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FIITJEE Solutions to IIT-JEE-2012

CODE
PAPER 1
Time: 3 Hours Maximum Marks: 210



INSTRUCTIONS
A. General:
1. This booklet is your Question paper. Do not break the seats of his booklet before being instructed to do so by the
invigilators.
2. The question paper CODE is printed on the right hand top corner of this page and on the back page of this booklet.
3. Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will be provided
for rough work.
4 Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic gadgets are
NOT allowed inside the examination hall.
5. Answers to the questions and personal details are to be filled on a two-part carbon-less paper, which is provided
separately. You should not separate these parts. The invigilator will separate them at the end of examination. The upper
sheet is machine-gradable Objective Response Sheet (ORS) which will be taken back by the invigilator.
6. Using a black ball point pen, darken the bubbles on the upper original sheet. Apply sufficient pressure so that the
impression is created on the bottom sheet.
7. DO NOT TAMPER WITH /MUTILATE THE ORS OR THE BOOKLET.
8. On breaking the seals of the booklet check that it contains 28 pages and all 60 questions and corresponding answer
choices are legible. Read carefully the instructions printed at the beginning of each section.
B. Filling the Right Part of the ORS:
9. The ORS also has a CODES printed on its left and right parts.
10. Check that the same CODE is printed on the ORS and on this booklet. IF IT IS NOT THEN ASK FOR A CHANGE
OF THE BOOKLET. Sign at the place provided on the ORS affirming that you have verified that all the code are
same.
11. Write your Name, Registration Number and the name of examination centre and sign with pen in the boxes provided on
the right part of the ORS. Do not write any of this information anywhere else. Darken the appropriate bubble
UNDER each digit of your Registration Number in such a way that the impression is created on the bottom sheet. Also
darken the paper CODE given on the right side of ORS(R
4
).
C. Question paper format and Marking scheme:
The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of three sections.
12. Section I contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
13. Section II contains 5 multiple choice questions. Each question has four choice (A), (B), (C) and (D) out of which
ONE or MORE are correct.
14. Section III contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).

D. Marking Scheme
15. For each question in Section I, you will be awarded 3 marks if you darken the bubble corresponding to the correct
answer ONLY and zero marks if no bubbles are darkened. In all other cases, minus one (− −− −1) mark will be awarded in
this section.
16. For each question in Section II, you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the
correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No negative marks will be awarded for
incorrect answer in this section.
17. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding to the correct
answer ONLY. In all other cases zero (0) marks will be awarded. No negative marks will be awarded for incorrect
answer in this section.
8
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Write your Name, Registration Number and sign in the space provided on the back page of this booklet.
IITJEE-2011-Paper 1-CPM-2

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PAPER-1 [Code – 8]

IITJEE 2012



SECTION I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.


1. In the determination of Young’s modulus
2
4MLg
Y
d
| |
=
|
π
\ ¹
l
by using Searle’s method, a wire of length L = 2m
and diameter d = 0.5 mm is used. For a load M = 2.5 kg, an extension l = 0.25 mm in the length of the wire
is observed. Quantities d and l are measured using a screw gauge and a micrometer, respectively. They
have the same pitch of 0.5 mm. The number of divisions on their circular scale is 100. The contributions to
the maximum probable error of the Y measurement
(A) due to the errors in the measurements of d and l are the same.
(B) due to the error in the measurement of d is twice that due to the error in the measurement of l.
(C) due to the error in the measurement of l is twice that due to the error in the measurement of d.
(D) due to the error in the measurement of d is four times that due to the error in the measurement of l.

Sol. (A)

0.5
L.C. 0.005
100
= = mm

Y 2 (d)
Y d
∆ ∆ ∆
= +
l
l


3
3
0.005 10 1
50 0.25 10


∆ ×
= =
×
l
l


3
3
(d) 2 0.005 10 1
2
d 50 0.5 10


∆ × ×
= =
×


2. A small mass m is attached to a massless string whose other end is fixed at P as shown in the figure. The
mass is undergoing circular motion in the x-y plane with centre at O and constant angular speed ω. If the
angular momentum of the system, calculated about O and P are denoted by
O
L
r
and
P
L
r
respectively, then

z

P

O

m

ω



(A)
O
L
r
and
P
L
r
do not vary with time.
(B)
O
L
r
varies with time while
P
L
r
remains constant.
(C)
O
L
r
remains constant while
P
L
r
varies with time.
(D)
O
L
r
and
P
L
r
both vary with time.
Sol. (C)
PART - I: PHYSICS

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P
L
r

O

m

ω

O
L
r



3. A bi-convex lens is formed with two thin plano-convex lenses as shown in the figure. Refractive index n of
the first lens is 1.5 and that of the second lens is 1.2. Both the curved surface are of the same radius of
curvature R = 14 cm. For this bi-convex lens, for an object distance of 40 cm, the image distance will be


R = 14 cm

n = 1.2

n = 1.5



(A) −280.0 cm (B) 40.0 cm (C) 21.5 cm (D) 13.3 cm

Sol. (B)

T
1 1
P (1.5 1) 0 (1.2 1) 0
14 14
| | | |
= − − + − −
| |

\ ¹ \ ¹
=
0.5 0.2 1
14 14 20
+ =
f = +20 cm

1 1 1
v 40 20
− =



1 1 1 1
v 20 40 40
= − =
∴ v = 40 cm

4. A thin uniform rod, pivoted at O, is rotating in the horizontal plane with
constant angular speed ω, as shown in the figure. At time t = 0, a small
insect starts from O and moves with constant speed v, with respect to the
rod towards the other end. It reaches the end of the rod at t = T and stops.
The angular speed of the system remains ω throughout. The magnitude of
the torque (| τ
r
|) about O, as a function of time is best represented by which
plot?

ω
v →
O
z

(A)
O
T
t
| τ
r
|

(B)
O
T
t
| τ
r
|

(C)
O
T
t
| τ
r
|

(D)
O
T
t
| τ
r
|


Sol. (B)
τ = ω
2 2
dI d
(C mv t )
dt dt
= ω +
= mωv
2
2t.

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5. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas (atomic mass = 40
amu) is kept at 300 K in a container. The ratio of the rms speeds
rms
rms
v (helium)
v (argon )
| |
|
\ ¹
is
(A) 0.32 (B) 0.45 (C) 2.24 (D) 3.16

Sol. (D)
v
rms
=
3RT
M

Required ratio =
Ar
He
M 40
10
M 4
= =
= 3.16.

6. Two large vertical and parallel metal plates having a separation of 1 cm are connected to a DC voltage
source of potential difference X. A proton is released at rest midway between the two plates. It is found to
move at 45
0
to the vertical JUST after release. Then X is nearly
(A) 1 × 10
-5
V (B) 1 × 10
-7
V (C) 1 × 10
-9
V (D) 1 × 10
-10
V

Sol. (C)
qE = mg
q(V/d) = mg
V =
mgd
q

=
27 2
19
1.67 10 10 10
1.6 10
− −

× × ×
×

=
28
9
19
10
10 V
10



=

7. Three very large plates of same area are kept parallel and close to each other. They are considered as ideal
black surfaces and have very high thermal conductivity. The first and third plates are maintained at
temperatures 2T and 3T respectively. The temperature of the middle (i.e. second) plate under steady state
condition is
(A)
1/ 4
65
T
2
| |
|
\ ¹
(B)
1/ 4
97
4
| |
|
\ ¹
T (C)
1/ 4
97
2
| |
|
\ ¹
T (D)
1/ 4
(97) T

Sol. (C)
σA (2T)
4
+ σA (3T)
4
= σ 2A(T′)
4

16T
4
+ 81T
4
= 2 (T′)
4

97 T
4
= 2 (T′)
4

(T′)
4
=
97
2
T
4

∴ T′ =
1/ 4
97
T
2
| |
|
\ ¹


3T
2T


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8. A small block is connected to one end of a massless spring of un-stretched length 4.9 m. The other end of
the spring (see the figure) is fixed. The system lies on a horizontal frictionless surface. The block is
stretched by 0.2 m and released from rest at t = 0. It then executes simple harmonic motion with angular
frequency ω = π/3 rad/s. Simultaneously at t = 0, a small pebble is projected with speed v form point P at
an angle of 45
0
as shown in the figure. Point P is at a horizontal distance of 10 m from O. If the pebble hits
the block at t = 1 s, the value of v is (take g = 10 m/s
2
)


45
0
v

x

P

10 m

O

z


(A) 50 m/ s (B) 51 m/ s (C) 52 m/ s (D) 53 m/ s

Sol. (A)
0
2vsin 45
1
g
=
∴ v = 50 m/ s .

9. Young’s double slit experiment is carried out by using green, red and blue light, one color at a time. The
fringe widths recorded are β
G
, β
R
and β
B
, respectively. Then,
(A) β
G
> β
B
> β
R
(B) β
B
> β
G
> β
R
(C) β
R
> β
B
> β
G
(D) β
R
> β
G
> β
B


Sol. (D)
λ
R
> λ
G
> λ
B

∴ β
R
> β
G
> β
B

10. Consider a thin spherical shell of radius R with centre at the origin, carrying uniform positive surface
charge density. The variation of the magnitude of the electric field | E(r)
r
| and the electric potential V(r)
with the distance r from the centre, is best represented by which graph?
(A)
O

r

R

V(r)

|E(r)|



(B)
O

r

R

V(r)

|E(r)|



(C)
O

r

R

V(r)

|E(r)|



(D)
O

r

R

V(r)

|E(r)|




Sol. (D)

IITJEE-2011-Paper 1-CPM-6

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SECTION II : Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.

11. Consider the motion of a positive point charge in a region where there are simultaneous uniform electric
and magnetic fields
0
ˆ
E E j =
ur
and
0
ˆ
B B j. =
r
At time t = 0, this charge has velocity v
r
in the x-y plane,
making an angle θ with the x-axis. Which of the following option(s) is (are) correct for time t > 0?
(A) If 0 , θ = ° the charge moves in a circular path in the x-z plane.
(B) If 0 , θ = ° the charge undergoes helical motion with constant pitch along the y-axis.
(C) If 10 , θ = ° the charge undergoes helical motion with its pitch increasing with time, along the y-axis.
(D) If 90 , θ = ° the charge undergoes linear but accelerated motion along the y-axis.

Sol. (C, D)
If 90 , B θ = °
r
exerts no force on q.
If 0 ,10 ; θ = ° ° the charge particle moves in helix with increasing pitch due to E
r
along y-axis.

12. A cubical region of side a has its centre at the origin. It encloses three fixed point charges, −q at
(0, −a/4, 0), +3q at (0, 0, 0) and −q at (0, +a/4, 0). Choose the correct options(s)


a
y
x
z
–q
–q
3q

(A) The net electric flux crossing the plane x = +a/2 is equal to the net electric flux crossing the plane x =
−a/2
(B) The net electric flux crossing the plane y = +a/2 is more than the net electric flux crossing the plane y =
−a/2.
(C) The net electric flux crossing the entire region is
0
q
ε
.
(D) The net electric flux crossing the plane z = +a/2 is equal to the net electric flux crossing the plane x =
+a/2.

Sol. (A, C, D)
Net flux through the cubical region
0 0
q 3q q q − + −
= =
ε ε

The flux passing through the faces
a
x ,
2

=
a
x
2
= + and
a
z
2
= + are same due to symmetry.

13. A person blows into open-end of a long pipe. As a result, a high pressure pulse of air travels down the pipe.
When this pulse reaches the other end of the pipe,
(A) a high-pressure pulse starts travelling up the pipe, if the other end of the pipe is open.
(B) a low-pressure pulse starts travelling up the pipe, if the other end of the pipe is open.
(C) a low-pressure pulse starts travelling up the pipe, if the other end of the pipe is closed.
(D) a high-pressure pulse starts travelling up the pipe, if the other end of the pipe is closed.
Sol. (B, D)
At the open end, the phase of a pressure wave changes by π radian due to reflection. At the closed end,
there is no change in the phase of a pressure wave due to reflection.
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14. A small block of mass of 0.1 kg lies on a fixed inclined plane PQ which makes an angle θ with the
horizontal. A horizontal force of 1 N acts on the block through its centre of mass as shown in the figure.
The block remains stationary if (take g = 10 m/s
2
)


θ
1N
P
O
Q

(A) θ = 45°
(B) θ > 45° and a frictional force acts on the block towards P.
(C) θ > 45° and a frictional force acts on the block towards Q.
(D) θ < 45° and a frictional force acts on the block towards Q.

