TUGAS TEKNOLOGI PUPUK

“PUPUK KALIUM SULFAT”

KELOMPOK 7

1. Ahmed Zikri

(1007133856)

2. Lia Yuningsih

(1107114174)

3. Muhammad Fazhlur Arrafiq

(1107114220)

4. Muhammad Riski Zuliadi

(1007121552)

5. Wan Elsa Novtari Adiani

(1107124206)

JURUSAN TEKNIK KIMIA
FAKULTAS TEKNIK UNIVERSITAS RIAU
PEKANBARU

2012

BAB I
PENDAHULUAN
1.1. LATAR BELAKANG
Pupuk adalah material yang ditambahkan pada media tanam atau tanaman
untuk mencukupi kebutuhan hara yang diperlukan tanaman sehingga mampu
berproduksi dengan baik.Material pupuk dapat berupa bahan organik ataupun non
organik.Pupuk berbeda dari suplemen. Pupuk mengandung bahan baku yang
diperlukan pertumbuhan dan perkembangan tanaman, sementara suplemen seperti
hormon tumbuhan

membantu kelancaran proses metabolisme. Meskipun

demikian, kedalam pupuk, khususnya pupuk buatan dapat ditambahkan sejumlah
material suplemen.
Pupuk terdiri dari berbagai macam bentuk, baik padat ataupun cair.
Kandungan yang terdapat dalam pupuk pun berbeda-beda sesuai dengan jenis
tanaman yang akan dikembangkan. Salah satu jenis pupuk tersebut adalah pupuk
Kalium Sulfat.Pupuk ini lebih dikenal dengan nama ZK. Kadar K2O-nya sekitar
48-52%.Bentuknya berupa tepung putih yang larut didalam air, dengan sifatnya
yang agak mengasamkan tanah.Pupuk ini dapat digunakan sebagai pupuk dasar
sesudah tanam.
Potassium Sulphate (ZK) atau biasa disebut Sulphate of Potash (SOP)
telah dikenal sejak abad ke-14 yang merupakan garam berwarna putih dan
memiliki sifat tidak mudah terbakar serta larut di dalam air. ZK digunakan
sebagai pupuk yakni sumber senyawa kalium dan sulfur pada tanaman
perkebunan seperti rami, kapas, dan tembakau. Di Indonesia pupuk ini tidak
disubsidi sehingga harganya relatif tinggi di pasaran.

1.2.TUJUAN

Adapun tujuan dari penulisan makalah ini adalah sebagai berikut :
1. Memenuhi tugas yang diberikan Dosen Pengampu mata kuliah
teknologi pupuk.
2. Menjelaskan proses pembuatan pupuk kalium sulfat.
3. Menjeleskan fungsi pupuk kalium sulfat dalam kehidupan sehari –
hari.

BAB II
ISI
2.1 Pengertian Pupuk Kalium Sulfat
Kalium sulfat (K2SO4) (juga dikenal sebagai garam abu sulfur)
merupakan garam yang terdiri dari kristal putih yang dapat larut dalam air dan
tidak mudah terbakar. Kalium sulfat ialah garam yang awalnya dikenal pada abad
ke-14, dan dipelajari oleh Glauber, Boyle dan Tachenius, disebut di abad ke-17
sebagai arcanuni atau sal duplicatum yang dianggap sebagai kombinasi antara
garam asam dengan garam alkalin. Senyawa ini dihasilkan sebagai biproduk
dalam banyak reaksi kimia, dan kemudian digunakan untuk disuling dari kainit,
salah satu mineral Stassfurt, namun proses itu telah ditinggalkan karena garam
dapat dibuat cukup murah dari klorida dengan membusukkannya denganasam
belerang dan calcining residunya. Untuk memurnikan produk mentahnya maka
dilarutkan dalam air panas dan larutan yang disaring dan bisa didinginkan, saat
bagian terbesar garam yang dilarutkan itu menghablur dengan promptitule yang
khas.
Pupuk ZK mempunyai potensi pasar yang cukup bervariasi. Beberapa
potensi pasar untuk pupuk ZK antara lain :
· Mampu meningkatkan jumlah dan mutu hasil
· Dapat memilih formula dan jenis bahan baku sesuaidengan kebutuhan: komoditi,
lokasi dan ekonomis
· Dapat memilih bentuk campuran yang dikehendaki sesuaidengan pertibangan
teknis dan ekonomis
· Mengantisipasi dan mengatasi masalah apabila terjadikelangkaan salah satu jenis
pupuk tunggal

