Point (4, 2, k) should lie in the given plane ⇒ 2 (4) − 4 (2) + 1 (k) = 7 ⇒ k = 7.
64. Angles are 30°, 30° and 120°. Hence sides are x, x and 2x cos30° ratio is
0
0
30 cos x 2 x 2
30 cos x 2
+
⇒ 3 : (2 + 3 ).
65. 
.

\

− − ⋅
→ → x
x tan
n ) n a ( lim
nx
nx sin
n lim
0 x 0 x
= 0 ⇒ n ((a−n)n− 1) = 0 ⇒ (a − n)n = 1 ⇒ a = n +
n
1
.
66. Total ways 2!
6
C
2
= 30. Favourable cases = 30 − 6 = 24. Probability =
5
4
30
24
=
67. ae =
2 2
b a + = α + α
2 2
sin cos = 1.
68. f(x) =
4
3
2
1
x
1
1
2
+ 
.

\

+
+ ⇒ Range = (1, 7/ 3].
69.
) 1 ( f ) 1 h h ( f
) 2 ( f ) h 2 h 2 ( f
lim
2
2
0 h
− + −
− + +
→
=
) h 2 1 )( 1 h h ( f
) h 2 2 )( h 2 h 2 ( f
lim
2
2
0 h
− + − ′
+ + + ′
→
=
1 4
2 6
×
×
= 3.
70. f(x) = (x + b)
2
+ 2c
2
− b
2
and g (x) = b
2
+ c
2
− (x + c)
2
⇒ 2c
2
− b
2
> b
2
+ c
2
⇒ c > 2 b.
71. Centre is (4, 7).
(2, 5)
(6, 9)
y = 5
y = 9
x = 2 x = 6
x
y
72. From diagram θ = 45° ⇒ slope = ± 1
√2 √2
(6, 0) (4, 0) 2
θ
FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi  16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
IITJEE2003S20
73. −
6
π
≤ sin
1
(2x) ≤
2
π
⇒
2
1
− ≤ 2x ≤ 1 ⇒ x ∈
−
2
1
,
4
1
74. arg (ω) = ±
2
π
⇒ ω is purely imaginary.
Re(ω) = 0
z
(1, 0) (1, 0) O
75.
x x
tan
x x
2
2
2
+
α
+ + ≥ 2 tanα (AM ≥ GM)
76. I(m , n) = ( )
∫
+
1
0
n m
dt t 1 t = (1 + t)
n
( )
∫
+
+ −
+
+
−
+
1
0
1 m
1 n
1
0
1 m
dt
1 m
t
t 1 n
1 m
t
= ( ) 1 n , 1 m I
1 m
n
1 m
2
n
− +
+
−
+
.
77. f′(x) =
2
) 1
2
x (
e
+ −
. 2x −
2 2
) x (
e
−
. 2x = 2x ( )
1 x 2 ) x 2 1 x (
2 2 4
e 1 e
+ + + −
− ⇒ f′ (x) > 0 ∀ x ∈ (− ∞, 0).
78. y
2
= 2y + 3 ⇒ y = 3
The required area
=
∫
− +
3
0
2
) y 3 y 2 ( dy = y
2
+ 3y −
3
0
3
3
y
= 9 + 9 − 9 = 9.
(3, 0)
x = y
2
(9, 3)
x = 2y + 3
x
y
79. (1 + t
2
)
12
(1 + t
12
) (1 + t
24
) = (1 + t
2
)
12
(1 + t
12
+ t
24
+ t
36
)
⇒ coefficient of t
24
is
12
C
12
+
12
C
6
+ 1 =
12
C
6
+ 2.
80. V =
1 0 a
a 1 0
1 a 1
= 1 + a
3
− a ⇒ =
da
dV
3a
2
− 1 = 3


.

\

−


.

\

+
3
1
a
3
1
a ⇒ Minimum at
3
1
.
81.
1 0 a
a 1 0
0 a 1
= 0 ⇒ 1 + a (a
2
) = 0 ⇒ a
3
= − 1 ⇒ a = − 1.
82. By multiplying e
−t
and rearranging the terms, we get
e
−t
(1 + t)dy + y(e
−t
− (1 + t)e
−t
)dt = e
−t
dt
⇒ d(e
−t
(1 + t)y) = d(−e
−t
) ⇒ ye
−t
(1 + t) = − e
−t
+ c. Also y
0
= 1 ⇒ c = 0 ⇒ y(1) =  1/2.
83. 1 sin y
3 3
cos x
= θ +
θ
. Sum of intercepts θ + θ ec cos sec 3 3 = f(θ) (say)
( )
θ θ
θ − θ
= θ ′
2 2
3 3
cos sin
cos sin 3 3
f ⇒ At θ = π/6, f(θ) is minimum.
84. From figure tanθ =
4
1
=
3
k
⇒ k =
4
3
A(3, 4)
B(4, 0) O(0, 0)
• (3, k)
θ
θ
3 1
x
y
IITJEE2003S2
7*.
The adjacent graph shows the extension (∆l) of a wire of length 1 m suspended from the top of a roof at one end and with a load W connected to the other end. If the crosssectional area of the wire is 10−6 m2, calculate the Young’s modulus of the material of the wire. (B) 2 × 10−11 N/m (A) 2 × 1011 N/m −12 (D) 2 × 10−13 N/m (C) 3 × 10 N/m In the adjacent diagram, CP represents a wavefront and AO & BP, the corresponding two rays. Find the condition on θ for constructive interference at P between the ray BP and reflected ray OP. (A) cosθ=3λ/2d (B) cosθ = λ/4d (C) secθ − cosθ =λ/d (D) secθ−cosθ=4λ/d
Q
∆l(×10−4m) 4 3 2 1 W (N) 20
O θ θ d C
40 60
80
R
8.
