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Número MSDSPF 47

MSDS - ESBR 1000 SERIES - EMULSION STYRENE BUTADIENE RUBBER -

Data 06/03/2002 Rev 3 Emitente Elcio Motta Aprov. Ricardo Matte

HISTÓRICO DE ALTERAÇÕES
Rev - Data - Histórico 0 - 04/07/2000 - Emissão Original 1 - 18/10/2000 - Alteração do CAS Number 2 - 28/03/2001 - Exclusão da ESBR 1009 3 - 05/03/2002 - Inclusão da ESBR 1009 Aprovação Ricardo Matte

SECTION I - PRODUCT IDENTIFICATION
PRODUCT NAME: PETROFLEX ESBR SERIES 1000 -Emulsion Styrene Butadiene Rubber SERIE SPECIFICATION : ESBR 1006 - ESBR 1009 - ESBR 1027 - ESBR 1028 CHEMICAL NAME: Styrene Butadiene Copolymer (ESBR 1006 - ESBR 1027 - ESBR 1028) e Divinylbenzene - ButadieneStyrene Terpolymer (ESBR 1009) CAS RN: 9003-55-8 PRODUCT DESCRIPTION: Butadiene-styrene copolymer (ESBR 1006 - ESBR 1027 - ESBR 1028) and terpolimer of butadiene-styrene and divinylbenzene (ESBR 1009) produced by hot emulsion polymerization using fatty-acid soaps as emulsifier. Coagulated by saltacid method. A non-staining antioxidant is used. PRODUCER: PETROFLEX INDÚSTRIA E COMÉRCIO S/A - BRASIL TRIUNFO PLANT Via de Contorno, 920 Complexo Básico Pólo Petroquímico Triunfo - RS CEP 95.853-000 Brazil phone.: 51 457-1144 ; fax: 51 457-1109

SECTION II - COMPOSITION
CHEMICAL FAMILY: Synthetic elastomer CHEMICAL FORMULA : (CH2-CH=CH-CH2-CH2-CH)nC6H5

SECTION IIl - EXPOSURE LIMITS
BRASIL L.T
ppm NC mg/m3 NC ppm NC

V.M
mg/m3 NC

LIMITES DE EXPOSIÇÃO OSHAEUA ACGIHEUA TWA TLV/TWA TLV/STEL
ppm NC mg/m3 NC ppm NC mg/m3 NC ppm NC mg/m3 NC

NIOSHEUA IDLH
ppm NC mg/m3 NC

Insignificant Health -1 Flammability . INGESTION: NA INHALATION: NA SKIN: No hazard in normal use industrial at ambient temperature.Moderate 1 . FIRE AND EXPLOSION HAZARD: may quickly burn introducing flame. remove as one would any foreign object. TOXIC SUBSTANCES PRODUCED BY COMBUSTION: CO SECTION VII . EYE CONTACT : Particulates may scratch eye surface and cause mechanical irritation. Exposure to hot material may cause thermal burns. dry chemical foam and CO2.1 Reactivity . SPECIAL PROCEDURES: take all fuel material away from the surrounding area. immediatly immerse in or flush the affected area with large amounts of cold water to dissipate heat.Slight 0 . CHRONIC / OTHERS: NA TOXICOLOGY DATA: NA SECTION V .Extreme 3 . SECTION VI .0 Special . extinguish fire in the wind direction.High 2 .NA 1 1 0 SECTION IV . . SKIN CONTACT: No hazard in normal industrial use. For hot product . FLASH POINT (°C): ND IGNITION TEMPERATURE (°C): 320 LOWER EXPLOSIVE LIMIT (%): ND UPPER EXPLOSIVE LIMIT (%): ND FIRE FIGHTING: extinguisher agents: foam. If in eye.SPILL CONTROL PROCEDURES LAND AND WATER SPILL: Recover spilled material and place in suitable containers for recycle or disposal.NFPA 704 HAZARD SIGNAL: 4 . INHALATION: Negligible hazard at ambient temperature.FIRE AND EXPLOSION HAZARD CLASSIFICATION: Solid fuel.HEALTH INFORMATION INGESTION: No hazard in normal industrial use .FIRST AID EYE: This product is an inert solid.Consult an expert on disposal of recovery material and ensure conformity to local disposal regulations. water spray.

