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Seminar -3

DENTAL CERAMIICS DENTAL CERAM CS CONTENT                Introduction History Structure Classification Composition Properties Strengthening of dental porcelain Condensation of dental porcelain Firing procedure Stages of maturity Metal -ceramic All ceramics Application of ceramics Conclusion References

INTRODUCTION : Man has been obsessed with duplicating, restoring and replacing various lost body parts like the limbs, ear, nose and eyes with artificial prosthesis and teeth being no exception. The quest for an artificial prosthesis similar to the natural tooth, both in function and aesthetics, in the oral environment still remains as a foremost concern to the dentist, which has led to the use of CERAMICS in dentist. WHAT ARE CERAMICS? The term ceramic is derived from the Greek word “keramos,” which means “potter” or “pottery.” This is related to a Sanskrit term meaning “burned earth,” because the basic components were clays from the earth that were heated to form pottery.1 Ceramic is an inorganic compound with non-metallic properties typically composed of metallic (or semi metallic) and non-metallic elements (example AI2O3, CaO) - Kenneth J. Anusavice

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Dental ceramic is an inorganic compound with non-metallic properties typically consisting of oxygen and one or more metallic or semi metallic elements (e.g. Al, Ca, Li, Mg, K, Si, Na, Sn, Ti and Zr) that is formulated to produce the whole or part of a ceramic based dental prosthesis.

HISTORICAL EVOLUTION OF CERAMICS : Till 18th Century dental technologie remian undeveloped . The candidate material for artificial teeth during these days were :  Human teeth  Animal teeth that were carved to size and shape of human teeth but they were unstable towards coorosive agents in saliva  Ivory : elephant ivory and bone contained pores which got stained easily.2 The current dental ceramics are far from the early ceramics that started being used over 200 years ago. Early records of the first ceramics used as dental materials date back to 1774, when french apothecary alexis duchateau and parisian dentist Nicholas dubois De Cheamnat manufactured the first complete ceramic denture.

Nicholas dubois De Cheamnat

The initial use of ceramics materials in dentistry was in the obtention of complete dentures. Early in the 19th century, Italian dentist Giuseppangelo Fonzi manufactured individual ceramic teeth attached to a metallic substructure which, in turn ,was attached to complete dentures.

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Giuseppangelo Fonzi

The restoration of individual ceramic teeth in the oral cavity was delayed until the late 1800s, when Logan constructed ceramic teeth fused to the metallic post so that these posts could function as an intra radicular for the restoration. During last 40 years ,research has foccused on improving metal free systems and developing superior materials regarding esthetics and clinical performances to offer patients several alternatives to restore missing or damaged teeth.3 1958 first dental porcelain for veneering was introduced, which led to the wide spread use of metal –ceramic restoration in the 1960s and beyond, followed by invention of the porcelain jacket crown that was popularized in hte 1960s by Mclean. 1970 saw the advent of the early experiments in CAD/CAM crown fabrication, followed by an influx of ceramic based restoration systems from 1980s through to the present day1 STRUCTURE: The structure of ceramic material is dictated by the type of atoms present, the type of bonding between the atoms and the way atoms are packed together. The atoms in ceramic materials are held together by a chemical bond and two most common bonds for ceramics are ionic bond(occurs between a metal and nonmetal and involves the attraction of opposite charges when electrons are transferred from the metal to the nonmetal); and covalent occurs between two nonmetals and involves sharing of atoms. The bonding of atoms together is much stronger in covalent and ionic than in metallic bonding. Because of this, metals are ductile and ceramics are brittle.

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Many dental ceramics contains a crystal phase and a glass phase based on silica structure. This structure is characterized by a silica tetrahedran in which a Si 4+ cations is positioned at the center of a tetrahedran with O- anions at each of the four corners.

The resulting structure is not closely packed and has both covalent and ionic characteristics. The regular dental porcelain, being glassy in nature, is largely non crystalline, and exhibits only short range order in atomic arrangement, which is referred to as dental glass ceramics. The only true crystalline ceramic used at present in restorative dentistry is alumina (Al2O3), which is hardest and strongest oxide known.4 CLASSIFICATION : 1. 2. 3. 4. 5. Based on chemical composition According to type According to use According to firing température According to firing technique
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6. According to substrate metal 7. Microstructural classification 8. Processing technique 1. BASED ON COMPOSITION: A) SILICATE CERAMICS: Characterized by an amorphous glass phase with porous structure. The main components are SiO2 with small addition of crystalline Al2O3, MgO, ZrO2 and or other oxides. Dental porcelain falls in this category. B) OXIDE CERAMICS: Contain principal crystalline phase (e.g., Al2O3, MgO, ThO2 or, ZrO2) with either no glass phase or a small content of glass phase. C) NON OXIDE CERAMICS: These are impractical for use in dentistry because of high processing temperatures, complex processing methods or unesthetic color and opacity. D) GLASS CERAMICS: These are types of ceramics containing a glass matrix phase and atleast one crystal phase.4 2. ACCORDING TO TYPE a) b) c) d) e) f) Feldspathic porcelain Leucite reinforced porcelain Aluminous porcelain Glass infiltrated aluminous Glass infiltrated spinell Glass ceramics4

3. ACCORDING TO USE a) Ceramic for artificial teeth b) Jacket crown, inlay and onlay ceramic
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ceramics can be defined by their composition of glass-tocrystalline ratio.4 7. 3. 2. MICROSTRUCTURAL CLASSIFICATION At a microstructural level.1101 t0 1300C c) Low fusing . Vacuum fired (at reduced pressure) 3. There can be infinite variability of the microstructures of materials. Diffusible gas firing 6. they can be divided into four basic compositional categories with a few subgroups: a) Composition Category 1: Glass-based systems (mainly silica) b) Composition Category 2: Glass-based systems (mainly silica) with fillers.<850C4 5. usually crystalline (Typically Leucite or a different high-fusing glass) c) Composition Category 3: Crystalline-based systems with glass fillers (mainly alumina) d) Composition Category 4: 6 .850-1101C d) Ultra low fusing .>1300 C b) Medium fusing . Cast metal Sintered metal Swaged metal Glass ceramics CAD/CAM. however. 4. 5. ACCORDING TO SUBSTRATE METAL 1. ACCORDING TO FIRING TECHNIQUE 1. METAL CERAMICS (PORCELAIN FUSED TO METAL) METAL FREE CERAMICS (ALL CERAMICS) 8. ACCORDING TO FIRING TEMPERATURE a) High fusing .Seminar -3 c) Metal ceramic d) Anterior bridge ceramic 4. Air fired (at atmospheric pressure) 2.

 Aluminosilicates occurs naturally. Subcategory 2. and contain various quantities of potassium and sodium. or fluorapatite.  The primary crystal types today are leucite. and opacity  It is further subdivided into three groups. Leucite is created in dental porcelain by increasing the K2O (potassium oxide) content of the aluminosilicates glass. Leucite  coefficient of thermal expansion (CTE). This filler was added to create porcelain that could be successfully fired on to the metal substructures.  The glass composition is similar to the pure glass Category 1. Amorphous Glass  Best mimic the optical properties of enamel and dentin. are known as feldspars. lowering the melting temperature of the material. lithium disilicate. and alumina (aluminium oxide). .color. 7 .1 Low-to-Moderate Leucite-Containing Feldspathic Glass These materials have been called feldspathic porcelains by default.  Derived from group of mined minerals called feldspar and are based on y silicon dioxide (also known as silica or quartz). It also acts a flux. Lithium disilicate crystals are made by adding Li2O (lithium oxide) to the aluminosilicates glass. The difference is varying amounts of crystal types have either been added to or grown in the glassy matrix.  Glasses based on feldspar are  Resistance to crystallization(devitrification)  Have low firing ranges  biocompatible COMPOSITION CATEGORY 2 Glass-Based Systems with fillers  Filler particles are added to the glass composition to improve mechanical properties.Seminar -3 Polycrystalline solids (alumina and zirconia) COMPOSITION CATEGORY 1: Glass-Based Systems. And to control optical effects such as opalescence .

where the aluminosilicates glass has lithium oxide added.  The most widely used version is the original iPs empress® (ivoclar Vivadent.  These materials have been developed in both powder/liquid. including veneers. with moderately high strength and is used for anterior crowns. COMPOSITION CATEGORY 4: Polycrystalline Solids  Have no glassy component. and pressable forms.2 High-Leucite containing glass  Glassy phase is based on an alumino-silicate glass. Amherst.3 Lithium-Disilicate Glass-Ceramics It is a new type of glass ceramic. all atoms are densely packed together without any intervening matrix to form a dense.g.g In-Ceram Spinell (alumina and magnesia matrix) is the most translucent. In-Ceram Zirconia (alumina and zirconia matrix) has very high strength and lower translucency and is used primarily for three-unit posterior bridges. glass-free polycrystalline structure.Seminar -3  Inhibit crack propagation. and anterior/posterior crowns and bridges. machinable.  This material is called a glass ceramic. In-Ceram Alumina (alumina matrix) has high strength and moderate translucency and is used for anterior and posterior crowns.” Subcategory 2. COMPOSITION CATEGORY 3: Crystalline-based systems with glass fillers cover the wide scope of all-ceramic restorations. inlays. thereby improving the material‟s strength. E.max). onlay. air-free. which has had the crystalline phase grown within the glass matrix by a process called “controlled crystallization of glass.  The amount of Leucite may be adjusted in the glass based on the type of core and required CTE Subcategory 2. IPS Empress II (now called as IPS e. ny) but there are several other products in this category. E. 8 .