Sol. (A, C)
At 45 θ = ° , mg sin θ = 1 cos × θ
At 45 θ > ° , mg sin θ > 1 cos × θ(friction acts upward)
At 45 θ < ° , mg sin θ < 1 cos × θ(friction acts downward)

15. For the resistance network shown in the figure, choose the correct option(s)


Q
2Ω 2Ω
4Ω 4Ω
T
S P I
2
I
1
4Ω
2Ω
1Ω 1Ω
12V

(A) The current through PQ is zero. (B) I
1
= 3A
(C) The potential at S is less than that at Q. (D) I
2
= 2A

Sol. (A, B, C, D)
Nodes P and Q are equipotential and nodes S
and T are equipotential from wheatstone bridge,
no current passes through PQ and ST.

1
12
I 3A
4
= =

2 1
12
I I 2A
6 12
| |
= =
|
+
\ ¹

I
2
I
1
12 V
6Ω
12 Ω


IITJEE-2011-Paper 1-CPM-8

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SECTION III : Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both
inclusive).

16. A circular wire loop of radius R is placed in the x-y plane centered at the origin O. A square loop of side
a(a<<R) having two turns is placed with its centre at z = 3R along the axis of the circular wire loop, as
shown in figure. The plane of the square loop makes an angle of 45° with respect to the z-axis. If the mutual
inductance between the loops is given by
2
0
p/ 2
a
2 R
µ
, then the value of p is


45°
R
O
y
x
z
3R
a


Sol. (7)

2
2 0
3
IR
2 a cos 45
2(8R ) N
M
I I
( µ
°
(
φ
¸ ¸
= =
2 2
0 0
1/ 2 7/ 2
a a
8R2 R2
µ µ
=
So P = 7

17. An infinitely long solid cylinder of radius R has a uniform volume charge density ρ. It has a spherical
cavity of radius R/2 with its centre on the axis of the cylinder, as shown in the figure. The magnitude of the
electric field at the point P, which is at a distance 2R from the axis of the cylinder, is given by the
expression
0
23 R
16k
ρ
ε
. The value of k is


P
R
R/2
2R
y
x
z


Sol. (6)

( )
3
2
0
4 R
ˆ
K j
ˆ
3 8 ( j)
E
2 (2R) 4R
| |
ρ π −
|
λ
\ ¹
= +
πε
r


2
0
ˆ ˆ
R ( j) K R( j)
E
4 R 24
ρπ πρ −
= +
πε
r


K
ˆ ˆ
E K R( j) R( j)
24
= ρπ + ρπ −
r


P
y
x
z


0
23 23
ˆ ˆ
E K R ( j) R( j)
24 96
= ρπ = ρ
ε
r

⇒k = 6
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18. A proton is fired from very far away towards a nucleus with charge Q = 120 e, where e is the electronic
charge. It makes a closest approach of 10 fm to the nucleus. The de Broglie wavelength (in units of fm) of
the proton at its start is: (take the proton mass, m
p
= (5/3) × 10
-27
kg; h/e = 4.2 × 10
-15
J.s / C;
9
0
1
9 10
4
= ×
πε
m/F; 1 fm = 10
-15
)

Sol. (7)

2
15 15
1 K(Q)e K(120e)e
0 mv
2 10 10 10 10
− −
+ = =
× ×


9 19 2
27 2
15
1 5 9 10 120 (1.6 10 )
10 v
2 3 10 10



× × × ×
× × =
×


9 38
42
9 6 10 120 2.56 10
v
50 10


× × × × ×
=
×


13
v 331.776 10 = ×

h
mv
λ =

15 19
27 13
4.2 10 1.6 10
5
10 331.776 10
3
− −

× × ×
λ =
× × ×
34
21
4.2 4.8 10
57.6 5 10


× ×
=
× ×
13
0.07 10

= ×

15
7 10

λ = × = 7fm

19. A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform mass density and
radius 2R, as shown in the figure. The moment of inertia of this lamina about axes passing though O and P
is I
O
and I
P
respectively. Both these axes are perpendicular to the plane of the lamina. The ratio I
P
/ I
O
to
the nearest integer is


O
2R
P 2R


Sol. (3)

( )
2 2
2 2
p
4mR m R m
I m 4R 5R
2 4 2 4
( (
= + − +
( (
¸ ¸ ¸ ¸


2
p
1 5
I mR (2 4)
8 4
( | |
= + − +
| (
\ ¹ ¸ ¸


2 2
p
11 37
I mR 6 mR
8 8
| |
= − =
|
\ ¹
...(1)

2 2
2
0
4mR m R m
I R
2 4 2 4
| | | |
= − +
| |
\ ¹ \ ¹


2 2 2
0
1 1 3 13
I mR 2 mR 2 mR
8 4 8 8
( | | ( | |
= − + = − =
| | ( (
\ ¹ ¸ ¸ \ ¹ ¸ ¸
...(2)
So
p
0
I
37 / 8
3
I 13/ 8
= (Nearest Integer)

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20. A cylindrical cavity of diameter a exists inside a cylinder of diameter 2a as shown in the figure. Both the
cylinder and the cavity are infinity long. A uniform current density J flows along the length. If the
magnitude of the magnetic field at the point P is given by
0
N
aJ
12
µ , then the value of N is


O
a
2a
P



Sol. (5)

2 2
0 0
(J a ) (J a / 4)
B
3a 2 a
2
2
µ π µ π
= −
π | |
π
|
\ ¹


0 0
5 Ja NJa
B
12 12
µ µ
= =
So N = 5
IITJEE-2012-Paper 1-PCM-11
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PAPER-1 [Code – 8]

IITJEE 2012



SECTION – I: Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

21. A compound M
p
X
q
has cubic close packing (ccp) arrangement of X. Its unit cell structure is shown below.
The empirical formula of the compound is

(A) MX (B) MX
2

(C) M
2
X (D) M
5
X
14

Sol. (B)

1 1
X 8 6 4
8 2
= × + × =

1
M 4 1 2
4
= × + =
So, unit cell formula of the compound is M
2
X
4
and the empirical formula of the compound is MX
2
.

22. The carboxyl functional group (–COOH) is present in
(A) picric acid (B) barbituric acid
(C) ascorbic acid (D) aspirin

Sol. (D)

COOH
O C
O
CH
3
(Asprin)
OH
NO
2
O
2
N
NO
2
(Picric Acid)
NH N H
O
O O
(Barbituric Acid)
O
O
OH
O H
O H
O H
(Ascorbic Acid)


23. As per IUPAC nomenclature, the name of the complex [Co(H
2
O)
4
(NH
3
)
2
]Cl
3
is
(A) Tetraaquadiaminecobalt (III) chloride (B) Tetraaquadiamminecobalt (III) chloride
(C) Diaminetetraaquacobalt (III) chloride (D) Diamminetetraaquacobalt (III) chloride

Sol. (D)
[Co(H
2
O)
4
(NH
3
)
2
]Cl
3

Diamminetetraaquacobalt (III) chloride
PART - II: CHEMISTRY

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24. In allene (C
3
H
4
), the type(s) of hybridization of the carbon atoms is (are)
(A) sp and sp
3
(B) sp and sp
2

(C) only sp
2
(D) sp
2
and sp
3


Sol. (B)

2 2
sp sp sp
2 2
H C C CH = =

25. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a
0
is Bohr radius]
(A)
2
2 2
0
h
4 ma π
(B)
2
2 2
0
h
16 ma π

(C)
2
2 2
0
h
32 ma π
(D)
2
2 2
0
h
64 ma π


Sol. (C)
As per Bohr’s postulate,

nh
mvr
2
=
π

So,
nh
v
2 mr
=
π


2
1
KE mv
2
=
So,
2
1 nh
KE m
2 2 mr
| |
=
|
π
\ ¹

Since,
2
o
a n
r
z
×
=
So, for 2
nd
Bohr orbit

2
o
o
a 2
r 4a
1
×
= =

( )
2 2
2
2 2
0
1 2 h
KE m
2
4 m 4a
| |
| =
|
π ×
\ ¹


2
2 2
0
h
KE
32 ma
=
π


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26. Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen?
(A) HNO
3
, NO, NH
4
Cl, N
2
(B) HNO
3
, NO, N
2
, NH
4
Cl
(C) HNO
3
, NH
4
Cl, NO, N
2
(D) NO, HNO
3
, NH
4
Cl, N
2


Sol. (B)

5 2 0 3
3 2 4
HNO , NO, N , NH Cl
+ + −


27. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV vs. 1/V plot is shown below. The
value of the van der Waals constant a (atm.litre
2
mol
–2
) is

(A) 1.0 (B) 4.5
(C) 1.5 (D) 3.0

Sol. (C)

θ

van der Waals equation for 1 mole of real gas is,
( )
2
a
P V b RT
V
| |
+ − =
|
\ ¹

but, b = 0 (given)
( )
2
a
P V RT
V
| |
⇒ + =
|
\ ¹

∴ PV
1
a RT
V
= − × + …..(i)
y = mx + c
Slope = tan (π – θ) = –a
So, tanθ = a =
21.6 20.1
3 2


=1.5
or,
24.6 20.1
tan 1.5
3 0

θ = =



28. The number of aldol reaction(s) that occurs in the given transformation is
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3
conc.aq. NaOH
CH CHO 4HCHO + →
OH
OH
OH
O H

(A) 1 (B) 2
(C) 3 (D) 4

Sol. (C)

C H
3
C H
O
O H CH
2
C
CH
2
H
CH O
OH
( ) i OH

( ) ii
H C
O
H
(aldol)
C CH O
CH
2
CH
2
CH
2
O H
OH
OH
( )
conc. NaOH HCHO
crossed Cannizzaro reaction
+
← +
H C
O
O
2 2
HO CH CH CH O − − − =
( )
( )
( )
i OH
ii H CH O
Aldol

− =
→
( )
( )
( )
i OH
ii H CH O
Aldol

− =
→
OH
OH
OH
O H


29. The colour of light absorbed by an aqueous solution of CuSO
4
is
(A) orange- red (B) blue-green
(C) yellow (D) violet

Sol. (A)
Aqueous solution of copper sulphate absorbs orange red light and appears blue (complementary colour).

B
G
Y
O
R
V


30. The number of optically active products obtained from the complete ozonolysis of the given compound is

C H
3
CH CH C
CH
3
H
CH CH C
H
CH
3
CH CH CH
3

(A) 0 (B) 1
(C) 2 (D) 4

Sol. (A)
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C H
3
CH CH C
CH
3
H
CH CH C
H
CH
3
CH CH CH
3
3 2
O / Zn / H O
C H
3
CH O
(achiral)
+
O CH C
CH
3
H
CH O
(achiral)
+
O HC C
H
CH
3
CH O
(achiral)
+
C H
3
CH O
(achiral)


SECTION II : Multiple Correct Answer (s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.

31. Which of the following hydrogen halides react(s) with AgNO
3
(aq) to give a precipitate that dissolves in Na-
2
S
2
O
3
(aq)?
(A) HCl (B) HF
(C) HBr (D) HI

Sol. (A, C, D)
( )
3 3
HX AgNO AgX HNO X Cl, Br, I + → ↓ + =
( )
2 2 3 3 2 3
2
AgX 2Na S O Na Ag S O NaX ( + → +
¸ ¸


32. Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction, as
shown in the given scheme.

Binary mixture containing
Compound 1 and Compound 2
( ) NaOH aq
→
( )
3
NaHCO aq
→
Compound 1
Compound 1 +
+
Compound 2
Compound 2

(A) C
6
H
5
OH and C
6
H
5
COOH (B) C
6
H
5
COOH and C
6
H
5
CH
2
OH
(C) C
6
H
5
CH
2
OH and C
6
H
5
OH (D) C
6
H
5
CH
2
OH and C
6
H
5
CH
2
COOH

Sol. (B, D)
(A) Both are soluble in NaOH, hence inseparable.
(B) Only benzoic acid (C
6
H
5
COOH) is soluble in NaOH and NaHCO
3
, while benzyl alcohol (C
6
H
5
CH
2
OH)
is not. Hence, separable.
(C) Although NaOH can enable separation between benzyl alcohol (C
6
H
5
CH
2
OH) and phenol (C
6
H
5
OH) as
only the later is soluble in NaOH. However, in NaHCO
3
, both are insoluble. Hence, inseparable.
(D) α-phenyl acetic acid (C
6
H
5
CH
2
COOH) is soluble in NaOH and NaHCO
3
. While benzyl alcohol
(C
6
H
5
CH
2
OH) is not. Hence, separable.

