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IIT-JEE-2011

CODE
PAPER 1
Time: 3 Hours Maximum Marks: 240

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS
A. General:
1. The question paper CODE is printed on the right hand top corner of this sheet and on the back page (page
No. 36) of this booklet.
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are NOT allowed.
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5. The answer sheet, a machine-gradable Optical Response Sheet (ORS), is provided separately.
6. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET.
7. Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators.
8. This question Paper contains 36 pages having 69 questions.
9. On breaking the seals, please check that all the questions are legible.

B. Filling the Right Part of the ORS:
10. The ORS also has a CODE printed on its Left and Right parts.
11. Make sure the CODE on the ORS is the same as that on this booklet. If the codes do not match ask for a
change of the booklet.
12. Write your Name, Registration No. and the name of centre and sign with pen in the boxes provided. Do not
write them anywhere else. Darken the appropriate bubble UNDER each digit of your Registration No.
with a good quality HB pencil.

C. Question paper format and Marking scheme:
13. The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part consists of four
sections.
14. In Section I (Total Marks: 21), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (–1) mark will be awarded.
15. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative
marks in this section.
16. In Section III (Total Marks: 15), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (–1) mark will be awarded.
17. In Section IV (Total Marks: 28), for each question you will be awarded 4 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks otherwise. There are no negative marks in
this section.

Write your name, registration number and sign in the space provided on the back of this booklet.
8
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PAPER-1 [Code – 8]

IITJEE 2011



SECTION – I (Total Marks : 21)
(Single Correct Answer Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. Extra pure N
2
can be obtained by heating
(A) NH
3
with CuO (B) NH
4
NO
3

(C) (NH
4
)
2
Cr
2
O
7
(D) Ba(N
3
)
2


Sol. (D)
( )
3 2
2
Ba N Ba 3N

→ +

2. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The
molarity of the solution is
(A) 1.78 M (B) 2.00 M
(C) 2.05 M (D) 2.22 M

Sol. (C)
Total mass of solution = 1000 + 120 = 1120 g
Total volume of solution in (L)
3
1120
10
1.15
= ×

( )
3
W 1 120 1.15 10
M 2.05 M
M V in L 60 1120
×
= × = × =

3. Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways, (i) and (ii) as
shown. Products X, Y and Z respectively are,

( ) ii
Al P Y → +
30
27
13
15
( ) i
Si X +
30
14
Si Z +
30
14

(A) proton, neutron, positron (B) neutron, positron, proton
(C) proton, positron, neutron (D) positron, proton, neutron

Sol. (A)
( )
27 4 30 1
13 2 14 1
Al Si p X + α → +
( )
27 4 30 1
13 2 15 0
Al P n Y + α → +
( )
30 30 0
15 14 1
P Si Z
+
→ + β

4. Geometrical shapes of the complexes formed by the reaction of Ni
2+
with Cl

, CN

and H
2
O, respectively,
are
(A) octahedral, tetrahedral and square planar (B) tetrahedral, square planar and octahedral
(C) square planar, tetrahedral and octahedral (D) octahedral, square planar and octahedral
PART - I: CHEMISTRY
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Sol. (B)
[ ]
2
4
NiCl Tetrahedral


( )
2
4
Ni CN Square Planar

( →
¸ ¸

( )
2
2
6
Ni H O Octahedral
+
( →
¸ ¸


5. The major product of the following reaction is

NH
C
C
O
O
( ) i KOH
→
Br CH
2
Cl (ii)

(A) N
C
C
O
O
CH
2
Br

(B) N
C
C
O
O
CH
2
Cl

(C)
N
C
O
O
CH
2
Br

(D)
N
C
C
O
O
CH
2
Cl


Sol. (A)

NH
O
O
( ) i KOH
→
Br CH
2
Cl ( ) ii
N
O
O
CH
2
Br

[Reason: Due to partial double bond character along C−Br bond prevents the attack of nucleophile at
phenylic position]

6. Among the following compounds, the most acidic is
(A) p-nitrophenol (B) p-hydroxybenzoic acid
(C) o-hydroxybenzoic acid (D) p-toluic acid
Sol. (C)
Due to ortho effect o-hydroxy benzoic acid is strongest acid and correct order of decreasing K
a
is

OH
COOH
COOH
CH
3
COOH
OH
OH
NO
2
> > >


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7. AgNO
3
(aq.) was added to an aqueous KCl solution gradually and the conductivity of the solution was
measured. The plot of conductance ( ) Λ versus the volume of AgNO
3
is

volume
(P) (Q)
volume
(R)
volume volume
(S)
Λ Λ Λ
Λ

(A) (P) (B) (Q)
(C) (R) (D) (S)

Sol. (D)
( ) ( ) ( )
3 3
AgNO KCl aq AgCl s KNO aq + → +
Initially there is aq. KCl solution now as solution of AgNO
3
is added, AgCl(s) is formed. Hence
conductivity of solution is almost compensated (or slightly increase) by the formation of KNO
3
. After end
point conductivity increases more rapidly because addition of excess AgNO
3
solution.

SECTION – II (Total Marks : 16)
(Multiple Correct Answers Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

8. Amongst the given options, the compound(s) in which all the atoms are in one plane in all the possible
conformations (if any), is (are)
(A)
C C
H
C H
2
CH
2
H

(B)
C C
CH
2
H
C H


(C)
C H
2
C O

(D)
C H
2
C CH
2


Sol. (B, C)
Along C−C single bond conformations are possible in butadiene in which all the atoms may not lie in the
same plane.

9. Extraction of metal from the ore cassiterite involves
(A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore
(C) removal of copper impurity (D) removal of iron impurity

Sol. (A, C, D)

2
SnO 2C 2CO Sn + → +
The ore cassiterite contains the impurity of Fe, Mn, W and traces of Cu.

10. According to kinetic theory of gases
(A) collisions are always elastic
(B) heavier molecules transfer more momentum to the wall of the container
(C) only a small number of molecules have very high velocity
(D) between collisions, the molecules move in straight lines with constant velocities

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Sol. (A, B, C, D)

11. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Physiosorption increases with increasing temperature but chemisorption decreases with increasing
temperature
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of
activation

Sol. (A, B, D)

SECTION-III (Total Marls : 15)
(Paragraph Type)

This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 12 and 13

An acyclic hydrocarbon P, having molecular formula C
6
H
10
, gave acetone as the only organic product through the
following sequence of reaction, in which Q is an intermediate organic compound.

( )
( )
( )
( )
( )
( )
( )
( )
( )
2 4
2 4 4 2
4 3
6 10
2
i conc. H SO
catalytic amount
i dil. H SO / HgSO H O
ii NaBH / ethanol ii O
C H
iii dil. acid iii Zn / H O
P Q 2

→ →
C
O
C H
3
CH
3


12. The structure of compound P is
(A)
3 2 2 2
CH CH CH CH C C H − ≡ − (B)
3 2 2 3
H CH C C C CH CH − ≡ −
(C)
C C C CH
3
C H
3
C H
3
H

(D)
C C C H
C H
3
C H
3
C H
3

Sol. (D)

13. The structure of the compound Q is
(A) C C CH
2
CH
3
C H
3
C H
3
H
H
OH

(B) C C CH
3
C H
3
C H
3
C H
3
H
OH

(C)
C CH
2
CHCH
3
C H
3
C H
3
H
OH

(D)
CH
3
CH
2
CH
2
CHCH
2
CH
3
OH

Sol. (B)

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Solution for the Q. No. 12 to 13

C C
C H
3
C H
3
C H
3
C H
(P)
( ) 2 4
H SO conc.
C C
C H
3
C H
3
C H
3
CH
3
O
2 4
4
dil. H SO
HgSO
→
C CH
C H
3
C H
3
C H
3
CH
3
OH
3 2
O / Zn / H O
←

C C
C H
3
C H
3
CH
3
CH
3
( )
( )
4
i NaBH / EtOH
ii dil. H
+
→
C O
C H
3
C H
3
+ C O
CH
3
CH
3
(Q)


Paragraph for Question Nos. 14 to 16

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns
light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH
3

dissolves O and gives an intense blue solution.

14. The metal rod M is
(A) Fe (B) Cu
(C) Ni (D) Co

Sol. (B)
( )
3 3
2
M N
Blue
Cu 2AgNO Cu NO 2Ag + → +
While Cu partially oxidizes to Cu(NO
3
)
2
and remaining AgNO
3
reacts with NaCl.

15. The compound N is
(A) AgNO
3
(B) Zn(NO
3
)
2

(C) Al(NO
3
)
3
(D) Pb(NO
3
)
2


Sol. (A)

16. The final solution contains
(A) ( ) [ ]
2
2
3 4
4
Pb NH and CoCl
+

(
¸ ¸
(B) ( ) ( )
3 2
3 3
4 4
Al NH and Cu NH
+ +
( (
¸ ¸ ¸ ¸

(C) ( ) ( )
2
3 3
2 4
Ag NH and Cu NH
+ +
( (
¸ ¸ ¸ ¸
(D) ( ) ( )
2
3 3
2 6
Ag NH and Ni NH
+ +
( (
¸ ¸ ¸ ¸


Sol. (C)

( ) ( )
3 3
O N
AgNO NaCl AgCl NaNO + → ↓ +
( )
3 3
2
AgCl 2NH Ag NH Cl
+

( + →
¸ ¸

( ) ( )
2
3 4 3
2 4
Cu NO 4NH OH Cu NH
+
( + →
¸ ¸



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SECTION-IV (Total Marks : 28)
(Integer Answer Type)

This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

17. The difference in the oxidation numbers of the two types of sulphur atoms in Na
2
S
4
O
6
is

Sol. (5)

O S
O
O
S S S
O
O
O
Na Na

S will have oxidation number = +5, 0
Difference in oxidation number = 5

18. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0% to the total weight of the hydrolysed products. The number of
glycine units present in the decapeptide is

Sol. (6)
For n-units of glycine,

( )
n 75
100
796 9 18
×
×
+ ×
= 47
⇒ n = 6

19. The work function ( ) φ of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
φ (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

Sol. (4)
The energy associated with incident photon =
hc
λ

⇒ E =
34 8
9
6.6 10 3 10
300 10


× × ×
×
J
E in eV =
34 8
9 19
6.6 10 3 10
300 10 1.6 10

− −
× × ×
× × ×
= 4.16 eV
So, number of metals showing photo-electric effects will be (4), i.e., Li, Na, K, Mg

20. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum
number,
s
1
m ,
2
= − is
Sol. (9)
For principal quantum number (n = 3)
Number of orbitals = n
2
= 9
So, number of electrons

with m
s
=
1
2
− will be 9.

