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58102-mt----advanced chemical engineering thermodynamics

58102-mt----advanced chemical engineering thermodynamics

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Published by: SRINIVASA RAO GANTA on Sep 19, 2008
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Code No: 58102/MT M.Tech.

– I Semester Supplementary Examinations, September, 2008

NR

ADVANCED CHEMICAL ENGINEERING THERMODYNAMICS (Chemical Engineering) Time: 3hours Answer any FIVE questions All questions carry equal marks --1.a) b) 2.a) b) 3. Explain the concept of fugacity and activity. Derive the Raoult’s law using fugacities and state the assumptions made. Give a detailed account of intermolecular forces between non polar molecules. Write about polarizability and induced dipoles. Discuss in detail about the molecular theory of corresponding states and explain how it can be extended to more complicated molecules. Write in detail about Scatchard – Hildebrand theory of solutions. Discuss in detail about Wilson’s extension of the Flory – Huggins equation. Obtain an expression for entropy from statistical thermodynamics perspective. Give a detailed account of the following methods for determining activity coefficients: a) ASOG method b) UNIFAC method. Define and explain partial molar properties. $$$ Max. Marks:60

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