• Aman digunakan untuk semua jenis tanaman. • Mudah larut dalam air. Pupuk ZK (Zwavel Kalium) atau kalium sulfat (K2SO4) yang baik digunakan pada tanaman yang tidak tahan terhadap konsentrasi ion klorida tinggi. meningkatkan produksi daun dan jumlahbulu serta minyak daun. karena berasal dari bahan baku yang bermutu dan prosesproduksi yang sempurna.2 Karakteristik dan Manfaat Pupuk ZK Pupuk ZK merupakan pupuk yang mengandung berbagai macam nutrient untuk keperluan tanaman atau tumbuhan. • Merupakan pilihan terbaik untuk memenuhi kebutuhan unsur hara Kalium. • Memperkuat daya tahan tanaman terhadap serangan hama penyakit. meningkatkan daya bakar rokok. · Harga mampu bersaing dan relatif lebih murahdibandingkan pupuk tunggal dan impor. penyimpanan dan penangananlainnya · Aplikasi pemupukan lebih praktis karena tidak perlumencampur beberapa jenis pupuk tunggal · Dijamin kualitas produk sesuai standar SNI. • Sumber unsur hara Kalium dan Belerang dengan kadar cukup tinggi. yaitu ZK 90 (mengandung 50% K2O) dan ZK 96 (mengandung 53% K2O). Manfaatserta keunggulan pupuk ZK adalah: • Tidak higroskopis.Ada 2 macam pupuk ZK yang beredar di pasaran. memperbaiki aroma dan rasa rokok.· Hasil racikan bahan baku melalui proses produksimenghasilkan kualitas campuran produk yang homogen · Mampu meningkatkan efisiensi dan efektifitaspenggunaan pupuk · Memudahkan transportasi. • Untuk tanaman Tembakau : memperbaiki kelenturan dan warna daun. . 2. • Dapat dicampur dengan pupuk lain.

984 Titik Lebur : 790 ºC Titik Didih : 1420 ºC Kelarutan dalam Air : 28.1 g/100 ml (0ºC) 34. kadar gula.1 • Bahan baku utama KCl Rumus Molekul : KCl Masa Atom : 74.asam sulfat Bentuk : Cair Masa Atom : 98.3. 7 Jenuh aq.08 Konsentrasi : 98 %minimum .4 g/100 ml (20 ºC) 56.55 Bau : Berbau Kadar Air : 1% maksimum Konsentrasi : 60 % K2Ominimum Penampilan : kristal putihsolid Warna : putih Grade partikel : halus Kepadatan : 1. Sedikit larut dalam alkohol Keasaman : 7 pH : ca. 2. rasa dan aroma buah. sl. sl. • Untuk tanaman Nanas : meningkatkan produksi buah. alkalies. @ 15C @ 15C Hazard : Tidak dianggap sebagai bahaya ledakan • H2SO4 Nama Lain : Minyak asam belerang Babcock asam. gliserol. dan daya tahan umbi selama penyimpanan. 7 Saturated aq. meningkatkan daya tahan buah selama penyimpanan.• Untuk tanaman Kentang : meningkatkan produksi umbi.3 Sifat fisika dan kimia 2.7 g/100 ml (100 ºC) Kelarutan : Larut dalam eter.

0.01 % maksimum Kelarutan dalam air : 22 g/100ml (20oC)7 g/100g (0oC) Hazard : Menyebabkan iritasi 2.35 g/cm3 Titik lebur : 2572oC (2845 K) Titik didih : 2850oC (3123 K) Kelarutan dalam air : Bereaksi CaO aktif : 65 % minimum Lolos mesh 100 : 90 % minimum Bahan tak larut air : 2 % maksimum • Na2CO3 Nama lain : Natrium karbonat .sodium karbonat Bentuk : Putih solid Bau : Tanpa bau Kelarutan : larut dalam air.45 % maksimum Kandungan Fe : 0.1 Hazard : Bereaksi padasuhu ekstrimdengankekerasandekomposisi 2.3 Produk Utama Produk utama yang dihasilkan dari unit produksi ini adalah pupuk ZK dengan spesifikasi sebagai berikut: .2 Bahan Baku Pendukung • CaO Nama lain : Kalsium oxide Bentuk : Powder / bubuk putih kuning pucat Densitas : 3.05 gr/cc Bahan tak larut air : 0.Bau : berbau Penampilan : cair berminyak pH : 1 N solusi(sekitar 5%b/b)=0.2 % minimum Kandungan NaCl : 0.etanol Kandungan Na2CO3 : 99.01 % maksimum Bulk density : 1.3.3.3. alcohol.05% b/b)=2.0009 % maksimum Kandungan SO4 : 0.1 Nsolution (sekitar 0.

1342 K.3.4 Produk Sampingan Dalam proses produksi pupuk ZK memiliki produk samping.1956oF Tititk didih : 1689oC.3072oF 2.18 g/cm3 Titik lebur : -27.5% Kadar air maksimal : 1% Bentuk : powder/serbuk solid Kepadatan : 2.1962 K.5% • Kadar air maksimal 1% . dengan spesifikasi sebagai berikut: • HCl Nama lain : Asam klorida Konsentrasi HCl : 32% Kadar besi (Fe) : 140 ppm max Bentuk : Cair Densitas : 1.2%48oC (321 K) larutan38% 2. Yaitu HCl.66 g/cm3 Warna : putih Titik lebur : 1069oC.4 Spesifikasi Pupuk ZK Spesifikasi pupuk ZK (SNI 02-2809-2005) : • Kalium ( K2O) : 50% • Sulfur (S) : 17% • Kadar Klorida (Cl) maksimal 2.32oC ( 274 K )larutan 38% Titik didih : 110oC (383 K) larutan20.• K2SO4 Nama lain : Kalium sulfat danpotassium sulfat Kalium ( K2O) : 50% Sulfur (S) : 17% Kadar Klorida (Cl) : maksimal 2.