A B
P
9*.
Two rods, one of aluminum and the other made of steel, having initial length l1 and l2 are connected together to form a single rod of length l1 + l2. The coefficients of linear expansion for aluminum and steel are αa and αs respectively. If the length of each rod increases by the same amount when their temperature are raised by t°C, then find the ratio l 1 (l 1 + l 2 ) . (A) αs/αa (B) αa/αs (C) α s (α a + α s ) (D) α a (α a + α s ) The size of the image of an object, which is at infinity, as formed by a convex lens of focal length 30 cm is 2 cm. If a concave lens of focal length 20 cm is placed between the convex lens and the image at a distance of 26 cm from the convex lens, calculate the new size of the image. (A) 1.25 cm (B) 2.5 cm (C) 1.05 cm (D) 2 cm A ray of light is incident at the glasswater interface at an angle i, it emerges finally parallel to the surface of water, then the value of µg would be (A) (4/3)sini (B) 1/sini (C) 4/3 (D) 1
Air r Water Glass r µW = 4/3
10.
11.
i
12.
r , where r0 is a r0 constant. Assuming Bohr’s model to be applicable, write variation of rn with n, n being the principal quantum number? (A) rn ∝ n (B) rn ∝ 1/n (D) rn ∝ 1/n2 (C) rn ∝ n2
The electric potential between a proton and an electron is given by V = V0 ln If the atom 100Fm257 follows the Bohr model and the radius of then find n. (A) 100 (B) 200 (C) 4 (D) 1/4
257 100Fm
13.
is n times the Bohr radius,
14.
When an AC source of emf e = E0 sin(100t) is connected across a circuit, the phase difference between the emf e and the current i in the circuit is observed to be π/4, as shown in the diagram. If the circuit consists possibly only of RC or RL or LC in series, find the relationship between the two elements. (A) R = 1 kΩ, C = 10 µF (B) R = 1 kΩ, C=1 µF (C) R = 1 kΩ, L = 10 H (D) R = 1 kΩ, L = 1 H
i
e
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New Delhi .IITJEE2003S3 15.16. there is a sudden change in its path due to the presence of electric and/or magnetic fields beyond P. where AC is an adiabatic process. Which one of the following combinations is possible? r r r r ˆ ˆ (A) E = 0. (A) 33 m/s (B) 22 m/s (C) zero (D) 11 m/s Motorcycle Stationary Siren (165 Hz) V 19. A V (C) A (D) V V A 17*. The police man sounds his horn at 176 Hz. Sarvapriya Vihar (Near Hauz Khas Bus Term. ICES House. 26515949 Fax : 26513942 . 26965626. Police Car A police car moving at 22 m/s. B = c j (D) E =a i j Express which of the following setups can be used to verify Ohm’s law? (B) (A) A V y P x 16. B = ck + b ˆ ˆ ˆ (C) E = 0. chases a motorcyclist. (A) A P B V C A P B C T (B) A P C V B (D) A P B V C (D) A P C V B 18*. Ph : 2686 5182. The curved path is shown in the xy plane and is found to be noncircular. The PT diagram for an ideal gas is shown in the figure. find the corresponding PV diagram. For a positively charged particle moving in a xy plane initially along the xaxis. while both of them move towards a 22 m/s stationary siren of frequency 165 Hz. B = b ˆ + c k i (B) E = a ˆ . if it is given that he does not observes any beats. Calculate the 176 Hz speed of the motorcycle. B =c k + a ˆ i i r r r r ˆ + bk ˆ . For uranium nucleus how does its mass vary with volume? (A) m ∝ V (B) m ∝ 1/V (C) m ∝ √V (D) m ∝ V2 FIITJEE Ltd.). 2685 4102.
with a tuning fork is 0. I II B ˆ n B ˆ n IV III B ˆ n B ˆ n (A) I > III > II > IV (C) I > IV > II > III 25*. The loop will have a tendency to (A) contract (B) expand (C) move towards +ve xaxis (D) move towards −ve x axis.024 m A particle undergoes uniform circular motion. About which point on the plane of the circle. X I 24. 23. Identify the graph which represents the variation of potential energy (PE) as a function of time t and displacement x. (A) I. It is given that the specific heats of water & ice are 1 kcal/kg/°C & 0. Calculate the end correction. III I PE II t III PE IV x (B) II. (B) I > II > III > IV (D) III > IV > I > II 2 kg of ice at −20°C is mixed with 5 kg of water at 20°C in an insulating vessel having a negligible heat capacity. 26965626. Calculate the final mass of water remaining in the container.5 kcal/kg/°C while the latent heat of fusion of ice is 80 kcal/kg. III (C) II. will the angular momentum of the particle remain conserved? (A) centre of the circle (B) on the circumference of the circle.05 m (D) 0. (D) outside the circle.1 m. ICES House. R1 G A x C R2 B FIITJEE Ltd. A conducting loop carrying a current I is placed in a uniform magnetic field pointing into the plane of the paper as shown. 26515949 Fax : 26513942 .). B × Y 22*. (C) inside the circle. A current carrying loop is placed in a uniform magnetic field in four different orientations. the length of the air column that resonates in the fundamental mode. When this length is changed to 0. I. 2685 4102. arrange them in the decreasing order of Potential Energy. IV (D) I.35 m.16. New Delhi . (A) 0. Ph : 2686 5182.025 m (C) 0. III & IV. Sarvapriya Vihar (Near Hauz Khas Bus Term. In the experiment for the determination of the speed of sound in air using the resonance column method. what would be its value if the radius of the wire AB is doubled? (A) x (B) x/4 (C) 4x (D) 2x 26. the same tuning fork resonates with the first overtone. (A) 7 kg (B) 6 kg (C) 4 kg (D) 2 kg In the shown arrangement of the experiment of the meter bridge if AC corresponding to null deflection of galvanometer is x. IV 21*. For a particle executing SHM the displacement x is given by x = A cosωt. II.012 m (B) 0.IITJEE2003S4 20.
