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JEE Mains Chemistry Model Paper 5

CHEMISTRY
81. Azimuthal quantum number determines the (a) Size of an atomic orbital. (c) Orientation of an atomic orbital. (b) Spin of an electron. (d) Angular momentum of an orbital.

82.

The set of quantum numbers not applicable to an electron is, 1 1 1 (a) 1, 1, 1, . (b) 1, 0, 0, . (c) 1, 0, 0, . 2 2 2 Which of the following ‘d’ orbitals has a diagonal nodal plane? (a) dxy. (b) dyz. (c) dzx. In C3O2, the hydridization state of carbon is (a) SP. (b) SP2. (c) SP3.

(d) 2, 0, 0,

1 . 2

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(d) dx2–y2. (d) dSP2.

86.

The half life of a radioactive substance is determined from a plot of, [where A = activity, decay constant, No = Initial number of radioactive nuclides.] (a) log A vs t. (b) log A vs . (c) log A vs No. (d) log (At) vs

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In the dichromate anion, (a) 4 (Cr–O) bonds are non-equivalent. (b) all (Cr–O) bonds are equivalent. (c) all (Cr–O) bonds are non-equivalent. (d) 3 (Cr–O) bonds are equivalent and the rest (Cr–O) bonds are non-equivalent. =

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1

.

87.

88.

The values of the vander Waals constant ‘a’ for gases O2, N2, NH3 and CH4 are 1.360 L2 atm mol–2 . 1.390 L2 atm mol–2, 4.170 L2 atm mol–2 and 2.253 L2 atm mol–2 respectively. The gas which can most easily be liquefied is, (a) CO2. (b) N2. (c) NH3. (d) CH4.

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At a high pressure, the compressibility factor (Z) of a real gas is usually greater than one. This can be explained from vander Waals equation by neglecting the value of, [a & b are vander Waal constants (a) b. (b) a. (c) both a and b. (d) v.

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JEE Mains Chemistry Model Paper 5

The number of electrons present in 1.8 mL of H2O is, (a) 6.02 × 1023. (b) 6.02 × 1024. (c) 6.02 × 1022.

(d) 6.02 × 1025.

For an ideal gas undergoing expansions in vacuum, [where U = change in internal energy, q = heat, w = work done]. (a) U = 0. (b) q = 0. (c) w = 0. (d) all the above are true. For an irreversible process, [where S = entropy] (a) Ssystem + Ssurr < 0. (b) Ssystem + Ssurr > 0. (c) Ssystem = Ssurr. (d) Ssystem + Ssurr = 0. For the dissociation reaction at equilibrium PCl5(g) PCl3(g) + Cl2 (g)

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(a) x

1 . (b) x (c) x P. P [x = degree of dissociation, P = equilibrium pressure]

1 . P2

(d) x

P.

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For a first order reaction, [t = time for the completion of particular fraction of reaction] (b) t0.75 = 2 t0.5. (c) t0.75 = 1.5t0.5. (d) t0.75 = 4t0.5. (a) t0.75 = 3t0.5. The hydrolysis of ester in an alkaline medium is a, (a) first order unimolecular reaction. (b) second order bimolecular reaction. (c) first order bimolecular reaction. (d) second order unimolecular reaction.

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95.

The ionic product of water will increase, if (a) pressure on the water is decreased. (c) OH– ions are added to the water.

96.

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Which of the following combinations will make a basic buffer? (a) NH3 (1M) and NH4Cl (1M). (b) HCN (2M) and NaOH (1M). (c) NaCN (2M) and HCN (1M). (d) All of these.

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(b) H+ ions are added to the water. (d) temperature of water is increased.

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JEE Mains Chemistry Model Paper 5

The function of salt bridge is to (a) eliminate liquid junction potential where the ions are present in large excess at the junction. (b) increase the cell potential at positive electrode. (c) decrease cell potential at negative electrode. (d) eliminate impurities present in the electrolyte. Which one of the following pairs will not form an ideal solution? (a) Benzene and toluene. (b) Chloroform and acetone. (c) 2-methyl propanol and 2-propanol. (d) Ethylene bromide and propylene bromide. Given that Tf is the depression in freezing point of the solvent in a solution of a non-volatile T solute of molality m, the quantity lim f is equal to m 0 m (a) Lf (latent heat of fusion). (b) Kb (ebullioscopic component). (c) Kf (Cryoscopic component). (d) Hfus (enthalpy of fusion).

98.

99.

