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( (P Pa ap pe er r I II I, , C Co od de e 8 8) )
Time: 3 hours M. Marks: 243
Note: (i) The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has 4 sections.
(ii) Section I contains 9 multiple choice questions which have only one correct answer. Each question carries +3 marks
each for correct answer and – 1 mark for each wrong answer.
(iii) Section II contains 4 questions. Each question contains STATEMENT1 (Assertion) and STATEMENT2 (Reason).
Bubble (A) if both the statements are TRUE and STATEMENT2 is the correct explanation of STATEMENT1
Bubble (B) if both the statements are TRUE but STATEMENT2 is NOT the correct explanation of STATEMENT 1
Bubble (C) if STATEMENT1 is TRUE and STATEMENT2 is FALSE.
Bubble (D) if STATEMENT1 is FALSE and STATEMENT2 is TRUE.
carries +3 marks each for correct answer and – 1 mark for each wrong answer.
(iv) Section III contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered. Each
question has only one correct answer and carries +4 marks for correct answer and – 1 mark for wrong answer.
(v) Section IV contains 3 questions. Each question contains statements given in 2 columns. Statements in the first column
have to be matched with statements in the second column and each question carries +6 marks and marks will be awarded if
all the four parts are correctly matched. No marks will be given for any wrong match in any question. There is no negative
marking.
PART I
SECTION – I
Straight Objective Type
This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1. A spherical portion has been removed from a solid sphere having a charge distributed
uniformly in its volume as shown in the figure. The electric field inside the emptied
space is
(A) zero everywhere (B) nonzero and uniform
(C) nonuniform (D) zero only at its center
Sol. (B)
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2. A magnetic field
0
ˆ
B B j =
,
exists in the region a < x < 2a and
0
ˆ
B B j = −
,
, in the region 2a < x < 3a, where B
0
is a positive constant. A
positive point charge moving with a velocity
0
ˆ
v v i =
,
, where v
0
is a
positive constant, enters the magnetic field at x = a. The trajectory of the
charge in this region can be like,
a
2a
3a
x
0
B
0
−B
0
(A)
a
2a
3a
x
z
(B)
a
2a
3a
x
z
(C)
a
2a
3a
x
z
(D)
a
2a
3a
x
z
Sol. (A)
for a < x < 2a path will be concave upward
2a < x < 3a path will be concave downward
3. A small object of uniform density rolls up a curved surface with an initial velocity v.
It reaches up to a maximum height of
2
3v
4g
with respect to the initial position. The
object is
(A) ring (B) solid sphere
(C) hollow sphere (D) disc
v
Sol. (D)
2
2
2
cm
1 1 v 3v
mv I mg
2 2 R 4g
 
 
+ =
 
\ .
\ .
Hence
2
cm
1
I mR
2
=
4. Electrons with deBroglie wavelength λ fall on the target in an Xray tube. The cutoff wavelength of the emitted X
rays is
(A)
2
0
2mc
h
λ
λ = (B)
0
2h
mc
λ =
(C)
2 2 3
0 2
2m c
h
λ
λ = (D)
0
λ = λ
Sol. (A)
h
2m(eV)
λ = ⇒ eV =
2
2
h
2mλ
0
hC
eV
λ =
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5. A student performs an experiment to determine the Young’s modulus of a wire, exactly 2 m long, by Searle’s method.
In a particular reading, the student measures the extension in the length of the wire to be 0.8 mm with an uncertainty of
±0.05 mm at a load of exactly 1.0 kg. The student also measures the diameter of the wire to be 0.4 mm with an
uncertainty of ±0.01 mm. Take g = 9.8 m/s
2
(exact). The Young’s modulus obtained from the reading is
(A) (2 .0 ± 0.3) × 10
11
N/m
2
(B) (2 .0 ± 0.2) × 10
11
N/m
2
(C) (2 .0 ± 0.1) × 10
11
N/m
2
(D) (2 .0 ± 0.05) × 10
11
N/m
2
Sol. (B)
2
4F
Y
d
=
π ∆
/
/
Y 2 D (L)
Y D L
∆ ∆ ∆
= +
∆
= 0.1125
∆Y = 2 × 10
11
× 0.1125
6. Positive and negative point charges of equal magnitude are kept at
a
0, 0,
2
 

\ .
and
a
0, 0,
2
−  

\ .
, respectively. The work
done by the electric field when another positive point charge is moved from (−a, 0, 0) to (0, a, 0) is
(A) positive
(B) negative
(C) zero
(D) depends on the path connecting the initial and final positions
Sol. (C)
(−a, 0, 0)
(0, a, 0)
B
A
y
x
−q
+q
a/2
a/2
7. In the experiment to determine the speed of sound using a resonance column,
(A) prongs of the tuning fork are kept in a vertical plane
(B) prongs of the tuning fork are kept in a horizontal plane
(C) in one of the two resonances observed, the length of the resonating air column is close to the wavelength of sound
in air
(D) in one of the two resonances observed, the length of the resonating air column is close to half of the wavelength of
sound in air
Sol. (A)
8. Water is filled up to a height h in a beaker of radius R as shown in the figure. The
density of water is ρ, the surface tension of water is T and the atmospheric pressure is
P
0
. Consider a vertical section ABCD of the water column through a diameter of the
beaker. The force on water on one side of this section by water on the other side of
this section has magnitude
(A)
2
0
2P Rh R gh 2RT + π ρ −
(B)
2
0
2P Rh R gh 2RT + ρ −
(C)
2 2
0
P R R gh 2RT π + ρ −
(D)
2 2
0
P R R gh 2RT π + ρ +
2R
h
A
B
D
C
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Sol. (B)
h
0
0
(P gx)2Rdx 2RT F + ρ − =
∫
2P
0
Rh + Rρgh
2
− 2RT = F
dx
x
2TR
(P0+ρgx)2Rdx
9. A particle moves in the XY plane under the influence of a force such that its linear momentum is
ˆ ˆ
p(t) A i cos(kt) jsin(kt)
(
= −
¸ ¸
,
, where A and k are constants. The angle between the force and the momentum is
(A) 0° (B) 30°
(C) 45° (D) 90°
Sol. (D)
dP
ˆ ˆ
F AK i sin(kt) jcos(kt)
dt
(
= = − −
¸ ¸
,
,
F P 0 ⋅ =
, ,
SECTION – II
Assertion  Reason Type
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT1 (Assertion) and STATEMENT2
(Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
10. STATEMENT1
A vertical iron rod has a coil of wire wound over it at the bottom end.
An alternating current flows in the coil. The rod goes through a
conducting ring as shown in the figure. The ring can float at a certain
height above the coil.
Because
STATEMENT2
In the above situation, a current is induced in the ring which interacts with the horizontal component of the magnetic
field to produce an average force in the upward direction.
(A) Statement 1 is True, Statement2 is True; Statement 2 is a correct explanation for Statement1.
(B) Statement 1 is True, Statement2 is True; Statement 2 is NOT a correct explanation for Statement1.
(C) Statement 1 is True, Statement2 is False.
(D) Statement 1 is False, Statement2 is True.
Sol. (A)
11. STATEMENT1
If there is no external torque on a body about its center of mass, then the velocity of the center of mass remains
constant.
because
STATEMENT2
The linear momentum of an isolated system remains constant.
(A) Statement 1 is True, Statement2 is True; Statement 2 is a correct explanation for Statement1.
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(B) Statement 1 is True, Statement2 is True; Statement 2 is NOT a correct explanation for Statement1.
(C) Statement 1 is True, Statement2 is False.
(D) Statement 1 is False, Statement2 is True.
Sol. (D)
12. STATEMENT1
The total translational kinetic energy of all the molecules of a given mass of an ideal gas is 1.5 times the product of its
pressure and its volume.
because
STATEMENT2
The molecules of a gas collide with each other and the velocities of the molecules change due to the collision.
(A) Statement 1 is True, Statement2 is True; Statement 2 is a correct explanation for Statement1.
(B) Statement 1 is True, Statement2 is True; Statement 2 is NOT a correct explanation for Statement1.
(C) Statement 1 is True, Statement2 is False.
(D) Statement 1 is False, Statement2 is True.
Sol. (B)
13. STATEMENT1
A cloth covers a table. Some dishes are kept on it. The cloth can be pulled out without dislodging the dishes from the
table.
because
STATEMENT2
For every action there is an equal and opposite reaction.
(A) Statement 1 is True, Statement2 is True; Statement 2 is a correct explanation for Statement1.
(B) Statement 1 is True, Statement2 is True; Statement 2 is NOT a correct explanation for Statement1.
(C) Statement 1 is True, Statement2 is False.
(D) Statement 1 is False, Statement2 is True.
Sol. (B)
SECTION – III
Linked Comprehension Type
This section contains 2 paragraphs P
1416
and P
1719
. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
P
14 – 16
: Paragraph for Question Nos. 14 to 16
The figure shows a surface XY separating two transparent media, medium
– 1 and medium 2. The lines ab and cd represent wavefronts of a light
wave travelling in medium1 and incident on XY. The lines ef and gh
represent wavefronts of the light wave in medium2 after refraction.
Medium1
Medium2
Y X
e
f
h
g
d
c
a
b
14. Light travels as a
(A) parallel beam in each medium (B) convergent beam in each medium
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(C) divergent beam in each medium (D) divergent beam in one medium and convergent beam
in the other medium.
Sol. (A)
a
i
Medium 2
r
b
d
c
f
h
g
e
Medium 1
15. The phases of the light wave at c, d, e and f are φ
c
, φ
d
, φ
e
and φ
f
respectively. It is given that φ
c
≠ φ
f
(A) φ
c
cannot be equal to φ
d
(B) φ
d
can be equal to φ
e
(C) (φ
d
− φ
f
) is equal to (φ
c
 φ
e
) (D) (φ
d
− φ
c
) is not equal to (φ
f
− φ
e
)
Sol. (C)
16. Speed of the light is
(A) the same in medium1 and medium2 (B) larger in medium1 than in medium2
(C) larger in medium2 than in medium1 (D) different at b and d
Sol. (B)
P
17 – 19
:
Paragraph for Question Nos. 17 to 19
Two trains A and B are moving with speeds 20 m/s and 30 m/s respectively in
the same direction on the same straight track, with B ahead of A. The engines
are at the front ends. The engine of train A blows a long whistle.
Assume that the sound of the whistle is composed of components varying in
frequency from f
1
= 800 Hz to f
2
= 1120 Hz, as shown in the figure. The spread
in the frequency (highest frequency − lowest frequency) is thus 320 Hz. The
speed of sound in still air is 340 m/s.
I
n
t
e
n
s
i
t
y
Frequency f
1 f
2
17. The speed of sound of the whistle is
(A) 340 m/s for passengers in A and 310 m/s for passengers in B
(B) 360 m/s for passengers in A and 310 m/s for passengers in B
(C) 310 m/s for passengers in A and 360 m/s for passengers in B
(D) 340 m/s for passengers in both the trains
Sol. (B)
Speed of sound is frame dependent.
18. The distribution of the sound intensity of the whistle as observed by the passengers in train A is best represented by
(A)
I
n
t
e
n
s
i
t
y
Frequency f
1 f
2
(B)
I
n
t
e
n
s
i
t
y
Frequency f
1 f
2
(C)
I
n
t
e
n
s
i
t
y
Frequency f
1 f
2
(D)
I
n
t
e
n
s
i
t
y
Frequency f
1 f
2
Sol. (A)
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19. The spread of frequency as observed by the passengers in train B is
(A) 310 Hz (B) 330 Hz
(C) 350 Hz (D) 290 Hz
Sol. (A)
SECTION – IV
MatrixMatch Type
This section contains 3 questions. Each question contains statements given in two columns which have to be matched. Statements
(A, B, C, D) in column I have to be matched with statements (p, q, r, s) in column II. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are Ap, As, Bq, Br, Cp, Cq and Ds, then the correctly bubbled 4 × 4 matrix should be as follows:
p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
20. Column I describe some situations in which a small object moves. Column II describes some characteristics of these
motions. Match the situation in Column I with the characteristics in Column II and indicate your answer by darkening
appropriate bubbles in the 4 × 4 matrix given in the ORS.
Column I Column II
(A) The object moves on the xaxis under a conservative force in such
a way that its “speed” and “position” satisfy v =
2
1 2
c c x − ,
where c
1
and c
2
are positive constants.
(p) The object executes a simple
harmonic motion.
(B) The object moves on the xaxis in such a way that its velocity and
its displacement from the origin satisfy v = −kx, where k is a
positive constant.
(q) The object does not change its
direction.
(C) The object is attached to one end of a massless spring of a given
spring constant. The other end of the spring is attached to the
ceiling of an elevator. Initially everything is at rest. The elevator
starts going upwards with a constant acceleration a. The motion of
the object is observed from the elevator during the period it
maintains this acceleration.
(r) The kinetic energy of the object
keeps on decreasing.
(D) The object is projected from the earth’s surface vertically upwards
with a speed
e e
2 GM R , where, M
e
is the mass of the earth and
R
e
is the radius of the earth. Neglect forces from objects other
than the earth.
(s) The object can change its direction
only once.
Sol. A→ (p), B → (q) & (r), C → (p), D → (r) & (q)
21. Two wires each carrying a steady current I are shown in four configurations in Column I. Some of the resulting effects
are described in Column II. Match the statements in Column I with the statements in Column II and indicate your
answer by darkening appropriate bubbles in the 4 × 4 matrix given in the ORS.
Column I Column II
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(A) Point P is situated midway
between the wires.
P
(p) The magnetic fields (B) at P due
to the currents in the wires are in
the same direction.
(B) Point P is situated at the mid
point of the line joining the
centers of the circular wires,
which have same radii.
P
(q) The magnetic fields (B) at P due
to the currents in the wires are in
opposite directions.
(C) Point P is situated at the mid
point of the line joining the
centers of the circular wires,
which have same radii.
P
(r) There is no magnetic field at P.
(D) Point P is situated at the common
center of the wires.
P
(s) The wires repel each other.
Sol. A→ (q) & (r), B → (p), C → (q) & (r), D → (q)
22. Column I gives some devices and Column II gives some process on which the functioning of these devices depend.
Match the devices in Column I with the processes in Column II and indicate your answer by darkening appropriate
bubbles in the 4 × 4 matrix given in the ORS.
Column I Column II
(A) Bimetallic strip (p) Radiation from a hot body
(B) Steam engine (q) Energy conversion
(C) Incandescent lamp (r) Melting
(D) Electric fuse (s) Thermal expansion of solids
Sol. A→ (s), B → (q), C → (p), D → (r)
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PART II (CHEMISTRY)
SECTION – I
Straight Objective Type
This section contains 9 multiple choice questions numbered 23 to 31. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
23. Among the following, the least stable resonance structure is
(A)
N
O
O
(B)
N
O
O
(C)
N
O
O
(D)
N
O
O
Sol. (A)
(A)
O
N
O
Same charges are present at nearest position (Less stable)
(B)
O
N
O
(C)
O
N
O
(D)
O
N
O
Hence (A) is correct
24. For the process H
2
O(l) (1 bar, 373 K) →H
2
O(g) (1 bar, 373 K), the correct set of thermodynamic parameters is
(A) G 0, S ve ∆ = ∆ = + (B) G 0, S ve ∆ = ∆ = −
(C) G ve, S 0 ∆ = + ∆ = (D) G ve, S ve ∆ = − ∆ = +
Sol. (A)
( )
( )
( )
( )
2 2
1 bar, 373 K 1 bar, 373K
H O H O g
÷÷÷
/
÷÷÷
At 100°C ( )
2
H O / has equilibrium with H
2
O(g) therefore ∆G = 0.
Because liquid molecules are converting into gases molecules therefore ∆S = +ve
Hence (A) is correct.
25. Cyclohexene on ozonolysis followed by reaction with zinc dust and water gives compound E. Compound E on further
treatment with aqueous KOH yields compound F. Compound F is
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(A)
CHO
(B)
CHO
(C)
COOH
(D)
CO
2
H
CO
2
H
Sol. (A)
3 2
O , H O
Zn
÷÷÷÷→
CHO
CHO
( )
KOH
aldol condensation
÷÷÷÷÷÷÷→
CHO
(E)
(F)
Hence (A) is correct.
26. Consider a reaction aG + bH →Products. When concentration of both the reactants G and H is doubled, the rate
increases by eight times. However, when concentration of G is doubled keeping the concentration of H fixed, the rate is
doubled. The overall order of the reaction is
(A) 0 (B) 1
(C) 2 (D) 3
Sol. (D)
aG + bH ÷÷→ Product
rate ∝ [G]
a
[H]
b
a = 1, b = 2
Hence (D) is correct
27. Among the following metal carbonyls, the C – O bond order is lowest in
(A) [Mn(CO)
6
]
+
(B) [Fe(CO)
5
]
(C) [Cr(CO)
6
] (D) [V(CO)
6
]

