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Version 1 Revision Date 07/22/2011 Print Date 09/30/2011
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name MSDS Number Product Use Description : : : Acetone 000000015713 Chemical intermediate
Honeywell International, Inc. 101 Columbia Road Morristown, NJ 07962-1057 1-855-410-4578 (Monday-Friday, 9:00am-5:00pm) Medical: 1-800-498-5701 or +1-651-523-0309 Transportation: 1-800-424-9300 or +1-703-527-3887 (24 hours/day, 7 days/week)
For more information call
In case of emergency call : : :
SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form Color Odor Hazard Summary : liquid : colourless : sweet pungent : DANGER! Extremely flammable liquid and vapor. Vapor may cause flash fire. In use, may form flammable/explosive vapour-air mixture. Forms or accumulates static electricity, may cause fire or explosion. Aspiration hazard if swallowed can enter lungs and cause damage. May be harmful if inhaled. Causes headache, drowsiness or other effects to the central nervous system. Irritating to eyes and respiratory system. May irritate skin. May cause target organ or system damage to the following: respiratory system, nervous system, kidney, blood system, liver.
Potential Health Effects Skin : May cause skin irritation. Prolonged or repeated skin contact with liquid may cause defatting resulting in drying, redness and possible blistering. Skin absorption can transport other toxins into the body.
and may lead to unconsciousness. May cause irritation of the gastrointestinal tract. dizziness. and nausea. May cause target organ or system damage to the following: respiratory system. kidney. May cause corneal injury. liver. drowsiness. burning. Vapours may be irritating to eyes. nervous system. IARC. : Aspiration hazard if swallowed . throat. High vapour concentrations can cause headaches.1% is identified as a known or anticipated carcinogen by NTP. nose. : Causes respiratory tract irritation. SECTION 3. : Causes headache. or OSHA. Causes itching. redness and possible blistering. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Substance Page 2 / 13 . May cause systemic poisoning with symptoms paralleling those of inhalation. Prolonged or repeated skin contact with liquid may cause defatting resulting in drying. and lungs. : Skin disorders Eye disorders Cardiac irregularities Respiratory disorders Asthma : Eyes Skin Respiratory system Central nervous system Heart Ingestion Inhalation Chronic Exposure Aggravated Medical Condition Target Organs Carcinogenicity No component of this product present at levels greater than or equal to 0. drowsiness or other effects to the central nervous system.can enter lungs and cause damage. blood system. redness and tearing.Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Print Date 09/30/2011 Eyes : Irritating to eyes. Inhalation of high vapour concentrations can cause CNSdepression and narcosis.
Use oxygen as required. Call a physician. FIRE-FIGHTING MEASURES Flash point Ignition temperature Lower explosion limit Upper explosion limit Suitable extinguishing media : : : : : -17 °C (1 °F) 465 °C (869 °F) 2. Rinse immediately with plenty of water. Call a physician.5 %(V) 12. Skin contact : Eye contact : Ingestion : Notes to physician Treatment : Treat symptomatically. for at least 15 minutes. Wash off immediately with plenty of water for at least 15 minutes. Do not induce vomiting without medical advice. Call a physician. place him in the recovery position. also under the eyelids. give artificial respiration.00% SECTION 4. Never give anything by mouth to an unconscious person. provided a qualified operator is present. SECTION 5. If not breathing.Material Safety Data Sheet Acetone Version 1 Chemical Name Acetone Revision Date 07/22/2011 CAS-No. Call a physician. Take off contaminated clothing and shoes immediately. If breathing is difficult.8 %(V) Cool closed containers exposed to fire with water spray. Risk of product entering the lungs on vomiting after ingestion. Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Extremely flammable. give oxygen. FIRST AID MEASURES Inhalation : Remove to fresh air. Wash contaminated clothing before re-use. 67-64-1 Print Date 09/30/2011 Concentration 100. Page 3 Specific hazards during fire : / 13 . If a person vomits when lying on his back.
