AskIITians IIT JEE Chemistry Test

Code – AC204 Time - One hour
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose. A. 1. 2. 3. B. 4. 5. 6. C. 7. 8. 9. 10. General : This booklet is your Question paper containing 69 questions. Blank papers, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets in any form are not allowed to be carried inside the examination hall. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided separately. Filling the ORS : On the lower part of the ORS, write in ink, your name, your Registration No. Do not write these anywhere else. Make sure the CODE on the ORS is the same as that on this booklet and put your signature on the ORS affirming that you have verified. Write your Registration No. in ink, provided in the lower part of the ORS and darken the appropriate bubble UNDER each digit of your Registration No. with a good quality HB pencil. Question paper format. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has 4 sections. Section I contains 6 multiple choice question. Each question has four choices (A), (B), (C) and (D), out of which only one is correct. Section II contains 4 questions. Each question has four choices (A), (B), (C) and (D), out of which one or more choices is correct. Section III contains 4 questions. Each question contains Statement -1 (Assertion) and Statement -2 (Reason). Bubble (A) if both the statements are TRUE and STATEMENT-2 is the correct explanation of STATEMENT-1. Bubble (B) if both the statements are TRUE butSTATEMENT-2 is NOT the correct explanation of STATEMENT-2. Bubble (C) if STATEMENT-1 is TRUE and STATEMENT-2 is FALSE. Bubble (D) if STATEMENT-1 is FALSE and STATEMENT-2 is TRUE. Section IV contains 3 paragraphs. Based upon each paragraph. Three multiple choice questions have to be answered. Each question has four choices (A) (B) (C) (D) out of which only one is correct. Marking Scheme. For each question in Section I, you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (– 1) mark will be awarded. For each question in Section II, you will be awarded 4 marks, if you darken only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, (–1) mark will be awarded. For each question in Section III, you will be awarded 3 marks, if you darken only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, (–1) mark will be awarded. For each question in Section IV, you will be awarded 3 marks, if you darken only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, (–1) will be awarded. Useful Data Gas Constant Avogadro’s Number R = 8.314 J K–1 mol–1 1 Faraday –1 –1 = 0.0821 Lit atm K mol 1 calorie –1 –1 = 1.987 2 Cal K mol 1 Ev = = 6.023 × 1023 = 96500 Coulomb = 4.2 Joule –1 1.6 × 10 J

11. D. 12. 13. 14. 15.

Na

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H = 1. Br = 80. Fe = 56. D = 2.askiitians.NOIDA. Ag = 108. K = 39. Be = 4. S = 16. Pb = 207. S = 32. Mg = 24. Ca = 40. F = 9. Fe = 26. F = 19. Cr = 24.Planck’s constant Atomic No: Atomic Masses: h = 6. C = 12. Mn = 25. s H = 1. Ag = 47. Li = 3. Na = 23. He = 20. Sec-6.1st Floor. Mn = 55. O = 16.204 . Trans Web Educational Services Pvt. O = 8. Cr = 52. Ltd B – 147. info@askiitians. He = 4. Br = 35. Cu = 63. UP-201301 Website:www. Au = 79.625 × 10–34 J . Cu = 29.5. Li = 7.5. N = 14.6. Na = 11. P = 31. Au = 197. Ca = 20. C = 6.com Email. Cs = 55. Rb = 37. P = 15. K = 19. CI = 35. Sn = 118. AI = 27. N = 7. Ni = 28.625 × 10 erg . s –27 = 6. CI = 17. Zn = 30. He = 2. D = 1.com Tel:0120-4616500 Ext .

com Email. Ltd B – 147. Sec-6.Cl– = 0.com Tel:0120-4616500 Ext .askiitians. UP-201301 Website:www. Calculate the useful work of the reaction Ag(s) + Cl2(g) AgCl(s) Given EoCl2/Cl– = + 1.36 V EoAgCl/Ag. 110 kJ/mol 55 kJ/mol (b) (d) O 220 kJ/mol 1000 kJ/mol The final product of the reaction OMe + Excess O (a) MeO O MeO (c) MeO + MeO O (b) MeO O MeO (d) MeO MeO Trans Web Educational Services Pvt.204 .SECTION I ______________________________________________________ 1.NOIDA. info@askiitians.1st Floor.22 V if PCl2 = 1 atm and T = 298 K (a) (c) 2.