Sol. (B)
(A) Mn
+
= 3d
5
4s
1
in presence of CO effective configuration = 3d
6
4s
0
.
Three lone pair for back bonding with vacant orbital of C in CO.
(B) Fe
0
= 3d
6
4s
2
in presence of CO effective configuration = 3d
8
four lone pair for back bonding with CO.
(C) Cr
0
= 3d
5
4s
1
Effective configuration = 3d
6
.
Three lone pair for back bonding with CO.
(D) V
−
= 3d
4
4s
2
effective configuration = 3d
6
three lone pair for back bonding with CO.
Maximum back bonding is present in Fe(CO)
5
there for CO bond order is lowest here.
28. A positron is emitted from
23
11
Na . The ratio of the atomic mass and atomic number of the resulting nuclide is
(A) 22/10 (B) 22/11
(C) 23/10 (D) 23/12
Sol. (C)
On position emission from nucleus, proton converts into neutron therefore atomic number decreases by one
but atomic mass remains constant.
Atomic mass 23
atomic number 10
=
Hence (C) is correct.
29. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenylamine as
indicator. The number of moles of Mohr’s salt required per mole of dichromate is
(A) 3 (B) 4
(C) 5 (D) 6
Sol. (D)
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2 2 3 3
2 7
Cr O Fe Fe Cr
− + + +
+ ÷÷→ +
n factor of
2
2 7
Cr O
−
= 6
n factor of Fe
2+
= 1
So to reduce one mole of dichromate 6 moles of Fe
2+
are required.
Hence (D) is correct.
30. The number of stereoisomers obtained by bromination of trans2butene is
(A) 1 (B) 2
(C) 3 (D) 4
Sol. (A)
C C
C H
3
H CH
3
H
( )
2
Br
Anti addition
÷÷÷÷÷÷→Meso product
Hence (A) is correct.
31. A solution of metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless
solution. Moreover, the solution of metal ion on treatment with a solution of cobalt(II) thiocyanate gives rise to a deep
blue crystalline precipitate. The metal ion is
(A) Pb
2+
(B) Hg
2+
(C) Cu
2+
(D) Co
2+
Sol. (B)
( )
2
2
Hg KI HgI Red ppt.
+
+ ÷÷→
( )
2 2 4
excess
Soluble
HgI KI K HgI + ÷÷→
( ) ( )
2
2 2
blue crystalline precipiates
HgI Co SCN Hg SCN
+
+ ÷÷→
SECTION – II
Assertion – Reason Type
This section 4 questions numbered 32 to 35. Each question contains STATEMENT1 (Assertion) and STATEMENT2 (Reason).
Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
32. STATEMENT1: Molecules that are not superimposable on their mirror images are chiral
because
STATEMENT2: All chiral molecules have chiral centres.
(A) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
(B) Statement1 is True, Statement2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement1 is True, Statement2 is False
(D) Statement1 is False, Statement2 is True
Sol. (C)
33. STATEMENT1: Alkali metals dissolves in liquid ammonia to give blue solution
because
STATEMENT2: Alkali metals in liquid ammonia give solvated species of the type [M(NH
3
)
n
]
+
(M = alkali metals).
(A) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
(B) Statement1 is True, Statement2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement1 is True, Statement2 is False
(D) Statement1 is False, Statement2 is True
Sol. (B)
Blue colour is due to solvated electrons.
34. STATEMENT1: Band gap in germanium is small.
because
STATEMENT2: The energy spread of each germanium atomic energy level is infinitesimally small.
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(A) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
(B) Statement1 is True, Statement2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement1 is True, Statement2 is False
(D) Statement1 is False, Statement2 is True
Sol. (C)
35. STATEMENT1: Glucose gives a reddishbrown precipitate with Fehling’s solution.
because
STATEMENT2: Reaction of glucose with Fehling’s solution gives CuO and gluconic acid.
(A) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
(B) Statement1 is True, Statement2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement1 is True, Statement2 is False
(D) Statement1 is False, Statement2 is True
Sol. (C)
( )
( )
6 12 6 6 11 7 2
Red ppt.
C H O Fehling solution C H O Cu O
−
+ ÷÷→ + ↓
SECTION – III
Linked Comprehension Type
This section contains 2 paragraphs C
3638
and C
3941
. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
C
3638
: Paragraph for question Nos 36 to 38
ReimerTiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This
reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicyladehydes as
depicted below.
OH
CH
3
[I]
O Na
CH
3
CHO
aq.HCl
OH
CHO
CH
3
(I) (II)
(III)
36. Which one of the following reagents is used in the above reaction?
(A) aq. NaOH + CH
3
Cl (B) aq. NaOH + CH
2
Cl
2
(C) aq. NaOH + CHCl
3
(D) aq. NaOH + CCl
4
Sol. (C)
aq 3 3 2
OH CHCl CCl H O + +
÷÷÷
÷÷÷
3 2
CCl Cl CCl : ÷÷→ +
dichlorocarbene intermediate
37. The electrophile in this reaction is
(A) : CHCl (B)
+
CHCl
2
(C) :CCl
2
(D) .CCl
3
Sol. (C)
aq 3 3 2
OH CHCl CCl H O + +
÷÷÷
÷÷÷
3 2
CCl Cl CCl : ÷÷→ +
dichlorocarbene intermediate
38. The structure of the intermediate I is
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(A)
O Na
CH
3
CH
2
Cl
(B)
O Na
CH
3
CHCl
2
(C)
O Na
CH
3
CCl
3
(D)
O Na
CH
3
CH
2
OH
Sol. (B)
O
CH
3
CCl
2
O
CH
3
CHCl
2
C
3941
: Paragraph for question Nos 39 to 41
Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential (E
o
) of two halfcell
reactions decide which way the reaction is expected to proceed. A simple example is a Daniel cell in which zinc goes into
solution and copper gets deposited. Given below are a set of halfcell reactions (acidic medium) along with their E
o
(V with
respect to normal hydrogen electrode) values. Using this data obtain the correct explanations to Questions 3941.
I
2
+ 2e