Contain spillage. Remove all sources of ignition. Do not allow run-off from fire fighting to enter drains or water courses.g. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear personal protective equipment. Acetone/water solutions that contain more than 2. Keep people away from and upwind of spill/leak. Immediately evacuate personnel to safe areas. Avoid contact with skin. Prevent further leakage or spillage if safe to do so. and then collect with non-combustible absorbent material. Discharge into the environment must be avoided. it would be within the flammable range and cause fire or explosion if a source of ignition were introduced. Vapors may travel to areas away from work site before igniting/flashing back to vapor source. Do not flush into surface water or sanitary sewer system. Do not breathe vapours or spray mist. Vapours may form explosive mixtures with air.5% acetone have flash points. Prevent product from entering drains. Special protective equipment for fire-fighters Additional advice SECTION 6. Unprotected persons must be kept away. eyes and clothing. (e. vermiculite) and place in container for disposal according to local / national regulations (see section 13). sand.Material Safety Data Sheet Acetone Version 1 fighting Revision Date 07/22/2011 Print Date 09/30/2011 Forms or accumulates static electricity. earth. diatomaceous earth. Environmental precautions : Methods for cleaning up : Page 4 / 13 . Use explosion-proof equipment. No sparking tools should be used. Ventilate the area. Do not swallow. Vapours are heavier than air and may spread along floors. Ensure adequate ventilation. When the acetone concentration is greater than 8% (by weight) in a closed container. In case of fire hazardous decomposition products may be produced such as: Carbon monoxide Carbon dioxide (CO2) : : Wear self-contained breathing apparatus and protective suit. may cause fire or explosion.
such as reduced loading rates and increased monitoring. Keep away from fire. Automatic gauging devices and other floats in vessels or tanks which contain static accumulating liquids should be electrically bonded to the shell. Do not fill any portable containers in or on a vehicle. Static electricity accumulation may be significantly increased by the presence of small quantities of water. Always bond the receiving container to the fill pipe before and during loading. Always keep the nozzle in contact with the container throughout the loading process. must be observed during "switch loading" operations (i. This liquid may accumulate static electricity even when transferred into properly grounded containers. In addition to bonding and grounding. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards associated with electrostatic charges. Do not breathe vapours or spray mist.e. Special precautions.Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Print Date 09/30/2011 SECTION 7. Page 5 Advice on protection against fire and explosion : / 13 . following NFPA-77 and/or API RP 2003 requirements. Do not smoke. loading. Use only in well-ventilated areas. gauging. Do not swallow. loading this material in tanks or shipping compartments that previously contained middle distillates or similar products). tank cleaning. This liquid may form an ignitable vapor-air mixture in closed tanks or containers. efforts to mitigate the hazards of an electrostatic discharge may include. Avoid contact with skin. ventilation. inerting and/or reduction of transfer velocities. Non-equilibrium conditions may increase the risks associated with static electricity such as tank and container filling. Bonding and grounding may be insufficient to remove static electricity. filtering. including bonding and grounding. Use explosion-proof equipment. sparks and heated surfaces. Do not use air pressure to unload containers. eyes and clothing. Keep container tightly closed. Dissipation of electrostatic charges may be improved with the use of conductivity additives when used with other mitigating efforts. but are not limited to. agitation. etc. sampling. mixing. HANDLING AND STORAGE Handling Handling : Wear personal protective equipment.