101. Which of the following is an example of aerosol? (a) smoke. (b) volcanic dust. (c) cloud. (d) ammonium chloride fumes. 102. Which of the following statements is correct? (a) The number of octahedral voids in a closest packing structure is equal to the number of spheres. (b) The number of tetrahedral voids in a closest packing structure is twice the number of spheres. (c) The number of tetrahedral voids in a closest packing structure is twice the number of octahedral voids present. (d) all of these. Space for rough work

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100. Among the following which shows the lowest osmotic pressure is (a) 0.1 M NaCl. (b) 0.5 M CaCl2. (d) 0.03 M FeCl3. (c) 0.04 M K3 Fe(CN)6].

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JEE Mains Chemistry Model Paper 5

103. In which of the following cases the electron affinity valve is positive? O 2 (g ). O (g ). (a) O (b) O(g ) e P (g). H (g ). (c) P(g) e (d) H (g ) e 104. The differences in properties which arise from the variation in mass of hydrogen are called, (a) isotone effect. (b) isobar effect. (c) isotope effect. (d) isomer effect. 105. Which of the following products are formed when boron is fused with NaOH? (a) B2O3 + H2. (b) Na3BO3 + H2. (d) NaB4O7 + H2. (c) NaBO2 + H2. 106. In the carbon family, the elements other than carbon do not form p -p bonds, because the (a) atomic orbitals are too small and diffused to undergo effective lateral overlap. (b) atomic orbitals are too large and diffused to undergo effective lateral overlap. (c) atomic orbitals are too large and diffused to overlap linearly. (d) atomic orbitals are too small to overlap both laterally and linearly. 107. N2O is (a) neutral oxide. (c) used as anaesthetic in dental surgery.

108. In aluminothermic process, aluminium acts as (a) an oxidizing agent. (c) a flux.

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109. The cyanamide ion [N=C=N]2– is (a) isoelectronic with CO2 and has bent structure. (b) isoelectronic with CO2 and has linear structure. (c) isoelectronic with N2O and has bent structure. (d) isoelectronic with N3– and has pyramidal structure.

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(b) used as a propellant to whip ice cream. (d) all of these. (b) a reducing agent. (d) a solder.

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JEE Mains Chemistry Model Paper 5

110. Which of the following compounds can react with NaOH to form an amide salt ( N Na ) ? CO NH . NH2. (b) (a) CO (c) (d) NH2. CONH2 . 111. Which of the following has the most acidic hydrogen? (a) CH3CN. (b) CH3NO2. (d) (C6H5)3CH. (c) CH(CN)3. 112. The correct order of increasing basicity is, (a) pyrrole < pyridine < Me3N < Me2NH (c) pyrrole < Me2NH < Me3N < pyridine. (b) pyridine < pyrrole < Me2NH < Me3N. (d) Me3N < Me2NH < pyridine < pyrrole.

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114. Which of the following structures is chiral?

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Br Cl

113. The correct order of increasing acidity is (a) CH3CH2CH3 < CH3CH=CH2 < CH3CHO < HCOOH. (b) CH3CH2CH3 < CH3CHO < CH3CH=CH2 < HCOOH. (c) CH3CH=CH2 < CH3CH2CH3 < HCOOH < CH3CHO. (d) CH3CHO < CH3CH2CH3 < CH3CH=CH2 < HCOOH.

Br
(a) Cl

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Br Cl
(b)

Cl

(c) Br

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(d)

116. Which of the following alkane forms a single monochloro derivative on chlorination? (a) Neopentane. (b) Ethane. (c) 2,2,3,3-tetra methyl butane. (d) all of these.

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115. An alkyl magnesium halide reacts with H2O to give alkane. In this reaction water acts as (a) an acid. (b) a base. (c) an catalyst. (d) a solvent.

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Cl

Br

Cl

Br

Cl

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JEE Mains Chemistry Model Paper 5
CCl4

117. In the reaction, RCOOAg + Br2 (a) RCOOBr (c) R

RBr + CO2 + AgBr, the intermediate formed is (b) RCOO (d) all of these.

118. Which of the following compounds is used as a refrigerant? (a) COCl2 (b) CCl4 (c) CF4 (d) CF2Cl2 119. Ethyl acetate (CH3COOC2H5) is allowed to react with an excess of CH3MgI in dry ether and subsequently heated with water. The final product formed is, (a) CH3COCH3. (b) CH3COC2H5. (c) (CH3)3C–OH. (d) C2H5–(CH3)2C–OH. 120. Which of the following undergoes esterification with acetic acid at the fastest rate? (a) (CH3)3COH (b) C2H5OH (c) (CH3)2CHOH (d) CH3OH

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