Thailand. Schoenite (K2SO4.MgSO4. Glaserite (K3Na(SO4)2) Pertambangan sumber batuan tersebut banyak terdapat di negara Rusia.• Bentuk powder/serbuk • Warna putih • Dikemas dalam kantong bercap Kerbau Emas dengan isi 50 kg 2.MgSO4.4H20) 3. Leonite (K2SO4. Bahan baku pembuatan ZK yang berasal dari pertambangan antara lain : 1. Israel. Kongo. dan Amerika Serikat. Dekomposisi KCl dengan Na2SO4 2. ZK digunakan sebagai pupuk yakni sumber senyawa kalium dan sulfur pada tanaman perkebunan seperti rami. dan tembakau. Dekomposisi KCl dengan CaSO4 . negara-negara timur tengah. yaitu: 1.Potassium Sulphate (ZK) atau biasa disebutSulphate of Potash (SOP) telah dikenal sejak abad ke-14 yang merupakan garam berwarna putih dan memiliki sifat tidak mudah terbakar serta larut di dalam air. Pemilihan proes produksi yang digunakan di dalam suatu pabrik pupuk ZK bergantung pada ketersediaan bahan baku. Secara umum ada 7 proses produksi pembuatan pupuk ZK. Di Indonesia pupuk ini tidak disubsidi sehingga harganya relatif tinggi di pasaran.5 Teknologi Proses Pupuk ZK Potassium Sulphate (ZK) biasa digunakan sebagai pupuk pada tanaman. kapas. Kanada. benua Eropa. Cina.6H2O) 4.Lanbeinite(K2SO4.2MgSO4) 2.

Produksi HCl. Dekomposisi KCl dengan (NH4)2SO4 5. Pengolahan limbah asam sulfat 0100090000036aea030000004138020000001610000026060f002220574d464301 0000000000010090cf000000001b00000000200000443f0300445f0300010000006 c00000000000000000000003f0100002e0100000000000000000000f11f00003e1e 000020454d4600000100445f03000c000000010000000000000000000000000000 00a00500008403000070010000e6000000000000000000000000000000809d0500 70820300460000002c00000020000000454d462b014001001c0000001000000002 10c0db01000000600000006000000046000000e8670000dc670000454d462b2240 04000c000000000000001e4009000c00000000000000244001000c000000000000 003040020010000000040000000000803f214007000c0000000000000008400005 34670000286700000210c0db010000000000000000000000000000000000000001 000000ffd8ffe000104a46494600010100000100010000ffe1185445786966000049 492a0008000000020031010200070000002600000069870400010000002e000000 580000005069636173610000030000900700040000003032323002a00400010000 . Pembuatan serat (viscose fibres) 4. dan H2O dengan KCl 6. O2. asam lemak. Dewasa ini. Proses Mannheim yaitu mencampur langsung KCl dengan H2SO4 dengan rasio mol tertentu 7. Pengolahan bijih chromium 2. dan trimethylolpropane 5. pigmen silica. Pemurnian flue gas 3. Pemurnian sumber sulfat alami seperti langbeinite dan kainit A. Proses Produksi ZK dengan Dekomposisi KCl dengan Na2SO4. Proses Hargreaves yaitu mereaksikan gas SO2. Dekompisisi KCl dengan MgSO4 4.3. sumber yang umum digunakan berasal dari Sodium Sulphate Na2SO4 yang dapat diperoleh dari hasil samping dari beberapa proses produksi yakni: 1.

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ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7f9c73b556ce391042ef3df75ede7b5a6bce39ff7fff 7ff75e104231466b2d9452bd771863ef3d10428c311863bd77b55610421042ef3d5a 6bff7fff7fff7f5a6b734ede7bff7fbd773146ef3dde7b734eef3d734e1042ef3dbd77de 7b524ace391042ce39d65ade7bf75e9452ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f .

ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f ff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f9c73ad3531467b6fde7b39671042f75 e94520000ff7f9c734a29b556de7bad35ce39b5564a297b6f9c73104294529452841 09452b556ad353146ff7fff7fff7ff75e8c31bd77bd77ce39c6186b2d7b6fad353146d 65aad3529253967ad3531467b6fff7f1863524a3967734e8c31ff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff 7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7f3967c6181863ff 7fff7fff7fff7fff7f186300005a6bd65a8c31f75eff7f3146104294528c31f75e5a6bce3 9d65af75e0821104231464a29524aff7fff7fff7f3967ef3df75ead35b556734ead35bd 7794521042524a6b2dad35186329253967ff7fff7fff7fde7bff7fb556ce39ff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 .

Selain itu digunakan juga potassium chloride (KCl) dalam bentuk larutan pada temperatur 20 – 25ºC. Beberapa variasi rasio mol (mr) bahan baku dan produk terhadap konversi yang diperoleh di dalam reaktor ditampilkan pada .1Diagram alir proses produksi ZK dengan melalui dekomposisi KCl dengan Na2SO4 Penjelasan proses: Bahan baku yang digunakan adalah sodium sulphate baik dalam bentuk anhydrous (Na2SO4) maupun dalam bentuk hydrated (Na2SO4. serta kondensat hasil kondensasi dari uap evaporator diumpankan ke reaktor.10H2O).fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7 fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fff7fbd77e f3d10427b6f9c733967524a39679c73f75e734ef75e18639c73ff7f7b6f3967de7b39 67734e524a8c319452de7b396794529452f75ebd77ff7fff7fff7f18630821a514f75e de7bb5562925de7b7b6fd65a9452b5567b6fde7b6b2d31467b6 Gambar A. sedangkan untuk rasio mol ZK : Na2SO4 dijaga 2 : 1. Na2SO4. Reaksi yang terjadi adalah sebagai berikut: 4Na2SO4 + 6KCl -->2K3Na(SO4)2 + 6NaCl 2KCl + 2K3Na(SO4)2 --> 4K2SO4 + 2NaCl Rasio mol Na2SO4 : KCl dibuat sangat berlebih yakni antara 1 : 6 sampai 1 : 10 untuk mendapatkan konversi yang tinggi (96 – 99%). Umpan KCl. dan recycle mother liquor yang mengandung kristalin glaserite K3Na(SO4)2 dan KCl.