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21. Reaction of Br
2
with Na
2
CO
3
in aqueous solution gives sodium bromide and sodium bromate with
evolution of CO
2
gas. The number of sodium bromide molecules involved in the balanced chemical
equation is

Sol. (5)

2 2 3 3 2
3Br 3Na CO 5NaBr NaBrO 3CO + → + +
So, number of NaBr molecules = 5

22. To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mol of He and 1.0 mol of
an unknown compound (vapour pressure 0.68 atm. at 0
o
C) are introduced. Considering the ideal gas
behaviour, the total volume (in litre) of the gases at 0
o
C is close to

Sol. (7)
For any ideal gas, PV = nRT
0.32 × V = 0.1 × 0.0821 × 273
V = 7 litre
(unknown compound X will not follow
ideal gas equation)
1 atm
He + X

For He, n = 0.1, P = 0.32 atm., V = ?, T = 273

23. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using
alcoholic KOH is

Sol. (5)
Total no. of alkenes will be = 5

C CH
2
CH
2
Br
CH
3
CH
2
C H
3
alc. KOH
→
C CH CH
2
CH
3
CH
2
C H
3
( ) E & Z


C CH
2
CH CH
3
CH
2
C H
3
or
( ) E & Z


C CH
2
CH
2
CH
3
CH
2
C H
3
or
( ) only 1



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SECTION – I (Total Marks : 21)
(Single Correct Answer Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

24. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall
building which reflects the sound waves. The speed of sound in air is 320 m/s. The frequency of the siren
heard by the car driver is
(A) 8.50 kHz (B) 8.25 kHz
(C) 7.75 kHz (D) 7.50 kHZ

Sol. (A)
f =
3
320 320 10
8 10
320 10 320
+
× × ×


= 8.5 kHz

25. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Ǻ. The wavelength
of the second spectral line in the Balmer series of singly-ionized helium atom is
(A) 1215 Ǻ (B) 1640 Ǻ
(C) 2430 Ǻ (D) 4687 Ǻ

Sol. (A)

1 1 1 5R
R
6561 4 9 36
| |
= − =
|
\ ¹


1 1 1 3R 4
4R
4 16 16
× | |
= − =
|
λ
\ ¹

1215 λ = Ǻ.

26. Consider an electric field
0
ˆ E E x =

, where E
0
is a constant. The flux
through the shaded area (as shown in the figure) due to this field is
(A) 2E
0
a
2
(B)
2
0
2E a
(C) E
0
a
2
(D)
2
0
E a
2


(0,a,0)
y
(0,0,0)
(a,a,a) (a,0,a)
z
x


Sol. (C)
(E
0
) (Projected area ) = E
0
a
2

27. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the initial temperature to be
T
1
, the work done in the process is
(A)
1
9
RT
8
(B)
1
3
RT
2

(C)
1
15
RT
8
(D)
1
9
RT
2


Sol. (A)
TV
γ-1
= C
T
1
(5.6)
2/3
= T
2
(0.7)
2/3
⇒ T
2
= T
1
(8)
2/3
= 4T
1

PART - II: PHYSICS
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∴ ∆w(work done on the system) =
1
nR T 9
RT
1 8

=
γ −


28. A 2 µF capacitor is charged as shown in the figure. The percentage of its
stored energy dissipated after the switch S is turned to position 2 is
(A) 0 % (B) 20 %
(C) 75 % (D) 80 %

S
2
2µ F

8µ F

1
V


Sol. (D)
U
i
=
2 2
1
2 V V
2
× × =
q
i
= 2V
Now, switch S is turned to position 2

2V q q
2 8

=
8V – 4q = q
⇒ q =
8V
5



2V-q q

∆H = V
2
-
2 2
64V 4V
2 25 8 2 25 2
| |
+
|
× × × ×
\ ¹

=
2
4V
5


29. A meter bridge is set-up as shown, to determine an
unknown resistance ‘X’ using a standard 10 ohm resistor.
The galvanometer shows null point when tapping-key is at
52 cm mark. The end-corrections are 1 cm and 2 cm
respectively for the ends A and B. The determined value of
‘X’ is

B
10Ω

A
X

(A) 10.2 ohm (B) 10.6 ohm
(C) 10.8 ohm (D) 11.1 ohm

Sol. (B)
X (48 + 2) = (10) (52 + 1)
X =
530
10.6
50
= Ω

30. A ball of mass (m) 0.5 kg is attached to the end of a string having length
(L) 0.5 m. The ball is rotated on a horizontal circular path about vertical
axis. The maximum tension that the string can bear is 324 N. The
maximum possible value of angular velocity of ball (in radian/s) is
(A) 9 (B) 18
(C) 27 (D) 36

L
m


Sol. (D)
324 = 0.5 ω
2
(0.5)
ω
2
= 324 × 4
ω = 1296 36 rad / s =
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SECTION – II (Total Marks : 16)
(Multiple Correct Answers Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

31. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. A thin disk of mass
‘M’ and radius ‘R’ (<L) is attached at its center to the free end of the rod. Consider
two ways the disc is attached: (case A). The disc is not free to rotate about its
centre and (case B) the disc is free to rotate about its centre. The rod-disc system
performs SHM in vertical plane after being released from the same displaced
position. Which of the following statement(s) is (are) true?
(A) Restoring torque in case A = Restoring torque in case B


(B) restoring torque in case A < Restoring torque in case B
(C) Angular frequency for case A > Angular frequency for case B.
(D) Angular frequency for case A < Angular frequency for case B.

Sol. (A, D)
In case A
mg(ℓ/2) sin θ + Mg ℓ sin θ =
2 2
2
A
m MR
M
3 2
| |
+ + α
|
\ ¹


In case B
mg (ℓ/2) sin θ + Mg ℓ sin θ =
2
2
B
m
M
3
| |
+ α
|
\ ¹


τ
A
= τ
B
, ω
A
< ω
B


32. A spherical metal shell A of radius R
A
and a solid metal sphere B of radius R
B
(<R
A
) are kept far apart and
each is given charge ‘+Q’. Now they are connected by a thin metal wire. Then
(A)
inside
A
E 0 = (B) Q
A
> Q
B

(C)

A B
B A
R
R
σ
=
σ

(D)

on surface on surface
A B
E E <

Sol. (A, B, C, D)
R
B
< R
A

Q
A
+ Q
B
= 2Q
A B
A B
kQ kQ
R R
=
σ
A
R
A
= σ
B
R
B

Q
A
=
A
A B
2QR
R R +

Q
B
=
B
A B
2QR
R R +


33. A composite block is made of slabs A, B, C, D and E of
different thermal conductivities (given in terms of a
constant K) and sizes (given in terms of length, L) as
shown in the figure. All slabs are of same width. Heat
‘Q’ flows only from left to right through the blocks. Then
in steady state
(A) heat flow through A and E slabs are same.
(B) heat flow through slab E is maximum.
(C) temperature difference across slab E is smallest.

A
2K
3K B
4K C
5K D
E
6K
1L
3L
4L
heat
0 1L 5L 6L

(D) heat flow through C = heat flow through B + heat flow through D.
IITJEE2011-Paper 1-CPM-12


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Sol. (A, C, D) or (A, B, C, D)
Let width of each rod is d
R
1
=
2
1 4
, R
8kd 3kd
=
R
3
=
4
1 4
, R
2kd 5kd
=
R
5
=
1
,
24kd




1
3
4
2
5



R1
R2
R3
R4
R5


34. An electron and a proton are moving on straight parallel paths with same velocity. They enter a semi-
infinite region of uniform magnetic field perpendicular to the velocity. Which of the following
statement(s) is / are true?
(A) They will never come out of the magnetic field region.
(B) They will come out travelling along parallel paths.
(C) They will come out at the same time.
(D) They will come out at different times.

Sol. (B, D)
Both will travel in semicircular path
Since, m is different, hence time will be different

SECTION-III (Total Marls : 15)
(Paragraph Type)

This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 35 and 36

A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids containing
fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let ‘N’ be the number density of
free electrons, each of mass ‘m’. When the electrons are subjected to an electric field, they are displaced relatively
away from the heavy positive ions. If the electric field becomes zero, the electrons begin to oscillate about the
positive ions with a natural angular frequency ‘ω
p
’ which is called the plasma frequency. To sustain the oscillations,
a time varying electric field needs to be applied that has an angular frequency ω, where a part of the energy is
absorbed and a part of it is reflected. As ω approaches ω
p
all the free electrons are set to resonance together and all
the energy is reflected. This is the explanation of high reflectivity of metals.

35. Taking the electronic charge as ‘e’ and the permittivity as ‘ε
0
’. Use dimensional analysis to determine the
correct expression for ω
p
.
(A)
0
Ne

(B)
0
m
Ne
ε

(C)
2
0
Ne

(D)
0
2
m
Ne
ε

Sol. (C)

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36. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons
N ≈ 4 × 10
27
m
-3
. Taking ε
0
= 10
-11
and m ≈ 10
-30
, where these quantities are in proper SI units.
(A) 800 nm (B) 600 nm
(C) 300 nm (D) 200 nm

Sol. (B)
ω = 2πc / λ

Paragraph for Question Nos. 37 to 39

Phase space diagrams are useful tools in analyzing all kinds of dynamical problems.
They are especially useful in studying the changes in motion as initial position and
momenum are changed. Here we consider some simple dynamical systems in one-
dimension. For such systems, phase space is a plane in which position is plotted along
horizontal axis and momentum is plotted along vertical axis. The phase space diagram is
x(t) vs. p(t) curve in this plane. The arrow on the curve indicates the time flow. For
example, the phase space diagram for a particle moving with constant velocity is a
straight line as shown in the figure. We use the sign convention in which positon or
momentum upwards (or to right) is positive and downwards (or to left) is negative.

