Solutions to Problems in Merzbacher

,
Quantum Mechanics, Third Edition
Homer Reid
November 20, 1999
Chapter 2
Problem 2.1
A one-dimensional initial wave packet with a mean wave number
k
x
and a Gaussian amplitude is given by
Ψ(x, 0) = C exp
¸

x
2
4(∆x)
2
+ ik
x
x

.
Calculate the corresponding k
x
distribution and Ψ(x, t), assuming
free particle motion. Plot |Ψ(x, t)|
2
as a function of x for several
values of t, choosing ∆x small enough to show that the wave packet
spreads in time, while it advances according to the classical laws.
Apply the results to calculate the effect of spreading in some typical
microscopic and macroscopic experiments.
The first step is to compute the Fourier transform of Ψ(x, 0) to find the
distribution of the wave packet in momentum space:
Φ(k) = (2π)
−1/2


−∞
Ψ(x, 0)e
−ikx
dx
= (2π)
−1/2
C


−∞
exp
¸

x
2
4(∆x)
2
+ i(k
0
−k)x

dx (1)
1
(I have dropped the x subscripts, and I write k
0
instead of k).
To proceed we need to complete the square in the exponent:

x
2
4(∆x)
2
+ i(k
0
−k)x = −
¸
x
2
4(∆x)
2
−i(k
0
−k)x −(k
0
−k)
2
(∆x)
2
+ (k
0
−k)
2
(∆x)
2

= −
¸
x
2(∆x)
−i(k
0
−k)∆x

2
−(k
0
−k)
2
(∆x)
2
= −
1
4(∆x)
2

x −2i(k
0
−k)(∆x)
2

2
−(k
0
−k)
2
(∆x)
2
(2)
Now we plug (??) into (??) to find:
Φ(k) = (2π)
−1/2
C exp[−(k
0
−k)
2
(∆x)
2
]


−∞
exp


1
4(∆x)
2
[x −2i(k
0
−k)(∆x)
2
]
2

dx
In the integral we can make the shift x → x − 2i(k
0
− k)(∆x)
2
and use the
standard formula


−∞
exp(ax
2
)dx = (π/a)
1/2
. The result is
Φ(k) =

2C∆xexp

−(k
0
−k)
2
(∆x)
2

To put this into direct correspondence with the form of the wave packet in
configuration space, we can write
Φ(k) =

2C∆xexp
¸

(k
0
−k)
2
4(∆k)
2

where ∆k = 1/(2∆x). This is the minimum possible k width attainable for
a wave packet with x width ∆x, which is why the Gaussian wave packet is
sometimes referred to as a minimum uncertainty wave packet.
The next step is to compute Ψ(x, t) for t > 0. Since we are talking about
a free particle, we know that the momentum eigenfunctions are also energy
eigenfunctions, which makes their time evolution particularly simple to write
down. In the above work we have expressed the initial wave packet Ψ(x, 0)
as a linear combination of momentum eigenfunctions, i.e. as a sum of terms
exp(ikx), with the kth term weighted in the sum by the factor Φ(k). The wave
packet at a later time t > 0 will be given by the same linear combination, but
now with the kth term multiplied by a phase factor exp[−iω(k)t] describing its
time evolution. In symbols we have
Ψ(x, t) =


−∞
Φ(k)e
i[kx−ω(k)t]
dk.
For a free particle the frequency and wave number are connected through
ω(k) =
¯ hk
2
2m
.
2
Using our earlier expression for Φ(k), we find
Ψ(x, t) =

2C∆x


−∞
exp
¸
−(k
0
−k)
2
(∆x)
2
+ ikx −i
¯ hk
2
2m
t

dk. (3)
Again we complete the square in the exponent:
−(k
0
−k)
2
(∆x)
2
+ ikx −i
¯ hk
2
2m
t = −

[(∆x)
2
+
i¯ h
2m
t]k
2
−[2k
0
(∆x)
2
+ ix]k + k
2
0
(∆x)
2

= −
¸
α
2
k
2
−βk + γ
¸
= −α
2

k
2

β
α
2
k +
β
2

4

β
2

4

−γ
= −α
2
[k −
β

2
]
2
+
β
2

2
−γ
where we have defined some shorthand:
α
2
= (∆x)
2
+
i¯ h
2m
t β = 2k
0
(∆x)
2
+ ix γ = k
2
0
(∆x)
2
.
Using this in (??) we find:
Ψ(x, t) =

2C∆xexp
¸
β
2

2
−γ


−∞
exp
¸
−α
2
(k −
β

2
)
2

dk.
The integral evaluates to π
1/2
/α. We have
Ψ(x, t) =

2πC∆x

1
α

exp
¸
β
2

2
−γ

=

2πC
¸
(∆x)
2
(∆x)
2
+
i¯ h
2m
t
¸
1/2
e
−k
2
0
(∆x)
2
exp
¸
(ix + 2k
0
(∆x)
2
)
2
4[(∆x)
2
+
i¯ h
2m
t]
¸
This is pretty ugly, but it does display the relevant features. The important
point is that term i¯ ht/2m adds to the initial uncertainty (∆x)
2
, so that the
wave packet spreads out with time.
In the figure, I’ve plotted this function for a few values of t, with the follow-
ing parameters: m=940 Mev (corresponding to a proton or neutron), ∆x=3
˚
A,
k
0
=0.8
˚
A
−1
. This value of k
0
corresponds, for a neutron, to a velocity of about
5 · 10
4
m/s; and note that, sure enough, the center of the wave packet travels
about 5 nm in 100 fs. The time scale of the spread of this wave packet is ≈ 100
fs.
3
0
50
100
150
200
250
300
350
-1e-08 -5e-09 0 5e-09 1e-08
W
a
v
e
f
u
n
c
t
i
o
n

(
a
r
b
i
t
r
a
r
y

u
n
i
t
s
)
Distance (meters)
Gaussian wave packet example
t=0 s
t=30 fs
t=70 fs
t=100 fs
4
Problem 2.2
Express the spreading Gaussian wave function Ψ(x, t) obtained
in Problem 1 in the form Ψ(x, t) = exp[iS(x, t)/¯ h]. Identify the
function S(x, t) and show that it satisfies the quantum mechanical
Hamilton-Jacobi equation.
In the last problem we found
Ψ(x, t) =

2πC

∆x
α

exp
¸
β
2

2
−γ

= exp
¸
ln


2πC
∆x
α

+
β
2

2
−γ

(1)
where we’ve again used the shorthand we defined earlier:
α
2
= (∆x)
2
+
i¯ h
2m
t β = 2k
0
(∆x)
2
+ ix γ = k
2
0
(∆x)
2
.
From (??) we can identify (neglecting an unimportant additive constant):
S(x, t) =
¯ h
i
¸
−lnα +
β
2

2

.
Things are actually easier if we define δ = α
2
. Then
δ = (∆x)
2
+
i¯ h
2m
t S(x, t) =
¯ h
i
¸

1
2
ln δ +
β
2

Now computing partial derivatives:
∂S
∂t
=
¯ h
i
¸

1


β
2

2

∂δ
∂t
= −
¯ h
2
2m
¸
1

+
β
2

2

(2)
∂S
∂x
=
¯ h
i
β

∂β
∂x
=
¯ hβ

(3)

2
S
∂x
2
=
i¯ h

(4)
The quantum-mechanical Hamilton-Jacobi equation for a free particle is
∂S
∂t
+
1
2m
¸
∂S
∂x

2

i¯ h
2m

2
S
∂x
2
= 0
5
Inserting (??), (??), and (??) into this equation, we find

¯ h
2
4mδ

¯ h
2
β
2
8mδ
2
+
¯ h
2
β
2
8mδ
2
+
¯ h
2
4mδ
= 0
so, sure enough, the equation is satisfied.
Problem 2.3
Consider a wave function that initially is the superposition of two
well-separated narrow wave packets:
Ψ
1
(x, 0) + Ψ
2
(x, 0)
chosen so that the absolute value of the overlap integral
γ(0) =

+∞
−∞
Ψ

1
(x)Ψ
2
(x)dx
is very small. As time evolves, the wave packets move and spread.
Will |γ(t)| increase in time, as the wave packets overlap? Justify
your answer.
It seems to me that the answer to this problem depends entirely on the
specifics of the particular problem.
One could well imagine a situation in which the overlap integral would not
increase with time. Consider, for example, the neutron wave packets plotted
in the figure from problem 2.1 If one of those wave packets were centered in
Chile and another in China, the overlap integral would be tiny, since the wave
packets only have appreciable value within a few angstroms of their centers.
Furthermore, even if the neutrons are initially moving toward each other, their
wave packets spread out on a time scale of ≈ 100 fs, long before their centers
ever come close to each other.
On the other hand, if the two neutron wave packets were each centered, say,
20 angstroms apart, then they would certainly overlap a little before collapsing
entirely.
Problem 2.4
A high resolution neutron interferometer narrows the energy spread
of thermal neutrons of 20 meV kinetic energy to a wavelength dis-
persion level of ∆λ/λ= 10
−9
. Estimate the length of the wave
packets in the direction of motion. Over what length of time will
the wave packets spread appreciably?
6
First let’s compute the average momentum of the neutrons.
p
0
= [ 2mE ]
1/2
≈ [ 2 · (940Mev · c
−2
) · (20mev) ]
1/2
= 6.1 kev / c
We’re given the fractional wavelength dispersion level; what does this tell us
about the momentum dispersion level?
p =
2π¯ h
λ
dp =
−2π¯ h
λ
2

so

dp
p

=


λ

= 10
−9
so the momentum uncertainty is
∆p = p
0
· 10
−9
= 6.1 · 10
−6
ev.
This implies a position uncertainty of
∆x ≈
¯ h
∆p
=
6.6 · 10
−16
ev · s
6.1 · 10
−6
ev / c
≈ c · 10
−10
s
≈ 30 cm.
This is HUGE! So the point is, if we know with this precision how quickly
our thermal neutrons are moving, we have only the most rough indication of
where in the room they might be.
To estimate the time scale of spreading of the wave packets, we can imagine
that they are Gaussian packets. In this case we start to get appreciable spreading
when
¯ h
2m
t ≈ (∆x)
2
or
t ≈ 2m(∆x)
2
/¯ h

2 · 9.4 · 10
8
ev · (0.3 m)
2
c
2
· 6.6 · 10
−16
ev · s
≈ 32 ks ≈ 10 hours.
7
Solutions to Problems in Merzbacher,
Quantum Mechanics, Third Edition
Homer Reid
March 8, 1999
Chapter 3
Problem 3.1
If the state Ψ(r) is a superposition,
Ψ(r) = c
1
Ψ
1
(r) + c
2
Ψ
2
(r)
where Ψ
1
(r) and Ψ
2
(r) are related to one another by time reversal,
show that the probability current density can be expressed without
an interference term involving Ψ
1
and Ψ
2
.
I found this to be a pretty cool problem! First of all, we have the probability
conservation equation:
d
dt
ρ = −

∇ ·

J.
To show that

J contains no cross terms, it suffices to show that its divergence
has no cross terms, and to show this it suffices (by probability conservation) to
show that dρ/dt has no cross terms. We have
ρ = Ψ

Ψ
= [c

1
Ψ

1
+ c

2
Ψ

2
] · [c
1
Ψ
1
+ c
2
Ψ
2
]
= |c
1
||Ψ
1
| + |c
2
||Ψ
2
| + c
1
c

2
Ψ
1
Ψ

2
+ c

1
c
2
Ψ

1
Ψ
2
(1)
1
Problem 3.2
For a free particle in one dimension, calculate the variance at time
t, (∆x)
2
t

(x − x
t
)
2

t
=

x
2

t
−x
2
t
without explicit use of the
wave function by applying (3.44) repeatedly. Show that
(∆x)
2
t
= (∆x)
2
0
+
2
m
¸
1
2
xp
x
+ p
x
x
0
− x
0
p
x

t +
(∆p
x
)
2
m
2
t
2
and
(∆p
x
)
2
t
= (∆p
x
)
2
0
= (∆p
x
).
2
I find it easiest to use a slightly different notation: w(t) ≡ (∆x)
2
t
. (The w
reminds me of “width.”) Then
w(t) = w(0) + t
dw
dt

t=0
+
1
2
t
2
d
2
w
dt
2

t=0
+ · · · (2)
We have
dw
dt
=
d
dt

x
2

− x
2

=
d
dt

x
2

− 2 x
d
dt
x (3)
d
2
w
dt
2
=
d
2
dt
2

x
2

− 2
¸
d
dt
x

2
− 2 x
d
2
dt
2
x (4)
We need to compute the time derivatives of x and

x
2

. The relevant
equation is
d
dt
F =
1
i¯ h
FH − HF +

∂F
∂t

for any operator F. For a free particle, the Hamiltonian is H = p
2
/2m, and
the all-important commutation relation is px = xp − i¯ h. We can use this to
calculate the time derivatives:
d
dt
x =
1
i¯ h
[x, H]
=
1
2im¯ h

xp
2
− p
2
x

=
1
2im¯ h

xp
2
− p(xp − i¯ h)

=
1
2im¯ h

xp
2
− pxp + i¯ hp

2
=
1
2im¯ h

xp
2
− (xp − i¯ h)p + i¯ hp

=
1
2im¯ h
2i¯ hp
=
p
m
(5)
d
2
dt
2
x =
1
m
d
dt
p = 0 (6)
d
dt

x
2

=
1
i¯ h

[x
2
, H]

=
1
2im¯ h

x
2
p
2
− p
2
x
2

=
1
2im¯ h

x
2
p
2
− p(xp − i¯ h)x

=
1
2im¯ h

x
2
p
2
− pxpx + i¯ hpx

=
1
2im¯ h

x
2
p
2
− (xp − i¯ h)
2
+ i¯ h(xp − i¯ h)

=
1
2im¯ h

x
2
p
2
− xpxp + 2i¯ hxp + ¯ h
2
+ ¯ h
2
+ i¯ hxp

=
1
2im¯ h

x
2
p
2
− x(xp − i¯ h)p + 3i¯ hxp + 2¯ h
2

=
1
2im¯ h

2¯ h
2
+ 4i¯ hxp

= −
i¯ h
m
+
2
m
xp (7)
d
2
dt
2

x
2

=
2
m
d
dt
xp
=
2
i¯ hm
[xp, H]
= −
1
i¯ hm
2

xp
3
− p
2
xp

= −
1
i¯ hm
2

xp
3
− p(xp − i¯ h)p

= −
1
i¯ hm
2

xp
3
− pxp
2
+ i¯ hp
2

= −
1
i¯ hm
2

xp
3
− (xp − i¯ h)p
2
+ i¯ hp
2

=
1
i¯ hm
2

2i¯ hp
2

=
2
m
2

p
2

(8)
d
3
dt
3

x
2

=
2
i¯ hm
2

[p
2
, H]

= 0 (9)
Now that we’ve computed all time derivatives of x and

x
2

, it’s time to
3
plug them into (3) and (4) to compute the time derivatives of w.
dw
dt
=
d
dt

x
2

− 2 x
d
dt
x
= −
i¯ h
m
+
2
m
xp −
2
m
x p
=
2
m


i¯ h
2
+ xp


2
m
x p
=
2
m

px − xp
2
+ xp


2
m
x p
=
2
m

px + xp
2


2
m
x p (10)
d
2
w
dt
2
=
d
2
dt
2

x
2

− 2
¸
d
dt
x

2
− 2 x
d
2
dt
2
x
=
2
m
2

p
2


2
m
2
p
2
=
2
m
2
(∆p)
2
(11)
Finally, we plug these into the original equation (2) to find
w(t) = w(0) +
2
m
¸
1
2
px + xp − x p

t +
(∆p)
2
m
2
t.
2
The other portion of this problem, the constancy of (∆p)
2
, is trivial, since
(∆p)
2
contains expectation values of p and p
2
, which both commute with H.
4
Problem 3.3
Consider a linear harmonic oscillator with Hamiltonian
H = T + V =
p
2
2m
+
1
2

2
x
2
.
(a) Derive the equation of motion for the expectation value x
t
,
and show that it oscillates, similarly to the classical oscillator,
as
x
t
= x
0
cos ωt +
p
0

sinωt.
(b) Derive a second-order differential equation of motion for the
expectation value T − V
t
by repeated application of (3.44)
and use of the virial theorem. Integrate this equation and,
remembering conservation of energy, calculate

x
2

t
.
(c) Show that
(∆x)
2
t

x
2

t
− x
2
t
= (∆x)
2
0
cos
2
ωt +
(∆p)
2
0
m
2
ω
2
sin
2
ωt
+
¸
1
2
xp + px
0
− x
0
p
0

sin 2ωt

Verify that this reduces to the result of Problem 2 in the limit
ω → 0.
(d) Work out the corresponding formula for the variance (∆p)
2
t
.
(a) Again I like to use slightly different notation: e(t) = x
t
. Then
d
dt
e(t) =
1
i¯ h
xH − Hx
=
1
2i¯ hm

xp
2
− p
2
x

=
1
2i¯ hm

xp
2
− p(xp − i¯ h)

=
1
2i¯ hm

xp
2
− (xp − i¯ h)p + i¯ hp

=
1
2i¯ hm
2i¯ hp
=
p
m
.
d
2
dt
2
e(t) =
d
dt
p
m
5
=
1
i¯ hm
pH − Hp
=
ω
2
2i¯ h

px
2
− x
2
p

=
ω
2
2i¯ h

(xp − i¯ h)x − x
2
p

=
ω
2
2i¯ h

x(xp − i¯ h) − i¯ hx − x
2
p

=
ω
2
2i¯ h
−2i¯ hx
= −ω
2
x .
So we have
d
2
dt
2
e(t) = −ω
2
e(t)
with general solution e(t) = Acos ωt +Bsin ωt. The coefficients are determined
by the boundary conditions:
e(0) = x
0
→ A = x
0
e

(0) =
p
0
m
→ B =
p
0

.
(b) Let’s define v(t) = T − V
t
. Then
d
dt
v(t) =
1
i¯ h
(T − V )H − H(T − V )
=
1
i¯ h
(T − V )(T + V ) − (T + V )(T − V )
=
2
i¯ h
TV − V T
=
ω
2
2i¯ h

p
2
x
2
− x
2
p
2

.
We already worked out this commutator in Problem 2:

p
2
x
2
− x
2
p
2

= −

4i¯ hxp + 2¯ h
2

so
d
dt
v(t) = −2ω
2
xp + i¯ hω
2
.
= −2ω
2
xp + ω
2
xp − px
= −ω
2
xp + px (12)
Next,
d
2
dt
2
v(t) = −