Al2O3) or zirconium oxide (ZrO2) framework5. Ceramics can be classified as:     Powder condensation Slip casting Hot pressing Computer aided design / computer aided manufacturing Powder condensation  This is the traditional method of forming ceramic prosthesis  Moist porcelain powder is applied with an artist brush and excess moisture is removed to compact powder particles together.Seminar -3  This structure makes difficult to drive crack through atoms compared to atoms in the less dense and irregular network found in glasses. opportunity for depth translucency and accuracy of fit. 9 .  This method results in a large amount of residual porosity. Slip casting  A slip is a low viscosity slurry or mixture of ceramic powder particles suspended in a fluid (usually water).  The porcelain is further compacted by visual flow of the glassy component during firing under vacuum.  The porosity and discontinuous nature of the crystalline phase lead to relatively low strength and a wide variation in strength. so these materials are usually applied as the esthetic veneer layers on stronger cores and frameworks. CLASSIFICATION BASED ON PROCESSING TECHNIQUE Ceramics having same composition may be fabricated by different laboratory techniques and each method of forming results in a different distribution of flaws.  These are relatively opaque and hence these high strength ceramics are used as substructure material upon which glassy ceramics are veneered to achieve pleasing aesthetics. 1.  Have greater translucency than can be achieved using other methods [13].  Several processing techniques allow the fabrication of either a solid-sintered aluminous oxide (alumina.

Pressable  Lost wax method is used to fabricate molds for pressable dental ceramics.  Available from manufacturers as prefabricated ingots made of crystalline particles distributed throughout a glassy material. and some of the powder particles in the slip become compacted against the walls of the mold forming a thin layer of green ceramic that is to become the framework The remaining slip is discarded. IPS e.  Pressable may be used for inlays.  Advantage is its good accuracy of fit  Used only as core and framework materials. E. glass infiltration (In-Ceram. Limited application is because of complicated series of steps.g. which provide a challenge to achieving accurate fit & may result in internal defects that weaken the material from incomplete glass infiltration The original In-Ceram and some partially stabilized zirconia blocks are fabricated based on slip casting of alumina or zirconia.g. and single-unit crowns  E.  Pressable ingots are heated to a temperature at which they become a highly viscous liquid.Seminar -3        Slip casting involves forming a mold or negative replica of the desired framework geometry and pouring a slip into the mold The mold is made of a material (usually gypsum) that extracts some water from the slip into the walls of the mold through capillary action.max ZirPress (Ivoclar-Vivadent) CAD/CAM  CAD-CAM ceramics are available as prefabricated ingots  CAD-CAM ceramics are available as prefabricated ingots6 Composition: 10 . onlay. Ceramics fabricated by slip casting can have higher fracture resistance than those produced by powder condensation because the strengthening crystalline Particles form a continuous network throughout the framework. and the framework can be removed from the mold after partial sintering to improve the strength to a point where the framework can support its own weight. veneers. and they are slowly pressed into the lost wax mold. Vita Zahnfabrik).

Additional properties like low fusion temperature. boron. Such a structure is called vitreous and the process of forming it is known as vitrification. sodium. and all porcelains based on feldspar are referred to as FELDSPATHIC PORCELAINS. SiO4. Feldspars are present in concentrations of 75 to 85% and undergo incongruent melting at temperatures between 1150C and 1530C. the basic ingredients of these types of porcelains are feldspar kaolin (clay) and quartz. Natural feldspars can be either sodium feldspar (albite) or potassium feldspar (orthoclase / microline) which are minerals composed of potash (K2O). molten glass solidifies with a liquid structure instead of a crystalline structure. For dental applications. The principal anion present in all glasses is O2 ion. phosphorous etc.g. high viscosity. only two glass forming oxides – silicon oxide and boron oxide are used to develop the principal network. Soda (Na2O) Alumina (Al2O3) and silica (SiO2). 11 . HIGH FUSING PORCELAINS Traditionally. are glassy materials. These are necessary to increase the thermal expansion compatible with metal coping. The pyroplastic flow of dental porcelain should be low in order to prevent rounding of margins. color and resistance to devitrification is obtained by the addition of other oxides like potassium. to a large extent. which forms very stable bonds with small multivalent cations such as silicon. boron or aluminium oxides to the glass forming lattice. Glasses are super-cooled liquids / non-crystalline solids with only a short-range order in their atomic arrangement. calcium. Incongruent melting is the process by which one material melts to form a liquid plus a different crystalline material. Feldspar is the primary constituent. in silicon glasses. SiO4 tetrahedral are formed which are responsible for the random network of glass). These ions are termed as glass formers. light potassium based feldspar is generally selected because of its increased resistance to pyroplastic flow and an increased viscosity.. loss of tooth from and Obliteration of surface markings. For dental purposes.Seminar -3 Dental porcelains. (e. Hence a glassy phase is formed and suspended inside it are crystalline potassium alumino silicate crystals known as Leucite. During cooling.

7 GLASS MODIFIERS  The sintering temperature of silica is too high for use in veneering esthetic layers bonded to metal substructure. 12 . It is present in concentrations of 13 to 14%. This softening allows the powder particles to coalesce together (sintering) and form a dense solid. However. and a greater translucency. LOW AN ULTRA LOW FUSING PORCELAINS The low and medium fusing porcelain powders are glasses which have been ground from blocks of matured porcelain. at such high temperature metal will melt. little or no pyrochemical reaction occurs. PURE QUARTZ Pure quartz is used porcelain as a strengthener. These additions tend to modify the properties by interrupting the glass network and hence are also known as glass modifiers. The raw ingredients for the low and medium fusing porcelains are basically the same as for the high fusing porcelain powders but in addition contain balancing oxides / fluxes. Consequently. but the glass phase softens and flows slightly. The main function of quartz (silica) is to impart more strength and firmness. In addition the thermal contraction of coefficient of crystalline silica is too low for the alloys. Traces of iron may be present as impurities in the quartz and must be removed to prevent discoloration of porcelain. The rapid cooling induces stresses in the glass to the extent that considerable cracks and fractures occur. It also adheres to the framework of quartz particles and shrinks considerably during firing. MEDIUM. the temperature must be controlled to minimize the pyroplastic flow. Silica remains uncharged at the usual firing temperatures and hence contributes stability to the mass during heating by providing a framework for other constituents. When mixed with water. it is included only in small concentrations of 4 to 5%. and the fused mass is the quenched in water. 2SiO2. 2H2O) serves as a binder. For this. it forms a sticky mass. The brittle material is then ground to a fine powder of almost colloidal dimensions. Unfortunately. which allows the unfired porcelain to be easily worked and molded. During subsequent firing. pure kaolin is white in color and reduces the translucency of porcelain.Seminar -3 KAOLIN / CLAY Kaolin / clay (Al2O3. On heating. the raw ingredients are mixed and fused. it reacts limitedly with feldspar (known as pyrochemical reaction) and thereby provides rigidly. This process is referred to as FRITTING and the product so obtained is called a frit.

are added . phosphorous pentoxide etc8 INTERMEDIATE OXIDES  The addition of glass modifiers not only lowers the softening temperature but also reduces the viscosity of the glass. sodium and calcium oxides.  Because if too many tetrahedral are disrupted. magnesium oxide. they disrupt the continuity of the SiO4 network.  These alkali decreases the amount of cross-linking between the oxygen and the glass forming elements like silica i.7 BORIC OXIDE  Boric oxide (B2O3) serves as a glass modifier as well as a glass former. Other oxides added lithium oxide.  Decreases viscosity  Lowers softening temperature  Forms own glass network8 OPACIFYING AGENTS  The translucency of porcelain can be decreased by using an opacifying agent. 13 .  Zirconium oxide is the most common opacifiers  The difference between the refractive indices of the glass and the opacifiers is the basic mechanism behind opalescence.e.  These breakage results in  Increased fluidity  Lower softening temperature  Increases thermal expansion  The modifier concentration should not be too high.  Different wavelength of visible light are scattered differently by the opacifying particles..Seminar -3  Bond between the silica tetrahedral can be broken by addition of alkali metal ion such as Na.  To overcome this problem intermediate oxides lie aluminium oxide (Al2O3). there may occur crystallization during the porcelain firing operations  reduce the chemical durability (resistance to attack by water .K and Ca.  An opacifying agent is generally a metal oxide-ground to a very fine particle size of <5m.acids and alkalis)  The most commonly used glass modifiers are potassium. These are introduced as carbonates that revert to oxides on heating.

fluoresced areas etc.Seminar -3  This effect depends upon the size as well as the volume distribution of the particles.4 to 0. platinum gray Gray Chromium oxide. 8 Different coloring pigments used in dental porcelain Ferric oxide (black). Stains in finely powdered form are mixed with water or glycerine and water or any other special liquid. or built into the porcelain (internal staining). Nickel oxide Titanium oxide Manganese oxide Chromium-tin.7 COLOURING AGENTS  Pigmenting or colouring oxides are added to obtain various shades needed to simulate natural teeth.  These pigments are produced by fusing metallic oxides together with fine glass and feldspar and then regrinding to a powder. Internal staining is preferable as it gives more lifelike results and also prevents direct damage to the stains by the surrounding chemical environment. The wet mix is applied with a brush either on to the surface of porcelain before glazing. 14 .  Preferably. calcification spots.  The different colouring pigments used in dental porcelain are given in the table below. Copper oxide Cobalt Salts Ferrous oxide. Particles in the size range 0.  This powder is blended with the un-pigmented porcelain powder to obtain the proper hue and chroma. the size of the particle should be nearly the same as the wavelength of visible light.8 m generate a blue tinge in reflecting light and turn yellowish red in transmitted light. Chromium-alumina Indium Green Blue Brown Yellowish brown Lavender Pink Yellow / Ivory STAINS AND COLOR MODIFIERS Stains are generally low fusing colored porcelains used to imitate markings like enamel check lines.

nonglazed porcelain.Seminar -3 Color modifiers on the other hand are less concentrated than stains and are used to obtain gingival effects or highlight body colours. It also seals pores on the surface of fired porcelain.  Self-glazing  Defined as a vitrified layer that forms on the surface of a dental porcelain ceramic containing a glass phase when the ceramic is heated to a glazing temperature for a specified time. 7 GLAZES AND ADD-ON PORCELAIN  Glazing is done so to produce enamel like lustre after occlusal and morphologic corrections have been made in a porcelain restoration.  Provides transverse strength  Unglazed porcelain  lead to abrasive wear of the opposing dentition or  increase the rate of plaque accumulation 9 Glazing can be of two types:  Self glazing (auto glazing)  Add-on glazing. 7  The aim of glazing is  Sealing of open pores in the surface of fired porcelain.  These are medium –fusing feldspathic porcelain is much stronger than ground.  glazing occurs at temperatures of 955-1065oC.  Add-on glazes /over glaze  The surface coating of glass formed by using thin layer of glass powder that matures at a lower temperature than that associated with the ceramic substructure.  These are uncolored glasses whose fusing temperatures have been lowered by the addition of glass modifiers.  Add-on porcelains should exclusively be used for simple corrections of tooth contour or contact points  Disadvantages of add-on glazes are 15 . and are best used at the same temperature as the dental porcelain.  If the glaze is removed by grinding .  Add-on porcelains are generally similar to glaze porcelains except for the addition of opacifiers and color pigments.the transverse strength is reduced By 40-46% compared to unglazed porcelain. rough.

