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10 Find the rate law for this reaction. [B] 0.050 0.10 0.050 0.050 [C] 0.10 0.10 0.10 0.30 Initial Rate (M.s-1) 1.1 x 10-3 4.4 x 10-3 1.1 x 10-3 3.3 x 10-3
Q2. For a first order reaction the following data are obtained from an experiment by measuring the concentration as a function of time. The reaction is of the type: A → products. time (secs.) [A] 0 1.00 50 0.500 100 ? Determine the molar concentration of A after 100 seconds have elapsed and also determine the value of rate constant k in sec-1. Q.3 In the reaction of potassium (K) with methyl iodide (CH3I) to for the product KI, how orientation of these reactant molecules play important role in product formation. Except from this what will be the other requirements for reactant molecules to form product according to collision theory. PART B Q.4 Balance the following redox equations:
a) CN- + MnO4- → CNO- + MnO2 b) Cr2O72- + C2O42- → Cr3+ + CO2
(in basic solution) (in acidic solution)
Q.5 Ca (s) + Cd2+ (aq) → Ca2+ (aq) + Cd (s) In the above reaction assume that initial concentration of dissolved species are 1.0 M. Predict whether this reaction will be feasible or not in aqueous solution at 250C. Q.6 Discuss the advantages and disadvantages of fuel cells over conventional power plants in producing electricity.