M
o
m
e
n
t
u
m

Position


37. The phase space diagram for a ball thrown vertically up from ground is
(A)

Momentum
Position

(B)

Momentum
Position

(C)

Momentum
Position

(D)

Momentum
Position


Sol. (D)

38. The phase space diagram for simple harmonic motion is a circle
centered at the origin. In the figure, the two circles represent the same
oscillator but for different initial conditions, and E
1
and E
2
are the
total mechanical energies respectively. Then
(A) E
1
=
2
2E (B) E
1
= 2E
2

(C) E
1
= 4E
2
(D) E
1
= 16E
2


Momentum
Position
2a
a
E1
E2

Sol. (C)
E ∝ A
2

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39. Consider the spring-mass system, with the mass submerged in
water, as shown in the figure. The phase space diagram for one
cycle of this system is



(A)

Momentum
Position

(B)

Momentum
Position

(C)

Momentum
Position

(D)

Momentum
Position


Sol. (B)

SECTION-IV (Total Marks : 28)
(Integer Answer Type)

This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

40. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as
shown in the figure. The stick applies a force of 2N on the ring and rolls it
without slipping with an acceleration of 0.3 m/s
2
. The coefficient of
friction between the ground and the ring is large enough that rolling
always occurs and the coefficeint of friction between the stick and the ring
is (P/10). The value of P is

Ground
Stick


Sol. (4)
Now
N − f
s
= ma ∴ f
s
= 1.4 N
and (f
s
− f
K
)R = Iα, a = Rα
∴ f
K
= 0.8 N
So, µ =
P
0.4
10
=
P = 4

N
R
Mg
fs
fk
a
α αα α

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41. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers at the corners of
a square of side 4 cm. The moment of inertia of the system about the diagonal of the square is N × 10
−4
kg-
m
2
, then N is

Sol. (9)
I =
2
2 2
2 2 a
2 mr 2 mr m
5 5 2
(
| | | |
× + + (
| |
\ ¹ \ ¹ (
¸ ¸

I = 9 × 10
−4
kg-m
2

∴ N = 9

a
m, r


42. Steel wire of lenght ‘L’ at 40°C is suspended from the ceiling and then a mass ‘m’ is hung from its free
end. The wire is cooled down from 40°C to 30°C to regain its original length ‘L’. The coefficient of linear
thermal expansion of the steel is 10
−5
/°C, Young’s modulus of steel is 10
11
N/m
2
and radius of the wire is 1
mm. Assume that L ≫ diameter of the wire. Then the value of ‘m’ in kg is nearly

Sol. (3)
Change in length ∆L =
MgL
YA
= Lα∆T
∴ m ≈ 3 kg

43. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of side ‘a’.
The surface tension of the soap film is γ. The system of charges and planar film are in equilibrium, and
1/ N
2
q
a k
(
=
(
γ
¸ ¸
, where ‘k’ is a constant. Then N is

Sol. (3)
Since F
electric

2
2
q
a
a
∝ ∝ γ
∴ a =
1/ 3
2
q
k
| |
|
γ
\ ¹

∴ N = 3

44. A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of
friction is µ. The force required to just push it up the inclined plane is 3 times the force required to just
prevent it from sliding down. If we define N = 10 µ, then N is

Sol. (5)
mg(sin θ + µcosθ) = 3mg(sinθ − µcosθ)
∴ µ = 0.5
∴ N = 5

45. The activity of a freshly prepared radioactive sample is 10
10
disintegrations per second, whose mean life is
10
9
s. The mass of an atom of this radioisotope is 10
−25
kg. The mass (in mg) of the radioactive sample is

Sol. (1)
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dN
N
dt
= λ
∴ N =
10 9 19
dN
dt
10 10 10
| |
|
\ ¹
= × =
λ
atoms
m
sample = 10
−25
× 10
19
kg = 1 mg

46. A long circular tube of length 10 m and radius 0.3 m carries a current I along its
curved surface as shown. A wire-loop of resistance 0.005 ohm and of radius 0.1 m is
placed inside the tube with its axis coinciding with the axis of the tube. The current
varies as I = I
0
cos(300 t) where I
0
is constant. If the magnetic moment of the loop is

0
I
0
sin(300 t), then ‘N’ is

I


Sol. (6)
B
inside
= µ
0
ni =
o
I
L
µ


2
0
ind
( r ) d dI
E
dt L dt
µ π φ
= − = −
So magnetic moment =
2 ind
E
r
R
| |
π
|
\ ¹

= 6µ
0
I
0
sin(300t)
Therefore, n = 6


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SECTION – I (Total Marks : 21)
(Single Correct Answer Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

47. Let (x
0
, y
0
) be solution of the following equations
(2x)
ln2
= (3y)
ln3

3
lnx
= 2
lny

Then x
0
is
(A)
1
6
(B)
1
3

(C)
1
2
(D) 6

Sol. (C)
(2x)
ln2
= (3y)
ln3
…(i)
3
lnx
= 2
lny
…(ii)
⇒ (logx) (log3) = (logy)log2
⇒ logy =
(log )(log3)
log2
x
…(iii)
In (i) taking log both sides
(log2) {log2 + logx} = log3{log3 + logy}
(log2)
2
+ (log2) (logx) = (log3)
2
+
2
(log3) (log )
log 2
x
from (iii)
⇒ (log2)
2
− (log3)
2
=
2 2
(log3) (log2)
(log )
log2
x

⇒ −log2 = logx

1
2
x = ⇒ x
0
=
1
2
.

48. Let
{ }
P : sin cos 2 cos = θ θ − θ = θ and Q =
{ }
: sin cos 2 sin θ θ + θ = θ be two sets. Then
(A) P ⊂ Q and Q − P ≠ ∅ (B) Q ⊄ P
(C) P ⊄ Q (D) P = Q

Sol. (D)
In set P, sinθ =
( )
2 1 cos + θ ⇒ tanθ = 2 1 +
In set Q,
( )
2 1 sin cos − θ = θ ⇒ tan θ =
1
2 1
2 1
= +

⇒ P = Q.

49. Let
ˆ ˆ ˆ ˆ ˆ ˆ
, = + + = + +

a i j k b i j k and
ˆ ˆ ˆ
= − −

c i j k be three vectors. A vector

v in the plane of

a and b , whose
projection on

c is
1
3
, is given by
(A)
ˆ ˆ ˆ
3 3 − + i j k (B)
ˆ ˆ ˆ
3 3 − − + i j k
(C)
ˆ ˆ ˆ
3 3 − + i j k (D)
ˆ ˆ ˆ
3 3 + − i j k
PART - III:
MATHEMATICS
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Sol. (C)
v

a b = λ +µ
= λ
( ) ( )
ˆ ˆ ˆ ˆ ˆ ˆ
i j k i j k + + + µ − +
Projection of v

on c

v c 1
| c | 3

= ⇒
( ) ( ) ( )
( )
ˆ ˆ ˆ ˆ ˆ ˆ
i j k i j k
1
3 3
(
λ +µ + λ −µ + λ +µ ⋅ − −
¸ ¸
=
⇒ λ + µ − λ + µ − λ − µ = 1 ⇒ µ − λ = 1 ⇒ λ = µ − 1
( )
( ) ( )
ˆ ˆ ˆ ˆ ˆ ˆ
v 1 i j k i j k = µ − + + + µ − + =
( )
ˆ ˆ ˆ ˆ ˆ
2i 2k i j k µ + − − −
( ) ( )
ˆ ˆ ˆ
v 2 1 i j 2 1 k = µ − − + µ −
At µ = 2,
ˆ ˆ ˆ
v 3i j 3k = − + .

50. The value of
( )
ln3
2
2 2
ln2
sin
sin sin ln 6 + −

x x
dx
x x
is
(A)
1 3
ln
4 2
(B)
1 3
ln
2 2

(C)
3
ln
2
(D)
1 3
ln
6 2


Sol. (A)
x
2
= t ⇒ 2x dx = dt
I =
( )
ln3
ln 2
1 sin t
dt
2 sin t sin ln6 t + −

and I =
( )
( )
ln3
ln 2
sin ln6 t
1
dt
2 sin ln6 t sin t

− +


2I =
ln 3
ln 2
1
1dt
2

⇒ I =
1 3
ln
4 2
.

51. A straight line L through the point (3, −2) is inclined at an angle 60° to the line 3 1 + = x y . If L also
intersects the x-axis, then the equation of L is
(A) 3 2 3 3 0 + + − = y x (B) 3 2 3 3 0 − + + = y x
(C) 3 3 2 3 0 − + + = y x (D) 3 3 2 3 0 + − + = y x

Sol. (B)

m 3
3
1 3m
+
=



( )
m 3 3 3m + = ± −
⇒ 4m = 0 ⇒ m = 0
or 2m = 2 3 ⇒ m = 3
∴ Equation is y + 2 = ( ) 3 x 3 −

( )
3x y 2 3 3 0 − − + =

(3, −2)
60°
m
y =- 3x 1 +
(0, 1)


52. Let α and β be the roots of x
2
– 6x – 2 = 0, with α > β. If a
n
= α
n
– β
n
for n ≥ 1, then the value of
10 8
9
a 2a
2a


is
(A) 1 (B) 2
(C) 3 (D) 4
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Sol. (C)
a
n
= α
n
− β
n

α
2
− 6α − 2 = 0
Multiply with α
8
on both sides
⇒ α
10
− 6α
9
− 2α
8
= 0 …(i)
similarly β
10
− 6β
9
− 2β
8
= 0 …(ii)
(i) and (ii)
⇒ α
10
− β
10
− 6(α
9
− β
9
) = 2(α
8
− β
8
)
⇒ a
10
− 6a
9
= 2a
8

10 8
9
a 2a
3
2a

= .

53. Let the straight line x = b divides the area enclosed by y = (1 − x)
2
, y = 0 and x = 0 into two parts R
1
(0 ≤ x
≤ b) and R
2
(b ≤ x ≤ 1) such that R
1
− R
2
=
1
4
. Then b equals
(A)
3
4
(B)
1
2

(C)
1
3
(D)
1
4


Sol. (B)

( ) ( )
b 1
2 2
0 b
1
1 x dx 1 x dx
4
− − − =
∫ ∫


( ) ( )
b 1
3 3
0 b
x 1 x 1 1
3 3 4
− −
− =

( ) ( )
3 3
b 1 1 b 1 1
0
3 3 3 4
| |
− −
+ − − = |
\ ¹


( )
3
2 b 1 1
3 12

= − ⇒ (b – 1)
3
= –
1
8
⇒ b =
1
2
.

o b 1
R
1
R
2


SECTION – II (Total Marks : 16)
(Multiple Correct Answers Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE may be correct.

54. Let f: R → R be a function such that f(x + y) = f(x) + f(y), ∀ x, y ∈ R. If f(x) is differentiable at x = 0, then
(A) f(x) is differentiable only in a finite interval containing zero
(B) f(x) is continuous ∀ x ∈ R
(C) f′(x) is constant ∀ x ∈ R
(D) f(x) is differentiable except at finitely many points

Sol. (B, C)
∵ f(0) = 0
and f′(x) =
0
( ) ( )
lim
h
f x h f x
h →
+ −

=
0
( )
lim
h
f h
h →
= = f′(0) = k(say)
⇒ f(x) = kx + c ⇒ f(x) = kx (∵ f(0) = 0).

