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Eciency of a Carnot engine

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The Carnot cycle makes an engine. The p-V diagram below sketches the operation of a Carnot engine, where the “working ﬂuid” that expands and contracts within the cylinder is an ideal gas.

p a

1 4

b

2

TH TL V

d 0 0

3

c

Here the high temperature TH and the low temperature TL are temperatures as measured on an ideal gas thermometer, that is pV T = . NR One cycle of the Carnot engine acts as follows: • Leg 1: Isothermal expansion at high temperature. As the gas expands, it lifts a big pile of sand — that is, it does work |W1 |. We’ve seen that expansion normally sends the temperature down. To keep the same temperature, the gas must absorb heat |Q1 | from its surroundings. • Leg 2: Adiabatic expansion. As the gas expands, it lifts a big pile of sand — that is, it does work |W2 |. The expansion sends the temperature down. Because it’s adiabatic, no heat is absorbed or ejected. • Leg 3: Isothermal compression at low temperature. As the gas contracts, it lets down a small pile of sand — that is, work |W3 | is done on the gas. We’ve seen that compression normally sends the temperature up. To keep the same temperature, the gas must eject heat |Q2 | into its surroundings. • Leg 4: Adiabatic compression. As the gas contracts, it lets down a small pile of sand — that is, work |W4 | is done on the gas. The compression sends the temperature up. Because it’s adiabatic, no heat is absorbed or ejected.

1

If there are currents in the gas. we’re interested in getting a large eﬃciency = net work done by gas |W1 | + |W2 | − |W3 | − |W4 | = . remember that the work done by a quasistatic ﬂuid is p(V ) dV. then one cannot even deﬁne a pressure in the way we’ve been using the term! Such currents will generally result in internal friction which throws oﬀ the work and heat calculations we’ll do soon. We’re interested in getting as large a net work as possible for a given amount of heat absorbed. That is. [[This formula applies only if the gas can be considered at equilibrium while the volume is changing.|Q1| expand at temperature TH |W4| |W1| adiabatic compression: temperature rises adiabatic expansion: temperature falls |W2| |Q3| compress at temperature TL |W3| Overall. but we’re stuck with “eﬃciency”. I actually prefer the name “duty” to “eﬃciency”. the gas absorbs some heat and ejects some heat. heat absorbed by gas |Q1 | (1) (James Watt had a similar measure that he called “duty”: the work in foot-pounds generated by a bushel of coal.]] 2 . Real engines with friction and currents and so forth will be less eﬃcient. The “net work done by the gas” is the work done by the gas minus the work done on the gas. The gas does some work and some work is done on it. If the piston experiences friction rubbing against the cylinder walls.) To ﬁnd the relevant quantities. In short. this calculation will ﬁnd the eﬃciency of an “ideal engine” using the working ﬂuid of an “ideal gas”. then the force will not be the same as pressure × area.

as expected. the gas does work by lifting something. the pressure and volume are related through pV γ = constant = pb Vbγ = pc Vcγ . 3 . in releasing air from a bicycle tire). V (2) W1 = a b p(V ) dV N RTH dV V a b dV = N RTH a V = b = N RTH ln(V ) a Vb = N RTH ln Va (3) Remember that Vb > Va . I’m going to ﬁnd a relation between temperature and volume that will turn out to be useful later: pb Vbγ pb Vb Vbγ−1 N RTH Vbγ−1 TH TL = pc Vcγ = pc Vc Vcγ−1 = N RTL Vcγ−1 = Vc Vb γ−1 (6) We’ve already said that an increase in volume will result in a decrease in temperature (for example. (4) (This derivation relies upon the already-stated fact that the energy of a given sample of an ideal gas is a function of temperature alone.) The heat absorbed merely counteracts the eﬀect of the work done. and this equation tells us quantitatively what that temperature change is. (In leg 1.) Leg 2: On this adiabatic expansion leg. so |Q1 | = |W1 |. not of temperature and volume. so this quantity is positive. (5) Before I calculate the work.Leg 1: On this isothermal expansion leg. the temperature is TH so p(V ) = The work done by the gas is then b N RTH .

this quantity is negative and |W4 | = −W4 = NR (TH − TL ) . The work done on the gas is |W3 | = −N RTL ln Furthermore. Leg 3: In the isothermal compression leg. this quantity is positive. the calculation of work done by the gas is performed exactly as it was in leg 1. and again as expected. Vc (8) Because Vd < Vc . the calculations are performed exactly as they were in leg 2. (10) Vc Vd = N RTL ln . γ−1 (7) Once again. this quantity — the work done by the gas — is negative. γ−1 (12) 4 . just as in leg 1. γ−1 (13) Va Vd γ−1 (11) NR (TL − TH ) . Referring to equation (3) we ﬁnd W3 = N RTL ln Vd .With this piece of bookkeeping out of the way. we go ahead and ﬁnd the work done by the gas: c W2 = b p(V ) dV c = 1 dV Vγ b 1 = constant V (−γ+1) −γ + 1 constant c b = = = = = 1 constant constant − −γ + 1 Vcγ−1 Vbγ−1 pb Vbγ 1 pc Vcγ − γ−1 −γ + 1 Vcγ−1 Vb 1 [pc Vc − pb Vb ] −γ + 1 1 N R [TL − TH ] −γ + 1 NR (TH − TL ) . Vc Vd (9) Leg 4: In the adiabatic compression leg. but of course with diﬀerent variables plugged in. but of course with diﬀerent variables plugged in. |Q3 | = |W3 |. Referring to equations (6) and (7) we ﬁnd TL = TH and W4 = As expected.

we ﬁnd TH = TL so Vc Vb γ−1 = Vd Va γ−1 Vc Vd = Vb Va or Vb Vc = . (14) TH This eﬃciency is independent of the details concerning volume and depends only on the two temperatures concerned.With all of the relevant quantities known we can go ahead and calculate the eﬃciency eﬃciency = |W1 | + |W2 | − |W3 | − |W4 | |W2 | − |W3 | − |W4 | =1+ . this is obvious for an ideal gas. (In retrospect. But lots of things are obvious in retrospect. To get a high eﬃciency (always a good thing) one wants the highest possible TH and the lowest possible TL . We didn’t need to evaluate W2 and W4 . 5 . Comparing equations (6) and (11). I am not ashamed. we ﬁnd eﬃciency = 1 − N RTL ln(Vc /Vd ) TL ln(Vc /Vd ) |W3 | =1− =1− . |Q1 | N RTH ln(Vb /Va ) TH ln(Vb /Va ) We seem to have found the ﬁnal answer.) Using our calculated values for |W3 | and Q1 . Vd Va The two natural logs in the expression for eﬃciency are equal! Our ﬁnal result for the eﬃciency of an ideal Carnot engine using an ideal gas as a working ﬂuid is the remarkably simple TL eﬃciency = 1 − . But there’s one more simpliﬁcation that can be performed. |Q1 | |Q1 | But our calculations show that |W2 | = |W4 |.

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