2
i¯ h
xpH − Hxp
= −

2
i¯ h
¸
1
2m

xp
3
− p
2
xp

+

2
2

xpx
2
− x
3
p

(13)
6
The bracketed expressions are

xp
3
− p
2
xp

=

xp
3
− p(xp − i¯ h)p

=

xp
3
− (xp − i¯ h)p
2
+ i¯ hp
2

=

2i¯ hp
2

xpx
2
− x
3
p

=

x(xp − i¯ h)x − x
3
p

=

x
2
(xp − i¯ h) − i¯ hx
2
− x
3
p

=

−2i¯ hx
2

and plugging these back into (13) gives
d
2
dt
2
v(t) = = −4ω
2
¸

p
2

m


2
2

x
2

¸
= −4ω
2
v(t)
with solution
v(t) = Acos 2ωt + B sin 2ωt. (14)
Evaluating at t = 0 gives
A = T
0
− V
0
.
Also, we can use (12) evaluated at t = 0 to determine B:
−ω
2
xp + px
0
+ i¯ hω
2
= 2ωB
so
B = −
ω xp + px
0
2
.
The next task is to compute

x
2

t
:

x
2

t
=
2

2
V
t
=
1

2
H − (T − V )
t
=
1

2
[H
t
− v(t)] .
Since H does not depend explicitly on time, H is constant in time. For v(t)
we can use (14):

x
2

t
=
1

2

T
0
+ V
0
− [T
0
− V
0
] cos 2ωt +
ω xp + px
0
2
sin 2ωt

=
1

2

2 T
0
sin
2
ωt + 2 V
0
cos
2
ωt +
ω xp + px
0
2
sin 2ωt

=

p
2

0
m
2
ω
2
sin
2
ωt +

x
2

0
cos
2
ωt +
1
2
xp + px
0
sin 2ωt

. (15)
7
(c) Earlier we found that
x
t
= x
0
cos ωt +
p
0

sin ωt
x
2
t
= x
2
0
cos
2
ωt +
p
2
0
m
2
ω
2
sin
2
ωt + x
0
p
0
sin 2ωt.
Subtracting from (15) gives
(∆x)
2
t
=

x
2

− x
2
=

x
2

0
− x
2
0

cos
2
ωt
+
1
m
2
ω
2

p
2

0
− p
2
0

+
¸
1
2
xp + px
0
− x
0
p
0

sin 2ωt
= (∆x)
2
0
cos
2
ωt +
(∆p)
2
0
m
2
ω
2
sin
2
ωt +
¸
1
2
xp + px
0
− x
0
p
0

sin 2ωt

.
As ω → 0, cos
2
ωt → 1, (sin
2
ωt/ω
2
) → 1, and (sin 2ωt/ω) → 2, as needed
to ensure matchup with the result of Problem 2.
Problem 3.4
Prove that the probability density and the probability current den-
sity at position r
0
can be expressed in terms of the operators r and
p as expectation values of the operators
ρ(r
0
) → δ(r − r
0
) j(r
0
) →
1
2m
[pδ(r − r
0
) + δ(r − r
0
)p] .
Derive expressions for these densities in the momentum represen-
tation.
The first one is trivial:
δ(r − r
0
) =

Ψ

(r)δ(r − r
0
)Ψ(r)dr = Ψ

(r
0
)Ψ(r
0
) = ρ(r
0
).
For the second one,
1
2m
pδ(r − r
0
) + δ(r − r
0
)p = −
i¯ h
2m



∇δ(r − r
0
)Ψ + Ψ

δ(r − r
0
)∇Ψ] dr
The gradient operator in the first term operates on everything to its right:
= −
i¯ h
2m



Ψ∇δ(r − r
0
) + 2δ(r − r
0


∇Ψ] dr.
8
Here we can use the identity

f(x)δ

(x − a)dx = −f

(a) :
= −
i¯ h
2m
|−∇(Ψ

Ψ) + 2Ψ

∇Ψ|
r=r0
=
i¯ h
2m
|Ψ∇Ψ

− Ψ

∇Ψ|
r=r0
= j(r
0
).
Problem 3.5
For a system described by the wave function Ψ(r

), the Wigner
distribution function is defined as
W(r

, p

) =
1
(2π¯ h)
3
exp(−ip

·x

/¯ h)Ψ

r


r

2

Ψ

r

+
r

2

dr

.
(a) Show that W(r

, p

) is a real-valued function, defined over the
six-dimensional “phase space” (r

, p

).
(b) Prove that

W(r

, p

)dp

= |Ψ(r

)|
2
and that the expectation value of a function of the operator
r in a normalized state is
f(r) =

f(r

)W(r

, p

)dr

dp

.
(c) Show that the Wigner distribution function is normalized as

W(r

, p

)dr

dp

= 1.
(d) Show that the probability density ρ(r
0
) at position r
0
is ob-
tained from the Wigner distribution function with
ρ(r
0
) → f(r) = δ(r − r
0
).
(a)
9
Solutions to Problems in Merzbacher,
Quantum Mechanics, Third Edition
Homer Reid
June 24, 2000
Chapter 5
Problem 5.1
Calculate the matrix elements of p
2
x
with respect to the energy eigenfunctions of the
harmonic oscillator and write down the first few rows and columns of the matrix.
Can the same result be obtained directly by matrix algebra from a knowledge of
the matrix elements of p
x
?
For the harmonic oscillator, we have
H =
1
2m
p
2
x
+
1
2

2
x
2
so
p
2
x
= 2mH −m
2
ω
2
x
2
and
< Ψ
n
|p
2
x

k
>= 2m¯ hω(n +
1
2

nk
−m
2
ω
2
< Ψ
n
|x
2

k
> . (1)
The nth eigenfunction is
Ψ(x) =

1
2
n
n!

1/2

¯ hπ

1/4
exp(−

2¯ h
x
2
)H
n
(


¯ h
x).
The matrix element of x
2
is then
< Ψ
n
|x
2

k
>=

1
2
n+k
n!k!

1/2

¯ hπ

1/2


−∞
x
2
exp(

¯ h
x
2
)H
n
(


¯ h
x)H
k
(


¯ h
x) dx.
1
Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 2
The obvious substitution is u = (mω/¯ h)x, with which we obtain
< Ψ
n
|x
2

k
>=

1
2
n+k
n!k!π

1/2

¯ h


−∞
u
2
e
−u
2
H
n
(u)H
k
(u) du. (2)
The integral is what Merzbacher calls I
nkp
with p = 2. The useful formula is
¸
n,k,p
I
nkp
s
n
t
k
(2λ)
p
n! k! p!
=

π e
λ
2
+2λ(s+t)+2st
.
=

π

1 +λ
2
+
1
2
λ
4
+ · · ·

1 + 2λ(s +t) +
1
2
(2λ)
2
(s +t)
2
+ · · ·

1 + (2st) +
1
2
(2st)
2
+ · · ·

(3)
There are two ways to get a λ
2
term out of this. One way is to take the λ
2
term
from the first series and the 1 from the second series, together with any term
from the last series. The second way is to take the 1 from the first series and
the λ
2
term from the second series, along with any term from the last series.
Writing down only terms obtainable in this way, we have
= · · · +

πλ
2

1 + 2(s +t)
2

1 + (2st) +
1
2
(2st)
2
+ · · ·

+ · · ·
= · · · +

πλ
2

1 + 2s
2
+ 2t
2
+ 4st


¸
j=0
1
j!
(2st)
j
+ · · ·
= · · · +

πλ
2

¸
j=0

2
j
j!
s
j
t
j
+
2
j+1
j!
s
j+2
t
j
+
2
j+1
j!
s
j
t
j+2
+
2
j+2
j!
s
j+1
t
j+1

+ · · ·
Comparing termwise with (3), we can read off
I
nk2
=

(n + 2)!2
n

π , n = k − 2
n!2
n−1

π(1 + 2n) , n = k
0 , otherwise.
Plugging this into (2), we have
< Ψ
n+2
|x
2

n
> =
1
2
[(n + 2)(n + 1)]
1/2

¯ h

< Ψ
n
|x
2

n
> =
1
2
(2n + 1)

¯ h

.
Finally, from (1),
< Ψ
n+2
|p
2

n
> = −
1
2
[(n + 2)(n + 1)]
1/2
(mω¯ h)
< Ψ
n
|x
2

n
> =
1
2
(2n + 1)(mω¯ h).
Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 3
I find it kind of confusing that the matrix element for p
2
comes out negative
in the first case. It would be absurd for the expectation value (i.e., diagonal
matrix element) of the square of an observable operator to come out negative.
In this case it is less absurd since there’s no classical interpretation of the off-
diagonal matrix elements of an operator, but it’s still weird.
However, in another sense it seems inescapable that p
2
should have a negative
off-diagonal matrix element here, because the off-diagonal matrix elements of H
must vanish in the energy eigenfunction basis, but x
2
has a nonvanishing matrix
element, and H is just a sum of x
2
and p
2
terms, so p
2
must have a negative
matrix element to cancel out the positive matrix element of x
2
.
Problem 5.2
Calculate the expectation values of the potential and kinetic energies in any station-
ary state of the harmonic oscillator. Compare with the results of the virial theorem.
The potential energy operator is U = mω
2
x
2
/2. We found the expectation
values of x
2
in the last problem, so
U =
1
2

2

x
2

=
¯ hω
2
(n +
1
2
)
which is just half the energy expectation value. The kinetic energy expectation
value must of course make up the difference, so we have T = U.
On the other hand, the virial theorem is supposed to be saying
2 T =

x
d
dx
V (x)

.
In this case,
d
dx
V (x) = mω
2
x,
so the virial theorem says that
T =

1
2

2
x
2

= U
in accord with what we concluded earlier.
Problem 5.3
Calculate the expectation value of x
4
for the nth energy eigenstate of the harmonic
oscillator.

Ψ
n

x
4

Ψ
n

=
1
n! 2
n


¯ hπ

1/2


−∞
x
4
exp(−

¯ h
x
2
)H
2
n
(


¯ h
x) dx
Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 4
=
1
n! 2
n

π

¯ h

2


−∞
u
4
e
−u
2
H
2
n
(u) du (4)
For the integral we want to use (3) again, but this time we’ll need to write
out the expansion a little further than before.
¸
n,k,p
I
nkp
s
n
t
k
(2λ)
p
n! k! p!
=

π e
λ
2
+2λ(s+t)+2st
. (5)
=

π

1 +λ
2
+
1
2
λ
4
+ · · ·

1 + · · · +
1
2
(2λ)
2
(s +t)
2
+ · · · +
1
4!
(2λ)
4
(s +t)
4
+ · · ·


¸
j=0
(2st)
j
j!
=

π

1 +λ
2
+
1
2
λ
4
+ · · ·

1 + · · · + 4λ
2
st + · · · + 4λ
4
(st)
2
+ · · ·


¸
j=0
(2st)
j
j!
= · · · +

π

¸
j=0

4
)(st)
j

2
j−1
j!
+ 4
2
j−1
(j − 1)!
+ 4
2
j−2
(j − 2)!

+ · · ·
= · · · +

π

¸
j=0

4
)(st)
j
2
j
j!

1
2
+ 2j +j(j − 1)

= · · · +

π

¸
j=0

4
)(st)
j
2
j
j!

1
2
+j +j
2

In the first line, I only wrote out terms that can be combined to give a factor of
λ
4
. In the second line, I further limited it to terms that also contain the same
number of powers of s as t. Equating powers in (5),
I
nn4
=
3
2
2
n
n!

π(
1
2
+n +n
2
),
so (4) is

Ψ
n

x
4

Ψ
n

=
3
2

¯ h

2
(
1
2
+n +n
2
).
Problem 5.4
For the energy eigenstates with n=0, 1, and 2, compute the probability that the
coordinate of a linear harmonic oscillator in its ground state has a value greater
than the amplitude of the classical oscillator of the same energy.
The classical amplitude is A =

(2E)/(mω
2
). The probability of finding
the particle with coordinate greater than this is
P(|x| > A) =

−A
−∞
Ψ
2
n
(x) dx +


A
Ψ
2
n
(x) dx
Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 5
= 2


A
Ψ
2
n
(x) dx
=
2
n! 2
n


¯ hπ

1/2


A
exp(−

¯ h
x
2
)H
2
n
(


¯ h
x) dx
=
2
n! 2
n

π



2E/¯ hω
e
−u
2
H
2
n
(u) du
=
1
n! 2
n−1

π



2n+1
e
−u
2
H
2
n
(u) du
In going from the first line to the second we invoked the fact that Ψ
n
has either
even or odd parity, so Ψ
2
n
has even parity. In going from the second to last line
to the last line, we noted that the energy of the nth eigenstate is ¯ hω(n + 1/2).
In particular,
P
n=0
(|x| > A) =
1

π


1
e
−u
2
du
=
1


0
e
−p
2
/2
dp −


2
0
e
−p
2
/2
dp
¸
=
1

π
2


2π · erf(

2)

=
1
2
− erf(

2) ≈ 0.31
Problem 5.5
Show that if an ensemble of linear harmonic oscillators is in thermal equilibrium,
governed by the Boltzmann distribution, the probability per unit length of finding
a particle with displacement x is a Gaussian distribution. Plot the width of the
distribution as a function of temperature. Check the results in the classical and
low-temperature limits. [Hint: Equation (5.43) may be used.]
Suppose we denote the number of oscillators in the nth energy state by N
n
.
If the ensemble is in thermal equilibrium, the ratio of the number of oscillators
in the n

th state to the number of oscillators in the nth state is
N
n

N
n
= e
−(n

−n)¯ hω/kT
.
In particular, for any n,
N
n
= N
0
e
−n¯ hω/kT
.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 6
The probability of finding a particle between x and dx is
P(x)dx =

¸
n=0
C
n

n
(x)|
2
dx
= C
0


¯ hπ

1/2
exp(−

¯ h
x
2
)

¸
n=0
e
−n¯ hω/kT
n! 2
n
H
2
n
(


¯ h
x)dx
This can be summed using the Mehler formula with t = exp(−¯ hω/kT) :
P(x) = C
0


¯ hπ

1/2
exp(−

¯ h
x
2
)

1

1 −t
2

exp
¸
2t
1 +t


¯ h
x
2

= C
0


¯ hπ

1/2

1

1 −t
2

exp
¸

1 −t
1 +t


¯ h
x
2

This is a Gaussian distribution with variance
σ
2
=
¯ h
2mω

1 +t
1 −t

=
¯ h
2mω

1 +e
−¯ hω/kT
1 −e
−¯ hω/kT

=
¯ h
2mω
coth

¯ hω
2kT

Solutions to Problems in Merzbacher,
Quantum Mechanics, Third Edition
Homer Reid
June 24, 2000
Chapter 6
Problem 6.1
Obtain the transmission coefficient for a rectangular potential barrier of width 2a
if the energy exceeds the height V
0
of the barrier. Plot the transmission coefficient
as a function E/V
0
(up to E/V
0
= 3), choosing (2ma
2
V
0
)
1/2
= (3π/2).
In the text, Merzbacher treats this problem for the case where the particle’s
energy is less than the potential barrier. He obtains the result
M
11
=

cosh2κa +
i
2
sinh 2κa

e
2ika
(1)
where
κ =

2m(V
0
−E)

2
and
=
κ
k

k
κ
. (2)
We can re-use the result (1) for the case where the energy is greater than
the potential barrier. To do this we note that κ becomes imaginary in this case,
and we write
κ = iβ = i

2m(E −V
0
)

2
so that (2) becomes
=

k

k

= i

β
k
+
k
β

≡ iλ
1
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 2
Plugging into (1) and noting that coshix = cos x, sinhix = i sinx we have
M
11
=

cos 2βa −

2
sin 2βa

e
2ika
.
and
|M
11
| =

cos
2
2βa +
λ
2
4
sin
2
βa

1/2
=
¸
1 +

λ
2
4
−1

sin
2
βa

1/2
=
¸
1 +

β
4
+k
4

2
k
2

1
2

sin
2
βa

1/2
=
¸
1 +


2
−k
2
)
2

2
k
2

sin
2
βa

1/2
=
¸
1 +

V
2
0
4E(E −V
0
)

sin
2
βa

1/2
=
¸
1 +

1
4γ(γ −1)

sin
2
βa

1/2
=
¸
4γ(γ −1) + sin
2
βa
4γ(γ −1)

1/2
where γ = E/V
0
.
We have
βa =
¸
2m
h
2
(E −V
0
)

1/2
a
=

2mV
0
a
2
h
2

1/2
(γ −1)
1/2
=

2
(γ −1)
1/2
so the transmission coefficient is
T =
1
|M
11
|
2
=
¸
4γ(γ −1)
4γ(γ −1) + sin
2


2
(γ −1)
1/2

¸
This is plotted in Figure 1.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 3
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 0.5 1 1.5 2 2.5 3 3.5 4
T
r
a
n
s
m
i
s
s
i
o
n

C
o
e
f
f
i
c
i
e
n
t
E/V0
Figure 1: Transmission coefficient versus E/V
0
for Problem 6.1.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 4
Problem 6.2
Consider a potential V = 0 for x > a, V = −V
0
for a ≥ x ≥ 0, and V = +∞
for x < 0. Show that for x > a the positive energy solutions of the Schr¨ odinger
equation have the form
e
i(kx+2δ)
−e
−ikx
Calculate the scattering coefficient |1 − e
2iδ
|
2
and show that it exhibits maxima
(resonances) at certain discrete energies if the potential is sufficiently deep and
broad.
We have
Ψ(x) =

0, x ≤0
Ae
ik1x
+Be
−ik1x
, 0 ≤x ≤ a
Ce
ik2x
+De
−ik2x
, a ≤ x
with
k
1
=

2m(E +V
0
)

2
k
2
=

2mE

2
.
Applying the requirement that Ψ be continuous at x = 0, we see we must take
A = −B, so Ψ(x) = γ sin k
1
x for 0 ≤ x ≤ a. The other standard requirement,
that the derivative of Ψ also be continuous, does not hold at x = 0 because the
potential is infinite there. Hence γ is undetermined as yet. Eventually, we could
apply the normalization condition on Ψ to find γ if we wanted to.
Next applying continutity of Ψ and its derivative at x = a, we obtain
γ sin k
1
a = Ce
ik2a
+De
−ik
2
a
k
1
γ cos k
1
a = ik
2
[Ce
ik2a
−De
−ik
2
a
]
Combining these yields
C =
1
2i
γe
−ik2a
¸
k
1
k
2
cos k
1
a +i sink
1
a

(3)
D = −
1
2i
γe
+ik2a
¸
k
1
ik
2
cos k
1
a −i sink
1
a

(4)
It’s now convenient to write
k
1
k
2
cos k
1
a +i sink
1
a = αe

(5)
where
α
2
=

k
1
k
2

2
cos
2
k
1
a + sin
2
k
1
a (6)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 5
and
δ = tan
−1
¸
k
2
k
1
tank
1
a

so that α contains magnitude information, while δ represents phase information.
Then we can rewrite (3) and (4) as
C =
γα
2i
e
−ik2a
e

D = −
γα
2i
e
+ik2a
e
−iδ
Then the expression for the wavefunction to the left of x = a becomes
Ψ(x) = Ce
ik2x
+De
−ik2x
(x > a)
=
γα
2i

e
ik2(x−a)
e

−e
−ik2(x−a)
e
−iδ

=
γα
2i
e
−iδ

e
ik2(x−a)
e
2iδ
−e
−ik2(x−a)

.
Using (5) and (6), the scattering coefficient is
|1 −e
2iδ
|
2
=

1 −

k1
k2

2
cos
2
k
1
a + 2i
k1
k2
cos k
1
a sin k
1
a −sin
2
k
1
a

k1
k2

2
cos
2
k
1
a + sin
2
k
1
a

2
=

2 sink
1
a

sin k
1
a −i
k1
k2
cos k
1
a

k1
k2

2
cos
2
k
1
a + sin
2
k
1
a

2
=
4 sin
2
k
1
a

k1
k2

2
cos
2
k
1
a + sin
2
k
1
a
(7)
We have

k
1
k
2

2
=
E +V
0
E
=

1 +
1
λ

k
1
a =

2ma
2
(E +V
0
)

2
= β(λ + 1)
1/2
where λ = E/V
0
and β = (2ma
2
V
0
/
2
)
1/2
in Merzbacher’s notation. Then the
scattering coefficient (7) is
scattering coefficient =
4 sin
2
[β(λ + 1)
1/2
]
(1 +
1
λ
)
2
cos
2
[β(λ + 1)
1/2
] + sin
2
[β(λ + 1)
1/2
]
In Figure 6.2 I have plotted this for β = 25.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 6
0
0.5
1
1.5
2
2.5
3
3.5
4
0 0.5 1 1.5 2 2.5 3
S
c
a
t
t
e
r
i
n
g

c
o
e
f
f
i
c
i
e
n
t
E/V0
Figure 2: Scattering coefficient versus E/V
0
for Problem 6.2.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 7
Problem 6.3
A particle of mass m moves in the one-dimensional double well potential
V (x) = −gδ(x −a) −gδ(x +a).
If g > 0, obtain transcendental equations for the bound-state energy eigenvalues of
the system. Compute and plot the energy levels in units of
2
/ma
2
as a function of
the dimensionless parameter mag/
2
. Explain the features of the plot. In the limit
of large separation, 2a, between the wells, obtain a simple formula for the splitting
∆E between the ground state (even parity) energy level, E
+
, and the excited (odd
parity) energy level, E