33. For an ideal gas, consider only P-V

work in going from an initial state X to the final state Z. The final state
Z can be reached by either of the two paths shown in the figure. Which of the following choice(s) is(are)
correct? [Take ∆S as change in entropy and w as work done]
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P
(
a
t
m
o
s
p
h
e
r
e
)
V(liter)
Z
X
Y

(A)
x z x y y z
S S S
→ → →
∆ = ∆ + ∆ (B)
x z x y y z
w w w
→ → →
= +
(C)
x y z x y
w w
→ → →
= (D)
x y z x y
S S
→ → →
∆ = ∆

Sol. (A, C)
( )
X Z X Y Y Z
S S S entropy S is a state function, hence additive
→ → →
∆ = ∆ + ∆ (
¸ ¸



X Y Z X Y
w w
→ → →
= (work done in Y → Z is zero as it is an isochoric process)


34. Which of the following molecules, in pure form, is (are) unstable at room temperature?
(A)

(B)

(C) O

(D) O



Sol. (B, C)
Compound

and
O
being antiaromatic are unstable at room temperature.

35. Choose the correct reason(s) for the stability of the lyophobic colloidal particles.
(A) Preferential adsorption of ions on their surface from the solution
(B) Preferential adsorption of solvent on their surface from the solution
(C) Attraction between different particles having opposite charges on their surface
(D) Potential difference between the fixed layer and the diffused layer of opposite charges around the
colloidal particles

Sol. (A, D)
Lyophobic colloids are stable due to preferential adsorption of ions on their surface from solution and
potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal
particles that makes lyophobic sol stable.


SECTION III: Integer Answer Type
This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).

36. 29.2 % (w/w) HCl stock solution has density of 1.25 g mL
-1
. The molecular weight of HCl is 36.5 g mol
-1
.
The volume (mL) of stock solution required to prepare a 200 mL solution of 0.4 M HCl is

Sol. (8)
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Stock solution of HCl = 29.2% (w/w)
Molarity of stock solution of HCl
29.2 1000 1.25
36.5 100
× ×
=
×

If volume of stock solution required = V ml

29.2 1000
V 200 0.4
36.5 80
× × = ×
⇒ V = 8 ml

37. The substituents R
1
and R
2
for nine peptides are listed in the table given below. How many of these
peptides are positively charged at pH = 7.0?

H
3
N CH
H
CO NH CH CO NH CH CO NH CH
H
COO
R
2
R
1

Peptide R
1
R
2

I H H
II H CH
3

III CH
2
COOH H
IV CH
2
CONH
2
(CH
2
)
4
NH
2

V CH
2
CONH
2
` CH
2
CONH
2

VI (CH
2
)
4
NH
2
(CH
2
)
4
NH
2

VII CH
2
COOH CH
2
CONH
2

VIII CH
2
OH (CH
2
)
4
NH
2

IX (CH
2
)
4
NH
2
` CH
3


Sol. (4)
Peptides with isoelectric point (pI) > 7, would exist as cation in neutral solution (pH = 7).
IV, VI, VIII and IX

38. An organic compound undergoes first-order decomposition. The time taken for its decomposition to 1/8 and
1/10 of its initial concentration are t
1/8
and t
1/10
respectively. What is the value of
[ ]
[ ]
1/8
1/10
t
10?
t
× (take log
10
2 =
0.3)

Sol. (9)

1/8
2.303log8 2.303 3log2
t
k k
×
= =

1/10
2.303 2.303
t log10
k k
= =

1/8
1/10
2.303 3log 2
t k
10 10 9
2.303 t
k
× | |
|
(
\ ¹
× = × =
(
| |
¸ ¸
|
\ ¹


39. When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its
pyranose form is
CHO
CH
2
CHOH
CHOH
CHOH
CH
2
OH

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Sol. (8)

H H
CHO
H OH
H OH
H OH
H
2
C OH
1
2
3
4
5
6
O
CH
2
H
H
OH
H
H
H
OH
H
OH
OH
1
2 3
4
5
Fixed in D-configuration
6

Hence total number of stereoisomers in pyranose form of D-configuration = 2
3
= 8

40. The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons, undergoes a
nuclear reaction yielding element X as shown below. To which group, element X belongs in the periodic
table?

63 1 1 1
29 1 0 1
Cu H 6 n 2 H X + → + α + +

Sol. (8)

63 1 1 4 1 A
29 1 0 2 1 Z
Cu H 6 n He 2 H X + → + + +
Mass number: 63 + 1 = 1 × 6 + 4 + 1 × 2 + A
A = 64 – 12 = 52
Atomic number: 29 + 1 = 6 × 0 + 2 + 2 × 1 + Z
Z = 30–4 = 26

A 52
Z 26
X Fe =
Hence X is in group ‘8’ in the periodic table.

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PAPER-1 [Code – 8]

IITJEE 2012



SECTION I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

41. If
2
1
lim 4
1 →∞
| |
+ +
− − =
|
+ \ ¹ x
x x
ax b
x
, then
(A) a = 1, b = 4 (B) a = 1, b = –4
(C) a = 2, b = – 3 (D) a = 2, b = 3

Sol. (B)
Given
2
1
lim 4
1 →∞
| |
+ +
− − =
|
|
+
\ ¹
x
x x
ax b
x


( )
2 2
1
lim 4
1 →∞
+ + − − − −
=
+ x
x x ax ax bx b
x

( ) ( ) ( )
( )
2
1 1 1
lim 4
1 →∞
− + − − + −
=
+ x
a x a b x b
x

⇒ 1 − a = 0 and 1 − a − b = 4 ⇒ b = −4, a = 1.

42. Let P = [a
ij
] be a 3 × 3 matrix and let Q = [b
ij
], where b
ij
= 2
i + j
a
ij
for 1 ≤ i, j ≤ 3. If the determinant of P is 2,
then the determinant of the matrix Q is
(A) 2
10
(B) 2
11

(C) 2
12
(D) 2
13


Sol. (D)
2 3 4
11 12 13
3 4 5
21 22 23
4 5 6
31 32 33
2 2 2
2 2 2
2 2 2
=
a a a
Q a a a
a a a

11 12 13
2 3 4
21 22 23
2 2 2
31 32 33
2 2 2 2 2 2
2 2 2
= ⋅ ⋅
a a a
Q a a a
a a a


11 12 13
9 2
21 22 23
31 32 33
2 2 2 = ⋅ ⋅
a a a
Q a a a
a a a

⇒ |Q| = 2
12
|P|
|Q| = 2
13
.

43. The locus of the mid–point of the chord of contact of tangents drawn from points lying on the straight line
4x – 5y = 20 to the circle x
2
+ y
2
= 9 is
(A)
2 2
20( ) 36 45 0 + − + = x y x y (B)
2 2
20( ) 36 45 0 + + − = x y x y
(C)
2 2
36( ) 20 45 0 + − + = x y x y (D)
2 2
36( ) 20 45 0 + + − = x y x y

Sol. (A)
Equation of the chord bisected at P (h, k)
hx + ky = h
2
+ k
2
…(i)
Let any point on line be
4
, 4
5
| |
α α−
|
\ ¹

Equation of the chord of contact is
PART - III: MATHEMATICS
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4
4 9
5
| |
α + α − =
|
\ ¹
x y …(ii)
Comparing (i) and (ii)

2 2
4
9
4
5
+
= =
α
α−
h k h k

α =
20h
4h 5k −

Now,
( )
2 2
h 4h 5k
h k
20h 9

+
=
20 (h
2
+ k
2
) = 9 (4h − 5k)
20 (x
2
+ y
2
) − 36x + 45y = 0.

P(h, k)
x y
1
5 4
− =
x
y
x
2
+y
2
= 9
(α,
4
5
α−4)
O


44. The total number of ways in which 5 balls of different colours can be distributed among 3 persons so that
each person gets at least one ball is
(A) 75 (B) 150
(C) 210 (D) 243

Sol. (B)
Number of ways
= 3
5

3
C
1
.2
5
+
3
C
2
1
5

= 243 − 96 + 3 = 150.

45. The integral
2
9
2
sec
(sec tan ) +

x
dx
x x
equals (for some arbitrary constant K)
(A)
{ }
2
11
2
1 1 1
(sec tan )
11 7
(sec tan )
− − + +
+
x x K
x x
(B)
{ }
2
11
2
1 1 1
(sec tan )
11 7
(sec tan )
− + +
+
x x K
x x

(C)
{ }
2
11
2
1 1 1
(sec tan )
11 7
(sec tan )
− + + +
+
x x K
x x
(D)
{ }
2
11
2
1 1 1
(sec tan )
11 7
(sec tan )
+ + +
+
x x K
x x


Sol. (C)

2
9
2
sec
I
(sec tan )
=
+

x
dx
x x

Let sec x + tan x = t
⇒ sec x − tan x = 1/t
Now (sec x tan x + sec
2
x) dx = dt
sec x (sec x + tan x) dx = dt
sec x dx =
dt
t
,
1 1
2
| |
+
|
\ ¹
t
t
= sec x
I =
9
2
1
1
2
| |
+
|
\ ¹

t
dt
t
t
t

=
9 13
2 2
1
( )
2
− −
+

t t dt
=
9 13
1 1
2 2
1
9 13
2
1 1
2 2
− + − +
(
(
+
(
− + − +
(
¸ ¸
t t

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=
7 11
2 2
1
7 11
2
2 2
− −
(
(
+
(
− −
(
¸ ¸
t t

=
7 11
2 2
1 1
7 11
− −
− − t t
=
7 11
2 2
1 1 1 1
7 11
− −
t t

=
( )
( )
2
2
11 11/ 2
2
1 1 1 1 1
sec tan
11 7 11 7
sec tan
| |
¦ ¹
− + = − + + +
| ´ `
|
¹ ) +
\ ¹
t
x x k
x x
t


46. The point P is the intersection of the straight line joining the points Q(2, 3, 5) and R(1, –1, 4) with the plane
5x – 4y – z = 1. If S is the foot of the perpendicular drawn from the point T(2, 1, 4) to QR, then the length
of the line segment PS is
(A)
1
2
(B) 2
(C) 2 (D) 2 2

Sol. (A)
D. R. of QR is 1, 4, 1
Coordinate of P ≡
4 1 13
, ,
3 3 3
| |
|
\ ¹

D. R. of PT is 2, 2, –1
Angle between QR and PT is 45º
And PT = 1
⇒ PS = TS =
1
2


T(2, 1, 4)
Q(2, 3, 5)
P
4 1 13
, ,
3 3 3
| |
|
\ ¹

R(1, –1, 4)
θ
S


47. Let
2
cos , 0
( )
, ,
0, 0
¦ π

¦
¦
=
´

¦
¦
=
¹
x x
x
f x
x
x

then f is
(A) differentiable both at x = 0 and at x = 2
(B) differentiable at x = 0 but not differentiable at x = 2
(C) not differentiable at x = 0 but differentiable at x = 2
(D) differentiable neither at x = 0 nor at x = 2

Sol. (B)
( )
( ) ( )
0
0 0
0 lim

+ −
′ =
h
f h f
f
h

=
2
0
cos 0
lim

π

h
h
h
h

=
0
lim cos 0

π | |
=
|
\ ¹
h
h
h

so, f(x) is differentiable at x = 0

( )
( ) ( )
0
2 2
2 lim
+

+ −
′ =
h
f h f
f
h

=
( )
2
0
2 cos 0
2
lim

π
+ −
+
h
h
h
h

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=
( )
2
0
2 cos
2
lim

π | |
+
|
+
\ ¹
h
h
h
h


( )
2
0
(2 )
2 lim sin
2 2
+

+ π π | |
′ = −
|
+
\ ¹
h
h
f
h h

=
2
0
(2 )
lim sin
2(2 ) →
( + π⋅
(
+
¸ ¸
h
h h
h h

=
2
0
(2 )
lim sin
2(2 ) 2(2 )
2(2 )

+ π π
×
π
+ +
+
h
h h
h
h h
h
= π
Again,
( )
0
(2 ) (2)
2 lim


− −
′ =
− h
f h f
f
h

=
( )
2
0
2 cos
2
lim

π | |

|

\ ¹
− h
h
h
h

=
( )
2
0
2 cos
2
lim

π | |
− −
|

\ ¹
− h
h
h
h

=
2
0
(2 ) sin
2 2
lim

π π (
− −
(

¸ ¸
h
h
h
h

=
2
0
(2 )
lim sin
2(2 ) →
( − −π

(

¸ ¸
h
h h
h h

=
2
0
(2 )
lim sin
2(2 ) 2(2 )
2(2 )

− π π
− ⋅ × = −π
π
− −

h
h h
h
h h
h


48. Let z be a complex number such that the imaginary part of z is nonzero and a = z
2
+ z + 1 is real. Then a
cannot take the value
(A) –1 (B)
1
3

(C)
1
2
(D)
3
4


Sol. (D)
Given equation is z
2
+ z + 1 − a = 0
Clearly this equation do not have real roots if
D < 0
⇒ 1 − 4(1 − a) < 0
⇒ 4a < 3
a <
3
4
.

