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PART A: CHEHISTRY
1. The standard enthalpy of formation of NH
3
is –46.0 kJ mol
–1
. If the enthalpy of formation of H
2
from
its atoms is –436 kJ mol
–1
and that of N
2
is –712 kJ mol
–1
, the average bond enthalpy of N–H bond in
NH
3
is
(1) –964 kJ mol
–1
(2) +352 kJ mol
–1
(3) + 1056 kJ mol
–1
(4) –1102 kJ mol
–1
1. (2)
Sol : Enthalpy of formation of NH
3
= –46 kJ/mole
∴ N
2
+ 3H
2
→ 2NH
3
∆H
f
= – 2 x 46 kJ mol
Bond breaking is endothermic and Bond formation is exothermic
Assuming ‘x’ is the bond energy of N–H bond (kJ mol
–1
)
∴ 712 + (3 x 436)– 6x = –46 x 2
∴ x = 352 kJ/mol
2. The time for half life period of a certain reaction A → products is 1 hour. When the initial
concentration of the reactant ‘A’, is 2.0 mol L
–1
, how much time does it take for its concentration to
come from 0.50 to 0.25 mol L
–1
if it is a zero order reaction ?
(1) 4 h (2) 0.5 h (3) 0.25 h (4) 1 h
2. (3)
Sol : For a zero order reaction
x
k
t
= → (1)
Where x = amount decomposed
k = zero order rate constant
for a zero order reaction
[ ]
0
1
2
A
k
2t
= → (2)
Since [A
0
] = 2M , t
1/2
= 1 hr; k = 1
∴ from equation (1)
0.25
t 0.25hr
1
= =
3. A solution containing 2.675 g of CoCl
3
. 6 NH
3
(molar mass = 267.5 g mol
–1
) is passed through a
cation exchanger. The chloride ions obtained in solution were treated with excess of AgNO
3
to give
4.78 g of AgCl (molar mass = 143.5 g mol
–1
). The formula of the complex is (At. Mass of Ag = 108 u)
(1) [Co(NH
3
)
6
]Cl
3
(2) [CoCl
2
(NH
3
)
4
]Cl (3) [CoCl
3
(NH
3
)
3
] (4) [CoCl(NH
3
)
5
]Cl
2
3. (1)
Sol : CoCl
3
. 6NH
3
→ xCl
–
AgNO
3
→x AgCl ↓
n(AgCl) = x n(CoCl
3
. 6NH
3
)
4.78 2.675
x
143.5 267.5
= ∴ x = 3
∴ The complex is ( )
3 3
6
Co NH Cl (
¸ ¸
4. Consider the reaction :
Cl
2
(aq) + H
2
S(aq) → S(s) + 2H
+
(aq) + 2Cl
–
(aq)
The rate equation for this reaction is rate = k [Cl
2
] [H
2
S]
Which of these mechanisms is/are consistent with this rate equation ?
(A) Cl
2
+ H
2
→ H
+
+ Cl
–
+ Cl
+
+ HS
–
(slow)
Cl
+
+ HS
–
→ H
+
+ Cl
–
+ S (fast)
(B) H
2
S ⇔ H
+
+ HS
–
(fast equilibrium)
Cl
2
+ HS
–
→ 2Cl
–
+ H
+
+ S (slow)
(1) B only (2) Both A and B (3) Neither A nor B (4) A only
4. (4)
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Sol: Rate equation is to be derived wrt slow
Step ∴ from mechanism (A)
Rate = k[Cl
2
] [H
2
S]
5. If 10
–4
dm
3
of water is introduced into a 1.0 dm
3
flask to 300 K, how many moles of water are in the
vapour phase when equilibrium is established ?
(Given : Vapour pressure of H
2
O at 300 K is 3170 Pa ; R = 8.314 J K
–1
mol
–1
)
(1) 5.56 x 10
–3
mol (2) 1.53 x 10
–2
mol (3) 4.46 x 10
–2
mol (4) 1.27 x 10
–3
mol
5. (4)
Sol :
PV
n
RT
= =
= 128 x 10
–5
moles
=
5
1 1
3170 10 atm 1L
0.0821L atm k mol 300K
−
− −
× ×
×
≈ 1.27 x 10
–3
mol
6. One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular
mass of 44 u. The alkene is
(1) propene (2) 1–butene (3) 2–butene (4) ethene
6. (3)
Sol : 2–butene is symmetrical alkene
CH
3
–CH=CH–CH
3
O
3
3 Zn / H O
2
2.CH CHO →
Molar mass of CH
3
CHO is 44 u.
7. If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous
solution, the change in freezing point of water (∆T
f
), when 0.01 mol of sodium sulphate is dissolved
in 1 kg of water, is (K
f
= 1.86 K kg mol
–1
)
(1) 0.0372 K (2) 0.0558 K (3) 0.0744 K (4) 0.0186 K
7. (2)
Sol : Vant Hoff’s factor (i) for Na
2
SO
4
= 3
∴ ∆T
f
= (i) k
f
m
= 3 x 1.80 x
0.01
0.0558 K
1
=
8. From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous
ZnCl
2
, is
(1) 2–Butanol (2) 2–Methylpropan–2–ol (3) 2–Methylpropanol (4) 1–Butanol
8. (2)
Sol : 3° alcohols react fastest with ZnCl
2
/conc.HCl due to formation of 3° carbocation and
∴ 2–methyl propan–2–ol is the only 3° alcohol
9. In the chemical reactions,
NH
2
NaNO
2
HCl, 278 K
A
HBF
4
B
the compounds ‘A’ and ‘B’ respectively are
(1) nitrobenzene and fluorobenzene (2) phenol and benzene
(3) benzene diazonium chloride and fluorobenzene (4) nitrobenzene and chlorobenzene
9. (3)
Sol :
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NH
2
N
2
Cl
NaNO
2
HCl, 278 K
HBF
4
F
N
2
BF
3
HCl
(A) (B)
benzene diazonium
chloride
fluorobenzene
10. 29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl’s method
and the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid
required 15 mL of 0.1 M NaOH solution for complete neutralization. The percentage of nitrogen in
the compound is
(1) 59.0 (2) 47.4 (3) 23.7 (4) 29.5
10. (3)
Sol : Moles of HCl reacting with
ammonia = (moles of HCl absorbed ) – (moles of NaOH solution required)
= (20 x 0.1 x 10
–3
) – (15 x 0.1 x 10
–3
)
= moles of NH
3
evolved.
= moles of nitrogen in organic compound
∴ wt. of nitrogen in org. comp = 0.5 x 10
–3
x 14
= 7 x 10
–3
g
% wt =
3
3
7 10
23.7%
29.5 10
−
−
×
=
×
11. The energy required to break one mole of Cl–Cl bonds in Cl
2
is 242 kJ mol
–1
. The longest
wavelength of light capable of breaking a single Cl – Cl bond is
(c = 3 x 10
8
ms
–1
and N
A
= 6.02 x 10
23
mol
–1
)
(1) 594 nm (2) 640 nm (3) 700 nm (4) 494 nm
11. (4)
Sol : Energy required for 1 Cl
2
molecule =
3
A
242 10
N
×
Joules.
This energy is contained in photon of wavelength ‘λ’.
34 8 3
23
hc 6.626 10 3 10 242 10
E
6.022 10
−
× × × ×
= ¬ =
λ λ ×
λ = 4947
0
A ≈ 494 nm
12. Ionisation energy of He
+
is 19.6 x 10
–18
J atom
–1
. The energy of the first stationary state (n = 1) of Li
2+
is
(1) 4.41 x 10
–16
J atom
–1
(2) –4.41 x 10
–17
J atom
–1
(3) –2.2 x 10
–15
J atom
–1
(4) 8.82 x 10
–17
J atom
–1
12. (2)
Sol :
2
2 2
He He
1 1
IE 13.6 Z
1
+ +
(
= −
(
∞
¸ ¸
=
( )
2
He He
13.6Z where Z 2
+ +
=
Hence
2 18
He
13.6 Z 19.6 10
−
+
× = × J atom
–1
.
( )
2
2
1 2 2 Li
Li
1
E 13.6 Z
1
+
+
= − × =
2
2
2 Li
2
He
He
Z
13.6 Z
Z
+
+
+
(
( − ×
(
¸ ¸
= –19.6 x 10
–18
x
17
9
4.41 10 J/ atom
4
−
= − ×
13. Consider the following bromides :
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Me Br
Br
Me Me
Br
Me
(A)
(B)
(C)
The correct order of S
N
1 reactivity is
(1) B > C > A (2) B > A > C (3) C > B > A (4) A > B > C
13. (1)
Sol : S
N
1 proceeds via carbocation intermediate, the most stable one forming the product faster. Hence
reactivity order for A, B, C depends on stability of carbocation created.
Me
Me
Me
Me
> >
14. Which one of the following has an optical isomer ?
(1) ( )( )
2
3
2
Zn en NH
+
(
¸ ¸
(2) ( )
3
3
Co en
+
(
¸ ¸
(3) ( ) ( )
3
2
4
Co H O en
+
(
¸ ¸
(4) ( )
2
2
Zn en
+
(
¸ ¸
(en = ethylenediamine)
14. (2)
Sol : Only option (2) is having non–super imposable mirror image & hence one optical isomer.
Zn
+
NH
3
NH
3
en
no optical isomer. It is
Tetrahedral with a plane of symmetry
Co
+
Co
+
en
en
en
en
en
en
optical isomer
( 1)
( 2)
2
3
3
H
2
O
H
2
O
Co
+
H
2
O
H
2
O
en
Horizontal plane is plane of symmtry
Zn
+
en
en
no optical isomer, it is
tetrahedral with a plane of symmetry
3)
4)
3
2
15. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two
liquid components (heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of
the solution obtained by mixing 25.0g of heptane and 35 g of octane will be (molar mass of heptane
= 100 g mol
–1
an dof octane = 114 g mol
–1
).
(1) 72.0 kPa (2) 36.1 kPa (3) 96.2 kPa (4) 144.5 kPa
15. (1)
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Sol : Mole fraction of Heptane =
25/100 0.25
0.45
25 35
0.557
100 114
= =
+
Heptane
X 0.45 = .
∴ Mole fraction of octane = 0.55 = X
octane
Total pressure =
0
i i
XP
¿
= (105 x 0.45) + (45 x 0.55) kP
a
= 72.0 KPa
16. The main product of the following reaction is C
6
H
5
CH
2
CH(OH)CH(CH
3
)
2
conc. H SO
2 4
→ ?
(1)
C C
H
5
C
6
H CH(CH
3
)
2
H
(2)
C C
C
6
H
5
CH
2
H CH
3
CH
3
(3) C C
C
6
H
5
H H
CH(CH
3
)
2
(4)
C CH
2
H
5
C
6
CH
2
CH
2
H
3
C
16. (1)
Sol :
CH
2
CH
OH
CH
CH
3
CH
3
CH
2
CH CH
CH
3
CH
3
CH CH HC
CH
3
CH
3
H
2
SO
4
conc.
loss of proton
(conjugated system)
Trans isomers is more stable & main product here
C C
H
CH(CH
3
)
2
H
(trans isomer)
17. Three reactions involving
2 4
H PO
−
are given below :
(i) H
3
PO
4
+ H
2
O → H
3
O
+
+
2 4
H PO
−
(ii)
2 4
H PO
−
+ H
2
O →
2
4
HPO
−
+ H
3
O
+
(iii)
2
2 4 3 4
H PO OH H PO O
− − −
+ → +
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In which of the above does
2 4
H PO
−
act as an acid ?
(1) (ii) only (2) (i) and (ii) (3) (iii) only (4) (i) only
17. (1)
Sol : (i)
3 4
acid
H PO + H
2
→
3
H O
+
+
2 4
conjugate base
H PO
−
(ii)
2 4
acid
H PO
−
+ H
2
O →
2
4
conjugate base
HPO
−
+
3
H O
+
(iii)
2 4
acid
H PO
−
+
acid
OH
−
→
3 4
conjugate acid
H PO + O
–2
Only in reaction (ii)
2 4
H PO
−
acids as ‘acid’.
18. In aqueous solution the ionization constants for carbonic acid are
K
1
= 4.2 x 10
–7
and K
2
= 4.8 x 10
–11
Select the correct statement for a saturated 0.034 M solution of the carbonic acid.
(1) The concentration of
2
3
CO
−
is 0.034 M.
(2) The concentration of
2
3
CO
−
is greater than that of
3
HCO
−
.
(3) The concentration of H
+
and
3
HCO
−
are approximately equal.
(4) The concentration of H
+
is double that of
2
3
CO
−
.
18. (3)
Sol : A → H
2
CO
3
H
+
+
3
HCO
−
K
1
= 4.2 x 10
–7
B →
3
HCO
−
H
+
+
2
3
CO
−
K
2
= 4.8 x 10
–11
As K
2
<< K
1
All major
total A
H H
+ +
( ( ≈
¸ ¸ ¸ ¸
and from I equilibrium,
3
A total
H HCO H
+ − +
( ( ( ≈ ≈
¸ ¸ ¸ ¸ ¸ ¸
2
3
CO
−
(
¸ ¸
is negligible compared to
3
total
HCO or H
− +
( (
¸ ¸ ¸ ¸
19. The edge length of a face centered cubic cell of an ionic substance is 508 pm. If the radius of the
cation is 110 pm, the radius of the anion is
(1) 288 pm (2) 398 pm (3) 618 pm (4) 144 pm
19. (4)
Sol : For an ionic substance in FCC arrangement,
( )
2 r r
+ −
+ = edge length
( )
2 110 r
−
+ = 508
r
–
= 144 pm
20. The correct order of increasing basicity of the given conjugate bases (R = CH
3
) is
(1)
2
RCOO HC C R NH < = < < (2)
2
R HC C RCOO NH < ≡ < <
(3)
2
RCOO NH HC C R < < ≡ < (4)
2
RCOO HC C NH R < ≡ < <
20. (4)
Sol : Correct order of increasing basic strength is
R–COO
(–)
< CH≡C
(–)
<
( )
2
NH
−
< R
(–)
21. The correct sequence which shows decreasing order of the ionic radii of the elements is
(1) Al
3+
> Mg
2+
> Na
+
> F
–
> O
2–
(2) Na
+
> Mg
2+
> Al
3+
> O
2–
> F
–
(3) Na
+
> F
–
> Mg
2+
> O
2–
> Al
3+
(4) O
2–
> F
–
> Na
+
> Mg
2+
> Al
3+
21. (4)
Sol : For isoelectronic species higher the
Z
e
ratio , smaller the ionic radius
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z
e
for
2
8
O 0.8
10
−
= =
9
F 0.9
10
−
= =
11
Na 1.1
10
+
= =
2
12
Mg 1.2
10
+
= =
3
13
Al 1.3
10
+
= =
22. Solubility product of silver bromide is 5.0 x 10
–13
. The quantity of potassium bromide (molar mass
taken as 120 g of mol
–1
) to be added to 1 litre of 0.05 M solution of silver nitrate to start the
precipitation of AgBr is
(1) 1.2 x 10
–10
g (2) 1.2 x 10
–9
g (3) 6.2 x 10
–5
g (4) 5.0 x 10
–8
g
22. (2)
Sol : Ag
+
+ Br
–
AgBr
Precipitation starts when ionic product just exceeds solubility product
sp
K Ag Br
+ −
( ( =
¸ ¸ ¸ ¸
13
sp 11
K
5 10
Br 10
0.05 Ag
−
− −
+
×
( = = =
¸ ¸
(
¸ ¸
i.e., precipitation just starts when 10
–11
moles of KBr is added to 1L of AgNO
3
solution.
No. of moles of KBr to be added = 10
–11
∴ weight of KBr to be added = 10
–11
x 120
= 1.2 x 10
–9
g
23. The Gibbs energy for the decomposition of Al
2
O
3
at 500°C is as follows :
2
3
Al
2
O
3
→
4
3
Al + O
2
, ∆
r
G = + 966 kJ mol
–1
The potential difference needed for electrolytic reduction of Al
2
O
3
at 500°C is at least
(1) 4.5 V (2) 3.0 V (3) 2.5 V (4) 5.0 V
23. (3)
Sol : ∆G = – nFE ¬
G
E
nF
−∆
=
3
966 10
E
4 96500
×
= −
×
= –2.5 V
∴ The potential difference needed for the reduction = 2.5 V
24. At 25°C, the solubility product of Mg(OH)
2
is 1.0 x 10
–11
. At which pH, will Mg
2+
ions start precipitating
in the form of Mg(OH)
2
from a solution of 0.001 M Mg
2+
ions ?
(1) 9 (2) 10 (3) 11 (4) 8
24. (2)
Sol :
2
2
Mg 2OH Mg(OH)
+ −
+
2
2
sp
sp 4
2
OH H
K Mg OH
K
OH 10
Mg
p 4 and p 10
+ −
− −
+
( ( =
¸ ¸ ¸ ¸
( = =
¸ ¸
(
¸ ¸
∴ = =
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25. Percentage of free space in cubic close packed structure and in body centred packed structure are
respectively
(1) 30% and 26% (2) 26% and 32% (3) 32% and 48% (4) 48% and 26%
25. (2)
Sol : packing fraction of cubic close packing and body centred packing are 0.74 and 0.68 respectively.
26. Out of the following, the alkene that exhibits optical isomerism is
(1) 3–methyl–2–pentene (2) 4–methyl–1–pentene
(3) 3–methyl–1–pentene (4) 2–methyl–2–pentene
26. (3)
Sol :
H
2
C=HC C
2
H
5
H
CH
3
only 3–methyl–1–pentene has a chiral carbon
27. Biuret test is not given by
(1) carbohydrates (2) polypeptides (3) urea (4) proteins
27. (1)
Sol : It is a test characteristic of amide linkage. Urea also has amide linkage like proteins.
28. The correct order of
0
2
M / M
E
+
values with negative sign for the four successive elements Cr, Mn, Fe
and Co is
(1) Mn > Cr > Fe > Co (2) Cr > Fe > Mn > Co (3) Fe > Mn > Cr > Co (4) Cr > Mn > Fe > Co
28. (1)
29. The polymer containing strong intermolecular forces e.g. hydrogen bonding, is
(1) teflon (2) nylon 6,6 (3) polystyrene (4) natural rubber
29. (2)
Sol : nylon 6,6 is a polymer of adipic acid and hexamethylene diamine
C
O
(CH
2
)
4
C
O
NH (CH
2
)
6
NH
n
30. For a particular reversible reaction at temperature T, ∆H and ∆S were found to be both +ve. If T
e
is
the temperature at equilibrium, the reaction would be spontaneous when
(1) T
e
> T (2) T > T
e
(3) T
e
is 5 times T (4) T = T
e
30. (2)
Sol : G H T S ∆ = ∆ − ∆
at equilibrium, ∆G = 0
for a reaction to be spontaneous ∆G should be negative
e
T T ∴ >
PART B: PHYSICS
31. A rectangular loop has a sliding connector PQ of length and resistance R Ω and it is moving with a
speed v as shown. The setup is placed in a uniform magnetic field going into the plane of the paper.
The three currents I
1
, I
2
and I are
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(1)
1 2
B v 2B v
I I , I
R R
= − = =
(2)
1 2
B v 2B v
I I , I
3R 3R
= = =
(3)
1 2
B v
I I I
R
= = =
(4)
1 2
B v B v
I I , I
6R 3R
= = =
31. 2
Sol. A moving conductor is equivalent to a battery of emf = v B (motion emf)
Equivalent circuit
1 2
I I I = +
applying Kirchoff’s law
1
I R IR vB 0 + − = ……………(1)
2
I R IR vB 0 + − = ……………(2)
adding (1) & (2)
R
R
I
1
I
2
2IR IR 2vB + =
2vB
I
3R
=
1 2
vB
I I
3R
= =
32. Let C be the capacitance of a capacitor discharging through a resistor R. Suppose t
1
is the time
taken for the energy stored in the capacitor to reduce to half its initial value and t
2
is the time taken
for the charge to reduce to onefourth its initial value. Then the ratio t
1
/t
2
will be
(1) 1 (2)
1
2
(3)
1
4
(4) 2
32. 3
Sol.
2 2
t / T 2 2t / T 0
0
q 1 q 1
U (q e ) e
2 C 2C 2C
− −
= = = (where CR τ = )
2t /
i
U U e
− τ
=
1
2t /
i i
1
U Ue
2
− τ
=
1
2t /
1
e
2
− τ
= ¬
1
T
t ln2
2
=
Now
t / T
0
q q e
−
=
t / 2T
0 0
1
q q e
4
−
=
2
t Tln4 2Tln2 = =
∴
1
2
t 1
t 4
=
Directions: Questions number 33 – 34 contain Statement1 and Statement2. Of the four choices given after
the statements, choose the one that best describes the two statements.
33. Statement1 : Two particles moving in the same direction do not lose all their energy in a
completely inelastic collision.
Statement2 : Principle of conservation of momentum holds true for all kinds of collisions.
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(1) Statement1 is true, Statement2 is true; Statement2 is the correct explanation of Statement1.
(2) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation of Statement
1
(3) Statement1 is false, Statement2 is true.
(4) Statement1 is true, Statement2 is false.
33. 1
Sol.
m
2
m
1
v
1
v
2
If it is a completely inelastic collision then
1 1 2 2 1 2
m v m v m v m v + = +
1 1 2 2
1 2
m v m v
v
m m
+
=
+
2 2
1 2
1 2
p p
K.E
2m 2m
= +
as
1 2
p and p
both simultaneously cannot be zero
therefore total KE cannot be lost.
34. Statement1 : When ultraviolet light is incident on a photocell, its stopping potential is V
0
and the
maximum kinetic energy of the photoelectrons is K
max
. When the ultraviolet light is replaced by X
rays, both V
0
and K
max
increase.
Statement2 : Photoelectrons are emitted with speeds ranging from zero to a maximum value
because of the range of frequencies present in the incident light.
(1) Statement1 is true, Statement2 is true; Statement2 is the correct explanation of Statement1.
(2) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation of Statement
1.
(3) Statement1 is false, Statement2 is true.
(4) Statement1 is true, Statement2 is false.
34. 4
Sol. Since the frequency of ultraviolet light is less than the frequency of X–rays, the energy of each
incident photon will be more for X–rays
K.E
photoelectron
=hν − ϕ
Stopping potential is to stop the fastest photoelectron
0
h
V
e e
ν ϕ
= −
so, K.E
max
and V
0
both increases.
But K.E ranges from zero to K.E
max
because of loss of energy due to subsequent collisions before
getting ejected and not due to range of frequencies in the incident light.
35. A ball is made of a material of density ρ where ρ
oil
< ρ < ρ
water
with ρ
oil
and ρ
water
representing the
densities of oil and water, respectively. The oil and water are immiscible. If the above ball is in
equilibrium in a mixture of this oil and water, which of the following pictures represents its equilibrium
position ?
(1)
(2)
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(3)
(4)
35. 2
Sol.
oil water
ρ < ρ < ρ
Oil is the least dense of them so it should settle at the top with water at the base. Now the ball is
denser than oil but less denser than water. So, it will sink through oil but will not sink in water. So it
will stay at the oil–water interface.
36. A particle is moving with velocity
ˆ ˆ
v K(y i x j) = +
, where K is a constant. The general equation for its
path is
(1) y = x
2
+ constant (2) y
2
= x + constant (3) xy = constant (4) y
2
= x
2
+ constant
36. 4
Sol.
ˆ ˆ
v Ky i Kx j = +
dx dy
Ky, Kx
dt dt
= =
dy dy dt Kx
dx dt dx Ky
= × =
y dy = x dx
y
2
= x
2
+ c.
37. Two long parallel wires are at a distance 2d apart. They carry steady equal current flowing out of the
plane of the paper as shown. The variation of the magnetic field along the line XX' is given by
(1)
(2)
(3)
(4)
37. 1
Sol. The magnetic field in between because of each will be in opposite direction
B
in between
=
0 0
i i
ˆ ˆ
j ( j)
2 x 2 (2d x)
µ µ
− −
π π −
0
i 1 1
ˆ
( j)
2 x 2d x
µ (
= −
(
π −
¸ ¸
at x = d, B
in between
= 0
for x < d, B
in between
=
ˆ
( j)
for x > d, B
in between
=
ˆ
( j) −
towards x net magnetic field will add up and direction will be
ˆ
( j) −
towards x' net magnetic field will add up and direction will be
ˆ
( j)
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38. In the circuit shown below, the key K is closed at t = 0. The current through the battery is
(1)
1 2
2 2
1 2
VR R
R R +
at t = 0 and
2
V
R
at t = ∞
(2)
2
V
R
at t = 0 and
1 2
1 2
V(R R )
R R
+
at t = ∞
(3)
2
V
R
at t = 0 and
1 2
2 2
1 2
VR R
R R +
at t = ∞
(4)
1 2
1 2
V(R R )
R R
+
at t = 0 and
2
V
R
at t = ∞
38. 2
Sol. At t = 0, inductor behaves like an infinite resistance
So at t = 0,
2
V
i
R
=
and at t = ∞, inductor behaves like a conducting wire
1 2
eq 1 2
V(R R ) V
i
R R R
+
= =
39. The figure shows the position – time (x – t)
graph of onedimensional motion of a body
of mass 0.4 kg. The magnitude of each
impulse is
(1) 0.4 Ns (2) 0.8 Ns
(3) 1.6 Ns (4) 0.2 Ns
39. 2
Sol. From the graph, it is a straight line so, uniform motion. Because of impulse direction of velocity
changes as can be seen from the slope of the graph.
Initial velocity =
2
1m/ s
2
=
Final velocity =
2
1m/ s
2
− = −
i P 0.4 =
N – s
i
Pj 0.4 = −
N – s
f
i
J P P = −
= – 0.4 – 0.4 = – 0.8 N – s ( J
= impulse)
J
= 0.8 N–s
Directions : Questions number 40 – 41 are based on the following paragraph.
A nucleus of mass M + ∆m is at rest and decays into two daughter nuclei of equal mass
M
2
each.
Speed of light is c.
40. The binding energy per nucleon for the parent nucleus is E
1
and that for the daughter nuclei is E
2
.
Then
(1) E
2
= 2E
1
(2) E
1
> E
2
(3) E
2
> E
1
(4) E
1
= 2E
2
40. 3
Sol. After decay, the daughter nuclei will be more stable hence binding energy per nucleon will be more
than that of their parent nucleus.
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41. The speed of daughter nuclei is
(1)
m
c
M m
∆
+ ∆
(2)
2 m
c
M
∆
(3)
m
c
M
∆
(4)
m
c
M m
∆
+ ∆
41. 2
Sol. Conserving the momentum
1 2
M M
0 V V
2 2
= −
1 2
V V = …………….(1)
2 2 2
1 2
1 M 1 M
mc . V . .V
2 2 2 2
∆ = + …………….(2)
2 2
1
M
mc V
2
∆ =
2
2
1
2 mc
V
M
∆
=
1
2 m
V c
M
∆
=
42. A radioactive nucleus (initial mass number A and atomic number Z) emits 3 αparticles and 2
positrons. The ratio of number of neutrons to that of protons in the final nucleus will be
(1)
A Z 8
Z 4
− −
−
(2)
A Z 4
Z 8
− −
−
(3)
A Z 12
Z 4
− −
−
(4)
A Z 4
Z 2
− −
−
42. 2
Sol. In positive beta decay a proton is transformed into a neutron and a positron is emitted.
0
p n e
+ +
→ +
no. of neutrons initially was A – Z
no. of neutrons after decay (A – Z) – 3 x 2 (due to alpha particles) + 2 x 1 (due to positive beta
decay)
The no. of proton will reduce by 8. [as 3 x 2 (due to alpha particles) + 2(due to positive beta decay)]
Hence atomic number reduces by 8.
43. A thin semicircular ring of radius r has a positive charge q
distributed uniformly over it. The net field E
at the centre O is
(1)
2 2
0
q
ˆ
j
4 r π ε
(2) –
2 2
0
q
ˆ
j
4 r π ε
(3) –
2 2
0
q
ˆ
j
2 r π ε
(4)
2 2
0
q
ˆ
j
2 r π ε
43. 3
Sol. Linear charge density
q
r
 