H2SO4 (c) NaCl + MnO2 (d) NaCl + Conc. Which pairs gives Cl 2 gas at room temperature? (a) Conc. y = 2 (b) x = 2.1 × 10 –11. info@askiitians. UP-201301 Website:www.NOIDA.com Email. . The solubility of a sparingly soluble salt A xBy in water at 25oC = 1. Which of the following process is used in the extractive metallurgy of magnesium? (a) fused salt electrolysis (b) self reduction (c) aqueous solution electrolysis (d) thermite process PCl5 (a) (b) (c) (d) molecule has three fold axis of symmetry two fold axis of symmetry both none of these 4.204 2. — C CH (a) (b) (c) (d) it it it it is is is is (1) (2) optically inactive hydroxyl ketone a resolvable hydroxyl acid a non resolvable aldehyde an optically inactive hydroxy acid. 5.askiitians. HNO3 Which statement is correct about the end product of the following reaction series :- 6. y = 3 (d) x = 3. The solubility product is 1. The possibilities are (a) x = 1.3. Sec-6. ______________________________________________________ SECTION II ______________________________________________________ 1. y = 1 (c) x = 1.1st Floor.com Tel:0120-4616500 Ext . y = 1 Which of the following complex(s) is/are correctly matched with their geometry? (a) [CoCl 4]2– — tetrahedral (b) [Co(Py)4]2– — square planar Trans Web Educational Services Pvt. HCl + KMnO4 (b) NaCl + Conc.4 × 10–4 M. Ltd B – 147.

Reason : In N3H.(c) (d) 3. (a) X is CH3 H Y + sodium acetate H O — C — CH3 O (c) Y is H CH3 H OH (d) Y is CH3 H H OH (b) X is H CH3 H O–C–CH3 O ______________________________________________________ SECTION III ______________________________________________________ 1. (d) Total pressure after 30 min is 1150 mm of Hg. Assertion : N2F3+ is planar at each nitrogen atom.0693 min–1 (c) Partial pressure of C at 30 min is 350 mm of Hg.com Tel:0120-4616500 Ext .com Email.204 . UP-201301 Website:www. Ltd B – 147.askiitians. [Cu(CN)4]3– — tetrahedral [Fe(CO)4]2– — square planar In the following gaseous phase first order reaction A(g) 2B(g) + C(g) initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. the bond angle H–N–N is 120o and both the N–N bond length are not equal. trans-2-methylcyclohexanol + acetyl chloride X X + NaOH(aq). Sec-6.NOIDA. 4. Trans Web Educational Services Pvt.1st Floor. Then: (a) Half life for A is 10 min (b) Rate constant is 0. info@askiitians.

askiitians.8 × 10–5) 1. 2. 3.06 mole of NaOH is (a) 0.25 (b) 4.1 mol each of NH 3 and NH4Cl (Kb of NH3 = 1.06 mole of dissolved HCl is (a) 0. Sec-6.3 (b) 0.com Tel:0120-4616500 Ext .602 (c) 0. Assertion : CH3O — CH = CH2 CH3O = CH — CH2 is correct resonating structure.0 (c) zero (d) 11. Assertion : Alkanes are monochlorinated with (CH 3)3 COCl. Reason : The initiating step is the heterolytic cleavage of hypochlorite.2 (d) zero Paragraph The -hydrogen present in aldehydes and ketones are labile due to electron withdrawing – I effect of carbonyl group.com Email.0 The ∆pH value upon addition of 0.NOIDA. Reason : Opposite charge separation is energetically unfavourable. the light energy absorbed is sufficient to eject out of the electron from an atom.2.1st Floor. 4. Reason : Potassium and Cesium when irradiated with light. pH of the mixture is (a) 9. Assertion : Potassium and Cesium are useful as electrodes in photoelectric cells.204 . UP-201301 Website:www. Aldeydes and ketones behave differently in certain reactions. info@askiitians. ______________________________________________________ SECTION IV ______________________________________________________ Paragraph A solution is prepared by mixing 0. Ltd B – 147.2 (d) 0 The ∆pH value upon addition of 0. •• + o 3. Also the carbanion formed is stabilized by conjugation with C=O bond.3 (b) 0. Some aldehydes undergo aldol condensation Trans Web Educational Services Pvt.602 (c) 0.