49. The ellipse
2 2
1
: 1
9 4
+ =
x y
E is inscribed in a rectangle R whose sides are parallel to the coordinate axes.
Another ellipse E
2
passing through the point (0, 4) circumscribes the rectangle R. The eccentricity of the
ellipse E
2
is
(A)
2
2
(B)
3
2

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(C)
1
2
(D)
3
4


Sol. (C)
Equation of ellipse is (y + 2) (y − 2) + λ(x + 3) (x − 3) = 0
It passes through (0, 4) ⇒ λ =
4
3

Equation of ellipse is
2 2
1
12 16
+ =
x y

e =
1
2
.
y
(0, 4)
x
y = 2
y = −2
(3, −2) (−3, −2)
(−3, 2)
x = −3
x = 3

Alternate
Let the ellipse be
2 2
2 2
x y
1
a b
+ = as it is passing through (0, 4) and (3, 2).
So, b
2
= 16 and
2
9 4
1
16
a
+ =
⇒ a
2
= 12
So, 12 = 16 (1 − e
2
)
⇒ e = 1/2.

50. The function f : [0, 3] → [1, 29], defined by f(x) = 2x
3
– 15x
2
+ 36x + 1, is
(A) one–one and onto (B) onto but not one–one
(C) one–one but not onto (D) neither one–one nor onto

Sol. (B)
f (x) = 2x
3
− 15x
2
+ 36x + 1
f′(x) = 6x
2
− 30x + 36
= 6 (x
2
− 5x + 6)
= 6 (x − 2) (x − 3)
f (x) is increasing in [0, 2] and decreasing in [2, 3]
f (x) is many one
f (0) = 1
f (2) = 29
f (3) = 28
Range is [1, 29]
Hence, f (x) is many-one-onto

SECTION II : Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.

51. Tangents are drawn to the hyperbola
2 2
1
9 4
− =
x y
, parallel to the straight line 2x − y = 1. The points of
contact of the tangents on the hyperbola are
(A)
9 1
,
2 2 2
| |
|
\ ¹
(B)
9 1
,
2 2 2
| |
− −
|
\ ¹

(C)
( )
3 3, 2 2 − (D)
( )
3 3, 2 2 −

Sol. (A, B)
Slope of tangent = 2
IITJEE-2011-Paper 1-CPM-24

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The tangents are y = 2x ± 9 4 4 × −
i.e., 2x − y = ± 4 2
⇒ 1
2 2 4 2
− =
x y
and 1
2 2 4 2
− + =
x y

Comparing it with
1 1
1
9 4
− =
xx yy

We get point of contact as
9 1
,
2 2 2
| |
|
\ ¹
and
9 1
,
2 2 2
| |
− −
|
\ ¹

Alternate:
Equation of tangent at P (θ) is
sec tan
x y 1
3 2
θ θ | | | |
− =
| |
\ ¹ \ ¹

⇒ Slope =
2sec
2
3tan
θ
=
θ


1
sin
3
θ =
⇒ points are
9 1
,
2 2 2
| |
|
\ ¹
and
9 1
,
2 2 2
| |
− −
|
\ ¹
.

52. Let θ, ϕ ∈ [0, 2π] be such that ( )
2
2cos 1 sin sin tan cot cos 1
2 2
θ θ | |
θ − ϕ = θ + ϕ−
|
\ ¹
, ( ) tan 2 0 π −θ > and
3
1 sin
2
− < θ < − . Then ϕ cannot satisfy
(A) 0
2
π
< ϕ < (B)
4
2 3
π π
< ϕ <
(C)
4 3
3 2
π π
< ϕ < (D)
3
2
2
π
< ϕ < π

Sol. (A, C, D)
2 cos θ (1 – sin ϕ) =
2
2sin
cos 1 2sin cos 1
sin
θ
ϕ− = θ ϕ−
θ

2 cos θ – 2 cos θ sin ϕ = 2 sin θ cos ϕ – 1
2 cos θ + 1 = 2 sin (θ + ϕ)
tan(2 ) 0 π−θ > ⇒ tan θ < 0 and
3
1 sin
2
− < θ < −

3 5
,
2 3
π π | |
θ∈
|
\ ¹


1
2
< sin (θ + ϕ) < 1

5
2 2
6 6
π π
π+ < θ+ ϕ < + π

max min
5
2 2
6 6
π π
π+ −θ < ϕ < π+ −θ

4
2 3
π π
< ϕ < .

53. If y(x) satisfies the differential equation y′ − ytanx = 2x secx and y(0) = 0, then
(A)
2
4 8 2
π π | |
=
|
\ ¹
y (B)
2
4 18
π π | |
′ =
|
\ ¹
y
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(C)
2
3 9
π π | |
=
|
\ ¹
y (D)
2
4 2
3 3 3 3
π π π | |
′ = +
|
\ ¹
y

Sol. (A, D)
tan 2 sec − =
dy
y x x x
dx

( ) cos sin 2 + − =
dy
x x y x
dx

( ) cos 2 =
d
y x x
dx

y (x) cos x = x
2
+ c, where c = 0 since y (0) = 0
when x =
4
π
,
2
y
4
8 2
π π | |
=
|
\ ¹
, when x =
2
2
, y
3 3 9
π π π | |
=
|
\ ¹

when x = , y
4 4
π π | |

|
\ ¹
=
2
8 2 2
π π
+
when x = , y
3 3
π π | |
′ =
|
\ ¹
2
2 4
3 3 3
π π
+

54. A ship is fitted with three engines E
1
, E
2
and E
3
. The engines function independently of each other with
respective probabilities
1 1
,
2 4
and
1
4
. For the ship to be operational at least two of its engines must
function. Let X denote the event that the ship is operational and let X
1
, X
2
and X
3
denote respectively the
events that the engines E
1
, E
2
and E
3
are functioning. Which of the following is(are) true ?
(A)
1
3
16
(
=
¸ ¸
c
P X X
(B) P [Exactly two engines of the ship are functioning | X] =
7
8

(C)
2
5
16
( =
¸ ¸
P X X (D)
1
7
16
( =
¸ ¸
P X X

Sol. (B, D)

1
1
( )
2
= P X ,
2
1
( )
4
= P X ,
3
1
( )
4
= P X
P(X) =
1 2 3 1 2 3 1 2 3 1 2 3
( ) ( ) ( ) ( ) ∩ ∩ + ∩ ∩ + ∩ ∩ + ∩ ∩
C C C
P X X X P X X X P X X X P X X X =
1
4

(A)
1
( / )
C
P X X =
1
( )
( )

C
P X X
P X
=
1
1
32
1
8
4
=
(B) P [exactly two engines of the ship are functioning | X] =
7
7
32
1
8
4
=
(C)
2
| |
|
\ ¹
X
P
X
=
5
5
32
1
8
4
=
(D)
1
| |
|
\ ¹
X
P
X
=
7
7
32
1
16
2
=

IITJEE-2011-Paper 1-CPM-26

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55. Let S be the area of the region enclosed by y =
2
−x
e , y = 0, x = 0 and x = 1. Then
(A) S ≥
1
e
(B) S ≥ 1 −
1
e

(C) S ≤
1 1
1
4
| |
+
|
\ ¹ e
(D) S ≤
1 1 1
1
2 2
| |
+ −
|
\ ¹ e


Sol. (A, B, D)
S >
1
e
(As area of rectangle OCDS = 1/e)
Since
2
x x
e e
− −
≥ ∀ x ∈ [0, 1]

1
0
1
1

| |
> = −
|
\ ¹

x
S e dx
e

Area of rectangle OAPQ + Area of rectangle QBRS > S
( )
1 1 1
1 1
2 2
| | | |
< + −
| |
\ ¹\ ¹
S
e
.
Since
1 1
1
4
| |
+
|
\ ¹ e
< 1 −
1
e

Hence, (C) is incorrect.

A(0, 1)
P
R
S Q O
2
x
y e

=
1 1
B ,
2 e
| |
|
\ ¹

1
1,
e
| |
|
\ ¹

D C


SECTION III : Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both
inclusive).

56. If ,
r
r
a b and
r
c are unit vectors satisfying
2 2
2
9 − + − + − =
r r
r r r r
a b b c c a , then 2 5 5 + +
r
r r
a b c is

Sol. (3)
As,
2 2 2 2
2 2 2
3
| |
− + − + − = + + − + +
|
\ ¹
r r r r
r r r r r r r r
a b b c c a a b c a b c
⇒ 3 × 3 −
2
+ +
r
r r
a b c = 9
⇒ 0 + + =
r
r r
a b c ⇒ 0 + + =
r
r r
a b c
⇒ + = −
r
r r
b c a

( )
2 5 3 3 3 + + = − = =
r
r r r r
a b c a a .

57. Let f : IR → IR be defined as f(x) =
2
1 + − x x . The total number of points at which f attains either a local
maximum or a local minimum is

Sol. (5)
( )
2
2
1
(2 )
1

′ = + ⋅

x
x
f x x
x x

=
2 1 , 1
(2 1) , 1 0
1 2 , 0 1
2 1 , 1
− < − ¦
¦
− + − < <
¦
´
− < <
¦
¦
+ >
¹
x x
x x
x x
x x

−ve +ve −ve +ve −ve +ve
−1 0 1 1/2 −1/2

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So, f′(x) changes sign at points
x = −1,
1 1
, 0, , 1
2 2

so, total number of points of local maximum or minimum is 5.

58. Let S be the focus of the parabola y
2
= 8x and let PQ be the common chord of the circle x
2
+ y
2
− 2x − 4y =
0 and the given parabola. The area of the triangle PQS is

Sol. (4)
The parabola is x = 2t
2
, y = 4t
Solving it with the circle we get :
4t
4
+ 16t
2
− 4t
2
− 16t = 0
⇒ t
4
+ 3t
2
− 4t = 0 ⇒ t = 0, 1
so, the points P and Q are (0, 0) and (2, 4) which are also diametrically opposite points on the circle. The
focus is S ≡ (2, 0).
The area of ∆PQS =
1
2 4 4
2
× × = .

59. Let p(x) be a real polynomial of least degree which has a local maximum at x = 1 and a local minimum at x
= 3. If p(1) = 6 and p(3) = 2, then p′(0) is

Sol. (9)
Let p′(x) = k(x − 1) (x − 3)
⇒ p(x) =
3
2
2 3
3
| |
− + +
|
|
\ ¹
x
k x x c
Now, p(1) = 6 ⇒
4
3
k + c = 6
also, p(3) = 2 ⇒ c = 2
so, k = 3, so, p′(0) = 3k = 9.