λ =

π
\ .
2
K.dq
ˆ ˆ
E dEsin ( j) sin ( j)
r
= θ − = θ −
} }
2
K qr
ˆ
E d sin ( j)
r r
= θ θ −
π
}
y
θ
x
θ
dθ
2
0
K q
ˆ
sin ( j)
r
π
= θ −
π
}
2 2
0
q
ˆ
( j)
2 r
= −
π ε
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44. The combination of gates shown below yields
(1) OR gate (2) NOT gate
(3) XOR gate (4) NAND gate
44. 1
Sol. Truth table for given combination is
A B X
0 0 0
0 1 1
1 0 1
1 1 1
This comes out to be truth table of OR gate
45. A diatomic ideal gas is used in a Car engine as the working substance. If during the adiabatic
expansion part of the cycle, volume of the gas increases from V to 32V the efficiency of the engine is
(1) 0.5 (2) 0.75 (3) 0.99 (4) 0.25
45. 2
Sol. The efficiency of cycle is
2
1
T
1
T
η = −
for adiabatic process
TV
γ–1
= constant
For diatomic gas
7
5
γ =
1 1
1 1 2 2
T V T V
γ − γ −
=
1
2
1 2
1
V
T T
V
γ−
 
=

\ .
7
1
5
1 2
T T (32)
−
=
5 2/ 5
2
T (2 ) =
= T
2
x 4
T
1
= 4T
2
.
1 3
1 0.75
4 4
 
η = − = =

\ .
46. If a source of power 4 kW produces 10
20
photons/second, the radiation belong to a part of the
spectrum called
(1) X–rays (2) ultraviolet rays (3) microwaves (4) γ–rays
46. 1
Sol. 4 x 10
3
= 10
20
x hf
3
20 34
4 10
f
10 6.023 10
−
×
=
× ×
f = 6.03 x 10
16
Hz
The obtained frequency lies in the band of X–rays.
47. The respective number of significant figures for the numbers 23.023, 0.0003 and 2.1 x 10
–3
are
(1) 5, 1, 2 (2) 5, 1, 5 (3) 5, 5, 2 (4) 4, 4, 2
47. 1
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48. In a series LCR circuit R = 200 Ω and the voltage and the frequency of the main supply is 220 V and
50 Hz respectively. On taking out the capacitance from the circuit the current lags behind the voltage
by 30°. On taking out the inductor from the circuit the current leads the voltage by 30
o
. The power
dissipated in the LCR circuit is
(1) 305 W (2) 210 W (3) Zero W (4) 242 W
48. 4
Sol. The given circuit is under resonance as X
L
= X
C
Hence power dissipated in the circuit is
2
V
P
R
= = 242 W
49. Let there be a spherically symmetric charge distribution with charge density varying as
0
5 r
(r)
4 R
 
