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59-240 Introductory Physical Chemistry Exercise and Problems - Lecture 13 Updated: November 9, 2009 - M3.

9 problems should have entropy decreasing, not increasing! Reading: Chapter 5, 7th edition, 3.7-3.9, 8th edition 7th edition: Set 1: 5.4, 5.5, 5.6, 5.7, 5.8, 5.9, 5.10, 5.12, 5.13 Set 2: 5.14a, 5.14b, 5.15a, 5.15b, P5.1, P5.5, P5.6, P5.7, P5.8, P5.9, P5.10, P.5.14, P5.21 8th edition: Set 1: M3.8, 3.16, 3.17, 3.18, M3.9, 3.19, 3.20, 3.21, 3.22 Set 2: M3.10, P3.22, P3.23a, P3.23b, M3.11, P3.24, P3.25, P3.26a, P3.26b, P3.27, P3.28, P3.30 P3.33 M3.8a (Ex. 5.4a, 7th edition) Express (MS / MV)T ' (Mp / MT)V in terms of and T. M3.8b (Ex. 5.4b, 7th edition) Express (MS / Mp)T ' &(MV / MT)p in terms of . M3.9a (Ex. 5.8a, 7th edition) When 2.00 mol of has at 330 K and 3.50 atm is subject to isothermal compression, its entropy decreases by 25.0 J K-1. Calculate (a) the final pressure of the gas and (b) the G for the compression. M3.9b (Ex. 5.8b, 7th edition) When 3.00 mol of has at 230 K and 150 kPa is subject to isothermal compression, its entropy decreases by 15.0 J K-1. Calculate (a) the final pressure of the gas and (b) the G for the compression. M3.10a (Ex. 5.14a, 7th edition) The molar Helmholz energy of a certain gas is given by a Am ' & & RT ln(Vm & b) % f(T) Vm where a and b are constants and f(T) is a function of temperature only. Obtain the equation of state of the gas. M3.10b (Ex. 5.14b, 7th edition) The molar Gibbs energy of a certain gas is given by Gm ' RT ln p % A % Bp % 1 2 1 Cp % Dp 3 2 3

where A, B, C and D are constants. Obtain the equation of state of the gas.

M3.11 (P5.1, 7th edition) Calculate rGo (375 K) for the reaction 2CO(g) + O2(g) 6 2CO2(g) from the value of rGo(298 K), rHo(298 K) and the Gibbs-Helmholz equation. Answers: M3.8a (Ex. 5.4a, 7th edition) See solutions slides M3.8b (Ex. 5.4b, 7th edition) See solutions slides M3.9a (Ex. 5.8a, 7th edition) (a) 15.7 atm; (b) 8.25 kJ M3.9b (Ex. 5.8b, 7th edition) (a) 274 kPa; (b) 3.45 kJ M3.10a (Ex. 5.14a, 7th edition) See solutions slides M3.10b (Ex. 5.14b, 7th edition) See solutions slides M3.11 (P5.1, 7th edition) See solutions slides A-list answers for the 8th edition: 3.16 -3.8 J 3.17 -36.5 J K-1 3.18 10 kJ 3.19 7.3 kJ mol-1 3.20 -0.55 kJ mol-1 3.21 10 kJ 3.22 11 kJ mol-1 P3.22 online solutions P3.23a solution manual P3.23b solution manual P3.24 online solutions P3.25 solution manual P3.26a online solutions P3.26b online solutions P3.27 solution manual P3.28 online solutions P3.30 online solutions P3.33 solution manual