).4 MeV (B) 5. 26515949 Fax : 26513942 . ClO3–. (A) 4. 31.5 MeV Among the following. New Delhi . (B) II < III < IV < I (D) I < III < II < IV A nucleus with mass number 220 initially at rest emits an αparticle. Sarvapriya Vihar (Near Hauz Khas Bus Term. The three resistance of equal value are arranged in the different combinations shown below. the molecule with the highest dipole moment is: (B) CH2Cl2 (A) CH3Cl (D) CCl4 (C) CHCl3 Which of the following are isoelectronic and isostructural? NO3–.IITJEE2003S5 27. If the Q value of the reaction is 5. NO3– (A) NO3–. CO32– – 2– (D) CO32–.6 MeV (D) 6. ICES House.16. II I i i III IV i i (A) III < II < IV < I (C) I < IV < III < II 28. CO32–. Arrange them in increasing order of power dissipation. SO3 (B) SO3. 30*. 2685 4102. O 2N CH OH The product A will be OOC OH OOC OH (A) O 2N CH O (B) O 2N C OH HOOC HOOC O OH (C) O 2N CH O (D) O 2N C O FIITJEE Ltd. 26965626. calculate the kinetic energy of the αparticle.4 MeV (C) 5. Ph : 2686 5182. SO3 (C) ClO3 .5 MeV. CO3 HOOC OH 2 moles NaNH 2 → A 29*.
ICES House. CO2 (C) S . 2685 4102.16.). Which of the following represents the given mode of hybridisation sp2 – sp2 – sp – sp from left to right? (B) HC C C CH (A) H2C CH C N (C) H2C C C CH2 (D) H2C CH2 37.IITJEE2003S6 32. H2S For H3PO3 and H3PO4 the correct choice is: (A) H3PO3 is dibasic and reducing (C) H3PO4 is tribasic and reducing 33*. The product of acid hydrolysis of P and Q can be distinguished by OCOCH3 P = H2C CH3 Q= OCOCH3 H3C (A) Lucas Reagent (C) Fehling’s Solution 39. 26515949 Fax : 26513942 . OH O + C2H5I C2H5 → − (B) 2. 26965626. Ph : 2686 5182.4−DNP (D) NaHSO3 Anhydrous ( C 2H5OH ) (A) C6H5OC2H5 (C) C6H5OC6H5 (B) C2H5OC2H5 (D) C6H5I FIITJEE Ltd. the product and its colour is: (B) KMnO4. SO2 2– (D) CO32–. Sarvapriya Vihar (Near Hauz Khas Bus Term. a coloured compound is formed. brown Rate of physiorption increases with (A) decrease in temperature (C) decrease in pressure 35. purple (A) K2MnO4. New Delhi . HCl (A) SO32–. When MnO2 is fused with KOH. (B) H3PO3 is dibasic and non−reducing (D) H3PO3 is tribasic and non−reducing 34. F NO2 3 2 2 →( A ) →(B). [X] + H2SO4 → [Y] a colourless gas with irritating smell [Y] + K2Cr2O7 + H2SO4 → green solution [X] and [Y] is: (B) Cl–. B is : DMF. (B) increase in temperature (D) decrease in surface area 36*. purple green (D) Mn3O4 black (C) Mn2O3. ∆ 0 ° − 5 °C ii) H2 / Ni ( CH ) NH i) NaNO / HCl CH3 (A) H2N N CH3 (B) H2N NH2 CH3 (C) O 2N N (D) H2N O 2N NH2 38.
New Delhi . (B) Monobasic and weak Bronsted acid (D) Tribasic and weak Bronsted acid 46*. ICES House.). 26965626.16. flow of electrons is from (A) Cathode to anode in solution (B) Cathode to anode through external supply (C) Cathode to anode through internal supply (D) Anode to cathode through internal supply In a first order reaction the concentration of reactant decreases from 800 mol/dm3 to 50 mol/dm3 is 2 × 104 sec.45 × 10–5 (A) 2 × 104 –4 (D) 2 × 10–4 (C) 1. solid solvent (B) liquid solvent. In the electrolytic cell. solid solute (C) liquid solute. solid solute (D) liquid solute solid solvent H3BO3 is: (A) Monobasic and weak Lewis acid (C) Monobasic and strong Lewis acid Ph C C O Ph Hg / CH3 H → A. Ph : 2686 5182. The rate constant of reaction in sec–1 is: (B) 3. A is : 2+ + 43*. Ph (A) H3C OH Ph (B) H3C Ph O (C) H3C (D) H3C OH FIITJEE Ltd.IITJEE2003S7 40*. 2685 4102. (i)NaOH / 100 → Major Product is : °C + (ii)H / H2O CHO COOH OHC HOOC OH HOOC (A) COOH HOOC (B) COOH HO O O CH2OH HOH2C (C) O O (D) CH2OH HOH2C 42. 44.386 × 10 During depression of freezing point in a solution the following are in equilibrium (A) liquid solvent. Which has maximum number of atoms? (A) 24g of C (12) (C) 27g of Al (27) CHO OHC (B) 56g of Fe (56) (D) 108g of Ag (108) 41. 26515949 Fax : 26513942 . Sarvapriya Vihar (Near Hauz Khas Bus Term. 45.