ρ = ρ −

\ .
upto r = R, and ρ(r) = 0 for r > R, where r is the distance from the origin. The
electric field at a distance r(r < R) from the origin is given by
(1)
0
0
4 r 5 r
3 3 R
πρ  
−

ε
\ .
(2)
0
0
r 5 r
4 3 R
ρ  
−

ε
\ .
(3)
0
0
4 r 5 r
3 4 R
ρ  
−

ε
\ .
(4)
0
0
r 5 r
3 4 R
ρ  
−

ε
\ .
49. 2
Sol. Apply shell theorem the total charge upto distance r can be calculated as followed
2
dq 4 r .dr. = π ρ
2
0
5 r
4 r .dr.
4 R
(
= π ρ −
(
¸ ¸
3
2
0
5 r
4 r dr dr
4 R
(
= πρ −
(
¸ ¸
r 3
2
0
0
5 r
dq q 4 r dr dr
4 R
 
= = πρ −

\ .
} }
3 4
0
5 r 1 r
4
4 3 R 4
(
= πρ −
(
¸ ¸
2
kq
E
r
=
3 4
0 2
0
1 1 5 r r
.4
4 r 4 3 4R
(  
= πρ −
( 
πε
\ . ¸ ¸
0
0
r 5 r
E
4 3 R
ρ (
= −
(
ε
¸ ¸
50. The potential energy function for the force between two atoms in a diatomic molecule is
approximately given by
12 6
a b
U(x)
x x
= − , where a and b are constants and x is the distance between
the atoms. If the dissociation energy of the molecule is D = [U(x = ∞) – U
at equilibrium
], D is
(1)
2
b
2a
(2)
2
b
12a
(3)
2
b
4a
(4)
2
b
6a
50. 3
Sol.
12 6
a b
U(x)
x x
= −
U(x = ∞) = 0
as,
13 7
dU 12a 6b
F
dx x x
(
= − = − +
(
¸ ¸
at equilibrium, F = 0
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∴
6
2a
x
b
=
∴
2
at equilibrium 2
a b b
U
2a 4a
2a
b
b
−
= − =
 
 


\ .
\ .
∴
2
at equilibrium
b
D U(x ) U
4a
( = = ∞ − =
¸ ¸
51. Two identical charged spheres are suspended by strings of equal lengths. The strings make an
angle of 30°with each other. When suspended in a liquid of density 0.8 g cm
–3
, the angle remains
the same. If density of the material of the sphere is 16 g cm
–3
, the dielectric constant of the liquid is
(1) 4 (2) 3 (3) 2 (4) 1
51. 3
Sol. From F.B.D of sphere, using Lami’s theorem
F
tan
mg
= θ ………………(i)
when suspended in liquid, as θ remains same,
∴
F'
tan
mg 1
d
= θ
ρ  
−

\ .
………………(ii)
θ
T
F
mg
using (i) and (ii)
F F' F
where, F'
mg K
mg 1
d
= =
ρ  
−

\ .
∴
F F'
mg
mg K 1
d
=
ρ  
−

\ .
or
1
K 2
1
d
= =
ρ
−
52. Two conductors have the same resistance at 0
o
C but their temperature coefficients of resistance are
α
1
and α
2
. The respective temperature coefficients of their series and parallel combinations are
nearly
(1)
1 2
1 2
,
2
α + α
α + α (2)
1 2
1 2
,
2
α + α
α + α (3)
1 2
1 2
1 2
,
α α
α + α
α + α
(4)
1 2 1 2
,
2 2
α + α α + α
52. 4
Sol. Let R
0
be the initial resistance of both conductors
∴ At temperature θ their resistance will be,
1 0 1 2 0 2
R R (1 ) and R R (1 ) = + α θ = + α θ
for, series combination, R
s
= R
1
+ R
2
s0 s 0 1 0 2
R (1 ) R (1 ) R (1 ) + α θ = + α θ + + α θ
where
s0 0 0 0
R R R 2R = + =
∴
0 s 0 0 1 2
2R (1 ) 2R R ( ) + α θ = + θ α + α
or
1 2
s
2
α + α
α =
for parallel combination,
1 2
p
1 2
R R
R
R R
=
+
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0 1 0 2
p0 p
0 1 0 2
R (1 )R (1 )
R (1 )
R (1 ) R (1 )
+ α θ + α θ
+ α θ =
+ α θ + + α θ
where,
0 0 0
p0
0 0
R R R
R
R R 2
= =
+
∴
2
0 0 1 2 1 2
p
0 1 2
R R (1 )
(1 )
2 R (2 )
+ α θ + α θ + α α θ
+ α θ =
+ α θ + α θ
as
1 2
and α α are small quantities
∴
1 2
α α is negligible
or
1 2 1 2
p 1 2
1 2
[1 ( ) ]
2 ( ) 2
α + α α + α
α = = − α + α θ
+ α + α θ
as
2
1 2
( ) α + α is negligible
∴
1 2
p
2
α + α
α =
53. A point P moves in counterclockwise direction on a circular path
as shown in the figure. The movement of ‘P’ is such that it
sweeps out a length s = t
3
+ 5, where s is in metres and t is in
seconds. The radius of the path is 20 m. The acceleration of ‘P’
when t = 2 s is nearly
(1) 13 m/s
2
(2) 12 m/s
2
(3) 7.2 m/s
2
(4) 14 m/s
2
53. 4
Sol. S = t
3
+ 5
∴ speed,
2
ds
v 3t
dt
= =
and rate of change of speed
dv
6t
dt
= =
∴ tangential acceleration at t = 2s, a
t
= 6 x 2 = 12 m/s
2
at t = 2s, v = 3(2)
2
= 12 m/s
∴ centripetal acceleration,
2
2
c
v 144
a m/ s
R 20
= =
∴ net acceleration =
2 2
t i
a a +
2
14 m/ s ≈
54. Two fixed frictionless inclined plane making an angle 30
o
and 60
o
with the vertical are shown in the figure. Two
block A and B are placed on the two planes. What is the
relative vertical acceleration of A with respect to B ?
(1) 4.9 ms
–2
in horizontal direction
(2) 9.8 ms
–2
in vertical direction
(3) zero
(4) 4.9 ms
–2
in vertical direction
54. 4
Sol. mg sin θ = ma
∴ a = g sin θ
where a is along the inclined plane
∴ vertical component of acceleration is g sin
2
θ
∴ relative vertical acceleration of A with respect to B is
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2 2 2
g
g[sin 60 sin 30] 4.9 m/ s
2
− = = in vertical direction.
55. For a particle in uniform circular motion the acceleration a
at a point P(R, θ) on the circle of radius R
is (here θ is measured from the x–axis)
(1)
2 2
v v
ˆ ˆ
cos i sin j
R R
− θ + θ (2)
2 2
v v
ˆ ˆ
sin i cos j
R R
− θ + θ
(3)
2 2
v v
ˆ ˆ
cos i sin j
R R
− θ − θ (4)
2 2
v v
ˆ ˆ
i j
R R
+
55. 3
Sol. For a particle in uniform circular motion,
2
v
a
R
=
towards centre of circle
∴
2
v
ˆ ˆ
a ( cos i sin j)
R
= − θ − θ
or
2 2
v v
ˆ ˆ
a cos i sin j
R R
= − θ − θ
x
y
P (R, θ)
a
c
a
c
Directions: Questions number 56 – 58 are based on the following paragraph.
An initially parallel cylindrical beam travels in a medium of refractive index
0 2
(I) I µ = µ + µ , where µ
0
and µ
2
are positive constants and I is the intensity of the light beam. The intensity of the beam is
decreasing with increasing radius.
56. As the beam enters the medium, it will
(1) diverge
(2) converge
(3) diverge near the axis and converge near the periphery
(4) travel as a cylindrical beam
56. 2
Sol. As intensity is maximum at axis,
∴ µ will be maximum and speed will be minimum on the axis of the beam.
∴ beam will converge.
57. The initial shape of the wave front of the beam is
(1) convex
(2) concave
(3) convex near the axis and concave near the periphery
(4) planar
57. 4
Sol. For a parallel cylinderical beam, wavefront will be planar.
58. The speed of light in the medium is
(1) minimum on the axis of the beam (2) the same everywhere in the beam
(3) directly proportional to the intensity I (4) maximum on the axis of the beam
58. 1
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59. A small particle of mass m is projected at an angle θ with the
xaxis with an initial velocity v
0
in the xy plane as shown in the
figure. At a time
0
v sin
t
g
θ
< , the angular momentum of the
particle is
(1)
2
0
ˆ
mgv t cos j − θ (2)
0
ˆ
mgv t cos k θ
(3)
2
0
1
ˆ
mgv t cos k
2
− θ (4)
2
0
1
ˆ
mgv t cos i
2
θ
where
ˆ ˆ ˆ
i, j and k are unit vectors along x, y and z–axis respectively.
59. 3
Sol. L m(r v) = ×
2
0 0 0 0
1
ˆ ˆ ˆ ˆ
L m v cos t i (v sin t gt )j v cos i (v sin gt)j
2
(
(
= θ + θ − × θ + θ −
(
¸ ¸
¸ ¸
0
1
ˆ
mv cos t gt k
2
(
= θ −
(
¸ ¸
2
0
1
ˆ
mgv t cos k
2
= − θ
60. The equation of a wave on a string of linear mass density 0.04 kg m
–1
is given by
t x
y 0.02(m)sin 2
0.04(s) 0.50(m)
(  
= π −
( 
\ . ¸ ¸
. The tension in the string is
(1) 4.0 N (2) 12.5 N (3) 0.5 N (4) 6.25 N
60. 4
Sol.
2 2
2
2 2
(2 / 0.004)
T v 0.04 6.25 N
k (2 / 0.50)
ω π
= µ = µ = =
π
PART C: HATHEHATICS
61. Let cos(α + β) =
4
5
and let sin(α – β) =
5
13
, where 0 ≤ α, β ≤
4
π
, then tan 2α =
(1)
56
33
(2)
19
12
(3)
20
7
(4)
25
16
61. 1
cos (α + β) =
4
5
¬ tan(α + β) =
3
4
sin(α – β) =
5
13
¬ tan(α – β) =
5
12
tan 2α = tan(α + β + α – β) =
3 5
56
4 12
3 5
33
1
4 12
+
=
−
62. Let S be a nonempty subset of R. Consider the following statement:
P: There is a rational number x ∈ S such that x > 0.
Which of the following statements is the negation of the statement P ?
(1) There is no rational number x ∈ S such that x ≤ 0
(2) Every rational number x ∈ S satisfies x ≤ 0
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(3) x ∈ S and x ≤ 0 ¬ x is not rational
(4) There is a rational number x ∈ S such that x ≤ 0
62. 2
P: there is a rational number x ∈ S such that x > 0
~P: Every rational number x ∈ S satisfies x ≤ 0
63. Let
ˆ ˆ ˆ ˆ ˆ
a j k and c i j k = − = − −
. Then vector b
satisfying a b c 0 and a b × + = ⋅
= 3 is
(1)
ˆ ˆ ˆ
2i j 2k − + (2)
ˆ ˆ ˆ
i j 2k − − (3)
ˆ ˆ ˆ
i j 2k + − (4)
ˆ ˆ ˆ
i j 2k − + −
63. 4
c b a = ×
¬ b c 0 ⋅ =
¬
( ) ( ) 1 2 3
ˆ ˆ ˆ ˆ ˆ ˆ
b i b j b k i j k + + ⋅ − − = 0
b
1
– b
2
– b
3
= 0
and a b ⋅
= 3
¬ b
2
– b
3
= 3
b
1
= b
2
+ b
3
= 3 + 2b
3
( ) ( )
3 3 3
ˆ ˆ ˆ
b 3 2b i 3 b j b k = + + + +
.
64. The equation of the tangent to the curve y = x +
2
4
x
, that is parallel to the xaxis, is
(1) y = 1 (2) y = 2 (3) y = 3 (4) y = 0
64. 3
Parallel to xaxis ¬
dy
dx
= 0 ¬
3
8
1
x
− = 0
¬ x = 2 ¬ y = 3
Equation of tangent is y – 3 = 0(x – 2) ¬ y – 3 = 0
65. Solution of the differential equation cos x dy = y(sin x – y) dx, 0 < x <
2
π
is
(1) y sec x = tan x + c (2) y tan x = sec x + c (3) tan x = (sec x + c)y (4) sec x = (tan x + c)y
65. 4
cos x dy = y(sin x – y) dx
2
dy
y tanx y sec x
dx
= −
2
1 dy 1
tanx sec x
dx y y
− = −
Let
1
t
y
=
2
1 dy dt
dx dx y
− =
dy
dx
− – t tan x = –sec x ¬
dt
dx
+ (tan x) t = sec x.
I.F. = e
} tan x dx
= sec x
Solution is t(I.F) = } (I.F) sec x dx
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1
y
sec x = tan x + c
66. The area bounded by the curves y = cos x and y = sin x between the ordinates x = 0 and x =
3
2
π
is
(1) 4 2 + 2 (2) 4 2 – 1 (3) 4 2 + 1 (4) 4 2 – 2
66. 4
( ) ( ) ( )
5 3
4 4 2
5 0
4 4
cosx sinx dx sinx cosx dx cosx sinx 4 2 2
π π π
π π
− + − + − = −
} } }
cos x sin x
4
π
5
4
π
3
2
π
2π
0
π
67. If two tangents drawn from a point P to the parabola y
2
= 4x are at right angles, then the locus of P is
(1) 2x + 1 = 0 (2) x = –1 (3) 2x – 1 = 0 (4) x = 1
67. 2
The locus of perpendicular tangents is directrix
i.e, x = –a; x = –1
68. If the vectors
ˆ ˆ ˆ ˆ ˆ ˆ ˆ ˆ ˆ
a i j 2k, b 2i 4j k and c i j k = − + = + + = λ + + µ
are mutually orthogonal, then (λ, µ) =
(1) (2, –3) (2) (–2, 3) (3) (3, –2) (4) (–3, 2)
68. 4
a b 0, b c 0, c a 0 ⋅ = ⋅ = ⋅ =
¬ 2λ + 4 + µ = 0 λ – 1 + 2µ = 0
Solving we get: λ = –3, µ = 2
69. Consider the following relations:
R = {(x, y)  x, y are real numbers and x = wy for some rational number w};
S =
m p
, m, n, p and q are integers such that n, q 0 and qm = pn
n q
¦ ¹
  ¦ ¦
≠
´ ` 
\ . ¦ ¦
¹ )
. Then
(1) neither R nor S is an equivalence relation
(2) S is an equivalence relation but R is not an equivalence relation
(3) R and S both are equivalence relations
(4) R is an equivalence relation but S is not an equivalence relation
69. 2
xRy need not implies yRx
S:
m p
s
n q
⇔ qm = pn
m m
s
n n
reflexive
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m p
s
n q
¬
p m
s
q n
symmetric
m p p r
s , s
n q q s
¬ qm = pn, ps = rq ¬ ms = rn transitive.
S is an equivalence relation.
70. Let f: R → R be defined by f(x) =
k 2x, if x 1
2x 3, if x 1
− ≤ − ¦
´
+ > −
¹
. If f has a local minimum at x = –1, then a
possible value of k is
(1) 0 (2)
1
2
− (3) –1 (4) 1
70. 3
f(x) = k – 2x if x ≤ –1
= 2x + 3 if x > –1
2x + 3
k – 2x
1
–1
x 1
lim
→− −
f(x) ≤ –1
This is true
where k = –1
71. The number of 3 × 3 nonsingular matrices, with four entries as 1 and all other entries as 0, is
(1) 5 (2) 6 (3) at least 7 (4) less than 4
71. 3
First row with exactly one zero; total number of cases = 6
First row 2 zeros we get more cases
Total we get more than 7.
Directions: Questions Number 72 to 76 are Assertion – Reason type questions. Each of these questions
contains two statements.
Statement1: (Assertion) and Statement2: (Reason)
Each of these questions also has four alternative choices, only one of which is the correct answer.
You have to select the correct choice.
72. Four numbers are chosen at random (without replacement) from the set {1, 2, 3, ....., 20}.
Statement1: The probability that the chosen numbers when arranged in some order will form an AP
is
1
85
.
Statement2: If the four chosen numbers from an AP, then the set of all possible values of common
difference is {±1, ±2, ±3, ±4, ±5}.
(1) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation for Statement1
(2) Statement1 is true, Statement2 is false
(3) Statement1 is false, Statement2 is true
(4) Statement1 is true, Statement2 is true; Statement2 is the correct explanation for Statement1
72. 2
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N(S) =
20
C
4
Statement1: common difference is 1; total number of cases = 17
common difference is 2; total number of cases = 14
common difference is 3; total number of cases = 11
common difference is 4; total number of cases = 8
common difference is 5; total number of cases = 5
common difference is 6; total number of cases = 2
Prob. =
20
4
17 14 11 8 5 2 1
85 C
+ + + + +
= .
73. Statement1: The point A(3, 1, 6) is the mirror image of the point B(1, 3, 4) in the plane x – y + z = 5.
Statement2: The plane x – y + z = 5 bisects the line segment joining A(3, 1, 6) and B(1, 3, 4).
(1) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation for Statement1
(2) Statement1 is true, Statement2 is false
(3) Statement1 is false, Statement2 is true
(4) Statement1 is true, Statement2 is true; Statement2 is the correct explanation for Statement1
73. 1
A(3, 1, 6); B = (1, 3, 4)
Midpoint of AB = (2, 2, 5) lies on the plane.
and d.r’s of AB = (2, –2, 2)
d.r’s Of normal to plane = (1, –1, 1).
AB is perpendicular bisector
∴ A is image of B
Statement2 is correct but it is not correct explanation.
74. Let S
1
= ( )
10
10
j
j 1
j j 1 C
=
−
¿
, S
2
=
10
10
j
j 1
j C
=
¿
and S
3
=
10
2 10
j
j 1
j C
=
¿
.
Statement1: S
3
= 55 × 2
9
Statement2: S
1
= 90 × 2
8
and S
2
= 10 × 2
8
.
(1) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation for Statement1
(2) Statement1 is true, Statement2 is false
(3) Statement1 is false, Statement2 is true
(4) Statement1 is true, Statement2 is true; Statement2 is the correct explanation for Statement1
74. 2
S
1
= ( )
( )( ) ( ) ( ) ( ) ( )
10 10
8
j 1 j 2
10! 8!
j j 1 90 90 2
j j 1 j 2 ! 10 j ! j 2 ! 8 j 2 !
= =
− = = ⋅
− − − − − −
¿ ¿
.
S
2
=
( ) ( ) ( ) ( ) ( ) ( )
10 10
9
j 1 j 1
10! 9!
j 10 10 2
j j 1 ! 9 j 1 ! j 1 ! 9 j 1 !
= =
= = ⋅
− − − − − −
¿ ¿
.
S
3
=
( )
( )
( )
10 10 10
10 10
j j
j 1 j 1 j 1
10!
j j 1 j j j 1 C j C
j! 10 j !
= = =
( − + = − =
¸ ¸
−
¿ ¿ ¿
= 90 . 2
8
+ 10 . 2
9
= 90 . 2
8
+ 20 . 2
8
= 110 . 2
8
= 55 . 2
9
.
75. Let A be a 2 × 2 matrix with nonzero entries and let A
2
= I, where I is 2 × 2 identity matrix. Define
Tr(A) = sum of diagonal elements of A and A = determinant of matrix A.
Statement1: Tr(A) = 0
Statement2: A = 1
(1) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation for Statement1
(2) Statement1 is true, Statement2 is false
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(3) Statement1 is false, Statement2 is true
(4) Statement1 is true, Statement2 is true; Statement2 is the correct explanation for Statement1
75. 2
Let A =
a b
c d
 