.
In this problem, we can divide the x axis into three regions. In each region,
the wavefunction is just the solution to the free-particle Schr¨ odinger equation,
but with energy E < 0 since we’re looking for bound states. Putting k =

2mE/
2
, we have
Ψ(x) =

Ae
kx
+Be
−kx
, x ≤ −a
Ce
kx
+De
−kx
, −a ≤ x ≤ a
Ee
kx
+Fe
−kx
, a ≤ x.
Now, first of all, the wavefunction can’t blow up at infinity, so B = E = 0.
Also, since the potential in this problem has mirror-reversal symmetry, the
wavefunction will have definite parity. Considering first the even parity solution,
Ψ(x) =

Ae
kx
, x ≤ −a
Bcosh(kx), −a ≤ x ≤ a
Ae
−kx
, a ≤ x.
(8)
Matching the value of the wavefunction at x = −a gives
Ae
−ka
= Bcosh(−ka). (9)
Since the potential becomes infinite at x = −a, the normal derivative-continuity
condition doesn’t hold there. Instead, we can write down the Schr¨ odinger equa-
tion,
d
2
dx
2
Ψ(x) =
2m

2
V (x)Ψ(x) −
2m

2
EΨ(x),
then integrate from −a − to −a + and take the limit as →0. This gives

dx

−a+
−a−
= −
2mg

2
Ψ(−a). (10)
Applying this condition to the wavefunction (8) yields
kBsinh(−ka) −kAe
−ka
= −
2mg

2
Bcosh(−ka).
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 8
Substituting from (9),
kBsinh(−ka) −kBcosh(−ka) = −
2mg

2
Bcosh(−ka)
or
tanh(ka) =
2mg

2
k
−1 =
β
ka
−1
with β = 2mag/
2
. This equation determines the energy eigenvalue of the even-
parity state, which will be the ground state. On the other hand, the odd parity
state looks like
Ψ(x) =

Ae
kx
, x ≤ −a
Bsinh(kx), −a ≤ x ≤ a
−Ae
−kx
, a ≤ x.
(11)
Matching values at x = −a gives
Ae
−ka
= Bsinh(−ka)
and applying condition (10) gives
kBcosh(−ka) −kAe
−ka
= −
2mg

2
Bsinh(−ka)
kBcosh(ka) +kBsinh(ka) =
2mg

2
Bsinh(ka)
coth(ka) =
β
ka
−1
so this is the condition that determines the energy of the odd parity state.
In Figure (3) I have plotted tanh(ka), coth(ka), and β/(ka) −1 for the case
β = 3. As expected, the coth curve crosses the β/(ka) −1 curve at a lower value
of ka than the tanh curve; that means that the energy eigenvalue for the odd
parity state is smaller in magnitude (less negative) than the even parity state.
Problem 6.4
Problem 3 provides a primitive model for a one-electron linear diatomic molecule
with interatomic distance 2a = |X|, if the potential energy of the “molecule” is
taken as E
±
(|X|), supplemented by a repulsive interaction λg/|X| between the wells
(“atoms”). Show that, for a sufficiently small value of λ, the system (“molecule”)
is stable if the particle (“electron”) is in the even parity state. Sketch the total
potential energy of the system as a function of |X|.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 9
0
0.5
1
1.5
2
1 1.2 1.4 1.6 1.8 2
P
S
f
r
a
g
r
e
p
l
a
c
e
m
e
n
t
s
tanh(ka)
coth(ka)
β/(ka) −1
ka
Figure 3: Graphical determination of energy levels for Problem 6.3 with β = 3.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 10
Problem 6.5
If the potential in Problem 3 has g < 0 (double barrier), calculate the transmission
coefficient and show that it exhibits resonances. (Note the analogy between the
system and the Fabry-Perot ´etalon in optics.)
Now we’re assuming that the energy E is positive, so
Ψ(x) =

Ae
ikx
+Be
−ikx
x ≤ −a
Ce
ikx
+De
−ikx
−a ≤ x ≤ a
Ee
ikx
+Fe
−ikx
a ≤ x
(12)
with k =

2mE/
2
. Matching values at x = −a, we have
Ae
−ika
+Be
ika
= C
−ika
+D
ika
(13)
Also, as before, we have the derivative condition

dx

x=−a+
x=a−
= −
2mg

2
Ψ(−a)
where g is now negative. Applying this to the wavefunction in (12), we have
ik[Ce
−ika
−De
ika
−Ae
−ika
+Be
ika
] = −
2mg

2
[Ae
−ika
+Be
ika
]. (14)
Combining (13) and (14) yields
C =

1 +
β
ika

A+
β
ika
e
2ka
B (15)
D = −
β
ika
e
−2ka
A+

1 −
β
ika

B (16)
with β = mag/
2
as before.
Now, applying the matching conditions to the wavefunction at x = +a will
give two equations exactly like (13) and (14), but with the substitutions A →C,
B →D, C →E, D →F, and a →−a. Making these substitutions in (15) and
(16) we obtain
E =

1 −
β
ika

C −
β
ika
e
2ka
D (17)
F = +
β
ika
e
2ka
C +

1 +
β
ika

D (18)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 11
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 5 10 15 20 25 30
P
S
f
r
a
g
r
e
p
l
a
c
e
m
e
n
t
s
ka
T
(
k
)
Figure 4: Transmission coefficient in Problem 6.4 with β = 15.
Combining equations (15) through (18), we have
E =
¸
1 +

β
ika

2
(e
−4ika
−1)
¸
A+ +
¸

ka

1 −
β
ika

sin2ka

B
F =
¸

ka

1 +
β
ika

sin 2ka

A+
¸
1 +

β
ika

2
(e
4ika
−1)
¸
B
This is the M matrix, and the transmission coefficient is given by T = 1/|M
11
|
2
,
or
T =
1
1 + 2

β
ka

2
¸

β
ka

2
+ 1

(1 −cos(4ka))
In Figure 4 I have plotted this for β = 15.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 12
Problem 6.6
A particle moves in one dimension with energy E in the field of a potential defined
as the sum of a Heaviside step function and a delta function:
V (x) = V
0
η(x) +gδ(x) (with V
0
and g > 0)
The particle is assumed to have energy E > V
0
.
(a) Work out the matrix M, which relates the amplitudes of the incident and
reflected plane waves on the left of the origin (x < 0) to the amplitudes on
the right (x > 0).
(b) Derive the elements of the matrix S, which relates incoming and outgoing
amplitudes.
(c) Show that the S matrix is unitary and that the elements of the S matrix satisfy
the properties expected from the applicable symmetry considerations.
(d) Calculate the transmission coefficient for particles incident from the right and
for particles incident from the left, which have the same energy (buf different
velocities).
We have
Ψ(x) =

Ae
ik1x
+Be
−ik1x
, x ≤ 0
Ce
ik2x
+De
−ik2x
, x ≥ 0
with
k
1
=

2m

2
E k
2
=

2m

2
(E −V
0
).
Matching values at x = 0 gives
C +D = A+B (19)
Also, the delta function at the origin gives rise to a discontinuity in the derivative
of the wavefunction as before:

dx

0+
0−
=
2mg

2
Ψ(0)
so
ik
2
(C −D) −ik
1
(A−B) =
2mg

2
(A+B)
or
C −D =
k
1
k
2
(A−B) +
2mg
ik
2

2
(A+B). (20)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 13
Adding and subtracting (19) and (20), we can read off
C =
1
2
¸
1 +
k
1
k
2
+
2mg
ik
2

2

A+
1
2
¸
1 −
k
1
k
2
+
2mg
ik
2

2

B
D =
1
2
¸
1 −
k
1
k
2

2mg
ik
2

2

A
1
2
¸
1 +
k
1
k
2

2mg
ik
2

2

B.
We could also write this as

C
D

=

M
11
M
12
M

12
M

11

A
B

Or instead of the M matrix we could use the S matrix, which is defined by

B
C

=

S
11
S
12
S
21
S
22

A
D

Since we already know the M coefficients, we can calculate the elements of the
S matrix from the formula
S
11
= −
M

12
M

11
S
12
=
1
M

11
S
21
=
1
M

11
S
22
= +
M12
M

11
However, this is tedious and long and boring and I don’t want to do it.
Solutions to Problems in Merzbacher,
Quantum Mechanics, Third Edition
Homer Reid
April 5, 2001
Chapter 7
Before starting on these problems I found it useful to review how the WKB
approximation works in the first place. The Schr¨ odinger equation is


2
2m
d
2
dx
2
Ψ(x) +V (x)Ψ(x) = EΨ(x)
or
d
2
dx
2
Ψ(x) +k
2
(x)Ψ(x) = 0, k(x) ≡

2m

2
[E −V (x)].
We postulate for Ψ the functional form
Ψ(x) = Ae
iS(x)/
in which case the Schr¨ odinger equation becomes
iS

(x) = [S

(x)]
2

2
k
2
(x). (1)
This equation can’t be solved directly, but we obtain guidance from the obser-
vation that, for a constant potential, S(x) = ±kx, so that S

vanishes. For a
nonconstant but slowly varying potential we might imagine S

(x) will be small,
and we may take S

= 0 as the seed of a series of successive approximations
to the exact solution. To be specific, we will construct a series of functions
S
0
(x), S
1
(x), · · · , where S
0
is the solution of (1) with 0 on the left hand side;
S
1
is a solution with S

0
on the left hand side; and so on. In other words, at
the nth step in the approximation sequence (by which point we have computed
S
n
(x)), we compute S

n
(x) and use that as the source term on the LHS of (1)
to calculate S
n+1
(x). Then we compute the second derivative of S
n+1
(x) and
use this as the source term for calculating S
n+2
, and so on ad infinitum. In
1
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 2
symbols,
0 = [S

0
(x)]
2

2
k
2
(x) (2)
iS

0
= [S

1
(x)]
2

2
k
2
(x) (3)
iS

1
= [S

2
(x)]
2

2
k
2
(x) (4)
· · · ·
Equation (2) is clearly solved by taking
S

0
(x) = ±k(x) ⇒ S
0
(x) = S
00
±

x
−∞
k(x

)dx

(5)
for any constant S
00
. Then S

0
(x) = ±k

(x), so (3) is
S

1
(x) = ±

k
2
(x) ±ik

(x).
With the two ± signs here, we appear to have four possible choices for S

1
. But
let’s think a little about the ± signs in this equation. The ± sign under the
radical comes from the two choices of sign in (5). But if we chose, say, the plus
sign in that equation, so that S

0
> 0, we would also expect that S

1
> 0. Indeed,
if we choose the plus sign in (5) but the minus sign in (3), then S

0
and S

1
have
opposite sign, so S

1
differs from S

0
by an amount at least as large as S

0
, in
which case our approximation sequence S
0
, S
1
, · · · has little hope of converging.
So we choose either both plus signs or both minus signs in (3), whence our two
choices are
S

1
= +

k
2
(x) +ik

(x) or S

1
= −

k
2
(x) −ik

(x). (6)
If V (x) is constant, k(x) is constant, and, as we observed before, the sequence
of approximations terminates at 0th order with S
0
being an exact solution. By
extension, if V (x) is not constant but changes little over one particle wavelength,
we have k

(x)/k
2
(x) 1, so we may expand the radicals in (6):
S

1
≈ k(x)

1 +
ik

(x)
2k
2
(x)

or S

1
≈ −k(x)

1 −
ik

(x)
2k
2
(x)

or
S

1
≈ ±k(x) +
ik

(x)
2k(x)
. (7)
Integrating,
S
1
(x) = S
1
(a) ±

x
a
k(u)du +
i
2

x
a
k

(u)
k(u)
dx

= S
1
(a) ±

x
a
k(u)du +
i
2
ln
k(x)
k(a)
where a is some point chosen such that the approximation (7) is valid in the
full range a < x

< x. We could go on to compute S
2
, S
3
, etc., but in practice
it seems the approximation is always terminated at S
1
.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 3
The wavefunction at this order of approximation is
Ψ(x) = exp(iS
1
(x)/) =

e
iS1(a)/

e
±i
R
x
a
k(u)du

e
ln k(x)/k(a)

−1/2
= Ψ(a)

k(a)
k(x)
e
±i
R
x
a
k(u)du
= Ψ(a)G
±
(x; a)
where
(8)
G
±
(x; a) ≡

k(a)
k(x)
e
±i
R
x
a
k(u)du
. (9)
We have written it this way to illustrate that the function G(x, a) is kind of like
a Green’s function or propagator for the wavefunction, in the sense that, if you
know what Ψ is at some point a, you can just multiply it by G
±
(x; a) to find
out what Ψ is at x. But this doesn’t seem quite right: Schr¨ odinger’s equation
is a second-order differential equation, but (8) seems to be saying that we need
only one initial condition—the value of Ψ at x = a—to find the value of Ψ at
other points. To clarify this subtle point, let’s investigate the equations leading
up to (8). If the approximation (7) makes sense, then there are two solutions
of Schr¨ odinger’s equation at x = a, one whose phase increases with increasing
x (positive derivative), and one whose phase decreases. Equation (8) seems to
be saying that we can use either G
+
or G

to get to Ψ(x) from Ψ(a); but the
requirement the dΨ/dx be continuous at x = a means that only one or the
other will do. Indeed, in using (8) to continue Ψ from a to x we must choose
the appropriate propagator—either G
+
or G

, according to the derivative of
Ψ at x = a; otherwise the overall wave function will have a discontinuity in its
first derivative at x = a. So to use (8) to obtain values for Ψ at a point x, we
need to know both Ψ and Ψ

at a nearby point x = a, as should be the case for
a second-order differential equation.
If we want to de-emphasize this nature of the solution with the propagator
we may write
Ψ(x) = C

1
k(x)
e
±i
R
x
a
k(u)du
(10)
where C = Ψ(a)

k(a). In regions where V (x) > E, k(x) is imaginary, so it’s
useful to define
κ(x) = −ik(x) =

2m

2
[V (x) −E] (11)
and
Ψ(x) = C

1
κ(x)
e
±
R
x
a
κ(u)du
. (12)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 4
If we have a region of space in which the WKB approximation is valid,
knowing the value of Ψ (and its derivative) at one point within the region is
equivalent to knowing it everywhere, because we can use the propagator (9)
to get from that one point to every other point within the region. The WKB
method, however, gives us no way of determining the value of Ψ at that one
starting point. Furthermore, even if we know Ψ at one point within a region of
validity, we can’t use (8) to determine Ψ in other, nonadjacent regions, because
we can’t carry the propagator across regions of invalidity. So basically what we
need is a way of finding one starting value for Ψ(x) in every region of validity
of the WKB approximation.
How do we find such points? Well, one sure-fire way to get starting points
in regions of validity is to identify regions of invalidity, of which there will be
at least one adjacent to each region of validity, and then get values of Ψ at the
boundaries of the regions of invalidity—which will also count as values in the
regions of validity. So we need to identify the regions of invalidity of the WKB
approximation and do a more accurate solution of the Schr¨ odinger equation
there.
The WKB approximation breaks down when k

/k
2
1 ceases to hold, which
is true when k ≈ 0 but k

= 0, which happens near a classical turning point of
the motion—i.e., a point x
0
at which V (x
0
) = E. But near such a point we may
expand V (x) − E in a Taylor series around the point x
0
; if we keep only the
first (linear in x) term in the series, we arrive at a Schr¨ odinger equation which
we can solve exactly in the vicinity of x
0
. To do this, suppose the point x
0
is a
classical turning point of the motion, so that V (x
0
) = E. In the neighborhood
of x
0
we may expand V (x):
V (x) = E + (x −x
0
)V

(x
0
) +· · · (13)
Then the Schr¨ odinger equation becomes
d
2
dx
2
Ψ(x) −
2m

2
V

(x
0
)(x −x
0
)Ψ(x) = 0. (14)
The useful substitution here is
u(x) = γ(x −x
0
) γ ≡
¸
2m

2
V

(x
0
)

1/3
so
x(u) =
u
γ
+x
0
.
If we define
Φ(u) = Ψ(x(u))
then

du
=

dx
dx
du
=
1
γ
Ψ

(x(u))
d
2
Φ
du
2
=
1
γ
2
Ψ

(x(u))
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 5
so (14) becomes
γ
2
d
2
du
2
Φ(u) −γ
3
(x −x
0
)Φ(u) = 0
or
d
2
du
2
Φ(u) −uΦ(u) = 0.
The solution to this differential equation is
Φ(u) = β
1
Ai(u) +β
2
Bi(u) (15)
so the solution to the Schr¨ odinger equation (14) is
Ψ(x) = β
1
Ai

γ(x −x
0
)


2
Bi

γ(x −x
0
)

.
For γ(x − x
0
) 1 we have the asymptotic expression
Ψ(x) ≈ π
−1/2
[γ(x −x
0
)]
−1/4

β
1
2
e

2
3
|γ(x−x0)|
3/2

2
e
+
2
3
|γ(x−x0)|
3/2

(16)
and for γ(x −x
0
) −1 we have
Ψ(x) ≈ π
−1/2
|γ(x −x
0
)|
−1/4

β
1
cos

2
3
|γ(x −x
0
)|
3/2

π
4

−β
2
sin

2
3
|γ(x −x
0
)|
3/2

π
4

. (17)
To simplify these, we need to consider two possible kinds of turning point.
Case 1: V

(x
0
) > 0.
In this case the potential is increasing through the turning point at x
0
, which
means that V (x) < E for x < x
0
, and V (x) > E for x > x
0
. Hence the region
to the left of the turning point is the classically accessible region, while the right
of the turning point is classically forbidden. Since V

(x
0
) > 0, γ > 0, so for
x < x
0
(??) holds. For points close to the turning point on the left side,
k(x) =

2m

2
[E −V (x)] ≈
¸
2m

2
V

1/2
(x
0
−x)
1/2
= γ
3/2
(x
0
−x)
1/2
so
|γ(x −x
0
)|
−1/4
=

γ
k(x)
(18)
and

x0
x
k(u)du = γ
3/2

x0
x
(x
0
−x)
1/2
du =
2
3
γ
3/2
(x
0
−x)
3/2
=
2
3
|γ(x −x
0
)|
3/2
. (19)
On the other hand, for points close to the turning point on the left side we
have x > x
0
, so γ(x −x
0
) > 0. In this region,
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 6
κ(x) =

2m

2

V (x) −E


¸
2m

2
V

(x
0
)(x −x
0
)

1/2
= γ
3/2
(x −x
0
)
1/2
(20)
so, for x near x
0
,

x
x0
κ(u)du = γ
3/2

x
x0
(u −x
0
)
1/2
du =
2
3
γ
3/2
(x −x
0
)
3/2
(21)
and also
|γ(x −x
0
)|
−1/4
=

γ
κ(x)
. (22)
Using (18) and (19) in (17), and (21) and (22) in (16), the solutions to the
Schr¨ odinger equation on either side of a classical turning point x
0
at which
V

(x
0
) > 0 are
Ψ(x) =

1
k(x)


1
cos

x0
x
k(u)du −
π
4

−β
2
sin

x0
x
k(u)du −
π
4

, x < x
0
(23)
Ψ(x) =

1
κ(x)

β
1
e
R
x
x
0
κ(u)du

2
e

R
x
x
0
κ(u)du

, x < x
0
(24)
(we redefined the β constants slightly in going to this equation).
Case 2: V

(x
0
) < 0.
In this case the potential is decreasing through the turning point, so the
classically accessible region is to the right of the turning point, and the forbidden
region to the left. Since V

(x
0
) < 0, γ < 0. That means that the regions of
applicability of (16) and (17) are on opposite sides of the turning points as they
were in the previous case. The solutions to the Schr¨ odinger equation on either
side of the turning point are
Ψ(x) =

1
κ(x)

β
1
e
R
x
0
x
κ(u)du

2
e

R
x
x
0
κ(u)du

, x < x
0
(25)
Ψ(x) =

1
k(x)