Y = [Zn(CN)4]2– (D) X = [Au(CN)4]–. 26965626. which one will precipitate first? (A) FeS (B) MgS (C) HgS (D) ZnS In the process of extraction of gold. 2685 4102. Y = [Zn(CN)4]2– (C) X = [Au(CN)2]–. (B) X = [Au(CN)4]3–. 1 1 H2(g) + F2(g) → HF(g) 2 2 1 (D) CO(g) + O2(g) → CO2(g) 2 (B) 24 11 50*.16. 1 litre of mixture X + excess AgNO3 → Y.01 (B) 0.02 (D) 0. 0.02 mol of [Co(NH3)5Br]SO4 was prepared in 2 litre of solution. New Delhi .01. (Me)2SiCl2 on hydrolysis will produce (A) (Me)2Si(OH)2 (C) – [ –O – (Me)2Si – O – ]n– (B) (Me)2Si = O (D) Me2SiCl(OH) 52*. Mixture X = 0. Find out the process by which (B) α emission (D) K electron capture Na can undergo radioactive decay (A) β– emission (C) β+ emission 51. 26515949 Fax : 26513942 . ICES House. Na is the more stable isotope of Na. 0. 10–23. Sarvapriya Vihar (Near Hauz Khas Bus Term. 0. 3 Ethyl ester → P.02.). Ph : 2686 5182. 1 litre of mixture X + excess BaCl2 → Z No.IITJEE2003S8 47.02 mol of [Co(NH3)5SO4]Br and 0. Y = Zn(CN)6]4– 53.02 Which of the reaction defines ∆Hf0 (A) C(diamond)+ O2(g) → CO2(g) (C) N2(g) + 3H2(g) → 2NH3(g) 23 49.01. Y = [Zn(CN)4]2– FIITJEE Ltd.02. Zn2+ and Hg2+ is treated with 10–16 M sulphide ion. Fe2+. 0. FeS.01 (C) 0. of moles of Y and Z are (A) 0. The product P will be CH MgBr H3C excess CH3 H3C C2 H5 OH C 2H5 OH (A) H3C H5 C2 OH C2 H5 OH (B) H5C 2 H5C 2 (C) H5C 2 (D) H7C3 48. A solution which is 10–3 M each in Mn2+. If Ksp of MnS. 10–20 and 10–54 respectively. O2 Roasted gold ore + CN– + H2O → [X] + OH– [X] + Zn → [Y] + Au Identify the complexes [X] and [Y] (A) X = [Au(CN)2]–. ZnS and HgS are 10–15.
2685 4102. units (B) 9 sq. and f (x) = (A) one−one and onto (C) onto but not one−one x then f is 1+ x 57. x≥ 2 2 (C) f(x) = xx (D) f(x) = x x≠0 x=0 60*. H3C OH How many structures of F is possible? (A) 2 (C) 6 56. New Delhi . 2 . 0). then P (B ∩ C) is 3 3 4 1 (B) 6 1 (D) 9 59. (B) 5 (D) 3 An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. units (D) 27 sq. The area of the quadrilateral formed by the tangents at the end points of latus recta to the ellipse x2 y2 + = 1. Positive deviation from ideal behaviour takes place because of (A) Molecular interaction between atoms and PV/nRT > 1 (B) Molecular interaction between atoms and PV/nRT < 1 (C) Finite size of atoms and PV/nRT > 1 (D) Finite size of atoms and PV/nRT < 1 CH3 H B r2 CCl →[F] . In [0. ICES House. 21) and (21. ∞). The ester formed will be (A) Optically active mixture (B) Pure enantiomer (C) Meso compound (D) Racemic mixture If f : [0. 26515949 Fax : 26513942 . (B) one−one but not onto (D) neither one−one nor onto 58. 26965626. 0). units 61*. 1] Lagranges Mean Value theorem is NOT applicable to 1 1 x< sin x 2 − x. (A) f(x) = (B) f(x) = x 2 1 1. units (C) 27/2 sq. (0. is (A) 133 (B) 190 (C) 233 (D) 105 FIITJEE Ltd. P (A ∩ B ∩ C ) = and P ( A ∩ B ∩ C ) = . If P (B) = 1 12 1 (C) 15 (A) 1 1 3 . 4 →C 4H8Br2 − H2O 1 24 4 3 + 5 such products are possible 55*. ∞) → [0.).16. 1 − x . The number of integral points (integral point means both the coordinates should be integer) exactly in the interior of the triangle with vertices (0.IITJEE2003S9 54*. is 9 5 (A) 27/4 sq. Sarvapriya Vihar (Near Hauz Khas Bus Term. Ph : 2686 5182.