\ .
, abcd ≠ 0
A
2
=
a b a b
c d c d
   
⋅
 
\ . \ .
¬ A
2
=
2
2
a bc ab bd
ac cd bc d
  + +

+ +
\ .
¬ a
2
+ bc = 1, bc + d
2
= 1
ab + bd = ac + cd = 0
c ≠ 0 and b ≠ 0 ¬ a + d = 0
Trace A = a + d = 0
A = ad – bc = –a
2
– bc = –1.
76. Let f: R → R be a continuous function defined by f(x) =
x x
1
e 2e
−
+
.
Statement1: f(c) =
1
3
, for some c ∈ R.
Statement2: 0 < f(x) ≤
1
2 2
, for all x ∈ R
(1) Statement1 is true, Statement2 is true; Statement2 is not the correct explanation for Statement1
(2) Statement1 is true, Statement2 is false
(3) Statement1 is false, Statement2 is true
(4) Statement1 is true, Statement2 is true; Statement2 is the correct explanation for Statement1
76. 4
f(x) =
x
x x 2x
1 e
e 2e e 2
−
=
+ +
f′(x) =
( )
( )
2x x 2x x
2
2x 2
e 2 e 2e e
e
+
+ − ⋅
f′(x) = 0 ¬ e
2x
+ 2 = 2e
2x
e
2x
= 2 ¬ e
x
= 2
maximum f(x) =
2 1
4
2 2
=
0 < f(x) ≤
1
2 2
∀ x ∈ R
Since 0 <
1 1
3
2 2
< ¬ for some c ∈ R
f(c) =
1
3
77. For a regular polygon, let r and R be the radii of the inscribed and the circumscribed circles. A false
statement among the following is
(1) There is a regular polygon with
r 1
R
2
= (2) There is a regular polygon with
r 2
R 3
=
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(3) There is a regular polygon with
r 3
R 2
= (4) There is a regular polygon with
r 1
R 2
=
77. 2
r =
a
cot
2 n
π
‘a’ is side of polygon.
R =
a
cosec
2 n
π
cot
r
n
cos
R n
cosec
n
π
π
= =
π
2
cos
n 3
π
≠ for any n ∈ N.
78. If α and β are the roots of the equation x
2
– x + 1 = 0, then α
2009
+ β
2009
=
(1) –1 (2) 1 (3) 2 (4) –2
78. 2
x
2
– x + 1 = 0 ¬ x =
1 1 4
2
± −
x =
1 3 i
2
±
α =
1 3
i
2 2
+ , β =
1 i 3
2 2
−
α = cos i sin
3 3
π π
+ , β = cos i sin
3 3
π π
−
α
2009
+ β
2009
= 2cos2009
3
π  

\ .
=
2 2
2cos 668 2cos
3 3
π π (  
π + π + = π +
 (
¸ ¸ \ .
=
2 1
2cos 2 1
3 2
π  
− = − − =

\ .
79. The number of complex numbers z such that z – 1 = z + 1 = z – i equals
(1) 1 (2) 2 (3) ∞ (4) 0
79. 1
Let z = x + iy
z – 1 = z + 1 ¬ Re z = 0 ¬ x = 0
z – 1 = z – i ¬ x = y
z + 1 = z – i ¬ y = –x
Only (0, 0) will satisfy all conditions.
¬ Number of complex number z = 1
80. A line AB in threedimensional space makes angles 45° and 120° with the positive xaxis and the
positive yaxis respectively. If AB makes an acute angle θ with the positive zaxis, then θ equals
(1) 45° (2) 60° (3) 75° (4) 30°
80. 2
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= cos 45° =
1
2
m = cos 120° =
1
2
−
n = cos θ
where θ is the angle which line makes with positive zaxis.
Now
2
+ m
2
+ n
2
= 1
¬
1 1
2 4
+ + cos
2
θ = 1
cos
2
θ =
1
4
¬ cos θ =
1
2
(θ Being acute)
¬ θ =
3
π
.
81. The line L given by
x y
5 b
+ = 1 passes through the point (13, 32). The line K is parallel to L and has
the equation
x y
c 3
+ = 1. Then the distance between L and K is
(1) 17 (2)
17
15
(3)
23
17
(4)
23
15
81. 3
Slope of line L =
b
5
−
Slope of line K =
3
c
−
Line L is parallel to line k.
¬
b 3
5 c
= ¬ bc = 15
(13, 32) is a point on L.
¬
13 32 32 8
1
5 b b 5
+ = ¬ = −
¬ b = –20 ¬ c =
3
4
−
Equation of K: y – 4x = 3
Distance between L and K =
52 32 3
23
17 17
− +
=
82. A person is to count 4500 currency notes. Let a
n
denote the number of notes he counts in the n
th
minute. If a
1
= a
2
= ...... = a
10
= 150 and a
10
, a
11
, ...... are in A.P. with common difference –2, then the
time taken by him to count all notes is
(1) 34 minutes (2) 125 minutes (3) 135 minutes (4) 24 minutes
82. 1
Till 10
th
minute number of counted notes = 1500
3000 =
n
2
[2 × 148 + (n – 1)(–2)] = n[148 – n + 1]
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n
2
– 149n + 3000 = 0
n = 125, 24
n = 125 is not possible.
Total time = 24 + 10 = 34 minutes.
83. Let f: R → R be a positive increasing function with
x
f(3x)
lim
f(x)
→∞
= 1. Then
x
f(2x)
lim
f(x)
→∞
=
(1)
2
3
(2)
3
2
(3) 3 (4) 1
83. 4
f(x) is a positive increasing function
¬ 0 < f(x) < f(2x) < f(3x)
¬ 0 < 1 <
f(2x) f(3x)
f(x) f(x)
<
¬
x x x
f(2x) f(3x)
lim1 lim lim
f(x) f(x)
→∞ →∞ →∞
≤ ≤
By sandwich theorem.
¬
x
f(2x)
lim
f(x)
→∞
= 1
84. Let p(x) be a function defined on R such that p′(x) = p′(1 – x), for all x ∈ [0, 1], p(0) = 1 and p(1) = 41.
Then
1
0
p(x)
}
dx equals
(1) 21 (2) 41 (3) 42 (4) 41
84. 1
p′(x) = p′(1 – x)
¬ p(x) = –p(1 – x) + c
at x = 0
p(0) = –p(1) + c ¬ 42 = c
now p(x) = –p(1 – x) + 42
¬ p(x) + p(1 – x) = 42
I =
1 1
0 0
p(x) dx p(1 x) dx = −
} }
2 I =
1
0
(42) dx
}
¬ I = 21.
85. Let f: (–1, 1) → R be a differentiable function with f(0) = –1 and f′(0) = 1. Let g(x) = [f(2f(x) + 2)]
2
.
Then g′(0) =
(1) –4 (2) 0 (3) –2 (4) 4
85. 1
g′(x) = 2(f(2f(x) + 2)) ( ) ( )
d
f 2f(x) 2
dx
 
+

\ .
= 2f(2f(x) + 2) f′(2f(x) + 2) . (2f′(x))
¬ g′(0) = 2f(2f(0) + 2) . f′(2f(0) + 2) . 2(f′(0) = 4f(0) f′(0)
= 4(–1) (1) = –4
AIEEE− −− −2010− −− −29
(Hyderabad Classes) Limited. 5914/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 04066777000 – 03 Fax: 04066777004
86. There are two urns. Urn A has 3 distinct red balls and urn B has 9 distinct blue balls. From each urn
two balls are taken out at random and then transferred to the other. The number of ways in which
this can be done is
(1) 36 (2) 66 (3) 108 (4) 3
86. 3
Total number of ways =
3
C
2
×
9
C
2
= 3 ×
9 8
2
×
= 3 × 36 = 108
87. Consider the system of linear equations:
x
1
+ 2x
2
+ x
3
= 3
2x
1
+ 3x
2
+ x
3
= 3
3x
1
+ 5x
2
+ 2x
3
= 1
The system has
(1) exactly 3 solutions (2) a unique solution
(3) no solution (4) infinite number of solutions
87. 3
D =
1 2 1
2 3 1
3 5 2
= 0
D
1
=
3 2 1
3 3 1
1 5 2
≠ 0
¬ Given system, does not have any solution.
¬ No solution.
88. An urn contains nine balls of which three are red, four are blue and two are green. Three balls are
drawn at random without replacement from the urn. The probability that the three balls have different
colour is
(1)
2
7
(2)
1
21
(3)
2
23
(4)
1
3
88. 1
n(S) =
9
C
3
n(E) =
3
C
1
×
4
C
1
×
2
C
1
Probability =
9
3
3 4 2 24 3! 24 6 2
6!
9! 9 8 7 7 C
× × × ×
= × = =
× ×
.
89. For two data sets, each of size 5, the variances are given to be 4 and 5 and the corresponding
means are given to be 2 and 4, respectively. The variance of the combined data set is
(1)
11
2
(2) 6 (3)
13
2
(4)
5
2
89. 1
σ
x
2
= 4
σ
y
2
= 5
x = 2
y = 4
AIEEE− −− −2010− −− −30
(Hyderabad Classes) Limited. 5914/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 04066777000 – 03 Fax: 04066777004
i
x
5
¿
= 2 ¿ x
i
= 10; ¿ y
i
= 20
σ
x
2
= ( ) ( )
2
2 2
i i
1 1
x x y 16
2 5
 
¿ − = ¿ −

\ .
¿ x
i
2
= 40
¿ y
i
2
= 105
σ
z
2
=
( ) ( )
2
2 2
i i
1 x y 1 145 90 55 11
x y 40 105 9
10 2 10 10 10 2
+ −  
¿ + ¿ − = + − = = =