0100090000037ce9000000001168000000001610000026060f002220574d464301 00000000000100d326000000000900000000200000e0e00000e000010001000000 6c00000000000000000000003f010000a30000000000000000000000f11f00005e1 0000020454d4600000100e00001000c00000001000000000000000000000000000 000a00500008403000070010000e6000000000000000000000000000000809d050 070820300460000002c00000020000000454d462b014001001c000000100000000 210c0db01000000600000006000000046000000242f0000182f0000454d462b224 004000c000000000000001e4009000c00000000000000244001000c00000000000 0003040020010000000040000000000803f214007000c000000000000000840000 5702e0000642e00000210c0db01000000000000000000000000000000000000000 1000000ffd8ffe000104a46494600010100000100010000ffe100604578696600004 9492a0008000000020031010200070000002600000069870400010000002e00000 0000000005069636173610000030000900700040000003032323002a0040001000 0004001000003a0040001000000a400000000000000ffdb00840003020208080808 080808080808080808080808080808080808080808080808080808080808080808 08080808080a080808080a090a08080b0e0a080c08080a08010304040202020902 020908020202080808080808080808080808080808080808080808080808080808 0808080808080808080808080808080808080808080808ffc000110800a40140030 11100021101031101ffc4001c000101010003010101000000000000000000060503 0407010209ffc4003d100002010400040306040307030500000001020300041112 050613211422310717515594d3162341d4326191152433425471d14352b1347281 a1f1ffc40014010100000000000000000000000000000000ffc40014110100000000 000000000000000000000000ffda000c03010002110311003f00fe9af1be097323ed 15ec96eba81d3486de4048272db4b1bb648206338ede9dcd0743f0adefcd26fa6b3f b340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb340fc2b7bf349be9acfecd03f0adef cd26fa6b3fb340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb340fc2b7bf349be9acfe cd03f0adefcd26fa6b3fb340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb340fc2b7bf 349be9acfecd03f0adefcd26fa6b3fb340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb 340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb340fc2b7bf349be9acfecd03f0adefc d26fa6b3fb340fc2b7bf349be9acfecd03f0adefcd26fa6b3fb341f97e58bc1dcf15980 .2.Gambar A.

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0101010102025a2b2c27122a332d8d1d0101010102100101010101010101010101 010101010101010101010101010201020103030308192a1b4d66754a33274f0201 010101010101010101010101010101010101010101010101010101010101100201 01445b4e1a5d2015017635620d5102020102010101010101010101010101010101 0101010101010101010110010210045e705b07333736297a483f01010301010301 010101010101010101010101010101010101010101010101010101010101010101 0202020101010204247501014d510401724101022c0201033d1c4f182b02040101 010101010101010101010101010101010101010101010101010101010101010101 01010101010101172f5c3169660101010101010101010101010101010101010101 01010101010101010101010101010101010101010101010101010102023b457163 661676048603010101010301010101010101010101010101010101010101010101 01010101030210011031874738ae522c1644b3184f2d0101030103010101010101 0101010101010101010101010101010101010103020310014a4e89516c041d2582 290161030102010103010101010101010101010101010101010101010101010101 010103112793491b060252311d267a531501012301010401010101010101010101 01010101010101010101010101010101010101010101010304030201010103175a 02044e230101a4410102380101100c50562d830101100101010101010101010101 010101010101010101010101010101010101010101010101010101010104753f8a 0a4c57010101010101010101010101010101010101010101010101010101010101 01010101010101010101010101010101010202010d1b02611c8c027f0111010102 01030101010101010101010101010101010101010101010101010322010201041a 061737550402184a0f078c01030101230101010101010101010101010101010101 01010101010101010102040202100f3570026a02104c0d0f0127030301010202010 101010101010101010101010101010101010101010101030101031a0b5a1b26040 101422a13654101021001010302010101010101010101010101010101010101010 101010101010101010101010101010101010311517b8c0101187b2304931210021 f110102ab141319430101010101010101010101010101010101010101010101010 1010101010101010101010101010101010101010170642f4f1c010101010101010 101010101010101010101010101010101010101010101010101010101010101010 1010101010101020231575701665a53236b0301020210100101010101010101010 1010101010101010101010101010101010201010102047f30311001014c50122f3f .