giving complete protection to eyes Solvent-resistant gloves Gloves must be inspected prior to use. braze. drill. Prevent vapor buildup by providing adequate ventilation during and after use. SECTION 8. Container hazardous when empty. Do not pressurize. Use only non-sparking tools. Keep away from direct sunlight. wear: Page 6 Engineering measures : Eye protection : Hand protection : Skin and body protection : / 13 . Keep away from heat and sources of ignition. Storage Requirements for storage areas and containers : Store in area designed for storage of flammable liquids. Keep containers tightly closed in a dry. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. wear: Goggles or face shield. cool and well-ventilated place. Do not wear contact lenses. Wear as appropriate: Solvent-resistant apron and boots Flame retardant antistatic protective clothing If splashes are likely to occur. Replace when worn. Electrical equipment should be protected to the appropriate standard. cut. grind or expose containers to heat or sources of ignition. Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur. weld. No smoking. Store away from incompatible substances. Use only in an area equipped with explosion proof exhaust ventilation. Containers which are opened must be carefully resealed and kept upright to prevent leakage. solder. Protect from physical damage.Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Print Date 09/30/2011 Keep product and empty container away from heat and sources of ignition.
Remove and wash contaminated clothing before re-use. Print Date 09/30/2011 Hygiene measures : Exposure Guidelines Acetone 67-64-1 ACGIH ACGIH ACGIH NIC ACGIH NIC NIOSH OSHA Z1 STEL TWA STEL TWA REL PEL 250 ppm 750 ppm 500 ppm 500 ppm 200 ppm 590 mg/m3 2. Avoid contact with skin.000 ppm OSHA Z1A TWA 750 ppm 1.400 mg/m3 2. Keep working clothes separately. drink or smoke. When using.400 mg/m3 1.800 mg/m3 SECTION 9.Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Protective suit Respiratory protection : In the case of vapour formation use a respirator with an approved filter. do not eat.08 g/mol Page 7 / 13 . For rescue and maintenance work in storage tanks use selfcontained breathing apparatus. Wash hands and face before breaks and immediately after handling the product. PHYSICAL AND CHEMICAL PROPERTIES Form Color Odor Molecular Weight : liquid : colourless : sweet pungent : 58. eyes and clothing.000 ppm OSHA Z1A STEL 1. Do not swallow. Use NIOSH approved respiratory protection. Do not breathe vapours or spray mist.
hexachloromelamine.79 g/cm3 : completely soluble Print Date 09/30/2011 Density Water solubility SECTION 10. potassium tertbutoxide. : Acids Aldehydes Alkalies Amines Ammonia Oxidizing agents Reducing agents Chlorine compounds May form explosive mixtures with chromic anhydride. Materials to avoid Hazardous decomposition products Hazardous reactions SECTION 11.1 °C (133. and thioglycol. : In case of fire hazardous decomposition products may be produced such as: Carbon monoxide Carbon dioxide (CO2) : Hazardous polymerisation does not occur.800 mg/kg Species: rat Page 8 / 13 . STABILITY AND REACTIVITY Conditions to avoid : Heat. Stable under normal conditions. hydrogen peroxide. chromyl alcohol.Material Safety Data Sheet Acetone Version 1 pH Melting point/range Boiling point/boiling range Vapor pressure Revision Date 07/22/2011 : 7 : -94 °C (-137 °F) : 56. Keep away from direct sunlight. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: 5. permonosulfuric acid. flames and sparks.0 °F) : 241 hPa at 20 °C (68 °F) : 0.
ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish : static test LC50: 5.540 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) : static test LC50: 8.300 mg/l Exposure time: 96 h Page 9 / 13 .Material Safety Data Sheet Acetone Version 1 Acute inhalation toxicity Revision Date 07/22/2011 : LC50: 32000 ppm Exposure time: 4 h Species: rat Print Date 09/30/2011 Acute dermal toxicity : LD50: > 7. Method: Draize Test Repeated dose toxicity : Species: rat NOEL: 19000 ppm Note: 8-Week Inhalation Toxicity Study 5 days/week for 8 weeks Slightly reduced weight gain compared to controls : Species: rat NOEL: 100 mg/kg Note: 90-Day Oral Toxicity Study increased liver and kidney weights : Species: rat Lowest observable effect level: 500 mg/kg Note: 90-Day Oral Toxicity Study increased liver and kidney weights SECTION 12.426 mg/kg Species: guinea pig Skin irritation : Species: rabbit Result: Mild skin irritation Exposure time: 24 h Eye irritation : Species: rabbit Result: Irritating to eyes.