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55. The vector(s) which is/are coplanar with vectors
ˆ ˆ ˆ
i j 2k + + and
ˆ ˆ ˆ
i 2j k + + , and perpendicular to the vector
ˆ ˆ ˆ
i j k + + is/are
(A)
ˆ ˆ
j k − (B)
ˆ ˆ
i j − +
(C)
ˆ ˆ
i j − (D)
ˆ ˆ
j k − +

Sol. (A, D)
Any vector in the plane of
ˆ ˆ ˆ
i j 2k + + and
ˆ ˆ ˆ
i 2j k + + is ( ) ( ) ( )
ˆ ˆ ˆ
r i 2 j 2 k = λ +µ + λ + µ + λ +µ

Also, r c 0 ⋅ =

⇒ λ + µ = 0
⇒ r a b 0
(
=
¸ ¸

.

56. Let the eccentricity of the hyperbola
2 2
2 2
x y
1
a b
− = be reciprocal to that of the ellipse x
2
+ 4y
2
= 4. If the
hyperbola passes through a focus of the ellipse, then
(A) the equation of the hyperbola is
2 2
x y
1
3 2
− = (B) a focus of the hyperbola is (2, 0)
(C) the eccentricity of the hyperbola is
5
3
(D) the equation of the hyperbola is x
2
– 3y
2
= 3

Sol. (B, D)
Ellipse is
2 2
2 2
x y
1
2 1
+ =
1
2
= 2
2
(1 − e
2
) ⇒ e =
3
2

∴ eccentricity of the hyperbola is
2
3
⇒ b
2
=
2
4
a 1
3
| |

|
\ ¹
⇒ 3b
2
= a
2

Foci of the ellipse are
( )
3, 0 and
( )
3, 0 − .
Hyperbola passes through
( )
3, 0

2
3
1
a
= ⇒ a
2
= 3 and b
2
= 1
∴ Equation of hyperbola is x
2
− 3y
2
= 3
Focus of hyperbola is (ae, 0) ≡
2
3 , 0
3
| |
×
|
\ ¹
≡ (2, 0).

57. Let M and N be two 3 × 3 non-singular skew symmetric matrices such that MN = NM. If P
T
denotes the
transpose of P, then M
2
N
2
(M
T
N)
–1
(MN
–1
)
T
is equal to
(A) M
2
(B) – N
2

(C) – M
2
(D) MN

Sol. (C)
MN = NM
M
2
N
2
(M
T
N)
−1
(MN
−1
)
T

M
2
N
2
N
−1
(M
T
)
−1
(N
−1
)
T
.M
T

= M
2
N.(M
T
)
−1
(N
−1
)
T
M
T
= −M
2
.N(M)
−1
(N
T
)
−1
M
T

= +M
2
NM
−1
N
−1
M
T
= −M.NMM
−1
N
−1
M = −MNN
−1
M = −M
2
.
Note: A skew symmetric matrix of order 3 cannot be non-singular hence the question is wrong.
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SECTION-III (Total Marls : 15)
(Paragraph Type)

This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 58 to 59

Let U
1
and U
2
be two urns such that U
1
contains 3 white and 2 red balls, and U
2
contains only 1 white ball. A fair
coin is tossed. If head appears then 1 ball is drawn at random from U
1
and put into U
2
. However, if tail appears then
2 balls are drawn at random from U
1
and put into U
2
. Now 1 ball is drawn at random from U
2
.

58. The probability of the drawn ball from U
2
being white is
(A)
13
30
(B)
23
30

(C)
19
30
(D)
11
30


Sol. (B)
H → 1 ball from U
1
to U
2

T → 2 ball from U
1
to U
2

E : 1 ball drawn from U
2

P/W from U
2
=
3 2 3 2
2 2 1 1
5 5 5
2 2 2
1 3 1 2 1 1 1 1 1 2
1 1
2 5 2 5 2 2 2 3 2 3
| | | | | |
⋅ | | | |
× × + × × + × × + × × + × × | | | | |
| | |
\ ¹ \ ¹
\ ¹ \ ¹ \ ¹
C C C C
C C C
=
23
30
.

59. Given that the drawn ball from U
2
is white, the probability that head appeared on the coin is
(A)
17
23
(B)
11
23

(C)
15
23
(D)
12
23


Sol. (D)

( / ) ( )
( / ) ( ) ( / ) ( )
H P W H P H
P
W P W T P T W H P H
× | |
=
|
⋅ + ⋅ \ ¹
=
1 3 2 1
1
12
2 5 5 2
23/ 30 23
| |
× + ×
|
\ ¹
= .

Paragraph for Question Nos. 60 to 62

Let a, b and c be three real numbers satisfying [ ] [ ]
1 9 7
a b c 8 2 7 0 0 0
7 3 7
(
(
=
(
(
¸ ¸
……(E)

60. If the point P(a, b, c), with reference to (E), lies on the plane 2x + y + z = 1, then the value of 7a + b + c is
(A) 0 (B) 12
(C) 7 (D) 6

Sol. (D)
a + 8b + 7c = 0
9a + 2b + 3c = 0
IITJEE2011-Paper 1-CPM-22


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website: www.fiitjee.com.
a + b + c = 0
Solving these we get
b = 6a ⇒ c = – 7a
now 2x + y + z = 0
⇒ 2a + 6a + (–7a) = 1 ⇒ a = 1, b = 6, c = – 7.

61. Let ω be a solution of x
3
– 1 = 0 with Im(ω) > 0. If a = 2 with b and c satisfying (E), then the value of
a b c
3 1 3
+ +
ω ω ω
is equal to
(A) –2 (B) 2
(C) 3 (D) – 3

Sol. (A)
a = 2, b and c satisfies (E)
b = 12, c = – 14

a b c 2 12 14
3 1 3 3 1 3

+ + = + +
ω ω ω ω ω ω
= –2.

62. Let b = 6, with a and c satisfying (E). If α and β are the roots of the quadratic equation ax
2
+ bx + c = 0,
then
n
n 0
1 1

=
| |
+
|
α β
\ ¹

is
(A) 6 (B) 7
(C)
6
7
(D) ∞

Sol. (B)
ax
2
+ bx + c = 0 ⇒ x
2
+ 6x – 7 = 0
⇒ α = 1, β = – 7

n n
n 0 n 0
1 1 1 1
7
1 7
∞ ∞
= =
| | | |
+ = − =
|
|
α β \ ¹
\ ¹
∑ ∑
.

SECTION-IV (Total Marks : 28)
(Integer Answer Type)

This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

63. Consider the parabola y
2
= 8x. Let ∆
1
be the area of the triangle formed by the end points of its latus rectum
and the point P
1
, 2
2
| |
|
\ ¹
on the parabola, and ∆
2
be the area of the triangle formed by drawing tangents at P
and at the end points of the latus rectum. Then
1
2


is

Sol. (2)
y
2
= 8x = 4.2.x
2
LPM
ABC

=



1
2
2

=



A
L
C
M
(2, −4)
(2, 0)
(2, 4)
(0, 0)
P(1/2, 2)
B(0, 2)
x = − 2

IITJEE2011-Paper 1-CPM-23


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website: www.fiitjee.com.
64. Let f(θ) =
1
sin
sin tan
cos 2

| θ | | |
| |
θ \ ¹ \ ¹
, where
4 4
π π
− < θ < . Then the value of
( )
( ) ( )
d
f
d tan
θ
θ
is

Sol. (1)

1
sin
sin tan
cos 2

| | θ | |
| |
θ \ ¹ \ ¹
, where θ ∈ ,
4 4
π π | |

|
\ ¹


1
2
sin
sin tan
2cos 1

| | | |
θ
| |
| |
θ − \ ¹ \ ¹

= ( ) ( )
1
sin sin tan

θ = tan θ.

( )
( )
d tan
1
d tan
θ
=
θ
.

65. Let f: [1, ∞) → [2, ∞) be a differentiable function such that f(1) = 2. If
( ) ( )
x
3
1
6 f t dt 3xf x x = −

for all x ≥
1, then the value of f(2) is

Sol. (6)
6
( )
x
1
f t dt

= 3x f(x) – x
3
⇒ 6f(x) = 3f(x) + 3xf′(x) – 3x
2

⇒ 3f(x) = 3xf′(x) – 3x
2
⇒ xf′(x) – f(x) = x
2


2
dy
x y x
dx
− = ⇒
dy 1
y x
dx x
− = …(i)
I.F. =
1
dx
x
e


=
e
log x
e


Multiplying (i) both sides by
1
x


2
1 dy 1
y 1
x dx x
− = ⇒
d 1
y. 1
dx x
| |
=
|
\ ¹

integrating

y
x c
x
= +
Put x = 1, y = 2
⇒ 2 = 1 + c ⇒ c = 1 ⇒ y = x
2
+ x
⇒ f(x) = x
2
+ x ⇒ f(2) = 6.
Note: If we put x = 1 in the given equation we get f(1) = 1/3.

66. The positive integer value of n > 3 satisfying the equation
1 1 1
2 3
sin sin sin
n n n
= +
π π π | | | | | |
| | |
\ ¹ \ ¹ \ ¹
is

Sol. (7)

1 1 1
3 2
sin sin sin
n n n
− =
π π π

3
sin sin
1
3 2
sin sin sin
n n
n n n
π π

=
π π π

2 2
2sin cos sin
n n n
1
3
sin sin
n n
π π π | |
|
\ ¹
=
π π

IITJEE2011-Paper 1-CPM-24


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website: www.fiitjee.com.

4 3
sin sin
n n
π π
= ⇒
4 3
n n
π π
+ = π ⇒ n = 7.
67. Let a
1
, a
2
, a
3
, …, a
100
be an arithmetic progression with a
1
= 3 and S
p
=
p
i
i 1
a
=

, 1 ≤ p ≤ 100. For any integer
n with 1 ≤ n ≤ 20, let m = 5n. If
m
n
S
S
does not depend on n, then a
2
is

Sol. (9)
a
1
, a
2
, a
3
, … a
100
is an A.P.
a
1
= 3, S
p
=
p
i
i 1
a
=

, 1 ≤ p ≤ 1 00

( ) ( )
( )
5n m
n n
5n
6 5n 1 d
S S
2
n
S S
6 d nd
2
+ −
= =
− +


m
n
S
S
is independent of n of 6 − d = 0 ⇒ d = 6.

68. If z is any complex number satisfying |z – 3 – 2i| ≤ 2, then the minimum value of |2z – 6 + 5i| is

Sol. (5)
Length AB =
5
2

⇒ Minimum value = 5.

C (3, 2)
(0, 0)
A(3, −5/2)
B (3, 0)


69. The minimum value of the sum of real numbers a
–5
, a
–4
, 3a
–3
, 1, a
8
and a
10
with a > 0 is

Sol. (8)

5 4 3 3 3 8 10
a a a a a a a 1
1
8
− − − − −
+ + + + + + +

minimum value = 8.