3.16. Sarvapriya Vihar (Near Hauz Khas Bus Term. 4) (C) (9. then a is equal to n +1 n 1 (D) n + n (C) 1 : 2 + 65. The probability that minimum of the two numbers is less than 4 is (A) 1/15 (B) 14/15 (C) 1/5 (D) 4/5 For hyperbola x2 − y2 = 1 which of the following remains constant with change in ‘α’ 67*. Range of the function f (x) = (A) (1. The value of k such that (A) 7 (C) no real value x−4 y−2 z−k = = lies in the plane 2x − 4y + z = 7. 26515949 Fax : 26513942 . 5. x ∈ R is (B) (1. 7/ 5] 68. 4. cos2 α sin2 α (A) abscissae of vertices (C) eccentricity (B) abscissae of foci (D) directrix . 2. 2685 4102. 4) (D) (4. If lim (A) 0 (C) n 66. ∞) (C) (1. 6} without replacement one by one. then the relation between b and c. is (A) no real value of b and c (C) c < b 2 (B) 0 < c < b 2 (D) c > b 2 71*. given that f ′ (2) = 6 and f′ (1) = 4 (B) is equal to − 3/ 2 (D) is equal to 3 70*. If f (x) = x2 + 2bx + 2c2 and g (x) = − x2 − 2cx + b2 such that min f (x) > max g (x). The centre of circle inscribed in square formed by the lines x2 − 8x + 12 = 0 and y2 − 14y + 45 = 0. 7/ 3] x2 + x + 2 x2 + x + 1 69. then the ratio of the longest side to the perimeter is (A) 3 : (2 + 3 ) 3 (B) 1 : 6 (D) 2 : 3 = 0. 11/ 7] (D) (1. 26965626. If the angles of a triangle are in the ratio 4 : 1 : 1. f (h − h2 + 1) − f (1) (A) does not exist (C) is equal to 3/ 2 h →0 lim f (2h + 2 + h2 ) − f (2) . New Delhi .). α 0 1 0 2 If A = and B = . ICES House. then value of α for which A = B. is 1 1 2 (B) − 7 (D) 4 64*. ((a − n)nx − tan x ) sin nx x2 x →0 (B) Two numbers are selected randomly from the set S = {1. is (A) (4. 9) FIITJEE Ltd. Ph : 2686 5182.IITJEE2003S10 62. is 1 1 5 1 (A) 1 (B) − 1 (C) 4 (D) no real values 63. 7) (B) (7. where n is nonzero real number.
4 2 73. Sarvapriya Vihar (Near Hauz Khas Bus Term. then x 2 + x + is always greater than or equal to 2 x2 + x (A) 2 tanα (B) 1 (C) 2 (D) sec2α 76. n+1 (A) (C) 2n n − I(m + 1 n − 1) . n − 1) m +1 m I(m + 1 n − 1) . 2y + 3 = x and x−axis in the Ist quadrant is (A) 9 (B) 27/4 (C) 36 (D) 18 Coefficient of t24 in (1 + t2)12 (1 + t12) (1 + t24) is (A) 12C6 + 3 (B) 12C6 + 1 12 (D) 12C6 + 2 (C) C6 79*. FIITJEE Ltd. ICES House. sin−1(2x ) + π for real valued x. The area bounded by the curves y = x . n − 1) m +1 m +1 x 2 +1 (B) (D) 77. ∞) x2 ∫e −t2 dt. 2 2 1 1 (C) − . 0) 78. m +1 m +1 2n n + I(m + 1. then the expression for I(m. 4 4 z −1 ( where z ≠ −1). Ph : 2686 5182. is 6 1 1 (B) − . New Delhi . 1} (B) {−2. π tan2 α If α ∈ 0. then f (x) increases in (B) no value of x (D) (−∞. 2685 4102. then the possible values of the slope of this chord. 2) (C) (0.1) is n I(m + 1. If z = 1 and ω = (A) 0 (C) z 1 ⋅ z + 1  z + 1 2 1 1 (D) − . 1/2} (D) {2. 2 9 74*.IITJEE2003S11 72*. If I(m. 2} (C) {−2. then Re(ω) is z +1 (B) (D) 1 z +1 2 2  z + 1 2 75*. 26965626.16.). are (A) {−1. n) in terms of I(m + 1. n) = ∫t 0 1 m (1 + t )n dt . −1/2} Domain of definition of the function f(x) = 1 1 (A) − . 26515949 Fax : 26513942 . n . The focal chord to y2 = 16x is tangent to (x – 6)2 + y2 = 2. If f (x) = (A) (2.
sin θ (where θ ∈ (0. is (A) π/3 (B) π/6 (C) π/8 (D) π/4 Tangent is drawn to ellipse ( ) 84*. If the system of equations x + ay = 0. x2 + y 2 = 1 at 3 3 cos θ. 4) and (4. ICES House. Then the value 27 of θ such that sum of intercepts on axes made by this tangent is minimum. FIITJEE Ltd. π/2)). 2685 4102. az + y = 0 and ax + z = 0 has infinite solutions. then y(1) is equal to dt (B) e + 1/2 (D) 1/2 82. ˆ + ak and a ˆ + k i j ˆ j i ˆ becomes minimum is (A) − 3 (B) 3 (C) 1/ 3 (D) 3 81. Orthocentre of triangle with vertices (0. 26965626. New Delhi . then the value of a is (A) − 1 (B) 1 (C) 0 (D) no real values If y(t) is a solution of (1 + t ) (A) − 1/2 (C) e − 1/2 dy − ty = 1 and y(0) = 1. 0). 12) 4 3 (C) 3.). 83*. (B) (3. yet FIITJEE does not guarantee its authenticity. Every effort has been made to reproduce the original paper in the interest of the aspirant students.16. 26515949 Fax : 26513942 . (3. 4 (D) (3. 0) is 5 (A) 3. 2003 Screening Test is based on Screening Test paper created using memory retention of select FIITJEE students appeared in this test. 9) Note: FIITJEE solutions to IIT−JEE. Ph : 2686 5182. Sarvapriya Vihar (Near Hauz Khas Bus Term. ˆ The value of ‘a’ so that the volume of parallelopiped formed by ˆ + aˆ + k.IITJEE2003S12 80.
35. 62. 70. 55. 48. 27. 50.IITJEE2003S13 Answers 1. 15. Ph : 2686 5182. 82. 26. 69. 45. 21. 14. 51. 57. 40. 19.). 67. 60. 42. 54. 31. 39. 59. 34. 8. 79. 74. Sarvapriya Vihar (Near Hauz Khas Bus Term. 47. 33. 65. 25. 78. 76. New Delhi . 4. 28. 43. 2685 4102. 23. 12. 58. 46. 24. A A B B A A B A A A A C B A A A A A A D D C A A D C B 3. 72. 44. 64. 49. 22. 37. 20. 18. 75. 10.16. 29. 66. 13. 81. 77. 71. 26515949 Fax : 26513942 . 32. 80. 36. 5. 73. 9. C B A B D A A A B B A A A A C A B C D A B A B D A A D A 2. A C C A B B B C A A A A A C A A C A B D A D D A A A A C FIITJEE Ltd. 38. 68. 7. 53. 61. 26965626. 83. 63. 30. 56. 41. 84. ICES House. 52. 16. 6. 17. 11.