1
cos

x
x0
k(u)du −
π
4

−β
2
sin

x
x0
k(u)du −
π
4

, x > x
0
(26)
(27)
So, to apply the WKB approximation to a given potential V (x), the first
step is to identify the classical turning points of the motion, and to divide space
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 7
up into regions bounded by turning points, within which regions the WKB
approximation (7) is valid. Then, for each turning point, we write down (23)
and (24) (or (25) and (26)) at nearby points on either side of the turning point,
and then use (10) to evolve the wavefunction from those points to other points
within the separate regions.
We should probably quantify the meaning of “nearby” in that last sentence.
Suppose x
0
is a classical turning point of the motion, and we are looking for
points x
0
± at which to make the “handoff” from approximations (16) and
(17) to the WKB approximation These points must satisfy several conditions.
First, the approximate Schr¨ odinger equation (14) is only valid as long as we can
neglect the quadratic and higher-order terms in the expansion (13), so we must
have
|V

(x
0
)| |V

(x
0
)| ⇒

V

(x
0
)
V

(x
0
)

. (28)
But at the same time, γ must be sufficiently greater than 1 to justify the
approximation (16) (or sufficiently less than -1 to justify (17)); the condition
here is

2m

2
V

(x
0
)

1/3
1 ⇒

2m

2
V

(x
0
)

−1/3
. (29)
Finally, the points x± must be sufficiently far away from the turning points that
the approximation (7) is valid for the derivative of the phase of the wavefunction;
the condition for this to be the case was

k

(x)
k
2
(x)

1 ⇒
1
2

2
2m

V

(x ±)
[E −V (x ±)]
3/2

1. (30)
If there are no points x
0
± satisfying all three conditions, the WKB approxi-
mation cannot be used.
To apply all of this to the problem of bound states in a potential well,
consider a potential like that shown in Figure 1, with two classical turning points
at x = a and x = b. Although there are no discontinuities in the potential
here, the problem may be analyzed in a manner similar to that used in the
consideration of one-dimensional piecewise constant potentials, as in Chapter
6: we divide space into a number of distinct regions, obtain solutions of the
Schr¨ odinger equation in each region, and then match values and derivatives at
the region boundaries.
To divide space into distinct regions in this case, we begin by identifying
narrow regions around the turning points a and b in which the linear approx-
imation (13) is valid. In the narrow region around x = a, we may use (25)
and (26); around x = b we may use (23) and (24). Let the narrow such region
around a be a−
1
< x < a+
1
, and that around b be b −
2
< x < b +
2
. Then
space divides naturally into five regions: (a) x < a −
In this region we are far enough to the left of the turning point that the WKB
approximation is valid, and the wavefunction takes the form (10). However, we
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 8
P
S
f
r
a
g
r
e
p
l
a
c
e
m
e
n
t
s
a b
E
V (x)
Figure 1: A potential V (x) with two classical turning points for an energy E.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 9
must throw out the term that grows exponentially as x → −∞, so we are left
with
Ψ(x) = A

1
κ(x)
e

R
(a−)
x
κ(u)du
, x < a −. (31)
(b) a − < x < a +
In this region we are close enough to the turning point that (13) is valid, so
(25) and (26) may be used.
Ψ(x) =

1
κ(x)

β
1
e

R
a
x
κ(u)du

2
e
+
R
a
x
κ(u)du

, x < (a −). (32)
From (31) and (32) we see that continuity of both the value and first derivative of
Ψ(x) at x = a− requires taking β
1
= A, β
2
= 0. With this choice of constants,
we achive continuity not only of the value and first derivative of Ψ but also of
all higher derivatives, as must be the case since there is no discontinuity in the
potential.
But now that we know the value of Ψ at x = a − , we also know it at
x = a + , because of course the solution of the Schr¨ odinger equation in the
narrow strip around a (to which (32) is an asymptotic approximation for x < a)
is valid throughout the strip; the same solution that’s valid at x = a − is valid
at x = a +. With β
1
= A and β
2
= 0, (26) becomes
Ψ(x) = 2A

1
k(x)
cos

x
a
k(u)du −
π
4

= A

1
k(x)

e
+i(
R
x
a
k(u)du−π/4)
+e
−i(
R
x
a
k(u)du−π/4)

, x = (a +)−
(33)
(c) a + < x < b −
In this region the WKB approximation (7) is valid, so we may use (8) to find
the wavefunction at any point within the region. Using the expression (33) for
the wavefunction at x = a+, integrating from a+ to x in the propagator (9),
and using G
+
and G

, respectively, to propagate the first and second terms in
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 10
(33), we obtain for the wavefunction at a point x in this region
Ψ(x) = A

1
k(x)
¸
e
+i

R
(a+)
a
k(u)du+
R
x
(a+)
k(u)du−π/4

+e
−i

R
(a+)
a
k(u)du+
R
x
(a+)
−π/4

= A

1
k(x)

e
+i(
R
x
a
k(u)du−π/4)
+e
−i(
R
x
a
k(u)du−π/4)

= 2A

1
k(x)
cos

x
a
k(u)du −
π
4

= 2A

1
k(x)
cos

b
a
k(u)du −

b
x
k(u)du −
π
4

, a + < x < b −
(34)
Okay, I have now carried this analysis far enough to see for myself exactly
where the Bohr-Sommerfeld quantization condition

b
a
k(u)du =

n +
1
2

π, n = 1, 2, · · · (35)
comes from, which was my original goal, so I am now going to stop this exercise
and proceed directly to the problems.
Problem 7.1
Apply the WKB method to a particle that falls with acceleration g in a uniform
gravitational field directed along the z axis and that is reflected from a perfectly
elastic plane surface at z = 0. Compare with the rigorous solutions of this problem.
We’ll start with the exact solution to the problem. The requirement of
perfect elastic reflection at z = 0 may be imposed by taking V (x) to jump
suddenly to infinity at z = 0, i.e.
V (x) =

mgz, z > 0
∞, z ≤ 0.
For z > 0, the Schr¨ odinger equation is
0 =
d
2
dx
2
Ψ(x) +
2m

2
[E −mgz] Ψ(x)
=
d
2
dx
2
Ψ(x) +
2m
2
g

2
¸
E
mg
−z

Ψ(x)
=
d
2
dx
2
Ψ(x) −
2m
2
g

2
[z −z
0
] Ψ(x) (36)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 11
where z
0
= E/mg. With the substitution
u = γ(z −z
0
) γ =

2m
2
g

2

1/3
and taking Φ(u) = Ψ(x(u)), we find that (36) is just the Airy equation for Φ(u),
d
2
du
2
Φ(u) −uΦ(u) = 0
with solutions
Φ(u) = β
1
Ai(u) +β
2
Bi(u).
Since we require a solution that remains finite as z →∞, we must take β
2
= 0.
The solution to (36) is then
Ψ(x) = β
1
Ai

γ(z −z
0
)

, (z > 0). (37)
For z < 0, I wasn’t quite sure how to account for the infinite potential
jump at z = 0, so instead I supposed the potential for z < 0 to be a constant,
V (z) = V
0
, where eventually I’ll take V
0
→ ∞. Then the Schr¨ odinger equation
for z < 0 is
d
2
dz
2
Ψ(z) −
2m

2
[V
0
− E] Ψ(z) = 0
with solution
Ψ(z) = Ae
−kz
, k =

2m

2
[V
0
−E]. (38)
Matching values and derivatives of (37) and (38) at z = 0, we have
β
1
Ai(−γz
0
) = A
γβ
1
Ai

(−γz
0
) = −kA
Dividing, we obtain
1
γ
Ai(−γz
0
)
Ai

(−γz
0
)
= −
1
k
Now taking V
0
→ ∞, we also have k → ∞, so the RHS of this goes to zero;
thus the condition is that −γz
0
be a zero of the Airy function, which means the
energy eigenvalues E
n
are given by

2m
2
g

2

1/3
E
n
mg
= x
nm
⇒E
n
=

mg
2

2
2

1/3
x
n
(39)
where x
n
is the nth root of the equation
Ai(−x
n
) = 0.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 12
So that’s the exact solution. In the WKB approximation, the spectrum of
energy eigenvalues is determined by the condition (35). In this case the classical
turning points are at z = 0 and z = z
0
, so we have

n +
1
2

π =

z0
0
k(z) dz
=

2m

2

z0
0
[E −mgz]
1/2
dz
=

2m
2
g

2

z0
0
[z
0
−z]
1/2
du
=

2m
2
g

2


2
3
(z
0
−z)
3/2

z0
0
=
2
3

2m
2
g

2

E
mg

3/2
so the nth eigenvalue is given by
E
n
=

mg
2

2
2

1/3
¸
3
2

n +
1
2

π

2/3
.
Solutions to Problems in Merzbacher,
Quantum Mechanics, Third Edition
Homer Reid
May 13, 2001
Chapter 8
1
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 2
Problem 8.1
Apply the variational method to estimate the ground state energy of a particle
confined in a one-dimensional box for which V = 0 for −a < x < a, and Ψ(±a) = 0.
(a) First, use an unnormalized trapezoidal trial function which vanishes at ±a and
is symmetric with respect to the center of the well:
Ψ
t
(x) =

(a −|x|), b ≤ x ≤ a
(a −b), |x| ≤ b.
(b) A more sophisticated trial function is parabolic, again vanishing at the end
points and even in x.
(c) Use a quartic trial function of the form
Ψ
t
(x) = (a
2
−x
2
)(αx
2
+β),
where the ratio of the adjustable parameters α and β is determined variation-
ally.
(d) Compare the results of the different variational calculations with the exact
ground state energy, and, using normalized wave functions, evaluate the mean
square deviation

a
−a
|Ψ(x) −Ψ
t
(x)|
2
dx for the various cases.
(e) Show that the variational procedure produces, in addition to the approximation
to the ground state, an optimal quartic trial function with nodes between the
endpoints. Interpret the corresponding stationary energy value.
First let’s observe that the exact expressions for the ground state wavefunction
and energy are
Ψ
n
(x) =
1

a
cos(k
n
x), k
n
=

2a
, E
n
= n
2

2
π
2
8ma
2
≈ 1.23

2
ma
2
.
(a) We need first to normalize the trial wavefunction. Taking
Ψ
t
(x) =

γ(a −|x|), b ≤ |x| ≤ a
γ(a −b), x| ≤ b.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 3
we have

a
−a
Ψ
2
t
(x)dx = 2

a
0
Ψ
2
t
(x)dx
= 2γ
2

(a −b)
2

b
0
dx +

a
b
(a −x)
2
dx
¸
= 2γ
2

b(a −b)
2
+
1
3
(a −b)
3

= 2γ
2

b(a
2
+b
2
−2ab) +
1
3
(a
3
−b
3
) −a
2
b +b
2
a

= γ
2
2
3

a
3
+ 2b
3
−3ab
2

so Ψ
t
is normalized by taking
γ
2
=
3
2

1
a
3
+ 2b
3
−3ab
2

. (1)
Now we can compute the energy expectation value of Ψ
t
:
< Ψ
t
|H|Ψ
t
> = −

2
2m

a
−a
Ψ
t
(x)
d
2
dx
2
Ψ
t
(x) dx
Integrating by parts,
= −

2
2m

Ψ
t
(x)Ψ

t
(x)

a
−a

a
−a
Ψ
2
t
(x) dx

(the first integral vanishes since Ψ
t
vanishes at the endpoints)
= +

2
m

a
0
Ψ
2
t
(x) dx
=

2
m
γ
2

a
b
dx
=

2
m
γ
2
(b −a).
Using (1), this is
< H >=
3
2
2m

(b −a)
a
3
+ 2b
3
−3ab
2

.
To find the optimal value of b, we zero the derivative of this with respect to b:
0 =
1
(a
3
+ 2b
3
−3ab
2
)

6b
2
(b −a)
(a
3
+ 2b
3
−3ab
2
)
2
+
6ab(b −a)
(a
3
+ 2b
3
−3ab
2
)
2
= −4b
3
+ 9b
2
a −6a
2
b +a
3
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 4
(b) For a parabolic trial function we take
Ψ
t
(x) = γ(a
2
−x
2
).
The normalization integral is

a
−a
Ψ
2
t
(x) dx = 2γ
2

a
0
(a
2
−x
2
)
2
dx
= 2γ
2

a
0
(a
4
+x
4
−2a
2
x
2
)dx
= 2γ
2

a
5
+
1
5
a
5

2
3
a
5

=
16
15
γ
2
a
5
so Ψ
t
(x) is normalized by taking
γ
2
=
15
16a
5
.
The expectation value of the energy is
< H > = −

2
2m

a
−a
Ψ
t
(x)
d
2
dx
2
Ψ
t
(x) dx
= 2

2
m
γ
2

a
0
(a
2
−x
2
)dx
=
4
3

2
m
γ
2
a
3
=
5
4

2
ma
2
≈ 1.25

2
ma
2
.
So this is in good agreement with the exact ground state energy.
(c) In this case we have
Ψ
t
(x) = γ(a
2
−x
2
)(αx
2
+β)
= γ[−αx
4
+ (αa
2
−β)x
2
+βa
2
]
The kinetic energy is


2
2m
d
2
dx
2
Ψ
t
(x) = γ

2
m
[6αx
2
−(αa
2
−β)].
The expectation value of the energy is
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 5
Problem 8.2
Using scaled variables, as in Section 5.1, consider the anharmonic oscillator Hamil-
tonian,
H =
1
2
p
2
ξ
+
1
2
ξ
2
+λξ
4
where λ is a real-valued parameter.
(a) Estimate the ground state energy by a variational calculation, using as a trial
function the ground state wave function for the harmonic oscillator
H
0
(ω) =
1
2
p
2
ξ
+
1
2
ω
2
ξ
2
where ω is an adjustable variational parameter. Derive an equation that
relates ω and λ.
(b) Compute the variational estimate of the ground state energy of H for various
positive values of the strength λ.
(c) Note that the method yields answers for a discrete energy eigenstate even if λ
is slightly negative. Draw the potential energy curve to judge if this result
makes physical sense. Explain.
(a) To find the ground state eigenfunction of the Hamiltonian Merzbacher pro-
poses, it’s convenient to rewrite it:
H
0
(ω) =
1
2
p
2
ξ
+
1
2
ω
2
ξ
2
= −
1
2

2
∂ξ
2
+
1
2
ω
2
ξ
2
Upon substituting u = ω
1/2
ξ we obtain
= ω


1
2

2
∂u
2
+
1
2
u
2

and now this is just the ordinary harmonic oscillator Hamiltonian, scaled by a
constant factor ω, with ground-state eigenfunction
Ψ(ω) = Ce
−u
2
/2
= Ce
−ωξ
2
/2
.
Adding the normalization constant,
Ψ(ω) =

ω
π

1/4
e
−ωξ
2
/2
.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 6
Now we want to treat ω as a parameter and vary it until the energy expectation
value of Ψ(ω) is minimized. The energy expectation value is
Ψ| H |Ψ = Ψ| T |Ψ +Ψ| V |Ψ
where T = p
2
ξ
/2 and V = ξ
2
/2 +λξ
4
. Let’s compute the two expectation values
separately. First of all, to compute the expectation value of T, we need to know
the result of operating on Ψ(ω) with p
2
ξ
:
p
2
ξ
Ψ(ω) = −

ω
π

1/4


∂ξ
¸

∂ξ
e
−ωξ
2
/2

= −

ω
π

1/4


∂ξ

−ωξe
−ωξ
2
/2

= −

ω
π

1/4
−ω +ω
2
ξ
2

e
−ωξ
2
/2
Then for the expectation value of T we have
Ψ| T |Ψ =
1
2


−∞
Ψ(ξ)p
2
ξ
Ψ(ξ)dξ
= −
1
2

ω
π


−∞

−ω +ω
2
ξ
2

e
−ωξ
2

= −
1
2

ω
π
¸
−ω

π
ω
+
1
2
ω
2

π
ω
3

=
ω
4
. (2)
On the other hand, for the expectation value of V we have
(3)
exptwoΨV Ψ =

ω
π

1
2


−∞
ξ
2
e
−ωξ
2
dξ +λ


−∞
ξ
4
e
−ωξ
2

=

ω
π

1
4

π
ω
3
+
3
4
λ

π
ω
5

=
1

+


2
. (4)
Adding (2) and (4),
exptwoΨHΨ =
1
2
¸
ω +
1
ω
+

ω
2

. (5)
To minimize this with respect to ω we equate its ω derivative to 0:
0 = 1 −
1
ω
2


ω
3
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 7
or
ω
3
−ω −6λ = 0. (6)
We could then solve this equation for ω in terms of λ to obtain the energy-
minimizing value of ω for a given perturbing potential strength λ. But writing
down the full solution would be tedious. Instead let’s see what happens when
λ is small.
Evidently, when λ = 0 the Hamiltonian in this problem degenerates to the
normal harmonic oscillator Hamiltonian, for which the energy is minimized by
the (unscaled) ground state harmonic oscillator wavefunction, i.e. Ψ(ω) with
ω = 1. We can thus imagine that, for small λ, the energy-minimizing value of
ω will be close to 1, and we may write ω(λ) ≈ 1 + for some small . Inserting
this in (6),
(1 + 3 + 3
2
+
3
) −(1 +) = 6λ
Keeping only terms of zeroth or first order in the small quantity (which is
equivalent to keeping terms of lowest order in the perturbing potential strength
λ) we obtain from this
≈ 3λ,
so for λ 0 the minimizing value of ω is
ω ≈ 1 + 3λ.
Inserting this estimate into (5) and again keeping only terms of lowest order in
λ we find
(7)
exptwoΨHΨ =
1
4

(1 +) + (1 +)
−1
+ 3λ(1 +)
−2


1
4

(1 + 3λ) + (1 + 3λ)
−1
+ 3λ(1 + 3λ)
−2


1
4
[(1 + 3λ) + (1 −3λ) + 3λ(1 −6λ)]

1
2
+
3
4
λ. (8)
Since the 1/2 term is the normal (unperturbed) energy of the state, the energy
shift caused by the perturbing potential is
∆E =
3
4
λ. (9)
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 8
Problem 8.3
In first-order perturbation theory, calculate the change in the energy levels of a
linear harmonic oscillator that is perturbed by a potential gx
4
. For small values of
the coefficient, compare the result with the variational calculation in Problem 2.
The energy shift to first order is
∆E = exptwoΨ
n
(x)|gx
4

n
(x) = g Ψ
n
| x
4

n
.
I worked out this expectation value in Problem 5.3:
∆E = gexptwoΨ
n
x
4
Ψ
n
=
3g
2

2
1
2
+n +n
2

In particular, the energy shift of the ground state is
∆E
0
=
3g
4

2
which agrees with () (the difference in the factor (/mω)
2
just represents the
fact that in Problem 8.2 we used scaled variables, whereas in this problem we
inserted the units explicitly).
Problem 8.4
Using a Gaussian trial function, e
−λx
2
, with an adjustable parameter, make a vari-
ational estimate of the ground state energy for a particle in a Gaussian potential
well, represented by the Hamiltonian
H =
p
2
2m
−V
0
e
−αx
2
(V
0
> 0, α > 0).
For notational simplicity, I like to put β/2 = λ. Then
Ψ(x) = Ce
−βx
2
/2
and the normalization constant is determined by
1 = C
2


−∞
e
−βx
2
dx ⇒ C =

β
π

1/4
.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 9
The kinetic energy operator operating on this state yields
TΨ =
p
2
2m
Ψ(x) = −

2
2m

∂x
¸

∂x
Ψ(x)