→2I

E
o
= 0.54
Cl
2
+ 2e

→2Cl

E
o
= 1.36
Mn
3+
+ e

→Mn
2+
E
o
= 1.50
Fe
3+
+ e

→Fe
2+
E
o
= 0.77
O
2
+ 4H
+
+ 4e

→2H
2
O E
o
= 1.23
39. Among the following, identify the correct statement.
(A) Chloride ion is oxidized by O
2
(B) Fe
2+
is oxidized by iodine
(C) Iodide ion is oxidized by chlorine (D) Mn
2+
is oxidized by chlorine
Sol. (C)
Reduction potential of I
2
is less than Cl
2
.
40. While Fe
3+
is stable, Mn
3+
is not stable in acid solution because
(A) O
2
oxidises Mn
2+
to Mn
3+
(B) O
2
oxidises both Mn
2+
and Fe
2+
to Fe
3+
(C) Fe
3+
oxidizes H
2
O to O
2
(D) Mn
3+
oxidises H
2
O to O
2
Sol. (D)
Reaction of Mn
3+
with H
2
O is spontaneous.
41. Sodium fusion extract, obtained from aniline, on treatment with iron (II) sulphate and H
2
SO
4
in presence of air gives a
Prussian blue precipitate. The blue colour is due to the formation of
(A) Fe
4
[Fe(CN)
6
]
3
(B) Fe
3
[Fe(CN)
6
]
2
(C) Fe
4
[Fe(CN)
6
]
2
(D) Fe
3
[Fe(CN)
6
]
3
Sol. (A)
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SECTION – IV
MatrixMatch Type
This section contains 3 questions. Each question contains statements given in two columns which have to be matched. Statements
(A, B, C, D) in ColumnI have to be matched with statements (p, q, r, s) in ColumnII. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are Ap, As, Bq, Br, Cp, Cq and Ds, then the correctly bubbled 4 × 4 matrix should be as follows:
p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
42. Match the reactions in Column I with nature of the reactions/type of the products in Column II. Indicate your answer by
darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS.
Column I Column II
(A) O
2
−
→O
2
+ O
2
2−
(p) redox reaction
(B) CrO
4
2−
+ H
+
→ (q) one of the products has trigonal planar structure
(C) MnO
4
−
+ NO
2
−
+ H
+
→ (r) dimeric bridged tetrahedral metal ion
(D) NO
3
−
+ H
2
SO
4
+ Fe
2+
→ (s) disproportionation
Sol. A – p, s
B –r
C – p, q
D – p
43. Match the compounds/ions in Column I with their properties/reactions in Column II. Indicate your answer by darkening
the appropriate bubbles of the 4 × 4 matrix given in the ORS.
Column I Column II
(A) C
6
H
5
CHO (p) gives precipitate with 2, 4dinitrophenylhydrazine
(B) CH
3
C ≡CH (q) gives precipitate with AgNO
3
(C) CN
−
(r) is a nucleophile
(D) I
−
(s) is involved in cyanohydrin formation
Sol. A – p, q, s
B –q
C – q, r, s
D – q, r
(Note: Assuming AgNO
3
is ammonical.)
(A)
PhCHO+ O
2
N
NO
2
NH NH
2
PhHC N NH NO
2
O
2
N
(ppt.)
( )
3
NH
2
white ppt.
PhCHO Ag O PhCOO Ag
−
+ ÷÷÷→ + ↓
KCN
PhCHO÷÷÷→ Ph C
CN
H
O
(B)
( )
3
ammonical AgNO
3 3
White ppt.
CH C CH CH C C Ag
− +
≡ ÷÷÷÷÷÷÷→ − ≡ ↓
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(C)
KCN
PhCHO÷÷÷→ Ph C
CN
H
O
3
AgNO CN AgCN
−
+ ÷÷→ ↓
(D)
3
AgNO I AgI
−
+ ÷÷→ ↓
44. Match the crystal system/unit cells mentioned in Column I with their characteristic features mentioned in Column II.
Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS.
Column I Column II
(A) Simple cubic and facecentred cubic (p) have these cell parameters
a = b = c and α = β = γ
(B) cubic and rhombohedral (q) are two crystal systems
(C) cubic and tetragonal (r) have only two crystallography angles of 90
o
(D) hexagonal and monoclinic (s) belong to same crystal system
Sol. A – p, s
B –p, q
C – q
D – q, r
Crystals class Axial distances Angles
Cubic a = b = c α = β = γ = 90°
Tetragonal a = b ≠ c α = β = γ = 90°
Orthorhombic a ≠ b ≠ c α = β = γ = 90°
Hexagonal a = b ≠ c
α = β = 90°
γ = 120°
Trigonal and rhombohedral a = b = c α = β = γ ≠ 90°
Monoclinic a ≠ b ≠ c
α = β = 90°
γ ≠ 90°
Triclinic a ≠ b ≠ c α ≠ β ≠ γ ≠ 90°
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PART III (MATHEMATICS)
SECTION – I
Straight Objective Type
This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (D),
out of which only one is correct.
45. Let a, b, c
,
, ,
be unit vectors such that a b c 0 + + =
, ,
, ,
. Which one of the following is correct?
(A) a b b c c a 0 × = × = × =
, , ,
, , , ,
(B) a b b c c a 0 × = × = × ≠
, , ,
, , , ,
(C) a b b c a c 0 × = × = × =
, , ,
, , , ,
(D) a b, b c, c a × × ×
, ,
, , , ,
are mutually perpendicular
Sol. (B)
Since a, b, c
,
, ,
are unit vectors and a b c 0 + + =
,
, ,
,
a, b, c
,
, ,
represent an equilateral triangle.
a b b c c a × = × = ×
, ,
, , , ,
≠ 0.
46. Let
( )
( )
1/ n
n
x
f x
1 x
=
+
for n ≥ 2 and g(x) = ( )
( )
f occurs n times
fofo ... of x
¸¸_¸¸
. Then
( )
n 2
x g x dx
−
∫
equals
(A)
( )
( )
1
1
n
n
1
1 nx K
n n 1
−
+ +
−
(B)
( )
1
1
n
n
1
1 nx K
n 1
−
+ +
−
(C)
( )
( )
1
1
n
n
1
1 nx K
n n 1
+
+ +
+
(D)
( )
1
1
n
n
1
1 nx K
n 1
+
+ +
+
Sol. (A)
Here
n 1/ n n 1/ x
f (x) x
ff (x)
[1 f (x) ] (1 2x )
= =
+ +
n 1/ n
x
fff (x)
(1 3x )
=
+
⇒ g(x) =
n terms
(fofo...of ) (x) =
n 1/ n
x
(1 nx ) +
Hence
n 1
n 2
n 1/ n
x dx
I x g(x)dx
(1 nx )
−
−
= =
+
∫ ∫
=
n
2 n 1
2 n 1/ n 2 n 1/ n
d
(1 nx )
1 n x dx 1
dx
dx
n (1 nx ) n (1 nx )
− +
=
+ +
∫ ∫
∴
1
1
n
n
1
I (1 nx ) k
n(n 1)
−
= + +
−
.
47.
2
2
d x
dy
equals
(A)
1
2
2
d y
dx
−
 

\ .
(B)
1
3
2
2
d y dy
dx dx
−
−
 
 
−
 
\ . \ .
(C)
2
2
2
d y dy
dx dx
−
 
 
 
\ . \ .
(D)
3
2
2
d y dy
dx dx
−
 
 
−
 
\ . \ .
Sol. (D)
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Since,
1
dx 1 dy
dy dy/ dx dx
−
 
= =

\ .
⇒
1
d dx d dy dx
dy dy dx dx dy
−
   
=
 
\ . \ .
⇒
2
2
d x
dy
2
2
2
d y dy dx
dx dy dx
−
     
= −
  

\ . \ . \ .
3
2
2
d y dy
dx dx
−
 
 
= −



\ .
\ .
.
*48. The letters of the word COCHIN are permuted and all the permutations are arranged in an alphabetical order as in an
English dictionary. The number of words that appear before the word COCHIN is
(A) 360 (B) 192
(C) 96 (D) 48
Sol. (C)
COCHIN
The second place can be filled in
4
C
1
ways and the remaining four alphabets can be arranged in 4! ways in four
different places. The next 97
th
word will be COCHIN.
Hence, there are 96 words before COCHIN.
*49. If z = 1 and z ≠ ± 1, then all the values of
2
z
1 z −
lie on
(A) a line not passing through the origin (B) z = 2
(C) the xaxis (D) the yaxis
Sol. (D)
Let z = cosθ + sinθ, so that
2
z cos sin
1 (cos 2 i sin 2 ) 1 z
θ + θ
=
− θ + θ −
2
cos i sin cos i sin
2i sin (cos i sin ) 2sin 2i sin cos
θ + θ θ + θ
= =
− θ θ + θ θ − θ θ
i
2sin
=
θ
Hence
2
z
1 z −
lies on the imaginary axis i.e., x = 0.
Alternative
Let E =
2 2
z z 1
z z 1 z zz z
= =
− − −
which is imaginary.
*50. Let ABCD be a quadrilateral with area 18, with side AB parallel to the side CD and AB = 2CD. Let AD be
perpendicular to AB and CD. If a circle is drawn inside the quadrilateral ABCD touching all the sides, then its radius is
(A) 3 (B) 2
(C) 3/2 (D) 1
Sol. (B)
18 =
1
2
(3α) (2r) ⇒ αr = 6
Line y =
2r
−
α
(x − 2α) is tangent to (x − r)
2
+
(y − r)
2
= r
2
2α = 3r and αr = 6
r = 2.
A B
C
D
(2α, 0)
(α, 2r)
(r, r)
(0, 2r)
(0, 0)
Alternate
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1
(x 2x) 2r 18
2
+ × =
xr = 6 …(1)
x r
tan
r
−
θ = tan(90 − θ) =
2x r
r
−
x r r
r 2x r
−
=
−
x(2x − 3r) = 0
x =
3r
2
…(2)
From (1) and (2)
r = 2.
x − r r
2 r
2x − r
θ
90−θ
2x
x
r
*51. Let O(0, 0), P(3, 4), Q(6, 0) be the vertices of the triangle OPQ. The point R inside the triangle OPQ is such that the
triangles OPR, PQR, OQR are of equal area. The coordinates of R are
(A)
4
, 3
3
 

\ .
(B)
2
3,
3
 

\ .
(C)
4
3,
3
 

\ .
(D)
4 2
,
3 3
 

\ .
Sol. (C)
Since, ∆ is isosceles, hence centroid is the
desired point.
(0, 0) (6, 0)
(3, 4)
52. The differential equation
2
1 y dy
dx y
−
= determines a family of circles with
(A) variable radii and a fixed centre at (0, 1)
(B) variable radii and a fixed centre at (0, −1)
(C) fixed radius 1 and variable centres along the xaxis
(D) fixed radius 1 and variable centres along the yaxis
Sol. (C)
2
1 y dy
dx y
−
=
⇒
2
y
dy dx
1 y
=
−
∫ ∫
⇒
2
1 y x c − − = +
⇒ (x + c)
2
+ y
2
= 1
centre (−c, 0); radius
2 2
c c 1 1 − + = .
53. Let E
c
denote the complement of an event E. Let E, F, G be pairwise independent events with P(G) > 0 and P(E∩F∩G)
= 0. Then P(E
C
∩F
C
 G) equals
(A) P(E
C
) + P(F
C
) (B) P(E
C
) − P(F
C
)
(C) P(E
C
) − P(F) (D) P(E) − P(F
C
)
Sol. (C)
c c c c
E F P(E F G) P(G) P(E G) P(G F)
P
G P(G) P(G)
 