ICES House.D.728 × 10−6 m3 Q l has two significant figure. 11. Fcos60° f Fsin60° mg 3.16. 2685 4102. 4. Electric field is perpendicular to the equipotential surfaces and is zero everywhere inside the metal. 26515949 Fax : 26513942 .2 × 10−2 m)3 = 1.IITJEE2003S14 Hints & Solution 1. Sarvapriya Vihar (Near Hauz Khas Bus Term. 26965626. Y= Ex > Ey & ax > ay E/a = constant F A ∆l 20 × 1 = −6 = 2 × 1011 N/m2 l 10 × 10 − 4 2π + π = 2nπ λ 8. Hence V will also have two significant figure.B. New Delhi .5 cm 4 h1  u  10. For no motion Fcos60° ≤ µ(mg + Fsin60°) F 3 1 ( 3 ×g + ) ⇒ F/2 ≤ 2 2 3 ⇒ F/2 ≤ g ⇒ Fmax = 20 N F. 5. ∴ W1 = W 2 = W 3 V = l3 = (1. Applying conservation of angular momentum about centre of the rod 2 L L L ⇒ ω = V/L Icmω = J ⇒ 2 × M = MV × 2 2 2 In a conservative field work done does not depend on the path. Q 7.). 2. Ph : 2686 5182. cosθ = (2n − 1)λ 4d l1αat = l2αst ⇒ l + l1 αa + αs l 2 αa = = ⇒ 2 l1 l1 αs αs αs l1 = ⇒ l1 + l 2 αa + αs For concave lens 1 1 1 − = ⇒ v = 5 cm v 4 − 20 h2  v  5 = ⇒ h2 = 2 × = 2. Using Snell’s law (1) sin90° = µglasssini µglass = 1/sini FIITJEE Ltd. 6. For constructive interference ∆φ = (dsecθ + dsecθ cos2θ) ⇒ 9.
Ammeter is always connected in series and voltmeter is always connected in parallel Out of the alternatives provided. ⇒ m∝V v 3v = 4(l 1 + x ) 4(l 2 + x ) 15. 2685 4102.5 cm 22.IITJEE2003S15 12. ICES House.53 )A° (rn)Fm = = 0. About the centre of circle the torque of the force causing the circular motion is zero. Sarvapriya Vihar (Near Hauz Khas Bus Term. 17. 25. 330 − v × 176 . m2 (0. New Delhi . 16.53 A°×n 100 m is 5 for Z = 100 ⇒ n = 1/4 rn = 14. 21. r r U = −µ. 26515949 Fax : 26513942 . Ph : 2686 5182. 24. none appears completely correct. f1 = frequency of the police car heard by motorcyclist. 18.53)A° Z m 2 (0.B miceCice[0 − (−20)] + m′L + mwaterCwater[0−20] = 0 m′ = 1 kg mass of water = 6 kg FIITJEE Ltd. 26965626. x = 2.16. f2 = frequency of the siren heard by motorcyclist. f1 = 330 − 22 330 + v × 165 f2 = 330 Q f1 − f2 = 0 ⇒ v = 22 m/s Since nuclear density is constant hence mass α volume. 19. F = − ⇒v= mv 2 dU = dr r v 0r which is a constant m nh mvnrn = 2π rn ∝ n 13.). Circuit is RC circuit π 1 tan = 4 RCω 1 ⇒ R= ωC Plane of motion must be perpendicular to at least one of the component of the magnetic field.
So. 2 − NO 3 and CO 3 − both have same number of electrons (equal to 32) and central atom in each 30. When the fourth Cl−atom is introduced.16. New Delhi . Sarvapriya Vihar (Near Hauz Khas Bus Term. 2MnO2 + 4KOH + O2 → 2K2MnO4 + 2H2O Rate of physiorsption increases with decrease of temperature sp 2 sp 2 sp sp 35. has zero dipole moment. Whereas P may have +5 oxidation state also. Replacement of one of the H− atoms by Cl atom increases the dipole moment. FIITJEE Ltd. the molecule (CCl4) again becomes symmetrical and dipole moment reduces to zero. The structure of H3PO3 is as follows: There are only two –OH groups and hence dibasic. 29. H2C CH C CH from left to right 37. 31. CH3Cl will have the maximum dipole moment. SO2 can be obtained by the action of acid upon sulphite while H2S is evolved by the action of acid upon sulphide. 34. 0 −5° i ) NaNO 2 +HCl N (B) NH2 H3C H3C 38. Replacement of another H atom of Cl increases the bond angle due to lone pair − lone pair repulsion between two Cl−atoms thereby reducing the dipole moment of the molecule.4 MeV Methane molecule being symmetrical. 26515949 Fax : 26513942 . 2685 4102. SO2 has a burning sulphur smell which is irritating. H P O OH OH 32. SO2 and H2S both being reducing agents. So. The oxidation number of P in this acid is +3. F ( CH ) NH Nucleophil ic aromatic substituti on H3C 3 NO 2 2 → H3C N (A) NO 2 → ii ) H2 / Ni.). Power dissipated ∝ Requivalent Applying conservation of linear momentum and COE ∴KEα = 5. P → H2C H2O / H+ OH H3C CH3 H2O / H Q → + O CH3 H3C CHO H3C OH Ketone (non−reducing) and aldehyde (reducing) can be distinguished by Fehling solution. However. 36. Stable oxidation state of Mn in alkaline medium is +6. H2S has rotten egg like smell. H3PO3 can be oxidised which means H3PO3 is a reducing agent. 33. The increase in dipole moment is rather more than what can be expected because of the fact that the bond dipole moment of C – H bond and that of C – Cl bond reinforce one another. Therefore. ICES House. 26965626. Ph : 2686 5182. being sp2 hybridised.IITJEE2003S16 27. 28. are isostructural too − Two moles of N H 2 ions will abstract two moles of most acidic hydrogen out of the four moles of hydrogen present per mole of the acidic compound. Increase in angle is again caused by the introduction of third Cl− atom. MnO2 is oxidised to K2MnO4 by atomospheric oxygen in KOH medium. can turn acidified dichromate solution green. The acidic strength is in the order: – COOH > – OH (phenolic deactivated by NO2 group) > – OH (phenolic) > alkynic H.