Voids and blebs greatly reduce the strength of porcelain.000 psi 5. Blebs are internal voids tend to reduce the specific gravity of porcelain.0% High fusing Low fusing - Refractive index - 1.2 to 2.Seminar -3 o its low chemical durability.000 psi 16. o Difficult to apply evenly and almost impossible to attain a detailed surface characterization. 4. 2. The compressive strength is quite high compare to tensile or shear strength. as clinician will adjust the occlusion by grinding the surface of the porcelain with diamond bur. 5. 3.54 1. The tensile strength is low because of the unavoidable surface defects. which removes the glaze and markedly weakens the porcelain and surface is left in a rough condition.9 PROPERTIES Compressive strength Tensile strength Shear strength Elastic modulus Linear coefficient of thermal expansion Specific gravity Liner shrinkage 50. This observation is of clinical importance because after the porcelain prosthesis is cemented in the mouth. 16 .8  Wiley (1989) stated that many studies have shown that polishing porcelain gives a smooth surface similar to that produced from a natural glaze.52 to 1. 8  Many ceramists prefer polishing instead of glazing to control the surface Iustre.9  Studies have shown that porcelain with highly polished surface have comparable strength with glazed porcelain.3 11.000 psi 10X106 psi 12X10-6 / C 2.5% 14. The shear strength is low because of lack of ductility in the material.

Chemically stable. b.1% deformation is sufficient to fracture porcelain before fracture. If a sodium-containing glass article is placed in a bath of molten potassium nitrate. d. f. Development of residual compressive stresses 2. Uranium oxide / cerium oxide is added to match the fluorescence of porcelain to that of the natural tooth. There are several techniques for introducing these residuals compressive stresses into the surfaces of ceramic articles.  Ion exchange  Thermal tempering  Thermal Compatibility: Ion Exchange:  The technique also called chemical tempering. a common constituent of a variety of glasses. e. The brittleness  0. 7.Seminar -3 6. Porcelains extremely hard materials and because of this property offer considerable resistance to abrasion. The squeezing of the potassium ion into the place formerly occupied by the sodium ion creates large 17 . Conducive to gingival health – as it prevents plaque addition. potassium ions in the bath exchange places with some of the sodium ions in the surface of the glass article. 7 STRENGTHENING OF DENTAL PORCELAIN METHODS 1. Highly biocompatible.  The potassium ion is about 35% larger than the sodium ion. Interruption of crack propagation DEVELOPMENT OF RESIDUAL COMPRESSIVE STRESSES:  Strengthening is gained by virtue of the face that the residual stresses must first be negated by developing tensile stresses before any net tensile stress develops. c. 8. This could be a disadvantage in that it causes excessive wear of the opposing natural tooth structure or the restorative material.  This process involves the exchange of larger potassium ions for the smaller sodium ions. 9. Corrosion resistant. Relatively inert. Solubility is less. Three of these methods are discussed below. Porcelain: a.

Thermal Tempering:  The most common method for strengthening glass is by thermal tempering.  Not all ceramics are amenable to ion exchange.  However. and. contact with acidulated phosphate fluoride over a cumulative time of 3 hours removes most of the ion-exchanged layer as well. the porcelain should be under slight compression in the final restoration.  Thermal tempering creates residual surface compressive stress by rapidly cooling (quenching) the surface of the object while it is hot and in the softened (molten) state. Thus. For example.  Consider three layers of porcelain: 18 . As the molten core solidifies.Seminar -3 residual compressive stresses (roughly 700 Mpa 100. a metal expands approximately the same amount when heated from 50 oC to 60oC as it does from 200oC to 210oC. Thermal Compatibility:  Most metals expand linearly with temperature up to the melting range. the thermal expansion or contraction of the porcelain cannot be precisely matched to that of the alloy. The pull of the solidifying molten core. DICOR glass-ceramic core material. it tends to shrink. as it shrinks. These residual compressive stresses produce a pronounced strengthening effect. it is more effective to quench hot glass-phase ceramics in silicone oil or other special liquids rather than using air jets as it may not uniformly cool the surface. creates residual tensile stresses in the core and residual compressive stresses within the outer surface. this process is best used on the internal surface of a crown. This objective is accomplished by selecting an alloy that contracts slightly more than the porcelain on cooling to room temperature. This rapid cooling produces a skin of rigid glass surrounding a soft (molten) core. they have different values in different temperatures ranges. but the outer skin remains rigid. Furthermore. and some conventional feldspathic porcelain that are highly enriched with potash feldspar (K2O.  Ideally. veneer. Al2O3.  Dental porcelains behave differently.6SiO2) cannot be sufficiently ion exchanged with potassium to warrant this treatment.000 psi) in the surfaces of glasses subjected to this treatment. as a result.  For dental applications. or inlay because this surface is protected from grinding and exposure to acids. alumina core materials.  One study has shown that grinding of only 100 m from an external surface reduces the strength of the treated structure to its original value.

thereby strengthening the crown. The technique has found application in dentistry in the development of aluminous porcelains (A1 2O3 particles in a glassy porcelain matrix) for PJCs. The other relies on a crystal structural change under stress to absorb energy from the crack. these microscopic crystals will disrupt crack propagation. One type relies on the toughness of the particle to absorb energy from the crack and deplete its driving force for propagation. on cooling to room temperature. the glass is toughened and strengthened because the crack cannot penetrate the alumina particles as easily as it can the glass. so that the metal contracts slightly more than the porcelain on cooling from the firing temperature to room temperature. the inner layer produces compressive stresses in the outer layers as previously described for thermal tempering.8 INTERRUPTION OF CRACK PROPAGATION Disruption of Crack Propagation : A further.  A similar rationale applies to porcelains and alloys for metal-ceramic restorations. The cast glass crown is subjected to a heat treatment that causes micron-sized mica crystals to grow in the glass. These methods of strengthening are described later Dispersion of a Crystalline Phase: When a tough.  When the layers are bonded together and the bonded structure is allowed to cool to room temperature. In most instances. yet fundamentally different.  The inner layer has a higher coefficient of thermal contraction and thus contracts more as it cools. Hence. This mismatch leaves the porcelain in residual compression and provides additional strength for the restoration. crystalline material such as alumina (Al2O3) in particulate form is added to a glass. method of strengthening glasses and ceramics is to reinforce them with a dispersed phase of a different material that is capable to hindering a crack from propagating through the material. When glass-ceramic restorations are subjected to high tensile stresses.  The metal and porcelain should be selected with a slight mismatch in their thermal contraction coefficients (the metal thermal contraction coefficient is slightly larger).Seminar -3  the outer two of the same composition and thermal contraction coefficient  The middle layer of a different composition and a higher thermal contraction coefficient. the use of a dispersed crystalline phase to disrupt crack propagation requires a 19 . There are two different types of dispersions used to interrupt crack propagation. Another ceramic dental material that uses reinforcement of a glass by a dispersed crystalline substance is Dicor glass-ceramic.

the void space comes down to 22 percent. The condensation occurs towards the blotted or 20 .  If only one-size particles are used. glycerin. 8  Two important factors.  With two sized particles. and this scattering produces an opacifying effect that may not be aesthetic in most dental restorations. As a result. However. CONDENSATION OF DENTAL PORCELAIN The process of bringing the particles closer and of removing the liquid binder is known as condensation. Transformation Toughening: A new technique for strengthening glasses involves the incorporation of a crystalline material that is capable of undergoing a change in crystal structure when placed under stress. are  The size and shape of the powder particles. One drawback of PSZ is that its index of refraction is much higher than that of surrounding glass matrix. and with three or more sized particles. even the greatest condensation is expected to leave a void space of 45 percent between the particles. Experimental work has shown that transformation toughening may be a viable method for strengthening dental porcelains. The energy required for the transformation of PSZ is taken from the energy that allows the crack to propagate. The crystalline material usually used is termed partially stabilized zirconia (PSZ). 7  Several methods of condensation are employed (1) Vibration method. which is then drawn away with a fine brush or clean tissue. the void space is reduced to2 5 percent. propylene glycol or alcohol has also been tried.  Distilled water is the liquid binder used most commonly.  The shape of the powder particles also governs the packing density.  The aim of condensation Is to pack the particles as close as possible in order to  reduce the amount of porosity  Shrinkage during firing. the particles of PSZ scatter light as it passes through the bulk of the porcelain. which determine the effectiveness of condensation.  System that uses three sizes of powder is known as the gap grading system. Round particles produce better packing compared with angular particles.Seminar -3 close match between the thermal contraction coefficients of the crystalline material and the surrounding glass matrix. This brings the excess water on to the surface. the paste is applied on to the platinum matrix and vibrated slowly.

a large soft brush is moved in a light dusting action over the wet porcelain. sufficient amount of liquid should be present so as to wet all the powder particles.  The role of firing is simply to sinter the particles of porcelain powder together to form a dense restoration. the wet particles are pulled together. As the liquid is withdrawn. it imparts low amplitude. The mix is first vibrated and then whipped with a brush. surface tension causes the powder particles to pack closely together. 8 (4) Whipping method. As the water is drawn towards the dry powder. a small spatula is used to apply and smooth the wet porcelain.Seminar -3        brushed area. (5) A combination of the vibration and the whipping methods can also be used. (3) Dry brush technique involves placement of dry powder onto the wet surface. Improves substructure of the porcelain & dispense trapped air & increase density Less shrinkage during firing Enhanced surface and strength FIRING PROCEDURE/ SINTERING PROCEDURE  Defined as process of heating closely packed particles to achieve interparticle bonding and sufficient diffusion to decrease the surface area or increase density of the structure. which is removed as described earlier. Excessive vibration should be avoided as it can cause slumping of the mass (2) Spatulation method. The most important factor in condensation is the effect of surface tension. The smoothening action disturbs the particles bringing them closer and also the water rises to the surface.  STAGES ARE  PREHEATING 21 .7 CERAMOSONIC CONDENSOR Through its ultrasonic function. This brings excess water to the surface and the same brush can be used to remove any course surface particles along with the excess water. high frequency vibration enabling Condensation of moist porcelain particle. The powder is placed by a brush to the side opposite from an increment of wet porcelain. The partial fusion or compaction of glass is referred to as sintering  Most of the thermo chemical reactions in porcelain are completed during the manufacturing process. However.