\ .
90. The circle x
2
+ y
2
= 4x + 8y + 5 intersects the line 3x – 4y = m at two distinct points if
(1) –35 < m < 15 (2) 15 < m < 65 (3) 35 < m < 85 (4) –85 < m < –35
90. 1
Circle x
2
+ y
2
– 4x – 8y – 5 = 0
Centre = (2, 4), Radius = 4 16 5 + + = 5
If circle is intersecting line 3x – 4y = m
at two distinct points.
¬ length of perpendicular from centre < radius
¬
6 16 m
5
− −
< 5
¬ 10 + m < 25
¬ –25 < m + 10 < 25
¬ –35 < m < 15.
* * *
AIEEE− −− −2010− −− −31
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AIEEE−2010−2 − −
1.
1. Sol :
The standard enthalpy of formation of NH3 is –46.0 kJ mol . If the enthalpy of formation of H2 from –1 –1 its atoms is –436 kJ mol and that of N2 is –712 kJ mol , the average bond enthalpy of N–H bond in NH3 is (1) –964 kJ mol–1 (2) +352 kJ mol–1 (3) + 1056 kJ mol–1 (4) –1102 kJ mol–1 (2) Enthalpy of formation of NH3 = –46 kJ/mole ∴ N2 + 3H2 → 2NH3 ∆Hf = – 2 x 46 kJ mol Bond breaking is endothermic and Bond formation is exothermic –1 Assuming ‘x’ is the bond energy of N–H bond (kJ mol ) ∴ 712 + (3 x 436)– 6x = –46 x 2 ∴ x = 352 kJ/mol The time for half life period of a certain reaction A → products is 1 hour. When the initial –1 concentration of the reactant ‘A’, is 2.0 mol L , how much time does it take for its concentration to –1 come from 0.50 to 0.25 mol L if it is a zero order reaction ? (1) 4 h (2) 0.5 h (3) 0.25 h (4) 1 h (3) x → (1) For a zero order reaction k = t Where x = amount decomposed k = zero order rate constant for a zero order reaction [ A ]0 → (2) k= 2t1
2
–1
2.
2. Sol :
Since [A0] = 2M , t1/2 = 1 hr; k = 1 ∴ from equation (1) 0.25 t= = 0.25hr 1 3. A solution containing 2.675 g of CoCl3. 6 NH3 (molar mass = 267.5 g mol–1) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give –1 4.78 g of AgCl (molar mass = 143.5 g mol ). The formula of the complex is (At. Mass of Ag = 108 u) (1) [Co(NH3)6]Cl3 (2) [CoCl2(NH3)4]Cl (3) [CoCl3(NH3)3] (4) [CoCl(NH3)5]Cl2 (1) – AgNO3 CoCl3. 6NH3 → xCl x AgCl ↓ → n(AgCl) = x n(CoCl3. 6NH3) 4.78 2.675 ∴x=3 =x 143.5 267.5 ∴ The complex is Co (NH3 )6 Cl3
3. Sol :
4.
4.
Consider the reaction : + – Cl2(aq) + H2S(aq) → S(s) + 2H (aq) + 2Cl (aq) The rate equation for this reaction is rate = k [Cl2] [H2S] Which of these mechanisms is/are consistent with this rate equation ? + – + – (A) Cl2 + H2 → H + Cl + Cl + HS (slow) + – + – Cl + HS → H + Cl + S (fast) + – (B) H2S ⇔ H + HS (fast equilibrium) – – + Cl2 + HS → 2Cl + H + S (slow) (1) B only (2) Both A and B (3) Neither A nor B (4)
(4) A only
(Hyderabad Classes) Limited. 5914/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 04066777000 – 03 Fax: 04066777004
AIEEE−2010−3 − −
Sol:
Rate equation is to be derived wrt slow Step ∴ from mechanism (A) Rate = k[Cl2] [H2S] If 10 dm of water is introduced into a 1.0 dm flask to 300 K, how many moles of water are in the vapour phase when equilibrium is established ? (Given : Vapour pressure of H2O at 300 K is 3170 Pa ; R = 8.314 J K–1 mol–1) –3 –2 –2 –3 (2) 1.53 x 10 mol (3) 4.46 x 10 mol (4) 1.27 x 10 mol (1) 5.56 x 10 mol (4) PV n= = RT –5 = 128 x 10 moles 3170 × 10 −5 atm × 1 L –3 = ≈ 1.27 x 10 mol 0.0821 L atm k −1mol−1 × 300K
One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass of 44 u. The alkene is (1) propene (2) 1–butene (3) 2–butene (4) ethene (3) 2–butene is symmetrical alkene O3 CH3–CH=CH–CH3 2.CH3 CHO → Zn / H2 O
Molar mass of CH3CHO is 44 u. If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water (∆Tf), when 0.01 mol of sodium sulphate is dissolved in 1 kg of water, is (Kf = 1.86 K kg mol–1) (1) 0.0372 K (2) 0.0558 K (3) 0.0744 K (4) 0.0186 K (2) Vant Hoff’s factor (i) for Na2SO4 = 3 ∴ ∆Tf = (i) kf m 0.01 = 3 x 1.80 x = 0.0558 K 1 From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2, is (1) 2–Butanol (2) 2–Methylpropan–2–ol (3) 2–Methylpropanol (4) 1–Butanol (2) 3° alcohols react fastest with ZnCl2/conc.HCl due to formation of 3° carbocation and ∴ 2–methyl propan–2–ol is the only 3° alcohol In the chemical reactions, NH2
–4 3 3
5.
5. Sol :
6. 6. Sol :
7.
7. Sol :
8. 8. Sol : 9.
NaNO2 HCl, 278 K
A
HBF4
B
9. Sol :
the compounds ‘A’ and ‘B’ respectively are (1) nitrobenzene and fluorobenzene (2) phenol and benzene (3) benzene diazonium chloride and fluorobenzene (4) nitrobenzene and chlorobenzene (3)
(Hyderabad Classes) Limited. 5914/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 04066777000 – 03 Fax: 04066777004
6 Z 2 + 2 − 2 = 13. comp = 0.6Z2 + where Z + = 2 He He He He 1 ∞ + –18 –1 2+ ( ) Hence 13.0 (2) 47.022 × 1023 λ λ λ = 4947 A ≈ 494 nm 0 11.41× 10−17 J / atom 4 Consider the following bromides : (Hyderabad Classes) Limited.1 x 10 ) – (15 x 0.5 × 10 −3 The energy required to break one mole of Cl–Cl bonds in Cl2 is 242 kJ mol . Sol : 12. The longest wavelength of light capable of breaking a single Cl – Cl bond is 8 –1 23 –1 (c = 3 x 10 ms and NA = 6. (Opp. Secretariat) Hyderabad.5 (3) Moles of HCl reacting with ammonia = (moles of HCl absorbed ) – (moles of NaOH solution required) –3 –3 = (20 x 0. 278 K N2 Cl HBF4 (A) benzene diazonium chloride F N2 (B) fluorobenzene BF3 HCl 10.6 × Z2 He+ 2 = 19.5 x 10–3 x 14 –3 = 7 x 10 g 7 × 10−3 % wt = = 23.1 M HCl solution.1 x 10 ) = moles of NH3 evolved. Sol : Ionisation energy of He is 19.6 x 10 –18 x 9 = −4. NA This energy is contained in photon of wavelength ‘λ’. The excess of the acid required 15 mL of 0. –1 11.6 × 10 −18 J atom . –1 (E1 )Li+2 13.1 M NaOH solution for complete neutralization. The energy of the first stationary state (n = 1) of Li is –16 –1 –17 –1 (1) 4. hc 6.2 x 10 J atom (4) 8. = −13. 12.41 x 10 J atom (2) –4.7 (4) 29.02 x 10 mol ) (1) 594 nm (2) 640 nm (3) 700 nm (4) 494 nm (4) 242 × 103 Energy required for 1 Cl2 molecule = Joules. 5914/B.6 Z Li+2 Z 2 +2 1 2 × 2 = −13.626 × 10−34 × 3 × 108 242 × 103 =E = 6. Phone: 04066777000 – 03 Fax: 04066777004 . Saifabad. 10.7% 29.6 x 10 J atom .6 Z + × Li He 1 Z2 + He = –19.4 (3) 23. = moles of nitrogen in organic compound ∴ wt. 500 063. Sol : 29.41 x 10 J atom –15 –1 –17 –1 (3) –2. The percentage of nitrogen in the compound is (1) 59. of nitrogen in org.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl’s method and the evolved ammonia was absorbed in 20 mL of 0.82 x 10 J atom (2) 1 1 IE + = 13.AIEEE−2010−4 − − NH2 NaNO2 HCl.
it is tetrahedral with a plane of symmetry 15.0g of heptane and 35 g of octane will be (molar mass of heptane –1 –1 = 100 g mol an dof octane = 114 g mol ). (2) Co ( en )3 3+ (3) Co (H2 O )4 ( en ) 3+ (4) Zn ( en )2 2+ 14. Me Me > > Me Me Which one of the following has an optical isomer ? (1) Zn ( en )(NH3 )2 2+ 14. Secretariat) Hyderabad. en en ( 2) ( 1) en Zn NH3 +2 en Co +3 Co +3 en NH3 no optical isomer. Sol : (en = ethylenediamine) (2) Only option (2) is having non–super imposable mirror image & hence one optical isomer. Saifabad. C depends on stability of carbocation created. 5914/B.AIEEE−2010−5 − − Me (A) Br Br Me Me Br Me 13. Hence reactivity order for A. the most stable one forming the product faster. (1) 72. It is Tetrahedral with a plane of symmetry en en optical isomer H2O 3) H 2O Co H2O H2O Horizontal plane is plane of symmtry +3 4) en Zn +2 en en no optical isomer. 15.1 kPa (3) 96. heptane and octane form an ideal solution.0 kPa (2) 36. the vapour pressures of the two liquid components (heptane and octane) are 105 kPa and 45 kPa respectively. Phone: 04066777000 – 03 Fax: 04066777004 . (Opp. At 373 K.2 kPa (4) 144. Sol : (B) (C) The correct order of SN1 reactivity is (1) B > C > A (2) B > A > C (3) C > B > A (4) A > B > C (1) SN1 proceeds via carbocation intermediate. On mixing. 500 063. Vapour pressure of the solution obtained by mixing 25. B.5 kPa (1) (Hyderabad Classes) Limited.
Phone: 04066777000 – 03 Fax: 04066777004 .45 .55) kPa = 72.45 25 35 0. ∴ Mole fraction of octane = 0.AIEEE−2010−6 − − Sol : Mole fraction of Heptane = 25 /100 0.557 + 100 114 XHep tan e = 0. Three reactions involving H2PO − are given below : 4 (i) H3PO4 + H2O → H3O + H2PO − 4 (iii) H2PO − + OH− → H3PO4 + O2 − 4 + (ii) H2PO − + H2O → HPO2 − + H3O 4 4 + (Hyderabad Classes) Limited. (Opp.25 = = 0. H2SO4 CH2 CH CH CH3 CH3 loss of proton CH3 CH CH HC CH3 Trans isomers is more stable & main product here CH(CH3) 2 H (conjugated system) C C H (trans isomer) 17.55 = Xoctane Total pressure = XiPi0 = (105 x 0. Sol : (1) CH2 CH CH CH3 OH CH3 conc. Secretariat) Hyderabad. 500 063. conc. Saifabad. H2 SO4 The main product of the following reaction is C6H5CH2CH(OH)CH(CH3)2 ? → H CH3 H5C 6 C6H5CH2 (1) C H C6H 5 C CH(CH3)2 CH(CH3)2 C H (2) C C H CH3 H5C6CH2CH2 (4) (3) C H C H3C CH2 16.45) + (45 x 0. 5914/B.0 KPa 16.
2 x 10 and K2 = 4. In aqueous solution the ionization constants for carbonic acid are –7 –11 K1 = 4. 2 (1) The concentration of CO3 − is 0. − (3) The concentration of H and HCO3 are approximately equal. the radius of the anion is (1) 288 pm (2) 398 pm (3) 618 pm (4) 144 pm (4) For an ionic substance in FCC arrangement. + + 18.8 x 10 Select the correct statement for a saturated 0. 5914/B. (3) + –7 − A→ H2CO3 H + HCO3 K1 = 4. (Opp. Secretariat) Hyderabad. The correct order of increasing basicity of the given conjugate bases (R = CH3) is (2) R < HC ≡ C < RCOO < NH2 (1) RCOO < HC = C < R < NH2 (3) RCOO < NH2 < HC ≡ C < R (4) Correct order of increasing basic strength is (–) (–) (–) R–COO < CH≡C < NH(2−) < R (4) RCOO < HC ≡ C < NH2 < R 20. 21. 500 063. Saifabad. Sol : 2 (4) The concentration of H is double that of CO3 − . Sol : 21.034 M solution of the carbonic acid.AIEEE−2010−7 − − 17. Sol : The edge length of a face centered cubic cell of an ionic substance is 508 pm. 2 − (2) The concentration of CO3 − is greater than that of HCO3 .034 M. 4 18. 2 (r + + r − ) = edge length 2 (110 + r − ) = 508 – r = 144 pm 20.8 x 10 –11 As K2 << K1 All major H+ total ≈ H+ A A − ≈ HCO3 ≈ H+ and from I equilibrium. smaller the ionic radius e (Hyderabad Classes) Limited.2 x 10 B→ − HCO3 − H + CO32 + K2 = 4. Phone: 04066777000 – 03 Fax: 04066777004 . Sol : The correct sequence which shows decreasing order of the ionic radii of the elements is 3+ 2+ + – 2– + 2+ 3+ 2– – (1) Al > Mg > Na > F > O (2) Na > Mg > Al > O > F + – 2+ 2– 3+ 2– – + 2+ 3+ (3) Na > F > Mg > O > Al (4) O > F > Na > Mg > Al (4) Z For isoelectronic species higher the ratio . Sol : In which of the above does H2PO − act as an acid ? 4 (1) (ii) only (2) (i) and (ii) (3) (iii) only (1) (i) H3PO 4 + H2 → H3 O + + H2PO − 4 acid conjugate base (4) (i) only (ii) H2PO acid acid − 4 + H2O → HPO acid −2 4 conjugate base + H3 O+ +O –2 (iii) H2PO− + OH− → H3PO 4 4 conjugate acid Only in reaction (ii) H2PO − acids as ‘acid’. H+ − CO32 total total − is negligible compared to HCO3 or H+ 19. 19. If the radius of the cation is 110 pm.
2 x 10 g (4) 5.0 x 10 . will Mg ions start precipitating 2+ in the form of Mg(OH)2 from a solution of 0. Phone: 04066777000 – 03 Fax: 04066777004 . At which pH.5 V (4) 5. precipitation just starts when 10 No. = 10–11 –11 = 10 x 120 –9 = 1. moles of KBr is added to 1L of AgNO3 solution. Saifabad.9 10 11 Na + = = 1.3 10 O2 − = –13 22.001 M Mg ions ? (1) 9 (2) 10 (3) 11 (4) 8 (2) Mg2 + + 2OH− Mg(OH)2 –11 2+ 24.1 10 12 Mg2 + = = 1.AIEEE−2010−8 − − z for e 8 = 0. 500 063.5 V ∴ The potential difference needed for the reduction = 2. Secretariat) Hyderabad.05 –11 i.5 V (2) 3.5 V At 25°C. Sol : The Gibbs energy for the decomposition of Al2O3 at 500°C is as follows : 2 4 –1 Al2O3 → Al + O2.2 10 13 Al3 + = = 1.0 V (3) −∆G ∆G = – nFE E= nF 966 × 103 E=− 4 × 96500 = –2.2 x 10 g 23.e..0 V (3) 2. 24. Sol : Solubility product of silver bromide is 5. the solubility product of Mg(OH)2 is 1.0 x 10 g (1) 1. 5914/B.8 10 9 F− = = 0.0 x 10 .2 x 10 g (2) + – Ag + Br AgBr Precipitation starts when ionic product just exceeds solubility product K sp = Ag+ Br − Br − = K sp Ag + = 5 × 10−13 = 10 −11 0. (Opp. Sol : K sp = Mg2 + OH− = ∴ pOH = 4 OH− K sp Mg2 + 2 = 10 −4 and pH = 10 (Hyderabad Classes) Limited. ∆rG = + 966 kJ mol 3 3 The potential difference needed for electrolytic reduction of Al2O3 at 500°C is at least (1) 4.2 x 10 g (3) 6. of moles of KBr to be added ∴ weight of KBr to be added 23. The quantity of potassium bromide (molar mass –1 taken as 120 g of mol ) to be added to 1 litre of 0.05 M solution of silver nitrate to start the precipitation of AgBr is –10 –9 –5 –8 (2) 1. 22.