∩ ∩ ∩ − ∩ − ∩
= =


\ .
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P(G)(1 P(E) P(F))
P(G)
− −
= [∵ P(G) ≠ 0]
= 1 − P(E) − P(F)
= P(E
c
) − P(F).
SECTION −II
Assertion − Reason Type
This section contains 4 questions numbered 54 to 57. Each question contains STATEMENT − 1 (Assertion) and STATEMENT 2
(Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
54. Let f(x) = 2 + cosx for all real x.
STATEMENT 1 : For each real t, there exists a point c in [t, t + π] such that f′(c) = 0.
because
STATEMENT 2 : f(t) = f(t + 2π) for each real t.
(A) Statement 1 is True, Statement 2 is True; Statement2 is a correct explanation for Statement1
(B) Statement 1 is True, Statement 2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement 1 is True, Statement 2 is False
(D) Statement 1 is False, Statement 2 is True
Sol. (B)
f(x) = 2 + cosx ∀ x ∈ R
Statement : 1
There exists a point c ∈ [t, t + π] where f′(c) = 0
Hence, statement 1 is true.
Statement 2:
f(t) = f(t + 2π) is true.
But statement 2 is not a correct explanation for statement 1.
55. Consider the planes 3x − 6y − 2z = 15 and 2x + y − 2z = 5.
STATEMENT 1 : The parametric equations of the line of intersection of the given planes are x = 3 + 14t,
y = 1 + 2t, z = 15t
because
STATEMENT 2 : The vectors
ˆ ˆ ˆ
14i 2j 15k + + is parallel to the line of intersection of the given planes.
(A) Statement 1 is True, Statement 2 is True; Statement2 is a correct explanation for Statement1
(B) Statement 1 is True, Statement 2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement 1 is True, Statement 2 is False
(D) Statement 1 is False, Statement 2 is True
Sol. (D)
3x − 6y − 2z = 15
2x + y − 2z = 5
for z = 0, we get x = 3, y = −1
Direction vectors of plane are
< 3 −6 −2 > and <2 1 −2>
then the dr’s of line of intersection of planes is <14 2 15>
x 3 y 1 z 0
14 2 15
− + −
= = = λ
⇒ x = 14λ + 3 y = 2λ − 1 z = 15λ
Hence, statement 1 is false.
But statement 2 is true.
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*56. Lines L
1
: y − x = 0 and L
2
: 2x + y = 0 intersect the line L
3
: y + 2 = 0 at P and Q, respectively. The bisector of the
acute angle between L
1
and L
2
intersects L
3
at R.
STATEMENT 1 : The ratio PR : RQ equals 2 2 : 5 .
because
STATEMENT 2 : In any triangle, bisector of an angle divides the triangle into two similar triangles.
(A) Statement 1 is True, Statement 2 is true; Statement2 is a correct explanation for Statement1
(B) Statement 1 is True, Statement 2 is True; Statement2 is NOT a correct explanation for Statement1
(C) Statement 1 is True, Statement 2 is False
(D) Statement 1 is False, Statement 2 is True
Sol. (C)
In ∆OPQ
Clearly
PR OP 2 2
RQ OQ 5
= =
y = −2
O
P R Q
L
1
L
2
L
3
(−2, −2) (1, −2)
θ/2 θ/2
*57. STATEMENT 1 : The curve y =
2
x
x 1
2
−
+ + is symmetric with respect to the line x = 1.
because
STATEMENT 2 : A parabola is symmetric about its axis.
(A) Statement 1 is True, Statement 2 is true; Statement2 is a correct explanation for Statement1
(B) Statement 1 is True, Statement 2 is true; Statement2 is NOT a correct explanation for Statement1
(C) Statement 1 is True, Statement 2 is False
(D) Statement 1 is False, Statement 2 is True
Sol. (A)
2
x
y x 1
2
= − + +
⇒
2
3 1
y (x 1)
2 2
− = − −
⇒ it is symmetric about x = 1.
SECTION − III
Linked Comprehension Type
This section contains 2 paragraphs M
58−60
and M
61−63
. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choice (A), (B), (C) and (D), out of which ONLY ONE is correct.
M
58−60
: Paragraph for question Nos. 58 to 60
If a continuous f defined on the real line R, assumes positive and negative values in R then the equation f(x) = 0 has a root in R.
For example, if it is known that a continuous function f on R is positive at some point and its minimum values is negative then
the equation f(x) = 0 has a root in R.
Consider f(x) = ke
x
− x for all real x where k is a real constant.
58. The line y = x meets y = ke
x
for k ≤ 0 at
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(A) no point (B) one point
(C) two points (D) more than two points
Sol. (B)
Line y = x intersect the curve y = ke
x
at exactly
one point when k ≤ 0.
x
y
59. The positive value of k for which ke
x
− x = 0 has only one root is
(A) 1/e (B) 1
(C) e (D) log
e
2
Sol. (A)
Let f(x) = ke
x
− x
f′(x) = ke
x
− 1 = 0 ⇒ x = −ln k
f′′(x) = ke
x
f′′(x)
x=−lnk
= 1 > 0
Hence f(−lnk) = 1 + lnk
For one root of given equation
1 + lnk = 0
hence k =
1
e
.
60. For k > 0, the set of all values of k for which k e
x
− x = 0 has two distinct roots is
(A)
1
0,
e
 

\ .
(B)
1
, 1
e
 

\ .
(C)
1
,
e
 
∞

\ .
(D) (0, 1)
Sol. (A)
For two distinct roots 1 + lnk < 0 (k > 0)
lnk < −1
k <
1
e
hence k ∈
1
0,
e
 

