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If I have a solution of 5000 ppm and I want to make standards at 100, 200, 300, 400, 500,

600, 700, and 800 ppm. What volume of the 5000 ppm standard must I use to make a
final volume of 10 mL?

Vol. of soln1 x conc. of soln1 = Vol. soln2 x conc. soln2

= (10 x 100)/5000 = 0.2 mL

The conversion equation is based on 25 ºC and 1 atmosphere:


X ppm = (Y mg/m3)(24.45)/(molecular weight)
or
Y mg/m3 = (X ppm)(molecular weight)/24.45

You will have to take into account the reference condition you are using.
eg 24.45 is the molar volume for a reference condition of 25degC. Reference at 0degC
would give you a molar volume of 22.40.

You are making a mistake here. This formula is only applicable when converting ppm to
mg/m³ for a gas. It won't be applicable for ppm glycol in an aqueous solution.