Professional Documents
Culture Documents
com
!
א אوאא א
א
67,-89:%
م/5&א/'א12
34(..."و! ق
و
ن#$א%*"אص ('&"و+,- مא/
A- ;(( ( ( و"نאAH @א$
ABאCD!?8وאE(F?א:=
(3(*( א?عאl'acide acétylsalicylique);(( ( ( א
:25°C?-:'
2
– –
pKA à 25 °C AH / A : 3,5 H2O / HO : 14
M(AH) = 180 g.mol-1
:=
(3(*א?عא H3O+ HO – A–
λ (mS.m2.mol-1) 35,0 19,9 3,6
:QD(S @CD!2:=
!لP! VS = 500,0 mLMNK
LאAH63Hذא&&!
(?&!אJ
C S = 5,55 × 10-3 mol.L-1ِ
pH(
س/:=
(3(*א&אلא$(د1
2,9 ,'-"25°C?-SلUאpH(
س
.SMUلאU[ אH3O+] éq?אאزن-دW (1.1
YאZ!AH63Hא-
4&!
دXא (1.2
(:4]&
^ولא2
_)`*א-
4\אאXf :=
?مא/"و[א (1.3
-
48A/مא/دאW (1.4
. -؟:وس$Yאلאc،-
4τ:=
?مא/&אa 2دW (1.5
&]אY(
سא/-
4
&אزنאe9(2
لUא#[אYאf
2 אD(אg&'aYلאU](&אh2 .σ = 44 mS.m-1,'-" 25°C?- S لU(
س!](&א
:&(
&א
σ = λ H O . [H3O ] + λ A . [A ] + λ
3
+
+
−
-
HO −
. [HO ]-
&]אY&و(
سאg!pH:r3
Yאr(?/(د&א3
2,8r#$AP*نpH&3("ن8".1 mS. m-1@
($
s(/&]אY
[
ز(
سא3?(#Wو0,1@
($
pH &3(g!pHs(/
45 mS. m-1و43 mS:r#$APلU
!](&א3?(3,0 و
σ&(]YوאpHلq(/אtuY:=
?مא/Ku!:
א^ولא:'
pH= 2,8 pH = 3,0 σ= 43 mS. m-1 σ= 45 mS. m-1
xf (en mol) 7,9 × 10-4 5,0 × 10-4 5,6 × 10-4 5,8 × 10-4
v ?(
@א$_
@אW[א;دون-،&"دr'א8"
www.ibnalkhatib2.canalblog.com
xmax = cS.VS :n? 2C?! وn0(AH)= CS.VS "نhو- Xmax = 0: YאZ!AH - 4$ a-אX'xmax@ W(1.4.
:=
(3(*א-
4!
د&א AH(aq) + H2O (l) A– (aq) + H3O+(aq)
(2.1
.σ= λH O +.[H3O+(aq)]éq +λ
A−
.[A− (aq)]éq
3
xf
σ = (λH O+ + λ A− ).
3
VS
σ.VS
xf =
(λ + λ −)
H 3O + A
(2.2
−3
44 × 0,5000.10
. xf = = 5,7.10–4 mol
(35 + 3,6)
m3 : ا!س أن ن وة ا ب
xf ≤ xmax. أن#$
xf σ
[A–(aq)]éq = [H3O+]éq = =
VS (λ + λ −)
H 3O + A
44
[A–(aq)]éq = [H3O+]éq = = 1,1 mol.m–3 = 1,1.10–3 mol.L–1
(35 + 3,6)
: [AH(aq)]éq = [AH(aq)]ini – [A–(aq)]éq:#
دYאy
4Nאz(a'
xf
[AH(aq)]éq = cS –
VS
[AH(aq)]éq = 5,55.10–3 – 1,14.10–3 = 4,4.10–3 mol.L–1
(2.4
[A(−aq)]éq.[H3O+(aq)]éq
K=
[AH (aq)]éq
K = 2,9.10–4
&3
Yאf
(?/(د&א3
د/pH
د3-
(
س/
א3?( ∆X f = (5,8.10 −4 − 5,6.10 −4 ) = 2.10 −5 = 0,2.10 −4 :Q$z'!@
(${אiد/&]אY
(
س/א
Xf لp|}~]":'
5א:c&&א د/'א:
و، ∆X f = (7,9.10 −4 − 5,0.10 −4 ) = 2,9.10 −4 :Q$z'!@
(${אi
&g!pH!&א]&"دY(
سא/:=
(3(*א$'אZa
NO2- ::c63&/%אYא#-
/א − :F2وt
X W−"
→ H + + NO2
HNO2
HNO2(aq) + H2O(l) NO2-(aq)+ H3O+(aq) :
YאZ!-
4@–!
د&א