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Jump to: navigation, search For other uses, see Tannin (demon).

Tannic acid

A bottle of tannic acid solution in water.

Tannin powder (mixture of compounds).

2 Presence in water and wood 2 Classes of tannins o 2.1.2. where they play a role in protection from predation.1.000[2] (gallic acid esters) and up to 20. vegetable tannin.2. The astringency from the tannins is what causes the dry and puckery feeling in the mouth following the consumption of unripened fruit or red wine. However.1.[1] Likewise.k.1 Drinks with tannins  3.2.2 Beer  3. an Old High German word for oak or fir tree. metallic salts.1 Presence in soils o 1. lime water. The compounds are widely distributed in many species of plants.A tannin (a. a type of biomolecule.1 Pseudo tannins 3 Nutrition o 3.2.2 Smoked foods  3.1. Contents [hide] • • • 1 Occurrence o 1. as opposed to modern synthetic tannin) is an astringent. gelatin. bitter plant polyphenolic compound that binds to and precipitates proteins and various other organic compounds including amino acids and alkaloids.000 (proanthocyanidins). as in Tannenbaum) refers to the use of wood tannins from oak in tanning animal hides into leather.5 Chocolate .2.2.2 Persimmons  3.4 Legumes  3.1 Fruits  3. hence the words "tan" and "tanning" for the treatment of leather. Tannins have molecular weights ranging from 500 to over 3. The term tannin (from tanna.e. i. the term "tannin" by extension is widely applied to any large polyphenolic compound containing sufficient hydroxyls and other suitable groups (such as carboxyls) to form strong complexes with proteins and other macromolecules. strong oxidizing agents and zinc sulfate.1 Coffee  3.3 Fruit Juices o 3.2. heavy metals.2.2 Food Items with Tannins  3. since they form complexes and precipitate in aqueous solution.1.a. iron.3 Herbs/spices  3. Tannins are incompatible with alkalis.2.1.3 Berries  3. the destruction or modification of tannins with time plays an important role in the ripening of fruit and the aging of wine.1 Pomegranates  3.1. and perhaps also in growth regulation.4 Nuts  3.

4 Metal chelation 4 Tannin market o 4. it is only after cell breakdown and death that the tannins are active in metabolic effects. particularly in northern boreal forests.1 Notes o o • 7 External links [edit] Occurrence Tannins are distributed in species throughout the plant kingdom. Tannins are classified as ergastic substances i.e.[3] The most abundant polyphenols are the condensed tannins. An example of the location of the tannins in stem tissue is that they are often found in the growth areas of trees. but also keep some tannins from affecting plant metabolism while the plant tissue is alive. and other pathogens. Botanically. Tannins may help regulate the growth of these tissues. bud. [edit] Presence in water and wood . seed. such as the secondary phloem and xylem and the layer between the cortex and epidermis.• • • 3. but more and more ecologists now recognize them as important controllers of decomposition and nitrogen cycling processes.3 Producers 5 See also 6 References o 6.1 Uses o 4. Tannins were once believed to function as antiherbivore defenses. pests. As concern grows about global warming. found in virtually all families of plants. root. and stem tissues. non-protoplasm materials found in cells. [edit] Presence in soils The convergent evolution of tannin-rich plant communities has occurred on nutrient-poor acidic soils throughout the world. Tannins are found in leaf. there is great interest to better understand the role of polyphenols as regulators of carbon cycling. tannins are mainly physically located in the vacuoles or surface wax of plants.2 Medical uses and potential o 4.3 Toxicity 3. These storage sites keep tannins active against plant predators. There may be a loss in the bio-availability of still other tannins in plants due to birds. They are commonly found in both gymnosperms as well as angiosperms. and comprising up to 50% of the dry weight of leaves.