60. The value of
3/ 2
1 1 1 1
6 log 4 4 4
3 2 3 2 3 2 3 2
| |
|
+ − − − ⋅ ⋅ ⋅
|
\ ¹
is

Sol. (4)
Let
1 1 1
4 4 4
3 2 3 2 3 2
− − − ⋅ ⋅⋅ = y
So,
2
1
4
3 2
− = y y (y > 0)

2
1
4 0
3 2
+ − = y y ⇒
8
3 2
= y
so, the required value is
3/ 2
1 8
6 log
3 2 3 2
| |
+ ×
|
\ ¹

=
3/ 2
4
6 log
9
+ = 6 − 2 = 4.

IITJEE-2011-Paper 1-CPM-2

PAPER-1 [Code – 8] IITJEE 2012 PART - I: PHYSICS
SECTION I : Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

1.

4MLg   In the determination of Young’s modulus  Y =  by using Searle’s method, a wire of length L = 2m πld 2   and diameter d = 0.5 mm is used. For a load M = 2.5 kg, an extension l = 0.25 mm in the length of the wire is observed. Quantities d and l are measured using a screw gauge and a micrometer, respectively. They have the same pitch of 0.5 mm. The number of divisions on their circular scale is 100. The contributions to the maximum probable error of the Y measurement (A) due to the errors in the measurements of d and l are the same. (B) due to the error in the measurement of d is twice that due to the error in the measurement of l. (C) due to the error in the measurement of l is twice that due to the error in the measurement of d. (D) due to the error in the measurement of d is four times that due to the error in the measurement of l.
(A)

Sol.

0.5 = 0.005 mm 100 ∆Y ∆l 2∆ (d) = + Y l d ∆l 0.005 × 10−3 1 = = l 0.25 × 10−3 50 ∆(d) 2 × 0.005 × 10−3 1 2 = = d 0.5 × 10−3 50 L.C. =
2. A small mass m is attached to a massless string whose other end is fixed at P as shown in the figure. The mass is undergoing circular motion in the x-y plane with centre at O and constant angular speed ω. If the r r angular momentum of the system, calculated about O and P are denoted by L O and L P respectively, then z
P O m

Sol.

ω r r (A) L O and L P do not vary with time. r r (B) L O varies with time while L P remains constant. r r (C) L O remains constant while L P varies with time. r r (D) L O and L P both vary with time. (C)

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26569493.3 cm Sol.IITJEE-2012-Paper 1-PCM-3 r LO O r LP m ω 3. Fax 26513942 website: www.5 0. At time t = 0. For this bi-convex lens. Ph 46106000. New Delhi -110016. A bi-convex lens is formed with two thin plano-convex lenses as shown in the figure. as a function of time is best represented by which plot? (A) |τ| z ω v→ O (B) r |τ| r O T t O T t (C) |τ| (D) r |τ| r O T t O T t Sol.5 and that of the second lens is 1. is rotating in the horizontal plane with constant angular speed ω.fiitjee.5 n = 1.5 − 1)  − 0  + (1. Both the curved surface are of the same radius of curvature R = 14 cm. Sarvapriya Vihar. for an object distance of 40 cm. Kalu Sarai. as shown in the figure.5 cm (D) 13.0 cm (C) 21. Refractive index n of the first lens is 1.2 R = 14 cm (A) −280. The magnitude of r the torque (| τ |) about O. The angular speed of the system remains ω throughout.2. a small insect starts from O and moves with constant speed v. A thin uniform rod.2 − 1)  0 − + =  = −14  14 14 20  14   f = +20 cm 1 1 1 − = v −40 20 1 1 1 1 = − = v 20 40 40 ∴ v = 40 cm 4. pivoted at O. (B) τ=ω dI d = ω (C + mv 2 t 2 ) dt dt = mωv2 2t. FIITJEE House. with respect to the rod towards the other end.. . (B) 1  0. FIITJEE Ltd.2 1 1   PT = (1.0 cm (B) 40. the image distance will be n = 1. 29-A.com. It reaches the end of the rod at t = T and stops.

6.67 × 10−27 × 10 ×10−2 1. Two large vertical and parallel metal plates having a separation of 1 cm are connected to a DC voltage source of potential difference X.16.45 (C) 2.32 (B) 0. 26569493. 1/ 4 T  97  (B)    4  1/ 4 T  97  (C)    2  2T 1/ 4 T 3T (D) (97)1/ 4 T (C) σA (2T)4 + σA (3T)4 = σ 2A(T′)4 16T4 + 81T4 = 2 (T′)4 97 T4 = 2 (T′)4 97 4 (T′)4 = T 2 1/ 4  97  ∴ T′ =   T  2  FIITJEE Ltd.fiitjee. The ratio of the rms speeds  rms  is  v rms (argon )  (A) 0. A proton is released at rest midway between the two plates. 3RT M M Ar = M He 40 = 10 4 Required ratio = = 3.6 × 10−19 −28 10 = −19 = 10−9 V 10 7. Three very large plates of same area are kept parallel and close to each other. Kalu Sarai. It is found to move at 450 to the vertical JUST after release. Ph 46106000. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas (atomic mass = 40  v (helium)  amu) is kept at 300 K in a container.24 (D) 3. FIITJEE House.e. They are considered as ideal black surfaces and have very high thermal conductivity. New Delhi -110016.com. 29-A. The temperature of the middle (i. The first and third plates are maintained at temperatures 2T and 3T respectively. ..IITJEE-2011-Paper 1-CPM-4 5.16 (D) vrms = Sol. 1. Fax 26513942 website: www. Then X is nearly (B) 1 × 10-7 V (C) 1 × 10-9 V (D) 1 × 10-10 V (A) 1 × 10-5 V (C) qE = mg q(V/d) = mg mgd V= q = Sol. Sarvapriya Vihar. second) plate under steady state condition is  65  (A)    2  Sol.

Simultaneously at t = 0. The variation of the magnitude of the electric field | E(r) | and the electric potential V(r) with the distance r from the centre. O R r V(r) O R r V(r) (C) → |E(r)| (D) → |E(r)| O R r O R r Sol. (A) βG > βB > βR (B) βB > βG > βR (C) βR > βB > βG (D) βR > βG > βB (D) λR > λG > λB ∴ β R > βG > βB Consider a thin spherical shell of radius R with centre at the origin.fiitjee. (D) FIITJEE Ltd. The block is stretched by 0.9 m. 10. carrying uniform positive surface r charge density. It then executes simple harmonic motion with angular frequency ω = π/3 rad/s. If the pebble hits the block at t = 1 s. Young’s double slit experiment is carried out by using green. Then. Point P is at a horizontal distance of 10 m from O.. 29-A. The other end of the spring (see the figure) is fixed. The system lies on a horizontal frictionless surface.2 m and released from rest at t = 0. The fringe widths recorded are βG. Fax 26513942 website: www. red and blue light. a small pebble is projected with speed v form point P at an angle of 450 as shown in the figure. 26569493. New Delhi -110016. Sarvapriya Vihar.com. Kalu Sarai. . 9.IITJEE-2012-Paper 1-PCM-5 8. one color at a time. FIITJEE House. βR and βB. Ph 46106000. A small block is connected to one end of a massless spring of un-stretched length 4. respectively. is best represented by which graph? → (A) → (B) |E(r)| V(r) |E(r)| V(r) Sol. the value of v is (take g = 10 m/s2) z v 450 O 10 m P x (A) Sol. 50 m / s (B) 51 m / s (C) 52 m / s (D) 53 m / s (A) 2v sin 450 =1 g ∴v= 50 m / s .

along the y-axis. C. r If θ = 0°. It encloses three fixed point charges. if the other end of the pipe is closed. if the other end of the pipe is closed. +a/4. Choose the correct options(s) z a –q –q y 3q x (A) The net electric flux crossing the plane x = +a/2 is equal to the net electric flux crossing the plane x = −a/2 (B) The net electric flux crossing the plane y = +a/2 is more than the net electric flux crossing the plane y = −a/2. x = + and z = + are same due to symmetry. Sarvapriya Vihar. FIITJEE House. (C) If θ = 10°. Sol. (B) a low-pressure pulse starts travelling up the pipe. this charge has velocity v in the x-y plane.IITJEE-2011-Paper 1-CPM-6 SECTION II : Multiple Correct Answer(s) Type This section contains 5 multiple choice questions. 2 2 2 The flux passing through the faces x = 13. 12. 0) and −q at (0. 29-A. the charge undergoes helical motion with constant pitch along the y-axis. Consider the motion of a positive point charge in a region where there are simultaneous uniform electric u r r r j j.com. (C) a low-pressure pulse starts travelling up the pipe. (A) a high-pressure pulse starts travelling up the pipe. (B). Fax 26513942 website: www. (D) If θ = 90°. the charge particle moves in helix with increasing pitch due to E along y-axis.fiitjee. if the other end of the pipe is open. A cubical region of side a has its centre at the origin. Sol. the phase of a pressure wave changes by π radian due to reflection. ε0 (D) The net electric flux crossing the plane z = +a/2 is equal to the net electric flux crossing the plane x = +a/2. and magnetic fields E = E 0 ˆ and B = B0 ˆ At time t = 0. A person blows into open-end of a long pipe. Kalu Sarai. a high pressure pulse of air travels down the pipe. (D) a high-pressure pulse starts travelling up the pipe. 0. the charge undergoes helical motion with its pitch increasing with time. Each question has four choices (A). D) r If θ = 90°. D) At the open end. 0). FIITJEE Ltd. (C. B exerts no force on q.. New Delhi -110016. Which of the following option(s) is (are) correct for time t > 0? (A) If θ = 0°. if the other end of the pipe is open. there is no change in the phase of a pressure wave due to reflection. 11. making an angle θ with the x-axis. Sol. 0).10°. +3q at (0. the charge moves in a circular path in the x-z plane. 26569493. (A. As a result. Ph 46106000. (C) and (D) out of which ONE or MORE are correct. . q (C) The net electric flux crossing the entire region is . −q at (0. the charge undergoes linear but accelerated motion along the y-axis. D) Net flux through the cubical region = −q + 3q − q q = ε0 ε0 −a a a . When this pulse reaches the other end of the pipe. At the closed end. (B. (B) If θ = 0°. −a/4.

Sarvapriya Vihar. A horizontal force of 1 N acts on the block through its centre of mass as shown in the figure. A small block of mass of 0.com. choose the correct option(s) P I2 2Ω 2Ω 1Ω 4Ω Q I1 4Ω 12V T 1Ω 4Ω S 2Ω 15.fiitjee. mg sin θ > 1× cos θ (friction acts upward) At θ < 45° . mg sin θ < 1× cos θ (friction acts downward) For the resistance network shown in the figure. D) Nodes P and Q are equipotential and nodes S and T are equipotential from wheatstone bridge. (D) θ < 45° and a frictional force acts on the block towards Q. C. no current passes through PQ and ST. . 12 I1 = = 3A 4  12  I 2 = I1   = 2A  6 + 12  (B) I1 = 3A (D) I2 = 2A 6Ω I2 I1 12 Ω 12 V FIITJEE Ltd. Sol. Fax 26513942 website: www. (A) The current through PQ is zero.1 kg lies on a fixed inclined plane PQ which makes an angle θ with the horizontal. (C) The potential at S is less than that at Q. (A. Ph 46106000. New Delhi -110016. B. 26569493. FIITJEE House.. C) At θ = 45° .IITJEE-2012-Paper 1-PCM-7 14. (C) θ > 45° and a frictional force acts on the block towards Q. The block remains stationary if (take g = 10 m/s2) Q 1N θ O P (A) θ = 45° (B) θ > 45° and a frictional force acts on the block towards P. Kalu Sarai. (A. mg sin θ = 1× cos θ At θ > 45° . Sol. 29-A.

as shown in figure. which is at a distance 2R from the axis of the cylinder.fiitjee.. (7)  µ IR 2  2  0 3  a 2 cos 45° 2(8R )  µ0 a 2 µ a2 Nφ M= =  = 0 7/ 2 1/ 2 I I 8R2 R2 So P = 7 17. Ph 46106000. The value of k is 16kε0 z R R/2 2R x P y Sol. is given by the 23ρR expression . FIITJEE House. The magnitude of the electric field at the point P. It has a spherical cavity of radius R/2 with its centre on the axis of the cylinder. Fax 26513942 website: www. A square loop of side a(a<<R) having two turns is placed with its centre at z = 3R along the axis of the circular wire loop. . If the mutual µ0a 2 inductance between the loops is given by p/ 2 .IITJEE-2011-Paper 1-CPM-8 SECTION III : Integer Answer Type This section contains 5 questions. (6) z 3 r E=  4 R  ˆ Kρ π  −j ˆ 3 8  λ( j) +  2πε0 (2R) 4R 2 r ρπR 2 (ˆ KπρR(−ˆ j) j) E= + 4πε 0 R 24 r K E = KρπR(ˆ + ρπR(−ˆ j) j) 24 ( ) P y x r 23 23 ρR(ˆ E = KρπR (ˆ = j) j) 24 96ε 0 ⇒k=6 FIITJEE Ltd. New Delhi -110016. ranging from 0 to 9 (both inclusive). Kalu Sarai. Sarvapriya Vihar. The plane of the square loop makes an angle of 45° with respect to the z-axis. The answer to each question is single digit integer. 16. 26569493. A circular wire loop of radius R is placed in the x-y plane centered at the origin O. 29-A.com. as shown in the figure. An infinitely long solid cylinder of radius R has a uniform volume charge density ρ. then the value of p is 2 R z 45° a 3R R O x y Sol.