H3C O  + H3C I H3C O CH3 + I− 40. C2H5O– is better nucleophile than C6H5O– (phenoxide) ion since while in the former the negative charge is localised over oxygen and in the latter it is delocalised over the whole molecular framework. OH2  45. Sarvapriya Vihar (Near Hauz Khas Bus Term. C2H5O– will abstract proton from phenol converting the latter into phenoxide ion. New Delhi . 26515949 Fax : 26513942 .303 log log = = 1. 2 × 6. 2685 4102. 26965626. Ph CH3 H → + Ph C + CH3 H2O H3C O Ph + CH3 Ph O H Ph O H3C H3C H3C FIITJEE Ltd. some of liquid solvent will separate as a solid solvent and thus the concentration of solution will increase. K= 43.IITJEE2003S17 39. it can accommodate only one additional electron pair in its outermost shell.386 × 104 s–1 4 t [ A ] t 2 × 10 50 44. ICES House.e.023 × 1023 atoms whereas all the rest amount to 1 mole each only. COO  HOH 2C H / 2O H→ + COOH HOH 2 C → intramolecular Cannizaro reaction OH− / 100° CHO OHC CH 2OH  OOC CH 2 OH HOOC 42.e.). At the freezing point liquid and solid remain in equilibrium. 24g carbon amounts to 2 mole i. The central boron atom in boric acid. So. Ph : 2686 5182. H3BO3 is electron−deficient i. But C2H5O– is in excess. it is C2H5O– ion that would make nucleophilic attack at ethyl iodide to give diethyl ether (Williamson’s synthesis). If a solution of a non−volatile solute is cooled to a temperature below the freezing point of solution.16. boric acid is a Lewis acid with one p−orbital vacant.303 800 2. In an electrolytic cell electrons do not flow themselves. H2O • + B(OH)3 → • Base Acid B HO OH OH [B(OH)4 ] − + H+ 46. It is the migration of ions towards oppositely charged electrons that indirectly constitutes the flow of electrons from cathode to anode through internal supply. CHO OHC 41. [ A ] 0 2. So. There is no d−orbital of suitable energy in boron atom. This would then make nucleophilic attack on the methylene carbon of alkyl iodide.
1 O2 → 2[Au(CN)2]– + 2OH– 2 For positive deviation: PV = nRT + nPb Thus. b is actually the effective volume of molecule. So. ICES House.01 mole 0. 26515949 Fax : 26513942 . 51. So the mixture will be optically active. will be emitted out as β−ray.). To achieve stability. OH H → −H O 2 + 55*. The optically active acid will react with d and l forms of alcohol present in the racemic mixture to form two types of isomeric esters. 0 n1 → +1 p 1 + −1 e 0 or β − The proton will stay inside the nucleus whereas electron which cannot exist in the nucleus. it is the finite size of molecules that leads to the origin of b and hence positive deviation at high pressure. H3C H3C CH3 (cis and trans) + H3C CH2 OH 56. 2Au + 4CN– + H2O + 52. we can see that A P (B ∩ C) = P (B) − P (A ∩ B ∩ C ) − P ( A ∩ B ∩ C ) 3 1 1 1 A ∩B ∩ C = − − = . Thus. 53. the factor nPb is responsible for increasing the PV value above ideal value.e. is unable to form π−bond. 58. HgS having the lowest Ksp among the lot will precipitate first. 26965626. 13 n ratio of 24Na nuclide is i. C A ∩B ∩ C FIITJEE Ltd.01 mole Ba + SO 4 → BaSO 4 Excess 2+ 2− 0. the choice with at least two methyl groups at the carbon linked with –OH group will be the correct choice. will form Me2Si = O.IITJEE2003S18 47. This can be done by breaking a would tend to adjust its p neutron into proton and electron. It appears at the first sight that Me2SiCl2 on hydrolysis will produce Me2Si(OH)2 which ultimately upon loss of water. 1) ⇒ function is one−one but not onto (1 + x )2 From venn diagram. 2685 4102.01 Excess 0. 2[Au(CN)2]– + Zn → [Zn(CN)4]2– + 2Au 54. ∞) and range ∈ [0. Sarvapriya Vihar (Near Hauz Khas Bus Term. it 11 p n ratio to the proper value of unity. Ph : 2686 5182. 48.01 mole 50. because of its very large size in comparison to oxygen. − Ag + + 0Brmole → AgBr . the product of hydrolysis is polymeric in nature. > 0 ∀ x ∈ [0. B 4 3 3 12 f′(x) = 1 57. greater than unity and hence radioactive. In each the configuration of the chiral centre of acid will remain the same.16. New Delhi . But silicon atom. R O O  O OC2H5 CH3 + CH3MgBr → OC2H5 R → R CH3 + C 2H5 O − CH3MgX HO R CH3 CH3 XMgO HOH / H ← + CH3 CH3 R Thus.