cedar. turning the water a tea-like brown The leaching of highly water soluble[4] tannins from decaying vegetation and leaves along a stream may produce what is known as a blackwater river. can be an easy way to avoid tannins.e. indicating a low tannin content.[5] Tannins leaching from an unprepared driftwood decoration in an aquarium can cause pH lowering and coloring of the water to a tea-like tinge. i.[7] are usually not recommended for use in an aquarium[8] so using a hardwood with a very light color.[9] Finnish hardwoods. do not contain tannins. but not.Bog-wood (similar to. Water flowing out of bogs has a characteristic brown color from dissolved peat tannins.[10] [edit] Classes of tannins There are three major classes of tannins:[11] .) tend to contain a lot of tannin. Adding baking soda to the water to raise its pH level will accelerate the process of leaching. Woods with a lot of yellow.[6] Softwoods. A remedy is to boil the wood in water several times (which will also darken and waterlog the wood. Using peat as an aquarium substrate can lead to the same problem. Tannic acid is brown in color. while generally much lower in tannins than hardwoods. The presence of tannins (and/or humic acid) in well water can make it smell bad or taste bitter. driftwood) in an aquarium. red oak. so generally white woods have a low tannin content. discarding the water each time. as the more alkaline solution can draw out tannic acid from the wood faster than the pHneutral water. redwood. but not be unsafe to drink.. like birch and aspen. make it sink). Many hours of boiling the driftwood may need to be followed by many weeks or months of constant soaking and many water changes before the water will stay clear. red or brown coloration to them (like southern yellow pine. etc.

2 %) in the diet can be beneficial.15-0. The new technologies used to analyze molecular and chemical structures have shown that a division into condensed and hydrolyzable tannins is far too simplistic. They do not answer gold beater skin test unlike hydrolysable and condensed tannins.Base Unit: Phloroglucinol Phlorotannins Brown algae Gallic acid Class/Polymer: Hydrolyzable tannins Sources Plants Flavone Non-Hydrolyzable or condensed tannins Plants [edit] Pseudo tannins Pseudo tannins are low molecular weight compounds associated with other compounds. see plant defense against . They are found in tea or coffee[12] or in:[13] • • • • Gallic acid: rhubarb Catechins: Acacia.[15] Some studies suggest that chestnut tannins have been shown to have positive effects on silage quality in the round bale silages. in particular reducing NPNs (non protein nitrogen) in the lowest wilting level. (2002)[18] on in vitro ammonia release and dry matter degradation of soybean meal comparing three different types of tannins (quebracho. catechu.[16] Improved fermentability of soya meal nitrogen in the rumen has also been reported by Mathieu F and Jouany JP (1993).[14] Recent studies have demonstrated that products containing chestnut tannins included at low dosages (0. mate Ipecacuanhic acid: Ipecacuanha [edit] Nutrition Tannins have traditionally been considered antinutritional but it is now known that their beneficial or antinutritional properties depend upon their chemical structure and dosage. after washing with water it gives a blue / black colour). et al. coffee. guarana Chlorogenic acid: Nux-vomica. acacia and chestnut) demonstrated that chestnut tannins are more efficient in protecting soybean meal from in vitro degradation by rumen bacteria. and by interfering with protein absorption and digestive enzymes (for more on that topic.[11] (When gold beater skin or ox skin is dipped in HCl & treated with 1% FeSO4 solution. Condensed tannins inhibit herbivore digestion by binding to consumed plant proteins and making them more difficult for animals to digest. cocoa.[17] Studies by Gonzalez S.

in a Flanders red ale. Tannins are removed using PVPP. Advantages in using salivary proline-rich proteins (PRPs) to inactivate tannins are: • • PRPs inactivate tannins to a greater extent than do dietary proteins. However. grape juices and berry juices are all high in tannins. haze forming proteins by using silica or tannic acid.[20] [edit] Fruit Juices Although citrus fruits do not themselves contain tannins. this results in reduced fecal nitrogen losses PRPs contain non specific nitrogen and nonessential amino acids. This chill haze can be prevented by removing part of the tannins or part of the haze forming proteins.herbivory). in some styles. the tannins can form a precipitate with specific haze forming proteins in the beer resulting in turbidity at low temperature. Sometimes tannins are even added to juices and ciders to create a more astringent feel to the taste. orange-colored juices often contain food dyes with tannins.[19] [edit] Beer In addition to the alpha acids extracted from hops to provide bitterness in beer. hydrolysable tannins sensu stricto were not detected in pulp. Many tannin-consuming animals secrete a tannin-binding protein (mucin) in their saliva. In lager type beers. and in contrast to previous reports. Tannin-binding capacity of salivary mucin is directly related to its proline content. These originate both from the malt and hops. Apple juice. condensed tannins are also present. The presence of soluble condensed tannins in Coffea arabica pulp was confirmed at approximately 1%. [edit] Food Items with Tannins [edit] Fruits [edit] Pomegranates . as. trained brewmasters consider the presence of tannins as a flaw. this makes them more convenient for an animal to exploit rather than using up valuable dietary protein [edit] Drinks with tannins Main articles: Tannins in tea and Tannins in wine [edit] Coffee Tannins were not found in any bean sample. Especially in Germany. for example. the presence of this astringency is acceptable or even desired.