= −

β
π

1/4

2
2m

∂x

−βxe
−βx
2
/2

= −

β
π

1/4

2
2m

−β +β
2
x
2

e
−βx
2
/2
and its expectation value is
T =

β
π

1/2

2
2m
¸
β

π
β

β
2
2

π
β
3

=

2
β
4m
. (10)
The expectation value of the potential energy is
V = −V
0


−∞
Ψ
2
(x)e
−αx
2
dx
= −V
0

β
π


−∞
e
−βx
2
e
−αx
2
dx
= −V
0

β
π

π
(α +β)
= −V
0

β
(α +β)
. (11)
Combining (10) and (11),
exptwoΨ|H|Ψ = Ψ| T |Ψ +Ψ| V |Ψ =

2
β
2m
−V
0

β
(α +β)
. (12)
To minimize with respect to β we equate the first β derivative of this to zero:
0 =

2
2m

V
0
2
¸
1

β(α +β)


β

(α +β)
3
¸
=

2
2m

V
0
2
¸
α
2
β(α +β)
3

1/2
= β(α +β)
3

mV
0
α

2

2
= β
4
+ 3β
3
α + 3β
2
α
2
+βα
3

mV
0
α

2

2
= x
4
+ 3x
3
+ 3x
2
+x −

mV
0

2
α

2
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 10
where I put x = β/α. In theory we could write down an explicit expression for
the roots of this quartic in terms of mV
0
/
2
α, and then insert said expression
into (12) to obtain the lowest energy attainable with this form of trial wave
function. In practice, however, this would be a mess, and I can’t see any way
to proceed other than numerically. Am I missing some kind of trick here?
Problem 8.5
Show that as inadequate a variational trial function as
Ψ(x) =

C

1 −
|x|
a

|x| ≤ a
0 |x| > a
yields, for the optimum value of a, an upper limit to the ground state energy of the
linear harmonic oscillator, which lies within less than 10 percent of the exact value.
The first task is to evaluate the normalization constant C.
1 = C
2

a
−a
Ψ(x)
2
dx
= 2C
2

a
0

1 −
x
a

2
dx
= 2C
2

a
0

1 −2
x
a
+
x
2
a
2

= 2C
2

a −a +
a
3

so
C =

3
2a
.
The harmonic oscillator hamiltonian is
E = T +V =
p
2
2m
+

2
x
2
2
.
(13)
exptwoΨTΨ = −

2
2m

a
−a
Ψ(x)

2
∂x
2
Ψ(x) dx (14)
Integrating by parts,
= −

2
2m

Ψ(x)

∂x
Ψ(x)

a
−a

a
−a
¸

∂x
Ψ(x)

2
dx
¸
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 11
The first term vanishes...
=

2
2m

3
2a

a
−a
1
a
2
dx
=
3
2
2ma
2
(15)
(16)
exptwoΨV Ψ =

2
2

a
−a
x
2
Ψ(x)
2
dx
= mω
2

a
0
x
2
Ψ(x)
2
dx
= mω
2

3
2a

a
0

x
2

2x
3
a
+
x
4
a
2

dx
= mω
2

3
2a

x
3
3

x
4
2a
+
x
5
5a
2

a
0
=

2
a
2
20
(17)
exptwoΨ|H|Ψ = Ψ| T |Ψ +Ψ| V |Ψ =
3
2
2ma
2
+

2
a
2
20
. (18)
To minimize with respect to a we set the a derivative of this to zero:
0 = −
3
2
ma
3
+

2
a
10
or
a
4
=
30
2
m
2
ω
2
a
2
=

30


.
Inserting into (18),
exptwoΨHΨ =
3

30
ω ≈ 0.547 · ω.
Of course the actual ground state energy is 0.5 · ω, so the fractional error is
0.047/0.5 < 10%.
Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 12
Problem 8.6
A particle of mass m moves in a potential V (r). The n −th discrete energy eigen-
function of this system, Ψ
n
(r), corresponds to the energy eigenvalue E
n
. Apply the
variational principle by using as a trial function,
Ψ
t
(r) = Ψ
n
(λr),
where λ is a variational (scaling) parameter, and derive the virial theorem for sta-
tionary states.

(I have dropped the x subscripts, and I write k0 instead of k). To proceed we need to complete the square in the exponent: x2 + i(k0 − k)x 4(∆x)2 x2 − i(k0 − k)x − (k0 − k)2 (∆x)2 + (k0 − k)2 (∆x)2 4(∆x)2
2

= − = −

x − i(k0 − k)∆x − (k0 − k)2 (∆x)2 2(∆x) 1 2 x − 2i(k0 − k)(∆x)2 − (k0 − k)2 (∆x)2 = − 4(∆x)2

(2)

Now we plug (??) into (??) to find:

Φ(k) = (2π)−1/2 C exp[−(k0 −k)2 (∆x)2 ]

−∞

exp −

1 [x − 2i(k0 − k)(∆x)2 ]2 dx 4(∆x)2

In the integral we can make the shift x → x − 2i(k0 − k)(∆x)2 and use the ∞ standard formula −∞ exp(ax2 )dx = (π/a)1/2 . The result is Φ(k) = √ 2C∆x exp −(k0 − k)2 (∆x)2

To put this into direct correspondence with the form of the wave packet in configuration space, we can write Φ(k) = √ 2C∆x exp − (k0 − k)2 4(∆k)2

where ∆k = 1/(2∆x). This is the minimum possible k width attainable for a wave packet with x width ∆x, which is why the Gaussian wave packet is sometimes referred to as a minimum uncertainty wave packet. The next step is to compute Ψ(x, t) for t > 0. Since we are talking about a free particle, we know that the momentum eigenfunctions are also energy eigenfunctions, which makes their time evolution particularly simple to write down. In the above work we have expressed the initial wave packet Ψ(x, 0) as a linear combination of momentum eigenfunctions, i.e. as a sum of terms exp(ikx), with the kth term weighted in the sum by the factor Φ(k). The wave packet at a later time t > 0 will be given by the same linear combination, but now with the kth term multiplied by a phase factor exp[−iω(k)t] describing its time evolution. In symbols we have

Ψ(x, t) =
−∞

Φ(k)ei[kx−ω(k)t] dk.

For a free particle the frequency and wave number are connected through ω(k) = 2 hk 2 ¯ . 2m

Using our earlier expression for Φ(k), we find √ 2C∆x
∞ −∞

Ψ(x, t) =

exp −(k0 − k)2 (∆x)2 + ikx − i

hk 2 ¯ t dk. 2m

(3)

Again we complete the square in the exponent: −(k0 − k)2 (∆x)2 + ikx − i hk 2 ¯ i¯ h 2 t = − [(∆x)2 + t]k 2 − [2k0 (∆x)2 + ix]k + k0 (∆x)2 2m 2m β β2 β2 k+ 4 − 4 2 α 4α 4α 2 β β = −α2 [k − 2 ]2 + 2 − γ 2α 4α = −α2 k 2 − where we have defined some shorthand: α2 = (∆x)2 + i¯ h t 2m β = 2k0 (∆x)2 + ix
2 γ = k0 (∆x)2 .

= − α2 k 2 − βk + γ

−γ

Using this in (??) we find: Ψ(x, t) = √ 2C∆x exp β2 −γ 4α2
∞ −∞

exp −α2 (k −

β 2 ) dk. 2α2

The integral evaluates to π 1/2 /α. We have √ √ 1 α β2 −γ 4α2
1/2

Ψ(x, t) = =

2πC∆x

exp

(∆x)2 2πC i¯ h (∆x)2 + 2m t

e−k0 (∆x) exp

2

2

(ix + 2k0 (∆x)2 )2 i¯ h 4[(∆x)2 + 2m t]

This is pretty ugly, but it does display the relevant features. The important point is that term i¯ t/2m adds to the initial uncertainty (∆x)2 , so that the h wave packet spreads out with time. In the figure, I’ve plotted this function for a few values of t, with the following parameters: m=940 Mev (corresponding to a proton or neutron), ∆x=3 ˚, A k0 =0.8 ˚−1 . This value of k0 corresponds, for a neutron, to a velocity of about A 5 · 104 m/s; and note that, sure enough, the center of the wave packet travels about 5 nm in 100 fs. The time scale of the spread of this wave packet is ≈ 100 fs.

3

Gaussian wave packet example 350 t=0 s t=30 fs t=70 fs t=100 fs

300

Wavefunction (arbitrary units)

250

4

200

150

100

50

0 -1e-08

-5e-09

0 Distance (meters)

5e-09

1e-08

Problem 2.2
Express the spreading Gaussian wave function Ψ(x, t) obtained in Problem 1 in the form Ψ(x, t) = exp[iS(x, t)/¯ ]. Identify the h function S(x, t) and show that it satisfies the quantum mechanical Hamilton-Jacobi equation. In the last problem we found ∆x β2 exp −γ α 4α2 √ β2 ∆x + 2 −γ 2πC = exp ln α 4α 2πC √

Ψ(x, t)

=

(1)

where we’ve again used the shorthand we defined earlier: α2 = (∆x)2 + h i¯ t 2m β = 2k0 (∆x)2 + ix
2 γ = k0 (∆x)2 .

From (??) we can identify (neglecting an unimportant additive constant): S(x, t) = β2 h ¯ − ln α + 2 . i 4α

Things are actually easier if we define δ = α2 . Then δ = (∆x)2 + i¯ h t 2m S(x, t) = 1 ¯ β2 h − ln δ + i 2 4δ

Now computing partial derivatives: ∂S ∂t h ¯ 1 β 2 ∂δ − − 2 i 2δ 4δ ∂t β2 h2 1 ¯ + 2 2m 2δ 4δ h β ∂β ¯ i 2δ ∂x hβ ¯ 2δ i¯ h 2δ (2)

=

= − ∂S ∂x = = ∂2S ∂x2 =

(3) (4)

The quantum-mechanical Hamilton-Jacobi equation for a free particle is 1 ∂S ∂S + ∂t 2m ∂x
2

− 5

i¯ ∂ 2 S h =0 2m ∂x2

− Problem 2. One could well imagine a situation in which the overlap integral would not increase with time.3 Consider a wave function that initially is the superposition of two well-separated narrow wave packets: Ψ1 (x. the overlap integral would be tiny. as the wave packets overlap? Justify your answer.4 A high resolution neutron interferometer narrows the energy spread of thermal neutrons of 20 meV kinetic energy to a wavelength dispersion level of ∆λ/λ= 10−9 . Problem 2. Will |γ(t)| increase in time. since the wave packets only have appreciable value within a few angstroms of their centers. even if the neutrons are initially moving toward each other. It seems to me that the answer to this problem depends entirely on the specifics of the particular problem. and (??) into this equation. As time evolves. the neutron wave packets plotted in the figure from problem 2. Over what length of time will the wave packets spread appreciably? 6 . 20 angstroms apart. for example. Consider. On the other hand. (??). 0) chosen so that the absolute value of the overlap integral +∞ γ(0) = −∞ Ψ∗ (x)Ψ2 (x)dx 1 is very small. then they would certainly overlap a little before collapsing entirely.1 If one of those wave packets were centered in Chile and another in China. if the two neutron wave packets were each centered. Furthermore. the equation is satisfied. their wave packets spread out on a time scale of ≈ 100 fs. we find h2 ¯ h2 β 2 ¯ h2 β 2 ¯ h2 ¯ − =0 + + 2 2 4mδ 8mδ 8mδ 4mδ so. say.Inserting (??). long before their centers ever come close to each other. 0) + Ψ2 (x. sure enough. Estimate the length of the wave packets in the direction of motion. the wave packets move and spread.

In this case we start to get appreciable spreading when h ¯ t ≈ (∆x)2 2m t ≈ 2m(∆x)2 /¯ h 2 · 9. This implies a position uncertainty of ∆x ≈ = h ¯ ∆p 6. To estimate the time scale of spreading of the wave packets.1 · 10−6 ev / c = 2π¯ h λ −2π¯ h dλ λ2 dλ = 10−9 λ ≈ c · 10−10 s ≈ 30 cm. we can imagine that they are Gaussian packets.3 m)2 ≈ c2 · 6. what does this tell us about the momentum dispersion level? p = dp = so dp p so the momentum uncertainty is ∆p = p0 · 10−9 = 6. p0 = [ 2mE ]1/2 ≈ [ 2 · (940Mev · c−2 ) · (20mev) ]1/2 = 6. This is HUGE! So the point is. we have only the most rough indication of where in the room they might be. 7 or . if we know with this precision how quickly our thermal neutrons are moving.4 · 108 ev · (0.1 · 10−6 ev.6 · 10−16 ev · s ≈ 32 ks ≈ 10 hours.First let’s compute the average momentum of the neutrons.6 · 10−16 ev · s 6.1 kev / c We’re given the fractional wavelength dispersion level.

I found this to be a pretty cool problem! First of all. Third Edition Homer Reid March 8. it suffices to show that its divergence has no cross terms. and to show this it suffices (by probability conservation) to show that dρ/dt has no cross terms. Quantum Mechanics.1 If the state Ψ(r) is a superposition. show that the probability current density can be expressed without an interference term involving Ψ1 and Ψ2 . 1999 Chapter 3 Problem 3. To show that J contains no cross terms.Solutions to Problems in Merzbacher. We have ρ = Ψ∗ Ψ = [c∗ Ψ∗ + c∗ Ψ∗ ] · [c1 Ψ1 + c2 Ψ2 ] 1 1 2 2 = |c1 ||Ψ1 | + |c2 ||Ψ2 | + c1 c∗ Ψ1 Ψ∗ + c∗ c2 Ψ∗ Ψ2 2 2 1 1 (1) 1 . we have the probability conservation equation: d ρ=− dt · J. Ψ(r) = c1 Ψ1 (r) + c2 Ψ2 (r) where Ψ1 (r) and Ψ2 (r) are related to one another by time reversal.

Problem 3.”) Then w(t) = w(0) + t We have dw dt = = d2 w dt2 = d 2 x2 − x dt d d x2 − 2 x x dt dt d2 d x2 − 2 x 2 dt dt dw dt + t=0 1 2 d2 w t 2 dt2 t=0 +··· (2) (3) 2 −2 x d2 x dt2 (4) We need to compute the time derivatives of x and x2 . (The w t reminds me of “width.44) repeatedly. For a free particle. H] i¯ h 1 xp2 − p2 x 2im¯ h 1 xp2 − p(xp − i¯ ) h 2im¯ h 1 xp2 − pxp + i¯ p h 2im¯ h 2 = = = = . The relevant equation is d 1 F = F H − HF + dt i¯ h ∂F ∂t for any operator F . calculate the variance at time 2 t.2 t 0 2 1 xpx + px x m 2 0− x 0 px t+ (∆px )2 2 t m2 I find it easiest to use a slightly different notation: w(t) ≡ (∆x)2 . Show that (∆x)2 = (∆x)2 + t 0 and (∆px )2 = (∆px )2 = (∆px ). We can use this to h calculate the time derivatives: d x dt 1 [x. and the all-important commutation relation is px = xp − i¯ .2 For a free particle in one dimension. (∆x)2 ≡ (x − x t )2 t = x2 t − x t without explicit use of the t wave function by applying (3. the Hamiltonian is H = p2 /2m.

it’s time to 3 . H] = 0 i¯ m2 h (5) (6) (7) (8) (9) Now that we’ve computed all time derivatives of x and x2 .= = = d2 x dt2 d x2 dt = = = = = = = = = = d2 x2 dt2 = = = = = = = = d3 x2 dt3 = 1 xp2 − (xp − i¯ )p + i¯ p h h 2im¯ h 1 2i¯ p h 2im¯ h p m 1 d p =0 m dt 1 [x2 . H] i¯ h 1 x2 p 2 − p 2 x2 2im¯ h 1 x2 p2 − p(xp − i¯ )x h 2im¯ h 1 x2 p2 − pxpx + i¯ px h 2im¯ h 1 x2 p2 − (xp − i¯ )2 + i¯ (xp − i¯ ) h h h 2im¯ h 1 x2 p2 − xpxp + 2i¯ xp + h2 + h2 + i¯ xp h ¯ ¯ h 2im¯ h 1 x2 p2 − x(xp − i¯ )p + 3i¯ xp + 2¯ 2 h h h 2im¯ h 1 2¯ 2 + 4i¯ xp h h 2im¯ h i¯ h 2 − + xp m m 2 d xp m dt 2 [xp. H] i¯ m h 1 − xp3 − p2 xp i¯ m2 h 1 − xp3 − p(xp − i¯ )p h i¯ m2 h 1 − xp3 − pxp2 + i¯ p2 h i¯ m2 h 1 − xp3 − (xp − i¯ )p2 + i¯ p2 h h i¯ m2 h 1 2i¯ p2 h i¯ m2 h 2 p2 m2 2 [p2 .

dw dt d d x x2 − 2 x dt dt i¯ h 2 2 − + xp − x p m m m i¯ h 2 2 − + xp − x p m 2 m 2 px − xp 2 + xp − x p m 2 m 2 2 px + xp − x p m 2 m d2 d2 d x x x2 − 2 −2 x dt2 dt dt2 2 2 2 p2 − 2 p 2 = 2 (∆p)2 m2 m m 2 = = = = = (10) d2 w dt2 = = (11) Finally. 4 .plug them into (3) and (4) to compute the time derivatives of w. which both commute with H. we plug these into the original equation (2) to find w(t) = w(0) + 2 1 px + xp − x p m 2 t+ (∆p)2 2 t. the constancy of (∆p)2 . is trivial. since (∆p)2 contains expectation values of p and p2 . m2 The other portion of this problem.

x t = x 0 cos ωt + mω (b) Derive a second-order differential equation of motion for the expectation value T − V t by repeated application of (3. (d) Work out the corresponding formula for the variance (∆p)2 . Integrate this equation and.Problem 3. as p0 sin ωt. and show that it oscillates. Then d e(t) = dt = = = = = d2 e(t) = dt2 1 xH − Hx i¯ h 1 xp2 − p2 x 2i¯ m h 1 xp2 − p(xp − i¯ ) h 2i¯ m h 1 xp2 − (xp − i¯ )p + i¯ p h h 2i¯ m h 1 2i¯ p h 2i¯ m h p . m d p dt m 5 .44) and use of the virial theorem. calculate x2 t . (c) Show that (∆x)2 ≡ x2 t − x t 2 t = (∆x)2 cos2 ωt + 0 + (∆p)2 0 sin2 ωt m2 ω 2 sin 2ωt 1 xp + px 0 − x 0 p 0 2 mω Verify that this reduces to the result of Problem 2 in the limit ω → 0. similarly to the classical oscillator. remembering conservation of energy. 2m 2 (a) Derive the equation of motion for the expectation value x t . t (a) Again I like to use slightly different notation: e(t) = x t .3 Consider a linear harmonic oscillator with Hamiltonian H =T +V = p2 1 + mω 2 x2 .

h dt 2 = −2ω xp + ω 2 xp − px = −ω 2 xp + px Next. The coefficients are determined by the boundary conditions: e(0) = x 0 p0 e (0) = m (b) Let’s define v(t) = T − V t . = 2i¯ h We already worked out this commutator in Problem 2: d v(t) dt = p2 x2 − x2 p2 = − 4i¯ xp + 2¯ 2 h h so d v(t) = −2ω 2 xp + i¯ ω 2 . d2 e(t) = −ω 2 e(t) dt2 with general solution e(t) = A cos ωt + B sin ωt.= = = = = = So we have 1 i¯ m h ω2 2i¯ h ω2 2i¯ h ω2 2i¯ h ω2 2i¯ h −ω 2 pH − Hp px2 − x2 p (xp − i¯ )x − x2 p h x(xp − i¯ ) − i¯ x − x2 p h h −2i¯ x h x . mω (12) (13) . Then 1 (T − V )H − H(T − V ) i¯ h 1 = (T − V )(T + V ) − (T + V )(T − V ) i¯ h 2 = TV − V T i¯ h 2 ω p 2 x2 − x 2 p 2 . d2 2ω 2 v(t) = − xpH − Hxp dt2 i¯ h 2ω 2 1 mω 2 = − xp3 − p2 xp + xpx2 − x3 p i¯ 2m h 2 6 → → A= x 0 p0 B= .