IITJEE2011-Paper 1-CPM-2

PAPER-1 [Code – 8] IITJEE 2011 PART - I: CHEMISTRY
SECTION – I (Total Marks : 21) (Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 (D) ∆ Ba ( N 3 ) 2  Ba + 3N 2 → Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The molarity of the solution is (A) 1.78 M (B) 2.00 M (C) 2.05 M (D) 2.22 M (C) Total mass of solution = 1000 + 120 = 1120 g 1120 Total volume of solution in (L) = ×103 1.15 W 1 120 1.15 × 103 M= × = × = 2.05 M M V ( in L ) 60 1120 Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways, (i) and (ii) as shown. Products X, Y and Z respectively are,
27 13

(B) NH4NO3 (D) Ba(N3)2

Sol.

2.

Sol.

3.

(i )

( ) Al  15 P + Y →
ii 30

30 Si + X 14 Si + Z (A) proton, neutron, positron (C) proton, positron, neutron 30 14

(B) neutron, positron, proton (D) positron, proton, neutron

Sol.

(A) 27 4 30 1 13 Al + 2 α →14 Si + 1 p ( X )
27 13 30 15 30 P → 14 Si + +1 β0 ( Z ) 30 Al + 2 α 4 →15 P + 0 n1 ( Y )

4.

Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl– , CN– and H2O, respectively, are (A) octahedral, tetrahedral and square planar (B) tetrahedral, square planar and octahedral (C) square planar, tetrahedral and octahedral (D) octahedral, square planar and octahedral

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(A) O O NH ()  → i KOH N CH2 Br (ii ) Br CH2 Cl O O [Reason: Due to partial double bond character along C−Br bond prevents the attack of nucleophile at phenylic position] 6. Kalu Sarai. 29-A. 2+ → Octahedral The major product of the following reaction is O C NH C O O C () →  i KOH (ii) Br CH2Cl O C Br (A) C N CH2 O O (B) C N O O C N C O CH2Cl C (C) N O CH2 Br (D) CH2 Cl Sol.IITJEE2011-Paper 1-CPM-3 Sol. 26569493. the most acidic is (A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid (C) Due to ortho effect o-hydroxy benzoic acid is strongest acid and correct order of decreasing Ka is COOH OH > > > COOH COOH OH Sol. CH3 OH NO2 FIITJEE Ltd.. Ph 46106000. Among the following compounds.fiitjee. New Delhi -110016. Sarvapriya Vihar.com. . (B) [ NiCl4 ] → Tetrahedral 2−  Ni ( CN ) 4  → Square Planar   2−  Ni ( H 2 O )6    5. FIITJEE House. Fax 26513942 website: www.

Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore (C) removal of copper impurity (D) removal of iron impurity (A. 29-A. Amongst the given options.com. Ph 46106000. FIITJEE House. (D) AgNO3 + KCl ( aq ) → AgCl ( s ) + KNO3 ( aq ) (B) (Q) (D) (S) Initially there is aq. C. KCl solution now as solution of AgNO3 is added. After end point conductivity increases more rapidly because addition of excess AgNO3 solution. Each question has four choices (A). Sol. D) SnO 2 + 2C → 2CO + Sn The ore cassiterite contains the impurity of Fe.IITJEE2011-Paper 1-CPM-4 7. is (are) H H H (A) C H2C C CH2 C O (B) H C C C CH2 (C) H2C Sol. Sarvapriya Vihar. SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions.fiitjee. FIITJEE Ltd. 26569493. Fax 26513942 website: www. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). (C) and (D) out of which ONE OR MORE may be correct. New Delhi -110016. (D) H2C C CH2 (B.. The plot of conductance ( Λ ) versus the volume of AgNO3 is Λ Λ Λ Λ volume (P) volume (Q) volume (R) volume (S) (A) (P) (C) (R) Sol. 8. Hence conductivity of solution is almost compensated (or slightly increase) by the formation of KNO3. According to kinetic theory of gases (A) collisions are always elastic (B) heavier molecules transfer more momentum to the wall of the container (C) only a small number of molecules have very high velocity (D) between collisions. the molecules move in straight lines with constant velocities 9. (B). . Mn. Kalu Sarai. AgNO3(aq. W and traces of Cu. AgCl(s) is formed. 10.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. C) Along C−C single bond conformations are possible in butadiene in which all the atoms may not lie in the same plane.

(D) The structure of the compound Q is OH H3C (A) H H3C H3C (B) H3C OH C C H OH CH3 C C H CH2 CH3 H3C H3C (C) H H3C OH C CH2CHCH3 (D) H3C Sol. Kalu Sarai. Fax 26513942 website: www.. H 2SO4 ( catalytic amount ) ( i ) dil.acid ( iii ) Zn / H 2 O O C CH3 H3C 12. 29-A.fiitjee.com. in which Q is an intermediate organic compound. D) The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic (B) Physisorption may transform into chemisorption at high temperature (C) Physiosorption increases with increasing temperature but chemisorption decreases with increasing temperature (D) Chemisorption is more exothermic than physisorption. having molecular formula C6H10. (C) and (D) out of which ONLY ONE is correct. C. New Delhi -110016. 12 and 13 An acyclic hydrocarbon P. (B). Each of these questions has four choices (A). however it is very slow due to higher energy of activation (A. B. .IITJEE2011-Paper 1-CPM-5 Sol. Paragraph for Question Nos. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. (A. FIITJEE House. 13. 26569493. D) Sol. H 2SO4 / HgSO4 ( − H2O ) P  Q → 2 →  ( ii ) NaBH 4 / ethanol ( ii ) O3 ( C6 H10 ) ( iii ) dil. ( i ) conc. 11. (B) CH3 CH2 CH2 CHCH2 CH3 FIITJEE Ltd. B. Sarvapriya Vihar. gave acetone as the only organic product through the following sequence of reaction. The structure of compound P is (A) CH 3 CH 2 CH 2 CH 2 − C ≡ C − H H3C (C) H (B) H 3 CH 2 C − C ≡ C − CH 2 CH 3 H3C (D) H3C C C C CH3 C C C H H3C Sol. Ph 46106000. SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs.

Sarvapriya Vihar.com. Addition of aqueous NaCl to the blue solution gives a white precipitate O. The compound N is (A) AgNO3 (C) Al(NO3)3 (A) The final solution contains (A)  Pb ( NH 3 )4    2+ + (B) Zn(NO3)2 (D) Pb(NO3)2 Sol. 14. Fax 26513942 website: www. 29-A. 12 to 13 H3C H3C H3C C C (P) C H3C dil. H + H3C C OH CH (Q) CH3 C C ( ) → CH3  H3C H3C H3C ∆ H 2 SO 4 ( conc. FIITJEE House. Kalu Sarai. H2 SO4 → H  H3C HgSO4 O ( i ) NaBH 4 / EtOH ii dil. While Cu partially oxidizes to Cu(NO3)2 and remaining AgNO3 reacts with NaCl. 15. Addition of aqueous NH3 dissolves O and gives an intense blue solution. Ph 46106000. (C) AgNO3 + NaCl → AgCl ↓ + NaNO3 (N) ( O) (D)  Ag ( NH 3 )2  and  Ni ( NH 3 )6      2+ AgCl + 2NH 3 →  Ag ( NH 3 )2  Cl −   Cu ( NO3 ) 2 + 4NH 4 OH → Cu ( NH 3 )4    2+ + FIITJEE Ltd.. The metal rod M is (A) Fe (C) Ni (B) Cu + 2AgNO3 → Cu ( NO3 ) 2 + 2Ag M N Blue (B) Cu (D) Co Sol. 14 to 16 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. and [ CoCl 4 ] 2− 2+ (B)  Al ( NH 3 ) 4    3+ + and  Cu ( NH 3 ) 4    2+ (C)  Ag ( NH 3 )2  and Cu ( NH 3 )4      Sol. No. New Delhi -110016. 26569493.) H3C C H3C O+ O C CH3 H3C O3 / Zn / H 2 O ←  CH3 C C CH3 CH3 H3C Paragraph for Question Nos. 16. the solution turns light blue.fiitjee. .IITJEE2011-Paper 1-CPM-6 Solution for the Q.

6 × 10−34 × 3 × 108 E in eV = = 4. ( φ) of some metals is listed below.com.fiitjee. 75). Glycine contributes 47. number of electrons with ms = − will be 9. The bubble corresponding to the correct is to be darkened in the ORS.0% to the total weight of the hydrolysed products. 29-A. Wt.IITJEE2011-Paper 1-CPM-7 SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions..8 4.2 3.3 φ (eV) Sol. 796) on complete hydrolysis gives glycine (Mol. alanine and phenylalanine. The number of glycine units present in the decapeptide is (6) For n-units of glycine.7 Pt 6.6 × 10−34 × 3 × 108 J 300 × 10−9 6. Ph 46106000. ranging from 0 to 9. 2 FIITJEE Ltd. Sol. The work function Sol.. i. number of metals showing photo-electric effects will be (4). is 2 (9) For principal quantum number (n = 3) Number of orbitals = n2 = 9 1 So. . Li.4 2. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is (5) O Na O S S S O S O Na O O S will have oxidation number = +5.3 W 4. 26569493. 0 Difference in oxidation number = 5 18. n × 75 × 100 = 47 796 + 9 × 18 ) ( ⇒n=6 19. 17. (4) The energy associated with incident photon = hc λ ⇒E= 6. Sol. Wt.75 photoelectric effect when light of 300 nm wavelength falls on the metal is Metal Li Na K Mg Cu Ag 2. A decapeptide (Mol. FIITJEE House. The answer to each of the questions is a single digit integer.e.7 4. ms = − . and spin quantum 1 number. Kalu Sarai. New Delhi -110016. K. Sarvapriya Vihar. Fax 26513942 website: www. n = 3. Na.16 eV 300 × 10−9 × 1. Mg 20.3 2. The number of metals which will show Fe 4.6 ×10−19 So. The maximum number of electrons that can have principal quantum number.

. Ph 46106000. 26569493. P = 0. Sarvapriya Vihar.68 atm.32 × V = 0.com.0821 × 273 V = 7 litre (unknown compound X will not follow ideal gas equation) Sol.fiitjee. New Delhi -110016. To an evacuated vessel with movable piston under external pressure of 1 atm. at 0oC) are introduced. the total volume (in litre) of the gases at 0oC is close to (7) For any ideal gas.IITJEE2011-Paper 1-CPM-8 21. Kalu Sarai.. 29-A. T = 273 23. KOH  → H3C CH2 CH2 C CH CH3 (E & Z) H3C CH2 CH C CH2 CH3 or H3C CH2 CH2 C or CH2 CH3 (E & Z) ( only 1) FIITJEE Ltd..1. of alkenes will be = 5 Br Sol. PV = nRT 0. FIITJEE House. V = ?.0 mol of an unknown compound (vapour pressure 0. H3C CH2 CH2 C CH2 CH3 alc. The number of sodium bromide molecules involved in the balanced chemical equation is (5) 3Br2 + 3Na 2 CO3  5NaBr + NaBrO3 + 3CO2 → So.1 × 0. 22. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is (5) Total no. 0. n = 0. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. 1 atm He + X For He. Fax 26513942 website: www. number of NaBr molecules = 5 Sol.1 mol of He and 1.32 atm. Considering the ideal gas behaviour.