Second change occurs with a further rise in temperature when the particles fuse together by sintering. After the mass has been fired. This permits removal of excess water and prevent the sudden production of steam that could result in voids or fractures  After pre heating for approx 5 min. it is cooled very slowly because rapid cooled might result in surface cracking and crazing. During firing slow heating is done . Porosity reduces both translucency 22 . As the sintering of the particles begins. POROSITY Bubbles or voids in the fired porcelain are caused by inclusion of air during firing or in some cases as a by-product of vitrification of feldspar.the porcelain is sintered within a range of atleast 30oC to 50oC below the maximum firing temperature.as temperature is raised.Seminar -3  The condensed mass is placed in front of or below the muffle of a preheated furnace at an approximately 650 C (1200 F) for low fusing porcelain. Different media can be employed for firing like: A) Air B) Vacuum C) Diffusible gas AIR FIRING PROCEDURE: Whenever air-firing methods are employed. after which temperature is maintained for specific time till the reaction is completed .34% for high fusing). the porcelain particles bond at their points of contact .  FIRING Can be fired by following methods  Temperature controlled method:furnance temperature is raised at a constant rate until a specified temperature is raised  Temperature –time control method: furnace temperature is raised at a given rate until a preset temperature is reached. the porcelain is placed into the furnace and firing cycle is initiated.preferred method as produces uniform restoration. a very slow maturation period is preferred to allow for the maximum amount of entrapped air to escape. the sintered glass gradually flows to fill up the air spaces. Such a temperature will mature porcelain without loss of color and high densities can be achieved. there occurs a decrease in volume referred to as firing shrinkage (32-37% for low fusing and 28.  At the initial firing temperature the voids are occupied by the atmosphere of the furnace. As a continuous mass is formed.

The interstitial spaces are hence reduced before the surface skin seals off the interior too rapidly. It works on the basis of removing air or atmosphere from the interstitial spaces before surface sealing occurs. and vacuum should be applied before the placement of porcelain in the hot zone of furnace. which make them highly opaque. high temperatures can cause swelling of these blisters. Prolonged application can force the residual air bubbles to rise to the surface and cause surface blistering. 4. Fewer bubbles. This results in very dense porcelain with very few remaining bubbles and that too of extremely small size.. clear that porcelain powders fired in air must be of necessarily coarse nature. even of large size. Large sized particles have fewer but larger air voids between them compared to small sized particles. When air at normal atmospheric pressure is allowed to enter the furnace. Factors to be kept in mind while firing porcelain in vacuum are: 1.e. On the other hand. some of it is left behind. Vacuum firing cannot reduce the large sized bubbles to any significant degree. With the increase in temperature and because of surface tension. 2. therefore. It is. it is necessary to avoid porcelains with large interstitial spaces i. porcelain powders with small sized particles are preferred. DIFFUSIBLE GAS FIRING In this technique. 3. This permits the dense skin to hydraulically compress the low-pressure internal voids. Although the vacuum (760 torr) removes most of the air from interstitial spaces. it exerts a compressive effect on the surface skin.Seminar -3 and strength of dental porcelain. the remaining air spaces assume a spherical appearance. Translucency depends on the number and size of the entrapped air bubbles. which further compresses the internal voids to one tenth of their original size. hydrogen or steam is substituted for the ordinary furnace temperature. Air is driven out of the porcelain powder bed and 23 . Hence. VACUUM FIRING This technique is used to reduce porosity in dental porcelains. a diffusible gas like helium. give improved translucency. Vacuum should not be applied after the surface skin has sealed and the porcelain has matured. The vacuum should be broken while the work is still in the hot zone of the furnace. fine sized particles have multiple small air bubbles present in between them. Porcelain powders must be dried slowly to eliminate the water vapour. Additionally.

but the flow of glass grains is increased.7-8 VARIOUS STAGES OF MATURITY Several stages of dental porcelain have been identified when it is „sintered‟ or „fired‟. In the case of non-Feldspathic porcelains.metal bond and mask the color of substructure. staine to improve the esthetic appearance and glazed.Seminar -3 replaced by the diffusible gas. This occurs because these gases diffuse outward through the porcelain or actually dissolve in porcelain. a metal substructure is waxed. Shrinkage is minimal and the fired body is extremely weak or friable. The grains of porcelain begin to soften and „lense‟ at their contact points. With these gases. The fired body is strong and any corrections by grinding can be made prior to final glazing at this stage. To fabricate this restoration. but decrease in size or disappear. thereby completely sealing the surface and presenting smoothness to the porcelain. The common terminology used for describing the surface appearance of unglazed porcelain is „bisque‟.7-8 METAL CERAMICS: The chief objection to the use of dental porcelain as a restorative material is its low strength under tensile and shears stress conditions. finished and heat treated (oxidized). shaped. Medium bisque: Pores still exist on the surface of porcelain. cast. a slight shine appears at this stage. Then enamel and dentine porcelains referred as incisal and body porcelains. As a result. Low bisque: The surface of porcelain is quite porous. A definite shrinkage is evident. are fused to the opaque porcelain.a thin layer of opaque porcelain is fused to the oxidized metal surface to establish porcelain.8 24 . High bisque: The flow of glass grains is further increased. the interstitial spaces do not enlarge under the influence of increasing temperature. any entrapped furnace atmosphere that could not escape via the grain boundaries becomes trapped and sphere shaped. The method by which this disadvantage can be minimized is to bond the porcelain directly to a cast alloy substructure made fit the prepared tooth.

Gold –platinum-palladium alloys 2. Gold –platinum-tantalum alloys LOW GOLD 1.Seminar -3 TYPES OF METAL CERAMIC SYSTEMS A large number of metal-ceramic systems have been developed for the use in dentistry and they may be classified as follows: NOBLE METAL ALLOY SYSTEM: HIGH GOLD : 1. Mechanical 2. 25 . Rough surface enhances the bond resistance against induced shear stresses especially for base metal alloy system. Compressive 3. Therefore metal porcelain bond can be classified into 3 main components: 1. Cobalt –chromium alloys10 THE NATURE OF METAL CERAMIC BOND THE success of metal –ceramic crowns and fixed bridges depends upon the firmness of the bond between metal and ceramic. Enhancement of wettability of the metal substrate by porcelain 2. Chemical MECHANICAL RETENTION: Depends upon good wetting of the metal or metal oxide surface by the porcelain. Nickel chromium alloy 2. Advantages of an air abraded surface over smooth surface for noble metal alloys and base metal alloys are: 1. Some additive bond strength because of mechanical interlocking of porcelain under compression.Palladium silver alloys BASE METAL ALLOY SYSTEM: 1. Gold –palladium-silver alloys GOLD FREE: 1.

Metal –metal oxide: 26 .seen when Metal surface is completely depleted of oxide prior to the baking of porcelain or when no oxides are available. 2.Seminar -3 3. CHEMICAL BONDING: A bulk diffusion of base metal atoms produces an oxide film on the metal surface which forms a chemical bond with porcelain. METAL –PORCELAIN: The interfacial fracture occurs leaving a clean surface of metal. May also be due to conyaminated or porous metal surfaces. 3. at the metal ceramic interface 2. Common in base metal alloy system. Metal –oxide porcelain: The metal oxide porcelain at the metal oxide surface leaving the oxide firmly attached to the metal. Excessive roughness resulting in stress conc. Steep interface angles that may not allow complete wetting and therefore result in air entrapment and voids at the metal ceramic interface. COMPRESSIVE STRESSES: COMPRESSIVE STRESSSES Developed during cooling of sintered porcelain veneer will also play a part in improving the bond strength.8 TYPES OF METAL/ PORCELAIN FAILURE: 1. Increased surface area for porcelain chemical bonding Disadvantages are: 1.

Metal oxide – metal oxide: This fracture occurs through the metal oxide at the interface and results from an over production of the oxide causing sandwitch effect between metal and porcelain. Most unlikely type of fracture for the individual metal –ceramic crown. 9(2):86 Advantages • • • • • • • Increased translucency Improved fluorescence Greater contribution of color from the underlying tooth structure Inertness Biocompatibility Resistance to corrosion Low temperature / electrical conductivity 27 . 6.10 ALL CERAMIC SYSTEMS The term of “All ceramic” refers to any restorative material composed excessively of ceramic. such as Feldspathic porcelain. 5. alumina core systems and certain combination of these materials J. 4. An ideal situation is created when the oxide film is only a few molecules thick and forms a solid solution with the porcelain.Seminar -3 This is an interfacial fracture in which the metal oside breaks away from the metal substrate an d is left attached to the porcelain.in this case the bond strength exceeds the strength of porcelain. Where the joint areas in the bridges breaks. glass ceramic. Cohesive within metal This type of fracture would only occur in cases for eg. Common in base metal alloy system when there is over production of chromium and nickel oxide athe interface. Cohesive within the porcelain: This is the optimum type of fracture in which tensile failure occurs within the porcelain. Esthetic Dent 1997.this is the most common frature in the high gold content alloys.