\ .
.
M
61−63
: Paragraph for Question Nos. 61 to 63
Let A
1
, G
1
, H
1
denote the arithmetic, geometric and harmonic means, respectively, of two distinct positive numbers. For n ≥ 2,
let A
n−1
and H
n−1
has arithmetic, geometric and harmonic means as A
n
, G
n
, H
n
respectively.
*61. Which one of the following statements is correct?
(A) G
1
> G
2
> G
3
> … (B) G
1
< G
2
< G
3
< …
(C) G
1
= G
2
= G
3
= … (D) G
1
< G
3
< G
5
< … and G
2
> G
4
> G
6
> …
Sol. (C)
1 1 1
a b 2ab
A ; G ab; H
2 a b
+
= = =
+
n 1 n 1 n 1 n 1
n n n 1 n 1 n
n 1 n 1
A H 2A H
A , G A H , H
2 A H
− − − −
− −
− −
+
= = =
+
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Clearly, G
1
= G
2
= G
3
= … = ab .
*62. Which of the following statements is correct?
(A) A
1
> A
2
> A
3
> … (B) A
1
< A
2
< A
3
< …
(C) A
1
> A
3
> A
5
> … and A
2
< A
4
< A
6
< … (D) A
1
< A
3
< A
5
< … and A
2
> A
4
> A
6
> …
Sol. (A)
A
2
is A.M. of A
1
and H
1
and A
1
> H
1
⇒ A
1
> A
2
> H
1
A
3
is A.M. of A
2
and H
2
and A
2
> H
2
⇒ A
2
> A
3
> H
2
∴ A
1
> A
2
> A
3
> …
*63. Which of the following statements is correct?
(A) H
1
> H
2
> H
3
> … (B) H
1
< H
2
< H
3
< …
(C) H
1
> H
3
> H
5
> … and H
2
< H
4
< H
6
< … (D) H
1
< H
3
< H
5
< … and H
2
> H
4
> H
6
> …
Sol. (B)
As above A
1
> H
2
> H
1
, A
2
> H
3
> H
2
∴ H
1
< H
2
< H
3
< …
SECTION −IV
Matrix − Match Type
This section contains 3 questions. Each question contains statements given in two columns which have to be matched. Statements
(A, B, C, D) in Column I have to be matched with statements (p, q, r, s) in Column II. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are A−p, A−s, B−q, B−r, C−p, C−q and D−s, then the correctly bubbled 4 × 4 matrix should be as follows:
p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
64. Let f(x) =
2
2
x 6x 5
x 5x 6
− +
− +
.
Match the conditions / expressions in Column I with statements in Column II and indicate your answers by darkening
the appropriate bubbles in 4 × 4 matrix given in the ORS.
Column I Column II
(A) If −1 < x < 1, then f(x) satisfies (p) 0 < f(x) < 1
(B) If 1 < x < 2, then f(x) satisfies (q) f(x) < 0
(C) If 3 < x < 5, then f(x) satisfies (r) f(x) > 0
(D) If x > 5, then f(x) satisfies (s) f(x) < 1
Sol. A → p, r, s ; B → q, s ; C → q, s ; D → p, r, s
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(x 1)(x 5)
f (x)
(x 2)(x 3)
− −
=
− −
The graph of f(x) is shown
(A) If −1 < x < 1
⇒ 0 < f(x) < 1
(B) If 1 < x < 2 ⇒ f(x) < 0
(C) If 3 < × < 5 ⇒ f(x) < 0
(D) If x > 5 ⇒ 0 < f(x) < 1
y = 1
x
y
1 2 3 5
*65. Let (x, y) be such that
sin
−1
(ax) + cos
−1
(y) + cos
−1
(bxy) =
2
π
.
Match the statements in Column I with the statements in Column II and indicate your answer by darkening the
appropriate bubbles in the 4 × 4 matrix given in the ORS.
Column I Column II
(A) If a = 1 and b = 0, then (x, y) (p) lies on the circle x
2
+ y
2
= 1
(B) If a = 1 and b = 1, then (x, y) (q) lies on (x
2
− 1) (y
2
− 1) = 0
(C) If a = 1 and b = 2, then (x, y) (r) lies on y = x
(D) If a = 2 and b = 2, then (x, y) (s) lies on (4x
2
− 1) (y
2
− 1) = 0
Sol. A → p ; B → q ; C → p ; D → s
(A) If a = 1, b = 0
then sin
−1
x + cos
−1
y = 0
⇒ sin
−1
x = −cos
−1
y
⇒ x
2
+ y
2
= 1.
(B) If a = 1 and b = 1, then
sin
−1
x + cos
−1
y + cos
−1
xy =
2
π
⇒ cos
−1
x − cos
−1
y =cos
−1
xy
⇒
2 2
xy 1 x 1 y xy + − − = (taking sine on both the sides)
(C) If a = 1, b = 2
⇒ sin
−1
x + cos
−1
y + cos
−1
(2xy) =
2
π
⇒ sin
−1
x + cos
−1
y = sin
−1
(2xy)
⇒
2 2
xy 1 x 1 y 2xy + − − =
⇒ x
2
+ y
2
= 1 (on squaring).
(D) If a = 2 and b = 2 then
sin
−1
(2x) + cos
−1
(y) + cos
−1
(2xy) =
2
π
⇒ 2xy +
2 2
1 4x 1 y 2xy − − =
⇒ (4x
2
− 1) (y
2
− 1) = 0.
*66. Match the statements in Column I with the properties Column II and indicate your answer by darkening the
appropriate bubbles in the 4 × 4 matrix given in the ORS.
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Column I Column II
(A) Two intersecting circles (p) have a common tangent
(B) Two mutually external circles (q) have a common normal
(C) two circles, one strictly inside the other (r) do not have a common tangent
(D) two branches of a hyperbola (s) do not have a common normal
Sol. A → p, q ; B → p, q ; C → q, r ; D → q, r
(A) When two circles are intersecting they have a common normal and common tangent.
(B) Two mutually external circles have a common normal and common tangent.
(C) When one circle lies inside of other then, they have a common normal but no common tangent.
(D) Two branches of a hyperbola have a common normal but no common tangent.
IITJEE2007PAPER22
2.
A magnetic field B = B0 ˆ exists in the region a < x < 2a and j
B0
B = − B0 ˆ , in the region 2a < x < 3a, where B0 is a positive constant. A j positive point charge moving with a velocity v = v ˆ , where v0 is a i
0
0 −B0
a
2a
3a
x
positive constant, enters the magnetic field at x = a. The trajectory of the charge in this region can be like, (A)
z
(B)
z a 2a 3a x
a
2a
3a
x
(C)
z
(D)
z a 2a 3a x
a
2a
3a
x
Sol.
(A) for a < x < 2a 2a < x < 3a
path will be concave upward path will be concave downward
3.
A small object of uniform density rolls up a curved surface with an initial velocity v. It reaches up to a maximum height of object is (A) ring (C) hollow sphere
3v 2 with respect to the initial position. The 4g
v
(B) solid sphere (D) disc
2
Sol.
(D)
3v 2 1 1 v mv 2 + Icm = mg 2 2 R 4g
Hence Icm = 4.
1 mR 2 2
Electrons with deBroglie wavelength λ fall on the target in an Xray tube. The cutoff wavelength of the emitted Xrays is
2mcλ 2 h 2m 2 c2 λ 3 (C) λ 0 = h2
(A) λ 0 = Sol. (A)
(B) λ 0 =
2h mc
(D) λ 0 = λ
λ=
λ0 =
h 2m(eV)
hC eV
⇒ eV =
h2 2mλ 2
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In the experiment to determine the speed of sound using a resonance column.8 m/s2 (exact). 0) +q a/2 (0. by Searle’s method. 0.110016. 0) −q a/2 x 7.01 mm. 0.IITJEE2007PAPER23 5.1) × 10 N/m (D) (2 . 4F πd 2 ∆ ∆Y 2∆D ∆ (L) = + = 0. The work 2 2 done by the electric field when another positive point charge is moved from (−a. In a particular reading. New Delhi . Ph : 26515949. 26569493. Consider a vertical section ABCD of the water column through a diameter of the beaker.8 mm with an uncertainty of ±0. 0.3) × 1011 N/m2 11 2 (C) (2 . a.05 mm at a load of exactly 1. respectively. The density of water is ρ. the surface tension of water is T and the atmospheric pressure is P0. . The student also measures the diameter of the wire to be 0.1125 ∆L Y D Positive and negative point charges of equal magnitude are kept at 0. the length of the resonating air column is close to half of the wavelength of sound in air (A) Water is filled up to a height h in a beaker of radius R as shown in the figure.4 mm with an uncertainty of ±0. the length of the resonating air column is close to the wavelength of sound in air (D) in one of the two resonances observed.0 kg. a. 0. A student performs an experiment to determine the Young’s modulus of a wire. Fax : 26513942 . (C) y B A (−a.1125 6.0 ± 0. 0) is (A) positive (B) negative (C) zero (D) depends on the path connecting the initial and final positions Sol. a −a and 0. Kalu Sarai. 2R B A C h D (D) P0 πR 2 + Rρgh 2 + 2RT FIITJEE Ltd.2) × 1011 N/m2 (A) (2 .0 ± 0. Sarvapriya Vihar. the student measures the extension in the length of the wire to be 0. ICES House.0 ± 0. 0) to (0. 29A. The force on water on one side of this section by water on the other side of this section has magnitude (A) 2P0 Rh + πR 2 ρgh − 2RT (B) 2P0 Rh + Rρgh 2 − 2RT 2 2 (C) P0 πR + Rρgh − 2RT Sol. Take g = 9. Y= ∆Y = 2 × 1011 × 0.0 ± 0.05) × 1011 N/m2 (B) Sol. 8. The Young’s modulus obtained from the reading is (B) (2 . (A) prongs of the tuning fork are kept in a vertical plane (B) prongs of the tuning fork are kept in a horizontal plane (C) in one of the two resonances observed. exactly 2 m long.
11.Reason Type This section contains 4 questions numbered 10 to 13. (B) ∫ (P 0 h 2TR 0 + ρgx)2Rdx − 2RT = F (P0+ρgx)2Rdx x dx 2P0Rh + Rρgh2 − 2RT = F 9. a current is induced in the ring which interacts with the horizontal component of the magnetic field to produce an average force in the upward direction. Statement2 is True. Fax : 26513942 . FIITJEE Ltd. (D) Statement 1 is False. (D) (B) 30° (D) 90° F= dP = AK −ˆ sin(kt) − ˆ jcos(kt) i dt F⋅P = 0 SECTION – II Assertion . (C) and (D) out of which ONLY ONE is correct. Statement2 is True. A particle moves in the XY plane under the influence of a force such that its linear momentum is p(t) = A ˆ cos(kt) − ˆ jsin(kt) . 10. The rod goes through a conducting ring as shown in the figure. Statement2 is True. (A) Statement 1 is True. Statement 2 is a correct explanation for Statement1. 29A.IITJEE2007PAPER24 Sol. (A) STATEMENT1 If there is no external torque on a body about its center of mass. The angle between the force and the momentum is i (A) 0° (C) 45° Sol. Each question contains STATEMENT1 (Assertion) and STATEMENT2 (Reason). where A and k are constants. Because STATEMENT2 In the above situation. Statement 2 is NOT a correct explanation for Statement1. (B) Statement 1 is True. New Delhi . (B). STATEMENT1 A vertical iron rod has a coil of wire wound over it at the bottom end. Kalu Sarai. The ring can float at a certain height above the coil. Each question has 4 choices (A). ICES House.110016. Statement2 is True. Sarvapriya Vihar. (C) Statement 1 is True. (A) Statement 1 is True. Ph : 26515949. Statement 2 is a correct explanation for Statement1. An alternating current flows in the coil. because STATEMENT2 The linear momentum of an isolated system remains constant. then the velocity of the center of mass remains constant. Statement2 is False. Sol. 26569493.
(B) STATEMENT1 A cloth covers a table. (B). Sol. (C) and (D). The cloth can be pulled out without dislodging the dishes from the table. Statement 2 is a correct explanation for Statement1. out of which ONLY ONE is correct. ICES House. Statement 2 is NOT a correct explanation for Statement1. (D) Statement 1 is False. The lines ab and cd represent wavefronts of a light wave travelling in medium1 and incident on XY. (D) STATEMENT1 The total translational kinetic energy of all the molecules of a given mass of an ideal gas is 1. 29A. because STATEMENT2 The molecules of a gas collide with each other and the velocities of the molecules change due to the collision. Statement2 is False. Sol. Statement2 is False. Light travels as a (A) parallel beam in each medium (B) convergent beam in each medium FIITJEE Ltd. Statement2 is True. Each question has 4 choices (A). Statement2 is True. 13. (B) Statement 1 is True. (B) SECTION – III Linked Comprehension Type This section contains 2 paragraphs P1416 and P1719. Some dishes are kept on it. Statement 2 is NOT a correct explanation for Statement1. Based upon each paragraph. (C) Statement 1 is True. Ph : 26515949. Statement 2 is NOT a correct explanation for Statement1.5 times the product of its pressure and its volume. Statement2 is True. Sarvapriya Vihar. 14 to 16 The figure shows a surface XY separating two transparent media.110016. New Delhi . (B) Statement 1 is True. (D) Statement 1 is False. Sol. (C) Statement 1 is True. (D) Statement 1 is False. (A) Statement 1 is True. Statement 2 is a correct explanation for Statement1. medium – 1 and medium 2. Statement2 is True. X a c f h b d Medium1 Y Medium2 e g 14. Statement2 is True. because STATEMENT2 For every action there is an equal and opposite reaction. 12. Kalu Sarai. Statement2 is False. P14 – 16 : Paragraph for Question Nos. The lines ef and gh represent wavefronts of the light wave in medium2 after refraction.IITJEE2007PAPER25 (B) Statement 1 is True. 3 multiple choice questions have to be answered. 26569493. (A) Statement 1 is True. Statement2 is True. Statement2 is True. Fax : 26513942 . Statement2 is True. (C) Statement 1 is True.