2Pengaruh rasio mol reagent terhadap derajat konversi Na2SO4 menjadi K2SO4 Setelah bereaksi di reaktor. produk ZK dipisahkan di filter dan selanjutnya mother liquor yang terbentuk diuapkan di unit konsentrasi 2 tingkat secara bertahap dan diikuti dengan proses kristalisasi pada temperatur rendah (-2ºC) untuk tahap 1. Setiap mother liquor yang sudah terpisah baik di tahap 1 maupun 2 akan dipisahkan di filter untuk selanjutnya di-recycle kembali ke reaktor. sedangkan uap dari unit konsentrasi akan dikondensasikan terlebih dahulu dan selanjutnya .520101040201010101010101010101010101010101010101010101010101010201 02020148360122870102029e18012a010410020101010101010101010101010101 01010101010101010101010103010101117737140c010170150837230101020403 010202010101010101010101010101010101010101010101010101010101010101 0101030303020101020435600101010202515b1101100301020454520413380101 010101010101010101010101010101010101010101010101010101010101010101 010101010101010110014125513f10030101010101010101010101010101010101 010101010101010101010101010101010101010101010101010101010102021813 5211021a3339480104010101010301010101010101010101010101010101010101 0101010101010101030201021b38711c01044f9238601c23010302020101010101 010101010101010101010101010101010101010101010210010313924136310101 011b33521901020101010101010101010101010101010101010101010101010101 0101010223010314410f1802017a372d0c21011001010101020101010101010101 010101010101010101010101010101010101010101010101010101010101020202 010301010301010102010110230103010403040101020102010101010101010101 010101010101010101010101010101010101010101010101010101010101010101 040101020101010101010101010101010101010101010101010101010101010101 010101010101010101010101010101010101010101020101030302010101010101 010104010101010101010101010101010101010101010101010101010204010101 030101010101231001010101010403010202030101010101010101010101010101 010101010101010101010101020101010102010204030102010202020102010301 0101010101010 Gambar A.

Konversi satu tahap (T = 25ºC) 3. Pelarutan gypsum 2. B. Proses Produksi ZK dengan bahan baku KCl dan CaSO4 Ada 3 tahapan utama dalam metode proses ini.dikirim ke reaktor. yaitu: 1. Siklus amoniak dalam proses 010009000003e4ef0200000021a4010000001610000026060f002220574d4643010 0000000000100ec3b0000000015000000002000008073020080930200010000006 c0000000000000000000000df0000003f01000000000000000000005b160000f11f 000020454d4600000100809302000c000000010000000000000000000000000000 00a00500008403000070010000e6000000000000000000000000000000809d0500 70820300460000002c00000020000000454d462b014001001c0000001000000002 10c0db01000000600000006000000046000000a461000098610000454d462b2240 04000c000000000000001e4009000c00000000000000244001000c000000000000 003040020010000000040000000000803f214007000c0000000000000008400005 f0600000e46000000210c0db010000000000000000000000000000000000000001 000000ffd8ffe000104a46494600010100000100010000ffe1006045786966000049 492a0008000000020031010200070000002600000069870400010000002e000000 000000005069636173610000030000900700040000003032323002a00400010000 00e000000003a00400010000004001000000000000ffdb008400030202080809080 808080808080808080808080808080808080808080808080808080808080808080 8080808080a080808080a0a0a08080b0d0a080d08080a08010304040605060a060 60a100d0c0d100f0d0d0d0d0e0d0d0c0d0d0c0c100d0d0c0d0d0c0e0d0c0d0d0d0d 0d0c0d0c0d0c0c0c0d0c0c0d0c0c0c0c0c0d0d0c0d0cffc0001108014000e0030111 00021101031101ffc4001d00000202030101010000000000000000000006050702 0304010809ffc4005e1000020200040302050d090a0a09050100010203040005111 20613210731142241517108151723355474919394b4d2d316323353556195d1d52 4254273758192b1b3d43456647276a1a2b2b5c2184445526265c1c5d6436383a5e 136ffc4001a010101010101010100000000000000000000010203040506ffc40038 110002010202070606020202020300000000010203111231041321517191b11433 .

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7ffa7ff97ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97 ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97f fa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ff a7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ff97ffa7ffa7ffb 7ff97ffa7fff7fff7ffa7ff87ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97 ffa7ff97ffa7ff97ffa7ffa7ffb7ffa7ffa7ffa7ffa7ff97ffb7ff97ff97ff97ffa7ff97ff97ff97 ff97f756fb8779056b056f25e9877fc7f766f6e4 Gambar B.6H2O + MgCl2 K2Mg(SO4)2.2H2O + (NH4)2CO3 --> (NH4)2SO4 + CaCO3 2KCl + (NH4)2CO3 --> K2SO4 + 2NH4Cl Adapun reaksi samping: CaCO3 --> CaO + CO2 2NH4Cl + CaO + H2O --> CaCl2 + 2NH4OH 2NH4OH + CO2 --> (NH4)2CO3 Karakter dasar dari proses ini ialah adanya sistem recovery multistage untuk gas amoniak dan KCl.6H2O + 2KCl --> 2K2SO4 + MgCl2 + 6H2O . juga produk ZK yang dihasilkanakan selalu mengandung amonium sulfat yang sangat dipengaruhi oleh komposisi mother liquor. C. Proses Produksi ZK melalui dekomposisi KCl dengan MgSO4 Reaksi yang terjadi: 2KCl + 2MgSO4.xH2O + 5H2O -->K2Mg(SO4)2.1Diagram alir proses produksi ZK dengan dekomposisi KCl dengan CaSO4 Reaksi yang terjadi dalam proses ini antara lain: CaSO4.