Evaluating at t = 0 gives A= T 0 p2 mω 2 2 − x m 2 (14) − V 0 . we can use (12) evaluated at t = 0 to determine B: −ω 2 xp + px so B=− 0 + i¯ ω 2 = 2ωB h ω xp + px 0 .The bracketed expressions are xp3 − p2 xp = = = xpx2 − x3 p = = = xp3 − p(xp − i¯ )p h 2i¯ p2 h h h xp3 − (xp − i¯ )p2 + i¯ p2 x(xp − i¯ )x − x3 p h −2i¯ x2 h x2 (xp − i¯ ) − i¯ x2 − x3 p h h and plugging these back into (13) gives d2 v(t) = = −4ω 2 dt2 = −4ω 2 v(t) with solution v(t) = A cos 2ωt + B sin 2ωt. Also. mω 2 t Since H does not depend explicitly on time. mω (15) . 2 The next task is to compute x2 t : x2 t = = = 2 V t mω 2 1 H − (T − V ) mω 2 1 [ H t − v(t)] . For v(t) we can use (14): x2 t = = = 1 mω 2 1 mω 2 ω xp + px 0 sin 2ωt 2 ω xp + px 0 2 T 0 sin2 ωt + 2 V 0 cos2 ωt + sin 2ωt 2 T 0 + V 0 −[ T 0 − V 0 ] cos 2ωt + p2 0 sin2 ωt + x2 m2 ω 2 0 cos2 ωt + 7 1 xp + px 2 0 sin 2ωt . H is constant in time.

and (sin 2ωt/ω) → 2. as needed to ensure matchup with the result of Problem 2. Problem 3. The first one is trivial: δ(r − r0 ) = For the second one. Subtracting from (15) gives (∆x)2 = x2 − x t 2 = + + x2 1 0 − x 2 0 cos2 ωt 0 m2 ω 2 p2 − p 0 2 0 1 xp + px 2 − x 0 p 0 sin 2ωt 0 = (∆x)2 cos2 ωt + 0 1 (∆p)2 0 sin2 ωt + xp + px m2 ω 2 2 − x 0 p 0 sin 2ωt . cos2 ωt → 1. 8 . 1 i¯ h pδ(r − r0 ) + δ(r − r0 )p = − 2m 2m Ψ∗ (r)δ(r − r0 )Ψ(r)dr = Ψ∗ (r0 )Ψ(r0 ) = ρ(r0 ). [Ψ∗ δ(r − r0 )Ψ + Ψ∗ δ(r − r0 ) Ψ] dr The gradient operator in the first term operates on everything to its right: =− i¯ h 2m [Ψ∗ Ψ δ(r − r0 ) + 2δ(r − r0 )Ψ∗ Ψ] dr. 2m Derive expressions for these densities in the momentum representation. mω As ω → 0.(c) Earlier we found that x x t 2 t = = p0 sin ωt mω 2 p x 2 cos2 ωt + 2 02 sin2 ωt + x 0 m ω x 0 cos ωt + 0 p 0 sin 2ωt. (sin2 ωt/ω 2 ) → 1.4 Prove that the probability density and the probability current density at position r0 can be expressed in terms of the operators r and p as expectation values of the operators ρ(r0 ) → δ(r − r0 ) j(r0 ) → 1 [pδ(r − r0 ) + δ(r − r0 )p] .

p ) = 1 r exp(−ip ·x /¯ )Ψ∗ r − h 3 (2π¯ ) h 2 Ψ r + r 2 dr . (a) 9 . Problem 3. (b) Prove that W (r . the Wigner distribution function is defined as W (r . defined over the six-dimensional “phase space” (r . p ). p )dr dp = 1. p )dr dp . (c) Show that the Wigner distribution function is normalized as W (r . p )dp = |Ψ(r )|2 and that the expectation value of a function of the operator r in a normalized state is f (r) = f (r )W (r .Here we can use the identity = − f (x)δ (x − a)dx = −f (a) : i¯ h |− (Ψ∗ Ψ) + 2Ψ∗ Ψ|r=r0 2m i¯ h = |Ψ Ψ∗ − Ψ∗ Ψ|r=r0 2m = j(r0 ). (d) Show that the probability density ρ(r0 ) at position r0 is obtained from the Wigner distribution function with ρ(r0 ) → f (r) = δ(r − r0 ). (a) Show that W (r . p ) is a real-valued function.5 For a system described by the wave function Ψ(r ).

h x 2 The nth eigenfunction is Ψ(x) = 1 n n! 2 1/2 1 2 1 p + mω 2 x2 2m x 2 (1) mω hπ ¯ 1/4 exp(− mω 2 x )Hn ( 2¯ h mω x). Third Edition Homer Reid June 24. 2000 Chapter 5 Problem 5. we have H= so p2 = 2mH − m2 ω 2 x2 x and 1 < Ψn |p2 |Ψk >= 2m¯ ω(n + )δnk − m2 ω 2 < Ψn |x2 |Ψk > . Can the same result be obtained directly by matrix algebra from a knowledge of the matrix elements of px ? For the harmonic oscillator.Solutions to Problems in Merzbacher. h ¯ The matrix element of x2 is then < Ψn |x2 |Ψk >= 1 n+k n!k! 2 1/2 mω hπ ¯ 1/2 ∞ x2 exp( −∞ mω 2 x )Hn ( h ¯ mω x)Hk ( h ¯ mω x) dx.1 Calculate the matrix elements of p2 with respect to the energy eigenfunctions of the x harmonic oscillator and write down the first few rows and columns of the matrix. h ¯ 1 . Quantum Mechanics.

along with any term from the last series. n! k! p! 1 1 + 2λ(s + t) + (2λ)2 (s + t)2 + · · · 2 1 1 + (2st) + (2st)2 + · · · 2 (3) There are two ways to get a λ2 term out of this. with which we obtain h < Ψn |x2 |Ψk >= 1 2n+k n!k!π 1/2 h ¯ mω ∞ u2 e−u Hn (u)Hk (u) du. from (1). otherwise. we can read off  √ . together with any term from the last series. we have = = ··· + = ··· + = ··· + √ πλ2 1 + 2(s + t)2 1 1 + (2st) + (2st)2 + · · · + · · · 2 ∞ √ 1 π 1 + λ 2 + λ4 + · · · 2 √ 2 πλ 1 + 2s2 + 2t2 + 4st √ ∞ j=0 1 (2st)j + · · · j! +··· πλ2 j=0 2 j j 2 2j+1 j j+2 2j+2 j+1 j+1 s t + sj+2 tj + s t + s t j! j! j! j! j j+1 Plugging this into (2). 1 1/2 h < Ψn+2 |p2 |Ψn > = − [(n + 2)(n + 1)] (mω¯ ) 2 1 < Ψn |x2 |Ψn > = (2n + 1)(mω¯ ). The useful formula is Inkp n. One way is to take the λ2 term from the first series and the 1 from the second series. Writing down only terms obtainable in this way. n=k−2  (n + 2)!2n π √ n!2n−1 π(1 + 2n) . The second way is to take the 1 from the first series and the λ2 term from the second series. 2 mω h ¯ mω Finally. −∞ 2 (2) The integral is what Merzbacher calls Inkp with p = 2.p √ 2 sn tk (2λ)p = π eλ +2λ(s+t)+2st . we have Comparing termwise with (3). < Ψn+2 |x2 |Ψn > = < Ψn |x2 |Ψn > = 1 1/2 [(n + 2)(n + 1)] 2 h ¯ 1 (2n + 1) . h 2 .k.Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 2 The obvious substitution is u = (mω/¯ )x. n = k Ink2 =  0 .

2 Calculate the expectation values of the potential and kinetic energies in any stationary state of the harmonic oscillator. but it’s still weird. On the other hand. Problem 5. Compare with the results of the virial theorem. Problem 5. In this case it is less absurd since there’s no classical interpretation of the offdiagonal matrix elements of an operator. It would be absurd for the expectation value (i. so p2 must have a negative matrix element to cancel out the positive matrix element of x2 . x d V (x) . 1 n! 2n mω hπ ¯ 1/2 ∞ Ψ n x4 Ψ n = x4 exp(− −∞ mω 2 2 x )Hn ( h ¯ mω x) dx h ¯ .3 Calculate the expectation value of x4 for the nth energy eigenstate of the harmonic oscillator.e.Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 3 I find it kind of confusing that the matrix element for p2 comes out negative in the first case. and H is just a sum of x2 and p2 terms. The potential energy operator is U = mω 2 x2 /2. dx d V (x) = mω 2 x. The kinetic energy expectation value must of course make up the difference. in another sense it seems inescapable that p2 should have a negative off-diagonal matrix element here.. but x2 has a nonvanishing matrix element. so we have T = U . the virial theorem is supposed to be saying U = 2 T = In this case. so 1 hω ¯ 1 mω 2 x2 = (n + ) 2 2 2 which is just half the energy expectation value. We found the expectation values of x2 in the last problem. diagonal matrix element) of the square of an observable operator to come out negative. because the off-diagonal matrix elements of H must vanish in the energy eigenfunction basis. dx 1 mω 2 x2 2 so the virial theorem says that T = = U in accord with what we concluded earlier. However.

The classical amplitude is A = (2E)/(mω 2 ). √ 1 3 Inn4 = 2n n! π( + n + n2 ). Equating powers in (5). compute the probability that the coordinate of a linear harmonic oscillator in its ground state has a value greater than the amplitude of the classical oscillator of the same energy. I further limited it to terms that also contain the same number of powers of s as t.k. n! k! p! (5) ∞ = = √ √ 1 π 1 + λ 2 + λ4 + · · · 2 1 π 1 + λ 2 + λ4 + · · · 2 √ √ √ ∞ 1 1 1 + · · · + (2λ)2 (s + t)2 + · · · + (2λ)4 (s + t)4 + · · · 2 4! ∞ j=0 (2st)j j! 1 + · · · + 4λ2 st + · · · + 4λ4 (st)2 + · · · j−1 j=0 (2st) j! j = ··· + = ··· + = ··· + π j=0 ∞ (λ4 )(st)j (λ4 )(st)j j=0 ∞ 2 2j j! 2j j! j! +4 2 2 +4 (j − 1)! (j − 2)! j−1 j−2 +··· π π j=0 1 + 2j + j(j − 1) 2 1 + j + j2 2 (λ4 )(st)j In the first line. 2 Problem 5. In the second line. The probability of finding the particle with coordinate greater than this is −A ∞ P (|x| > A) = −∞ Ψ2 (x) dx + n A Ψ2 (x) dx n . 1. but this time we’ll need to write out the expansion a little further than before. Inkp n.Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 2 4 = 1 √ n! 2n π h ¯ mω ∞ 2 u4 e−u Hn (u) du −∞ 2 (4) For the integral we want to use (3) again. and 2. 2 2 so (4) is Ψ n x4 Ψ n = 3 2 h ¯ mω 2 1 ( + n + n2 ). I only wrote out terms that can be combined to give a factor of λ4 .4 For the energy eigenstates with n=0.p √ 2 sn tk (2λ)p = π eλ +2λ(s+t)+2st .

5 Show that if an ensemble of linear harmonic oscillators is in thermal equilibrium. h Nn = N0 e−n¯ ω/kT . the ratio of the number of oscillators in the n th state to the number of oscillators in the nth state is Nn h = e−(n −n)¯ ω/kT . Plot the width of the distribution as a function of temperature.31 2 Problem 5. In going from the second to last line n to the last line. for any n.] Suppose we denote the number of oscillators in the nth energy state by Nn .Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 ∞ 5 = 2 A Ψ2 (x) dx n mω x) dx h ¯ = = = mω 1/2 ∞ 2 mω 2 2 exp(− x )Hn ( n n! 2 hπ ¯ h ¯ A ∞ 2 2 2 √ √ e−u Hn (u) du n! 2n π 2E/¯ ω h n! 2 √ n−1 1 ∞ π √ 2n+1 2 e−u Hn (u) du 2 In going from the first line to the second we invoked the fact that Ψn has either even or odd parity. so Ψ2 has even parity. the probability per unit length of finding a particle with displacement x is a Gaussian distribution. ¯ In particular. If the ensemble is in thermal equilibrium. [Hint: Equation (5. Nn In particular. we noted that the energy of the nth eigenstate is hω(n + 1/2). governed by the Boltzmann distribution. 1 √ π 1 √ 2π ∞ 2 Pn=0 (|x| > A) = = = = e−u du 1 ∞ e 0 −p2 /2 √ 2 dp − e−p 0 2 /2 dp √ π √ 1 √ − 2π · erf( 2) 2 2π √ 1 − erf( 2) ≈ 0. . Check the results in the classical and low-temperature limits.43) may be used.

Homer Reid’s Solutions to Merzbacher Problems: Chapter 5 6 The probability of finding a particle between x and dx is ∞ P (x)dx = n=0 Cn |Ψn (x)|2 dx mω hπ ¯ 1/2 = C0 exp(− h e−n¯ ω/kT 2 mω 2 x ) Hn ( h ¯ n! 2n n=0 ∞ mω x)dx h ¯ This can be summed using the Mehler formula with t = exp(−¯ ω/kT ) : h P (x) = C0 = C0 mω hπ ¯ mω hπ ¯ 1/2 exp(− √ mω 2 x ) h ¯ 1/2 1 1 − t2 h ¯ 2mω 1 2t exp 2 1+t 1−t 1 − t mω 2 exp − x 1+t h ¯ √ mω 2 x h ¯ This is a Gaussian distribution with variance σ2 = = = 1+t 1−t h 1 + e−¯ ω/kT h ¯ h 2mω 1 − e−¯ ω/kT hω ¯ h ¯ coth 2mω 2kT .

2000 Chapter 6 Problem 6. Third Edition Homer Reid June 24. Merzbacher treats this problem for the case where the particle’s energy is less than the potential barrier.1 Obtain the transmission coefficient for a rectangular potential barrier of width 2a if the energy exceeds the height V0 of the barrier.Solutions to Problems in Merzbacher. In the text. To do this we note that κ becomes imaginary in this case. He obtains the result M11 = where κ= and 2m(V0 − E) 2 cosh 2κa + i sinh 2κa e2ika 2 (1) κ k − . Plot the transmission coefficient as a function E/V0 (up to E/V0 = 3). choosing (2ma2 V0 )1/2 = (3π/2) . (2) k κ We can re-use the result (1) for the case where the energy is greater than the potential barrier. Quantum Mechanics. and we write 2m(E − V0 ) κ = iβ = i 2 = so that (2) becomes = iβ k − =i k iβ 1 k β + k β ≡ iλ .

We have βa = = λ2 − 1 sin2 βa 4 1 β4 + k4 − 4β 2 k 2 2 (β 2 − k 2 )2 4β 2 k 2 V02 4E(E − V0 ) 1 4γ(γ − 1) 1/2 1/2 sin2 βa 1/2 sin2 βa 1/2 sin2 βa 1/2 sin2 βa 1/2 4γ(γ − 1) + sin2 βa 4γ(γ − 1) 2m (E − V0 ) h2 1/2 1/2 a 2mV0 a2 (γ − 1)1/2 h2 3π (γ − 1)1/2 = 2 so the transmission coefficient is T = 1 4γ(γ − 1) = 2 |M11 | 4γ(γ − 1) + sin2 3π (γ − 1)1/2 2 This is plotted in Figure 1.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 2 Plugging into (1) and noting that cosh ix = cos x. 2 = 1+ = 1+ = 1+ = 1+ = 1+ = where γ = E/V0 . . sinh ix = i sin x we have M11 = and |M11 | = cos2 2βa + λ2 sin2 βa 4 1/2 cos 2βa − iλ sin 2βa e2ika .

5 1 1.2 0.5 0.5 4 Figure 1: Transmission coefficient versus E/V0 for Problem 6.7 Transmission Coefficient 0.5 2 E/V0 2.4 0.6 0.9 0.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 3 1 0.3 0.5 3 3.1.8 0.1 0 0 0. .

2 Consider a potential V = 0 for x > a.  Ψ(x) = Aeik1 x + Be−ik1 x . Next applying continutity of Ψ and its derivative at x = a. Hence γ is undetermined as yet.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 4 Problem 6. we could apply the normalization condition on Ψ to find γ if we wanted to. that the derivative of Ψ also be continuous. Show that for x > a the positive energy solutions of the Schr¨dinger o equation have the form ei(kx+2δ) − e−ikx Calculate the scattering coefficient |1 − e2iδ |2 and show that it exhibits maxima (resonances) at certain discrete energies if the potential is sufficiently deep and broad.   ik2 x Ce + De−ik2 x . Eventually. V = −V0 for a ≥ x ≥ 0. we obtain γ sin k1 a = Ceik2 a + De−ik 2 a 2 k1 γ cos k1 a = ik2 [Ceik2 a − De−ik a ] Combining these yields 1 −ik2 a k1 γe cos k1 a + i sin k1 a 2i k2 1 k1 D = − γe+ik2 a cos k1 a − i sin k1 a 2i ik2 C= It’s now convenient to write k1 cos k1 a + i sin k1 a = αeiδ k2 where α2 = k1 k2 2 (3) (4) (5) cos2 k1 a + sin2 k1 a (6) . and V = +∞ for x < 0. so Ψ(x) = γ sin k1 x for 0 ≤ x ≤ a. k1 = 2m(E + V0 ) 2 x ≤0 0 ≤x ≤ a≤ . does not hold at x = 0 because the potential is infinite there. The other standard requirement. we see we must take A = −B. We have   0. a x with k2 = 2mE 2 Applying the requirement that Ψ be continuous at x = 0.

2 I have plotted this for β = 25. 2i Using (5) and (6). Then we can rewrite (3) and (4) as γα −ik2 a iδ e e 2i γα D = − e+ik2 a e−iδ 2i C= Then the expression for the wavefunction to the left of x = a becomes Ψ(x) = Ceik2 x + De−ik2 x (x > a) γα ik2 (x−a) iδ −ik2 (x−a) −iδ e e −e e = 2i γα −iδ ik2 (x−a) 2iδ e = e e − e−ik2 (x−a) . . the scattering coefficient is k1 k2 2 k1 cos2 k1 a + 2i k2 cos k1 a sin k1 a − sin2 k1 a k1 k2 2 2 |1 − e2iδ |2 = 1 − cos2 k1 a + sin2 k1 a 2 = k1 2 sin k1 a sin k1 a − i k2 cos k1 a k1 k2 2 cos2 k1 a + sin2 k1 a (7) = k1 k2 4 sin2 k1 a 2 cos2 k1 a + sin2 k1 a We have k1 k2 2 = E + V0 = E 2 1+ 1 λ = β(λ + 1)1/2 k1 a = 2ma2 (E + V0 ) where λ = E/V0 and β = (2ma2 V0 / 2 )1/2 in Merzbacher’s notation. Then the scattering coefficient (7) is scattering coefficient = 1 2 λ) (1 + 4 sin2 [β(λ + 1)1/2 ] cos2 [β(λ + 1)1/2 ] + sin2 [β(λ + 1)1/2 ] In Figure 6. while δ represents phase information.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 5 and δ = tan−1 k2 tan k1 a k1 so that α contains magnitude information.

5 E/V0 2 2.5 3 Scattering coefficient 2.5 2 1.5 0 0 0.5 1 1.5 3 Figure 2: Scattering coefficient versus E/V0 for Problem 6. .2.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 6 4 3.5 1 0.