Mechinable ceramic  Cerec Vitablocs Mark I and II  Celay Blocks  DICOR MGC ACCORDING TO Crispin 1994.  Resin-bonded ceramic systems: The support of the ceramic is provided by the tooth structure itself. Procera AllCeram. Al 2 O 3 and a glass (In-Ceram).Ceram). Rosenblum and Schulman 1997): 11 • Castable Ceramic Systems: They are modelled in a wax (Dicor. Infiltrated ceramic  In-Ceram 4. • Infiltrated Ceramic Systems: They are based on the principle of two infiltrated phases. • Pressable Ceramic Systems: They are produced by molding under pressure and heat (IPS Empress. Castable ceramic  DICOR  Cera Pearl 5. Cerapearl). Conventional powder slurry ceramic  Hi Ceram – Alumina reinforced porcelain  Optec HSP – Leucite reinforced porcelain  Duceram LFC – Hydrothermal low fusing ceramic 2. • Machinable Ceramic Systems: They are based on taking an optical impression of a patient‟s oral situation and have a restoration milled from a ceramic block chairside with CAD/CAM and copy-milling systems (Cerec Vitablocks. Procera All. which has the necessary high strength and toughness‟ but may lack the desired aesthetics (In-Ceram. Cerec. Celay). Celay. Optec) ACCORDING TO supporting structure (Van Noort 2002)  Reinforced ceramic core systems: The support for the aesthetic ceramic is provided by another ceramic material.Seminar -3 CLASSIFICATION7 1. by bonding the aesthetic ceramic directly to the enamel and dentine. Pressable ceramic  IPS Empress  Optec Pressable ceramic 3. Dicor MGC. In this instance the ceramic provides the necessary aesthetics and the strength is provided by the ability to bond to 28 .

bonded ceramic restorations are varieties of glass –ceramics. to avoid excessive opacity which occurs because of difference in the refractive index of glass porcelain and alumina crystals. The 2 imp requirements when using these filler reinforced porcelains are: Bond between filler particles and matrix Identical CTE of the two phased If CTE of Glass matrix > alumina crystals. there would occur radial compression and tangential tension in the glass matrix on cooling resulting in decrease in Elasticity and strength.Seminar -3 the tooth tissues. elasticity and fracture toughness compared to conventional porcelains. dispersing alumina Crystals of high strength and elasticity in a glass matrix. Conventional powder slurry ceramic ALUMINA REINFORCED PORCELAIN It was introduced by McLean and HUGES in 1965. For dental purpose single crystals of alumina are preferred over fine powdered alumina. Glass used for incorporating alumina crystals is BOROSILICATE GLASS Containing:  Silica  Alumina  Potash  Soda  Lime  Boric acid  Strength and opacity of aluminous porcelain is dependent on alumina crystal:  Size  Shape  Concentration SIZE OF ALUMINA CRYSTALS: 29 .e. A core structured is formed that has increased flexure Strength. to improve strength by Prevention of crack propagation. The materials available for resin. These are based on the principle of dispersion strengthening i.

Higher concentration Prevent complete flow and wetting by the glass matrix.higher than conventional Feldspathic porcelains 30 . more translucent Dentin and enamel Porcelain. Grain size on average should be 25 µm (max.  The buildup.6%  These porcelains contain dispersed LEUCITE {potassium aluminosilicates} in glassy Matrix. due to high difference in refractive index of the two component .  Because of its increased strength it does not require core when used to fabricate All ceramic Restoration as is necessary with aluminous porcelain PJCs.good translucency  Moderate flexure strength . Concentration of alumina crystals should range from 40-50% by weight. being37 µm) that would allow light transmission of atleast 10-15% on 1 mm thick discs and fine enough to give sufficient strengths.  Lecuite and glass matix are fused together during the baking process at 1020 C. Coarse grain size: reduces strength because of the “notched effect” created on glass boundaries. They are opaque. but results in increased opacity. Uses:  Used both for incisal and body portions being more aesthetics Advantages:  Lack of metal or opaque substructure .7-8 LEUCITE REINFORCED PORCELAIN:  Commercially available as OPTEC HSP  Leucite conc. defeating the esthetics. Shape: rounded grains are preferable over angular ones as latter interface with the flow of the glass Phase producing flaws around grains and reducing strength.which causes increased scattering of light. Uses: Forming refractory framework capable of supporting weaker.Seminar -3 Finer the grain size: greater is strength .Therefore more stronger than conventional Feldspathic porcelains. Commercially available product is Hi-Ceram (Vita). condensation and contouring is done using powder slurry technique on special semi permeable die material. is:50.

Lang BR. Restoration from Duceram LFC is made in 2 layers: The base layer is Duceram metal ceramics (Leucite containing porcelain) which is placed on refractory die using powder slurry technique and then baked at 930 C.  Available in variety of shades and can be characterized by variety of stains and modifiers.Seminar -3  Ability to be used without any special lab equipments Disadvantages:  Margins inaccuracy caused by porcelains sintering shrinkage  Potential to fracture in posterior teeth  High wear of opposing tooth due to high Leucite content No clinically published studies on Optec HSP DUCERAM LFC:  Also known as hydrothermal low fusing ceramics.  It is then strengthened by ion exchange mechanism involving h hydroxyl ions thus decreases the surface micro flaws and increase fracture resistance. composed of an amorphous glass containing hydroxyl ions. the result of 1 year clinical study recently conducted for manufacture r seems to indicate that the material wears at a rate equivalent to that of natural tooth enamel ( Showtwell J.Beard CC.unpublished data 1990). Over the base layer is Duceram LFC is applied using powder slurry technique and then baked at 660 C. veeners. the hardness of the materials and its ability to abrade the opposing natural tooth structure is reduced. However.  However.  Properties: compared to Feldspathic porcelain  Greater density  Higher flexure strength  Greater fracture resistance  Lower hardness  Because of the absence of Leucite crystals. USES: Ceramics inlays.  It is a low fusing ceramic. there are no clinical studies to substantiate the manufactures claim that the material is less abrasive than feldspathic porcelain. Lang B. and full contour crowns PRESSABLE GLASS CERAMIC 31 .

ADVANTAGES :      Lack of metal Translucent ceramic core Moderately high flexure strength Excellent fit Excellent aesthetics DISADVANTAGES:  Potential to fracture in posterior areas  Use of resin cement to bond crown micromechanically to tooth structure  Require special equipment. needles or plates formed during this ceramming process serve to interrupt the propagation of the cracks in the material when intraoral force is applied. feldspathic porcelain is added to the surface to obtain full contour and the correct shade.  A full contour crown is waxed.  The ceramic ingots are placed under the plunger.  In the veneering technique. the entire assembly is heated to 1150C and the plunger presses the molten ceramic into the mold.  The final shade of the crown is adjusted by staining or veneering. and then subjected to a heat treatment to induce partial devitrification (that is loss of glassy structure by crystallization of the glass). OPTEC PRESSEABLE CERAMIC : 32 . causing increased strength and toughness. invested and placed in specialized mold that has an aluminium plunger.  The ingot are heated and molded under pressure to produce the restoration.(pressing oven and die material.) IPS EMPRESS :  A leucite-reinforced glass-ceramic material was first described by Wohlwend and Scharer12  This type of Feldspathic porcelain is supplied in the ingot form.Seminar -3  IPS empress  Optec pressable ceramics A glass ceramics is material that is formed into desired shape as a glass. The crystalline particles.3 mm. the original wax –up is cut by about 0.  After molding and baking as described.

full crowns. 27 vol % glass and 5 vol % porosity12 The microstructure consists of blocky alumina grains of various sizes and shapes. 7. sintered. Three crystalline phases are available. one composed of the glassy phase and the other being the crystalline infrastructure. namely alumina (Al 2 O 3).8 Alumina-based slip-cast ceramics contain 68 vol % alumina. for veenering conventional powder alurry techniques with high Leucite content Feldspathic porcelain. processed by molding under pressure and heat.  Can be used as core material.  Used for –  Full contour restoration : inlays. and later infiltrated with a lanthanum-based glass.Seminar -3  Type of Feldspathic porcelain with increased lecucite content. spinel (MgAl 2 O 4 ) and Zirconia-alumina (12 Ce-TZP-Al 2 O 3 ). veneers.11 INFILTERED CERAMICS: IN-CERAM  SADOUN developed INCERAM in 1985 In-ceram is supplied as one of the three core ceramics:  In-ceram spinnel  In-ceram alumina  In-ceram zirconia The slurry of one of these materials is slip cast on a porous refractory die and heated in the furnace to produce a partially sintered coping and framework.  Crystalline Leucite particle size is reduced and content is increased which result in increase in flexural strength  Because of high Leucite content abrasion of opposing natural teeth is high. similar to Optec HSP porcelain. producing two interpenetrating continuous networks.8. bridging and crack deflection was reported with this type of 33 . 4 Thus A porous infrastructure is produced by slip-casting. The partially sintered core is infiltered with glass at 1100 C for 4 hours to eliminate porosity and to strengthen the slip cast core. Evidence of grain pull-out.

accompanied by micro crack nucleation. account for some degree of opacity in this all-ceramic system. INDICATION: In-ceram spinnel: Anterior single unit inlays. The dual crystalline reinforcement in this system allows two types of strengthening mechanisms: (1) The stress-induced transformation in zirconia grains produces compressive stresses within the transformed grains and surrounding glassy matrix. with about 8 vol % residual porosity . (2) Crack deflection. The presence of large alumina crystals with a high refractive index. Spinel-based slip-cast ceramics offer better translucency . In clinical situations where maximum translucency is needed In ceram alumina: Anterior and posterior crowns Anterior 3 unit prosthesis 34 . The glass phase represents approximately 23 vol % of the final product.Seminar -3 ceramic indicative of efficient crystalline reinforcement.onlays crowns and veeners. as well as circumferential tensile stresses around the grains. contact shielding and crack bridging are expected from the presence of large alumina grains The combination of these two strengthening mechanisms explains why alumina-zirconia slip-cast ceramics offer the highest flexural strength and fracture toughness of all slip-cast ceramics. and accounting for mechanical properties in the range of heat-pressed lithium disilicate glass-ceramics. Transgranular fracture is difficult in zirconia. similar to that of lithium disilicate heat-pressed ceramics. and a non-negligible amount of porosity. this represents an efficient strengthening mechanism. It has also been suggested that the coefficient of thermal expansion mismatch between the alumina crystals and the infiltration glass could contribute to strengthening due thermal residual stresses. at the expense of mechanical properties Zirconia-toughened alumina slip-cast ceramics comprise 34 vol % alumina and 33 vol % of 12 mol % ceria-stabilized zirconia (12Ce-TZP).