Proses produksi ZK melalui dekomposisi KCl dengan MgSO4 terdiri dari dua
tahap konversi, yakni magnesium sulphate bereaksi dengan sylvite (KCl)
membentuk schoenite (K2Mg(SO4)2.6H2O) terlebih dahulu sebelum membentuk
produk akhir yaitu SOP (ZK).
Skema proses yang biasa digunakan dapat dilihat pada gambar di bawah ini.
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010009000003f83802000000a142010000001610000026060f002220574d464301 00000000000100d66600000000100000000020000084c9010084e9010001000000 6c00000000000000000000003f010000ab0000000000000000000000f11f00002b1 1000020454d460000010084e901000c00000001000000000000000000000000000 000a00500008403000070010000e6000000000000000000000000000000809d050 070820300460000002c00000020000000454d462b014001001c000000100000000 210c0db01000000600000006000000046000000a83900009c390000454d462b224 004000c000000000000001e4009000c00000000000000244001000c00000000000 0003040020010000000040000000000803f214007000c000000000000000840000 5f4380000e83800000210c0db01000000000000000000000000000000000000000 1000000ffd8ffe000104a46494600010100000100010000ffe100604578696600004 9492a0008000000020031010200070000002600000069870400010000002e00000 0000000005069636173610000030000900700040000003032323002a0040001000 0004001000003a0040001000000ac00000000000000ffdb00840003020208080808 08080a080808080808080808080808080808080808080808080808080808080808 08080808080a080808080a0a0908080b0d0a080d08080908010304040605060a06 060a100d0c0d100e0d0d0c0d0d0c0c0c0c0d0c0d0d0c0c0d0d0d0d0d0c0c0c0c0c0c 0c0d080d0c0c0c0c0c080c0c0c080d080d0c080c0d08ffc000110800ac0140030111 00021101031101ffc4001c000100020301010100000000000000000000050601040 7020309ffc4005b1000020103020204060b090b090705000001020300041105120 613071421312241516171a11517233234549194b1d1d2245373749395b3b4d4081 6333542527581b2b5d525444555648592c1d343627284a4c3f082a3a5c2c4ffc4001 . Selain itu NH4Cl dan KCl dapat direcover dengan proses kristalisasi dari larutan induk. Rasio K2O : N di pupuk dapat divariasikan dari 50 : 1 hingga 40 : 5. PFD dari proses ini dapat dilihat pada gambar di bawah ini. Proses Produksi ZK melalui Dekomposisi KCl dengan (NH4)2SO4 Reaksi yang terjadi: 2KCl + (NH4)2SO4 --> K2SO4 +2NH4Cl Proses ini memiliki beberapa karakteristik. diantaranya yaitu konversi KCl menjadi pupuk K2SO4 atau K2SO4-(NH4)2SO4 pada temperatur 25ºC.D.

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1Diagram alir proses produksi ZK dengan dekomposisi KCl dan .ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7fcb3dfb7ff97ffa7ff97 ffa7ff97ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ff97ffa7ffa7ffa7ffa7ff97ffb7ff97ffa7ff97f fa7ffa7ffa7ffa7ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ff a7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa 7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7 ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7f fa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ff a7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ff97ff97ffa7ff97ff97ff97ffb7fff7fff7ffb7ff87ffa 7ff97ffa7ff97ff97ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7f9777d 15af97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff97fb05afb7ff97f f97ff97ffa7ff97ffa7ff97ffa7ffa7ffa7ffa7ffa7f90529773f87ffb7f9256776ff97ff97ff 97ffa7ffa7ffa7ffa7ffa7ffa7ffa7ff97ff97ff97ff97ff97ffa7ff97ffa7ffa7ffa7ff97ff97f9 773f35ef97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7f f97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffc7f ab39d87bf97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa 7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7fd97bcc3dfa7ffa7ff97ff a7ff97ff97ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ffa7ffa7ff87ff97ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff a7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ffa7ff97ff97ffa7ff97ff97ffa7ffa7fff7fff7ffb 7ff97ffa7ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ffa7ffa7ffa7 fb877d15afa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa 7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97fd15afb 7ffa7ff97ffa7ff97ffa7ff97ffa7ffa7ffa7ff97ffb7ffa7f9156776ff97ffb7fb256766ffa7f fa7ffa7ffa7ffa7ff97ffa7ffa7ffa7ff97ffa7ff97ff97ff97ffa7ffa7ffa7ffa7ffa7ff97ffa7ff 97f9877f35efa7ffa7ffa7ff97ffa Gambar D.

Karakteristik dari proses ini yaitu: 1. Proses Mannheim dengan Mencampur Langsung KCl dengan H2SO4 Proses ini menggunakan furnace Mannheim yang berupa bejana silindris yang memiliki 2 ruang bakar.(NH4)2SO4 Pengaruh kadar NH4 di larutan induk terhadap kadar K2SO4 pada garam yang telah dikristalisasi direpresentasikan oleh grafik. Dalam proses ini KCl dikeringkan. diayak. Gas SO2 panas dari Sulfur burner direaksikan dengan uap air dan udara (kondisi excess) di masukan ke dalam converter secara batch dan counter-current. E. dan diumpankan ke chamber reaksi. Diperoleh by-product HCl Reaksi yang terjadi adalah: KCl + H2SO4 --> KHSO4 + HCl KCl + KHSO4 --> K2SO4 + HCl . Proses Hargreaves Tidak banyak literatur yang membahas proses ini. Temperatur tinggi 2. dll) 3. yaitu combustion chamber dan reaction chamber. Temperatur operasi furnace Mannheim adalah sebesar 800ºC. Terlihat bahwa semakin rendah kandungan NH4 di larutan induk maka semakin besar pula yield produk yang diperoleh. Banyak problem pada material (tingkat korosi. Reaksi yang terjadi adalah sebagai berikut: 4KCl + 2SO2 + O2 + 2H2O --> 2K2SO4 + 4HCl F.

