Expanded Octet Review

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Try to draw the structures and label bond angles and predict shapes without using your notes. After you have done all that you can w/o notes, change pencil/pen color and finish the assignment making any corrections using the new color. 1. Which of the following have bond angles of 90°? Show the Lewis structures of all species. TeF6 AsBr5 GaI3 XeF4

2. Which of the following have bond angles of 120°? ClF3 SbBr6 1 SbCl5 InCl3

Show the Lewis structures of all species.

3. Draw the Lewis structure for each of the following and give the geometry (shape) of each, and label the bond angles: IBr4 1 PCl4 1+ BF4 1 IF4 1+

4. Draw the Lewis structure for each of the following and then predict the shape of each: SeOCl2 SO2 Cl2 SOF4 ClO3 F

5. Follow the directions in #4 for each of the following species: SOCl3 1 XeO2 XeO2 F4

BrO2 1 IO2 F3

TeF5 1 -

6. The species NO2 1+ and NO2 1 - have O – N – O bond angles of 180° and 115°, respectively. Use VSEPR theory to explain the differences. Draw these on the other side of this page.

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