Code No: R05011801

Set No. 1

I B.Tech Supplimentary Examinations, Aug/Sep 2008 METALLURGICAL ANALYSIS (Metallurgy & Material Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. Discuss various techniques for the preparation for solutions for different metallurgical materials. [16] 2. (a) Discuss briefly how the identification of metals is carried out by dry reaction (b) How are the following detected in metallurgical materials using spot tests. Give necessary chemical equations. i. Aluminium . ii. Copper. [6+10]

3. Explain the determination of Nickel in Nickel-Silvers, Cupro-Nickels and high tensile brasses. [16] 4. (a) Discuss the various methods for the estimation of Cr in alloy steels. (b) How is Phosphorous in Iron determined by Volumetric method. [8+8]

5. Describe the procedure for the determination of the following in the manganese ores. (a) Determination of Lime. (b) Determination of Sulphur. (c) Determination of Phosphorus. [5+5+6]

6. (a) Define the term Colorimetry? How is the colour developed in the solution in Colorimetry studies. (b) Name the different techniques of Colorimetry. Give their advantages and disadvantages. [8+8] 7. (a) Explain the procedure involved in colour measurement by standard series method. (b) Discuss colorimetric titration using duplication method. [8+8]

8. (a) With the help of a Wheatstone bridge circuit, explain measurement of conductivity. (b) Discuss the basis of conductometric titrations. ⋆⋆⋆⋆⋆ [10+6]

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(b) Discuss the principle involved in the determination of iron content in iron ores by any one method with relevant equations. Give your suggestions for better results in this technique. 2 I B. [16] 2. explain the technique of amperometric titrations with the dropping mercury electrode.Code No: R05011801 Set No. Is it going to lead for major errors in final analysis? How the error may be prevented or reduced. (b) Give the advantages and disadvantages of classical methods of analysis. (a) (b) (c) (d) Molarity Normality Molality Equivalent weight. [8+8] 7. (b) How do you determine Sulfur in Iron & Steel by gravimetric method? [8+8] 5. [8+8] ⋆⋆⋆⋆⋆ 1 of 1 . Where does really judgment by human eye involve. (a) List the different methods for determining iron content. (a) Mention the factors that should be taken into consideration in choosing an analytical method. Explain the following with sutiable examples and equations. (a) What is the basic principle on which the colorimetric analysis works.[8+8] 3. (a) What is the fundamental principle of amperometric titration? (b) With neat sketches. in Iron oxes. (b) Name three methods used for evaluation of quantitative results and briefly explain each one of them. Compare the advantages and limitations of colorimetric analysis with other methods of instrumental analysis. (b) In case of colorimetric analysis the final analysis involves judgment by human eye. (a) Discuss the general considerations in quantitative technique of polarography. [4+12] 6. Explain the determination of Nickel in Nickel-Silvers. Cupro-Nickels and high tensile brasses. (a) How is Silicon estimated by perchloric acid method. [16] 4. (c) What is the use of concentrated reagents? [5+6+5] 8. Aug/Sep 2008 METALLURGICAL ANALYSIS (Metallurgy & Material Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1.Tech Supplimentary Examinations.

(b) Differential potentiometric titrations. Ni iii.Tech Supplimentary Examinations.1M NaC2 O4 solution? [12+4] 2. What are the various types of instrumental analysis used in metallurgical analysis? Explain their principles of operation in detail. Give the various important chemical reactions and the precautions to be considered. [7+9] 3. (b) Estimation of Cr in Iron & Steels containing less than 2 % Cr. at least with one example? (b) Explain how do you prepare 500 ml of 0. Give an account on the following: (a) Potentiometric titrations using classical method. Explain the procedure in detail for the determination of total iron in iron ore by potassium permanganate method.Code No: R05011801 Set No. [8+8] 5. Mo. Al ii. (a) What are the advantages of dropping mercury electrode? (b) What are the factors affecting the limiting current with a dropping mercury cathode? Briefly discuss each one of them. Aluminium Broznes and Nickel Silvers? [5+6+5] 4. What do you mean by instrumental analysis. (a) What is a borax bead test? How is it carried out? Give the applications of this test for qualitative analysis. Aug/Sep 2008 METALLURGICAL ANALYSIS (Metallurgy & Material Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. 3 I B. [7+9] ⋆⋆⋆⋆⋆ [8+8] 1 of 1 . (a) What are primary and secondary standard substances? Explain the method of preparation of a standard solution. (b) Mention the spot test analysis for the following i. [16] 7. [16] 6. 8. Write notes on the following: (a) Estimation of Ni in High Cr & High Ni steels by Gravimetric method. How is Copper determined in Brasses.

[6+4+6] 7. (a) Explain the advantages and disadvantages of instrumental methods of analysis. Explain their working principle with the help of suitable figures. (b) How are the following detected? Give the necessary chemical reactions i. [16] 6. (a) Discuss determination of the absorption curve and concentration of a substance (potassium nitrate) method. How are the furnaces for assaying process are broadly divided. ⋆⋆⋆⋆⋆ [8+8] 1 of 1 . Write short notes on: (a) Electro . 4 I B. (b) List the different instrumental techniques used in analysis of metallurgical samples. (b) What is metallurgical analysis? Explain its scope.Analysis. [8+8] 5. (b) What is the chief advantage of colorimetric and spectrophotometric methods? [9+7] 8. (a) Give the essential requirements for the successful application of spot tests for the identification of radicals. Iron. Aug/Sep 2008 METALLURGICAL ANALYSIS (Metallurgy & Material Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1.Tech Supplimentary Examinations. (a) Explain the need for instrumental analysis in metallurgical analysis. [6+10] 3.Code No: R05011801 Set No. (b) Ni determination from Cast Irons by Gravimetric method. Chromium. [8+8] 2. [16] 4. ii. (b) Conductometry. Write a short note on the following: (a) Cr estimation in high Cr & high Ni steels. Write the procedure for finding the Phosphorous content in Phosphor bronzes and Gun metals. (c) State and explain Beer-Lambert law.

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