It has been recommended to look for pomegranate ingredients that mimic the polyphenol ratio of the fruit. the marker compound of pomegranate.[24] [edit] Persimmons . particularly hydrolysable tannins. A persimmon fruit. Punicalagins have a molecular weight of 1038 and are the largest molecule found intact in rat plasma after oral ingestion[21] and were found to show no toxic effects in rats who were given a 6% diet of punicalagins for 37 days.[23] Several dietary supplements and nutritional ingredients are available that contain extracts of whole pomegranate and/or are standardized to punicalagins.Pomegranate fruit. Strawberries in a bowl Pomegranates contain a diverse array of tannins. as potent synergistic effects have been observed in 'natural spectrum' extracts. opened. Extracts of pomegranate are also Generally Recognized as Safe (GRAS) by the United States Food and Drug Administration.[22] Punicalagins are also found to be the major component responsible for pomegranate juice's antioxidant and health benefits. especially pomegranate concentrate normalized to punicalagins. The most abundant of pomegranate tannins are called punicalagins.

[26] contain both hydrolyzable and condensed tannins. yet the saliva glands will continue to secrete saliva which cannot affect the tannin-laced food. vanilla. oak and other woods used in smoking are present on the surface of smoked fish and meat (although smoke from cherry wood can be toxic to humans.) [edit] Herbs/spices Cloves. and cinnamon all contain tannins. Almonds feature a lower content. American.Some persimmons are highly astringent and therefore inedible when they are not extremely ripe (specifically the Korean. walnuts and pecans.[28] [edit] Legumes Most legumes contain tannins.[2] which in some ruminant animals inhibits the absorption of nutrients from high-tannin grains such as sorghum. Chickpeas (also known as garbanzo beans) have a smaller amount of tannins. and Hachiya or Japanese).[29] [edit] Chocolate Chocolate liquor contains about 6% tannins. Peanuts without shells have a very low tannin content. .[25] strawberries and blueberries. The areca nut also contains tannin which contributes to its antibacterial properties. and if eaten by humans (and many other animals).[27] Acorns contain such high concentrations of tannins that they need to be processed before they can be consumed safely. cherry. cumin. [edit] Smoked foods Tannins from the wood of mesquite. Red-colored beans contain the most tannins. tarragon. and whitecolored beans have the least. [edit] Nuts Nuts that can be consumed raw such as hazelnuts.[30] [edit] Toxicity Tannins have been shown to precipitate proteins. Tannin concentration in the crude extract of these nuts did not directly translate to the same relationships for the condensed fraction.[clarification needed] [edit] Berries Most berries. such as cranberries. the mouth will become completely dry. contain high amounts of tannins. This is due to the high level of tannins. thyme.

as pesticide. or heme iron absorption will not be affected by tannins. The lethal dose is said to be around 6% of the animal's body weight. With the exception of tea. It has not been determined whether tannin was produced for another purpose. also known as non-heme. condensed tannins do not interfere with iron absorption. like squirrels and mule deer have developed the ability to consume high concentrations of tannins without ill effects. Some animals. Foods rich in vitamin C help neutralize tannin's effects on iron absorption.[34] In order to prevent these problems. e.[33] Some deer and moose were found to have perished due to ingesting acorns. This is only an approximate figure since acorns from Red Oak were shown to contain on average two to four times the tannins than those from White Oak. it is advised to drink tea and coffee between meals.[citation needed] [edit] Metal chelation If ingested in excessive quantities. Adding milk to coffee and tea has very little to no influence on the inhibitory effect of tannins.g. not during. Tannic acid does not affect absorption of other trace minerals such as zinc. However.[32] Animals that consume excessive amounts of these plants fall ill or die. Animal sources. chlorogenic acid) and the effect on iron absorption. liver damage.[31] Many plants employ tannins to deter animals. or whether it evolved specifically for the purpose of inhibiting predation. Tannins only reduce the bioavailability of plant sources of iron.In sensitive individuals. tannins inhibit the absorption of minerals such as iron which may.[36] Tannins interfere with iron absorption through a complex formation with iron when it is in the gastrointestinal lumen which decreases the bioavailability of iron. Adding lemon juice to tea will reduce the negative effect of tannins in iron absorption as well. irritation of the stomach and gastrointestinal pain. kidney irritation. if prolonged.) Tannins are leached from acorns before they are used for human consumption. catechin.[37] [edit] Tannin market . There is an important difference in the way in which the phenolic compounds interact with different hydroxylation patterns (gallic acid. a large intake of tannins may cause bowel irritation. A correlation has been made between esophogeal or nasal cancer in humans and regular consumption of certain herbs with high tannin concentrations. Acorns are a well known problem in cattle breeding. and manganese in rats.[34] This is because tannins are metal ion chelators[35] and tannin-chelated metal ions are not bioavailable. lead to anemia. (Some humans were found to be unable to taste bitter foods. Symptoms include ataxia and shortness of breath. long-term and/or excessive use of herbs containing high concentrations of tannins is not recommended. The content of the iron-binding galloyl groups may be the major determinant of the inhibitory effect of phenolic compounds. Humans would usually find the bitter taste of foods containing high amounts of tannins unpalatable. copper.