which packs the particles into a rigid network. The alumina powder is mixed with deionized water supplied in pre-measured container. The low viscosity lanthanum glass is used to infiltrate the alumina core in INCERAM. The water is removed by the capillary action of the porous gypsum.2% thus an interconnected porous network is created connecting pores on the outer surface with those on the inner surface. This solution of alumina is referred to as “slip” which is then painted onto the gypsum die with a brush. Dispensing agent is added to create a homogenous mix of alumina in water. The cycle involves a slow heating of approximately 2oC/min to 1120oC for 2 hours to produce approximation of the particles with minimal compaction and minimal shrinkage of alumina. then the INCERAM ALUMINA is applied onto the die. The aluminous core is then placed in the IN-CERAMET furnace and sintered. 35 . This mixture is sonicated in VITASONIC thus initiating the dispersion process. which is heated in the IN-CERMET to 1100oC for 4-6 hours. Sintering is only about 0. The glass is mixed with water and placed on a platinum – gold alloy sheet. The alumina is built up to form a core for the ceramic tooth. Low viscosity lanthanum aluminosilicate glass is used to fill the pores in the alumina. The external surface of the core is placed on the glass. Then vacuum is applied to remove the air bubbles. The INCERAM aluminous glass ceramic produced by lanthanum glass infiltration is about 50% translucent as dentin. Fabrication Procedure An All-Ceramic restoration system INCERAM is based on the slip casting of an alumina core with its subsequent glass infusion. This should be in air environment as recommended by the manufacture. The glass becomes molten and flows into the pores by capillary diffusion.Seminar -3 Inceram zirconia: Because of high strength and fracture toughness it is indicated for posterior crowns and FPD. The excess glass is removed by sandblasting with alumina particles. After the impression is taken the die is poured with special gypsum supplied with INCERAM. The last step is fabrication of INCERAM restoration involves application of aluminous porcelain to the core to produce the final form of restoration.

 Crystals are also less abrasive to opposing tooth structure. DICOR. Properties The physical properties of DICOR are given in the table. Classification of Castable Dental Glass Ceramics:  Flucoromicas Dicor  Apatite glass ceramics pearl  Other glass ceramics Lithia . g.  The fabrication method uses lost wax and centrifugal casting technique similar to those used to fabricate alloy castings.27 11000 25000 36 .Calcium Phosphate DICOR  A Polycrystalline glass ceramic is a material that is formed into the desired shape as a glass and subsequently heat-treated under controlled conditions to induce partial devitrification. CASTABLE GLASS CERAMIC The first commercially available castable ceramic material for dental use.  These crystals function in 2 ways:  They create a relatively opaque material out of the initially transparent crown and increase the fracture resistance and strength of the ceramic.cm3 Translucency Modulus of rupture psi Compressive strength.48 1500 58000 2. DICOR 2. This heat treatment is known as ceramming causes partial crystallization (55%) of tetrasilic mica like crystals.  A full contour transparent glass crown is cast at 1350 C then is heat treated at 1075 C for 10 hours. was developed by corning glass works and marketed by Dentsply international.4 0.7 0.56 22000 120000 FELDSPATHIC ENAMEL PORCELAIN 3.Seminar -3 In clinical situations where there is a discolored preparation or a cast post and core this increased opacity over the dentin is advantageous were as when maximum translucency is necessary INCERAM ALUMINA is problematic.0 0. PROPERTY Density.

Little discomfort occurs on contact with hot or cold foods because of its extremely low thermal conductivity and a coefficient of thermal expansion. The numerous small mica crystals that constitute castable ceramic closely match the index of refraction to the surrounding glass phase. Precision Of Fit The resistance of DICOR to chemicals and staining agents also compares favourably with conventional feldspathic porcelains. as mentioned before. There is no need for opaque porcelains to mask the metal substructure. However. These coarse grained opaque porcelains generally promote the adherence of plaque. the castable ceramic permits a one-piece restoration made entirely of the same material. The DICOR shading porcelains contain minimal abrasive opacifying agents. b.2 343 12.2 362 12. Tissue Acceptance DICOR is chemically inert and has shown to pass all the biocompatibility tests. A chameleon effect is seen with DICOR restorations in which the restoration acquires a part of the color from adjacent teeth and fillings as well as the underlying cement lute.Seminar -3 psi Modulus of Elasticity. Two reasons for this property are: a. psix106 Microhardness 10. 2. and no opaque substructure exists to impede light scattering. The periodontal tissue reaction to DICOR is considered quite favorable because 1. which closely matches that of natural enamel. 37 . Closely matching hardness between the cast ceramic material and natural enamel. The absence of an opaque layer allows the technician to obtain natural contouring often found in metal ceramic restorations. Application of an external coloring system allows independent control over hue. Little wear of the cast ceramic or the opposing dentition occurs when using DICOR restorations.0 450 Esthetic Qualities DICOR restorations are highly esthetic because of their translucency. In addition. which closely matches that of natural tooth enamel. chroma and value. there are chances of losing this external layer thereby defeating the best of esthetics.

Excellent marginal fit 2. Surface hardness and occlusal wear is similar to enamel 4. Because the crystalline constituent is similar to natural enamel.Seminar -3 Radiographic Qualities The radiographic density of DICOR is similar to that of enamel allowing proper evaluation of the underlying structures and the margins. They are essential for formation of hydroxylapatite crystals as well. Inherent resistance to plaque accumulation (seven times less than on the natural tooth surfaces). Uses Inlays. MgO (5%) helps in the formation of hydroxyapatite and along with CaO decreases the viscosity of the compound when melted. Further SiO2 regulates the thermal properties. CERA PEARL  Castable apatite ceramic was first developed by Hobo and Bioceram Group as CaO-P2O5-MgO-SiO2 glass ceramic. Advantages 1. Young‟s modulus – 103 Gpa 38 . SiO2(34%) in combination with P2O5 forms the matrix.0 x 10-6/oC. The Young‟s modulus. onlay. Chances of losing low fusing feldspathic shading porcelains. tensile strength and compressive strength of Cera Pearl are appreciably higher than conventional porcelains. CaO(45%) and P2O5 (15%) are the main ingredients in glass formation. MgO. Can reproduce wax patterns precisely by using the lost wax technique 5. Simple uncomplicated fabrication from wax up to casting. Disadvantages 1. Ease of adjustment 7. complete crowns and possibly partial tooth coverage restorations. Relatively high strength 3. ceramming and colouring 6. It is not indicated for fixed partial denture or removable partial denture abutments with deep rests or internal attachments. Physical properties • • Coefficient of thermal expansion: 11. which have been applied for good colour matching. SiO2 and traces of other elements. Excellent aesthetics resulting from natural translucency 8. Cera Pearl is quite biocompatible.  Cera Pearl is composed of CaO. P2O5.

The use of a shrink-free ceramic coping formed on an epoxy die by a transfer molding process overcomes the limits and firing shrinkage of conventionally 39 .Seminar -3 • Casting shrinkage – 0.53% • Flexural strength similar to Dicor • Biological properties – Dense material. and later sold to Johnson & Johnson.4SiO2 after heat treatment. It is fabricated using lost wax technique and then injection molding to produce a coping. A12O3. PH similar to natural enamel • Non toxic / biocompatible Lithia based glass ceramic Developed by Urgu Composition: It contains mica crystals and Beta spodumene crystals of LiO. Calcium phosphate glass ceramic • • Reported by Kihara and others Combination of calcium phosphate and phosphosus pentoxide plus trace elements • Cast at 1050°C in gypsum investment mold • Clear cast crown is converted to a crystalline ceramic by heat treating at 645°C for 12 hours Disadvantages • Weaker than other castable ceramics • Opacity reduces the indication for use in anterior teeth SHRINK FREE CERAMIC CERESTORE It is a shrink-free alumina crown developed by the Coors Biomedical Co. chemically stable. MgAl2O4 spinell and an alpha-alumina oxide make the core replaced by Alceram.

an innovative approach to fabricate same day restorations at the chair side in the dental office. strength and wear properties are similar to Feldspathic porcelain used for PFM restorations  Cerec Vitablocks Mark II This is feldspathic porcelains of increased strength and has finer grain size the mark I composition.Anderson developed Procera System He attempted to fabricate titanium copings by spark erosion and introduced CAD/CAM technology into the process of composite veneered restorations.  Dr.its composition.  This system later developed as a processing center networked with satellite digitizers around the world for the fabrication of all ceramic frameworks13 Machinable ceramic:  CAD/CAM ceramics: a ceramic restoration fabricated by use of a computer aided design and computer aided milling  Copy milled ceramics: a process of milling a structure using a device that traces the surface of a metal. ceramic or a polymer pattern and transfers the traced special positions to a cutting station. he began to fabricate crowns with an optical impression of abutment followed by designing and milling. Flexural strength: It is approximately 150 Mpa. 40 . The different types of ceramic ingots used in the process as follows: 11  Cerec vitablocks Mark I: This is a feldspathic porcelain which was the first composition used with the Cerec system (Siemens). ALTSCHULER in US & BRANDESTINI in Switzerland. Mormann developed CEREC System.  From 1971. MACHINABLE CERAMICS: Brief history:  Development of CAD-CAM (Computer Assisted Design-Computer Aided Manufacturing) system for the dental profession began in 1970‟s with DURET in France. The Cerestore coping is veneered with conventional aesthetic porcelain.  Dr.Seminar -3 produced aluminous porcelain jacket crowns.  Later he developed Sopha system.