Explain the features of the plot. obtain a simple formula for the splitting ∆E between the ground state (even parity) energy level. 2a. Matching the value of the wavefunction at x = −a gives Ae−ka = B cosh(−ka). the normal derivative-continuity condition doesn’t hold there. obtain transcendental equations for the bound-state energy eigenvalues of the system. o but with energy E < 0 since we’re looking for bound states. since the potential in this problem has mirror-reversal symmetry. so B = E = 0. we have  x ≤ −a  Aekx + Be−kx . −a ≤ x ≤ a Ψ(x) =  Eekx + F e−kx . Cekx + De−kx . . Compute and plot the energy levels in units of 2 /ma2 as a function of the dimensionless parameter mag/ 2 . Considering first the even parity solution. (9) Since the potential becomes infinite at x = −a. the wavefunction can’t blow up at infinity. If g > 0. we can divide the x axis into three regions. −a ≤ x ≤ a Ψ(x) = (8)  Ae−kx . E− . Putting k = 2mE/ 2 . B cosh(kx). Now. first of all. (10) Applying this condition to the wavefunction (8) yields kB sinh(−ka) − kAe−ka = − 2mg 2 B cosh(−ka). d2 2m 2m Ψ(x) = 2 V (x)Ψ(x) − 2 EΨ(x). the wavefunction will have definite parity. In each region. between the wells. and the excited (odd parity) energy level. the wavefunction is just the solution to the free-particle Schr¨dinger equation. 2 dx then integrate from −a − to −a + and take the limit as → 0.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 7 Problem 6. Instead.  x ≤ −a  Aekx . a ≤ x. a ≤ x. In this problem. E+ .3 A particle of mass m moves in the one-dimensional double well potential V (x) = −gδ(x − a) − gδ(x + a). This gives dΨ dx −a+ −a− =− 2mg 2 Ψ(−a). In the limit of large separation. we can write down the Schr¨dinger equao tion. Also.

.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 8 Substituting from (9). Problem 6. −a ≤ x ≤ a (11) Ψ(x) =  −Ae−kx . coth(ka). In Figure (3) I have plotted tanh(ka). B sinh(kx). Show that. This equation determines the energy eigenvalue of the evenparity state. As expected. the system (“molecule”) is stable if the particle (“electron”) is in the even parity state. On the other hand. supplemented by a repulsive interaction λg/|X| between the wells (“atoms”). for a sufficiently small value of λ. kB sinh(−ka) − kB cosh(−ka) = − or tanh(ka) = β 2mg −1= −1 2k ka 2mg 2 B cosh(−ka) with β = 2mag/ 2 . Sketch the total potential energy of the system as a function of |X|. the odd parity state looks like  x ≤ −a  Aekx . that means that the energy eigenvalue for the odd parity state is smaller in magnitude (less negative) than the even parity state. the coth curve crosses the β/(ka) − 1 curve at a lower value of ka than the tanh curve. which will be the ground state.4 Problem 3 provides a primitive model for a one-electron linear diatomic molecule with interatomic distance 2a = |X|. if the potential energy of the “molecule” is taken as E± (|X|). a ≤ x. Matching values at x = −a gives Ae−ka = B sinh(−ka) and applying condition (10) gives kB cosh(−ka) − kAe−ka = − kB cosh(ka) + kB sinh(ka) = coth(ka) = β −1 ka 2mg 2 2 B sinh(−ka) 2mg B sinh(ka) so this is the condition that determines the energy of the odd parity state. and β/(ka) − 1 for the case β = 3.

4 ka 1.5 1 0.8 2 Figure 3: Graphical determination of energy levels for Problem 6.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 9 PSfrag replacements 2 tanh(ka) coth(ka) β/(ka) − 1 1. .3 with β = 3.2 1.6 1.5 0 1 1.

(14) with β = mag/ 2 as before. C → E. Making these substitutions in (15) and (16) we obtain E= β 2ka e D ika β 2ka β F =+ D e C + 1+ ika ika 1− C− β ika (17) (18) . as before. B → D. Matching values at x = −a.5 If the potential in Problem 3 has g < 0 (double barrier). we have the derivative condition dΨ dx x=−a+ x=a− (12) with k = (13) =− 2mg 2 Ψ(−a) where g is now negative. D → F . (Note the analogy between the system and the Fabry-Perot ´talon in optics. Applying this to the wavefunction in (12).Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 10 Problem 6. we have Ae−ika + Beika = C −ika + Dika Also. but with the substitutions A → C. and a → −a. so  ikx −ikx x ≤ −a  Ae + Be  ikx −ikx Ψ(x) = Ce + De −a≤x≤a   ikx −ikx a≤x Ee + F e 2mE/ 2 . we have ik[Ce−ika − Deika − Ae−ika + Beika ] = − Combining (13) and (14) yields β 2ka e B ika β −2ka β D=− B e A+ 1− ika ika C= 1+ β ika A+ (15) (16) 2mg 2 [Ae−ika + Beika ]. applying the matching conditions to the wavefunction at x = +a will give two equations exactly like (13) and (14). calculate the transmission coefficient and show that it exhibits resonances. Now.) e Now we’re assuming that the energy E is positive.

5 0.3 0. we have E = 1+ F = 2β ka β ika 1+ 2 (e−4ika − 1) A + + β ika sin 2ka A + 1 + 2β ka β ika 1− 2 β ika sin 2ka B (e4ika − 1) B This is the M matrix.1 0 0 5 10 15 ka 20 25 30 Figure 4: Transmission coefficient in Problem 6. and the transmission coefficient is given by T = 1/|M11 |2 .Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 11 PSfrag replacements 1 0. .4 0. or 1 T = 2 2 β β + 1 (1 − cos(4ka)) 1 + 2 ka ka In Figure 4 I have plotted this for β = 15.9 0. Combining equations (15) through (18).6 T (k) 0.8 0.4 with β = 15.2 0.7 0.

Ce ik2 x + De −ik2 x . (b) Derive the elements of the matrix S. which have the same energy (buf different velocities).Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 12 Problem 6. We have Ψ(x) = with k1 = 2m 2 Aeik1 x + Be−ik1 x . which relates the amplitudes of the incident and reflected plane waves on the left of the origin (x < 0) to the amplitudes on the right (x > 0). which relates incoming and outgoing amplitudes. Matching values at x = 0 gives C +D =A+B (19) Also. (c) Show that the S matrix is unitary and that the elements of the S matrix satisfy the properties expected from the applicable symmetry considerations. k2 ik2 2 .6 A particle moves in one dimension with energy E in the field of a potential defined as the sum of a Heaviside step function and a delta function: V (x) = V0 η(x) + gδ(x) (with V0 and g > 0) The particle is assumed to have energy E > V0 . (a) Work out the matrix M . (d) Calculate the transmission coefficient for particles incident from the right and for particles incident from the left. x≤0 x≥0 E k2 = 2m 2 (E − V0 ). the delta function at the origin gives rise to a discontinuity in the derivative of the wavefunction as before: dΨ dx so ik2 (C − D) − ik1 (A − B) = or C −D = 0+ = 0− 2mg 2 Ψ(0) 2mg 2 (A + B) (20) k1 2mg (A − B) + (A + B).

which is defined by B C = S11 S21 S12 S22 A D Since we already know the M coefficients.Homer Reid’s Solutions to Merzbacher Problems: Chapter 6 13 Adding and subtracting (19) and (20). . we can read off 1 2mg 2mg 1 k1 k1 A+ B + + 1+ 1− 2 k2 ik2 2 2 k2 ik2 2 2mg 2mg 1 1 k1 k1 − − D= A 1+ B. this is tedious and long and boring and I don’t want to do it. we can calculate the elements of the S matrix from the formula S11 S21 = − M12 ∗ 11 1 = M∗ 11 M∗ 1 S12 = M ∗ 11 M S22 = + M12 ∗ 11 However. 1− 2 k2 ik2 2 2 k2 ik2 2 C= We could also write this as C D = M11 ∗ M12 M12 ∗ M11 A B Or instead of the M matrix we could use the S matrix.

In 1 . and so on. S(x) = ±kx. 2001 Chapter 7 Before starting on these problems I found it useful to review how the WKB approximation works in the first place. we will construct a series of functions S0 (x). · · · . To be specific. dx2 We postulate for Ψ the functional form k(x) ≡ 2m 2 [E − V (x)]. For a nonconstant but slowly varying potential we might imagine S (x) will be small. Quantum Mechanics. Then we compute the second derivative of Sn+1 (x) and use this as the source term for calculating Sn+2 . we compute Sn (x) and use that as the source term on the LHS of (1) to calculate Sn+1 (x). for a constant potential. (1) This equation can’t be solved directly. and so on ad infinitum. In other words. The Schr¨dinger equation is o − or d2 Ψ(x) + V (x)Ψ(x) = EΨ(x) 2m dx2 2 d2 Ψ(x) + k 2 (x)Ψ(x) = 0. so that S vanishes. but we obtain guidance from the observation that. and we may take S = 0 as the seed of a series of successive approximations to the exact solution.Solutions to Problems in Merzbacher. where S0 is the solution of (1) with 0 on the left hand side. Ψ(x) = AeiS(x)/ in which case the Schr¨dinger equation becomes o i S (x) = [S (x)]2 − 2 2 k (x). at the nth step in the approximation sequence (by which point we have computed Sn (x)). Third Edition Homer Reid April 5. S1 (x). S1 is a solution with S0 on the left hand side.

we appear to have four possible choices for S1 .Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 2 symbols. then S0 and S1 have opposite sign. the sequence of approximations terminates at 0th order with S0 being an exact solution. But let’s think a little about the ± signs in this equation. if we choose the plus sign in (5) but the minus sign in (3). But if we chose. so (3) is S1 (x) = ± k 2 (x) ± ik (x). S1 (x) = S1 (a) ± = S1 (a) ± x k (u) i dx 2 a k(u) a x i k(x) k(u)du + ln 2 k(a) a x ik (x) 2k 2 (x) or S1 ≈ − k(x) 1 − i k (x) . as we observed before. By extension. S1 . we have k (x)/k 2 (x) 1. the plus sign in that equation. if V (x) is not constant but changes little over one particle wavelength. (6) If V (x) is constant. whence our two choices are S1 = + k 2 (x) + ik (x) or S1 = − k 2 (x) − ik (x). With the two ± signs here. 2k(x) ik (x) 2k 2 (x) (7) k(u)du + where a is some point chosen such that the approximation (7) is valid in the full range a < x < x. Then S0 (x) = ± k (x). we would also expect that S1 > 0. and. . so we may expand the radicals in (6): S1 ≈ k(x) 1 + or S1 ≈ ± k(x) + Integrating. say. etc. so that S0 > 0. so S1 differs from S0 by an amount at least as large as S0 . S3 . 0 = [S0 (x)]2 − 2 2 2 2 k (x) k (x) k (x) (2) (3) (4) i S0 = [S1 (x)] − 2 2 i S1 = [S2 (x)] − ···· 2 2 Equation (2) is clearly solved by taking x S0 (x) = ± k(x) ⇒ S0 (x) = S00 ± k(x )dx −∞ (5) for any constant S00 . k(x) is constant. Indeed. but in practice it seems the approximation is always terminated at S1 . · · · has little hope of converging. We could go on to compute S2 . in which case our approximation sequence S0 . So we choose either both plus signs or both minus signs in (3). The ± sign under the radical comes from the two choices of sign in (5)..

k(x) (9) We have written it this way to illustrate that the function G(x. but (8) seems to be saying that we need only one initial condition—the value of Ψ at x = a—to find the value of Ψ at other points. according to the derivative of Ψ at x = a. To clarify this subtle point. so it’s κ(x) = −ik(x) = and Ψ(x) = C 1 ± R x κ(u)du e a . a) ≡ k(a) ±i R x k(u)du e a . you can just multiply it by G± (x. if you know what Ψ is at some point a. let’s investigate the equations leading up to (8). But this doesn’t seem quite right: Schr¨dinger’s equation o is a second-order differential equation. k(x) is imaginary. So to use (8) to obtain values for Ψ at a point x. If we want to de-emphasize this nature of the solution with the propagator we may write 1 ±i R x k(u)du Ψ(x) = C e a (10) k(x) where C = Ψ(a) useful to define k(a). but the requirement the dΨ/dx be continuous at x = a means that only one or the other will do. then there are two solutions of Schr¨dinger’s equation at x = a. Equation (8) seems to be saying that we can use either G+ or G− to get to Ψ(x) from Ψ(a). a) to find out what Ψ is at x. κ(x) (12) 2m 2 [V (x) − E] (11) . a) where (8) G± (x. we need to know both Ψ and Ψ at a nearby point x = a. one whose phase increases with increasing o x (positive derivative). Indeed. otherwise the overall wave function will have a discontinuity in its first derivative at x = a. and one whose phase decreases. in using (8) to continue Ψ from a to x we must choose the appropriate propagator—either G+ or G− . a) is kind of like a Green’s function or propagator for the wavefunction. In regions where V (x) > E. in the sense that. as should be the case for a second-order differential equation. If the approximation (7) makes sense.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 3 The wavefunction at this order of approximation is Ψ(x) = exp(iS1 (x)/ ) = eiS1 (a)/ = Ψ(a) e±i Rx a k(u)du eln k(x)/k(a) −1/2 k(a) ±i R x k(u)du e a k(x) = Ψ(a)G± (x.

In the neighborhood of x0 we may expand V (x): V (x) = E + (x − x0 )V (x0 ) + · · · Then the Schr¨dinger equation becomes o d2 2m Ψ(x) − 2 V (x0 )(x − x0 )Ψ(x) = 0. because we can’t carry the propagator across regions of invalidity. But near such a point we may expand V (x) − E in a Taylor series around the point x0 . which happens near a classical turning point of the motion—i. γ . gives us no way of determining the value of Ψ at that one starting point. one sure-fire way to get starting points in regions of validity is to identify regions of invalidity. How do we find such points? Well. So we need to identify the regions of invalidity of the WKB approximation and do a more accurate solution of the Schr¨dinger equation o there. we can’t use (8) to determine Ψ in other. Furthermore. even if we know Ψ at one point within a region of validity. knowing the value of Ψ (and its derivative) at one point within the region is equivalent to knowing it everywhere. so that V (x0 ) = E. we arrive at a Schr¨dinger equation which o we can solve exactly in the vicinity of x0 . of which there will be at least one adjacent to each region of validity. nonadjacent regions. The WKB method.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 4 If we have a region of space in which the WKB approximation is valid. a point x0 at which V (x0 ) = E.e. however. So basically what we need is a way of finding one starting value for Ψ(x) in every region of validity of the WKB approximation. and then get values of Ψ at the boundaries of the regions of invalidity—which will also count as values in the regions of validity. because we can use the propagator (9) to get from that one point to every other point within the region. suppose the point x0 is a classical turning point of the motion. 2 dx The useful substitution here is u(x) = γ(x − x0 ) so x(u) = If we define Φ(u) = Ψ(x(u)) then dΦ dΨ dx 1 = = Ψ (x(u)) du dx du γ 1 d2 Φ = 2 Ψ (x(u)) du2 γ γ≡ 2m 2 1/3 (13) (14) V (x0 ) u + x0 . The WKB approximation breaks down when k /k 2 1 ceases to hold.. To do this. which is true when k ≈ 0 but k = 0. if we keep only the first (linear in x) term in the series.

In this region. we need to consider two possible kinds of turning point. du2 The solution to this differential equation is Φ(u) = β1 Ai(u) + β2 Bi(u) so the solution to the Schr¨dinger equation (14) is o Ψ(x) = β1 Ai γ(x − x0 ) + β2 Bi γ(x − x0 ) . Case 1: V (x0 ) > 0. In this case the potential is increasing through the turning point at x0 . (17) To simplify these. which means that V (x) < E for x < x0 . Hence the region to the left of the turning point is the classically accessible region. 3 On the other hand. for points close to the turning point on the left side we have x > x0 . so for x < x0 (??) holds. . while the right of the turning point is classically forbidden.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 5 so (14) becomes γ2 or d2 Φ(u) − γ 3 (x − x0 )Φ(u) = 0 du2 d2 Φ(u) − uΦ(u) = 0. so γ(x − x0 ) > 0. γ > 0. k(x) = so |γ(x − x0 )| and x0 x0 −1/4 2m 2 [E − V (x)] ≈ 2m 2 1/2 V (x0 − x)1/2 = γ 3/2 (x0 − x)1/2 = γ k(x) 2 3/2 γ (x0 − x)3/2 3 (19) (18) k(u)du = γ 3/2 x x (x0 − x)1/2 du = 2 = |γ(x − x0 )|3/2 . and V (x) > E for x > x0 . For points close to the turning point on the left side. Since V (x0 ) > 0. For γ(x − x0 ) 1 we have the asymptotic expression −1/4 3/2 β1 − 2 |γ(x−x0 )|3/2 2 e 3 + β2 e+ 3 |γ(x−x0 )| 2 (15) Ψ(x) ≈ π −1/2 [γ(x − x0 )] and for γ(x − x0 ) (16) −1 we have −1/4 Ψ(x) ≈ π −1/2 |γ(x − x0 )| β1 cos 2 π 3/2 |γ(x − x0 )| − 3 4 π 2 3/2 − β2 sin |γ(x − x0 )| − 3 4 .

x < x0 x < x0 (23) (24) − β2 sin Ψ(x) = k(u)du − Rx R 1 κ(u)du − x κ(u)du β1 e x 0 + β 2 e x0 . κ(x) x < x0 (25) 1 2β1 cos k(x) x x0 k(u)du − x x0 π 4 π 4 . and the forbidden region to the left. so the classically accessible region is to the right of the turning point. In this case the potential is decreasing through the turning point. the solutions to the Schr¨dinger equation on either side of a classical turning point x0 at which o V (x0 ) > 0 are Ψ(x) = 1 2β1 cos k(x) x0 x k(u)du − x0 x π 4 π 4 . to apply the WKB approximation to a given potential V (x). That means that the regions of applicability of (16) and (17) are on opposite sides of the turning points as they were in the previous case. for x near x0 . and to divide space . the first step is to identify the classical turning points of the motion. κ(x) (we redefined the β constants slightly in going to this equation). and (21) and (22) in (16). γ < 0. x x0 κ(u)du = γ 3/2 x x0 (u − x0 )1/2 du = 2 3/2 γ (x − x0 )3/2 3 (21) and also |γ(x − x0 )| −1/4 = γ . Since V (x0 ) < 0. x > x0 (26) (27) − β2 sin k(u)du − So.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 6 κ(x) = 2m 2 V (x) − E ≈ 2m 2 1/2 V (x0 )(x − x0 ) = γ 3/2 (x − x0 )1/2 (20) so. κ(x) (22) Using (18) and (19) in (17). Case 2: V (x0 ) < 0. The solutions to the Schr¨dinger equation on either o side of the turning point are Ψ(x) = Ψ(x) = R Rx 1 0 − x κ(u)du β1 e x κ(u)du + β2 e x0 .

obtain solutions of the Schr¨dinger equation in each region. and then use (10) to evolve the wavefunction from those points to other points within the separate regions. We should probably quantify the meaning of “nearby” in that last sentence. we . However. consider a potential like that shown in Figure 1. within which regions the WKB approximation (7) is valid. To divide space into distinct regions in this case. the problem may be analyzed in a manner similar to that used in the consideration of one-dimensional piecewise constant potentials. and then match values and derivatives at o the region boundaries. so we must have V (x0 ) . Suppose x0 is a classical turning point of the motion. the WKB approximation cannot be used. Then. (30) If there are no points x0 ± satisfying all three conditions. Although there are no discontinuities in the potential here. and that around b be b − 2 < x < b + 2. the approximate Schr¨dinger equation (14) is only valid as long as we can o neglect the quadratic and higher-order terms in the expansion (13). the points x± must be sufficiently far away from the turning points that the approximation (7) is valid for the derivative of the phase of the wavefunction. the condition for this to be the case was k (x) k 2 (x) 1⇒ 1 2 2 2m [E − V (x ± )] V (x ± ) 3/2 1. (29) V (x0 ) V (x0 ) 2 2 Finally. with two classical turning points at x = a and x = b.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 7 up into regions bounded by turning points. Then space divides naturally into five regions: (a) x < a − In this region we are far enough to the left of the turning point that the WKB approximation is valid. we write down (23) and (24) (or (25) and (26)) at nearby points on either side of the turning point. First. and the wavefunction takes the form (10). as in Chapter 6: we divide space into a number of distinct regions. To apply all of this to the problem of bound states in a potential well. Let the narrow such region around a be a − 1 < x < a + 1. γ must be sufficiently greater than 1 to justify the approximation (16) (or sufficiently less than -1 to justify (17)). we begin by identifying narrow regions around the turning points a and b in which the linear approximation (13) is valid. In the narrow region around x = a. the condition here is 1/3 −1/3 2m 2m 1 ⇒ . we may use (25) and (26). (28) |V (x0 )| |V (x0 )| ⇒ V (x0 ) But at the same time. and we are looking for points x0 ± at which to make the “handoff” from approximations (16) and (17) to the WKB approximation These points must satisfy several conditions. for each turning point. around x = b we may use (23) and (24).