The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Ǻ.com.a.25 kHz (C) 7. the work done in the process is 9 3 (A) RT1 (B) RT1 2 8 15 9 (C) RT1 (D) RT1 2 8 (A) TVγ-1 = C T1(5. FIITJEE House. (C) (E0) (Projected area ) = E0a2 5.0. 29-A.II: PHYSICS SECTION – I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. 24.0.50 kHz (B) 8. The flux through the shaded area (as shown in the figure) due to this field is (A) 2E0a2 (B) 2E 0 a 2 (C) E0 a2 (D) z (a.6)2/3 = T2 (0. ˆ Consider an electric field E = E 0 x .50 kHZ (A) f= Sol. Fax 26513942 website: www. Sol.a.7 liter. 27. 320 320 + 10 × 8 × 103 × 320 − 10 320 = 8..6 liter of helium gas at STP is adiabatically compressed to 0. The speed of sound in air is 320 m/s.7)2/3 Sol. Sarvapriya Vihar.0) (0.fiitjee. 26. Taking the initial temperature to be T1. New Delhi -110016. 26569493. . A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves. (B). where E0 is a constant. The frequency of the siren heard by the car driver is (A) 8.IITJEE2011-Paper 1-CPM-9 PART . Kalu Sarai. ⇒ T2 = T1(8)2/3 = 4T1 FIITJEE Ltd. The wavelength of the second spectral line in the Balmer series of singly-ionized helium atom is (A) 1215 Ǻ (B) 1640 Ǻ (C) 2430 Ǻ (D) 4687 Ǻ (A) 1  1 1  5R = R −  = 6561  4 9  36 1  1 1  3R × 4 = 4R  −  = λ 16  4 16  λ = 1215 Ǻ.a) (a. Ph 46106000.75 kHz (D) 7. (C) and (D) out of which ONLY ONE is correct.0) y Sol.a) E0 a 2 2 x (0.5 kHz 25. Each question has four choices (A).

A ball of mass (m) 0.com. The maximum tension that the string can bear is 324 N. New Delhi -110016. The percentage of its stored energy dissipated after the switch S is turned to position 2 is (A) 0 % (B) 20 % (C) 75 % (D) 80 % 1 2 S V 2µ F 8µ F Sol. FIITJEE House.5 ω2 (0.6Ω X= 50 10 Ω B Sol. nR∆T 9 = RT1 γ −1 8 A 2 µF capacitor is charged as shown in the figure..1 ohm (B) X (48 + 2) = (10) (52 + 1) 530 = 10. . The determined value of A ‘X’ is (A) 10. (D) Ui = 1 × 2 × V2 = V2 2 qi = 2V Now.2 ohm (B) 10.6 ohm (C) 10.5 m. Ph 46106000.5) ω2 = 324 × 4 ω = 1296 = 36 rad / s FIITJEE Ltd. 30.5 kg is attached to the end of a string having length (L) 0.fiitjee. The galvanometer shows null point when tapping-key is at 52 cm mark. A meter bridge is set-up as shown.8 ohm (D) 11. The end-corrections are 1 cm and 2 cm respectively for the ends A and B. Fax 26513942 website: www. to determine an unknown resistance ‘X’ using a standard 10 ohm resistor. Kalu Sarai. 29-A. +   2 × 25 × 8 2 × 25 × 2  = 2V-q q 4V 2 5 X 29. 26569493. The ball is rotated on a horizontal circular path about vertical axis. Sarvapriya Vihar.IITJEE2011-Paper 1-CPM-10 ∴ ∆w(work done on the system) = 28. The maximum possible value of angular velocity of ball (in radian/s) is (A) 9 (B) 18 (C) 27 (D) 36 m L Sol. (D) 324 = 0. switch S is turned to position 2 2V − q q = 2 8 8V – 4q = q 8V ⇒q= 5  64V 2 4V 2  ∆ H = V2 .

com. (B) heat flow through slab E is maximum. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. Which of the following statement(s) is (are) true? (A) Restoring torque in case A = Restoring torque in case B (B) restoring torque in case A < Restoring torque in case B (C) Angular frequency for case A > Angular frequency for case B. Heat ‘Q’ flows only from left to right through the blocks. 0 A composite block is made of slabs A. Each question has four choices (A). 29-A. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (<RA) are kept far apart and each is given charge ‘+Q’. (D) heat flow through C = heat flow through B + heat flow through D. Kalu Sarai. B. Sarvapriya Vihar. A thin disk of mass ‘M’ and radius ‘R’ (<L) is attached at its center to the free end of the rod. D and E of heat different thermal conductivities (given in terms of a A 1L constant K) and sizes (given in terms of length. 31. C. (A. FIITJEE House.IITJEE2011-Paper 1-CPM-11 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. The rod-disc system performs SHM in vertical plane after being released from the same displaced position. Then 2K in steady state 3L (A) heat flow through A and E slabs are same. 26569493. Consider two ways the disc is attached: (case A). D) In case A Sol. L) as shown in the figure. (B). Fax 26513942 website: www. New Delhi -110016. Then (A) E inside = 0 (B) QA > QB A (C) Sol. ωA < ωB 32. D) RB < RA QA + QB = 2Q kQ A kQ B = RA RB σARA = σBRB 2QR A QA = RA + RB QB = 2QR B RA + RB 1L B 3K 5L E 6L 33. The disc is not free to rotate about its centre and (case B) the disc is free to rotate about its centre. (D) Angular frequency for case A < Angular frequency for case B. (C) and (D) out of which ONE OR MORE may be correct.  mℓ 2 MR 2  + + Mℓ 2  α A mg(ℓ/2) sin θ + Mg ℓ sin θ =  2  3  In case B  mℓ 2  mg (ℓ/2) sin θ + Mg ℓ sin θ =  + Mℓ 2  α B 3   τA = τB. All slabs are of same width. C. Now they are connected by a thin metal wire.. σA R B = σB R A (D) E on A surface < E on B surface (A. Ph 46106000. 4L (C) temperature difference across slab E is smallest.fiitjee. . C 4K 6K D 5K FIITJEE Ltd. B.

SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs. (B.com. To sustain the oscillations. D) Let width of each rod is d 1 4 R1 = . They enter a semiinfinite region of uniform magnetic field perpendicular to the velocity. This is the explanation of high reflectivity of metals. Taking the electronic charge as ‘e’ and the permittivity as ‘ε0’. (B) They will come out travelling along parallel paths. 24kd 2 5 1 3 4 R2 R1 R3 R4 R5 34. Each of these questions has four choices (A). C. (C) Ne 2 mε 0 (D) mε 0 Ne 2 FIITJEE Ltd. As ω approaches ωp all the free electrons are set to resonance together and all the energy is reflected. (D) They will come out at different times. If the electric field becomes zero. where a part of the energy is absorbed and a part of it is reflected.. Sarvapriya Vihar. mε0 Ne (A) (B) mε0 Ne (C) Sol. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. R4 = R3 = 2kd 5kd 1 R5 = . An electron and a proton are moving on straight parallel paths with same velocity. D) Both will travel in semicircular path Since. . B. Use dimensional analysis to determine the correct expression for ωp. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. 35. the electrons begin to oscillate about the positive ions with a natural angular frequency ‘ωp’ which is called the plasma frequency. Which of the following statement(s) is / are true? (A) They will never come out of the magnetic field region. FIITJEE House.IITJEE2011-Paper 1-CPM-12 Sol. they are displaced relatively away from the heavy positive ions. R2 = 8kd 3kd 1 4 . Kalu Sarai. hence time will be different Sol. 26569493. (C) They will come out at the same time. Ph 46106000. Paragraph for Question Nos. C. D) or (A.fiitjee. Fax 26513942 website: www. 35 and 36 A dense collection of equal number of electrons and positive ions is called neutral plasma. (B). each of mass ‘m’. Let ‘N’ be the number density of free electrons. When the electrons are subjected to an electric field. a time varying electric field needs to be applied that has an angular frequency ω. (A. (C) and (D) out of which ONLY ONE is correct. 29-A. m is different. New Delhi -110016.

Fax 26513942 website: www.fiitjee. Sarvapriya Vihar. For such systems. New Delhi -110016. (D) The phase space diagram for simple harmonic motion is a circle centered at the origin. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons N ≈ 4 × 1027 m-3. Here we consider some simple dynamical systems in onedimension. Paragraph for Question Nos. 38. Taking ε0 = 10-11 and m ≈ 10-30. The phase space diagram is x(t) vs. (C) E ∝ A2 FIITJEE Ltd.. For example.com. They are especially useful in studying the changes in motion as initial position and momenum are changed. Then (A) E1 = 2E 2 (B) E1 = 2E2 (C) E1 = 4E2 (D) E1 = 16E2 Momentum E1 E2 2a a Position Sol. 37. where these quantities are in proper SI units. The arrow on the curve indicates the time flow. and E1 and E2 are the total mechanical energies respectively. We use the sign convention in which positon or momentum upwards (or to right) is positive and downwards (or to left) is negative. (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm (B) ω = 2πc / λ Sol. . 26569493. the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure. Kalu Sarai.IITJEE2011-Paper 1-CPM-13 36. In the figure. p(t) curve in this plane. 29-A. the two circles represent the same oscillator but for different initial conditions. Ph 46106000. The phase space diagram for a ball thrown vertically up from ground is Momentum Momentum Momentum Position (A) Position (B) Position Momentum Momentum (C) Position (D) Position Sol. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. 37 to 39 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. FIITJEE House.