010009000003e8e40200000021a4010000001610000026060f002220574d464301 00000000000100f0f4000000001400000000200000b45d0200b47d020001000000 6c0000000000000000000000df0000003f01000000000000000000005b160000f11 f000020454d4600000100b47d02000c00000001000000000000000000000000000 000a00500008403000070010000e6000000000000000000000000000000809d050 070820300460000002c00000020000000454d462b014001001c000000100000000 210c0db01000000600000006000000046000000d84b0000cc4b0000454d462b224 004000c000000000000001e4009000c00000000000000244001000c00000000000 0003040020010000000040000000000803f214007000c000000000000000840000 5244b0000184b00000210c0db01000000000000000000000000000000000000000 1000000ffd8ffe000104a46494600010100000100010000ffe100604578696600004 9492a0008000000020031010200070000002600000069870400010000002e00000 0000000005069636173610000030000900700040000003032323002a0040001000 000e000000003a00400010000004001000000000000ffdb00840003020208080808 080808080808080808080808080808080808080808080808080808080808080808 08080808080a0808080809090908080b0d0a080d08080908010304040605060a06 060a0f0d0c0d0f0f0d0d0d0d0f0d0d0d0d0d0d0d0d0f0d0d0d0d0d0d0d0d0c0c0d0d 0d0e0d0d0c0c0d0d0c0d0d0d0c0c0d0d0c0c0c0d0c0cffc0001108014000e0030111 00021101031101ffc4001d00010002030101010100000000000000000005060102 0704030809ffc400571000020201020204060a0d080805050000010203040011120 513060714211722314194d31623345153547493b3d20824323352556171737591b 4d4156492b1b2b5d1d53542435672828495254481a1f0626383c1e2ffc4001b0101 0001050100000000000000000000000001020304050607ffc40044110002010102 080a08040505010101000000010211030412213141515291d1051415617192a1b1 c1f0133233537281b2e1223442c216236273822443a2b3f106d263ffda000c030100 .Produk ZK selanjutnya didinginkan di cooling drum. Residu H2SO4 dinetralkan dengan penambahan Ca(OH)2 dan CaCO3 sedangkan by-product HCl yang terbentuk didinginkan di graphite heat exchanger dan selanjutnya dilakukan absorbsi 2 tahap dengan air.Reaksi tahap pertama bersifat eksotermis dan terjadi pada temperatur yang rendah. sedangkan reaksi tahap kedua bersifat endotermis dan berlangsung pada temperatur 550 – 600ºC.

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Amerika Serikat. Beberapa negara di dunia yang telah mendirikan pabrik ZK dengan proses Mannheim antara lain Belgia.013535b13601c864c839939b939304020713463101345c933101304d010101036a 9b4d014c6e34314d469b463639c801010301010101010101010101010101010101 01010103015327030103ba2203010302aea15f014ccfa9010101010101010101010 101010101010101010101010101010101010101010101010101010101010101010 10101010101010101010101010101010101010101010325c7013103257106af353 d2301016e8fc6c6147b540101019acf5c015d3e13a11c0404903401021a3c0104010 101010101010101010101010101010101010101010101010101010101010101010 101b82f0403036f3bd31301074fa6b806011fc42401030101010101010101010101 010101010101010101010101010101010101010101010101010101010101010101 010101010101010101030103011a9f03020104b80f35415c5f410208cf81a0a654ca 270401010d8135311d5e9cb131b22505010404d490240172580a3053cf45b0540b 080103030101010101010101010101010101010101010103015327030104293d01 0103018c47a34cb300530101010101010101010101010101010101010101010101 010101010101010101010101010101010101010101010101010101010101010101 010101010101010101043c960103019f619b7439e43a019dad73a8e0a0003b01020 10e168d047c6330c56505319654030122d24d02030101010101010101010101010 101010101010101010101010101010101010101010101b83e040107aaa17c6f0468 d5d53f67053fcc2a010101010101010101010101010101010101010101010101010 101010101010101010101010101010101010101010101010101010101010301030 11a9f03020103c5db5c9c9d16c99b9573e13800ba607501030175e40301dcdb5238 4ab5d406010301dba27035b38874320dcc2de9c9d5880303030101010101010101 0101010101010101010101030153270301042d2e0104019398082a3d13e8723101 010101010101010101010101010101010101010101010101010101010101010101 010101010101010101010101010101010101010101010101010101010101012510 0101011fd807c54d593d0258495fde7c46d02f01010129c39b0526029b0da22d045 49801c88b8b9001030101010101010101010101010101010101010101010101010 Emisi yang dihasilkan dikontrol dengan batasan HCl maksimum 5 ppm dan SO2 maksimum 800 ppm. Indonesia. dan Cina. .