The ratio IP / IO to the nearest integer is 2R O 2R P Sol.s / C. Ph 46106000.com. (3)  4mR 2   m R2 m 2  Ip =  + m ( 4R 2 )  −  + 5R  4  2  4 2    1 5  I p = mR 2 (2 + 4) −  +    8 4    11  37 I p = mR 2  6 −  = mR 2 8 8  .. 1 fm = 10-15 ) 4πε0 (7) Sol. 1 K(Q)e K(120e)e 0 + mv 2 = = −15 2 10 × 10 10 ×10−15 9 1 5 9 × 10 × 120 × (1.8 × 10−34 λ= = = 0. A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform mass density and radius 2R.6 × 10−19 4. New Delhi -110016..07 × 10 −13 5 57.776 × 1013 h λ= mv 4.2 × 4.IITJEE-2012-Paper 1-PCM-9 18. A proton is fired from very far away towards a nucleus with charge Q = 120 e.. Kalu Sarai.. 1 = 9 × 109 m/F.(2)  8 8   8 4  I p 37 / 8 So = 3 (Nearest Integer) I0 13 / 8 FIITJEE Ltd. .. as shown in the figure.2 × 10-15 J. The de Broglie wavelength (in units of fm) of the proton at its start is: (take the proton mass.56 ×10−38 v= 50 × 10−42 v = 331. Sarvapriya Vihar. The moment of inertia of this lamina about axes passing though O and P is IO and IP respectively. Fax 26513942 website: www. Both these axes are perpendicular to the plane of the lamina. FIITJEE House.6 × 10−19 )2 × × 10−27 v 2 = 2 3 10 × 10−15 9 9 × 6 ×10 × 120 × 2.6 × 5 × 10−21 −27 13 × 10 × 331.(1)  4mR 2 I0 =   2   m R2 m 2  + R  − 4  4 2    1 1   3  13  I0 = mR 2  2 −  +   = mR 2  2 −  = mR 2   . It makes a closest approach of 10 fm to the nucleus.fiitjee.776 ×10 3 λ = 7 × 10 −15 = 7fm 19. h/e = 4. mp = (5/3) × 10-27 kg. where e is the electronic charge. 26569493. 29-A.2 × 10−15 × 1.

Fax 26513942 website: www. .IITJEE-2011-Paper 1-CPM-10 20. Sarvapriya Vihar. 26569493.fiitjee. A uniform current density J flows along the length. 29-A. (5) µ0 (Jπa 2 ) µ 0 (Jπa 2 / 4) − 2πa  3a  2π    2 5µ Ja µ NJa B= 0 = 0 12 12 So N = 5 B= FIITJEE Ltd. New Delhi -110016. FIITJEE House. Kalu Sarai. Both the cylinder and the cavity are infinity long. Ph 46106000.. then the value of N is 12 P O a 2a Sol. A cylindrical cavity of diameter a exists inside a cylinder of diameter 2a as shown in the figure. If the N magnitude of the magnetic field at the point P is given by µ 0 aJ .com.

the name of the complex [Co(H2O)4(NH3)2]Cl3 is (A) Tetraaquadiaminecobalt (III) chloride (B) Tetraaquadiamminecobalt (III) chloride (C) Diaminetetraaquacobalt (III) chloride (D) Diamminetetraaquacobalt (III) chloride Sol. Its unit cell structure is shown below.fiitjee. unit cell formula of the compound is M2X4 and the empirical formula of the compound is MX2. Ph 46106000. (D) OH O2N NO2 HN O NO2 (Picric Acid) (Barbituric Acid) O NH O HO HO COOH O HO OH (Asprin) O O O C CH3 (Ascorbic Acid) 23. . 26569493. (B) (B) MX2 (D) M5X14 1 1 X = 8× + 6× = 4 8 2 1 M = 4× +1 = 2 4 So.II: CHEMISTRY SECTION – I: Single Correct Answer Type This section contains 10 multiple choice questions.IITJEE-2012-Paper 1-PCM-11 PAPER-1 [Code – 8] IITJEE 2012 PART . New Delhi -110016.. (D) [Co(H2O)4(NH3)2]Cl3 Diamminetetraaquacobalt (III) chloride FIITJEE Ltd. FIITJEE House.com. As per IUPAC nomenclature. (B). The empirical formula of the compound is (A) MX (C) M2X Sol. Each question has four choices (A). 21. The carboxyl functional group (–COOH) is present in (A) picric acid (B) barbituric acid (C) ascorbic acid (D) aspirin Sol. Sarvapriya Vihar. Fax 26513942 website: www. (C) and (D) out of which ONLY ONE is correct. A compound MpXq has cubic close packing (ccp) arrangement of X. Kalu Sarai. 29-A. 22.

The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a0 is Bohr radius] h2 h2 (A) (B) 2 2 2 4π ma 0 16π 2 ma 0 (C) h2 2 32π 2 ma 0 (D) h2 2 64π 2 ma 0 sp 2 sp sp 2 Sol.. KE = m   2  2πmr  Since. (C) As per Bohr’s postulate.fiitjee. H 2 C = C = CH 2 25. . Ph 46106000. for 2nd Bohr orbit a × 22 r= o = 4a o 1 1  22 h 2 KE = m  2 2 2  4π m × ( 4a 0 )2  h2 KE = 2 32π2 ma 0     FIITJEE Ltd. Kalu Sarai. v = 2πmr 1 KE = mv 2 2 2 1  nh  So. the type(s) of hybridization of the carbon atoms is (are) (A) sp and sp3 (B) sp and sp2 2 (C) only sp (D) sp2 and sp3 (B) Sol. Fax 26513942 website: www.com.IITJEE-2011-Paper 1-CPM-12 24. FIITJEE House. New Delhi -110016. In allene (C3H4). 26569493. r = ao × n2 z So. 29-A. nh mvr = 2π nh So. Sarvapriya Vihar.

0 θ van der Waals equation for 1 mole of real gas is. H N O3 . NO. NH4Cl. Sarvapriya Vihar. NO. ….fiitjee. N2 (B) +5 +2 0 −3 Sol. Ph 46106000.com.IITJEE-2012-Paper 1-PCM-13 26. 1/V plot is shown below. b = 0 (given) a   ⇒  P + 2  ( V ) = RT V   1 ∴ PV = − a × + RT V y = mx + c Slope = tan (π – θ) = –a 21. 29-A.6 − 20.6 − 20. NO. N O. NH4Cl. FIITJEE House. N 2 . HNO3. NH4Cl (C) HNO3. N2. N2 (D) NO.5 Sol.1 or. N H 4 Cl 27. New Delhi -110016. For one mole of a van der Waals gas when b = 0 and T = 300 K.5 (D) 3. 26569493.(i) The number of aldol reaction(s) that occurs in the given transformation is FIITJEE Ltd. . Fax 26513942 website: www. Kalu Sarai. tan θ = = 1. tanθ = a = =1. The value of the van der Waals constant a (atm. the PV vs.1 So. (C) (B) 4. a    P + 2  ( V − b ) = RT V   but.5 3−0 28.0 (C) 1. N2 (B) HNO3. Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen? (A) HNO3.5 3− 2 24. NH4Cl.litre2mol–2) is (A) 1...

New Delhi -110016.NaOH + HCHO ← HO CH2 C ( crossed Cannizzaro reaction ) + HO OH CH O CH2 OH 29. Sarvapriya Vihar. NaOH OH HO (A) 1 (C) 3 Sol. The number of optically active products obtained from the complete ozonolysis of the given compound is CH3 H H3C (A) 0 (C) 2 Sol. 29-A. (A) CH CH C H CH CH C CH3 CH CH CH3 (B) 1 (D) 4 FIITJEE Ltd. . Fax 26513942 website: www. Ph 46106000. FIITJEE House.red (B) blue-green (C) yellow (D) violet (A) Aqueous solution of copper sulphate absorbs orange red light and appears blue (complementary colour). Sol. Kalu Sarai. V R B O G Y 30.fiitjee. The colour of light absorbed by an aqueous solution of CuSO4 is (A) orange..aq.com.IITJEE-2011-Paper 1-CPM-14 OH CH3 CHO + 4HCHO  → conc. (C) OH (B) 2 (D) 4 OH O H3C C ( i ) OH− H  ( ii ) H − CH = O → ( Aldol) CH2 HO − CH 2 − CH 2 − CH = O ( i ) OH −  HO ( ii ) H − CH = O → ( Aldol) CH2 C H ( i ) OH − CH O O ( ii ) H C H (aldol) OH O H C O OH OH CH2 conc. 26569493.

While benzyl alcohol (C6H5CH2OH) is not. 31. The final state Z can be reached by either of the two paths shown in the figure. FIITJEE Ltd. 26569493. (C) and (D) out of which ONE or MORE are correct. Sarvapriya Vihar. while benzyl alcohol (C6H5CH2OH) is not. ( )  → NaOH aq Compound 1 + Compound 2 Binary mixture containing Compound 1 and Compound 2 3( )  Compound 1 → NaHCO aq + Compound 2 (A) C6H5OH and C6H5COOH (C) C6H5CH2OH and C6H5OH (B) C6H5COOH and C6H5CH2OH (D) C6H5CH2OH and C6H5CH2COOH Sol. Hence. FIITJEE House. both are insoluble. inseparable. Which of the following choice(s) is(are) correct? [Take ∆S as change in entropy and w as work done] 33. (B) HF (D) HI Identify the binary mixture(s) that can be separated into individual compounds. Br. I ) AgX + 2Na 2S2 O 3 → Na 3  Ag ( S2 O 3 ) 2  + NaX   32. separable.fiitjee. Kalu Sarai. (C) Although NaOH can enable separation between benzyl alcohol (C6H5CH2OH) and phenol (C6H5OH) as only the later is soluble in NaOH. New Delhi -110016. Hence. D) (A) Both are soluble in NaOH. (B. For an ideal gas.IITJEE-2012-Paper 1-PCM-15 CH3 H3C CH CH C H H CH CH C CH3 O3 / Zn / H 2 O CH CH CH3 CH3 H3C CH O (achiral) H CH O + O CH C + O HC C CH O + H (achiral) CH3 (achiral) H3C CH O (achiral) SECTION II : Multiple Correct Answer (s) Type This section contains 5 multiple choice questions. Fax 26513942 website: www. (A. D) HX + AgNO3 → AgX ↓ + HNO3 ( X = Cl. hence inseparable. C. separable. Hence.com. by differential extraction. consider only P-V work in going from an initial state X to the final state Z. However. Ph 46106000.. Which of the following hydrogen halides react(s) with AgNO3(aq) to give a precipitate that dissolves in Na2S2O3(aq)? (A) HCl (C) HBr Sol. . (B) Only benzoic acid (C6H5COOH) is soluble in NaOH and NaHCO3. Each question has four choices (A). in NaHCO3. (D) α-phenyl acetic acid (C6H5CH2COOH) is soluble in NaOH and NaHCO3. 29-A. as shown in the given scheme. (B).