The engines are at the front ends. The engine of train A blows a long whistle. New Delhi . e and f are φc. Kalu Sarai. (A) FIITJEE Ltd. d i c r e g Medium 2 f h Medium 1 15. The distribution of the sound intensity of the whistle as observed by the passengers in train A is best represented by Intensity (A) (B) f1 f2 Frequency Intensity f1 Intensity f2 Frequency (C) Intensity (D) f1 f2 Frequency f1 f2 Frequency Sol. 29A. 26569493. (B) larger in medium1 than in medium2 (D) different at b and d Sol. Two trains A and B are moving with speeds 20 m/s and 30 m/s respectively in the same direction on the same straight track. 18. Sarvapriya Vihar.φe) (C) Speed of the light is (A) the same in medium1 and medium2 (C) larger in medium2 than in medium1 (B) P17 – 19 : Paragraph for Question Nos. φd. f2 Frequency Sol. 17. The speed of sound in still air is 340 m/s.110016. Fax : 26513942 . 16. The speed of sound of the whistle is (A) 340 m/s for passengers in A and 310 m/s for passengers in B (B) 360 m/s for passengers in A and 310 m/s for passengers in B (C) 310 m/s for passengers in A and 360 m/s for passengers in B (D) 340 m/s for passengers in both the trains (B) Speed of sound is frame dependent.IITJEE2007PAPER26 (C) divergent beam in each medium Sol. d. as shown in the figure. (A) a b (D) divergent beam in one medium and convergent beam in the other medium. The spread in the frequency (highest frequency − lowest frequency) is thus 320 Hz. It is given that φc ≠ φf (B) φd can be equal to φe (A) φc cannot be equal to φd (D) (φd − φc) is not equal to (φf − φe) (C) (φd − φf) is equal to (φc . φe and φf respectively. ICES House. Assume that the sound of the whistle is composed of components varying in frequency from f1 = 800 Hz to f2 = 1120 Hz. Ph : 26515949. 17 to 19 Intensity f1 Sol. with B ahead of A. The phases of the light wave at c.
q. A→ (p). Match the statements in Column I with the statements in Column II and indicate your answer by darkening appropriate bubbles in the 4 × 4 matrix given in the ORS.IITJEE2007PAPER27 19. where. Cp. Sarvapriya Vihar. Statements (A. B. Kalu Sarai. s) in column II. FIITJEE Ltd. C. Cq and Ds. r. (D) The object is projected from the earth’s surface vertically upwards with a speed 2 GM e R e . a simple where c1 and c2 are positive constants. (C) The object is attached to one end of a massless spring of a given spring constant. Each question contains statements given in two columns which have to be matched. D) in column I have to be matched with statements (p. (q) The object does not change its direction. Column I (A) The object moves on the xaxis under a conservative force in such a way that its “speed” and “position” satisfy v = c1 c2 − x .110016. Match the situation in Column I with the characteristics in Column II and indicate your answer by darkening appropriate bubbles in the 4 × 4 matrix given in the ORS. (r) The kinetic energy of the object keeps on decreasing. Sol. D → (r) & (q) Two wires each carrying a steady current I are shown in four configurations in Column I. The motion of the object is observed from the elevator during the period it maintains this acceleration. The spread of frequency as observed by the passengers in train B is (A) 310 Hz (B) 330 Hz (C) 350 Hz (D) 290 Hz (A) SECTION – IV MatrixMatch Type Sol. C → (p). Column II describes some characteristics of these motions. If the correct matches are Ap. Fax : 26513942 . 26569493. (B) The object moves on the xaxis in such a way that its velocity and its displacement from the origin satisfy v = −kx. B → (q) & (r). Initially everything is at rest. The answers to these questions have to be appropriately bubbled as illustrated in the following example. The elevator starts going upwards with a constant acceleration a. Me is the mass of the earth and Re is the radius of the earth. 29A. Bq. where k is a positive constant. Br. As. Ph : 26515949. Some of the resulting effects are described in Column II. ICES House. (s) The object can change its direction only once. 2 Column II (p) The object executes harmonic motion. Neglect forces from objects other than the earth. New Delhi . This section contains 3 questions. Column I describe some situations in which a small object moves. The other end of the spring is attached to the ceiling of an elevator. Column I Column II 21. then the correctly bubbled 4 × 4 matrix should be as follows: p A B C D p p p p q q q q q r r r r r s s s s s 20.
New Delhi . ICES House. P (C) Point P is situated at the midpoint of the line joining the centers of the circular wires.110016. Fax : 26513942 . C → (p). P (r) There is no magnetic field at P. Sol. P (p) The magnetic fields (B) at P due to the currents in the wires are in the same direction. D → (r) FIITJEE Ltd. which have same radii. (s) P The wires repel each other. Match the devices in Column I with the processes in Column II and indicate your answer by darkening appropriate bubbles in the 4 × 4 matrix given in the ORS. Sarvapriya Vihar. B → (q). B → (p). A→ (s). D → (q) Column I gives some devices and Column II gives some process on which the functioning of these devices depend. which have same radii. 29A. 26569493. Kalu Sarai.IITJEE2007PAPER28 (A) Point P is situated midway between the wires. (A) Bimetallic strip (B) Steam engine (C) Incandescent lamp (D) Electric fuse (p) Radiation from a hot body (q) Energy conversion (r) Melting (s) Thermal expansion of solids Sol. (B) Point P is situated at the midpoint of the line joining the centers of the circular wires. (q) The magnetic fields (B) at P due to the currents in the wires are in opposite directions. (D) Point P is situated at the common center of the wires. A→ (q) & (r). Ph : 26515949. C → (q) & (r). Column I Column II 22.
Compound F is FIITJEE Ltd. ∆S = + ve (A) (1 bar.110016. Fax : 26513942 . 23. Each question has 4 choices (A). ICES House. ∆S = 0 (D) ∆G = − ve. Among the following. 373 K). Ph : 26515949.II (CHEMISTRY) SECTION – I Straight Objective Type This section contains 9 multiple choice questions numbered 23 to 31. out of which ONLY ONE is correct. the least stable resonance structure is (B) (A) O O N O N O (C) O N O (D) O N O Sol.373 K ) Sol. 29A. 373 K) → H2O(g) (1 bar.IITJEE2007PAPER29 PART. Because liquid molecules are converting into gases molecules therefore ∆S = +ve Hence (A) is correct. Cyclohexene on ozonolysis followed by reaction with zinc dust and water gives compound E. Kalu Sarai. (A) (A) N O (B) O Same charges are present at nearest position (Less stable) N O (C) O N O (D) O N O Hence (A) is correct O 24. 25. the correct set of thermodynamic parameters is (A) ∆G = 0. Sarvapriya Vihar. ∆S = + ve (B) ∆G = 0. H 2O ( ) (1 bar. (C) and (D). For the process H2O(l) (1 bar. 26569493. New Delhi . 373K ) H 2O ( g ) At 100°C H 2O ( ) has equilibrium with H2O(g) therefore ∆G = 0. Compound E on further treatment with aqueous KOH yields compound F. ∆S = − ve (C) ∆G = + ve. (B).
29A. Consider a reaction aG + bH → Products. the rate increases by eight times. The overall order of the reaction is (A) 0 (B) 1 (C) 2 (D) 3 (D) aG + bH → Product a b rate ∝ [G] [H] a = 1. 28.110016. A positron is emitted from (A) 22/10 (C) 23/10 23 Na11 . (B) Fe0 = 3d64s2 in presence of CO effective configuration = 3d8 four lone pair for back bonding with CO. Kalu Sarai. New Delhi . FIITJEE Ltd. Atomic mass 23 = atomic number 10 Hence (C) is correct. H 2 O → Zn CHO (E) KOH → ( aldol condensation ) CHO (F) Hence (A) is correct. Among the following metal carbonyls. (C) Cr0 = 3d54s1 6 Effective configuration = 3d . Maximum back bonding is present in Fe(CO)5 there for CO bond order is lowest here. (A) CHO O3 . Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenylamine as indicator. When concentration of both the reactants G and H is doubled. Fax : 26513942 . the C – O bond order is lowest in (A) [Mn(CO)6]+ (B) [Fe(CO)5] (C) [Cr(CO)6] (D) [V(CO)6](B) (A) Mn+ = 3d54s1 in presence of CO effective configuration = 3d64s0. Three lone pair for back bonding with CO. proton converts into neutron therefore atomic number decreases by one but atomic mass remains constant. 27. The number of moles of Mohr’s salt required per mole of dichromate is (A) 3 (B) 4 (C) 5 (D) 6 (D) Sol. 26569493. (C) On position emission from nucleus. (D) V− = 3d44s2 effective configuration = 3d6 three lone pair for back bonding with CO. The ratio of the atomic mass and atomic number of the resulting nuclide is (B) 22/11 (D) 23/12 Sol. 29. ICES House. Three lone pair for back bonding with vacant orbital of C in CO. b = 2 Hence (D) is correct Sol. when concentration of G is doubled keeping the concentration of H fixed. Ph : 26515949. 26. Sol. However. Sarvapriya Vihar.IITJEE2007PAPER210 (A) CHO (B) CHO (C) COOH (D) CO2 H CO2 H Sol. the rate is doubled.
Statement2 is False (D) Statement1 is False. Statement2 is True. Statement2 is True (B) Blue colour is due to solvated electrons. New Delhi . Statement2 is a correct explanation for Statement1 (B) Statement1 is True. Hence (D) is correct. Sol. (C) and (D) out of which ONLY ONE is correct. because STATEMENT2: The energy spread of each germanium atomic energy level is infinitesimally small. Statement2 is NOT a correct explanation for Statement1 (C) Statement1 is True. the solution of metal ion on treatment with a solution of cobalt(II) thiocyanate gives rise to a deep blue crystalline precipitate. Ph : 26515949. Statement2 is True. Statement2 is False (D) Statement1 is False. Statement2 is True.) → HgI 2 + KI K 2 HgI 4 → ( excess ) So lub le Sol. H C C 2 → Meso product ( Anti addition ) Br H CH3 Hence (A) is correct.110016. Sarvapriya Vihar. Each question has 4 choices (A). Statement2 is NOT a correct explanation for Statement1 (C) Statement1 is True. Statement2 is True. ICES House. (B). Sol. The number of stereoisomers obtained by bromination of trans2butene is (A) 1 (B) 2 (C) 3 (D) 4 (A) H3C Sol. Each question contains STATEMENT1 (Assertion) and STATEMENT2 (Reason). 26569493. 34. 33. STATEMENT1: Molecules that are not superimposable on their mirror images are chiral because STATEMENT2: All chiral molecules have chiral centres. 29A. (A) Statement1 is True. Kalu Sarai. STATEMENT1: Band gap in germanium is small. 31. (A) Statement1 is True. HgI 2+ + Co ( SCN )2 → 2 blue crystalline precipiates Hg ( SCN ) SECTION – II Assertion – Reason Type This section 4 questions numbered 32 to 35. FIITJEE Ltd. Fax : 26513942 . Moreover. A solution of metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution. Statement2 is a correct explanation for Statement1 (B) Statement1 is True. Statement2 is True (C) STATEMENT1: Alkali metals dissolves in liquid ammonia to give blue solution because STATEMENT2: Alkali metals in liquid ammonia give solvated species of the type [M(NH3)n]+ (M = alkali metals). 30. 32. The metal ion is (B) Hg2+ (A) Pb2+ (D) Co2+ (C) Cu2+ (B) Hg 2 + + KI HgI2 ( Red ppt.IITJEE2007PAPER211 2 Cr2O7 − + Fe2 + Fe3+ + Cr 3+ → 2 n factor of Cr2 O 7 − = 6 2+ n factor of Fe = 1 2+ So to reduce one mole of dichromate 6 moles of Fe are required.
