To = 0 K

100000

To = 300 K

90000

R(T) and G(T) (J/mol)

To* = 531.4 K
80000
70000

=5

60000
50000
40000
30000
* = 0.66

20000

To = 350 K

10000
0
200

300

400

500

T (K)

600

700

1000 900 =5 800 Ta = 300 K 700 Ts (K) 600 500 400 ignition 300 200 100 0 0 100 200 300 400 To (K) 500 600 700 800 .

400 stable (lower SS) S* 300 unstable (upper SS) 200 100 0 300 310 320 330 340 Tc (K) 350 360 370 380 .