A milling unit is used to prepare the restoration.5 µm ±19.Cerec introduced in 1980s. It has greater flexural strength than castable Dicor and Cerec composition. Designed restoration is transmitted to a remote milling unit for fabrication. After designing VITA In-cream blocks are used for milling. which is used by the milling device to create the shape from a restorative material CAD CAM SYSTEMS: CEREC : An acronym for chair side economic reconstruction of esthetic ceramic .Seminar -3 Less abrasive wear of the opposing teeth. With newer Cerec 3-D. enabling clinician to prepare multiple teeth in same quadrant and create a virtual cast for the entire quadrant.  The operator designs a restoration shape using the computer which generates a tool path. improved Cerec 2 introduced in 1996 and the advanced 3-D Cerec 3 in 2000. In vitro evaluation of marginal adaptation of crown of cerec 3-D (47.D caulk Division): This is a machinable glass ceramic composed of flurosilicic mica crystals in a glass matrix.procuses less abrasive wear. It is a fine grained Feldspathic porcelain with reduced wear of opposing tooth .  Celay: Can be used CAD-CAM produced restorations or used in the copy-milled technique.5 µm) was better compared with cerec 2 (97. an optical scanner is used to scan the prepared tooth or impression and a 3-D image is generated on monitor.0±33. The computer translates this information into a 3-D map (point could).  Dicor MGC (Dentsply L. designing and milling phases. Cerec in-lab is a lab system in which dies are laser scanned and image displayed on screen. the operator records multiple images within seconds.8 µm) 41 . The coping is glass infiltrated and veneer porcelain added. With Cerec 1 and Cerec 2. CAD/ CAM process:  A CAD/CAM system utilizes a process chain consisting of scanning.  The scanning device converts the shape of the prepared teeth into three dimensional (3-D) units of Information (voxels).

Once the master die is scanned the 3-D images is transferred through an internet link to processing center where an enlarged die is milled by a computer controlled milling machines. An in vitro study showed that marginal discrepancies of alumina and ziroconia based posterior fixed partial denture machined by the DCS system was between 60 µm to 70µm CERCON: Commonly referred to as a CAM system. a precision 42 . According to research data average marginal gap for Procera all Ceram restoration ranges from 54 µm to 64 µm CICERO SYSTEM (COMPUTER INTEGRATED CROWN RECONSTRUCTION) Introduced by Denison et al in 1999.3 µm respectively. leucite free cercon Ceram to provide esthetic contour. it does not have a CAD component. Marginal adaptation for cercon all ceramic crowns and fixed partial dentures was reported 31. The DCS software automatically suggests connector sizes and pontic forms for bridges. It is one of the few systems that can mill titanium and fully dense sintered zirconia.Seminar -3 DCS PRECIDENT: Comprises of a Preciscan laser Scanner and Precimill CAM multitool milling centre. Aluminum oxide powder is compacted on the die and coping is milled before sintering at a very high temp (>1550°C). The coping is sent back to the lab for porcelain veneering. It can scan 14 dies simultaneously and mill up to 30 frameworks unit in one fully automated operation. The system scans the wax pattern and mills a zirconia bridge coping from presintered zirconia blanks. Veneering is done with a low fusing.350°C for 6-8 hrs. metal and Ceramic sintering and computer assisted milling to obtain restoration. it is the first system which provided outsourced fabrication using a network connection.3µm and 29. it includes optical scanning. PROCERA ALL CERAM SYSTEM Introduced in 1994. This enlargement compensates for sintering shrinkage. Basic reconstruction includes layered life like ceramic for natural esthetics. This enlargement compensates for sintering shrinkage. Aluminum oxide powder is compacted on the die and coping is milled by a computer controlled milling machines. which is sintered at 1.

HOYA ConBio) is used to expose Subgingival margins. Milled framework undergoes sintering to attain final dimensions. The soft tissue diode laser offer precision.  The soft tissue diode laser (Odyssey Navigator. used for fabrication of zirconia framework for all ceramic restorations. It includes rapid custom fabrication of high strength alumina coping and semi finished crowns to be delivered to dental laboratories for porcelain layering / finishing. 43 . Studies on marginal adaptation of Y-TZP bridges processed with Lava system for 2 milling times (75 mins Vs 56 mins) did not affect the 16 marginal adaptat CAD/CAM Restorative Technique: 15  Consists of Handheld scanning device that digitally records the form and margins of the preparation.Seminar -3 milled occlusal surface and a machined high strength ceramic core. CAM produces an enlarged framework to compensate shrinkage.  The scanners require a dry field and soft tissue that must be thoroughly separate at the level of the margin from the hard tissue. Lava system uses a laser optical system to digitize information. that result in a narrow band of lased tissue. The Lava CAD software automatically finds the margin and suggests a pontic. DioDent Micro 980. density and strength. The aim of CICERO is to mass produce ceramic restoration at one integrated site. A partially sintered ziroconia block is selected for milling. LAVA CAD/CAM SYSTEM Introduced in 2002. This system uses yttria stabilized tetragonal zirconia poly crystals (YTZP) which have greater fracture resistance than conventional ceramics. and produces good hemostasis. Ivoclar Vivadent. GENTLEray 980. Kavo.

 Two basic techniques can be utilized for CAD/CAM restorations.Seminar -3 SOFT TISSUE DIODE LASER  Alternative soft tissue management techniques include electro surgery and standard manual retraction technique. Sirona.  Chairside – a single-visit technique  Integrated Chairside—laboratory CAD/CAM Procedure. Chairside CAD/CAM Technique:  The chairside technique involves scanning the preparation and then fabricating the restoration in the milling device (CEREC 3.max. was developed in The Netherlands and used a pressing. Leucite-reinforced glass ceramics (IPS Empress CAD. E4D. a very thin layer of powder is distributed over the preparation using the CEREC system. Paradigm C. sintering.  Prior to scanning.  For Chairside CAD/CAM restorations. Ivoclar Vivadent. CICERO. an esthetic.  The CEREC 3 uses still images. strong material requiring minimal post-milling esthetic adjustment to minimize Chairside time is needed.  Depending on the system used. Ivoclar Vivadent) Advantages         One-visit fixed restorative procedure No impression making No temporary restoration required Reduced potential for tooth sensitization No laboratory costs No model or die pouring Accuracy Less opportunity for error compared to traditional technique 44 . and milling technique prior to laboratory finishing of the restoration.  During scanning. D4D TECH). while the E4D uses a laser in the handheld scanning device  A third system. 3M ESPE) lithium disilicate glass ceramics (IPS e. the clinician can see the preparation magnified on the computer screen as the scan is being processed. the clinician must ensure that all margins of the cavity are captured by the scan and visualized.

ANTERIOR ESTHETIC ZONE15 Maxillary incisor pretreatment CAD/CAM milled & finished restoration Finished CAD/CAM restoration placed 45 .Seminar -3  Aids prep visualization  Projects a state-of-the-art image Disadvantages  Less conservative than direct composite fillings  Slightly less exacting fit than laboratory-made  Esthetic capabilities are limited 14  Soft tissue management more critical than with traditional technique  Depending on the material and patient. customization may be required  High learning curve  Higher production required to cover capital investment CASE 1.

Completed esthetic CAD/CAM restoration (IPSempress CAD) 46 . REPLACEMENT OF FAILING AMALGAMS CAD/CAM conservative preparation design preserves more of the natural tooth structure compared with a crown and offers the clinical longevity of gold without the esthetic drawbacks. When using the current generation bonding adhesives according to the manufacturer‟s instructions.Seminar -3 CASE 2. the CEREC ceramic will recreate a tooth like strength Amalgam restoration and caries pre-treatment preparation.

or for milling of the coping at the manufacturer‟s lab (iTero). Advantages         Automates steps or all of fixed restorative fabrication Accuracy Less opportunity for error compared to traditional technique Opportunity to subcontract CAD/CAM to avoid capital costs Opportunity to focus on artistic ceramics Scanned image transferred directly to the laboratory from the office Reduced Chairside time Team approach to fixed restorations Disadvantages  Requires two visits 47 .Seminar -3 INTEGRATED CHAIRSIDE—LABORATORY CAD/CAM TECHNIQUE  Requires two visits.  CEREC Connect (Sirona) and iTero (Cadent) scans either take a series of stills and send the digital image either to a laboratory for milling of the restoration (CEREC Connect). or can take a traditional impression.  ceramic blocks for laboratory-milled restorations are available as Zirconia (zirconium oxide) and lithium disilicate glass blocks.  Chairside scanning of a preparation and digital transmission to the laboratory can be achieved by several systems.  The clinician either can scan the preparation directly and then send the scan to the laboratory.  The external ceramic layer can be created either using press ceramics (in the same manner as for a traditional bridge) or layering ceramic material onto the substructure using a !ne brush and powder/liquid. after which a stone model is poured and the laboratory scans the stone model.

Seminar -3 Case Presentation: Integrated Chairside— Laboratory Technique Preoperative view: discolored central incisor with disparity in color crown and veneer preparation Scanning image from dental office CAD/CAM 48 impression milled using .

Seminar -3 In lab image of crown In lab image of veneer design Poured model and CAD milled wax restoration CAD ceramic blocks used for the Milled restoration ceramic layering in process 49 .

all ceramic system use specialcialized equipments and techniques. STRENGTH:  All systems have adequate strength for single units but significantly less than that of ceramic metal crowns.  IPS Empress and Optec pressable ceramic.  Ability of bonding to tooth structure provides additional strengthening mechanism. FABRICATION TECHNIQUES: With exception of Optec HSP and Duceram system.  Dicor is strengthened through the partial recrystallization of the glass through a ceramming process.  Duceram LFC. 4. So can be considered disadvantage because of the added cost of fabrication. the fit of the all ceramic crowns to the underlying tooth structure is extremely accurate.Compenstion for discrepancy or gaps can be made by using resin cements. MARGINAL FIT With exception of the machined ceramics restoration.Seminar -3 Final seated crown and veneer COMPARISON OF THE ALL CERAMIC SYSTEMS: 11 1. WEAR OF OPPOSING TOOTH STRUCTURE:  All of the Leucite containing all ceramic materials wears opposing natural tooth. 2. 3.  In-ceram has highest flexural strength values for all the ceramic system and can be used for multiple unit bridges.  IPS Empress>Optec HSP>Optec OPC>Dicor> Duceram 50 . strengthened by an ion exchange mechanism involving hydroxyl ions. strengthened by dispersion of Leucite crystals throughout their internal structure.