SKIN: where contact may occur with hot material. APPEARANCE: ESBR 1006 .ESBR 1009 .DISPOSAL PROCEDURE DISPOSAL: Place in suitable containers for recycle or disposal.94 VISCOSITY: NA VOLATILES (% VOLUME): 0. BOILING POINT (°C): ND MELTING POINT (°C): ND MOLECULAR WEIGHT: ND SPECIFIC GRAVITY (WATER=1): 0.PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: solid.EXPOSURE CONTROL AND INDIVIDUAL PROTECTION RESPIRATORY PROTECTION: not required . EYES: wear safety glasses.REACTIVITY DATA STABILITY: [ X ] . white . alifatics solvents and chlorinated hydrocarbons.75 (max. ENVIRONMENTAL IMPACTS : No hazard.ESBR 1028 -pale yellow. SECTION XIII .UNSTABLE HAZARDOUS POLYMERIZATION: [ ] . TREATMENT AND FINAL DISPOSAL : According to applied local enviromental laws. SECTION IX . SECTION XIV .OCCUR [ X ] . IDENTIFICATION: Non toxic. PRESSURE: 760 mmHg. SECTION XII .C . VENTILATION: Natural. SECTION XI .) VAPOR PRESSURE (mm Hg):ND SOLUBILITY IN WATER (20°C): Insoluble.SECTION VII – HANDLING AND PROTECTION TEMPERATURE: should be lower than 50°C.WILL NOT OCCUR CONDITIONS TO AVOID INSTABILITY: NA DECOMPOSITION TEMPERATURE: NA THERMAL DECOMPOSITION PRODUCTS: oxides of carbon under burning conditions.ESBR 1027 . SOLUBILITY (g/100g): Soluble in aromatics. wear thermal resistant gloves. ADDITIONAL PROTECTIVE MEASURES: NA SECTION X . Consult an expert on disposal of recovery material and ensure conformity to local disposal regulations.TRANSPORTATION UN NUMBER: N.ENVIRONMENTAL PROTECTION LEAKAGE AND SPILLAGE : Recover in container for disposal.STABLE [ ] .

PETROFLEX.INFORMATION ON REGULATION TSCA Inventory Status : All components of this product are listed on the U.: not classified. REFERENCE: 1. IDLH: Immediately Dangerous to life and Health. LD50: The dose that causes death in 50% of the animals exposed. TWA: Time Weighted Average. STEL: Short Term Exposure Limit . MSDS: Material Safety Data Sheet.. EPA Toxic Substances Control Act Inventory.C. CAS: Chemical Abstract Service.S. OSHA: Occupational Safety and Health Administration. mg/m3: Milligrams of substance per cubic meter of air. NIOSH: National Institute for Occupational Safety and Health. ND: not available. TLV: Thershold Limit Value. GUIA NR-32. PEL: Permissible Exposure Limits. LC50:The concentration in air that causes death in 50% of the animals exposed. 1994. SECTION XV .0 CLASS/SUBCLASS: 4/4. INDÚSTRIA E COMÉRCIO S/A .C.C.PRÓ. NC. PETROFLEX MAKES NO WARRANTY.ADDITIONAL INFORMATION ABBREVIATIONS: NA: not applicable. MANUAL PARA ATENDIMENTO DE EMERGÊNCIAS COM PRODUTOS PERIGOSOS. . THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. NFPA: National Fire Protection Association. Obs: The classification below is valid only to powder or debris up to 640 micrometers with more than 45% of rubber. HOWEVER.1 ADDITIONAL RECOMMENDATIONS: Use labeling according to subclass. UN NUMBER: 1345 LABELING: flammable solid HAZARD CLASS: 4. HAZARD CLASS: N. In others situations is not classified as hazard product. Maximum to be transposted without emergency kit 250 kg. SECTION XVI . method of expressing the concentration of a substance in air. EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THEIR USE THEREOF.LABELING: N.QUÍMICA .Brasil 2. PETROFLEX ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. ACGIH: American Conference of Governmental Industrial Hygienists.ABIQUIM. CLASS/SUBCLASS: N.