Sol : For a particular reversible reaction at temperature T. Phone: 04066777000 – 03 Fax: 04066777004 . 30. The three currents I1. Sol : and Co is (1) Mn > Cr > Fe > Co (2) Cr > Fe > Mn > Co (3) Fe > Mn > Cr > Co (4) Cr > Mn > Fe > Co (1) The polymer containing strong intermolecular forces e.g. ∆G = 0 for a reaction to be spontaneous ∆G should be negative ∴ T > Te 31. A rectangular loop has a sliding connector PQ of length and resistance R Ω and it is moving with a speed v as shown. Secretariat) Hyderabad. (Opp. 25. ∆H and ∆S were found to be both +ve. I2 and I are (Hyderabad Classes) Limited. 27. Urea also has amide linkage like proteins. Sol : Percentage of free space in cubic close packed structure and in body centred packed structure are respectively (1) 30% and 26% (2) 26% and 32% (3) 32% and 48% (4) 48% and 26% (2) packing fraction of cubic close packing and body centred packing are 0. 500 063. is (1) teflon (2) nylon 6. If Te is the temperature at equilibrium.74 and 0. the alkene that exhibits optical isomerism is (1) 3–methyl–2–pentene (2) 4–methyl–1–pentene (3) 3–methyl–1–pentene (4) 2–methyl–2–pentene (3) H H2C=HC CH3 C2 H5 only 3–methyl–1–pentene has a chiral carbon 27. Sol : 26. Out of the following. 29.6 (3) polystyrene (4) natural rubber (2) nylon 6. the reaction would be spontaneous when (1) Te > T (2) T > Te (3) Te is 5 times T (4) T = Te (2) ∆G = ∆H − T∆S at equilibrium.AIEEE−2010−9 − − 25. The correct order of E0 2 + M /M values with negative sign for the four successive elements Cr. The setup is placed in a uniform magnetic field going into the plane of the paper. 29.68 respectively. hydrogen bonding. Sol : 28. Mn. Fe 28. Saifabad. Biuret test is not given by (1) carbohydrates (2) polypeptides (3) urea (4) proteins (1) It is a test characteristic of amide linkage. 26. 5914/B.6 is a polymer of adipic acid and hexamethylene diamine O O C (CH2)4 C NH (CH2)6 NH n 30.
I= R R B v 2B v (2) I1 = I2 = . Sol. Secretariat) Hyderabad. choose the one that best describes the two statements. 500 063. Sol. Of the four choices given after the statements. (Opp. Phone: 04066777000 – 03 Fax: 04066777004 . (Hyderabad Classes) Limited. Saifabad. 5914/B. Let C be the capacitance of a capacitor discharging through a resistor R. I= 6R 3R 2 A moving conductor is equivalent to a battery of emf = v B Equivalent circuit I = I1 + I2 applying Kirchoff’s law ……………(1) I1R + IR − v B = 0 (3) I1 = I2 = I = (motion emf) I2R + IR − v B = 0 adding (1) & (2) 2IR + IR = 2v B ……………(2) R I1 I2 R I= 2vB 3R vB 3R I1 = I2 = 32. 33. B v R B v B v (4) I1 = I2 = .AIEEE−2010−10 − − (1) I1 = −I2 = B v 2B v . Statement2 : Principle of conservation of momentum holds true for all kinds of collisions. 32. I= 3R 3R 31. Statement1 : Two particles moving in the same direction do not lose all their energy in a completely inelastic collision. Then the ratio t1/t2 will be 1 1 (1) 1 (2) (3) (4) 2 2 4 3 q2 1 q2 1 U= (q0 e− t / T )2 = 0 e−2t / T (where τ = CR ) = 2 C 2C 2C U = Ui e −2t / τ Now 1 Ui = Ui e−2t 2 1 = e −2t / τ 2 q = q0 e − t / T 1 1 /τ t1 = T ln 2 2 1 q0 = q0 e − t / 2T 4 t 2 = T ln 4 = 2T ln 2 ∴ t1 1 = t2 4 Directions: Questions number 33 – 34 contain Statement1 and Statement2. Suppose t1 is the time taken for the energy stored in the capacitor to reduce to half its initial value and t2 is the time taken for the charge to reduce to onefourth its initial value.
E = m1v1 + m2 v 2 m1 + m2 2 p1 p2 + 2 2m1 2m2 as p1 and p2 both simultaneously cannot be zero therefore total KE cannot be lost. the energy of each incident photon will be more for X–rays K. Statement2 is true. A ball is made of a material of density ρ where ρoil < ρ < ρwater with ρoil and ρwater representing the densities of oil and water. which of the following pictures represents its equilibrium position ? (1) (2) 35. Statement2 is true. Statement2 : Photoelectrons are emitted with speeds ranging from zero to a maximum value because of the range of frequencies present in the incident light. both V0 and Kmax increase. Secretariat) Hyderabad. Phone: 04066777000 – 03 Fax: 04066777004 . Statement1 : When ultraviolet light is incident on a photocell. 4 Since the frequency of ultraviolet light is less than the frequency of X–rays. (4) Statement1 is true. Statement2 is true. respectively. (4) Statement1 is true. The oil and water are immiscible. Sol.Emax because of loss of energy due to subsequent collisions before getting ejected and not due to range of frequencies in the incident light. (Opp. Statement2 is false. Statement2 is true. (2) Statement1 is true. (Hyderabad Classes) Limited.E photoelectron = hν − ϕ Stopping potential is to stop the fastest photoelectron hν ϕ V0 = − e e so. (1) Statement1 is true. But K. 5914/B. Statement2 is false. (3) Statement1 is false.E ranges from zero to K. 34. 34. (2) Statement1 is true. Statement2 is true. its stopping potential is V0 and the maximum kinetic energy of the photoelectrons is Kmax. Saifabad. (1) Statement1 is true. Statement2 is true. If the above ball is in equilibrium in a mixture of this oil and water. 1 m1 m2 v1 v2 If it is a completely inelastic collision then m1v1 + m2 v 2 = m1v + m2 v v= K.AIEEE−2010−11 − − 33. 500 063. Statement2 is the correct explanation of Statement1. Statement2 is the correct explanation of Statement1. When the ultraviolet light is replaced by Xrays. Statement2 is not the correct explanation of Statement1 (3) Statement1 is false. Sol. Statement2 is not the correct explanation of Statement1.Emax and V0 both increases. K.
Two long parallel wires are at a distance 2d apart. They carry steady equal current flowing out of the plane of the paper as shown. The general equation for its path is 2 2 2 2 (1) y = x + constant (2) y = x + constant (3) xy = constant (4) y = x + constant 4 v = Ky ˆ + Kx ˆ i j dx dy = Ky. Sol.AIEEE−2010−12 − − (3) (4) 35. Bin between = 0 for x < d. 36. i j) A particle is moving with velocity v = K(y ˆ + x ˆ . = Kx dt dt dy dy dt Kx = × = dx dt dx Ky y dy = x dx 2 2 y = x + c. The variation of the magnetic field along the line XX 'is given by (2) (1) (3) (4) 37. Bin between = ( ˆ j) for x > d. Bin between = ( − ˆ j) towards x net magnetic field will add up and direction will be ( −ˆ j) ˆ towards x 'net magnetic field will add up and direction will be ( j) (Hyderabad Classes) Limited. it will sink through oil but will not sink in water. where K is a constant. So it will stay at the oil–water interface. 1 The magnetic field in between because of each will be in opposite direction µ i µ0i Bin between = 0 ˆ − j ( −ˆ j) 2πx 2π(2d − x) µi 1 1 = 0 − (ˆ j) 2π x 2d − x at x = d. So. Saifabad. (Opp. 37. 2 ρoil < ρ < ρwater Oil is the least dense of them so it should settle at the top with water at the base. 36. Sol. Now the ball is denser than oil but less denser than water. Phone: 04066777000 – 03 Fax: 04066777004 . Secretariat) Hyderabad. 500 063. Sol. 5914/B.
6 Ns (4) 0.8 N – s ( J = impulse) J = 0. Pji = −0. In the circuit shown below. 2 At t = 0. i = R2 and at t = ∞ . 500 063.8 N–s Directions : Questions number 40 – 41 are based on the following paragraph. uniform motion. Sol. 40. A nucleus of mass M + ∆m is at rest and decays into two daughter nuclei of equal mass Speed of light is c.4 N – s 39.AIEEE−2010−13 − − 38.4 kg. the daughter nuclei will be more stable hence binding energy per nucleon will be more than that of their parent nucleus.4 – 0. inductor behaves like an infinite resistance V So at t = 0. The magnitude of each impulse is (1) 0. the key K is closed at t = 0. 2 The binding energy per nucleon for the parent nucleus is E1 and that for the daughter nuclei is E2. M each.4 Ns (2) 0. Sol. Then (1) E2 = 2E1 (2) E1 > E2 (3) E2 > E1 (4) E1 = 2E2 3 After decay. Sol.8 Ns (3) 1. 39. 2 Initial velocity = = 1 m / s 2 2 Final velocity = − = −1 m / s 2 Pi = 0. 40. inductor behaves like a conducting wire V(R1 + R 2 ) V i= = Re q R1 R 2 The figure shows the position – time (x – t) graph of onedimensional motion of a body of mass 0.4 N – s J = Pf − Pi = – 0.2 Ns 2 From the graph. Secretariat) Hyderabad.4 = – 0. Because of impulse direction of velocity changes as can be seen from the slope of the graph. The current through the battery is V R1 R2 V (1) at t = 0 and at t = ∞ 2 2 R2 R1 + R2 (2) (3) (4) V (R1 + R2 ) V at t = 0 and at t = ∞ R2 R1 R 2 V at t = 0 and R2 V R1 R2 2 2 R1 + R2 at t = ∞ V (R1 + R2 ) V at t = 0 and at t = ∞ R1 R 2 R2 38. Phone: 04066777000 – 03 Fax: 04066777004 . 5914/B. it is a straight line so. (Hyderabad Classes) Limited. Saifabad. (Opp.
of proton will reduce by 8.V22 2 2 2 2 M 2 2 ∆mc = V1 2 2∆mc 2 = V12 M 2∆m V1 = c M 42. V12 + . Sol. 5914/B. 43. The net field E at the centre O is q q ˆ ˆ (1) (2) – j j 4 π2 ε0 r 2 4 π2 ε 0 r 2 (3) – q ˆ j 2 π2 ε0 r 2 (4) q ˆ j 2 π2 ε 0 r 2 q πr 43. The ratio of number of neutrons to that of protons in the final nucleus will be A −Z−8 A − Z − 12 A−Z−4 A−Z−4 (2) (3) (4) (1) Z−4 Z−4 Z−2 Z−8 2 In positive beta decay a proton is transformed into a neutron and a positron is emitted. y dθ θ θ x K.dq E = dE sin θ( −ˆ = j) sin θ( −ˆ j) r2 K qr E= 2 d θ sin θ( −ˆ j) r πr = K qπ sin θ( − ˆ j) r2 π 0 = q (−ˆ j) 2π ε 0 r 2 2 (Hyderabad Classes) Limited. Secretariat) Hyderabad.AIEEE−2010−14 − − 41. p + n0 + e + → no.(2) 1 M 1 M ∆mc 2 = .(1) ……………. Sol. of neutrons initially was A – Z no. A thin semicircular ring of radius r has a positive charge q distributed uniformly over it. (Opp. A radioactive nucleus (initial mass number A and atomic number Z) emits 3 αparticles and 2 positrons. [as 3 x 2 (due to alpha particles) + 2(due to positive beta decay)] Hence atomic number reduces by 8. 500 063. 3 Linear charge density λ = Sol. 42. 2 Conserving the momentum M M 0 = V1 − V2 2 2 V1 = V2 ∆m M + ∆m (2) c 2∆m M (3) c ∆m M (4) c ∆m M + ∆m ……………. of neutrons after decay (A – Z) – 3 x 2 (due to alpha particles) + 2 x 1 (due to positive beta decay) The no. Phone: 04066777000 – 03 Fax: 04066777004 . The speed of daughter nuclei is (1) c 41. Saifabad. .
(Hyderabad Classes) Limited.0003 and 2. Secretariat) Hyderabad. 2 (4) 4. 45.AIEEE−2010−15 − − 44.023 × 10−34 16 f = 6. 45. 46. 2 1 20 47.25 2 The efficiency of cycle is T η = 1− 2 T1 for adiabatic process TVγ–1 = constant 7 For diatomic gas γ = 5 γ −1 γ −1 T1V1 = T2 V2 44. Sol. 1. Sol. If a source of power 4 kW produces 10 photons/second. 1.023. The respective number of significant figures for the numbers 23.1 x 10–3 are (1) 5. 5 (3) 5. The combination of gates shown below yields (2) NOT gate (1) OR gate (3) XOR gate (4) NAND gate 1 Truth table for given combination is A B X 0 0 0 0 1 1 1 0 1 1 1 1 This comes out to be truth table of OR gate A diatomic ideal gas is used in a Car engine as the working substance. T1 = T2 V2 V1 7 γ −1 T1 = T2 (32)5 −1 = T2 (25 )2 / 5 = T2 x 4 T1 = 4T2. Sol. 500 063. 47. 2 (2) 5. the radiation belong to a part of the spectrum called (1) X–rays (2) ultraviolet rays (3) microwaves (4) γ–rays 1 3 20 4 x 10 = 10 x hf 4 × 103 f = 20 10 × 6.5 (2) 0. 0. 1 3 η = 1− = = 0. If during the adiabatic expansion part of the cycle.75 (3) 0.03 x 10 Hz The obtained frequency lies in the band of X–rays.99 (4) 0.75 4 4 46. volume of the gas increases from V to 32V the efficiency of the engine is (1) 0. Saifabad. 5914/B. Phone: 04066777000 – 03 Fax: 04066777004 . 4. (Opp. 5.