FIITJEE House.fiitjee.3 m/s2. Consider the spring-mass system. with the mass submerged in water. µ = = 0. (B) SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. New Delhi -110016.8 N P So..4 10 P=4 R a N α fk fs Mg FIITJEE Ltd. ranging from 0 to 9. as shown in the figure. The stick applies a force of 2N on the ring and rolls it without slipping with an acceleration of 0.5 m with a stick as shown in the figure.IITJEE2011-Paper 1-CPM-14 39. 26569493. a = Rα ∴ fK = 0. 29-A. (4) Now N − fs = ma ∴ fs = 1. 40.com. The bubble corresponding to the correct is to be darkened in the ORS. The value of P is Ground Stick Sol.4 N and (fs − fK)R = Iα. The phase space diagram for one cycle of this system is (A) Momentum (B) Momentum Position Position (C) Momentum (D) Momentum Position Position Sol. Ph 46106000. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficeint of friction between the stick and the ring is (P/10). The answer to each of the questions is a single digit integer. A boy is pushing a ring of mass 2 kg and radius 0. . Kalu Sarai. Sarvapriya Vihar. Fax 26513942 website: www.

fiitjee. Four solid spheres each of diameter 5 cm and mass 0. each of +q. m.5 ∴N=5 The activity of a freshly prepared radioactive sample is 1010 disintegrations per second. New Delhi -110016. Sarvapriya Vihar. Then the value of ‘m’ in kg is nearly (3) Change in length ∆L = ∴ m ≈ 3 kg Sol. 1/3 A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of friction is µ. The mass (in mg) of the radioactive sample is (1) Sol. The moment of inertia of the system about the diagonal of the square is N × 10−4 kgm2. and  q2  a = k  γ  Sol. The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down. 26569493. MgL = Lα∆T YA 43. Fax 26513942 website: www. FIITJEE Ltd. Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. The surface tension of the soap film is γ. Ph 46106000. then N is (5) mg(sin θ + µcosθ) = 3mg(sinθ − µcosθ) ∴ µ = 0. are rigidly fixed at the four corners of a square planar soap film of side ‘a’. The system of charges and planar film are in equilibrium. If we define N = 10 µ. The wire is cooled down from 40°C to 30°C to regain its original length ‘L’. 45. FIITJEE House. Then N is Since Felectric ∝ q2 ∝ γa a2  q2  ∴ a = k   γ  ∴N=3 44. where ‘k’ is a constant.5 kg are placed with their centers at the corners of a square of side 4 cm. Steel wire of lenght ‘L’ at 40°C is suspended from the ceiling and then a mass ‘m’ is hung from its free end. The mass of an atom of this radioisotope is 10−25 kg.. Sol. .IITJEE2011-Paper 1-CPM-15 41. whose mean life is 109 s. The coefficient of linear thermal expansion of the steel is 10−5/°C. 29-A. r a 42. Assume that L ≫ diameter of the wire. Kalu Sarai. then N is (9) 2 2  a   2  I = 2  × mr 2  + 2  mr 2 + m    5   2  5   −4 2 I = 9 × 10 kg-m ∴N=9 Sol. Four point charges. (3) 1/ N .com.

Kalu Sarai. A long circular tube of length 10 m and radius 0. Ph 46106000. Fax 26513942 website: www. 29-A. 26569493.. A wire-loop of resistance 0. . The current varies as I = I0cos(300 t) where I0 is constant. If the magnetic moment of the loop is Nµ0I0sin(300 t).1 m is placed inside the tube with its axis coinciding with the axis of the tube.fiitjee. n = 6  2  πr  FIITJEE Ltd. then ‘N’ is I Sol.005 ohm and of radius 0. New Delhi -110016. (6) µo I L µ (πr 2 ) dI dφ ∴ E ind = − =− 0 dt L dt E So magnetic moment =  ind  R Binside = µ0ni = = 6µ0I0sin(300t) Therefore. FIITJEE House.3 m carries a current I along its curved surface as shown.IITJEE2011-Paper 1-CPM-16 dN = λN dt  dN    dt  ∴N=  = 1010 ×109 = 1019 atoms λ msample = 10−25 × 1019 kg = 1 mg 46.com. Sarvapriya Vihar.

is given by (B) −3ˆ − 3ˆ + k i j ˆ (D) ˆ + 3ˆ − 3k i j ˆ FIITJEE Ltd. y0) be solution of the following equations (2x)ln2 = (3y)ln3 3lnx = 2lny Then x0 is 1 (A) 6 1 (C) 2 (C) (2x)ln2 = (3y)ln3 …(i) 3lnx = 2lny …(ii) ⇒ (logx) (log3) = (logy)log2 (log x )(log 3) ⇒ logy = …(iii) log 2 In (i) taking log both sides (log2) {log2 + logx} = log3{log3 + logy} (log2)2 + (log2) (logx) = (log3)2 + ⇒ (log2)2 − (log3)2 = ⇒ x= 48. Sol. whose i j ˆ i j ˆ i j ˆ projection on c is (A) ˆ − 3ˆ + 3k i j ˆ (C) 3ˆ − ˆ + 3k i j ˆ 1 3 . 26569493. 29-A.fiitjee. 47. Kalu Sarai. . (B). A vector v in the plane of a and b . Ph 46106000.IITJEE2011-Paper 1-CPM-17 PART .III: MATHEMATICS SECTION – I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. Each question has four choices (A). New Delhi -110016. 49. Let a = ˆ + ˆ + k . (log 3)2 (log x) log 2 from (iii) (log 3) 2 − (log 2)2 (log x) ⇒ −log2 = logx log 2 1 1 ⇒ x0 = .com. FIITJEE House. Then (A) P ⊂ Q and Q − P ≠ ∅ (B) Q ⊄ P (C) P ⊄ Q (D) P = Q (D) In set P. Fax 26513942 website: www. Sarvapriya Vihar. 2 2 Let P = {θ : sin θ − cos θ = 2 cos θ} and Q = {θ : sin θ + cos θ = 2 sin θ} be two sets. sinθ = In set Q. Let (x0. (B) 1 3 (D) 6 Sol. (C) and (D) out of which ONLY ONE is correct.. ( ) 2 + 1 cos θ ⇒ tanθ = ) 2 +1 ( 2 − 1 sin θ = cos θ ⇒ tan θ = 1 2 −1 = 2 + 1 ⇒ P = Q. b = ˆ + ˆ + k and c = ˆ − ˆ − k be three vectors.

(B) (A) x2 = t ⇒ 2x dx = dt ln 3 ln 3 sin ( ln 6 − t ) 1 sin t 1 dt and I = ∫ dt I= ∫ 2 ln 2 sin t + sin ( ln 6 − t ) 2 ln 2 sin ( ln 6 − t ) + sin t 2I = ln 3 1 3 1 ∫21dt ⇒ I = 4 ln 2 . A straight line L through the point (3. 3 ∴ Equation is y + 2 = 3 ( x − 3) 3x − y − 2 + 3 3 = 0 60° (3. −2) is inclined at an angle 60° to the line intersects the x-axis. FIITJEE House. 29-A. If L also 3y − x + 3 + 2 3 = 0 (D) 3y + x − 3 + 2 3 = 0 Sol. New Delhi -110016.IITJEE2011-Paper 1-CPM-18 Sol. Ph 46106000.com. −2) ( ) Let α and β be the roots of x2 – 6x – 2 = 0. . then the value of is (A) 1 (C) 3 (B) 2 (D) 4 a10 − 2a 8 2a 9 FIITJEE Ltd..fiitjee. v = 3i − ˆ + 3k . Fax 26513942 website: www. 1) ⇒ 4m = 0 ⇒ m = 0 or 2m = 2 3 ⇒ m = ⇒ 52. ln 3 50. The value of ∫ ln 2 sin x 2 + sin ( ln 6 − x 2 ) x sin x 2 dx is 1 3 ln 2 2 1 3 (D) ln 6 2 1 3 ln 4 2 3 (C) ln 2 (A) Sol. Sarvapriya Vihar. (B) m+ 3 1 − 3m = 3 y =. 26569493. then the equation of L is (A) y + 3x + 2 − 3 3 = 0 (B) y − 3x + 2 + 3 3 = 0 (C) 3x + y = 1 . If an = αn – β n for n ≥ 1.3x + 1 m ⇒ m+ 3 = ± ( 3 − 3m ) (0. Kalu Sarai. (C) v = λ a + µb = λ ˆ+ˆ+k +µ ˆ−ˆ+k i j ˆ i j ˆ ( ) ( ) Projection of v on c ˆ i j ˆ ( λ + µ ) ˆ + ( λ − µ ) ˆ + ( λ + µ ) k  ⋅ ˆ − ˆ − k i j v⋅c 1 1  = = ⇒  |c| 3 3 3 ⇒λ+µ−λ+µ−λ−µ=1⇒µ−λ=1⇒λ=µ−1 ˆ ˆ i j ˆ v = ( µ − 1) ˆ + ˆ + k + µ ˆ − ˆ + k = µ 2i + 2k − ˆ − ˆ − k i j ˆ i j ˆ ( ) ( ) ( ) ( ) ˆ v = ( 2µ − 1) ˆ − ˆ + ( 2µ − 1) k i j ˆ j ˆ At µ = 2. with α > β . 2 ln 51.

Then b equals 4 3 1 (A) (B) 4 2 1 1 (C) (D) 4 3 (B) ∵ ∫ (1 − x ) dx − ∫ (1 − x ) dx = 2 2 0 b b 1 53. then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous ∀ x ∈ R (C) f′(x) is constant ∀ x ∈ R (D) f(x) is differentiable except at finitely many points Sol. Each question has four choices (A). If f(x) is differentiable at x = 0. FIITJEE Ltd. (B. C) ∵ f(0) = 0 and f′(x) = lim = = lim h →0 h →0 f (x + h ) − f (x) h f (h) = f′(0) = k(say) h ⇒ f(x) = kx + c ⇒ f(x) = kx (∵ f(0) = 0). . FIITJEE House.. (B). 26569493. 1 4 ⇒ ⇒ ( x − 1) 3 3 b − 0 ( x − 1)3 3 1 R1 o b 1 = 4 3 R2 b 1 ( b − 1) 1  ( b − 1)  1 + −0 − = 3 3  3  4 3 2 ( b − 1) 1 1 1 ⇒ =− ⇒ (b – 1)3 = – ⇒ b = . (C) an = αn − β n α2 − 6α − 2 = 0 Multiply with α8 on both sides ⇒ α10 − 6α9 − 2α8 = 0 …(i) …(ii) similarly β 10 − 6β9 − 2β8 = 0 (i) and (ii) ⇒ α10 − β 10 − 6(α9 − β 9) = 2(α8 − β 8) a − 2a 8 ⇒ a10 − 6a9 = 2a8 ⇒ 10 =3.IITJEE2011-Paper 1-CPM-19 Sol. New Delhi -110016. 54. Ph 46106000. Let f: R → R be a function such that f(x + y) = f(x) + f(y).fiitjee. Kalu Sarai. y = 0 and x = 0 into two parts R1(0 ≤ x 1 ≤ b) and R2(b ≤ x ≤ 1) such that R1 − R2 = . ∀ x. Fax 26513942 website: www. Sarvapriya Vihar. Sol. 2a 9 Let the straight line x = b divides the area enclosed by y = (1 − x)2. y ∈ R. 2 3 12 8 3 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions.com. (C) and (D) out of which ONE or MORE may be correct. 29-A.