though inorganic tanning agents are also in use today and account for 90% of the world's leather production. the most cost-effective method is hot water extraction. many small tannin industry sites closed. Tannic acid is used worldwide as clarifying agent in alcoholic drinks and as aroma ingredient in both alcoholic and soft drinks or juices. due the scarity of vegetable tannins during World War II. (August 2009) Tannins are an important ingredient in the process of tanning leather. For large quantities. At that time. or green to greenish black) according to the type of tannin.[39] Tannins produce different colors with ferric chloride (either blue. Iron gall ink is produced by treating a solution of tannins with iron(II) sulfate. Please help improve this article by adding reliable references. [edit] Uses This section needs additional citations for verification. The cost of the final product depends on the method used to extract the tannins. Tannins from different botanical origins also find extensive uses in the wine industry.[38] Vegetable tannins are estimated to be used for the production of 10-20% of the global leather production. There has been a collapse in the vegetable tannin market in the 1950s-1960s. blue black. in particular the use of solvents. alkali and other chemicals used (for instance glycerin).[citation needed] Tannin is a component in a type of industrial particleboard adhesive developed jointly by the Tanzania Industrial Research and Development Organization and Forintek Labs . Before that time. Oak bark. mimosa and quebracho tree have traditionally been the primary source of tannery tannin. processes used plant material and were long (up to six months). to produce tanning material for the need for more leather. Unsourced material may be challenged and removed. due to the appearance of synthetic tannins.Tannin in a plastic container Tannin production began at the beginning of the 19th century with the industrial revolution.

the poliovirus.[41] Tannins can be used for production of anti-corrosive primer.[44] Tannins have shown potential antiviral. rust converter to transform oxidized steel into a smooth sealed surface and rust inhibitor. and various enteric viruses are inactivated.[40] Pinus radiata tannins has been investigated for the production of wood adhesives. Please improve this section if you can. herpes simplex virus. which may be of benefit to neuro disease patients. When incubated with red grape juice and red wines with a high content of condensed tannins. (September 2009) Tannins can also be effective in protecting the kidneys. discovered that the tannins isolated from the stem bark also has the antiinflammatory and antiulcer potency on rodents.[43] [edit] Medical uses and potential See also: Wine and health This section may require cleanup to meet Wikipedia's quality standards.[45] antibacterial[46] and antiparasitic effects. The plant has shown promising futures for therapeutic use. a hereditary disease characterized by excessive absorption of dietary iron resulting in a pathological increase in total body iron stores. .[42] Immobilized tannins have been tested to recover uranium from seawater. showing a strong anioxidant property for possible therapeutic applications. The talk page may contain suggestions. sold under brand name-Nox Primer for treatment of rusted steel surfaces prior to painting.[49] Foods rich in tannins can be used in the treatment of HFE hereditary hemochromatosis. The use of resins made of tannins has been investigated to remove mercury and methylmercury from solution.[47] It is believed that tannins isolated from the stem bark of Myracrodruon urundeuva are of neuroprotective functions capable of reversing 6-hydroxydopamine induced toxicity.[48] Souza et al.Canada.

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