12.020 mg/l Exposure time: 14 d Species: Chlorella pyrenoidosa Toxicity to bacteria : EC50: 14. Description of the goods Class Packaging group Hazard Labels Packing instruction (cargo : : : : : : UN 1090 ACETONE 3 II 3 364 / 13 Page 10 . SECTION 14.500 mg/l Exposure time: 15 min Species: Photobacterium phosphoreum Elimination information (persistence and degradability) Biodegradability : anaerobic Result: Readily biodegradable Value: 78 % Method: OECD 301 D Further information on ecology SECTION 13.700 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Toxicity to algae : EC50: 3. : LC50: 12. TRANSPORT INFORMATION DOT UN/ID No.Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Print Date 09/30/2011 Species: Lepomis macrochirus (Bluegill sunfish) Toxicity to daphnia and other aquatic invertebrates. Proper shipping name Class Packing group Hazard Labels : UN 1090 : ACETONE 3 II 3 IATA UN/ID No. and Local Environmental regulations. DISPOSAL CONSIDERATIONS Waste Information: Observe all Federal.600 . State.
Material Safety Data Sheet Acetone Version 1 aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG UN/ID No. Kashin-Hou Law List Korea. : On TSCA Inventory US. Toxic Substances Control Act Australia. Gaz. Description of the goods Class Packaging group Hazard Labels EmS Number Marine pollutant Revision Date 07/22/2011 Print Date 09/30/2011 : 353 : Y341 : : : : : : : UN 1090 ACETONE 3 II 3 F-E no SECTION 15. Domestic Substances List (DSL). 1907/2006 (REACH). : On the inventory. or in compliance with the inventory : On the inventory. The Toxic Substances and Hazardous and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances : On the inventory. or in compliance with the inventory Page 11 / 13 . Existing Chemicals Inventory (KECI) Philippines. Industrial Chemical (Notification and Assessment) Act Canada. REGULATORY INFORMATION Inventories 1907/2006 (EU) : This mixture contains only ingredients which have been subject to a pre-registration according to Regulation (EC) No. Part II. Vol. or in compliance with the inventory : On the inventory. or in compliance with the inventory : All components of this product are on the Canadian DSL list. or in compliance with the inventory : On the inventory. Canadian Environmental Protection Act (CEPA). (Can. 144) Japan.
as published by ERMA New Zealand Revision Date 07/22/2011 Print Date 09/30/2011 : On the inventory.Material Safety Data Sheet Acetone Version 1 New Zealand. Benzene 71-43-2 Acetaldehyde 75-07-0 Cumene 98-82-8 : WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Inventory of Chemicals (NZIoC). Toluene 108-88-3 Benzene 71-43-2 Massachusetts RTK : Acetone : Benzene : Acetaldehyde : Acetone : Acetone : Benzene 67-64-1 71-43-2 75-07-0 67-64-1 67-64-1 71-43-2 New Jersey RTK Pennsylvania RTK WHMIS Classification : B2 D2B This product has been classified according to the hazard criteria Page 12 / 13 . 65 : WARNING! This product contains a chemical known to the State of California to cause cancer. or in compliance with the inventory National regulatory information SARA 311/312 Hazards : Fire Hazard Acute Health Hazard Chronic Health Hazard : 5000 lbs CERCLA Reportable Quantity California Prop.
SECTION 16. OTHER INFORMATION Health hazard Flammability Physical Hazard Instability * .Chronic health hazard HMIS III : 2* : 3 : 0 : NFPA 1 3 0 Page 13 / 13 .Material Safety Data Sheet Acetone Version 1 Revision Date 07/22/2011 Print Date 09/30/2011 of the CPR and the MSDS contains all of the information required by the CPR.
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