Ph : 26515949. on to the aromatic ring of phenol. 26569493. Statement2 is a correct explanation for Statement1 Statement1 is True. Kalu Sarai. Each question has 4 choices (A). OH O Na OH CHO aq. NaOH + CHCl3 (C) OH aq + CHCl3 CCl3 + H 2O CCl3 Cl + : CCl2 → dichlorocarbene intermediate 37. Statement2 is True. Statement2 is False Statement1 is False. Sarvapriya Vihar. NaOH + CH2Cl2 (A) aq. (A) Statement1 is True. Sol.HCl CHO [I] CH3 (I) 36. Based upon each paragraph. (C) and (D). NaOH + CCl4 (C) aq. New Delhi . STATEMENT1: Glucose gives a reddishbrown precipitate with Fehling’s solution. Statement2 is NOT a correct explanation for Statement1 (C) Statement1 is True. Fax : 26513942 . Statement2 is True. because STATEMENT2: Reaction of glucose with Fehling’s solution gives CuO and gluconic acid. NaOH + CH3Cl (D) aq. Statement2 is True. 3 multiple choice questions have to be answered.) − SECTION – III Linked Comprehension Type This section contains 2 paragraphs C3638 and C3941. ICES House. Statement2 is a correct explanation for Statement1 (B) Statement1 is True. Statement2 is True. The structure of the intermediate I is FIITJEE Ltd.110016. (A) (B) (C) (D) (C) Statement1 is True. 29A. Statement2 is True (C) C6 H12O 6 + Fehling solution ( C6 H11O 7 ) + Cu 2O ↓ → ( Re d ppt.CCl3 CCl3 Cl + : CCl2 → dichlorocarbene intermediate 38. This reaction involves electrophilic aromatic substitution. Sol. Statement2 is True 35. ortho to the hydroxyl group. Statement2 is NOT a correct explanation for Statement1 Statement1 is True. The electrophile in this reaction is (A) : CHCl (C) :CCl2 (C) OH aq + CHCl3 CCl3 + H 2O (B) +CHCl2 (D) . C3638 : Paragraph for question Nos 36 to 38 ReimerTiemann reaction introduces an aldehyde group. Statement2 is False (D) Statement1 is False.IITJEE2007PAPER212 Sol. out of which ONLY ONE is correct. This is a general method for the synthesis of substituted salicyladehydes as depicted below. (B). CH3 CH3 (II) (III) Which one of the following reagents is used in the above reaction? (B) aq. Sol.
(B) CH3 O CHCl2 O CCl2 CH3 CH3 C3941 : Paragraph for question Nos 39 to 41 Redox reactions play a pivotal role in chemistry and biology.23 O2 + 4H + 4e → 2H2O 39. Ph : 26515949. on treatment with iron (II) sulphate and H2SO4 in presence of air gives a Prussian blue precipitate.→ 2IEo = 0.110016.77 + Eo = 1. Fax : 26513942 . Sodium fusion extract.IITJEE2007PAPER213 (A) O Na CH2 Cl (B) O Na CHCl2 CH3 (C) CH3 (D) O Na CCl3 O Na CH2 OH CH3 Sol. 29A. ICES House. New Delhi . Kalu Sarai. Mn3+ is not stable in acid solution because (A) O2 oxidises Mn2+ to Mn3+ (B) O2 oxidises both Mn2+ and Fe2+ to Fe3+ 3+ (C) Fe oxidizes H2O to O2 (D) Mn3+ oxidises H2O to O2 (D) Reaction of Mn3+ with H2O is spontaneous. FIITJEE Ltd.50 Mn3+ + e. 26569493. While Fe3+ is stable.36 Eo = 1.→ Mn2+ 3+ 2+ Fe + e → Fe Eo = 0. Sol. Sol. Sarvapriya Vihar. The blue colour is due to the formation of (B) Fe3[Fe(CN)6]2 (A) Fe4[Fe(CN)6]3 (D) Fe3[Fe(CN)6]3 (C) Fe4[Fe(CN)6]2 (A) 41. A simple example is a Daniel cell in which zinc goes into solution and copper gets deposited. Sol. Among the following.54 Cl2 + 2e.→ 2ClEo = 1. Using this data obtain the correct explanations to Questions 3941. obtained from aniline. identify the correct statement. The values of standard redox potential (Eo) of two halfcell reactions decide which way the reaction is expected to proceed. I2 + 2e. (A) Chloride ion is oxidized by O2 (C) Iodide ion is oxidized by chlorine (C) Reduction potential of I2 is less than Cl2. Given below are a set of halfcell reactions (acidic medium) along with their Eo (V with respect to normal hydrogen electrode) values. (B) Fe2+ is oxidized by iodine (D) Mn2+ is oxidized by chlorine 40.
s B –r C – p. If the correct matches are Ap. D) in ColumnI have to be matched with statements (p. Column I Column II (A) C6H5CHO (p) gives precipitate with 2. Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS. As. r. Sol.) NH NO2 3 PhCHO + Ag 2O PhCOO − + Ag ↓ → ( white ppt. s B –q C – q. s D – q. Sarvapriya Vihar. C. q. Bq. Match the reactions in Column I with nature of the reactions/type of the products in Column II.IITJEE2007PAPER214 SECTION – IV MatrixMatch Type This section contains 3 questions. r. Ph : 26515949. Column I Column II (A) O2− → O2 + O22− (p) redox reaction (B) CrO42− + H+ → (q) one of the products has trigonal planar structure (C) MnO4− + NO2− + H+ → (r) dimeric bridged tetrahedral metal ion (D) NO3− + H2SO4 + Fe2+ → (s) disproportionation A – p. New Delhi . r r r r s s s s q q q Sol. Each question contains statements given in two columns which have to be matched. r (Note: Assuming AgNO3 is ammonical. 26569493. Br.) (A) NO2 O2 N PhCHO + O2 N NH 43.) CN KCN PhCHO Ph → C H O (B) CH 3C ≡ CH CH 3 − C ≡ C − Ag + ↓ → ammonical AgNO3 ( White ppt. Cq and Ds. Fax : 26513942 . The answers to these questions have to be appropriately bubbled as illustrated in the following example. ICES House.110016. Statements (A. Cp. Kalu Sarai. q D–p Match the compounds/ions in Column I with their properties/reactions in Column II. then the correctly bubbled 4 × 4 matrix should be as follows: p q q r s A p B p C p D p 42. s) in ColumnII. 4dinitrophenylhydrazine (B) CH3C ≡ CH (q) gives precipitate with AgNO3 (C) CN− (r) is a nucleophile (D) I− (s) is involved in cyanohydrin formation A – p. B.) FIITJEE Ltd. q. 29A. NH NH2 PhHC N (ppt. Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS.
110016.IITJEE2007PAPER215 (C) KCN PhCHO Ph → CN C H AgNO3 + CN − AgCN ↓ → O (D) AgNO3 + I− AgI ↓ → 44. 26569493. Sarvapriya Vihar. q C–q D – q. Kalu Sarai. s B –p. ICES House. Match the crystal system/unit cells mentioned in Column I with their characteristic features mentioned in Column II. Ph : 26515949. 29A. r Crystals class Axial distances Angles Cubic Tetragonal Orthorhombic Hexagonal Trigonal and rhombohedral Monoclinic Triclinic a=b=c a=b≠c a≠b≠c a=b≠c a=b=c a≠b≠c a≠b≠c α = β = γ = 90° α = β = γ = 90° α = β = γ = 90° α = β = 90° γ = 120° α = β = γ ≠ 90° α = β = 90° γ ≠ 90° α ≠ β ≠ γ ≠ 90° FIITJEE Ltd. New Delhi . Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS. Sol. Fax : 26513942 . Column I Column II (A) Simple cubic and facecentred cubic (p) have these cell parameters a = b = c and α = β = γ (B) cubic and rhombohedral (q) are two crystal systems (C) cubic and tetragonal (r) have only two crystallography angles of 90o (D) hexagonal and monoclinic (s) belong to same crystal system A – p.
Fax : 26513942 . Which one of the following is correct? (A) a × b = b × c = c × a = 0 (C) a × b = b × c = a × c = 0 (B) a × b = b × c = c × a ≠ 0 (D) a × b. of ) ( x ) .110016. a.. c are unit vectors and a + b + c = 0 . (B) Since a. out of which only one is correct. Each question has 4 choices (A). b. a × b = b × c = c × a ≠ 0. n(n − 1) 1 47.III (MATHEMATICS) SECTION – I Straight Objective Type This section contains 9 multiple choice questions numbered 1 to 9. c × a are mutually perpendicular Sol.. b. 46. New Delhi . Ph : 26515949. 29A. b. (C) and (D). Kalu Sarai. ICES House. Let a.IITJEE2007PAPER216 PART. (D) FIITJEE Ltd. c be unit vectors such that a + b + c = 0 .of ) (x) = x (1 + nx n )1/ n Hence I = ∫ x n − 2g(x)dx = ∫ x n −1dx (1 + nx n )1/ n d (1 + nx n ) 1 n 2 x n −1dx 1 dx = 2∫ = 2∫ dx n (1 + nx n )1/ n n (1 + nx n )1/ n ∴ I= 1− 1 (1 + nx n ) n + k . 45. b × c. c represent an equilateral triangle.. Let f ( x ) = x (1 + x n )1/ n for n ≥ 2 and g(x) = ( fofo . Then f occurs n times 1 ∫x n −2 g ( x )dx equals (A) (C) Sol. (A) 1 (1 + nx n )1− n + K ( n − 1) n (B) 1− 1 ( 1 + nx n ) n + K n −1 1 1 (1 + nx n )1+ n + K ( n + 1) n 1 (D) 1+ 1 ( 1 + nx n ) n + K n +1 1 Here ff (x) = fff (x) = f (x) x = [1 + f (x) n ]1/ n (1 + 2x n )1/ x x (1 + 3x n )1/ n n terms ⇒ g(x) = (fofo. 26569493.. d2x equals dy 2 d2y (A) 2 dx −1 d 2 y dy −3 (B) − 2 dx dx d 2 y dy −3 (D) − 2 dx dx −1 d 2 y dy −2 (C) 2 dx dx Sol. (B). Sarvapriya Vihar.
110016. Ph : 26515949. 0) Alternate FIITJEE Ltd. there are 96 words before COCHIN. The next 97th word will be COCHIN. so that z cos θ + sin θ = 1 − z 2 1 − (cos 2θ + isin 2θ) = = cos θ + isin θ cos θ + isin θ = 2sin 2 θ − 2isin θ cos θ −2isin θ(cos θ + isin θ) i 2sin θ z lies on the imaginary axis i. 2r) D C (α. 2r) (r. 0) A B (2α.. New Delhi . ICES House. Hence. then all the values of (A) a line not passing through the origin (C) the xaxis z lie on 1 − z2 (B) z = 2 (D) the yaxis Sol. The number of words that appear before the word COCHIN is (A) 360 (B) 192 (C) 96 (D) 48 (C) COCHIN The second place can be filled in 4C1 ways and the remaining four alphabets can be arranged in 4! ways in four different places. Sol. Let ABCD be a quadrilateral with area 18. 18 = (0. 1 − z2 Alternative z z 1 Let E = = = 2 2 z−z 1− z zz − z which is imaginary. Sol. Sarvapriya Vihar. Hence *50. ⇒ ⇒ *48. 26569493.e. (D) Let z = cosθ + sinθ. r) (0. Fax : 26513942 . dx dx dx dx dy2 dy The letters of the word COCHIN are permuted and all the permutations are arranged in an alphabetical order as in an English dictionary. x = 0. Kalu Sarai. with side AB parallel to the side CD and AB = 2CD.IITJEE2007PAPER217 Since. If z = 1 and z ≠ ± 1. then its radius is (A) 3 (B) 2 (C) 3/2 (D) 1 (B) 1 (3α) (2r) ⇒ αr = 6 2 2r Line y = − (x − 2α) is tangent to (x − r)2 + α (y − r)2 = r2 2α = 3r and αr = 6 r = 2. If a circle is drawn inside the quadrilateral ABCD touching all the sides. dx 1 dy = = dy dy / dx dx −1 −1 d dx d dy dx = dy dy dx dx dy d 2 y dy −2 dx d 2 y dy −3 d2x = − 2 = − 2 . Let AD be perpendicular to AB and CD. *49. 29A.