PSfrag replacements V (x) E a b .Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 8 Figure 1: A potential V (x) with two classical turning points for an energy E.

integrating from a + to x in the propagator (9). we also know it at x = a + . because of course the solution of the Schr¨dinger equation in the o narrow strip around a (to which (32) is an asymptotic approximation for x < a) is valid throughout the strip. β2 = 0. and using G+ and G− . so we may use (8) to find the wavefunction at any point within the region. But now that we know the value of Ψ at x = a − . (26) becomes 1 cos k(x) 1 e+i( k(x) Rx a x a Ψ(x) = 2A =A k(u)du − π 4 Rx a k(u)du−π/4) + e−i( k(u)du−π/4) . we achive continuity not only of the value and first derivative of Ψ but also of all higher derivatives. With β1 = A and β2 = 0.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 9 must throw out the term that grows exponentially as x → −∞. to propagate the first and second terms in . κ(x) x < (a − ). the same solution that’s valid at x = a − is valid at x = a + . so we are left with 1 − R (a− ) κ(u)du e x . respectively. Ψ(x) = Ra Ra 1 β1 e− x κ(u)du + β2 e+ x κ(u)du . With this choice of constants. x<a− . Using the expression (33) for the wavefunction at x = a + . x = (a + )− (33) (c) a + < x < b − In this region the WKB approximation (7) is valid. so (25) and (26) may be used. as must be the case since there is no discontinuity in the potential. (31) Ψ(x) = A κ(x) (b) a − < x < a + In this region we are close enough to the turning point that (13) is valid. (32) From (31) and (32) we see that continuity of both the value and first derivative of Ψ(x) at x = a − requires taking β1 = A.

which was my original goal.e. i. 2. n = 1. z ≤ 0. a+ <x <b− (34) Okay. z > 0 ∞. we obtain for the wavefunction at a point x in this region Ψ(x) = A =A = 2A = 2A 1 +i e k(x) “R (a+ ) a k(u)du+ Rx (a+ ) k(u)du−π/4 ” +e −i “R (a+ ) a k(u)du+ Rx (a+ ) −π/4 ” Rx Rx 1 e+i( a k(u)du−π/4) + e−i( a k(u)du−π/4) k(x) 1 cos k(x) 1 cos k(x) x a b a k(u)du − k(u)du − π 4 b x k(u)du − π 4 . V (x) = mgz. so I am now going to stop this exercise and proceed directly to the problems. · · · (35) comes from.1 Apply the WKB method to a particle that falls with acceleration g in a uniform gravitational field directed along the z axis and that is reflected from a perfectly elastic plane surface at z = 0. I have now carried this analysis far enough to see for myself exactly where the Bohr-Sommerfeld quantization condition b k(u)du = a n+ 1 2 π. We’ll start with the exact solution to the problem.Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 10 (33). Problem 7. the Schr¨dinger equation is o 0= d2 2m Ψ(x) + 2 [E − mgz] Ψ(x) 2 dx d2 2m2 g E = 2 Ψ(x) + − z Ψ(x) 2 dx mg d2 2m2 g = 2 Ψ(x) − [z − z0 ] Ψ(x) 2 dx (36) . For z > 0. Compare with the rigorous solutions of this problem. The requirement of perfect elastic reflection at z = 0 may be imposed by taking V (x) to jump suddenly to infinity at z = 0.

Then the Schr¨dinger equation o for z < 0 is d2 2m Ψ(z) − 2 [V0 − E] Ψ(z) = 0 2 dz with solution 2m [V0 − E]. we have β1 Ai(−γz0 ) = A γβ1 Ai (−γz0 ) = −kA Dividing. The solution to (36) is then Ψ(x) = β1 Ai γ(z − z0 ) . Since we require a solution that remains finite as z → ∞. (37) For z < 0. (38) Ψ(z) = Ae−kz . V (z) = V0 . which means the energy eigenvalues En are given by 2m2 g 2 1/3 En = xnm ⇒ En = mg mg 2 2 2 1/3 xn (39) where xn is the nth root of the equation Ai(−xn ) = 0. (z > 0). so the RHS of this goes to zero. we obtain 1 Ai(−γz0 ) 1 =− γ Ai (−γz0 ) k Now taking V0 → ∞. where eventually I’ll take V0 → ∞. d2 Φ(u) − uΦ(u) = 0 du2 with solutions Φ(u) = β1 Ai(u) + β2 Bi(u). thus the condition is that −γz0 be a zero of the Airy function. I wasn’t quite sure how to account for the infinite potential jump at z = 0. . k= 2 Matching values and derivatives of (37) and (38) at z = 0. we must take β2 = 0. so instead I supposed the potential for z < 0 to be a constant. we also have k → ∞. we find that (36) is just the Airy equation for Φ(u).Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 11 where z0 = E/mg. With the substitution u = γ(z − z0 ) γ= 2m2 g 2 1/3 and taking Φ(u) = Ψ(x(u)).

so we have n+ 1 2 z0 π= 0 k(z) dz 2m 2 0 z0 = = = = 2 3 [E − mgz]1/2 dz z0 2m2 g 2 0 [z0 − z]1/2 du z0 0 2m2 g 2 2 − (z0 − z)3/2 3 E mg 3/2 2m2 g 2 so the nth eigenvalue is given by En = mg 2 2 2 1/3 3 2 n+ 1 2 2/3 π .Homer Reid’s Solutions to Merzbacher Problems: Chapter 7 12 So that’s the exact solution. the spectrum of energy eigenvalues is determined by the condition (35). . In this case the classical turning points are at z = 0 and z = z0 . In the WKB approximation.

Solutions to Problems in Merzbacher. Third Edition Homer Reid May 13. Quantum Mechanics. 2001 Chapter 8 1 .

(c) Use a quartic trial function of the form Ψt (x) = (a2 − x2 )(αx2 + β). b≤x≤a |x| ≤ b. using normalized wave functions. (e) Show that the variational procedure produces. a kn = nπ . Interpret the corresponding stationary energy value. Ψt (x) = . 8ma2 ma2 2 2 (a) We need first to normalize the trial wavefunction. (d) Compare the results of the different variational calculations with the exact ground state energy. First let’s observe that the exact expressions for the ground state wavefunction and energy are 1 Ψn (x) = √ cos(kn x). in addition to the approximation to the ground state. γ(a − b). (b) A more sophisticated trial function is parabolic.1 Apply the variational method to estimate the ground state energy of a particle confined in a one-dimensional box for which V = 0 for −a < x < a. and Ψ(±a) = 0. where the ratio of the adjustable parameters α and β is determined variationally. use an unnormalized trapezoidal trial function which vanishes at ±a and is symmetric with respect to the center of the well: Ψt (x) = (a − |x|). Taking γ(a − |x|).23 . and. an optimal quartic trial function with nodes between the endpoints. again vanishing at the end points and even in x. (a) First. 2a En = n 2 2 π ≈ 1. (a − b).Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 2 Problem 8. b ≤ |x| ≤ a x| ≤ b. evaluate the mean a square deviation −a |Ψ(x) − Ψt (x)|2 dx for the various cases.

(1) Now we can compute the energy expectation value of Ψt : 2 < Ψt |H|Ψt > = − Integrating by parts. < H >= To find the optimal value of b. this is m γ2 Ψt2 (x) dx dx 2 a b m 2 m γ 2 (b − a).Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 3 we have a −a Ψ2 (x)dx = 2 t a 0 Ψ2 (x)dx t (a − b)2 b a = 2γ 2 = 2γ 2 = 2γ 2 = γ2 dx + 0 b (a − x)2 dx 1 b(a − b)2 + (a − b)3 3 1 b(a2 + b2 − 2ab) + (a3 − b3 ) − a2 b + b2 a 3 2 3 a + 2b3 − 3ab2 3 3 2 1 a3 + 2b3 − 3ab2 a so Ψt is normalized by taking γ2 = . 3 2 2m (b − a) a3 + 2b3 − 3ab2 . we zero the derivative of this with respect to b: 0= (a3 1 6b2 (b − a) 6ab(b − a) − 3 + 3 3 − 3ab2 ) 3 − 3ab2 )2 + 2b (a + 2b (a + 2b3 − 3ab2 )2 = −4b3 + 9b2 a − 6a2 b + a3 . 2m Ψt (x) −a d2 Ψt (x) dx dx2 2 =− 2m Ψt (x)Ψt (x) a −a a − Ψt2 (x) dx −a (the first integral vanishes since Ψt vanishes at the endpoints) 2 a 0 =+ = = Using (1).

2 t 2m dx m 2 = γ[−αx4 + (αa2 − β)x2 + βa2 ] The expectation value of the energy is .25 . = 4 ma2 ma2 So this is in good agreement with the exact ground state energy. 16a5 <H >=− =2 = 2m 2 Ψt (x) −a a 0 d2 Ψt (x) dx dx2 m γ2 (a2 − x2 )dx 4 2 2 3 γ a 3m 2 5 2 ≈ 1. The normalization integral is a −a a 0 a 0 Ψ2 (x) dx = 2γ 2 t = 2γ = 2γ = 2 (a2 − x2 )2 dx (a4 + x4 − 2a2 x2 )dx 2 1 2 a5 + a5 − a5 5 3 16 2 5 γ a 15 so Ψt (x) is normalized by taking γ2 = The expectation value of the energy is 2 a 15 .Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 4 (b) For a parabolic trial function we take Ψt (x) = γ(a2 − x2 ). (c) In this case we have Ψt (x) = γ(a2 − x2 )(αx2 + β) The kinetic energy is − 2 d2 Ψ (x) = γ [6αx2 − (αa2 − β)].

Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 5 Problem 8. scaled by a constant factor ω. Derive an equation that relates ω and λ. e−ωξ 2 /2 . Ψ(ω) = ω π 1/4 2 /2 = Ce−ωξ 2 /2 . consider the anharmonic oscillator Hamiltonian.1. Explain. (c) Note that the method yields answers for a discrete energy eigenstate even if λ is slightly negative. (a) Estimate the ground state energy by a variational calculation. . (a) To find the ground state eigenfunction of the Hamiltonian Merzbacher proposes. (b) Compute the variational estimate of the ground state energy of H for various positive values of the strength λ.2 Using scaled variables. it’s convenient to rewrite it: H0 (ω) = 1 2 1 2 2 p + ω ξ 2 ξ 2 1 1 ∂2 + ω2 ξ 2 =− 2 2 ∂ξ 2 Upon substituting u = ω 1/2 ξ we obtain =ω − 1 ∂2 1 + u2 2 ∂u2 2 and now this is just the ordinary harmonic oscillator Hamiltonian. using as a trial function the ground state wave function for the harmonic oscillator H0 (ω) = 1 2 1 2 2 p + ω ξ 2 ξ 2 where ω is an adjustable variational parameter. with ground-state eigenfunction Ψ(ω) = Ce−u Adding the normalization constant. 1 1 H = p2 + ξ 2 + λξ 4 2 ξ 2 where λ is a real-valued parameter. as in Section 5. Draw the potential energy curve to judge if this result makes physical sense.

we need to know the result of operating on Ψ(ω) with p2 : ξ p2 Ψ(ω) = − ξ ω π ω =− π ω =− π 1/4 1/4 ∂ ∂ −ωξ2 /2 e ∂ξ ∂ξ 2 ∂ −ωξe−ωξ /2 ∂ξ −ω + ω 2 ξ 2 e−ωξ 2 1/4 /2 Then for the expectation value of T we have Ψ| T |Ψ = 1 2 1 2 1 2 ∞ Ψ(ξ)p2 Ψ(ξ)dξ ξ −∞ =− =− = ω π ∞ −∞ −ω + ω 2 ξ 2 e−ωξ dξ π 1 + ω2 ω 2 π ω3 (2) 2 ω −ω π ω . The energy expectation value is Ψ| H |Ψ = Ψ| T |Ψ + Ψ| V |Ψ where T = p2 /2 and V = ξ 2 /2 + λξ 4 .Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 6 Now we want to treat ω as a parameter and vary it until the energy expectation value of Ψ(ω) is minimized. to compute the expectation value of T . First of all. for the expectation value of V we have (3) exptwoΨV Ψ = ω π ω π 1 2 ∞ ∞ ξ 2 e−ωξ dξ + λ −∞ −∞ 2 ξ 4 e−ωξ dξ 2 3 1 π = + λ 3 4 ω 4 1 3λ = + . 4 On the other hand. 4ω 4ω 2 Adding (2) and (4). Let’s compute the two expectation values ξ separately. exptwoΨHΨ = π ω5 (4) 1 3λ 1 ω+ + 2 . 2 ω ω (5) To minimize this with respect to ω we equate its ω derivative to 0: 0=1− 1 6λ − 3 ω2 ω .

for small λ. Inserting this estimate into (5) and again keeping only terms of lowest order in λ we find (7) exptwoΨHΨ = ≈ ≈ ≈ 1 (1 + ) + (1 + )−1 + 3λ(1 + )−2 4 1 (1 + 3λ) + (1 + 3λ)−1 + 3λ(1 + 3λ)−2 4 1 [(1 + 3λ) + (1 − 3λ) + 3λ(1 − 6λ)] 4 1 3 + λ. We can thus imagine that. the energy-minimizing value of ω will be close to 1. But writing down the full solution would be tedious. and we may write ω(λ) ≈ 1 + for some small . Instead let’s see what happens when λ is small. Evidently. when λ = 0 the Hamiltonian in this problem degenerates to the normal harmonic oscillator Hamiltonian. for which the energy is minimized by the (unscaled) ground state harmonic oscillator wavefunction. 4 (9) . Inserting this in (6). (1 + 3 + 3 2 + 3 ) − (1 + ) = 6λ Keeping only terms of zeroth or first order in the small quantity (which is equivalent to keeping terms of lowest order in the perturbing potential strength λ) we obtain from this ≈ 3λ.e. so for λ 0 the minimizing value of ω is ω ≈ 1 + 3λ.Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 7 or ω 3 − ω − 6λ = 0. i. 2 4 (8) Since the 1/2 term is the normal (unperturbed) energy of the state. (6) We could then solve this equation for ω in terms of λ to obtain the energyminimizing value of ω for a given perturbing potential strength λ. the energy shift caused by the perturbing potential is ∆E = 3 λ. Ψ(ω) with ω = 1.

For notational simplicity. Then Ψ(x) = Ce−βx 2 /2 and the normalization constant is determined by ∞ 1 = C2 −∞ e−βx dx 2 ⇒ C= β π 1/4 . the energy shift of the ground state is ∆E0 = 3g 4 2 mω which agrees with () (the difference in the factor ( /mω)2 just represents the fact that in Problem 8. make a variational estimate of the ground state energy for a particle in a Gaussian potential well. .Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 8 Problem 8. α > 0). The energy shift to first order is ∆E = exptwoΨn (x)|gx4 |Ψn (x) = g Ψn | x4 |Ψn . For small values of the coefficient. calculate the change in the energy levels of a linear harmonic oscillator that is perturbed by a potential gx4 .3 In first-order perturbation theory.2 we used scaled variables. compare the result with the variational calculation in Problem 2.4 Using a Gaussian trial function. with an adjustable parameter. Problem 8. I like to put β/2 = λ. represented by the Hamiltonian H= 2 p2 − V0 e−αx 2m 2 (V0 > 0. e−λx . I worked out this expectation value in Problem 5. whereas in this problem we inserted the units explicitly).3: ∆E = gexptwoΨn x4 Ψn = 3g 2 2 mω 1 + n + n2 2 In particular.

4m The expectation value of the potential energy is ∞ V = −V0 = −V0 = −V0 = −V0 Combining (10) and (11).Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 9 The kinetic energy operator operating on this state yields TΨ = 2 ∂ p2 ∂ Ψ(x) = − Ψ(x) 2m 2m ∂x ∂x =− =− and its expectation value is T = = β π 2 1/2 β π β π 2 1/4 2 ∂ −βxe−βx /2 2m ∂x 2 1/4 2 2m −β + β 2 x2 e−βx 2 /2 2m β β2 π − β 2 π β3 (10) β . (α + β) exptwoΨ|H|Ψ = Ψ| T |Ψ + Ψ| V |Ψ = β − V0 2m 2 β . Ψ2 (x)e−αx dx −∞ 2 β π β π ∞ e−βx e−αx dx −∞ 2 2 π (α + β) (11) β . (α + β) (12) To minimize with respect to β we equate the first β derivative of this to zero: √ 2 V0 1 β − − 0= 2m 2 β(α + β) (α + β)3 2 = 2m − α2 V0 2 β(α + β)3 mV0 α 2 1/2 2 = β(α + β)3 − = β 4 + 3β 3 α + 3β 2 α2 + βα3 − = x4 + 3x3 + 3x2 + x − mV0 2α mV0 α 2 2 2 .

The first task is to evaluate the normalization constant C. however. In practice. for the optimum value of a. In theory we could write down an explicit expression for the roots of this quartic in terms of mV0 / 2 α. 2a p2 mω 2 x2 + . and then insert said expression into (12) to obtain the lowest energy attainable with this form of trial wave function. this would be a mess.Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 10 where I put x = β/α. and I can’t see any way to proceed other than numerically. 1 = C2 = 2C 2 = 2C 2 0 a Ψ(x)2 dx 1− a −a a 0 x a 2 dx 1−2 a 3 x x2 + 2 a a = 2C so C= 2 a−a+ 3 . 2m 2 (13) The harmonic oscillator hamiltonian is E =T +V = 2 a exptwoΨT Ψ = − Integrating by parts. Am I missing some kind of trick here? Problem 8. an upper limit to the ground state energy of the linear harmonic oscillator. which lies within less than 10 percent of the exact value. 2m Ψ(x) −a ∂ Ψ(x) dx ∂x2 2 (14) 2 =− 2m Ψ(x) ∂ Ψ(x) ∂x a −a a − −a ∂ Ψ(x) ∂x 2 dx .5 Show that as inadequate a variational trial function as Ψ(x) = C 1− 0 |x| a |x| > a |x| ≤ a yields.

2 = 2m 3 2a a −a 1 dx a2 (15) 3 2 = 2ma2 (16) exptwoΨV Ψ = mω 2 2 a −a a x2 Ψ(x)2 dx = mω 2 0 x2 Ψ(x)2 dx 3 2a 3 2a a 0 = mω 2 = mω 2 x2 − 2x3 x4 + 2 a a a 0 dx x3 x4 x5 − + 2 3 2a 5a mω 2 a2 = 20 3 2 mω 2 a2 + .5 < 10%. a2 = 30 mω (17) (18) Inserting into (18).547 · ω. 2 2ma 20 To minimize with respect to a we set the a derivative of this to zero: exptwoΨ|H|Ψ = Ψ| T |Ψ + Ψ| V |Ψ = mω 2 a 3 2 + ma3 10 0=− or a4 = 30 2 m2 ω 2 √ ... 3 exptwoΨHΨ = √ ω ≈ 0.Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 11 The first term vanishes. . so the fractional error is 0. 30 Of course the actual ground state energy is 0.047/0.5 · ω.

and derive the virial theorem for stationary states. Ψt (r) = Ψn (λr).Homer Reid’s Solutions to Merzbacher Problems: Chapter 8 12 Problem 8. Apply the variational principle by using as a trial function. The n − th discrete energy eigenfunction of this system. Ψn (r). where λ is a variational (scaling) parameter. . corresponds to the energy eigenvalue En .6 A particle of mass m moves in a potential V (r).

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