G. Pemurnian Sumber Sulfat Alami seperti Langbeinite dan Kainite
Dasar pemurnian proses ini adalah reaksi kristal dan pertukaran ion.
Proses pemurnian langbeinite dapat dilakukan dengan menggunakan Muriate of
Potash (MOP) atau KCl dengan mencampurnya dengan langbeinite.
4KCl + K2SO4.2MgSO4 --> 3K2SO4 + 2MgCl2
Bijih langbeinite dipisahkan dari KCl dan NaCl dengan pencucian selektif,
pengapungan, dan penambahan agen pemisah.Selanjutnya bijih tersebut
dihaluskan dengan ball mill dan dicampur dengan larutan MOP yang telah
dilarutkan dan di-clarified terlebih dahulu pada unit terpisah. Produk ZK yang
terbentuk berupa larutan garam dan kristal. Kristal dapat difiltrasi atau
disenrifugasi kemudian dikeringkan, dan terakhir diayak untuk memperoleh
ukuran produk yang sesuai.Sedangkan garam dapat dievaporasi, kristalisasi, dan
terakhir difiltrasi.Campuran dari garam yang diperoleh dapat diumpankan kembali
ke reaktor, sedangkan filtratnya dapat dibuang sebagai limbah.
Proses pemurnian bijih kainite yang hampir mirip dengan pemrosesan
langbainite terdiri dari 4 tahap:
1. Persiapan bijih dan pengapungan
2. Produksi schoenite (K2SO4.MgSO4.6H2O) dan recovery-nya
3.Leaching schoenite menjadi ZK
4. Pengolahan larutan induk
Kainite dihaluskan bersama garam recycle di ball mill dan hydroclasifier.
Overflow akan menuju ke thickner dan filter utama sedangkan underflow diolah
dengan flotasi dan filtrasi. Cake dari filter utama akan diumpankan ke reaktor
schoenite dan cyclone. Setelah 2 tahap pemisahan, Schoenite diumpankan ke
reaktor leaching dan ZK yang terbentuk dipisahkan di thickner lalu di sentrifugasi
dan dikeringkan, sedangkan overflow thickner di-recycle kembali. Spesifikasi
produk yang terbentuk juga cukup baik, yakni kadar K2O minimal 50% dan
kandungan klorin yang kecil yaitu kurang dari 1 %.
2.6 Industri Yang Memproduksi Pupuk ZK
Di Indonesia, pabrik atau pun industry pupuk yang memproduksi pupuk

ZK (Kalium Sulfat) adalah PT Petrokimia Gresik yang berada dibawah
pengawasan. PT Pupuk Sriwidjaja(Persero) yang telah ditunjuk oleh pemerintah
sebagai perusahaan induk yang bergerak dalam bidang kegiatan usaha pupuk,
petrokimia, rekayasa, konstruksi, dan pengadaan umum.
2.7 Gambar Pupuk ZK

BAB III
KESIMPULAN

Salah satu jenis pupuk adalah pupuk Kalium Sulfat.Pupuk ini lebih dikenal
dengan nama ZK. Kadar K2O-nya sekitar 48-52%.Bentuknya berupa tepung putih
yang larut didalam air, dengan sifatnya yang agak mengasamkan tanah.Pupuk ini
dapat digunakan sebagai pupuk dasar sesudah tanam.Potassium Sulphate (ZK)
atau biasa disebut Sulphate of Potash (SOP) telah dikenal sejak abad ke-14 yang
merupakan garam berwarna putih dan memiliki sifat tidak mudah terbakar serta
larut di dalam air. ZK digunakan sebagai pupuk yakni sumber senyawa kalium
dan sulfur pada tanaman perkebunan seperti rami, kapas, dan tembakau.
Pupuk ZK memiliki banyak keuntungan sehingga banyak diminati
pasar.Pupuk ZK (Zwavel Kalium) atau kalium sulfat (K2SO4) yang baik
digunakan pada tanaman yang tidak tahan terhadap konsentrasi ion klorida
tinggi.Ada 2 macam pupuk ZK yang beredar di pasaran, yaitu ZK 90
(mengandung 50% K2O) dan ZK 96 (mengandung 53% K2O).
Terdapat beberapa macam teknologi yang digunakan dalam pengolahan pupuk
ZK, yaitu :
1. Dekomposisi KCl dengan Na2SO4
2. Dekomposisi KCl dengan CaSO4
3. Dekompisisi KCl dengan MgSO4
4. Dekomposisi KCl dengan (NH4)2SO4
5. Proses Hargreaves yaitu mereaksikan gas SO2, O2, dan H2O dengan KCl
6. Proses Mannheim yaitu mencampur langsung KCl dengan H2SO4 dengan rasio
mol tertentu
7. Pemurnian sumber sulfat alami seperti langbeinite dan kainit

wikipedia.com/msds/englishhtml/S8234.com/msds/englishhtml/p5631.jtbaker.html .htm ) http://www.wikipedia.com/2009/08/teknologi-proses-produksipupuk-zk.org/wiki/Potassium_sulfate) http://adityabeyubay359.htm ) (http://en.blogspot.petrokimia-gresik.DAFTAR PUSTAKA ( http://www.com/) (http://en.jtbaker.org/wiki/Calcium_oxide) ( http://www.

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