2 % (w/w) HCl stock solution has density of 1.25 g mL-1. C) ∆SX → Z = ∆SX → Y + ∆SY → Z  entropy ( S) is a state function. is (are) unstable at room temperature? (A) (B) (C) O (D) O Sol. hence additive    w X →Y → Z = w X →Y (work done in Y → Z is zero as it is an isochoric process) 34. (B) w x → z = w x → y + w y → z (D) ∆Sx → y → z = ∆Sx → y (A.5 g mol-1. Kalu Sarai. 26569493. (B. . The answer to each question is a single digit integer. The volume (mL) of stock solution required to prepare a 200 mL solution of 0. C) O Compound and being antiaromatic are unstable at room temperature.IITJEE-2011-Paper 1-CPM-16 P(atmosphere) X Y Z V(liter) (A) ∆Sx → z = ∆Sx → y + ∆Sy → z (C) w x → y → z = w x → y Sol. 29. D) Lyophobic colloids are stable due to preferential adsorption of ions on their surface from solution and potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal particles that makes lyophobic sol stable. (8) FIITJEE Ltd. in pure form..com. SECTION III: Integer Answer Type This section contains 5 questions. Sarvapriya Vihar. Fax 26513942 website: www. Which of the following molecules. FIITJEE House. 35. (A. Choose the correct reason(s) for the stability of the lyophobic colloidal particles. The molecular weight of HCl is 36. Ph 46106000.4 M HCl is Sol. 29-A.fiitjee. (A) Preferential adsorption of ions on their surface from the solution (B) Preferential adsorption of solvent on their surface from the solution (C) Attraction between different particles having opposite charges on their surface (D) Potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal particles Sol. 36. New Delhi -110016. ranging from 0 to 9 (both inclusive).

IITJEE-2012-Paper 1-PCM-17 Stock solution of HCl = 29. would exist as cation in neutral solution (pH = 7). Ph 46106000.com.2 × 1000 × 1. the total number of stereoisomers in its pyranose form is CHO CH2 CHOH CHOH CHOH CH2 OH FIITJEE Ltd. Sol.2% (w/w) 29. (9) 2. IV.303 t1/10 = log10 = k k  2.0? H3 N CH H CO NH CH R1 CO NH CH R2 CO NH CH H COO Peptide I II III IV V VI VII VIII IX Sol.303 × 3log 2 = k k 2. The time taken for its decomposition to 1/8 and [ t1/8 ] ×10? (take log 2 = 1/10 of its initial concentration are t1/8 and t1/10 respectively. New Delhi -110016.5 80 ⇒ V = 8 ml 37.3) 38. 29-A.303 × 3log 2     t1/8  k   ×10 = 9   × 10 =  2.25 Molarity of stock solution of HCl = 36. How many of these peptides are positively charged at pH = 7.4 36.. Sarvapriya Vihar. What is the value of 10 [ t1/10 ] 0. Fax 26513942 website: www. Kalu Sarai.303 2. When the following aldohexose exists in its D-configuration. The substituents R1 and R2 for nine peptides are listed in the table given below. VI. 26569493.2 1000 V× × = 200 × 0.303log 8 2.303   t1/10     k  t1/8 = 39.5 × 100 If volume of stock solution required = V ml 29. FIITJEE House. .fiitjee. R1 H H CH2COOH CH2CONH2 CH2CONH2` (CH2)4NH2 CH2COOH CH2OH (CH2)4NH2` R2 H CH3 H (CH2)4NH2 CH2CONH2 (CH2)4NH2 CH2CONH2 (CH2)4NH2 CH3 (4) Peptides with isoelectric point (pI) > 7. VIII and IX An organic compound undergoes first-order decomposition.

Sarvapriya Vihar. . To which group. undergoes a nuclear reaction yielding element X as shown below.com. Kalu Sarai. FIITJEE House. An isotope of copper. FIITJEE Ltd.fiitjee. (8) 1CHO H 2 3 H 4 H 5 H 6 H 2C 40. New Delhi -110016. 6 CH 2 OH 5 H H 4 H 3 OH H O Fixed in D-configuration H 1 OH 2 H H OH OH OH OH OH Hence total number of stereoisomers in pyranose form of D-configuration = 23 = 8 The periodic table consists of 18 groups. 26569493.IITJEE-2011-Paper 1-CPM-18 Sol. element X belongs in the periodic table? 63 1 1 1 29 Cu +1 H → 6 0 n + α + 21 H + X (8) 63 1 1 4 1 A 29 Cu + 1 H → 6 0 n + 2 He + 2 1 H + Z X Mass number: 63 + 1 = 1 × 6 + 4 + 1 × 2 + A A = 64 – 12 = 52 Atomic number: 29 + 1 = 6 × 0 + 2 + 2 × 1 + Z Z = 30–4 = 26 A 52 Z X = 26 Fe Hence X is in group ‘8’ in the periodic table.. Fax 26513942 website: www. Ph 46106000. on bombardment with protons. Sol. 29-A.

. Fax 26513942 website: www..com. j ≤ 3. a12 a22 a32 a13 a23 a33 The locus of the mid–point of the chord of contact of tangents drawn from points lying on the straight line 4x – 5y = 20 to the circle x2 + y2 = 9 is (A) 20( x 2 + y 2 ) − 36 x + 45 y = 0 (B) 20( x 2 + y 2 ) + 36 x − 45 y = 0 (C) 36( x 2 + y 2 ) − 20 x + 45 y = 0 (D) 36( x 2 + y 2 ) + 20 x − 45 y = 0 Sol. then the determinant of the matrix Q is (B) 211 (A) 210 12 (C) 2 (D) 213 (D) Sol. Kalu Sarai. Each question has four choices (A). (C) and (D) out of which ONLY ONE is correct.IITJEE-2012-Paper 1-PCM-19 PAPER-1 [Code – 8] IITJEE 2012 PART . Sarvapriya Vihar.  x2 + x + 1  If lim  − ax − b  = 4 . 29-A.  x2 + x + 1  Given lim  − ax − b  = 4  x +1  x →∞   ⇒ lim (1 − a ) x2 + (1 − a − b ) x + (1 − b ) x 2 + x + 1 − ax 2 − ax − bx − b = 4 ⇒ lim =4 x →∞ x →∞ ( x + 1) ( x + 1) ⇒ 1 − a = 0 and 1 − a − b = 4 ⇒ b = −4. b = 4 (C) a = 2. α − 4   5  Equation of the chord of contact is FIITJEE Ltd. 22 a11 Q = 2 a21 3 23 a12 2 a22 2 a32 2 5 4 24 a13 2 a23 ⇒ Q = 2 ⋅ 2 ⋅ 2 5 2 3 4 a11 2a21 2 a31 2 a12 2a22 2 a32 2 a13 2a23 22 a33 2 a31 9 4 2 a33 6 a11 Q = 2 ⋅ 2 ⋅ 2 a21 a31 ⇒ |Q| = 212|P| |Q| = 213. a = 1. Let P = [aij] be a 3 × 3 matrix and let Q = [bij]. 43. 26569493. 42. (B). then x →∞  x +1  (A) a = 1. b = – 3 (B) (B) a = 1. 41. k) hx + ky = h2 + k2 …(i) 4   Let any point on line be  α. Ph 46106000. where bij = 2i + jaij for 1 ≤ i. If the determinant of P is 2. New Delhi -110016. FIITJEE House. b = –4 (D) a = 2.fiitjee.III: MATHEMATICS SECTION I : Single Correct Answer Type This section contains 10 multiple choice questions. (A) Equation of the chord bisected at P (h. b = 3 Sol.

x y − =1 5 4 O x P(h.. ∫ (sec x + tan x) 1 11 2 sec 2 x 9 dx equals (for some arbitrary constant K) 2 (sec x + tan x) 1 (sec x + tan x) 11 2 { { 1 1 − (sec x + tan x) 2 + K 11 7 1 1 + (sec x + tan x)2 + K 11 7 } } (B) (D) 1 (sec x + tan x ) 1 (sec x + tan x ) 11 2 11 2 { { 1 1 − (sec x + tan x) 2 + K 11 7 1 1 + (sec x + tan x)2 + K 11 7 } } Sol. Fax 26513942 website: www. (C) I= ∫ (sec x + tan x) sec2 x 9 dx 2 Let sec x + tan x = t ⇒ sec x − tan x = 1/t Now (sec x tan x + sec2 x) dx = dt sec x (sec x + tan x) dx = dt dt 1  1  sec x dx = . 20h 9 20 (h2 + k2) = 9 (4h − 5k) 20 (x2 + y2) − 36x + 45y = 0.fiitjee. The total number of ways in which 5 balls of different colours can be distributed among 3 persons so that each person gets at least one ball is (A) 75 (B) 150 (C) 210 (D) 243 (B) Number of ways = 35 − 3C1. 44. FIITJEE House. 26569493. Sarvapriya Vihar. 45. The integral (A) − (C) − Sol. Kalu Sarai.  t +  = sec x t 2 t   1 t+  1  t  dt  I= 9 2 t 2 t ∫ 1 −9 −13 (t 2 + t 2 )dt 2 −13 +1   − 9 +1 1 t 2 t 2  = + 2  − 9 + 1 − 13 + 1   2   2  = ∫ FIITJEE Ltd.IITJEE-2011-Paper 1-CPM-20 4  ⇒ αx +  α − 4  y = 9 5  Comparing (i) and (ii) …(ii) y x +y = 9 2 2 h k h2 + k 2 = = 9 α 4α−4 5 20h α= 4h − 5k h ( 4h − 5k ) h2 + k 2 = Now. k) 4 α−4) 5 (α. Ph 46106000.com. 29-A. New Delhi -110016. .25 + 3C215 = 243 − 96 + 3 = 150.

5) S θ  4 1 13  P . –1. –1. x ≠ 0  Let f ( x) =  then f is . 1. 29-A. New Delhi -110016. h π h 2 cos − 0 h = lim h →0 h π = lim h cos   = 0 h →0 h so. FIITJEE House. 26569493.com. x = 0  (A) differentiable both at x = 0 and at x = 2 (B) differentiable at x = 0 but not differentiable at x = 2 (C) not differentiable at x = 0 but differentiable at x = 2 (D) differentiable neither at x = 0 nor at x = 2 (B) Sol. (A) D. –1 Angle between QR and PT is 45º And PT = 1 1 ⇒ PS = TS = 2 T(2. 1.  3 3 3  D. 1  4 1 13  Coordinate of P ≡  . 4) Q(2.fiitjee. then the length of the line segment PS is 1 (A) (B) 2 2 (C) 2 (D) 2 2 Sol. If S is the foot of the perpendicular drawn from the point T(2.IITJEE-2012-Paper 1-PCM-21 −11   −7 1 t 2 t 2  + 2  − 7 − 11   2  2   −7 −11 1 1 = − t 2− t 2 7 11 1 1 1 1 = − 7 − 7 t 2 11 t11 2 = = − 1  1 t2 11   + t 2  11 7  1 2 1 1 + ( sec x + tan x )  + k =− 11/2 11 7    sec x + tan x ) (  46. R. 4. 3. Sarvapriya Vihar. .  2 π  x cos x . 2. Ph 46106000. R.   0. . The point P is the intersection of the straight line joining the points Q(2.  3 3 3  R(1. f(x) is differentiable at x = 0 f ( 2 + h ) − f ( 2) f ′ 2+ = lim h→ 0 h π 2 −0 ( 2 + h ) cos 2+h = lim h →0 h f ′ ( 0 ) = lim f ( 0 + h) − f ( 0) h →0 ( ) FIITJEE Ltd. 5) and R(1. of PT is 2. . 4) with the plane 5x – 4y – z = 1. x∈ . of QR is 1. 4) to QR.. Kalu Sarai. Fax 26513942 website: www. 4) 47. 3.