com Tel:0120-4616500 Ext . Ltd B – 147. Consider the following set of reaction: Trans Web Educational Services Pvt. 1. UP-201301 Website:www.1st Floor. In Cannizaro reaction.NOIDA. OH (c) —CH—CHO by aldol condensation OH (d) —C—COOH by aldol formation O 3. Aldehydes and ketones form acetals which are resistant to alkaline hydrolysis. OH (b) —CH—COONa by intramolecular Cannizaro reaction.askiitians.Methyl ketones also differ with other type of ketones.204 .while some other undergo Cannizarro reaction. the intermediate that will be the best hydride donor is H H (a) Ph — C O OH H C (c) CH3O 2.com Email. info@askiitians. Sec-6. O— O — — (b) Ph — C O— O — H C (d) O2N O— O — Ph—C—CHO in the presence of concentrated solution of NaOH gives O (a) —CH—COONa by crossed Cannizaro reaction.

Consider the following set of reaction: 3-oxocyclopentanal one equivalent H × CH3OH Y H3O+ Z X and Z are (a) —CH O—CH2 O—CH2 H (b) —CH CH2 H (c) —CHO CH2 OH and — CH2OH O—CH2 O—CH2 and — CHO and — CH2OH OH CH2 O (d) CH2 O and —CHO — CHO H OH Trans Web Educational Services Pvt. info@askiitians.askiitians.com Tel:0120-4616500 Ext . UP-201301 Website:www.com Email.1st Floor. Sec-6. Ltd B – 147.204 .NOIDA.

defined as the slope of the enthalpy curve. one simply writes HCl + aq. where n is the no. UP-201301 Website:www.204 .com Tel:0120-4616500 Ext . The heats of solution depend on the composition of the solution as shown in the figure :0 — 20 — — 40 — H/kJ — 60 — — 80 — 6 10 20 30 Moles of H2O 40 50 Integral heat of solution HCl + 2H2O HCl in 2H2O Integral heat of dilution HCl+2H2O+3H2O HCl in 5H2O Trans Web Educational Services Pvt. HCl in (m + n) moles of H2O These quantities are indicated in figure. When n is large enough that continued addition of water does not increase the heat of solution.askiitians. Another quantity of interest is the differential heat of solution.Paragraph The enthalpy in the process HCl + nH 2O HCl in n moles of H2O.NOIDA. The enthalpy of the process HCl in n moles of H2O + mH2O is called the integral heat of dilution. Ltd B – 147. of moles of water is called the integral heat of solution.com Email. info@askiitians. Sec-6. HCl(aq.1st Floor.) The enthalpy for this process it the limiting value for the integral heat of solution.

33 kJ 2. 3. UP-201301 Website:www.1st Floor.NOIDA.com Email.0 kJ (c) –1.0 kJ (d) +30. Sec-6.askiitians.com Tel:0120-4616500 Ext . Integral heat of solution for the following step is HCl + 5H2O HCl(5H2O) (a) –12 kJ (b) –44kJ (c) +60 kJ (d) –60kJ What is the approximate enthalpy change for the reaction (a) –80 kJ/mole (b) –60 kJ/mole (c) –70 kJ/mole (d) –20 kJ/mole Approximate value of differential heat of that solution in which 1 mole of HCl is dissolved in 6 moles of water is (a) –2.1.4 kJ (b) –4. Trans Web Educational Services Pvt.204 . info@askiitians. Ltd B – 147.

1st Floor.204 . Sec-6.com Tel:0120-4616500 Ext . Ltd B – 147. UP-201301 Website:www.Trans Web Educational Services Pvt.com Email. info@askiitians.askiitians.NOIDA.

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