50. The power dissipated in the LCR circuit is (1) 305 W (2) 210 W (3) Zero W (4) 242 W 4 The given circuit is under resonance as XL = XC Hence power dissipated in the circuit is V2 = 242 W P= R Let there be a spherically symmetric charge distribution with charge density varying as 5 r upto r = R. F = 0 (Hyderabad Classes) Limited. If the dissociation energy of the molecule is D = [U(x = ∞) – Uat equilibrium]. Sol. Phone: 04066777000 – 03 Fax: 04066777004 . 49.ρ0 = 4πρ0 dq = q = 4πρ0 = 4πρ0 r 5 r − 4 R 5 2 r3 r dr − dr 4 R 0 5 2 r3 r dr − dr 4 R 5 r3 1 r4 − 43 R 4 E= kq r2 1 1 5 r3 r4 = . F=− = − 13 + 7 dx x x at equilibrium.ρ 49. 500 063. On taking out the capacitance from the circuit the current lags behind the voltage o . Saifabad. (Opp. Sol. where a and b are constants and x is the distance between x x the atoms. Secretariat) Hyderabad.AIEEE−2010−16 − − 48. 48. = 4πr 2 . 5914/B. Sol.4πρ0 − 2 4πε0 r 4 3 4R ρ0 r 5 r − 4ε 0 3 R E= 50. where r is the distance from the origin. The ρ(r) = ρ0 − 4 R electric field at a distance r(r < R) from the origin is given by 4πρ0 r 5 r ρ r 5 r 4 ρ0 r 5 r ρ r 5 r (1) (2) 0 (3) (4) 0 − − − − 3 ε0 3 R 4 ε0 3 R 3 ε0 4 R 3 ε0 4 R 2 Apply shell theorem the total charge upto distance r can be calculated as followed dq = 4 πr 2 .dr. The potential energy function for the force between two atoms in a diatomic molecule is a b approximately given by U(x) = 12 − 6 . In a series LCR circuit R = 200 Ω and the voltage and the frequency of the main supply is 220 V and 50 Hz respectively.dr. and ρ(r) = 0 for r > R. by 30° On taking out the inductor from the circuit the current leads the voltage by 30 . D is b2 b2 b2 b2 (1) (2) (3) (4) 2a 12a 4a 6a 3 a b U(x) = 12 − 6 x x U(x = ∞) = 0 dU 12a 6b as.
Sol.D of sphere. If density of the material of the sphere is 16 g cm . When suspended in a liquid of density 0. the dielectric constant of the liquid is (1) 4 (2) 3 (3) 2 (4) 1 3 From F. 5914/B.AIEEE−2010−17 − − ∴ ∴ x6 = Uat equilibrium = 2a b a 2a b 2 − b −b2 = 2a 4a b ∴ 51. The strings make an –3 angle of 30° with each other. Rs = R1 + R2 R s 0 (1 + α s θ) = R0 (1 + α1θ) + R0 (1 + α 2 θ) where R s 0 = R 0 + R0 = 2R0 ∴ or 2R0 (1 + α s θ) = 2R0 + R0 θ(α1 + α 2 ) αs = α1 + α 2 2 Rp = R1 R 2 R1 + R 2 for parallel combination. The respective temperature coefficients of their series and parallel combinations are nearly α + α2 α + α2 α1 α 2 α + α 2 α1 + α 2 (1) 1 . Two conductors have the same resistance at 0oC but their temperature coefficients of resistance are α1 and α2.B.8 g cm . (Opp. D = U(x = ∞) − Uat equilibrium = b2 4a 51. the angle remains –3 the same. F' = ρ mg K mg 1 − d ∴ F = mg F' mg K 1 − ρ d or K= 1 1− ρ d =2 52. 52. as θ remains same. Two identical charged spheres are suspended by strings of equal lengths. 500 063. Sol. 1 (3) α1 + α 2 . using Lami’s theorem F = tan θ ………………(i) T θ mg F when suspended in liquid. F' ………………(ii) ∴ = tan θ ρ mg 1 − mg d using (i) and (ii) F F' F = where. Secretariat) Hyderabad. 2 2 α1 + α 2 2 2 4 Let R0 be the initial resistance of both conductors ∴ At temperature θ their resistance will be. (4) 1 . (Hyderabad Classes) Limited. R1 = R0 (1 + α1θ) and R2 = R0 (1 + α 2 θ) for. α1 + α 2 (2) α1 + α 2 . series combination. Phone: 04066777000 – 03 Fax: 04066777004 . Saifabad.
ac = = m / s2 R 20 rate of change of speed = net acceleration = ≈ 14 m / s2 a2 + ai2 t 54. Saifabad. What is the relative vertical acceleration of A with respect to B ? –2 (1) 4. 500 063.9 ms in vertical direction 4 mg sin θ = ma ∴ a = g sin θ where a is along the inclined plane 2 ∴ vertical component of acceleration is g sin θ ∴ relative vertical acceleration of A with respect to B is (Hyderabad Classes) Limited. Rp0 = ∴ as ∴ or as ∴ 53. dv = 6t dt 2 tangential acceleration at t = 2s. The acceleration of ‘P’ when t = 2 s is nearly 2 2 (2) 12 m/s (1) 13 m/s 2 2 (3) 7. 5914/B. where s is in metres and t is in seconds. Secretariat) Hyderabad.8 ms in vertical direction (3) zero –2 (4) 4. at = 6 x 2 = 12 m/s 2 t = 2s. Sol.AIEEE−2010−18 − − Rp0 (1 + αp θ) = where. R0 (1 + α1θ)R0 (1 + α 2 θ) R0 (1 + α1θ) + R0 (1 + α 2 θ) R0 R0 R = 0 R0 + R 0 2 R0 R2 (1 + α1θ + α 2 θ + α1α 2 θ) (1 + αp θ) = 0 2 R 0 (2 + α1θ + α 2 θ) α1 and α 2 are small quantities α1 α 2 is negligible αp = α1 + α 2 α + α2 = 1 [1 − (α1 + α 2 )θ] 2 + (α1 + α 2 )θ 2 ( α1 + α 2 )2 is negligible αp = α1 + α 2 2 A point P moves in counterclockwise direction on a circular path as shown in the figure. Sol. (Opp. v = ds = 3t 2 dt 53. The radius of the path is 20 m. v = 3(2) = 12 m/s v 2 144 centripetal acceleration.9 ms in horizontal direction –2 (2) 9.2 m/s (4) 14 m/s 4 S = t3 + 5 ∴ and ∴ at ∴ ∴ speed. Phone: 04066777000 – 03 Fax: 04066777004 o 54. Two fixed frictionless inclined plane making an angle 30 and 60o with the vertical are shown in the figure. Two block A and B are placed on the two planes. . The movement of ‘P’ is such that it 3 sweeps out a length s = t + 5.
Sol. 2 55. θ) ac v2 ∴ a= ( − cos θ ˆ − sin θ ˆ i j) R x 2 ac v2 ˆ − v sin θ ˆ or a = − cos θ i j R R Directions: Questions number 56 – 58 are based on the following paragraph. 58. 57. 56. Phone: 04066777000 – 03 Fax: 04066777004 . As the beam enters the medium. The speed of light in the medium is (1) minimum on the axis of the beam (3) directly proportional to the intensity I 1 (2) the same everywhere in the beam (4) maximum on the axis of the beam 56. (Opp. where µ0 and µ2 are positive constants and I is the intensity of the light beam. y v2 towards centre of circle a= R P (R. An initially parallel cylindrical beam travels in a medium of refractive index µ(I) = µ0 + µ 2I . The initial shape of the wave front of the beam is (1) convex (2) concave (3) convex near the axis and concave near the periphery (4) planar 4 For a parallel cylinderical beam. ∴ beam will converge. Sol. 57. 5914/B.AIEEE−2010−19 − − g[sin2 60 − sin2 30] = 55. The intensity of the beam is decreasing with increasing radius. θ) on the circle of radius R is (here θ is measured from the x–axis) v2 v2 v2 v2 (2) − sin θ ˆ + cos θ ˆ (1) − cos θ ˆ + i sin θ ˆ j i j R R R R v2 v2 v2 ˆ v2 ˆ (3) − cos θ ˆ − sin θ ˆ (4) i j i+ j R R R R 3 For a particle in uniform circular motion.9 m / s2 in vertical direction. Sol. ∴ µ will be maximum and speed will be minimum on the axis of the beam. it will (1) diverge (2) converge (3) diverge near the axis and converge near the periphery (4) travel as a cylindrical beam 2 As intensity is maximum at axis. Saifabad. g = 4. (Hyderabad Classes) Limited. wavefront will be planar. Secretariat) Hyderabad. For a particle in uniform circular motion the acceleration a at a point P(R. 500 063. 58.
then tan 2α = 5 13 4 19 20 25 (2) (3) (4) 12 7 16 tan(α + β) = 61.04(s) 0. 500 063. (1) 4.5 N . Secretariat) Hyderabad.25 N k2 (2π / 0. 1 1 ˆ (3) − mgv 0 t 2 cos θ k (4) mgv 0 t 2 cos θ ˆ i 2 2 ˆ where ˆ ˆ and k are unit vectors along x. At a time t < 0 .004)2 = 0. The equation of a wave on a string of linear mass density 0. Which of the following statements is the negation of the statement P ? (1) There is no rational number x ∈ S such that x ≤ 0 (2) Every rational number x ∈ S satisfies x ≤ 0 (Hyderabad Classes) Limited. Phone: 04066777000 – 03 Fax: 04066777004 .5 N (4) 6. The tension in the string is (3) 0.0 N 4 T = µv 2 = µ (2) 12. Sol. the angular momentum of the g particle is ˆ (1) −mgv 0 t 2 cos θ ˆ j (2) mgv 0 t cos θ k 59.04 kg m –1 is given by t x y = 0. A small particle of mass m is projected at an angle θ with the xaxis with an initial velocity v0 in the xy plane as shown in the v sin θ figure. 1 3 4 5 tan(α – β) = 12 3 5 + 56 tan 2α = tan(α + β + α – β) = 4 12 = 3 5 33 1− 4 12 4 5 5 sin(α – β) = 13 cos (α + β) = 62. Consider the following statement: P: There is a rational number x ∈ S such that x > 0.04 = 6.50(m) 60.02(m)sin 2π − 0. 5914/B. j 3 L = m(r × v) 1 ˆ ˆ L = m v 0 cos θt ˆ + (v 0 sin θt − gt 2 )j × v 0 cos θ ˆ + (v 0 sin θ − gt)j i i 2 1 ˆ = mv 0 cos θt − gt k 2 1 ˆ = − mgv 0 t 2 cos θk 2 60.AIEEE−2010−20 − − 59.50)2 61. y and z–axis respectively. (Opp. where 0 ≤ α.25 N ω2 (2π / 0. Let S be a nonempty subset of R. β ≤ . i. Sol. Saifabad. Let cos(α + β) = (1) 56 33 π 4 5 and let sin(α – β) = .
Then vector b satisfying a × b + c = 0 and a ⋅ b = 3 is j ˆ i j ˆ ˆ j ˆ ˆ ˆ ˆ (1) 2i − ˆ + 2k (2) ˆ − ˆ − 2k i j (3) ˆ + ˆ − 2k i j (4) −ˆ + ˆ − 2k i j 4 c = b×a b⋅c = 0 ˆ i j ˆ b1ˆ + b2 ˆ + b3k ⋅ ˆ − ˆ − k = 0 i j 63. (3) x ∈ S and x ≤ 0 x is not rational (4) There is a rational number x ∈ S such that x ≤ 0 2 P: there is a rational number x ∈ S such that x > 0 ~P: Every rational number x ∈ S satisfies x ≤ 0 Let a = ˆ − k and c = ˆ − ˆ − k . that is parallel to the xaxis. = e = sec x Solution is t(I. 63.F) sec x dx (Hyderabad Classes) Limited. Phone: 04066777000 – 03 Fax: 04066777004 . 0 < x < (1) y sec x = tan x + c (2) y tan x = sec x + c 4 cos x dy = y(sin x – y) dx dy = y tan x − y 2 sec x dx 1 dy 1 − tan x = − sec x y 2 dx y Let − − π is 2 (3) tan x = (sec x + c)y (4) sec x = (tan x + c)y 1 =t y 1 dy dt = y 2 dx dx dy dt – t tan x = –sec x + (tan x) t = sec x. 64. Secretariat) Hyderabad. Saifabad. 65. i j 64. The equation of the tangent to the curve y = x + (1) y = 1 3 Parallel to xaxis (2) y = 2 dy =0 dx 4 . y–3=0 Solution of the differential equation cos x dy = y(sin x – y) dx. (Opp. ( )( ) b1 – b2 – b3 = 0 and a ⋅ b = 3 b2 – b3 = 3 b1 = b2 + b3 = 3 + 2b3 ˆ b = ( 3 + 2b3 ) ˆ + ( 3 + b3 ) ˆ + b3k . 5914/B.F) = (I.AIEEE−2010−21 − − 62. is x2 (3) y = 3 (4) y = 0 1− 8 =0 x3 x=2 y=3 Equation of tangent is y – 3 = 0(x – 2) 65.F. 500 063. dx dx tan x dx I.
then (λ.AIEEE−2010−22 − − 1 sec x = tan x + c y 66. µ = 2 (3) (3. –3) (2) (–2. 500 063. µ) = i j j ˆ i j (1) (2. c ⋅a = 0 2λ + 4 + µ = 0 λ – 1 + 2µ = 0 Solving we get: λ = –3. 5914/B. S= m p . 2) 69. 68. Then 69. (Opp. If two tangents drawn from a point P to the parabola y = 4x are at right angles. b = 2i + 4ˆ + k and c = λ ˆ + ˆ + µk are mutually orthogonal. n. ˆ ˆ ˆ If the vectors a = ˆ − ˆ + 2k. The area bounded by the curves y = cos x and y = sin x between the ordinates x = 0 and x = (1) 4 2 + 2 4 π 4 0 5π 4 π 4 3π is 2 (2) 4 2 – 1 3π 2 (3) 4 2 + 1 (4) 4 2 – 2 ( cos x − sin x ) dx + ( sin x − cos x ) dx + ( cos x − sin x ) = 4 5π 4 2 −2 cos x sin x 5π 3π 2 π 0 π 4 4 2π 67. Secretariat) Hyderabad. x = –1 2 68. 3) 4 a ⋅ b = 0. n q m. b ⋅ c = 0. 66.e. y are real numbers and x = wy for some rational number w}. then the locus of P is (1) 2x + 1 = 0 (2) x = –1 (3) 2x – 1 = 0 (4) x = 1 2 The locus of perpendicular tangents is directrix i. Saifabad. Consider the following relations: R = {(x. (1) neither R nor S is an equivalence relation (2) S is an equivalence relation but R is not an equivalence relation (3) R and S both are equivalence relations (4) R is an equivalence relation but S is not an equivalence relation 2 xRy need not implies yRx m p S: s ⇔ qm = pn n q m m s reflexive n n (Hyderabad Classes) Limited. –2) (4) (–3. y)  x. Phone: 04066777000 – 03 Fax: 04066777004 . q ≠ 0 and qm = pn . x = –a. p and q are integers such that n. 67.