51 . the use of the all posts and cores was suggested as an alternative to solve the esthetic problems that metal posts and cores exhibit. corrosion products may deposit in the gingival tissues or cause root discoloration. Dense sintered alumina ceramic .Procera. Almost simultaneously with the introduction of the current all-ceramic systems.In ceram. Dental Ceramic material used for all ceramic post and core Ø Ø Ø Conventional dental ceramics High toughness ceramic .' The restoration of anterior nonvital teeth with metal posts and cores and all-ceramic restorations may lead to compromised aesthetics because of the semi translucence of ceramics and the opacious metal substructure of the underlying post and core. metal posts may also shine through in the cervical root areas. especially when nonprecious alloys are used for post-and-core fabrication. thus altering the appearance of thin gingival tissue. the metal post and core may shine through or at least decrease the depth of translucency of the restoration. Depending on the thickness and the opacity of the luting cement and the all-ceramic restoration. It provides an essential depth of translucency in the cervical root areas  Excellent biocompatibility and does not exhibit galvanic corrosion DISADVANTAGE:  Relatively low fracture strength and fracture toughness.'' Furthermore.Seminar -3 ALL-CERAMIC POSTS AND CORES: Endodontically treated teeth often need a post and core as foundation for the final restoration.' In addition. ADVANTAGES:  Dentine like shade it is related to the deeper diffusion and absorption of the transmitted light in the ceramic core mass  An all ceramic restorations transmits a certain percentage of the incident light to the ceramic core and the post on which it has been placed thus the color of the final restorations will be derived from an internal shade similar to optical behavior of the natural teeth  Does not reflect intensively through thin gingival tissues.

In.Seminar -3 Ø Zirconium oxide ceramics Techniques or construction of all ceramic post and core with high toughness ceramic materials Ø Slip casting technique Ø Copy milling technique Ø Two piece technique  Heat press technique SLIP CASTING TECHNIQUE:  described by Kem and Knode in 1991  core buildup and post are made in 1 piece from the aluminum oxide ceramic material. The Celay system involves a rnanually guided copy-milling process in which a predesigned resin pattern is surface traced and copied in ceramic.and crown-and-bridge framework fabrication." The cases of regular root canals (smaller than ISO 110). onlay. as an alternative to the slipcasting technique. for that reason. The ceramic substructures are prefabricated blanks made of presintcrcd aluminum oxide ceramic (Celay Alumina Blanks. InCeram ceramic does not seem to provide a sufficient strength. and its fabrication process have been adapted to the Celay copy-milling method (Mikrona). In-Ceram. In-Ceram ceramic restorations made with the Celay method present a 10% higher flexural strength (about 500 iVlPa) than do conventional In-Ceram restorations. TWO-PIECE TECHNIQUE: Because the fracture strength of In-Ceram posts and cores is less than that of metal posts and cores.  Used only in wide root canals without a crucial reduction of the circumferential dentin structure. Vita Zahnfabrik).Ceram posts and cores have only been recommended for wide root canals. In-Ceram. COPY MILLING RECHNIQUE: the glass-infiltrated alumina ceramic. This method can be used for inlay.as well as for copy-milled In-Ceram posts and cores. until 52 . veneer.

and therefore both materials are fused into a solid post-and-core restoration. 110} and supplement the existing ER-Post system (Brasseler). These transducers generate the ultrasonic acoustic waves and detect the reflected signals to form the image. Ivoclar). precerammed Leucite-reinforced glass-ceramic material is heated and pressed in an investment mold after the burnout of the wax analog (lost-wax technique). Gadgets for Dental Applications. it became possible to combine both materials. modern ceramic materials play an important role in gadgets used for medical diagnosis including both ultrasonic and X-ray computed tomography (CT) systems. The applications are based on the fact that when used as implants or even as coatings to metal replacements. promote tissue formation and provide protection from the immune system. HEAT-PRESS TECHNIQUE The heat-press technique has recently found application to an all-ceramic post-and-core construction.pressed over a prefabricated zirconium dioxide post (Cosmo Post. 090.diseased heart valves. and other body parts . In this system. For a 2-piece post-and. knees. fabricated either by the copy-milling or the slip-casing technique. Brasseler) is used in conjunction with an all-ceramic core made of alumina or alumina-magnesia'-* ceramics. Transducers utilizing lead zirconate titanate (PZT) based piezoelectric ceramics are the heart of ultrasonic systems. an all-ceramic post and core was not recommended for such eases.core construction a post made of yttrium oxide-partially stabilized zirconia (ER-Cerapost. 53 . After the recent development of zirconia ceramic posts. The zirconia ceramic posts are commercially available in three ISO sizes (050. a castable. It is based on the well-known IPS Empress system (Ivoclar).Seminar -3 presently. ceramic materials can stimulate bone growth. In the heat-press technique. Ivoclar) is heat.17 OTHER APPLICATION OF CERAMICS Ceramics in Medical Applications Ceramics are employed in a wide range in the medical specialty such as repair and replacement of human hips. Moreover. a glass-ceramic core (EmpressCosmo.

Hydroxyapatite and tricalcium phosphate are similar in composition to bone and teeth and can be used for augmentation of alveolar ridges and filling bony defects. The hard. Alumina.e.g.g. Polycrystalline (Hydroxyapatite) Glass (Bioactive glass) Glass ceramics (Ceravital) Composites (Stainless steel reinforced Bioglass) Types of Bioceramics There are about four types of bioceramics: INERT: Attached by compact morphological fixation. Piezo Ceramics Piezoelectricity can be defined as pressure electricity which is a property of certain classes of crystalline materials including natural crystals of Quartz. They are manufactured and are available in block.g. When mechanical pressure is applied to one of these materials.Seminar -3 Various recently introduced diagnostic and working tools of which ceramics play an integral part include: Radio Visio Graphy (RVG) Pulp tester Apex locators 1st generation . dense ceramics can be manufactured in almost any given shape or size. 2nd generation . when an electric field is applied. Hydroxyapatite 54 .impedance based 3rd generation . Bioceramics Bioceramics are a group of ceramics. Porous Alumina. They are more versatile with physical. e. Conversely. Bioglass. the structure changes shape producing dimensional changes in the material. the crystalline structure produces a voltage proportional to the pressure.resistance based. These bioactive materials are packed in the required site providing a scaffold for new bone growth and are Osseo-inductive in nature. chemical and piezoelectric characteristics able to be tailored to specific applications. e. The piezoelectric materials use polycrystalline ceramics instead of natural piezoelectric crystals. granular and injectable forms. SURFACE ACTIVE: Directly attach by chemical bonding with bone. Carbon POROUS: Attached by vascularisation through pores. Rochelle salt and Tourmaline plus manufactured ceramics such as Barium Titanate and Lead Zirconate Titanates (PZT). which are chemically inert and immune to moisture and other atmospheric conditions. The various forms of bioceramics are Single crystals (Sapphire).frequency based. which are biologically active materials rich in calcium and phosphate.

Ahmad I. Tamayo LFR. 3.p.Ceramics update. Chapter 21. 2. 20(1):7-11.6(3):33-37. Santander SA. Phillips Science of Dental Materials.Chicago.textbook of operative dentistry. Schulman .Artif. USA.J Dent 1997.J Am Dent Assoc 1997. 128:297-307 12. J Prosthet Dent 1996 . Nishimura I. 51(3): 713–727.e. Kelly JR.glazing and clinical applications. 17(9):593-598.Mclean JW: The science and art of dental ceramics.25:91 55 .1. such that now all-ceramic restorations can be used both anteriorly and posteriorly.types. 4.1st edition.Organs2006. 75 :18-32. Giordano R. Anuvanice KJ (Ed) Phillips RW. Ceramics for Dental restoration –An introduction. 8. Wahadni AA.A review of all ceramic restorations.Seminar -3 RESORBABLE Designed to be slowly replaced by bone.Qualtrough AJE . 10. Therefore need for dental practitioners to be aware of the rapidly changing field of dental ceramics to ensure that the correct choice is made for each patient.co.pg439-481. Pennsylvania. Dent Clin North Am.CBS publishers & didtributors.quintessence publ. 9. Sukumaran VG. 5. 11th Edition.1979. Griggs JA.vol. Chu S. Historical perspectives of synthetic ceramics and traditional Feldspathic porcelain. 2007. REFERNCES 1. 77(163):26-36.Pract Proced Aesthet Dent 2005. New Delhi India. Vargas AP. 7. Ceramics in dental applications. Campbell SD. WB Saunders Company. Monteiro FJ.chapter 19.Rosenblum MA. Tricalcium Phosphate4 CONCLUSION: There has been a revolution in the provision of ceramics for dental restorations in the last 15 years.Piddock V. pg692. Escobar JS. Sikri V. Dental news 1999. Ceramics in Dentistry : historical roots and current perspectives. Bharadwaj N. Al-Ajlouni RF. Dyna 2010. Khasawneh S. 11. Trend Biomater. The Compendium of Continuing Education in Dentistry 6. Dental porcelain: composition. McLaren EA Ceramics Overview: Classification by Microstructure and Processing Methods.72. Recent Advances in Materials for All-Ceramic Restorations.There is no doubt that new materials and processing routes will continue to be developed and that ceramics will play a growing role in the provision of aesthetic restorations.g.

351-368.Innovation in Dentistry: CAD/CAM Restorative Procedures 16.André V. 2002 15.Sneha SM.Koutayas SO.Seminar -3 13. Bhasin. 56 .II Issue 3 July – Sept. 1999. All ceramic posts and cores: the state of the art. 17.CAD/CAM in dental restorations: an overview Annals and Essences of Dentistry Vol. 3. 30(6):383-392. Ritter. Quintessence international. 2010 14. . Kern M. Ceramics for Dental Applications: Review Materials 2010.James Klim.Chairside CAD/CAM in Dentistry JERD15( 2 ). Holloway JA. Abhilasha S.Denry S. Corrales KV .