.fiitjee.IITJEE2011-Paper 1-CPM-20 55. Note: A skew symmetric matrix of order 3 cannot be non-singular hence the question is wrong. Sarvapriya Vihar. D) ˆ Any vector in the plane of ˆ + ˆ + 2k and ˆ + 2ˆ + k is r = ( λ + µ ) ˆ + ( λ + 2µ ) ˆ + ( 2λ + µ ) k i j ˆ i j ˆ i j Also. D) Ellipse is x 2 y2 + =1 2 2 12 12 = 22 (1 − e2) ⇒ e = 3 2 2 4  ⇒ b2 = a 2  − 1 ⇒ 3b2 = a2 3 3  ∴ eccentricity of the hyperbola is Foci of the ellipse are ( 3. Let M and N be two 3 × 3 non-singular skew symmetric matrices such that MN = NM.com..N(M)−1(NT)−1MT = +M2NM−1N−1MT = −M. If the a 2 b2 hyperbola passes through a focus of the ellipse. 0  ≡ (2. If PT denotes the transpose of P. 0) (D) the equation of the hyperbola is x2 – 3y2 = 3 (C) the eccentricity of the hyperbola is Sol.MT = M2N. (B. 29-A. r ⋅ c = 0 ⇒ λ + µ = 0 ⇒  r a b = 0 . 0) ≡  3 × . Ph 46106000.NMM−1N−1M = −MNN−1M = −M2. FIITJEE Ltd. Kalu Sarai. New Delhi -110016. 0 and − 3. then (A) the equation of the hyperbola is x2 − y2 x 2 y2 − =1 3 2 5 3 (B) a focus of the hyperbola is (2. then M2N2 (MTN)–1 (MN–1)T is equal to (A) M2 (B) – N2 2 (C) – M (D) MN Sol. The vector(s) which is/are coplanar with vectors ˆ + ˆ + 2k and ˆ + 2ˆ + k . Let the eccentricity of the hyperbola = 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. Hyperbola passes through ( ) 3. (C) MN = NM M2N2(MTN)−1(MN−1)T M2N2N−1(MT)−1(N−1)T. 0 . 3   57. 0). FIITJEE House. (A. 26569493. 0 ) ( ) 3 = 1 ⇒ a2 = 3 and b2 = 1 2 a ∴ Equation of hyperbola is x2 − 3y2 = 3  2  Focus of hyperbola is (ae. and perpendicular to the vector i j ˆ i j ˆ ˆ + ˆ + k is/are i j ˆ (A) ˆ − k j ˆ (C) ˆ − ˆ i j (B) −ˆ + ˆ i j (D) −ˆ + k j ˆ Sol.   56.(MT)−1(N−1)TMT = −M2. Fax 26513942 website: www.

Given that the drawn ball from U2 is white.IITJEE2011-Paper 1-CPM-21 SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs. with reference to (E). 58 to 59 Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls. 58. Fax 26513942 website: www. . Ph 46106000. However. and U2 contains only 1 white ball. b and c be three real numbers satisfying [ a b c ]  8 2 7  = [ 0 0 0]   7 3 7    60. c). (B).    2  5  2  5 2  2  5 C2  2  5 C2 3  2  5 C2 3  30    59. the probability that head appeared on the coin is 17 11 (A) (B) 23 23 15 12 (C) (D) 23 23 (D) Sol. A fair coin is tossed. If head appears then 1 ball is drawn at random from U1 and put into U2. if tail appears then 2 balls are drawn at random from U1 and put into U2. Kalu Sarai. then the value of 7a + b + c is (A) 0 (B) 12 (C) 7 (D) 6 Sol. Paragraph for Question Nos. Each of these questions has four choices (A).. New Delhi -110016. FIITJEE House. 23 / 30 23  W  P (W / T ) ⋅ P ( T ) + ( W / H ) ⋅ P ( H ) Paragraph for Question Nos. 26569493. 1  3  1  2 1  1  3 C 2  1  2 C 2 1  1  3 C1 ⋅2 C1 2  23 ×  × 1 + ×  ×  + ×  × 1 + ×  ×  + × ×  = . (D) a + 8b + 7c = 0 9a + 2b + 3c = 0 FIITJEE Ltd.fiitjee. The probability of the drawn ball from U2 being white is 13 (A) (B) 30 19 (D) (C) 30 (B) H → 1 ball from U1 to U2 T → 2 ball from U1 to U2 E : 1 ball drawn from U2 P/W from U2 = 23 30 11 30 Sol. lies on the plane 2x + y + z = 1. Now 1 ball is drawn at random from U2. 13 2 1  ×1 + ×  12 P( W / H) × P( H) H 25 5 2 P  = = = . ……(E) If the point P(a.com. b. 29-A. 60 to 62 1 9 7  Let a. (C) and (D) out of which ONLY ONE is correct. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. Sarvapriya Vihar.

New Delhi -110016. FIITJEE House. The bubble corresponding to the correct is to be darkened in the ORS. ranging from 0 to 9. 4) B(0. If α and β are the roots of the quadratic equation ax2 + bx + c = 0. Then 1 is ∆2 Sol.2. b = 6. b and c satisfies (E) b = 12. −4) FIITJEE Ltd. and ∆2 be the area of the triangle formed by drawing tangents at P 2  ∆ and at the end points of the latus rectum. 0) x=−2 M (2. If a = 2 with b and c satisfying (E). 0) C (2. .. 62. 29-A. c = – 14 3 1 3 3 1 3 + b + c = 2 + 12 + −14 = –2. (2) y2 = 8x = 4. 2  on the parabola. then the value of 3 1 3 + + is equal to ωa ωb ωc (A) –2 (B) 2 (C) 3 (D) – 3 (A) a = 2. β = – 7 ∑  1 1 1 1   −  = 7. 2) (0.fiitjee.IITJEE2011-Paper 1-CPM-22 a+b+c=0 Solving these we get b = 6a ⇒ c = – 7a now 2x + y + z = 0 ⇒ 2a + 6a + (–7a) = 1 ⇒ a = 1. 63.com. Fax 26513942 website: www. 26569493. then ∞ Sol. Sarvapriya Vihar. ∑  1 1 α +β  n =0  n is (B) 7 (D) ∞ (A) 6 6 (C) 7 Sol. Kalu Sarai. c = – 7. The answer to each of the questions is a single digit integer. Let ω be a solution of x3 – 1 = 0 with Im(ω) > 0.x ∆LPM =2 ∆ABC ∆1 =2 ∆2 L A (2. Let ∆1 be the area of the triangle formed by the end points of its latus rectum 1  and the point P  . Consider the parabola y2 = 8x. (B) ax2 + bx + c = 0 ⇒ x2 + 6x – 7 = 0 ⇒ α = 1. Ph 46106000. 61. a ω ω ω ω ω ω Let b = 6. 2) P(1/2. with a and c satisfying (E). α + β = 1 7   n =0  n =0 ∞ n ∑ ∞ n SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions.

 = 1 x dx x dx  x  integrating y = x+c x Put x = 1. Let f: [1. π π d   sin θ   Let f(θ) = sin  tan −1    .. = e ∫ − x dx = e − loge x 1 x 1 Multiplying (i) both sides by 1 dy 1 d  1 − 2 y = 1⇒  y. Note: If we put x = 1 in the given equation we get f(1) = 1/3. 29-A. 26569493. Kalu Sarai.com. ∞) → [2. then the value of f(2) is Sol. If 6 f ( t ) dt = 3xf ( x ) − x 3 for all x ≥ 1 ∫ x 1. where θ ∈  − .IITJEE2011-Paper 1-CPM-23 64.   sin θ    π π sin  tan −1    . Fax 26513942 website: www. where − 4 < θ < 4 .fiitjee. Sarvapriya Vihar. 65. New Delhi -110016.   4 4  cos 2θ       sin θ sin  tan −1      2  2cos θ − 1    = sin ( sin −1 ( tan θ ) ) = tan θ. . ∞) be a differentiable function such that f(1) = 2.F. Then the value of d ( tan θ ) ( f ( θ ) ) is  cos 2θ    (1) Sol. y = 2 ⇒ 2 = 1 + c ⇒ c = 1 ⇒ y = x2 + x ⇒ f(x) = x2 + x ⇒ f(2) = 6. The positive integer value of n > 3 satisfying the equation 1 1 1 = + is π  2π   3π  sin   sin   sin   n  n   n  Sol. FIITJEE House. 66. (7) π 2π  2π  3π π sin − sin  2sin cos  sin 1 1 1 n n  n  n n = ⇒ =1 − = π 3π 2π π 3π π 3π 2π sin sin sin sin sin sin sin sin n n n n n n n n 1 FIITJEE Ltd. (6) 6 f ( t ) dt = 3x f(x) – x3 ⇒ 6f(x) = 3f(x) + 3xf′(x) – 3x2 1 ∫ x ⇒ 3f(x) = 3xf′(x) – 3x2 ⇒ xf′(x) – f(x) = x2 dy dy 1 − y = x2 ⇒ − y = x …(i) ⇒ x dx dx x I. d ( tan θ ) d ( tan θ ) =1. Ph 46106000.

n n n n Let a1. Sp = ∑a i =1 p i . … a100 is an A. The minimum value of the sum of real numbers a–5. then the minimum value of |2z – 6 + 5i| is (5) Length AB = 5 2 ⇒ Minimum value = 5. a3. For any integer Sm does not depend on n. Sn 68. Fax 26513942 website: www. Sol. …. a8 and a10 with a > 0 is (8) a −5 + a −4 + a −3 + a −3 + a −3 + a 8 + a10 + 1 ≥1 8 minimum value = 8. (9) a1.P. Kalu Sarai. 2) B (3. 4π 3π 4π 3π = sin ⇒ + = π ⇒ n = 7. New Delhi -110016. Sol. a3. −5/2) 69. a2. 26569493. then a2 is Sn Sol. If ∑a i =1 p i .. 29-A. 1. 1 ≤ p ≤ 1 00 5n ( 6 + ( 5n − 1) d ) Sm S5n = = 2 n Sn Sn ( 6 − d + nd ) 2 Sm is independent of n of 6 − d = 0 ⇒ d = 6. FIITJEE House. (0. a–4. 0) C (3. If z is any complex number satisfying |z – 3 – 2i| ≤ 2. let m = 5n. a100 be an arithmetic progression with a1 = 3 and Sp = n with 1 ≤ n ≤ 20.IITJEE2011-Paper 1-CPM-24 ⇒ sin 67.fiitjee. 3a–3. Sarvapriya Vihar. a2. Ph 46106000. 1 ≤ p ≤ 100.com. FIITJEE Ltd. 0) A(3. a1 = 3. .

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