OQR are of equal area. x r x−r 2r θ r 90−θ 2x − r 2x *51. (3.IITJEE2007PAPER218 1 (x + 2x) × 2r = 18 2 xr = 6 …(1) x−r 2x − r tan(90 − θ) = tan θ = r r x−r r = r 2x − r x(2x − 3r) = 0 3r x= …(2) 2 From (1) and (2) r = 2. radius 53. Then P(EC∩FC  G) equals (A) P(EC) + P(FC) (B) P(EC) − P(FC) C (D) P(E) − P(FC) (C) P(E ) − P(F) (C) E c ∩ Fc P(E c ∩ Fc ∩ G) P(G) − P(E ∩ G) − P(G ∩ F) P = G = P(G) P(G) Sol. Fax : 26513942 . The coordinates of R are 4 2 (A) . Sol. 0) 52. Kalu Sarai. FIITJEE Ltd. hence centroid is the desired point. 3 3 4 4 2 (D) .110016. 3 (B) 3. New Delhi . ∆ is isosceles. Ph : 26515949. Let O(0. −1) fixed radius 1 and variable centres along the xaxis fixed radius 1 and variable centres along the yaxis (6. The point R inside the triangle OPQ is such that the triangles OPR. Let Ec denote the complement of an event E. ICES House. 3 3 3 (C) Since. 1) variable radii and a fixed centre at (0. 26569493. G be pairwise independent events with P(G) > 0 and P(E∩F∩G) = 0. (C) 3. P(3. 0). 0) be the vertices of the triangle OPQ. PQR. Sarvapriya Vihar. F. The differential equation (A) (B) (C) (D) Sol. (C) 1 − y2 dy = dx y ⇒ ∫ y 1 − y2 dy = ∫ dx ⇒ − 1 − y2 = x + c ⇒ (x + c)2 + y2 = 1 centre (−c. 4) (0. Q(6. 29A. Let E. c2 − c2 + 1 = 1 . 0). 0) 1 − y2 dy = determines a family of circles with dx y variable radii and a fixed centre at (0. 4).
ICES House. (B) f(x) = 2 + cosx ∀ x ∈ R Statement : 1 There exists a point c ∈ [t. Statement 2: f(t) = f(t + 2π) is true. Statement 2 is True Sol. t + π] such that f′(c) = 0. we get x = 3. Kalu Sarai. (B). Statement 2 is True. Ph : 26515949. t + π] where f′(c) = 0 Hence. 54. FIITJEE Ltd. (A) Statement 1 is True. because STATEMENT 2 : f(t) = f(t + 2π) for each real t. STATEMENT 1 : The parametric equations of the line of intersection of the given planes are x = 3 + 14t. j (A) Statement 1 is True. 26569493. y = 1 + 2t. Each question has 4 choices (A). SECTION −II Assertion − Reason Type This section contains 4 questions numbered 54 to 57. (D) 3x − 6y − 2z = 15 2x + y − 2z = 5 for z = 0. statement 1 is false. Statement 2 is True. there exists a point c in [t. Statement 2 is True. Statement2 is NOT a correct explanation for Statement1 (C) Statement 1 is True. 29A. Statement 2 is True. Fax : 26513942 . But statement 2 is not a correct explanation for statement 1. But statement 2 is true. Statement2 is a correct explanation for Statement1 (B) Statement 1 is True.110016. Statement 2 is True Sol. Each question contains STATEMENT − 1 (Assertion) and STATEMENT 2 (Reason).IITJEE2007PAPER219 = P(G)(1 − P(E) − P(F)) P(G) [∵ P(G) ≠ 0] = 1 − P(E) − P(F) = P(Ec) − P(F). y = −1 Direction vectors of plane are < 3 −6 −2 > and <2 1 −2> then the dr’s of line of intersection of planes is <14 2 15> x − 3 y +1 z − 0 = = =λ 14 2 15 ⇒ x = 14λ + 3 y = 2λ − 1 z = 15λ Hence. Let f(x) = 2 + cosx for all real x. Statement2 is NOT a correct explanation for Statement1 (C) Statement 1 is True. 55. STATEMENT 1 : For each real t. Statement 2 is False (D) Statement 1 is False. Consider the planes 3x − 6y − 2z = 15 and 2x + y − 2z = 5. Sarvapriya Vihar. Statement2 is a correct explanation for Statement1 (B) Statement 1 is True. Statement 2 is False (D) Statement 1 is False. statement 1 is true. z = 15t because ˆ ˆ STATEMENT 2 : The vectors 14i + 2ˆ + 15k is parallel to the line of intersection of the given planes. New Delhi . (C) and (D) out of which ONLY ONE is correct.
New Delhi . 2 STATEMENT 2 : A parabola is symmetric about its axis. Ph : 26515949. ICES House. Statement 2 is true. Statement2 is a correct explanation for Statement1 (B) Statement 1 is True. Sarvapriya Vihar. M58−60 : Paragraph for question Nos. For example. The bisector of the acute angle between L1 and L2 intersects L3 at R.110016. Statement2 is a correct explanation for Statement1 (B) Statement 1 is True. STATEMENT 1 : The ratio PR : RQ equals 2 2 : because 5. Consider f(x) = kex − x for all real x where k is a real constant. out of which ONLY ONE is correct. Statement2 is NOT a correct explanation for Statement1 (C) Statement 1 is True. 3 multiple choice questions have to be answered. Statement 2 is True Sol. 26569493. y=− SECTION − III Linked Comprehension Type This section contains 2 paragraphs M58−60 and M61−63. Statement 2 is False (D) Statement 1 is False. −2) *57. (A) Statement 1 is True. Based upon each paragraph. respectively. The line y = x meets y = kex for k ≤ 0 at FIITJEE Ltd. 58. Statement 2 is true. STATEMENT 2 : In any triangle. Lines L1 : y − x = 0 and L2 : 2x + y = 0 intersect the line L3 : y + 2 = 0 at P and Q. Each question has 4 choice (A). (A) x2 + x +1 2 3 1 ⇒ y − = − (x − 1) 2 2 2 ⇒ it is symmetric about x = 1. (A) Statement 1 is True. STATEMENT 1 : The curve y = because O θ/2 θ/2 L2 R Q (1. if it is known that a continuous function f on R is positive at some point and its minimum values is negative then the equation f(x) = 0 has a root in R. −2) y = −2 −x 2 + x + 1 is symmetric with respect to the line x = 1. (B). assumes positive and negative values in R then the equation f(x) = 0 has a root in R. Statement 2 is False (D) Statement 1 is False. 29A. (C) and (D). Statement 2 is true. 58 to 60 If a continuous f defined on the real line R. bisector of an angle divides the triangle into two similar triangles.IITJEE2007PAPER220 *56. Statement2 is NOT a correct explanation for Statement1 (C) Statement 1 is True. Kalu Sarai. (C) In ∆OPQ PR OP 2 2 Clearly = = RQ OQ 5 L1 L3 P (−2. Statement 2 is True. Statement 2 is True Sol. Fax : 26513942 .
let An−1 and Hn−1 has arithmetic. H n = 2 A n −1 + H n −1 Sol. 1) e (A) Sol. (B) one point (D) more than two points y x 59. The positive value of k for which kex − x = 0 has only one root is (A) 1/e (B) 1 (C) e (D) loge2 (A) Let f(x) = kex − x f′(x) = kex − 1 = 0 ⇒ x = −ln k f′′(x) = kex f′′(x)x=−lnk = 1 > 0 Hence f(−lnk) = 1 + lnk For one root of given equation 1 + lnk = 0 1 hence k = . For n ≥ 2. Fax : 26513942 . Hn respectively. of two distinct positive numbers. G1. respectively. *61. New Delhi . (B) . Gn. (B) Line y = x intersect the curve y = kex at exactly one point when k ≤ 0. Which one of the following statements is correct? (A) G1 > G2 > G3 > … (B) G1 < G2 < G3 < … (C) G1 = G2 = G3 = … (D) G1 < G3 < G5 < … and G2 > G4 > G6 > … (C) A1 = a+b 2ab . H1 denote the arithmetic. G1 = ab. geometric and harmonic means. H1 = 2 a+b A + H n −1 2A n −1H n −1 A n = n −1 . e Sol. 29A. For two distinct roots 1 + lnk < 0 (k > 0) lnk < −1 1 k< e 1 hence k ∈ 0. 60. Sarvapriya Vihar. 61 to 63 Let A1.IITJEE2007PAPER221 (A) no point (C) two points Sol. For k > 0. G n = A n −1H n −1 . 1 e e 1 (C) . . ICES House. e M61−63 : Paragraph for Question Nos. geometric and harmonic means as An. Ph : 26515949. ∞ (D) (0. FIITJEE Ltd. the set of all values of k for which k ex − x = 0 has two distinct roots is 1 1 (A) 0. Kalu Sarai. 26569493.110016.
(B) A1 < A2 < A3 < … (D) A1 < A3 < A5 < … and A2 > A4 > A6 > … Which of the following statements is correct? (A) A1 > A2 > A3 > … (C) A1 > A3 > A5 > … and A2 < A4 < A6 < … Sol. D → p. The answers to these questions have to be appropriately bubbled as illustrated in the following example. B. s . A−s. Statements (A. s FIITJEE Ltd. C−q and D−s. B → q. then f(x) satisfies Column II (p) (q) (r) (s) 0 < f(x) < 1 f(x) < 0 f(x) > 0 f(x) < 1 (B) If 1 < x < 2. s . s) in Column II. (A) A2 is A. G1 = G2 = G3 = … = *62.110016. Each question contains statements given in two columns which have to be matched. Which of the following statements is correct? (A) H1 > H2 > H3 > … (C) H1 > H3 > H5 > … and H2 < H4 < H6 < … (B) (B) H1 < H2 < H3 < … (D) H1 < H3 < H5 < … and H2 > H4 > H6 > … Sol. Ph : 26515949. r. then f(x) satisfies (C) If 3 < x < 5. ab . ICES House. A → p. B−r. then f(x) satisfies Sol. A2 > H3 > H2 ∴ H1 < H2 < H3 < … SECTION −IV Matrix − Match Type This section contains 3 questions. of A1 and H1 and A1 > H1 ⇒ A1 > A2 > H1 A3 is A. s . Sarvapriya Vihar.M. Column I (A) If −1 < x < 1. New Delhi . r. 26569493. of A2 and H2 and A2 > H2 ⇒ A2 > A3 > H2 ∴ A1 > A2 > A3 > … *63.IITJEE2007PAPER222 Clearly. C → q. r. then the correctly bubbled 4 × 4 matrix should be as follows: p A p B p C p D p 64. Kalu Sarai. D) in Column I have to be matched with statements (p. Fax : 26513942 . B−q. C.M. C−p. Let f(x) = q q q q q r r r r r s s s s s x 2 − 6x + 5 . q. x 2 − 5x + 6 Match the conditions / expressions in Column I with statements in Column II and indicate your answers by darkening the appropriate bubbles in 4 × 4 matrix given in the ORS. then f(x) satisfies (D) If x > 5. 29A. As above A1 > H2 > H1. If the correct matches are A−p.
Ph : 26515949. sin−1(ax) + cos−1(y) + cos−1(bxy) = Column I (A) If a = 1 and b = 0. D→s lies on (x2 − 1) (y2 − 1) = 0 lies on y = x lies on (4x2 − 1) (y2 − 1) = 0 (A) (B) If a = 1. Kalu Sarai. Let (x. Match the statements in Column I with the properties Column II and indicate your answer by darkening the appropriate bubbles in the 4 × 4 matrix given in the ORS. FIITJEE Ltd. ICES House. Fax : 26513942 . A→p. then sin−1x + cos−1y + cos−1xy = π 2 ⇒ cos−1x − cos−1y =cos−1xy ⇒ xy + 1 − x 2 1 − y 2 = xy (taking sine on both the sides) (C) If a = 1. then (x.C→p. b = 2 ⇒ sin−1x + cos−1y + cos−1(2xy) = ⇒ sin−1x + cos−1y = sin−1(2xy) ⇒ xy + 1 − x 2 1 − y 2 = 2xy (D) ⇒ x2 + y2 = 1 (on squaring). New Delhi . 26569493. If a = 1 and b = 1. 29A.IITJEE2007PAPER223 (x − 1)(x − 5) (x − 2)(x − 3) The graph of f(x) is shown (A) If −1 < x < 1 ⇒ 0 < f(x) < 1 (B) If 1 < x < 2 ⇒ f(x) < 0 (C) If 3 < × < 5 ⇒ f(x) < 0 (D) If x > 5 ⇒ 0 < f(x) < 1 f (x) = y y=1 x 1 2 3 5 *65. then (x. y) be such that π . y) Sol. y) (D) If a = 2 and b = 2.110016. y) (p) (q) (r) (s) Column II lies on the circle x2 + y2 = 1 (B) If a = 1 and b = 1. Sarvapriya Vihar. then (x. 2 Match the statements in Column I with the statements in Column II and indicate your answer by darkening the appropriate bubbles in the 4 × 4 matrix given in the ORS. y) (C) If a = 1 and b = 2. B→q. *66. b = 0 then sin−1x + cos−1y = 0 ⇒ sin−1x = −cos−1y ⇒ x2 + y2 = 1. then (x. If a = 2 and b = 2 then sin−1(2x) + cos−1(y) + cos−1(2xy) = ⇒ 2xy + 2 π 2 π 2 1 − 4x 2 1 − y 2 = 2xy ⇒ (4x − 1) (y2 − 1) = 0.
Ph : 26515949. (C) When one circle lies inside of other then. one strictly inside the other (D) two branches of a hyperbola Sol. FIITJEE Ltd. q . they have a common normal but no common tangent. 26569493. (B) Two mutually external circles have a common normal and common tangent. A → p.110016. New Delhi . q . ICES House. 29A. (D) Two branches of a hyperbola have a common normal but no common tangent.IITJEE2007PAPER224 Column I (A) Two intersecting circles (p) (q) (r) (s) Column II have a common tangent (B) Two mutually external circles (C) two circles. r have a common normal do not have a common tangent do not have a common normal (A) When two circles are intersecting they have a common normal and common tangent. D → q. Fax : 26513942 . Sarvapriya Vihar. B → p. Kalu Sarai. r . C → q.
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