Ph 46106000.com. 49. Kalu Sarai. The eccentricity of the ellipse E2 is (A) 2 2 (B) 3 2 FIITJEE Ltd. f ′ 2− = lim h →0 −h π  ( 2 − h )2 cos     2−h = lim h →0 −h 2  π  − ( 2 − h ) cos   2−h = lim h →0 −h π  π (2 − h) 2 sin  − 2 2−h   = lim h →0 h ( ) = lim  −πh  (2 − h) 2 ⋅ sin   h →0 h  2(2 − h)  (2 − h)2 πh π ⋅ sin × = −π πh h →0 2(2 − h) 2(2 − h) 2(2 − h) = − lim 48. Let z be a complex number such that the imaginary part of z is nonzero and a = z2 + z + 1 is real.. New Delhi -110016. 4 The ellipse E1 : Sol. Sarvapriya Vihar. . 26569493.IITJEE-2011-Paper 1-CPM-22 ( 2 + h )2 cos   = lim h →0 π    2+h h (2 + h) 2 π  π sin  −  h→0 h  2 2+h f ′ 2+ = lim = lim ( )  π⋅h  (2 + h) 2 sin   h →0 h  2(2 + h)  = lim (2 + h)2 πh π sin × =π πh h →0 2(2 + h) 2(2 + h) 2(2 + h) f (2 − h) − f (2) Again. Fax 26513942 website: www. 4) circumscribes the rectangle R. Then a cannot take the value 1 (A) –1 (B) 3 1 3 (D) (C) 2 4 (D) Given equation is z2 + z + 1 − a = 0 Clearly this equation do not have real roots if D<0 ⇒ 1 − 4(1 − a) < 0 ⇒ 4a < 3 3 a< .fiitjee. FIITJEE House. 29-A. 9 4 Another ellipse E2 passing through the point (0. x2 y2 + = 1 is inscribed in a rectangle R whose sides are parallel to the coordinate axes.

Sarvapriya Vihar. 29]. 2 Alternate = 1 as it is passing through (0. −2) y=2 x=3 x y = −2 (3. −2) x2 y2 Equation of ellipse is + =1 12 16 1 e= .IITJEE-2012-Paper 1-PCM-23 (C) Sol. 1 2 (D) 3 4 (C) Equation of ellipse is (y + 2) (y − 2) + λ(x + 3) (x − 3) = 0 4 It passes through (0. Fax 26513942 website: www. 2). New Delhi -110016. The function f : [0. 2) x = −3 (−3. − 2 2 Sol.. The points of 9 4 contact of the tangents on the hyperbola are 1  9 1   9  (A)  . 3] f (x) is many one f (0) = 1 f (2) = 29 f (3) = 28 Range is [1. . 12 = 16 (1 − e2) ⇒ e = 1/2. SECTION II : Multiple Correct Answer(s) Type This section contains 5 multiple choice questions. B) Slope of tangent = 2 FIITJEE Ltd. 51. f (x) is many-one-onto Sol. 2] and decreasing in [2. 4) and (3. (B)  − . parallel to the straight line 2x − y = 1. 29] Hence. Tangents are drawn to the hyperbola x2 y2 − = 1 . Ph 46106000. b2 = 16 and 2 + =1 16 a ⇒ a2 = 12 So. b2 4 So. −   2 2 2 2  2 2 (C) 3 3. Let the ellipse be x2 2 a 9 + y2 50. 29-A. 26569493. Kalu Sarai.com. (B). defined by f(x) = 2x3 – 15x2 + 36x + 1. is (A) one–one and onto (B) onto but not one–one (C) one–one but not onto (D) neither one–one nor onto (B) f (x) = 2x3 − 15x2 + 36x + 1 f′(x) = 6x2 − 30x + 36 = 6 (x2 − 5x + 6) = 6 (x − 2) (x − 3) f (x) is increasing in [0. 4) (−3. Each question has four choices (A). 4) ⇒ λ = 3 y (0. 2 2 ( ) (A. (C) and (D) out of which ONE or MORE are correct. FIITJEE House. ( ) (D) −3 3.fiitjee. 3] → [1.

Sarvapriya Vihar. 2x − y = ± 4 2 x y x y ⇒ − = 1 and − + =1 2 2 4 2 2 2 4 2 xx yy Comparing it with 1 − 1 = 1 9 4 1  9 1   9  We get point of contact as  .fiitjee. 2π] be such that 2 cos θ (1 − sin ϕ ) = sin 2 θ  tan + cot  cos ϕ − 1 . . New Delhi -110016.e. −  and  − .. Fax 26513942 website: www. 2 3 2 cos θ (1 – sin ϕ) = 53.   2 3  1 < sin (θ + ϕ) < 1 2 π 5π ⇒ 2π + < θ + ϕ < + 2π 6 6 π 5π 2π + − θmax < ϕ < 2π + − θmin 6 6 π 4π <ϕ< . Then ϕ cannot satisfy 2 π 4π <ϕ< 2 3 3π (D) < ϕ < 2π 2 (B) π 2 4π 3π <ϕ< 3 2 (A. tan ( 2π − θ ) > 0 and 2 2  −1 < sin θ < − (A) 0 < ϕ < (C) Sol. 3 .com. C. . ϕ ∈ [0. Ph 46106000. 2 2 2 2  2 2 52. −  and  −  2 2 2 2  2 2 Alternate:  sec θ   tan θ  Equation of tangent at P (θ) is  x − y = 1  3   2  2sec θ ⇒ Slope = =2 3 tan θ 1 ⇒ sin θ = 3 1  9 1   9  ⇒ points are  . If y(x) satisfies the differential equation y′ − ytanx = 2x secx and y(0) = 0. Kalu Sarai.IITJEE-2011-Paper 1-CPM-24 The tangents are y = 2x ± 9× 4 − 4 i. FIITJEE House. 26569493. θ θ  Let θ. . 29-A. then 2 π π (A) y   = 4 8 2 2 π π (B) y ′   =  4  18 FIITJEE Ltd.. D) 2sin 2 θ cos ϕ − 1 = 2sin θ cos ϕ − 1 sin θ 2 cos θ – 2 cos θ sin ϕ = 2 sin θ cos ϕ – 1 2 cos θ + 1 = 2 sin (θ + ϕ) 3 tan(2π − θ) > 0 ⇒ tan θ < 0 and −1 < sin θ < − 2  3π 5π  ⇒ θ∈ .

For the ship to be operational at least two of its engines must 2 4 4 function. Ph 46106000. Which of the following is(are) true ? 3 c (A) P  X 1 X  =   16 7 (B) P [Exactly two engines of the ship are functioning | X] = 8 5 7 (C) P  X X 2  = (D) P  X X1  =   16   16 (B. P( X 2 ) = . .com. 29-A. FIITJEE House. y′   = + 4 4 8 2 2  2 π 4π  π  2π .IITJEE-2012-Paper 1-PCM-25 2 π π (C) y   = 3 9 2  π  4π 2π (D) y ′   = + 3 3 3 3 Sol.fiitjee. and . D) dy − y tan x = 2 x sec x dx dy cos x + ( − sin x ) y = 2 x dx d ( y cos x ) = 2 x dx y (x) cos x = x2 + c. Kalu Sarai. 26569493. New Delhi -110016. A ship is fitted with three engines E1. E2 and E3 are functioning. (A. E2 and E3. where c = 0 since y (0) = 0 when x = when x = when x = 2 π π2 π π  π  2π . y′   = + 3 3 3 3 3 54. D) Sol. y  = .. P( X 3 ) = 2 4 4 C C C P(X) = P( X1 ∩ X 2 ∩ X 3 ) + P ( X1 ∩ X 2 ∩ X 3 ) + P( X1 ∩ X 2 ∩ X 3 ) + P( X1 ∩ X 2 ∩ X 3 ) = 1 4 1 C P( X ∩ X1 ) 1 C (A) P( X1 / X ) = = 32 = 1 8 P( X ) 4 7 32 = 7 (B) P [exactly two engines of the ship are functioning | X] = 1 8 4 5  X  32 5 (C) P   = 1 =8 X2   4 7  X  32 7 (D) P   = 1 = 16  X1  2 FIITJEE Ltd. Fax 26513942 website: www. y   = 4 3 9 4 8 2 3 π π2 π π . P( X1 ) = 1 1 1 . Sarvapriya Vihar. Let X denote the event that the ship is operational and let X1. when x = . X2 and X3 denote respectively the events that the engines E1. The engines function independently of each other with 1 1 1 respective probabilities .

Sol. Let S be the area of the region enclosed by y = e − x . −1 < x < 0 . x < −1 x2 − 1 . New Delhi -110016. 1) (As area of rectangle OCDS = 1/e) P 2 y = e− x Since e − x ≥ e − x ∀ x ∈ [0. O Q S SECTION III : Integer Answer Type This section contains 5 questions. 0 < x <1 x >1 −ve −1 +ve −ve 0 +ve −ve 1/2 1 +ve −1/2 FIITJEE Ltd. The answer to each question is single digit integer. x = 0 and x = 1. 1]  1 1  B . then 2a + 5b + 5c is (3) r r2 r r2 r r2 r2 r2 r2 r r r2 As. ( ) 57. . 26569493. The total number of points at which f attains either a local maximum or a local minimum is Sol. r r r r r r r2 r r2 r r2 r If a . Kalu Sarai. y = 0. (C) is incorrect. Ph 46106000. B. FIITJEE House. Fax 26513942 website: www. a − b + b − c + c − a = 3  a + b + c  − a + b + c     r r r2 ⇒ 3 × 3 − a +b +c = 9 r r r r r r ⇒ a +b +c = 0 ⇒ a +b +c = 0 r r r ⇒ b + c = −a r r r r r ⇒ 2a + 5 b + c = −3a = 3 a = 3 .   2 e  1 ⇒ S > e dx = 1 −   e 0 ∫ 1 R C  1 1. (A. Sarvapriya Vihar. 56.. 2 2  e   1 1  1 Since 1 +  <1− 4 e e Hence. (5) + x  2x −1  −(2 x + 1)  =   1 − 2x  2x + 1  f ′( x) = x ⋅ (2 x) x2 − 1 . D) 1 S> e 2 A(0.fiitjee. Then 1 1 (A) S ≥ (B) S ≥ 1 − e e 1 1  1 1  1  (C) S ≤ 1 + (D) S ≤ +  1 −  4 e 2 e 2 2 Sol. 29-A.IITJEE-2011-Paper 1-CPM-26 55. Let f : IR → IR be defined as f(x) = x + x 2 − 1 . b and c are unit vectors satisfying a − b + b − c + c − a = 9 .com. ranging from 0 to 9 (both inclusive).  D  e  −x Area of rectangle OAPQ + Area of rectangle QBRS > S 1 1  1   S< (1) + 1 −    . .

0) and (2. the required value is 6 + log3/2  ×  3 2 3 2  4 = 6 + log 3/2 = 6 − 2 = 4. 0. then p′(0) is (9) Let p′(x) = k(x − 1) (x − 3)  x3  ⇒ p(x) = k  − 2 x 2 + 3 x  + c  3    4 Now. 26569493.IITJEE-2012-Paper 1-PCM-27 So. 4− 1 3 2 4− 1 3 2 4− 1 3 2 ⋅⋅⋅ = y 1 y = y2 (y > 0) 3 2 1 8 ⇒ y2 + y−4 = 0 ⇒ y = 3 2 3 2 8   1 so. . 1 The area of ∆PQS = × 2 × 4 = 4 . the points P and Q are (0. p′(0) = 3k = 9. f′(x) changes sign at points 1 1 x = −1. FIITJEE House. 0). so.. p(1) = 6 ⇒ k + c = 6 3 also. − . Sarvapriya Vihar. New Delhi -110016. Sol. 4) which are also diametrically opposite points on the circle. Fax 26513942 website: www. Let S be the focus of the parabola y2 = 8x and let PQ be the common chord of the circle x2 + y2 − 2x − 4y = 0 and the given parabola. total number of points of local maximum or minimum is 5. 59. Ph 46106000. The area of the triangle PQS is (4) The parabola is x = 2t2. 60. 4 − FIITJEE Ltd. The focus is S ≡ (2. 9 So.  1 1 1 1 The value of 6 + log 3/2  4− 4− 4− ⋅⋅⋅ 3 2 3 2 3 2 3 2  (4) Let   is   Sol. 29-A. . 2 Let p(x) be a real polynomial of least degree which has a local maximum at x = 1 and a local minimum at x = 3. 58. Kalu Sarai.fiitjee. 1 2 2 so. p(3) = 2 ⇒ c = 2 so. If p(1) = 6 and p(3) = 2. k = 3. Sol.com. y = 4t Solving it with the circle we get : 4t4 + 16t2 − 4t2 − 16t = 0 ⇒ t4 + 3t2 − 4t = 0 ⇒ t = 0. 1 so.

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