Sarvapriya Vihar (Near Hauz Khas Bus Term. Probability = 30 5 lim n ae = a 2 + b2 = 1 cos 2 α + sin2 α = 1. no real value of α. 2 b. New Delhi . Favourable cases = 30 − 6 = 24. y y=9 (6. is x + = 1 i.IITJEE2003S19 59. 67. 9 3 5 9/2 3 3 1 9 Area = 4. ae = a2 − b2 ⇒ ae = 2 x y 2 5 y 5 + =1 ⇒ tangent (in first quadrant) at end of latus rectum 2. 9) x=6 x=2 (2. 2685 4102. Angles are 30°. 0) FIITJEE Ltd. 68. Point (4. 66. 7/ 3].16. 70. k) should lie in the given plane ⇒ 2 (4) − 4 (2) + 1 (k) = 7 ⇒ k = 7. 2. 4 ×1 f(x) = (x + b)2 + 2c2 − b2 and g (x) = b2 + c2 − (x + c)2 ⇒ 2c2 − b2 > b2 + c2 ⇒ c > Centre is (4. From diagram θ = 45° ⇒ slope = ± 1 √2 θ (4.3 = 27 sq units. 0) 2 √2 (6. f(x) = 1 + 1 3 x + + 2 4 2 ⇒ Range = (1. So area is four times the area of the right angled triangle formed by the tangent and axes in the Ist quadrant. 26515949 Fax : 26513942 . ICES House. x and 2x cos30° ratio is ⇒ 3 : (2 + 3 ). 7). n nx x →0 x x →0 24 4 = Total ways 2! 6C2 = 30.e. The function defined in (A) is not differentiable at x = 1/2. 2x cos 300 2x + 2 x cos 300 65. 26965626. 2 63.). Hence sides are x. Number of points exactly in the interior of the triangle = α 2 0 α 0 α 0 A2 = = α + 1 1 1 1 1 1 clearly. 69. ⋅ . 62. 1 sin nx tan x ⋅ lim (a − n)n − = 0 ⇒ n ((a−n)n− 1) = 0 ⇒ (a − n)n = 1 ⇒ a = n + . 20 × 20 − 20 = 190. Ph : 2686 5182. 71. h→0 lim f (2h + 2 + h2 ) − f (2) f (h − h + 1) − f (1) 2 = lim f ′(2h + 2 + h2 )(2 + 2h) f ′(h − h + 1)(1 − 2h) 2 h →0 = 6×2 = 3. 64. 30° and 120°. 5) y=5 x 72. By symmetry the quadrilateral is a rhombus. 60. 2 2 61. Now.
f(θ) is minimum. 0) x = 9 + 9 − 9 = 9. 4) 84. 79. Re(ω) = 0 arg (ω) = ± x2 + x + 1 (1.). tan2 α x2 + x m ≥ 2 tanα (AM ≥ GM) 2n n tm+1 tm+1 − I(m + 1. − π π 1 ≤ sin1(2x) ≤ ⇒ − ≤ 2x ≤ 1 ⇒ x ∈ 6 2 2 1 1 − 4 . 2x − e . 2 z π 2 ⇒ ω is purely imaginary. − n(1 + t )n−1 dt = m+1 m+1 m +1 m +1 0 1 1 76. y A(3. we get e−t(1 + t)dy + y(e−t − (1 + t)e−t )dt = e−tdt ⇒ d(e−t (1 + t)y) = d(−e−t) ⇒ ye−t(1 + t) = − e−t + c. Sum of intercepts 3 3 sec θ + cos ecθ = f(θ) (say) 83. 3 3 sin3 θ − cos3 θ sin2 θ cos2 θ ⇒ At θ = π/6.IITJEE2003S20 73.1/2. da 3 3 3 a 0 1 1 a 0 81. 78. 26515949 Fax : 26513942 . 80. ICES House. From figure tanθ = k 1 3 = ⇒k= 3 4 4 θ • (3. y y2 = 2y + 3 ⇒ y = 3 The required area = ∫ 0 3 y3 2 (2y + 3 − y 2 ) dy = y + 3y − 3 3 x = y2 (9. 0) θ 3 1 B(4. 0). 2685 4102. 2x = 2x e −( x +1+ 2 x ) 1 − e 2 x +1 ⇒ f′ (x) > 0 ( ) ∀ x ∈ (− ∞. Sarvapriya Vihar (Near Hauz Khas Bus Term. Also y0 = 1 ⇒ c = 0 ⇒ y(1) = . k) O(0. x cos θ 3 3 f ′(θ) = + y sin θ = 1 . 3) 0 x = 2y + 3 (3. By multiplying e−t and rearranging the terms. 0) O (1. I(m . 0 1 a = 0 ⇒ 1 + a (a ) = 0 ⇒ a = − 1 ⇒ a = − 1. n) = ∫ 0 t (1 + t ) dt = (1 + t) n n ∫ 0 77. 1 a 1 dV 1 1 1 a − ⇒ Minimum at = 3a2 − 1 = 3 a + V = 0 1 a = 1 + a3 − a ⇒ . 26965626. 0) x FIITJEE Ltd. New Delhi . Ph : 2686 5182.16. 2 2 4 2 2 −( x 2 ) 2 f′(x) = e−( x +1) . n − 1) . 74. 0) 75. (1 + t2)12 (1 + t12) (1 + t24) = (1 + t2)12 (1 + t12 + t24 + t36) ⇒ coefficient of t24 is 12C12 + 12C6 + 1 = 12C6 + 2. a 0 1 2 3 82.
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