. Statement1: The probability that the chosen numbers when arranged in some order will form an AP 1 is .. if x ≤ −1 . You have to select the correct choice. 72. is (1) 5 (2) 6 (3) at least 7 (4) less than 4 3 First row with exactly one zero. Statement2 is not the correct explanation for Statement1 (2) Statement1 is true. 500 063.. 2. Saifabad. Let f: R → R be defined by f(x) = possible value of k is (1) 0 70. (1) Statement1 is true. Statement1: (Assertion) and Statement2: (Reason) Each of these questions also has four alternative choices. Each of these questions contains two statements. Four numbers are chosen at random (without replacement) from the set {1. Phone: 04066777000 – 03 Fax: 04066777004 . 70. If f has a local minimum at x = –1. ±4.. 71. Directions: Questions Number 72 to 76 are Assertion – Reason type questions. . 85 Statement2: If the four chosen numbers from an AP.AIEEE−2010−23 m p s n q m p p r s . 20}. S is an equivalence relation. The number of 3 × 3 nonsingular matrices. only one of which is the correct answer. ±5}.. Statement2 is true. ±3. 72. then a 2x + 3. Secretariat) Hyderabad. ±2. 5914/B. Statement2 is true. s n q q s p m s symmetric q n qm = pn. Statement2 is true (4) Statement1 is true. 3 f(x) = k – 2x = 2x + 3 k − 2x. total number of cases = 6 First row 2 zeros we get more cases Total we get more than 7. ps = rq ms = rn transitive. Statement2 is the correct explanation for Statement1 2 (Hyderabad Classes) Limited. then the set of all possible values of common difference is {±1. with four entries as 1 and all other entries as 0. Statement2 is false (3) Statement1 is false. if x > −1 (3) –1 (4) 1 (2) − if x ≤ –1 if x > –1 1 2 k – 2x 1 –1 x →−1− 2x + 3 lim f(x) ≤ –1 This is true where k = –1 71. 3. (Opp.
Statement2 is not the correct explanation for Statement1 (2) Statement1 is true. total number of cases = 11 common difference is 4. 1. 1). –2. Statement2 is true (4) Statement1 is true. B = (1. Statement2 is the correct explanation for Statement1 1 A(3. Statement2 is false 2 8 (Hyderabad Classes) Limited. Statement2 is true (4) Statement1 is true. 5914/B. Let A be a 2 × 2 matrix with nonzero entries and let A = I. Statement2 is not the correct explanation for Statement1 (2) Statement1 is true. 2. (Opp. Statement2 is not the correct explanation for Statement1 (2) Statement1 is true. Phone: 04066777000 – 03 Fax: 04066777004 . total number of cases = 8 common difference is 5. 2 8 9 8 9 = 90 . 1. 2 + 20 . Statement2 is true. 3. and d. (1) Statement1 is true. –1. 2 + 10 . 2 . S2 = 9 10 j =1 j 10 C j and S3 = 10 j =1 j2 10 Cj . 5) lies on the plane. 3. 3. Statement2 is false (3) Statement1 is false. 4). 74.r’s Of normal to plane = (1. Statement1: The point A(3. 2 = 55 . 2) d. Statement2 is true. (1) Statement1 is true. 4) in the plane x – y + z = 5. Statement2 is true. 74. Statement1: S3 = 55 × 2 8 8 Statement2: S1 = 90 × 2 and S2 = 10 × 2 . Statement1: Tr(A) = 0 Statement2: A = 1 (1) Statement1 is true. AB is perpendicular bisector ∴ A is image of B Statement2 is correct but it is not correct explanation. j ( j − 1)( j − 2 ) ! (10 − j )! j − 2)! ( 8 − ( j − 2) )! j =1 j= 2 ( S2 = S3 = 10 j =1 10 j =1 j 10 10! 9! = 10 = 10 ⋅ 29 . 4) Midpoint of AB = (2. 6) is the mirror image of the point B(1. Secretariat) Hyderabad. Saifabad. Statement2 is the correct explanation for Statement1 2 10 10 10! 8! S1 = j ( j − 1) = 90 = 90 ⋅ 28 . total number of cases = 14 common difference is 3.r’s of AB = (2. 75. 1. total number of cases = 17 common difference is 2. 6).AIEEE−2010−24 N(S) = C4 Statement1: common difference is 1. 20 73. 6) and B(1. j ( j − 1)! ( 9 − ( j − 1) )! j − 1)! ( 9 − ( j − 1) )! j =1 ( j ( j − 1) + j 10! = j! (10 − j )! 10 j =1 j ( j − 1) 10 C j = 8 10 j =1 j 10 C j = 90 . 500 063. Statement2 is true. = 20 85 C4 73. where I is 2 × 2 identity matrix. Statement2 is true. Statement2: The plane x – y + z = 5 bisects the line segment joining A(3. 2 = 110 . Statement2 is false (3) Statement1 is false. = . total number of cases = 5 common difference is 6. total number of cases = 2 17 + 14 + 11 + 8 + 5 + 2 1 Prob. Define Tr(A) = sum of diagonal elements of A and A = determinant of matrix A. Let S1 = 10 j =1 j ( j − 1) 10 C j .
(Opp. Statement2 is the correct explanation for Statement1 2 a b Let A = . Phone: 04066777000 – 03 Fax: 04066777004 . for some c ∈ R. Let f: R → R be a continuous function defined by f(x) = Statement1: f(c) = 1 . bc + d2 = 1 ab + bd = ac + cd = 0 c ≠ 0 and b ≠ 0 a+d=0 Trace A = a + d = 0 A = ad – bc = –a2 – bc = –1. e + 2e − x x 76. Statement2 is not the correct explanation for Statement1 (2) Statement1 is true. A false statement among the following is r 1 r 2 (1) There is a regular polygon with = (2) There is a regular polygon with = R R 3 2 (Hyderabad Classes) Limited. Secretariat) Hyderabad. for all x ∈ R 2 2 (1) Statement1 is true. 3 1 Statement2: 0 < f(x) ≤ . Statement2 is true (4) Statement1 is true. 5914/B.AIEEE−2010−25 75. let r and R be the radii of the inscribed and the circumscribed circles. For a regular polygon. Saifabad. 76. 500 063. abcd ≠ 0 c d A = 2 2 a b a b ⋅ c d c d a2 + bc ab + bd ac + cd bc + d2 A = a2 + bc = 1. Statement2 is true. Statement2 is the correct explanation for Statement1 4 1 ex f(x) = x = 2x e + 2e− x e + 2 f′(x) = (e 2x + 2 e x − 2e2x ⋅ e x (e ) ) 2x + 2 2 f′(x) = 0 2x e =2 maximum f(x) = 0 < f(x) ≤ 2 1 = 4 2 2 e + 2 = 2e x e = 2 2x 2x 1 2 2 1 1 Since 0 < < 3 2 2 1 f(c) = 3 ∀x∈R for some c ∈ R 77. Statement2 is true. Statement2 is true. Statement2 is true (4) Statement1 is true. (3) Statement1 is false. 1 . Statement2 is false (3) Statement1 is false.
r 3 = R 2 (4) There is a regular polygon with r 1 = R 2 a π cot 2 n ‘a’ is side of polygon. Secretariat) Hyderabad. cos ≠ n 3 r= 78. then α (1) –1 (2) 1 (3) 2 2 x –x+1=0 2 2 2009 2 +β 2009 = (4) –2 x= 1± 1− 4 2 1 i 3 − 2 2 π π β = cos − isin 3 3 π 2009 2009 α +β = 2cos2009 3 2π 2π = 2cos 668π + π + = 2cos π + 3 3 2π 1 = −2 − =1 = −2cos 3 2 β= 79. 5914/B. a π R = cosec 2 n π cot r n = cos π = π R n cosec n π 2 for any n ∈ N. 500 063.AIEEE−2010−26 (3) There is a regular polygon with 77. Number of complex number z = 1 A line AB in threedimensional space makes angles 45° and 120° with the positive xaxis and the positive yaxis respectively. Phone: 04066777000 – 03 Fax: 04066777004 . If α and β are the roots of the equation x – x + 1 = 0. (Hyderabad Classes) Limited. Saifabad. If AB makes an acute angle θ with the positive zaxis. The number of complex numbers z such that z – 1 = z + 1 = z – i equals (1) 1 (2) 2 (3) ∞ (4) 0 1 Let z = x + iy z – 1 = z + 1 Re z = 0 x=0 x=y z – 1 = z – i z + 1 = z – i y = –x Only (0. 0) will satisfy all conditions. 80. 3 3 x= 80. then θ equals (1) 45° (2) 60° (3) 75° (4) 30° 2 1± 3 i 2 1 3 α = +i . 78. 2 2 π π α = cos + isin . 79. (Opp.
Phone: 04066777000 – 03 Fax: 04066777004 .... with common difference –2. 500 063. 82. Then the distance between L and K is c 3 17 23 (2) (3) 15 17 (4) 23 15 Slope of line L = − b 5 3 Slope of line K = − c Line L is parallel to line k.. a11. 13 32 32 8 + =1 =− 5 b b 5 3 b = –20 c= − 4 Equation of K: y – 4x = 3 52 − 32 + 3 23 Distance between L and K = = 17 17 th 82. then the time taken by him to count all notes is (1) 34 minutes (2) 125 minutes (3) 135 minutes (4) 24 minutes 1 th Till 10 minute number of counted notes = 1500 n 3000 = [2 × 148 + (n – 1)(–2)] = n[148 – n + 1] 2 (Hyderabad Classes) Limited. = a10 = 150 and a10. The line L given by the equation (1) 81. b 3 bc = 15 = 5 c (13.. A person is to count 4500 currency notes. 3 (θ Being acute) x y + = 1 passes through the point (13.P. 32). Let an denote the number of notes he counts in the n minute. 3 81.. The line K is parallel to L and has 5 b 17 x y + = 1. Secretariat) Hyderabad. If a1 = a2 = .. 5914/B. .. (Opp. 2 2 2 Now + m + n = 1 1 1 2 + + cos θ = 1 2 4 1 2 cos θ = 4 1 cos θ = 2 π θ= .. Saifabad. 32) is a point on L. are in A.AIEEE−2010−27 = cos 45° = 1 2 1 2 m = cos 120° = − n = cos θ where θ is the angle which line makes with positive zaxis..
2 x →∞ f(3x) f(2x) = 1. 2(f′(0) = 4f(0) f′(0) = 4(–1) (1) = –4 2 (Hyderabad Classes) Limited. 5914/B. for all x ∈ [0.AIEEE−2010−28 n – 149n + 3000 = 0 n = 125. Let p(x) be a function defined on R such that p′(x) = p′(1 – x). Then lim = x →∞ f(x) f(x) (4) 1 2 3 (2) 3 2 (3) 3 4 f(x) is a positive increasing function 0 < f(x) < f(2x) < f(3x) f(2x) f(3x) < 0<1< f(x) f(x) f(2x) f(3x) lim 1 ≤ lim ≤ lim x →∞ x →∞ f(x) x →∞ f(x) By sandwich theorem. 83. Saifabad. Let f: R → R be a positive increasing function with lim (1) 83. f(2x) lim =1 x →∞ f(x) 84. 1 Then 0 p(x) dx equals (3) 42 (4) 41 84. (Opp. 500 063. 85. Secretariat) Hyderabad. 85. (1) 21 (2) 41 1 p′(x) = p′(1 – x) p(x) = –p(1 – x) + c at x = 0 p(0) = –p(1) + c 42 = c now p(x) = –p(1 – x) + 42 p(x) + p(1 – x) = 42 1 I= 0 p(x) dx = p(1 − x) dx 0 1 1 2I= 0 (42) dx I = 21. Total time = 24 + 10 = 34 minutes. 1]. (2f′(x)) dx g′(0) = 2f(2f(0) + 2) . Phone: 04066777000 – 03 Fax: 04066777004 . Then g′(0) = (1) –4 (2) 0 (3) –2 (4) 4 1 d g′(x) = 2(f(2f(x) + 2)) ( f ( 2f(x) + 2)) = 2f(2f(x) + 2) f′(2f(x) + 2) . 1) → R be a differentiable function with f(0) = –1 and f′(0) = 1. f′(2f(0) + 2) . 24 n = 125 is not possible. p(0) = 1 and p(1) = 41. Let g(x) = [f(2f(x) + 2)] . Let f: (–1.
Urn A has 3 distinct red balls and urn B has 9 distinct blue balls. (Opp. 89. does not have any solution. No solution. Consider the system of linear equations: x1 + 2x2 + x3 = 3 2x1 + 3x2 + x3 = 3 3x1 + 5x2 + 2x3 = 1 The system has (1) exactly 3 solutions (3) no solution 3 1 2 1 D= 2 3 1=0 (2) a unique solution (4) infinite number of solutions 3 5 2 3 2 1 D1 = 3 3 1 ≠ 0 1 5 2 Given system. Three balls are drawn at random without replacement from the urn. 87. The probability that the three balls have different colour is 2 1 2 1 (1) (2) (3) (4) 7 21 23 3 1 9 n(S) = C3 3 4 2 n(E) = C1 × C1 × C1 3 × 4 × 2 24 × 3! 24 × 6 2 Probability = 9 = × 6! = = . The number of ways in which this can be done is (1) 36 (2) 66 (3) 108 (4) 3 3 3 9 Total number of ways = C2 × C2 9×8 =3× = 3 × 36 = 108 2 86. 500 063. 5914/B. 87.AIEEE−2010−29 86. 9! 9×8×7 7 C3 For two data sets. each of size 5. the variances are given to be 4 and 5 and the corresponding means are given to be 2 and 4. (Hyderabad Classes) Limited. Saifabad. four are blue and two are green. From each urn two balls are taken out at random and then transferred to the other. Secretariat) Hyderabad. Phone: 04066777000 – 03 Fax: 04066777004 . 88. There are two urns. 89. respectively. The variance of the combined data set is 11 13 5 (1) (2) 6 (3) (4) 2 2 2 1 2 σx = 4 2 σy = 5 x= 2 y= 4 88. An urn contains nine balls of which three are red.
4). (Opp. Phone: 04066777000 – 03 Fax: 04066777004 . yi = 20 xi2 − ( x ) = 2 1 ( yi2 ) − 16 5 xi = 40 2 yi = 105 σz = 90. length of perpendicular from centre < radius 6 − 16 − m <5 5 10 + m < 25 –25 < m + 10 < 25 –35 < m < 15. Radius = 4 + 16 + 5 = 5 If circle is intersecting line 3x – 4y = m at two distinct points. Saifabad. *** (Hyderabad Classes) Limited. 5914/B. 90. 2 2 1 10 ( xi 2 + 2 2 y i2 − ) x+y 2 2 = 1 145 − 90 55 11 = = ( 40 + 105 ) − 9 = 10 10 10 2 The circle x + y = 4x + 8y + 5 intersects the line 3x – 4y = m at two distinct points if (1) –35 < m < 15 (2) 15 < m < 65 (3) 35 < m < 85 (4) –85 < m < –35 1 2 2 Circle x + y – 4x – 8y – 5 = 0 Centre = (2.AIEEE−2010−30 xi =2 5 1 2 σx = 2 xi = 10. Secretariat) Hyderabad. 500 063.
! . Phone: 04066777000 – 03 Fax: 04066777004 . ) / ( > # .AIEEE−2010−31 READ THE FOLLOWING INSTRUCTIONS CAREFULLY: ( ! . $/ 4 " A < % # < #  < ! < < < # < < < ! < 5 :  5) ! 7 < ( ! 5 < < ! ! 7 : # $ 5) 7 < 4 4 4 4 % * 1 # < ! ) ) # # ) # # (Hyderabad Classes) Limited. / 2 $ ! % * 3 2 < # 1 ! > 4 1 ! # . < # . 500 063. 5914/B. 8 3 4 & ' 5 1 # ! 7 7 @! ' . ) < ! . Secretariat) Hyderabad. Saifabad. %/ # ! < # ( 9 7  ! !  # /# . (Opp.
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